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Sentinel-2A multispectral image analysis for seagrass mapping in Bintan’s shallow water ecosystem: A case study of Teluk Bakau, Malang Rapat, and Berakit villages 用于绘制民丹岛浅水生态系统海草图的哨兵-2A 多光谱图像分析:直落巴考、马郎拉帕特和 Berakit 村的案例研究
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-07-08 DOI: 10.1016/j.kjs.2024.100286

Seagrasses are in danger due to anthropogenic activities causing a reduction in seagrass area and global damage. It is crucial to map seagrass distribution, as there is limited information on its existence. Sentinel-2A satellite provides high-resolution multispectral data with a 10-m resolution. The study aimed to evaluate the ability of Sentinel-2A imagery from the Google Earth Engine (GEE) platform to classify with the random forest (RF) algorithm in mapping seagrass in shallow water and various other objects in the study area. The results showed the area's presence of seagrass, coral, sand, sand seagrass, and rubble. Also, the photo transect method was used for collecting field data. The random forest algorithm had an accuracy of 76% in classifying each of the five classes. The combination of Sentinel-2A imagery and random forest algorithms can provide insight into the status and distribution of seagrass.

由于人类活动造成海草面积减少和全球性破坏,海草正处于危险之中。由于有关海草存在的信息有限,绘制海草分布图至关重要。哨兵-2A 卫星提供分辨率为 10 米的高分辨率多光谱数据。该研究旨在评估谷歌地球引擎(GEE)平台上的哨兵-2A 图像使用随机森林(RF)算法进行分类的能力,以绘制研究区域浅水中的海草和其他各种物体的分布图。结果显示该区域存在海草、珊瑚、沙、沙海草和碎石。此外,还采用了照片横断法收集实地数据。随机森林算法对五个类别的分类准确率为 76%。将哨兵-2A 图像与随机森林算法相结合,可以深入了解海草的状况和分布。
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引用次数: 0
Phytochemical screening, quantitative analysis and antioxidant properties of crude extracts from stems, leaves, and flowers of three Ruta species 从三种芸香科植物的茎、叶和花中提取的粗提取物的植物化学筛选、定量分析和抗氧化特性
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-07-08 DOI: 10.1016/j.kjs.2024.100287
Mohammed Barbouchi , Bouchra Benzidia , Kaoutar Elamrani , Maryame Sabiri , Mostafa El Idrissi , M'barek Choukrad

In this work, the stems, leaves, and flowers of Ruta chalepensis L., R. graveolens L., and R. montana L. harvested in Morocco were subject to a comparative study to determine the phytochemical composition, antioxidant capacities, and the content of total phenols and flavonoids. For this purpose, 45 crude extracts (CEs) were prepared using different solvents, including water, ethyl acetate, methanol, ethanol, and hexane. Upon undergoing secondary metabolites screening, it was discovered that the different parts of three Ruta species contain a high level of secondary metabolites such as alkaloids, catechic tannins, flavonoids, coumarins, sterols, and triterpenes. This was confirmed by the results of the quantitative analysis, which proved that the three Ruta species contain a significant amount of total phenolic compounds, ranging from 27.05 to 213.42 mg GAE/g CE. With regard to antioxidant capacities, antiradical power (ARP) results prove that the majority of CEs have great ARP (were within the range of 0.42–1.99) compared to the BHT (butylated hydroxytoluene) standard (0.33 APR). In addition, the results of total antioxidant capacity (TAC) analysis of Ruta CEs showed good TAC (varies between 37.67 and 396.80 mg AAE/g CE).

在这项工作中,我们对在摩洛哥收获的 Ruta chalepensis L.、R. graveolens L. 和 R. montana L. 的茎、叶和花进行了比较研究,以确定其植物化学成分、抗氧化能力以及总酚和类黄酮的含量。为此,研究人员使用不同的溶剂(包括水、乙酸乙酯、甲醇、乙醇和正己烷)制备了 45 种粗提取物(CEs)。在进行次生代谢物筛选时发现,三种芸香科植物的不同部位含有大量次生代谢物,如生物碱、儿茶单宁、黄酮类、香豆素、甾醇和三萜类。定量分析的结果也证实了这一点,即这三种芸香科植物含有大量的总酚类化合物,含量从 27.05 到 213.42 毫克 GAE/g CE 不等。在抗氧化能力方面,抗自由基能力(ARP)结果表明,与 BHT(丁基羟基甲苯)标准(0.33 APR)相比,大多数 CE 都具有很高的 ARP 值(范围在 0.42-1.99 之间)。此外,芦塔 CEs 的总抗氧化能力(TAC)分析结果表明其总抗氧化能力良好(介于 37.67 至 396.80 毫克 AAE/g CE 之间)。
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引用次数: 0
Comparative evaluation on chemical composition and in vitro anti-Fusarium activity of solvent extracts of Zingiberaceae rhizomes from Indonesia 印度尼西亚茜草科植物根茎溶剂提取物化学成分和体外抗镰刀菌活性的比较评价
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-07-03 DOI: 10.1016/j.kjs.2024.100281
Toga Pangihotan Napitupulu , Ismu Purnaningsih , Atit Kanti , I Made Sudiana

Fusarium oxysporum f.sp. cubense (Foc) is a fungus that not only causes disease while bananas are being grown, but it also causes begetting after bananas are harvested, which limits the production of bananas. Zingiberaceae plants contain a high number of extractable secondary metabolites that are regarded to have effective antifungal activities. However, in order for the compounds to be suitable for use, they must be tested by modifying the polarity in the extracting solvent. In this study, four Zingiberaceae species were examined, namely Zingiber officinale, Curcuma longa, C. zanthorrhiza, and Alpinia galanga. The extraction of rhizomes of each plant was accomplished by using solvents with distinct polarity index (PI) viz. water (PI 9.0); a mixture of 50% water and 50% ethanol (PI 7.1); ethanol (PI 5.2); and n-hexane (PI 0.0). The anti-Fusarium evaluation of these 16 extracts was carried out in vitro by implementing the pour plate method in potato dextrose agar (PDA). Our results showed that the C. zanthorrhiza n-hexane extract possessed the greatest antifungal activity among other extracts. The fungal inhibition ability of the extracts was negatively correlated with the increase in solvent polarity index. In order to comprehend our understanding of the antifungal activity, the chemical compositions of each extract were identified through non-targeted Gas Chromatography–Mass Spectrometry (GC-MS), showing the main components of the n-hexane extracts were terpenes and terpenoids. Particularly, C. zanthorrhiza n-hexane extract contained, with the percentage of abundance in parentheses, germacrene B (22.99%), β-farnesene (14.72%), curzerene (10.87%), 2-bornanone (9.60%), α-curcumene (9.32%), zingiberene (8.30%), β-curcumene (6.36%), β-elemene (5.31%), caryophyllene (3.36%), cedrene (2.73%), α-bergamotene (1.36%), and humulene (0.20%). As conclusion, this crude extract or its pure chemical constituents have potential application as biofumigant to control Foc in postharvest banana.

Fusarium oxysporum f.sp. cubense(Foc)是一种真菌,它不仅会在香蕉生长过程中引起病害,还会在香蕉收获后引起生育,从而限制香蕉的产量。人参科植物含有大量可提取的次生代谢物,被认为具有有效的抗真菌活性。然而,为了使这些化合物适合使用,必须通过改变萃取溶剂的极性对其进行测试。本研究考察了四种姜科植物,即 Zingiber officinale、Curcuma longa、C. zanthorrhiza 和 Alpinia galanga。每种植物根茎的提取均采用不同极性指数(PI)的溶剂,即水(PI 9.0)、50% 水和 50%乙醇的混合物(PI 7.1)、乙醇(PI 5.2)和正己烷(PI 0.0)。通过在马铃薯葡萄糖琼脂(PDA)中采用浇板法,对这 16 种提取物进行了体外抗镰刀菌评价。结果表明,在其他提取物中,C. zanthorrhiza 正己烷提取物具有最强的抗真菌活性。提取物的抑菌能力与溶剂极性指数的增加呈负相关。为了更好地理解这些提取物的抗真菌活性,我们对每种提取物的化学成分进行了非目标气相色谱-质谱(GC-MS)鉴定,结果表明正己烷提取物的主要成分是萜烯和萜类化合物。特别是,C. zanthorrhiza 正己烷提取物中(括号内为丰度百分比)含有胚芽烯 B(22.99%)、β-法呢烯(14.72%)、莪术烯(10.87%)、2-龙脑酮(9.60%), α-curcumene (9.32%), zingiberene (8.30%), β-curcumene (6.36%), β-elemene (5.31%), caryophyllene (3.36%), cedrene (2.73%), α-bergamotene (1.36%), and humulene (0.20%).总之,这种粗提取物或其纯化学成分有可能用作生物熏蒸剂来控制收获后香蕉中的虫害。
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引用次数: 0
Shoreline morphological change prognostic model based on spatiotemporal framework imagery data on the northern coast of Java, Indonesia 基于印度尼西亚爪哇岛北部海岸时空框架图像数据的海岸线形态变化预报模型
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-29 DOI: 10.1016/j.kjs.2024.100274
Nurul Khakhim , Agung Kurniawan , Widodo Setiyo Pranowo , Ernaini Uswatun Khasanah , Purity Halilintar

This study focuses on identifying the degree of shoreline changes on the north coast of Java Island (Indonesia), particularly the Batang Regency segment, using multiple data sources: Landsat 9 and 8, Landsat 5 TM, and PlanetScope spanning from 2000 to 2023. The degree of change was obtained by statistically calculating net shoreline movement (NSM), linear regression rate (LRR), and end-point rate (EPR) using the digital shoreline analysis system (DSAS) software. The three rate-of-change statistics were used to calculate the multidecadal shoreline change prediction or projection for the next 10 and 20 years using a Kalman filter-based model with a simple data assimilation technique. Based on these results, NSM indicated that the shoreline experienced a total accretion and erosion of 361.04 and 111.58 m, respectively, from 2000 to 2023. Over these years, the highest accretion rate reached 16.44 m/year (according to LRR) or 15.83 m/year (EPR), while the maximum erosion rate was up to 11.34 m/year (LRR) or 9.43 m/year (EPR). The use of two data sources with different spatial resolutions produces varying statistical values, which depend on the degree of detail and complexity of the data derived from the source imagery. The coastline prognosis model produced with the Kalman filter shows that the entire coastline in Batang Regency will most likely experience an average accretion and erosion of 18.03 and 21.42 m, respectively, in 10 years, while that in the next 20 years will be 26.38 and 33.3 m, respectively.

本研究的重点是利用多种数据源确定爪哇岛(印度尼西亚)北海岸,特别是巴塘地区的海岸线变化程度:大地遥感卫星 9 号和 8 号、大地遥感卫星 5 号 TM 以及 PlanetScope,时间跨度为 2000 年至 2023 年。通过使用数字海岸线分析系统(DSAS)软件统计计算海岸线净移动量(NSM)、线性回归率(LRR)和终点率(EPR),得出变化程度。利用这三种变化率统计数据,采用基于卡尔曼滤波器的模型和简单的数据同化技术,计算出未来 10 年和 20 年的多年代海岸线变化预测或预报。根据这些结果,国家海岸监测表明,从 2000 年到 2023 年,海岸线共经历了 361.04 米的增生和 111.58 米的侵蚀。在这些年中,最高的增生率达到 16.44 米/年(根据 LRR)或 15.83 米/年(根据 EPR),而最大的侵蚀率达到 11.34 米/年(根据 LRR)或 9.43 米/年(根据 EPR)。使用两种不同空间分辨率的数据源会产生不同的统计值,这取决于从源图像中提取的数据的详细程度和复杂程度。使用卡尔曼滤波法生成的海岸线预测模型显示,巴塘地区的整个海岸线在 10 年内最有可能经历的平均增高和侵蚀分别为 18.03 米和 21.42 米,而在未来 20 年内将分别为 26.38 米和 33.3 米。
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引用次数: 0
A hybrid biomass-natural kaolinite for refractory ceramic manufacturing 用于耐火陶瓷制造的生物质-天然混合高岭石
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-28 DOI: 10.1016/j.kjs.2024.100278
Oumaima Grine , Ali Sdiri , Walid Hajjaji , Bechir Moussi , Pascal Pilate , Chaouki Sadik , Johan Yans , Hamza Elfil , Fakher Jamoussi

The current study investigates the effect of adding a low-cost biomaterial (sawdust biomass) to kaolinite clay on the properties of insulating refractory materials. Natural kaolinite clay from NW Tunisia has been selected for porous ceramic preparation due to its high alumina content (23.64%) with low impurities, especially iron and alkaline oxides. For this study, a set of cylindrical samples were prepared from mixtures of Tabarka clay with different proportions of sawdust (10, 15 and 20%). Those green specimens were pressed and sintered to 1350 °C for 2 h. Experimental data showed that the increase in sawdust proportion increased the open porosity from 24 to 35%. SEM images showed higher important porosity with higher biomass addition. Similarly, bulk density and compressive strength decreased to 1.65 g/cm3 and 17 MPa, respectively. Mullite phase was also generated by the abundant alumina and silica in the raw feed. Several ceramic specimens were also manufactured under optimal conditions: sawdust (20%), pressure (10 kN), and sintering at 1200, 1250 and 1300 °C. The obtained ceramics showed higher porosity (57%), but lower bulk density (1.13 g/cm3). These are the required standards for silica-alumina insulating materials, confirming the possible valorization of kaolinite clay from Tunisia for refractory insulating ceramic.

本研究探讨了在高岭石粘土中添加低成本生物材料(锯末生物质)对绝缘耐火材料性能的影响。突尼斯西北部的天然高岭石粘土因其氧化铝含量高(23.64%)、杂质少(尤其是铁和碱性氧化物)而被选为制备多孔陶瓷的原料。在这项研究中,我们用塔巴卡粘土与不同比例(10%、15% 和 20%)锯屑的混合物制备了一组圆柱形样品。实验数据显示,锯屑比例的增加使开放孔隙率从 24% 增加到 35%。扫描电镜图像显示,生物质添加量越高,重要孔隙率也越高。同样,体积密度和抗压强度分别降至 1.65 克/立方厘米和 17 兆帕。原料中丰富的氧化铝和二氧化硅也产生了莫来石相。在锯屑(20%)、压力(10 kN)和 1200、1250 和 1300 °C 烧结等最佳条件下,还制造出了几种陶瓷试样。获得的陶瓷孔隙率较高(57%),但体积密度较低(1.13 克/立方厘米)。这些都是硅铝绝缘材料所要求的标准,证实了突尼斯高岭石粘土在耐火绝缘陶瓷中的应用价值。
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引用次数: 0
Identification of microbial groups in the aeration tanks of secondary wastewater treatment stage 二级污水处理阶段曝气池中微生物群的鉴定
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-28 DOI: 10.1016/j.kjs.2024.100279
Farah Al Ajeel , Mohamed Kishk , Elsayed Ibrahim

Microbes are prevalent in wastewater, degrading organic matter that impact the environment. In recent years, wastewater treatment plants have been used to process treated water for domestic purposes, sustaining groundwater resources for the future. The current study assessed the present microbial species in the aeration tanks for the secondary wastewater treatment stage in the Sulaibiya Wastewater Treatment and Reclamation Plant, Kuwait. Biweekly wastewater samples were collected for a period of three months from October 2022 to December 2022 from the aeration tanks. The collected wastewater samples were analyzed for microbiological parameters including total coliform, fecal coliform, Salmonella, and E. coli. Further, the microbial species were identified using the Biolog Omnilog Instrument. The results indicated that a total of 45 bacterial species isolates were identified with the most dominant genus being Bacillus with twenty-one isolates. Though Bacillus is common in aeration tanks, the presence of Bacillus thuringiens/cereus is rare and their existence could be due to the change in climatic conditions such as rainfall, dust and wind. Therefore, the study recommends that all microbial groups should be identified at all treatment stages including, primary, secondary, tertiary, and advanced treatment stages to ensure the complete removal of microbes.

微生物普遍存在于废水中,降解影响环境的有机物。近年来,废水处理厂被用来处理经过处理的生活用水,以维持未来的地下水资源。本研究对科威特苏莱比亚废水处理和再生厂二级废水处理阶段曝气池中的现有微生物种类进行了评估。在 2022 年 10 月至 2022 年 12 月的三个月期间,每两周从曝气池中收集一次废水样本。对收集的废水样本进行了微生物参数分析,包括总大肠菌群、粪大肠菌群、沙门氏菌和大肠杆菌。此外,还使用 Biolog Omnilog 仪器对微生物种类进行了鉴定。结果表明,共鉴定出 45 个细菌分离物,其中最主要的属是芽孢杆菌,有 21 个分离物。虽然芽孢杆菌在曝气池中很常见,但苏云金芽孢杆菌/苏云金杆菌却很少出现,它们的存在可能是由于降雨、灰尘和风等气候条件的变化。因此,该研究建议,应在所有处理阶段(包括一级、二级、三级和高级处理阶段)识别所有微生物群,以确保彻底清除微生物。
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引用次数: 0
Assessment of seasonal variations in the air quality index (2019–2022) in Al-Jahra city, Kuwait 科威特 Al-Jahra 市空气质量指数季节变化评估(2019-2022 年
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-27 DOI: 10.1016/j.kjs.2024.100280
Sharifah Alsowaidan , Adeeba Al-Hurban , Ahmad Alsaber , Amal Anbar

The daily air quality indices (AQIs) for pollutants, including particulate matter (PM10 and PM2.5), carbon monoxide (CO), nitrogen oxides (NO2), ozone (O3), and sulfur dioxide (SO2), were evaluated for the period of 2019–2022 in Al-Jahra City, Kuwait. This study is designed to (1) evaluate overall and seasonal changes in pollutants, (2) investigate the correlation for PM10 and PM2.5 and other pollutants during each season, and (3) examine the best model for prediction of air pollutant concentration of PM10 and PM2.5. An assessment of air quality indices was carried out by using different algorithms models, including random forest (RF), an artificial neural network (ANN), and extreme gradient boosting (XGBoost). The overall level of PM10, PM2.5, and SO2 pollutants shows an increasing trend from 2019 to 2022, reaching their highest in 2022 with a significant decrease in 2020 during COVID-19 lockdown restrictions. The pollutants CO and O3 reached their peak in 2021.The obtained results showed that the PM10 and O3 levels are higher in the summer, whereas PM2.5, NO2, and CO were recorded at the highest levels during spring, autumn, and winter respectively due to a variation in the meteorologic condition. Furthermore, during the winter season, the PM10 is positively correlated with CO (rp = 0.401), NO2 (rp = 0.121), and SO2 (rp = 0.119) AQIs while PM2.5 is significantly positively correlated with the CO (rp = 0.198), O3 (rp = 0.310), and SO2 (rp = 0.129) AQIs. In contrast, the performance of XGBoost is a more reliable predictor for PM10 and PM2.5 levels.

本研究评估了科威特 Al-Jahra 市 2019-2022 年期间的污染物日空气质量指数(AQIs),包括颗粒物(PM10 和 PM2.5)、一氧化碳(CO)、氮氧化物(NO2)、臭氧(O3)和二氧化硫(SO2)。本研究旨在:(1)评估污染物的总体变化和季节变化;(2)调查 PM10 和 PM2.5 与各季节其他污染物的相关性;(3)研究预测 PM10 和 PM2.5 空气污染物浓度的最佳模型。空气质量指数评估采用了不同的算法模型,包括随机森林(RF)、人工神经网络(ANN)和极梯度提升(XGBoost)。从 2019 年到 2022 年,PM10、PM2.5 和二氧化硫污染物的总体水平呈上升趋势,在 2022 年达到最高值,在 COVID-19 封锁限制期间的 2020 年显著下降。结果表明,由于气象条件的变化,PM10 和 O3 的水平在夏季较高,而 PM2.5、NO2 和 CO 分别在春季、秋季和冬季达到最高水平。此外,在冬季,PM10 与 CO(rp = 0.401)、NO2(rp = 0.121)和 SO2(rp = 0.119)空气质量指数呈正相关,而 PM2.5 与 CO(rp = 0.198)、O3(rp = 0.310)和 SO2(rp = 0.129)空气质量指数呈显著正相关。相比之下,XGBoost 的性能对 PM10 和 PM2.5 水平的预测更为可靠。
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引用次数: 0
Hydrochar preparation from wild weeds (Amaranthus sp.) and its application as artificial soil for hydroponic system 从野生杂草(苋属植物)中制备水炭并将其用作水培系统的人工土壤
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-25 DOI: 10.1016/j.kjs.2024.100277
Yosep Lawa , Frederik L. Benu , Kristomus Boimau , Defmit Bifjum Nathaniel Riwu , Pieter Kune , Amandio Faria da Silva , Bernadeta Ayu Widyaningrum , Handoko Darmokoesoemoe , Heri Septya Kusuma , Yantus A.B. Neolaka

Hydroponics is a viable alternative for urban contexts with limited resources and space since it offers efficient and low-maintenance planting methods. This study specifically examines the development of synthetic soil by utilizing hydrochar obtained from wild weeds (Amaranthus sp.). X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and field-emission scanning electron microscopy (FE-SEM) were used to study the hydrochar after it was made using the hydrothermal carbonization method. The analysis showed that the hydrochar had an undefined crystal structure and an uneven, varied porosity. The expansion capacity test clearly showed a significant growth potential of 32%. Nevertheless, the water retention tests revealed a progressive decline in the capacity to retain water as time passed. The kinetics model was used to simulate the release of NPK from the counterfeit soil. The P and K components adhered to a first-order model, but the N elements adhered to the Kosmeyer-Peppas model. The use of artificial soil as a substrate for kale plants had excellent outcomes, with the highest growth rate of 0.75 cm reported on day 7. Subsequently, the growth stabilized and gradually decreased to 0.3 cm by day 21. Hydrochar generated from wild weeds (Amaranthus sp.) is a practical choice for hydroponic farming systems, as it provides fertilizer storage and slow-release advantages.

对于资源和空间有限的城市环境来说,水培法是一种可行的替代方法,因为它提供了高效、低维护的种植方法。本研究利用从野生杂草(苋菜属)中提取的水炭开发合成土壤。研究人员利用 X 射线衍射 (XRD)、傅立叶变换红外光谱 (FTIR) 和场发射扫描电子显微镜 (FE-SEM) 研究了水热碳化法制成的水炭。分析结果表明,水煤炭的晶体结构不明确,孔隙率不均匀且变化较大。膨胀能力测试清楚地显示了 32% 的显著增长潜力。然而,保水试验表明,随着时间的推移,保水能力逐渐下降。使用动力学模型模拟了假冒土壤中氮磷钾的释放情况。P 和 K 元素采用了一阶模型,而 N 元素则采用了 Kosmeyer-Peppas 模型。使用人造土壤作为羽衣甘蓝植物的基质取得了很好的效果,第 7 天的生长速度最高,达到 0.75 厘米。随后,生长趋于稳定,并在第 21 天时逐渐降至 0.3 厘米。野生杂草(苋菜属)产生的水炭是水培耕作系统的实用选择,因为它具有肥料储存和缓释优势。
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引用次数: 0
Microstructural and photocatalytic properties of nanostructured near-β Ti-Nb-Zr alloy for total hip prosthesis use 用于全髋关节假体的纳米结构近 β Ti-Nb-Zr 合金的微结构和光催化特性
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-06-21 DOI: 10.1016/j.kjs.2024.100276
Mamoun Fellah , Naouel Hezil , Dikra Bouras , Majeed Ali Habeeb , Fouzia Hamadi , Nabila Bouchareb , Salah Eddine Laouini , Alejandro Perez Larios , Obrosov Aleksei , Gamal A. El-Hiti

With its unique corrosion resistance, light weight, mechanical strength, and biocompatibility, TNZ is a versatile metal alloy that is used in the aerospace and medical industries. The current study aims to investigate the effect of milling time (2, 12, 24, and 36 h) on the nanostructured ternary alloy Ti-25Nb-25Zr (TNZ) prepared by high energy ball milling, a process involving the use of a high-energy ball mill to mix and grind the alloy powders, on its structural, physical, and photocatalytic characterizations. The alloys' characteristics, such as morphology, structural properties, relative density/porosity, surface roughness, hardness, and Young's modulus, were evaluated using SEM, XRD, surface profilometer, and microdurometer, respectively. The photocatalytic characterization was conducted by measuring their absorbance as a function of time using a spectrophotometer of visible and ultraviolet light in the wavelength range of 250–650 nm. Results showed that the crystallite and mean pore size reduced with increasing milling time, with the smallest values of 25 nm and 34 μm, respectively, after 36 h. This indicates that longer milling times result in a more compact and uniform structure, which could enhance the mechanical properties of the alloy. Structural characterization shows that the amount of the β-Ti phase increased with increasing milling time, resulting in the spherical morphology and texturing of the synthesized alloys. The milled alloys' structural evolution and morphological changes were sensitive to their milling times. Also, the relative density, Young's modulus, and hardness increased, reaching values of 89 %, 105 GPa, and 352 HV, respectively, due to grain size decreasing with increasing milling time. This suggests that longer milling times lead to a denser and harder alloy, which could be beneficial for its use in total hip prostheses. The photocatalytical characterization demonstrated that the degradation of orange II (OII) increased with increasing milling time. The Ti-25Nb-25Zr catalyst gave the best degree of degradation, which meant that the decolorization process could be operated rapidly and at a relatively low cost without UV irradiation.

TNZ 具有独特的耐腐蚀性、轻质、机械强度和生物相容性,是一种多功能金属合金,广泛应用于航空航天和医疗行业。本研究旨在探讨高能球磨法制备的纳米结构三元合金 Ti-25Nb-25Zr (TNZ)的研磨时间(2、12、24 和 36 小时)对其结构、物理和光催化特性的影响。使用扫描电镜、X射线衍射、表面轮廓仪和显微硬度计分别对合金的形态、结构特性、相对密度/孔隙率、表面粗糙度、硬度和杨氏模量等特性进行了评估。光催化表征是通过使用波长范围为 250-650 纳米的可见光和紫外线分光光度计测量它们的吸光度随时间变化的函数来进行的。结果表明,随着研磨时间的延长,晶粒和平均孔径减小,36 小时后的最小值分别为 25 nm 和 34 μm。结构表征结果表明,随着研磨时间的延长,β-Ti 相的含量增加,从而使合成合金呈现球形形态和纹理。研磨合金的结构演变和形态变化对研磨时间很敏感。此外,相对密度、杨氏模量和硬度也有所增加,分别达到 89 %、105 GPa 和 352 HV,这是由于晶粒尺寸随着研磨时间的延长而减小。这表明,铣削时间越长,合金的密度和硬度越高,这有利于其在全髋关节假体中的应用。光催化特性分析表明,随着研磨时间的延长,橙 II(OII)的降解率也在增加。Ti-25Nb-25Zr 催化剂的降解效果最好,这意味着脱色过程无需紫外线照射即可快速进行,而且成本相对较低。
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引用次数: 0
The spatial and temporal variation of the terrestrial water storage anomaly (TWSA) of Iraq for the period 2002–2019 based on GRACE gravity data 基于 GRACE 重力数据的 2002-2019 年期间伊拉克陆地蓄水异常点 (TWSA) 的空间和时间变化
IF 1.4 4区 综合性期刊 Q2 Multidisciplinary Pub Date : 2024-06-14 DOI: 10.1016/j.kjs.2024.100275
Alaa M. Al-Abadi , Jawad A. Al-Mohammdawi , Ali K. Abass , Fadhil K. Jabbar , Majid S. Mohamod , Hassan Alzahrani

This study utilized data from the NASA Gravity Recovery and Climate Experiment (GRACE) to examine the variability of the terrestrial water storage anomaly (TWSA) in Iraq between 2002 and 2019. The analysis focused on six grid cells representing the Iraqi territory. The season trend decomposition (SLT) method was used to decompose the signal time series of TWSA to reveal the seasonality, trend, and random noise for the six GRACE blocks. Results proved that Block01 in northwestern side of Iraq, experienced a significant reduction in TWS between 2002 and 2009, followed by a negative linear trend until 2015, and then a positive trend. Block02 which is located in the northeastern part of Iraq showed a decreasing trend in TWS until 2008, after which it had a positive trend. Block03 in the western central side of Iraq reveals a decrease in TWS from 2002 to 2008, followed by a negative linear trend until 2016, and then a positive trend. Block04 in the eastern Mesopotamian plain had a minor increase in TWS until 2006, followed by a substantial decrease until 2016, before stabilizing and showing a positive trend. Block05 in the southwestern side of Iraq demonstrated a continuous decline in TWSA. In contrast, TWS increased in block6 on the southeastern side from 2002 to 2007, then decreased from 2007 to 2009. TWSA levels remained stable from 2009 to 2016, then increased from 2016 to the end of 2019. The seasonal fluctuations in TWS varied across the blocks, but generally, surpluses were observed in winter and spring, while deficits were observed in summer and autumn. The shortage in TWS is attributed to drought and excessive use of groundwater for irrigation. The recent positive trends in TWS in some blocks suggest that the drought may be coming to an end, but further analysis is necessary to reach a definitive conclusion.

本研究利用美国国家航空航天局重力恢复和气候实验(GRACE)的数据,研究了 2002 年至 2019 年期间伊拉克陆地蓄水异常(TWSA)的变化情况。分析侧重于代表伊拉克领土的六个网格单元。采用季节趋势分解(SLT)方法对 TWSA 信号时间序列进行分解,以揭示六个 GRACE 区块的季节性、趋势和随机噪声。结果表明,位于伊拉克西北部的区块 01 在 2002 年至 2009 年期间经历了 TWS 的显著下降,随后呈负线性趋势,直至 2015 年,然后呈正趋势。位于伊拉克东北部的02区块在2008年之前的总温升呈下降趋势,之后呈正趋势。位于伊拉克中西部的区块03显示,2002年至2008年期间,总谐波系数呈下降趋势,随后呈负线性趋势,直至2016年,然后呈正趋势。位于美索不达米亚平原东部的04区块在2006年之前总温升高率略有上升,随后大幅下降,直到2016年才趋于稳定并呈现出正趋势。位于伊拉克西南部的 05 区块的总温升持续下降。相比之下,位于东南侧的 6 号区块的总悬浮固体含量在 2002 年至 2007 年期间有所上升,然后在 2007 年至 2009 年期间有所下降。2009 年至 2016 年 TWSA 水平保持稳定,2016 年至 2019 年底又有所上升。各区块 TWS 的季节性波动各不相同,但总体而言,冬季和春季出现过剩,而夏季和秋季则出现短缺。总耗水量不足的原因是干旱和过度使用地下水灌溉。最近,一些区块的总悬浮含水量呈上升趋势,这表明干旱可能即将结束,但要得出确切结论,还需要进一步分析。
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引用次数: 0
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Kuwait Journal of Science
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