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Viruses infecting soybean and molecular characterization of soybean mosaic virus isolates in the Black Sea Region of Turkiye 感染大豆的病毒和土耳其黑海地区大豆花叶病毒分离物的分子特征
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-11-06 DOI: 10.1016/j.kjs.2024.100340
Ilyas Deligoz , Mehmet A. Sevik , Nazli D. Kutluk Yilmaz
Many viruses are known to infect and damage soybean (Glycine max) around the world. To detect viruses and determine their incidence, surveys were conducted in soybean fields in Samsun province located in the northern part of Türkiye for four consecutive years from 2014 to 2017. Soybean mosaic virus (SMV) and cucumber mosaic virus (CMV) were detected in soybeans after analyzing 444 leaf samples by enzyme linked immunosorbent assay (ELISA). SMV was the most prevalent virus, with an average of 13.9%, followed by CMV (3.6%), and SMV + CMV (0.9%) in this study. However, alfalfa mosaic virus (AMV), tobacco ringspot virus (TRSV), and tomato spotted wilt virus (TSWV) were not detected in any of the soybean samples tested. In this study, four SMV-infected samples were selected according to their location and the SMV isolates were molecularly analyzed based on P3 cistrons. Results showed that all SMV isolates were the same at the amino acid level in terms of P3 amino acid sequence when those isolates were compared. The BLAST analysis of the P3 cistron of the Turkish SB20, SC25, and STK1 isolates showed that they were most closely related to the German Salzlandkreis-2_17 isolate (99.71–99.62% nucleotide identity; 100% amino acid identity, respectively), while the other isolate, STR2, was more similar to the Iranian Ar33 and Lo3 isolates, the German Salzlandkreis-2_17, and the Dutch Summer Shell isolates (99.62% nucleotide identity; 100% amino acid identity, respectively). To our knowledge, this is the first report for SMV and CMV infection in soybean plants in the Black Sea Region and the first molecular characterization of SMV isolates in Türkiye.
已知全世界有许多病毒感染并损害大豆(Glycine max)。为了检测病毒并确定其发病率,2014 年至 2017 年连续四年对位于土耳其北部萨姆松省的大豆田进行了调查。通过酶联免疫吸附试验(ELISA)分析了444份叶片样本,在大豆中检测到了大豆花叶病毒(SMV)和黄瓜花叶病毒(CMV)。在这项研究中,SMV 是最普遍的病毒,平均占 13.9%,其次是 CMV(3.6%)和 SMV + CMV(0.9%)。然而,在检测的任何大豆样本中都没有检测到苜蓿花叶病毒(AMV)、烟草环斑病毒(TRSV)和番茄斑点枯萎病病毒(TSWV)。在本研究中,根据大豆的生长位置选择了四个受 SMV 感染的样本,并根据 P3 cistrons 对 SMV 分离物进行了分子分析。结果表明,比较所有 SMV 分离物的 P3 氨基酸序列,它们在氨基酸水平上是相同的。对土耳其 SB20、SC25 和 STK1 分离物的 P3 单列子进行的 BLAST 分析表明,它们与德国 Salzlandkreis-2_17 分离物的亲缘关系最密切(核苷酸同一性分别为 99.71%-99.62%;氨基酸同一性分别为 100%),而另一个分离物 STR2 与伊朗 Ar33 和 Lo3 分离物、德国 Salzlandkreis-2_17 以及荷兰 Summer Shell 分离物的亲缘关系更为相似(核苷酸同一性分别为 99.62%;氨基酸同一性分别为 100%)。据我们所知,这是黑海地区大豆植物感染 SMV 和 CMV 的首次报告,也是土耳其首次对 SMV 分离物进行分子鉴定。
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引用次数: 0
A reappraisal of Mesozoic-Cenozoic sequence stratigraphy in Offshore Indus Basin, Pakistan 巴基斯坦近海印度河盆地中生代-新生代层序地层学再评价
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-11-03 DOI: 10.1016/j.kjs.2024.100338
Tanveer Ahmed , Khaista Rehman , Muhammad Iqbal Hajana , Sajjad Ahmed , Syed Haroon Ali , Qamar Yasin
The Offshore Indus Basin is a passive continental margin and a frontier zone for hydrocarbon exploration based on structural and stratigraphic features observed on seismic data. In this study, the seismic and biostratigraphic framework is established using seismic data, geophysical well logs, along with biostratigraphic information to define the depositional sequences in the study region. A re-examination of the seismic data exhibits normal faults and a total of six seismic sequences ranging from Cretaceous to Quaternary. Nummulites atacicus, Nummulites globulus, Discocyclina sp., Miscellanea miscella, and Ranikothalia sp. are the major identified fauna in the Karachi South A1 well (2030–2724 m). The Miscellanea miscella, Ranikothalia, and Discocyclina sp. ages range from 55 to 56.5, 55–59, and 55–59 Ma respectively. Employing biostratigraphy, Ranikothalia/Miscellanea miscella/Discocyclina biozone (55–59 Ma), a single sequence, a third order cycle of deposition and transgressive and highstand system tracts have been recognized in the Karachi South A1 well. Linking biostratigraphic results to seismic stratigraphy indicates that the strata located in the range of 2030–2724 m is of the Ranikot (Paleocene) Formation and has been previously given Eocene age rather than the Paleocene using vintage seismic data. The environment of deposition of the Ranikot Formation in the Karachi South A1 well is the subtidal environment of the middle-shelf (30–45m depth) setting.
近海印度河盆地是一个被动大陆边缘,也是根据地震数据观察到的结构和地层特征进行油气勘探的前沿地带。本研究利用地震数据、地球物理测井记录和生物地层学信息建立了地震和生物地层学框架,以确定研究区域的沉积序列。对地震数据的重新审查显示出正常断层和从白垩纪到第四纪的共六个地震序列。Nummulites atacicus、Nummulites globulus、Discocyclina sp.、Miscellanea miscella 和 Ranikothalia sp.是卡拉奇南 A1 井(2030-2724 米)发现的主要动物群。Miscellanea miscella、Ranikothalia 和 Discocyclina sp.的年龄分别为 55 至 56.5、55 至 59 和 55 至 59 Ma。根据生物地层学,卡拉奇南 A1 井确认了 Ranikothalia/Miscellanea miscella/Discocyclina 生物区(55-59 Ma)、单一序列、三阶沉积周期以及横断和高地系统道。将生物地层学结果与地震地层学联系起来表明,位于 2030-2724 米范围内的地层属于 Ranikot(古新世)地层,而以前使用的古老地震数据将其定为始新世而不是古新世。卡拉奇南 A1 井中 Ranikot 地层的沉积环境是中陆架(30-45 米深)的潮下环境。
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引用次数: 0
A comprehensive review of spatial distribution modeling of plant species in mountainous environments: Implications for biodiversity conservation and climate change assessment 山区环境植物物种空间分布模型综合评述:对生物多样性保护和气候变化评估的影响
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-22 DOI: 10.1016/j.kjs.2024.100337
Sadaf Safdar , Isma Younes , Adeel Ahmad , Srikumar Sastry
Species Distribution Modelling (SDM) techniques, developed in the 1980s, have gained significant attention in recent years. These techniques are increasingly recognized as powerful tools to support forest management strategies in the context of climate change. This study presents a comprehensive literature review of SDM techniques in mountainous environments, utilizing remote sensing techniques and data. Forty-one published papers were reviewed, covering 25 years (1997–2022). The review explores various SDM techniques, the use of remotely sensed data, accuracy assessments, environmental variables, and the limitations and challenges of species distribution modeling in mountainous environments across different spatial scales. The study revealed that the most widely used SDM techniques were Maximum Entropy (MaxEnt), Random Forest (RF), and Generalized Linear Models (GLMs), with recent studies emphasizing machine learning. We describe different modeling algorithms, including presence-only and presence/absence modeling algorithms, machine-learning algorithms, distance-based algorithms, and regression-based algorithms. This study presents the first global literature review of SDM techniques in mountainous environments, emphasizing the necessity of considering the uncertainties associated with climate change scenarios. This study also argues the strengths and limitations of SDM techniques in mountainous environments. Despite limitations of SDM techqniues, the study found an increasing trend in their application in mountainous environments. Finally, this review aims to provide a valuable resource for forest managers, researchers, practitioners, and policymakers employed in forest conservation in mountainous environments around the globe.
物种分布建模(SDM)技术开发于 20 世纪 80 年代,近年来受到广泛关注。这些技术越来越被认为是在气候变化背景下支持森林管理策略的有力工具。本研究利用遥感技术和数据,对山区环境中的 SDM 技术进行了全面的文献综述。共查阅了 41 篇已发表的论文,时间跨度为 25 年(1997-2022 年)。综述探讨了各种 SDM 技术、遥感数据的使用、精度评估、环境变量,以及山区环境中不同空间尺度物种分布建模的局限性和挑战。研究表明,使用最广泛的 SDM 技术是最大熵(MaxEnt)、随机森林(RF)和广义线性模型(GLMs),最近的研究强调了机器学习。我们介绍了不同的建模算法,包括仅存在和存在/不存在建模算法、机器学习算法、基于距离的算法和基于回归的算法。本研究首次对山区环境中的 SDM 技术进行了全球性文献综述,强调了考虑与气候变化情景相关的不确定性的必要性。本研究还论证了山区环境中可持续土地管理技术的优势和局限性。尽管 SDM 技术存在局限性,但研究发现其在山区环境中的应用呈上升趋势。最后,本综述旨在为全球从事山区森林保护工作的森林管理者、研究人员、从业人员和决策者提供有价值的资源。
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引用次数: 0
The entropy-transformed Gompertz distribution: Distributional insights and cross-disciplinary utilizations 熵变贡珀兹分布:分布洞察与跨学科利用
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-18 DOI: 10.1016/j.kjs.2024.100335
Tabassum Naz Sindhu , Anum Shafiq , Showkat Ahmad Lone , Tahani A. Abushal
A novel two-parameter continuous model titled the entropy-transformed Gompertz (ETGPZ) distribution has been developed via the entropy transform. A new framework has been investigated and found to meet the criteria of the probability function. By significantly improving the functional shape and having the ability to model the most likely form of the hazard rate function, this new modification has increased the adaptability of the typical distribution. Some of its core characteristics, such as its statistical and computational features, are clearly presented. A thorough simulation analysis has been done to examine the final behavior of maximum likelihood estimators while estimating model parameters. We assess the performance and practical applicability of the ETGPZ distribution using eight real datasets from engineering and biomedical fields. The results demonstrate that the ETGPZ outperforms the baseline Gompertz (GPZ) distribution, highlighting its superiority and broader potential for various applications.
通过熵变换,一种名为熵变换冈珀兹(ETGPZ)分布的新型双参数连续模型被开发出来。研究发现,新框架符合概率函数的标准。通过大幅改进函数形状,并有能力模拟危险率函数的最可能形式,这种新的修正提高了典型分布的适应性。它的一些核心特征,如统计和计算特征,都得到了清晰的介绍。我们进行了全面的模拟分析,以检验最大似然估计器在估计模型参数时的最终行为。我们使用工程和生物医学领域的八个真实数据集评估了 ETGPZ 分布的性能和实际应用性。结果表明,ETGPZ 优于基线 Gompertz(GPZ)分布,凸显了其优越性以及在各种应用中的广泛潜力。
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引用次数: 0
Assessment of groundwater quality of Al-Shagaya area (Kuwait) for irrigation and industrial purposes using water quality index and GIS techniques 利用水质指数和地理信息系统技术评估 Al-Shagaya 地区(科威特)灌溉和工业用地下水水质
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-18 DOI: 10.1016/j.kjs.2024.100334
Fawzia Al-Ruwaih, Redha Mohammad, Shafiullah Mohideen
Groundwater samples and pumping test data were analyzed from three selected fields (Fields B, C, and D) of the Dammam limestone aquifer (Al-Shagaya, Kuwait) to investigate their aquifer hydrogeological properties and reveal the main geochemical processes. The suitability for irrigation and industrial use was assessed by using water quality index (WQI) and determining the agricultural quality. The pumping tests revealed a confined to semi-confined aquifer, with transmissivity ranging between 4000 and 1.5x106 Igpd/ft, and a storage coefficient of 2 to 4x10−4. The aquifer salinity ranged from 2403 to 5672 mg/l with Na2SO4 and CaSO4 as the main chemical types. The values of WQI indicated that 18% of groundwater samples were of very good quality while 82% of the samples were of acceptable quality. This study has found that the groundwater of this area can be used for industrial and irrigation purposes.
对达曼石灰岩含水层(科威特沙加亚)的三个选定水田(B、C 和 D 田)的地下水样本和抽水试验数据进行了分析,以研究其含水层的水文地质特性并揭示主要的地球化学过程。通过使用水质指数(WQI)和确定农业质量,对灌溉和工业用途的适宜性进行了评估。抽水试验显示,含水层为封闭至半封闭含水层,渗透率在 4000 至 1.5x106 Igpd/ft 之间,储水系数为 2 至 4x10-4。含水层的盐度介于 2403 至 5672 毫克/升之间,主要化学类型为 Na2SO4 和 CaSO4。水质指数值表明,18% 的地下水样本水质很好,82% 的样本水质合格。这项研究发现,该地区的地下水可用于工业和灌溉目的。
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引用次数: 0
Quantile-based robust Kibria–Lukman estimator for linear regression model to combat multicollinearity and outliers: Real life applications using T20 cricket sports and anthropometric data 基于量值的线性回归模型稳健 Kibria-Lukman 估计器,用于消除多重共线性和异常值:利用 T20 板球运动和人体测量数据的实际应用
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-18 DOI: 10.1016/j.kjs.2024.100336
Danish Wasim , Muhammad Suhail , Sajjad Ahmad Khan , Maha Shabbir , Fuad A. Awwad , Emad A.A. Ismail , Hijaz Ahmad , Amjad Ali
The performance of ordinary least squares (OLS) and ridge regression (RR) are influenced when outliers are present in y-direction with multicollinearity among independent variables. The robust RR with ridge parameters provides a biased estimator that has a smaller variance than conventional OLS and RR estimators. The optimal value of the ridge parameter has a vital role in bias-variance tradeoff. This study proposes quantile-based estimation of ridge parameter in robust RR to deal with the joint issue of y-direction outliers and multicollinearity. The effectiveness of the proposed estimators is evaluated using intensive Monte Carlo simulation and two real data sets in terms of mean square error (MSE) and predictions sum of squared error (PSSE) criterion. Simulation findings reveal that the newly developed estimators of ridge parameter in robust RR have better performance than OLS, RR, and existing robust RR estimators when errors are normally and non-normally distributed. The results from two numerical examples of T20 Cricket sports and anthropometric data show that the new estimator with quantile probability 0.50 and 0.99 respectively has winning performance among all competing and proposed estimators.
当自变量之间存在多重共线性时,Y 方向的异常值会影响普通最小二乘法(OLS)和脊回归(RR)的性能。与传统的 OLS 和 RR 估计器相比,带有脊参数的稳健 RR 估计器提供了一个方差较小的有偏估计器。脊参数的最佳值在偏差-方差权衡中起着至关重要的作用。本研究在稳健 RR 中提出了基于量化的脊参数估计,以解决 y 方向异常值和多重共线性的共同问题。利用密集蒙特卡罗模拟和两个真实数据集,从均方误差(MSE)和预测平方误差之和(PSSE)标准的角度评估了所提出的估计器的有效性。仿真结果表明,当误差呈正态分布和非正态分布时,新开发的鲁棒 RR 的脊参数估计器比 OLS、RR 和现有的鲁棒 RR 估计器性能更好。T20 板球运动和人体测量数据这两个数字实例的结果表明,量子概率分别为 0.50 和 0.99 的新估计器在所有竞争估计器和建议估计器中表现出色。
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引用次数: 0
A framework for automatically generating composite keywords for geo-tagged street images 为有地理标记的街道图像自动生成复合关键词的框架
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-16 DOI: 10.1016/j.kjs.2024.100333
Abdullah Alfarrarjeh , Seon Ho Kim , Jungwon Yoon
Due to the ubiquity of sensor-equipped cameras such as smartphones, images are associated with spatial metadata, including camera’s geographical location and viewing orientation, which can be used for automatically generating better semantic keywords about geo-tagged urban street images in addition to visual keywords extracted from image analysis. This study introduces a novel framework for auto-tagging images that integrates both spatial and visual properties to generate comprehensive and accurate tags. The framework operates through four phases: extraction, abstraction, composition, and assessment. Our research highlights the benefits of combining visual and spatial analyses, demonstrated through a case study using geo-tagged urban street images from Orlando, Pittsburgh, and Manhattan. Experimental results show that the proposed framework significantly enhances the accuracy of keyword-based searches compared to conventional methods. In particular, based on our experiments, image search using the tags generated by our proposed framework, referred to as descriptive tags, achieved an average precision improvement factor of 0.9 compared to conventional tags. Additionally, our proposed ranking algorithm, which extends the term frequency-inverse document frequency (TF-IDF) algorithm, resulted in improvement factors of 0.86 for mean average precision (MAP) and 0.57 for mean reciprocal rank (MRR). Moreover, our framework’s flexibility and robustness make it suitable for diverse applications, from smart cities to online shopping. The paper also includes a detailed evaluation and user study, confirming the precision and reliability of the generated tags.
由于智能手机等配备传感器的相机无处不在,图像与空间元数据相关联,包括相机的地理位置和观看方向,除了从图像分析中提取的视觉关键词外,这些元数据还可用于自动生成有关地理标记城市街道图像的更好的语义关键词。本研究介绍了一种用于自动标记图像的新型框架,该框架整合了空间和视觉属性,可生成全面、准确的标记。该框架通过四个阶段运行:提取、抽象、组合和评估。我们的研究强调了将视觉分析和空间分析相结合的好处,并通过使用奥兰多、匹兹堡和曼哈顿的地理标记城市街道图像进行案例研究加以证明。实验结果表明,与传统方法相比,所提出的框架大大提高了基于关键词搜索的准确性。特别是,根据我们的实验,与传统标签相比,使用我们提出的框架生成的标签(称为描述性标签)进行图像搜索的平均精确度提高了 0.9 倍。此外,我们提出的排序算法扩展了词频-反向文档频率(TF-IDF)算法,使平均精度(MAP)和平均倒数排序(MRR)分别提高了 0.86 和 0.57。此外,我们框架的灵活性和鲁棒性使其适用于从智能城市到在线购物等各种应用。论文还包括详细的评估和用户研究,证实了生成标签的精确性和可靠性。
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引用次数: 0
Investigating the impact of biochar on methane gas emissions and its effect on enteric fermentation 研究生物炭对甲烷气体排放的影响及其对肠道发酵的影响
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-09 DOI: 10.1016/j.kjs.2024.100332
Hana'a Burezq, Fatin Khalil
This study aims to evaluate the impact of biochar on methane gas emissions and to investigate its effect on enteric fermentation. Methane gas emissions from Naeemi ewes’ ruminants were measured, with animals divided into two groups, each containing 14 ewes. The treatment group was fed a combination of biochar and a basal ration, while the control group received the basal ration alone. The results demonstrate that the initial gas emission for both animal groups at day 0 was 1082 ppm, and the inclusion of biochar in the diet significantly (P<0.05) reduced CH4 gas emissions by 65.58 % to 78.39%. Furthermore, feeding Naeemi sheep with biochar and the basal ration led to a significant (P<0.05) increase in body weight (63.66 kg) and growth rate (length: 79.3 cm, waist: 81.75 cm, and height: 99.76 cm) compared to the control group. Additionally, it raised the average body condition score (BCS) to 3.56, in contrast to the control group's score of 2.83, primarily due to the positive impact of biochar on fat gain. The study revealed that biochar enhances nutrient utilization, improves feed efficiency, and significantly reduces methane gas emissions in livestock. When incorporated into the sheep's diet, biochar can modify digestive processes and promote better nutrient absorption.
本研究旨在评估生物炭对甲烷气体排放的影响,并调查其对肠道发酵的影响。研究测量了纳伊米母羊反刍动物的甲烷气体排放量,并将动物分为两组,每组 14 只母羊。处理组喂食生物炭和基础日粮的组合,而对照组只喂食基础日粮。结果表明,两组动物在第 0 天的初始气体排放量均为 1082 ppm,在日粮中添加生物炭可显著(P<0.05)减少 65.58 % 至 78.39 % 的甲烷气体排放量。此外,与对照组相比,用生物炭和基础日粮饲喂 Naeemi 羊,体重(63.66 千克)和生长速度(体长:79.3 厘米,腰围:81.75 厘米,身高:99.76 厘米)均有显著提高(P<0.05)。此外,生物炭还将平均体况评分(BCS)提高到 3.56,而对照组的评分为 2.83,这主要是由于生物炭对脂肪增长产生了积极影响。研究表明,生物炭能提高牲畜的养分利用率,提高饲料效率,并显著减少甲烷气体排放。在羊的日粮中添加生物炭,可以改变消化过程,促进营养吸收。
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引用次数: 0
Impact of sol-gel synthesized α-aluminium oxide nanoparticles for the enhancement of transformer oil insulation properties 溶胶-凝胶合成的 α-氧化铝纳米粒子对提高变压器油绝缘性能的影响
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-09 DOI: 10.1016/j.kjs.2024.100331
Venkatesh Yepuri, Palikela Ramachandramurthy
Transformers require advanced insulating materials that outperform mineral oil in terms of cooling, insulation effectiveness, eco-friendliness, and operational efficiency in extreme operational and weather conditions. As a result, emphasis has shifted to renewable and ecologically friendly materials. This change in emphasis is motivated by worries about the environment, fuel shortages, and the disposal of waste oil. Transformers have historically employed solid insulators like paper and pressboard as well as mineral or synthetic oil. However, the development of ecologically friendly insulating materials has been spurred by new environmental regulations as well as economic benefits. This research investigates the use of sol-gel synthesized aluminium oxide (Al2O3) nanoparticles to improve the insulation properties of host transformer oil. The synthesized aluminium nanoparticles were characterized with X-ray diffractometer (XRD) and found rhombohedral structure, whose chemical composition was studied by energy dispersive X-ray spectrum (EDAX). Investigation using Fourier transform infrared spectroscopy (FTIR) also revealed the production of AlOOH and hydroxyl vibrational bands at wavenumbers of 690 and 2976 cm-1, respectively. Studies using field emission scanning electron microscopy (FESEM) showed that the nanoparticles are spherical in form and have a diameter of around 38 nm. Additionally, the incorporation of α-aluminium oxide nanoparticles into the host oil showed an improvement in the breakdown voltage and suggested a possible use for better transformer oil insulation.
变压器需要先进的绝缘材料,这些材料在冷却、绝缘效果、生态友好性以及极端运行和天气条件下的运行效率方面都优于矿物油。因此,重点已转向可再生和生态友好型材料。对环境、燃料短缺和废油处理的担忧促成了这一重点的转变。变压器历来使用纸和压纸板等固体绝缘材料以及矿物油或合成油。然而,新的环保法规和经济效益推动了生态友好型绝缘材料的发展。本研究探讨了利用溶胶凝胶合成的纳米氧化铝(Al2O3)颗粒来改善变压器主机油的绝缘性能。用 X 射线衍射仪(XRD)对合成的纳米铝粒子进行了表征,发现其具有斜方体结构,并用能量色散 X 射线光谱(EDAX)对其化学成分进行了研究。利用傅立叶变换红外光谱(FTIR)进行的研究还发现,在 690 和 2976 cm-1 波长处分别产生了 AlOOH 和羟基振动带。利用场发射扫描电子显微镜(FESEM)进行的研究表明,纳米颗粒呈球形,直径约为 38 纳米。此外,将 α- 氧化铝纳米粒子加入主油中还能提高击穿电压,并可用于改善变压器油的绝缘性能。
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引用次数: 0
Fabrication of Cu-doped iron oxyhydroxide for phosphate removal: A comprehensive spectroscopic, equilibrium, and thermodynamic approach 制造用于去除磷酸盐的掺铜氧化铁:光谱、平衡和热力学综合方法
IF 1.2 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-10-04 DOI: 10.1016/j.kjs.2024.100330
Mabkhoot Alsaiari , Muhammad Iqbal Zaman , Abdul Niaz , Sadullah Khan , Sania Bibi , Muhammad Ibrahim Khan , Rehmat Ali Khan , Jamie Morgan , Abdulrahman Faraj Alharbi
Phosphate remediation from natural and wastewater systems is of great importance, and the use of adsorption and ion exchange processes are efficient means for its decontamination. In this study, pure and Cu-doped iron oxyhydroxide was synthesized by the co-precipitation method and was successfully applied for the decontamination of phosphate from aqueous solutions. The solid sample was characterized using a surface area analyzer, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), pHiep, and Fourier transform infrared (FT-IR) spectroscopy. The results reveal that the surface area of iron oxyhydroxide increases from 35.1 m2/g to 126 m2/g with Cu ion doping, which may be due to the difference in ionic radii of Fe+3 (0.645 Å) vs. Cu+2 (0.73 Å), thus creating crystal defects. The isoelectric point (pHiep) for the Cu-doped sample was found to be 3.05 in 0.1M KNO3 and decreased to 2.5 when treated with phosphate anions in solution. Elemental analyses confirmed by XPS indicated that 0.1% by weight Cu was incorporated into the doped iron oxyhydroxide, changing the overall surface parameters. The adsorption process was evaluated with different doses of Cu-doped iron oxyhydroxide, contact time, phosphate anion concentrations, and pH of solution over a range of temperatures (303–323K). The adsorption of phosphate increased with increasing phosphate anion concentrations and decrease with increase in temperature. Langmuir models fittedthe adsorption data well with a good correlation coefficient (R2 = 0.99). The sorption maxima for pure iron oxyhydroxide were found to be 0.04 mmol/g at pH 3 and 303K. With Cu ion doping, sorption maxima increased elevenfold to 0.442 mmol g−1 at 303K. Thermodynamic specifications indicated that the sorption process was spontaneous and endothermic in nature. Thermodynamic parameters were evaluated from the Langmuir constant Xm (mmol.g−1) and B (L.mmol−1). FT-IR analyses revealed that phosphate species were adsorbed via electrostatic interactions on the positive sites of the Cu-doped iron oxyhydroxide along with ion exchange mechanism on the surface of the solid.
对自然和废水系统中的磷酸盐进行修复具有重要意义,而使用吸附和离子交换过程是对其进行净化的有效手段。本研究采用共沉淀法合成了纯氧氢氧化铁和掺杂铜的氧氢氧化铁,并将其成功应用于水溶液中磷酸盐的净化。使用表面积分析仪、扫描电子显微镜(SEM)、X 射线光电子能谱(XPS)、pHiep 和傅立叶变换红外光谱(FT-IR)对固体样品进行了表征。结果表明,掺入 Cu 离子后,氢氧化铁的表面积从 35.1 平方米/克增加到 126 平方米/克,这可能是由于 Fe+3 的离子半径(0.645 Å)与 Cu+2 的离子半径(0.73 Å)不同,从而产生了晶体缺陷。掺铜样品的等电点(pHiep)在 0.1M KNO3 中为 3.05,在溶液中用磷酸盐阴离子处理后降至 2.5。经 XPS 确认的元素分析表明,掺杂氢氧化铁中含有 0.1% 重量的铜,从而改变了整体表面参数。在不同的温度(303-323K)范围内,用不同剂量的掺铜氧化铁、接触时间、磷酸盐阴离子浓度和溶液 pH 值对吸附过程进行了评估。磷酸盐的吸附量随着磷酸盐阴离子浓度的增加而增加,随着温度的升高而减少。Langmuir 模型与吸附数据拟合良好,相关系数为 (R2 = 0.99)。在 pH 值为 3 和 303K 时,纯氧化铁的吸附最大值为 0.04 mmol/g。掺入铜离子后,吸附最大值增加了 11 倍,在 303K 时达到 0.442 mmol g-1。热力学参数表明,吸附过程是自发的,具有内热性质。热力学参数是通过朗缪尔常数 Xm(mmol.g-1)和 B(L.mmol-1)来评估的。傅立叶变换红外分析表明,磷酸盐物种是通过静电作用吸附在掺铜氧化铁的正极位点上,同时在固体表面形成离子交换机制。
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Kuwait Journal of Science
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