Materials Today Sustainability最新文献

{"title":"An overview of metal-free diazine-based dyes for dye-sensitized solar cells: Synthesis, optical, and photovoltaic properties","authors":"Aisha R. Al-Marhabi ,&nbsp;Reda M. El-Shishtawy ,&nbsp;Khalid O. Al-Footy","doi":"10.1016/j.mtsust.2024.101014","DOIUrl":"10.1016/j.mtsust.2024.101014","url":null,"abstract":"<div><div>The constant rise in global energy usage has depleted fossil fuel reserves. Therefore, researchers explored solar energy as an alternative energy reserve due to the need for limitless power. In particular, dye-sensitized solar cells (DSSCs) hold great promise in meeting the growing demand for renewable energy supplies due to a low-cost and environmentally friendly photovoltaic technology for harnessing solar energy. The sensitizers' molecular engineering is essential for accomplishing high conversion efficiencies. Numerous research activities have been concentrated on diazine scaffolds (substituted diazines, benzodiazines, and fused heterocyclic diazines) among the many different types of sensitizers because of their strong absorption bands in the visible light region, electron-withdrawing ability, and the ease of modifications that can be made to their skeleton. This review classified the diazines according to their scaffolds (pyridazine, pyrimidine, pyrazine). The improvements to the performance of metal-free DSSCs according to the molecular engineering of the sensitizer are discussed. The effect of the donors, auxiliary donors, auxiliary acceptors, mono or di-anchoring groups, and incorporation of π-spacers or alkyl chains in the sensitizer molecule on the photovoltaic performance are discussed. The synthetic approaches, optical properties in solution, and their photovoltaic performances in DSSCs were also summarized. The present work aims to give readers a distinct picture of the subject and enlighten the researchers by developing future ideas about designing sensitizers employing other heterocyclic scaffolds with electron-deficient properties to achieve an excellent solar energy conversion.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101014"},"PeriodicalIF":7.1,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the potential of additives in optimizing halide perovskite solar cells performance and reliability","authors":"Neda Kalantari ,&nbsp;Nagihan Delibaş ,&nbsp;Aligholi Niaei","doi":"10.1016/j.mtsust.2024.101011","DOIUrl":"10.1016/j.mtsust.2024.101011","url":null,"abstract":"<div><div>This overview delves into the crucial role of additives in bolstering the performance and robustness of Halide Perovskite Solar Cells (PSCs). Categorizing both organic and inorganic additives, the study explores their substantial impact on enhancing the thermal and UV-light stability of PSCs. Various strategies such as solvent manipulation, doping, alloying, and nucleation control are discussed for optimizing the stability of PSCs. Additionally, focusing on improving hole and electron transporting layers, interface protections, and energy band configurations aids in augmenting the efficiency of PSCs. The employment of carbon electrodes and encapsulation techniques emerges as effective methods to bolster thermal stability in PSCs. Furthermore, a profound understanding of defect properties and interface materials is pivotal for augmenting the stability and durability of PSCs. The review encapsulates experimental methods, characterization techniques, and underlying mechanisms behind the additive-induced enhancements in PSCs. Moreover, the article addresses the challenges and future directions in utilizing inorganic additives to elevate the efficiency and stability of PSCs, providing a comprehensive overview of the current state of research and proposing avenues for further advancements in the realm of inorganic additives for Halide Perovskite Solar Cells.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101011"},"PeriodicalIF":7.1,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optoelectronic properties of GaP:Ti photovoltaic devices","authors":"J. Olea ,&nbsp;J. Gonzalo ,&nbsp;J. Siegel ,&nbsp;A.F. Braña ,&nbsp;G. Godoy-Pérez ,&nbsp;R. Benítez-Fernández ,&nbsp;D. Caudevilla ,&nbsp;S. Algaidy ,&nbsp;F. Pérez-Zenteno ,&nbsp;S. Duarte-Cano ,&nbsp;A. del Prado ,&nbsp;E. García-Hemme ,&nbsp;R. García-Hernansanz ,&nbsp;D. Pastor ,&nbsp;E. San-Andrés ,&nbsp;I. Mártil","doi":"10.1016/j.mtsust.2024.101008","DOIUrl":"10.1016/j.mtsust.2024.101008","url":null,"abstract":"<div><div>Supersaturated GaP is of interest for the photovoltaic field since optical transitions at energies below the bandgap (2.26 eV) could enhance the overall device efficiency up to theoretically 60%. We have previously demonstrated that Ti supersaturated GaP can be obtained by means of ion implantation and pulsed-laser melting with high structural quality and measured its below-bandgap photoconductivity. In this work we report the first results of a GaP:Ti based photovoltaic device. We have fabricated and measured photovoltaic devices with a GaP:Ti absorber layer showing enhanced external quantum efficiency at wavelengths above 550 nm. Also, we have measured the absorption coefficient (around 10⁴ cm⁻¹) and refractive index of this absorber layer. Finally, current-voltage curves in darkness were measured and analyzed using a two-diodes model, showing improvable characteristics. Ideas to enhance the properties of the devices are suggested.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101008"},"PeriodicalIF":7.1,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"V2O5-MnO2 nanocomposites as an efficient electrode material for high-performance aqueous supercapacitors","authors":"Tapan K. Pani ,&nbsp;Sadananda Muduli ,&nbsp;Kiran Kumar Garlapati ,&nbsp;Surendra Kumar Martha","doi":"10.1016/j.mtsust.2024.101010","DOIUrl":"10.1016/j.mtsust.2024.101010","url":null,"abstract":"<div><div>Redox-active supercapacitors are very interesting due to their high energy density (&gt;25 Wh kg⁻¹ at device level) and redox charge storage mechanism. In this work, V₂O₅-MnO₂ nanocomposites are synthesized by a scalable hydrothermal approach. MnO₂ in V₂O₅ provides better structural stability with reasonable electrochemical performance, in which V₂O₅ enhances the cyclic stability and rate capabilities. The V₂O₅-MnO₂ -based electrodes deliver a specific capacitance of 266 F g⁻¹ at 0.5 A g⁻¹ and are stable up to 6500 cycles with 97 % capacitance retention at 5 A g⁻¹. The kinetic study depicts that composite electrodes have a 64 % diffusive and 36 % capacitive charge storage contribution to the overall charge storage at 1 mV s⁻¹. In symmetric full cells, the composite materials show a wide active potential window of 2.5 V and retain 83 % capacitance after 10000 continuous GCD cycles at an applied current density of 2 A g⁻¹. The promising charge storage performance is due to a suitable conducting matrix and the effective coating of MnO₂ nanoparticles over the unique V₂O₅ niddle shape (two-dimensional) micro-rods.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101010"},"PeriodicalIF":7.1,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Performance evaluation of waste phosphogypsum-based solidified sludge: From laboratory test to field application","authors":"Jun Wu ,&nbsp;Zengyan Luo ,&nbsp;Yunzhi Tan ,&nbsp;De'an Sun ,&nbsp;Yongfeng Deng ,&nbsp;Wenqi Li","doi":"10.1016/j.mtsust.2024.101013","DOIUrl":"10.1016/j.mtsust.2024.101013","url":null,"abstract":"<div><div>Massive dredged sludge is being landfilled without effective use due to its high-water content and poor engineering properties, which not only leads to soil resources waste, but also occupies a large amounts of land sources. In this study, ternary stabilizer, including waste phosphogypsum (PG), ground granulated blast-furnace slag (GGBS), and lime (LM) with a mixing proportion of PG: GGBS: LM = 35:60:5, was adopted to improve the mechanical and environmental behaviors of sludge for subgrade filling purpose. The initial water content of sludge was controlled using two different dehydration methods for comparison. A series of laboratory tests, including unconfined compressive strength (UCS), organic matter content, and pH value were tested to understand its physical-mechanical properties. Thereafter, field application model equipped with a mini weather monitoring station was constructed to monitor the influence of solidified matrix on the surrounding water and soil environment. Time -dependent parameters such as plant growth, temperature, humidity, total nitrogen, phosphorus/potassium content, electrical conductivity, and pH value were monitored. Results indicate that the incorporation of PG-GGBS-LM ternary stabilizer significantly improves the mechanical and environmental properties of dredged sludge. The optimal dosage of the ternary stabilizer is 36%, which can result in a UCS value of the 2.0 MPa (slightly higher than ordinary Portland cement) after 28 days of curing. Field application reveals that plants could grow normally in solidified sludge. The environmental related parameters (<em>i.e</em>., total nitrogen, phosphorus/potassium content, electrical conductivity, and pH value) were similar with those in conventional planting soil, suggesting the advantage of the proposed PG-GGBS-LM ternary stabilizer in mechanical, economic and environmental aspects.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101013"},"PeriodicalIF":7.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Secondary carbon skeletons constructed in porous carbon for electric double layer capacitors","authors":"Yue Mo ,&nbsp;Junyu Chen ,&nbsp;Yue Han,&nbsp;Kun Zhang,&nbsp;Guangxue Chen","doi":"10.1016/j.mtsust.2024.101007","DOIUrl":"10.1016/j.mtsust.2024.101007","url":null,"abstract":"<div><div>In this work, a secondary skeleton was constructed by filling the larger spaces of porous carbon derived from passion fruit peels with glucose to created more carbon surface in same volume. The combined use of KOH activation and simultaneous etching of micropores on the carbon skeleton and secondary skeleton resulted in the preparation of porous carbon (PGC1-0.5) containing a large number of micropores. PGC1-0.5 have less total pore volume (0.987 cm³ g⁻¹), but more micropore volume (0.821 cm³ g⁻¹), different with 1.171 cm³ g⁻¹, 0.668 cm³ g⁻¹ of PGC1-0, which without glucose. Symmetric supercapacitor bases on PPGC1-0.5 have an obvious improvement in specific capacity (275.6 F g⁻¹ (175 F cm⁻³), 0.1 A g⁻¹) in 6 M KOH electrolyte compared to PGC1-0 (215.2 F g⁻¹ (121.5 F cm⁻³), 0.1 A g⁻¹). Additionally, the device exhibits excellent cycling performance and retained 103% of its specific capacity after 10,000 cycles and notable reduction in transfer internal resistance in comparison to the sample without glucose. This study shows that filling space with glucose to reduce macropores is an effective method for adjusting the pore size distribution of porous carbon.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101007"},"PeriodicalIF":7.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polyvinyl alcohol assisted citrate based reduction of gold(III) ions: Theoretical design and experimental study on green synthesis of spherical and biocompatible gold nanoparticles","authors":"Anshuman Jakhmola ,&nbsp;Valentina Onesto ,&nbsp;Francesco Gentile ,&nbsp;Farshad Moradi Kashkooli ,&nbsp;Krishnan Sathiyamoorthy ,&nbsp;Edmondo Battista ,&nbsp;Raffaele Vecchione ,&nbsp;Kevin Rod ,&nbsp;Michael C. Kolios ,&nbsp;Jahangir (Jahan) Tavakkoli ,&nbsp;Paolo A. Netti","doi":"10.1016/j.mtsust.2024.101012","DOIUrl":"10.1016/j.mtsust.2024.101012","url":null,"abstract":"<div><div>In this study, we demonstrate the synthesis of small gold nanoparticles (typically 8–10 nm) through a green synthesis approach. This method involves utilizing chloroauric acid as the gold precursor, trisodium citrate as a mild reducing and co-capping agent, and polyvinyl alcohol (PVA), as a co-capping and shape-directing agent. This novel synthesis method stands alone as a protocol that involves just mixing the reagents at room temperature and allowing the reaction to proceed at ambient temperature without any disturbance. In the absence of PVA, spherical particles are not formed and the reaction mixture slowly turns black followed by precipitation.The synthesis process was meticulously tracked using time-resolved monitoring of the growth of the localized surface plasmon resonance (LSPR) by UV-vis spectroscopy and transmission electron microscopy. The as-prepared colloidal gold solution was bright red, attributed to the small size (≤10 nm) and spherical geometry of nanoparticles. This colloidal solution could be stored indefinitely at room temperature without precipitation or a change in its absorption profile. The nanoparticles remained stable in adverse conditions such as 100 mM NaCl solution, 1 × PBS and cell culture medium. Additionally, they could be easily loaded with drugs like doxorubicin by adsorption. The particles were thoroughly characterized using a range of techniques, including UV-vis spectroscopy, attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR), high-resolution transmission electron microscopy (HRTEM), hyperspectral-enhanced dark field microscopy (HEDFM), dynamic light scattering (DLS), and X-ray photoelectron spectroscopy (XPS). Cell viability tests conducted on 2D cell lines and 3D spheroids revealed negligible toxicity even at high concentrations. Furthermore, we demonstrated that an advanced version of conventional diffusion-limited aggregation (DLA) schemes, which allows individual clusters to move freely within a domain to form larger aggregates, can effectively replicate the intricate interactions between chloroauric acid, trisodium citrate, and PVA, the agents involved in the synthesis of gold nanoparticles.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101012"},"PeriodicalIF":7.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced CO2 hydrogenation performance of CoCrNiFeMn high entropy alloys","authors":"Chunjing Su ,&nbsp;Lizhuo Wang ,&nbsp;Sibei Zou ,&nbsp;Xingmo Zhang ,&nbsp;Haoyue Sun ,&nbsp;Xingxu Liu ,&nbsp;Chenze Li ,&nbsp;Yijiao Jiang ,&nbsp;Xiaopeng Li ,&nbsp;Jiaquan Li ,&nbsp;Jun Huang","doi":"10.1016/j.mtsust.2024.101006","DOIUrl":"10.1016/j.mtsust.2024.101006","url":null,"abstract":"<div><div>CO₂ hydrogenation is a promising process for removing anthropogenic CO₂ emissions and yielding C1 chemicals that can be utilized as fuels and valuable precursors for chemical synthesis. Commercial high-entropy alloys (HEAs) have widespread application in various fields owing to their exceptional thermal stability and tunable microstructure. However, their potential application as catalysts is often limited by the low exposure of active sites. In this study, the commercial CoCrNiFeMn powder was applied for atmospheric pressure CO₂ hydrogenation and enhanced its catalytic performance by a combined treatment of ball milling and high-temperature H₂ reduction. The high-energy ball milling results in a morphological transition in CoCrNiFeMn HEAs from spherical to irregular. This transformation leads to a significant decrease in particle size and more surface reactive sites. The high-temperature H₂ reduction promoted the atomic rearrangement on the CoCrNiFeMn surface, thereby improving its alloy structural homogeneity. These modifications greatly improve the performance of CoCrNiFeMn for CO₂ hydrogenation. This work introduces a facile modification approach to facilitate the catalytic efficiency of commercial HEAs in CO₂ hydrogenation with high selectivity.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101006"},"PeriodicalIF":7.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Applications of thermochromic material in opaque building envelopes: A comprehensive review","authors":"Chenxi Hu ,&nbsp;Liming Ge ,&nbsp;Xi Meng","doi":"10.1016/j.mtsust.2024.101009","DOIUrl":"10.1016/j.mtsust.2024.101009","url":null,"abstract":"<div><div>Solar radiation heat gain can lower the air-conditioning energy consumption and improve the thermal environment in winter while it is in summer. However, the traditional building skin material does not address the difference in thermal demand between winter and summer due to the constant solar reflectance. An innovative solution to this issue is the use of thermochromic materials (TCMs), which are capable of altering their colour and solar reflectance in response to temperature changes, thus aligning with the seasonal thermal requirements. Despite the potential of TCMs, a thorough analysis of their advantages and drawbacks to inform their practical application has been lacking in the literature. This review provides an overview of the classification and discolouration mechanism of TCM, performance measurement indicators and evaluation methods, and the main factors affecting the application efficiency of TCM. It provides a comprehensive account of the application efficiency of TCM in the thermal environment of urban buildings and building energy consumption. Finally, the review concludes with suggestions for future research avenues and potential applications, taking into account the limitations currently impeding the full realization of TCMs' efficiency.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101009"},"PeriodicalIF":7.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable full-cell NCM||Graphite system with superior stability: The hybrid impact of sulfone-containing and flame-retardant additives on interface formation and cyclability","authors":"Fereshteh Abbasi ,&nbsp;Mohammadreza Mansournia ,&nbsp;Farshad Boorboor Ajdari ,&nbsp;Abolfazl Fathollahi Zonouz","doi":"10.1016/j.mtsust.2024.101004","DOIUrl":"10.1016/j.mtsust.2024.101004","url":null,"abstract":"<div><div>S-containing additives improve the performance, lifetime, and sustainability of lithium-ion batteries (LIBs) through the stabilization of electrode-electrolyte interfaces, modification of electrolyte properties, and facilitating the efficient resource utilization and rapid Li⁺ migration. Non-etheless, fire safety, extended shelf life, and capacity maintenance are critical concerns for commercial LIBs. Herein, a S-containing film-forming additive, including 4,4-diaminodiphenylsolfon (DADP) by incorporating flame retardancy of dimethyl methyl phosphonate (DMMP) was considered toward taking the barriers of above-mentioned challenges. Based on the calculation, the additives decompose sequentially to produce a distinct SEI via a narrower energy gap under both cathodic and anodic conditions. The NCM532||Graphite with DADP/DMMP showed the enhanced preservation and stability of structure, defined by XRD, Rietveld refinement pattern, SEM, and FT-IR. While the DMMP decreased the fire risk and lowered the capacity due to side reactions, the DADP improved the capacity loss, where the retention rate was 94.91%, 92.01%, 81.29%, and 76.22% within 100, 200, 300, and 400 cycles, respectively. The additive also maintained a capacity of 1123.115 mAhg⁻¹ for 650 cycles, demonstrating excellent cyclability. Therefore, DADP/DMMP facilitate the formation of stable SEI layer, reduce fire risk, improve cycle stability, and offer an achievable path to develop the safe and long-lasting commercial batteries.</div></div>","PeriodicalId":18322,"journal":{"name":"Materials Today Sustainability","volume":"28 ","pages":"Article 101004"},"PeriodicalIF":7.1,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142420941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}