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APMP.QM-S19: Toxic elements in seafood APMP.QM-S19:海产品中的有毒元素
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-19 DOI: 10.1088/0026-1394/61/1a/08001
Kelvin Chun-wai Tse, Wai-hong Fung, Mala Khan, Soraya Sandoval Riquelme, Javier Vera, Li Xiao, Lu Hai, Ronald Cristancho, Adriana Rodriguez, Diego A Garzon Z , Carlos Andres España, Elias Kakoulides, G Karanikolopoulos, E Stathoudaki, V Schoina, Christine Elishian, Isna Komalasari, Luigi Bergamaschi, Giancarlo D'Agostino, Marco di Luzio, Shin-ichi Miyashita, Maria-del-Rocio Arvizu-Torres, Emilia Vasileva-Veleva, Elmer Carrasco, Alleni T Junsay, Michał Strzelec, Richard Shin, Radojko Jaćimović, Milena Horvat, Darja Mazej, Adna Alilović, Tea Zuliani, Angelique Botha, Maré Linsky, Nunnapus Laitip, Ramiro Pérez Zambra, Romina Napoli
Main textSeafood is one of the major food resources for human consumption in the world. The CODEX Alimentarius Commission and many jurisdictions have set maximum levels of metallic contaminants in seafood. The use of reliable methods for measurement of metallic contaminants is important in safeguarding the quality of these products and public health.The Supplementary Comparison APMP.QM-S19: Toxic Elements in Seafood was coordinated by the Government Laboratory, Hong Kong, China (GLHK). Four measurands (arsenic, cadmium, mercury and lead) in seafood were chosen. The last CCQM or RMO key comparison / supplementary comparison in the area of metallic contaminants in seafood was organized by GLHK in 2011 (APMP.QM-S5). Hence, it was timely to organize another comparison that covers different measurands. This Supplementary Comparison (APMP.QM-S19) offers different analytical challenges (e.g. in analysis of mercury and a different range of measurands) as compared to the previous comparison. Moreover, it enabled National Metrology Institutes / Designated Institutes (NMIs/DIs) that did not participate in the previous comparisons to demonstrate their measurement competencies.Nineteen institutes participated in APMP.QM-S19. Most participating NMIs/DIs employed microwave-assisted acid digestion for sample dissolution. Inductively coupled plasma mass spectrometry (ICP-MS), including triple quadrupole and sector field, were the most commonly used instrumental techniques. Results of all participating NMIs/DIs were evaluated against the supplementary comparison reference value (SCRV). The SCRV and associated uncertainty were determined from results of NMIs/DIs that participated in the supplementary comparison using methods with demonstrated metrological traceability. Median was used as estimator of the SCRVs. For arsenic, the SCRV was 1.342 mg/kg calculated from 15 participating NMIs/DIs. For arsenic, cadmium, mercury and lead, the SCRVs were 1.342 mg/kg, 0.3630 mg/kg, 0.1230 mg/kg and 0.4101 mg/kg, respectively, calculated from 15, 14, 13 and 11 participating NMIs/DIs.Participating NMIs/DIs that have successfully participated in APMP.QM-S19 have demonstrated measurement capabilities in determining inorganic elements, in a mass fraction range from 0.02 mg/kg to 50 mg/kg in high organic content matrix, including seafood of animal origin and high protein food.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).
正文海产品是世界上供人类消费的主要食品资源之一。食品法典委员会和许多司法管辖区都规定了海产品中金属污染物的最高含量。使用可靠的方法测量金属污染物对保障这些产品的质量和公众健康非常重要。APMP.QM-S19 号补充比对:海产品中的有毒元素由中国香港政府化验所(GLHK)负责协调。选择了海产品中的四种测量元素(砷、镉、汞和铅)。上一次有关海产品中金属污染物的CCQM或RMO主要比对/补充比对由香港政府化验所于2011年举办(APMP.QM-S5)。因此,再组织一次涵盖不同测量物的比对是及时的。与上次比较相比,本次补充比较(APMP.QM-S19)提出了不同的分析挑战(如汞分析和不同范围的测量剂)。此外,它还使未参加前几次比对的国家计量机构/指定机构(NMIs/DIs)能够展示其测量能力。19个机构参加了APMP.QM-S19。大多数参与比对的 NMI/DI 采用微波辅助酸消解法进行样品溶解。电感耦合等离子体质谱(ICP-MS),包括三重四极杆和扇形场,是最常用的仪器技术。所有参与的 NMIs/DIs 的结果都对照补充比较参考值(SCRV)进行了评估。SCRV 和相关的不确定性是根据参与补充比对的 NMIs/DIs 的结果确定的,这些 NMIs/DIs 使用的方法都具有计量溯源性。中位数被用作 SCRV 的估计值。砷的 SCRV 值为 1.342 mg/kg,由 15 个参与的 NMI/DI 计算得出。砷、镉、汞和铅的 SCRV 值分别为 1.342 mg/kg、0.3630 mg/kg、0.1230 mg/kg 和 0.4101 mg/kg,由 15、14、13 和 11 个参与的 NMI/DIs 计算得出。QM-S19已证明具有测定高有机含量基质(包括动物源海产品和高蛋白食品)中无机元素质量分数范围为0.02毫克/千克至50毫克/千克的能力。请注意,该文本是出现在 BIPM 关键比对数据库附录 B 中的文本 https://www.bipm.org/kcdb/.The 根据 CIPM 互认安排(CIPM MRA)的规定,最终报告已经过同行评审,并获准由 CCQM 出版。
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引用次数: 0
CCEM key comparison CCEM.RF-K26. Attenuation at 18 GHz, 26.5 GHz and 40 GHz using a step attenuator. Final report of the pilot laboratory CCEM 密钥比较 CCEM.RF-K26。使用阶跃衰减器在 18 GHz、26.5 GHz 和 40 GHz 的衰减情况。试验实验室最终报告
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-19 DOI: 10.1088/0026-1394/61/1a/01001
A Widarta
Main textThis report summarizes the results of the Key Comparison CCEM.RF-K26 Attenuation at 18 GHz, 26.5 GHz and 40 GHz using a step attenuator which has been performed from January 2015 to February 2018. Fourteen National Metrology Institutes (NMIs) participated in this key comparison, including the National Metrology Institute of Japan (NMIJ/AIST, Japan) which served as pilot laboratory, the National Institute of Metrology (NIM, China), the Physikalisch-Technische Bundesanstal (PTB, Germany), the Laboratoire national de métrologie et d'essais (LNE, France), the Swiss Federal Office for Metrology and Accreditation (METAS, Switzerland), the National Physical Laboratory of India (NPLI, India), the All-Russian Scientific Research Institute of Physico-Technical Measurements (VNIIFTRI, Russia), the Korea Research Institute of Standard and Science (KRISS, South Korea), the National Physical Laboratory (NPL, United Kingdom), the National Metrology Institute of South Africa (NMISA, South Africa), the Tubitak Ulusal Metrologi Enstitűsű (TUBITAK-UME, Turkey), the National Metrology Centre (NMC-A*STAR, Singapore), the Czech Metrology Institute (CMI, Czech Republic) and the Instituto Nacional de Tecnica Aeroespacial (INTA, Spain). The Key Comparison Reference Values (KCRVs) were determined from the measurement results of five to ten participating NMIs, depending on the attenuation and frequency.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.The final report has been peer-reviewed and approved for publication by the CCEM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).
正文本报告总结了2015年1月至2018年2月期间使用阶跃衰减器进行的CCEM.RF-K26在18 GHz、26.5 GHz和40 GHz衰减的关键比对结果。十四个国家计量院(NMI)参与了此次关键比对,包括作为试点实验室的日本国家计量院(NMIJ/AIST,日本)、中国国家计量院(NIM,中国)、德国联邦物理技术局(PTB,德国)、法国国家计量和测试实验室(LNE,法国)、瑞士联邦计量和认可局(METAS,瑞士)、印度国家物理实验室(NPLI,印度)、全俄物理技术测量科学研究院(VNIIFTRI,俄罗斯)、韩国标准与科学研究院 (KRISS,韩国)、国家物理实验室(NPL,英国)、南非国家计量研究院 (NMISA、南非)、Tubitak Ulusal Metrologi Enstitűsű(TUBITAK-UME,土耳其)、国家计量中心(NMC-A*STAR,新加坡)、捷克计量研究所(CMI,捷克共和国)和西班牙国家航空技术研究所(INTA,西班牙)。关键比较参考值 (KCRV) 是根据五到十个参与国家计量院的测量结果确定的,具体取决于衰减和频率。请注意,此文本为 BIPM 关键比对数据库附录 B 中的文本 https://www.bipm.org/kcdb/.The 根据 CIPM 互认安排 (CIPM MRA) 的规定,最终报告已通过同行评审,并批准由 CCEM 出版。
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引用次数: 0
International comparison of measurements of neutron source emission rate (2016-2021) - CCRI(III)-K9.Cf.2016 中子源发射率测量的国际比较(2016-2021 年)--CCRI(III)-K9.Cf.2016
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-19 DOI: 10.1088/0026-1394/61/1a/06001
N J Roberts, N A Horwood, Z Vykydal, H Park, J Kim, W W Pereira, E S da Fonseca, C Thiam, Zhang Hui, M S Dewey, H P Mumm, H Harano, T Matsumoto, A Masuda, S Manabe, J P Archambault, N N Moiseev, A V Didyk
Main textSection III (neutron measurements) of the Comité Consultatif des Rayonnements Ionisants, CCRI, conducted a comparison of primary measurements of the neutron emission rate of a 252Cf radionuclide source. A single 252Cf source was circulated to all participants between 2016 and 2020. Ten laboratories participated -CMI (Czech Republic), KRISS (Republic of Korea), IRD/LNMRI (Brazil), LNE-LNHB (France), NIM (China), NIST (USA), NMIJ (Japan), NPL (UK), NRC (Canada) and VNIIM (Russia) - with NPL making their measurements at the start and repeating them at the end of the exercise to verify the 250Cf content of the source. Each laboratory reported the emission rate into 4π sr together with a detailed uncertainty budget. All participants used the manganese bath technique except NMIJ who used a relative method based on measurements with a 3He detector in a graphite pile. VNIIM also made measurements using an associated particle technique. CMI, KRISS, LNE-LNHB, NIM, NPL and VNIIM also measured the anisotropy of the source although this did not formally form part of the comparison.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.The final report has been peer-reviewed and approved for publication by the CCRI, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).
正文电离辐射咨询委员会第三分会(中子测量)对252Cf放射性核素源的中子发射率进行了一次初级测量比较。在 2016 年至 2020 年期间,向所有参与者分发了一个 252Cf 源。十个实验室参加了此次活动:CMI(捷克共和国)、KRISS(大韩民国)、IRD/LNMRI(巴西)、LNE-LNHB(法国)、NIM(中国)、NIST(美国)、NMIJ(日本)、NPL(英国)、NRC(加拿大)和 VNIIM(俄罗斯),其中 NPL 在活动开始时进行测量,并在活动结束时重复测量,以验证源中的 250Cf 含量。每个实验室都报告了 4π sr 的发射率以及详细的不确定性预算。所有参与者都使用了锰浴技术,只有日本国家海洋研究所使用了一种基于石墨堆中 3He 探测器测量的相对方法。VNIIM 也使用了伴生粒子技术进行测量。CMI、KRISS、LNE-LNHB、NIM、NPL 和 VNIIM 还测量了源的各向异性,尽管这并不是比较的正式组成部分。请注意,此文本是出现在 BIPM 关键对比数据库附录 B 中的文本 https://www.bipm.org/kcdb/.The 根据 CIPM 互认安排 (CIPM MRA) 的规定,最终报告已经过同行评审,并获准由 CCRI 出版。
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引用次数: 0
Evaluation of the relativistic redshift in frequency standards at KRISS 对 KRISS 频率标准中相对论红移的评估
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-09 DOI: 10.1088/1681-7575/ad1ca9
Jisun Lee, Jay Hyoun Kwon, Chang Yong Park, Huidong Kim, In-Mook Choi, Jin Wan Chung, Won-Kyu Lee
Relativistic redshift correction should be accurately considered in frequency comparisons between frequency standards. In this study, we evaluated the relativistic redshift at Korea Research Institute of Standards and Science (KRISS) using three different methods, depending on whether the approach was traditional or modern or whether the geopotential model was global or local. The results of the three methods agreed well with one another, and the height of an Yb optical lattice clock (KRISS-Yb1) was determined to be 75.15 m with an uncertainty of 0.04 m with respect to the conventionally adopted equipotential surface W_0^CGPM, the value of which is defined to be 62 636 856.0 m2s-2. Accordingly, the relativistic redshift of KRISS-Yb1 was evaluated to be 8.193(4) × 10−15. These data are applicable to the frequency standards at KRISS, one of which regularly participates in the calibration of the International Atomic Time (TAI).
在频率标准之间进行频率比较时,应准确考虑相对论红移校正。在这项研究中,我们使用三种不同的方法评估了韩国标准与科学研究院(KRISS)的相对论红移,这取决于采用的方法是传统的还是现代的,或者地球位势模型是全球的还是局部的。三种方法的结果相互吻合,镱光晶格钟(KRISS-Yb1)的高度被确定为 75.15 米,与传统采用的等势面 W_0^CGPM 相比,不确定度为 0.04 米,等势面 W_0^CGPM 的值被定义为 62 636 856.0 m2s-2。因此,KRISS-Yb1 的相对论红移被评估为 8.193(4) × 10-15。这些数据适用于 KRISS 的频率标准,其中一个频率标准定期参与校准国际原子时(TAI)。
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引用次数: 0
A New Interpolation Equation in the ITS-90 Subrange from the Triple Point of Water to the Freezing Point of Indium 从水的三相点到铟的凝固点的 ITS-90 子范围内的新插值公式
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-08 DOI: 10.1088/1681-7575/ad1bfb
Kang Lan, Lide Fang, Ying Wang, Zhiru Kang, Suli Sang
For all the subranges above 0.01 ℃, other than the interpolation between the triple point of water (TPW) to the melting point of gallium, temperatures on the ITS-90 are specified without the melting point of gallium. This study suggests a new interpolation equation in the subrange from the triple point of water to the freezing point of indium which is a polynomial of fractional third order with two coefficients to be determined by the measuring values of standard platinum resistance thermometers (SPRTs)’ resistance ratios at the melting point of gallium (WGa) and at the freezing point of indium (WIn). A sample set of 30 SPRTs from various countries and laboratories is used to quantify the comparisons between this new interpolation and the ITS-90. Analyses show that the reproducibility is significantly improved compared with the ITS-90 in the same subrange. The peak value of overlapping subrange inconsistencies (SRI) from TPW to the melting point of gallium is reduced from 0.91 mK to 0.21 mK. Both the mean and standard deviation of the SRI peak values for the new equation decrease by approximately a factor of four compared to those of the ITS-90 (mean decreasing form 0.20 mK to 0.05 mK and standard deviation decreasing form 0.32 mK to 0.07 mK). Type 3 non-uniqueness (NU3) determinations of the same subrange have also been looked into with a data set of four SPRTs compared in thermostatic baths using a copper block and the results show that NU3 scales down from a range -0.15 mK to 0.25 mK of the ITS-90 to -0.10 mK to 0.15 mK of the new interpolation equation. Propagation of Uncertainties investigation shows that the new equation inflates merely 7% the measurement uncertainties of fixed points in a relatively short interval from 30 ℃ to 60 ℃.
对于 0.01 ℃ 以上的所有子范围,除了水的三相点(TPW)到镓的熔点之间的插值以外,ITS-90 上的温度都是在没有镓的熔点的情况下指定的。本研究提出了一个从水的三重点到铟的凝固点的新插值方程,它是一个分数三阶多项式,有两个系数,由标准铂电阻温度计(SPRT)在镓的熔点(WGa)和铟的凝固点(WIn)的电阻比测量值决定。一组来自不同国家和实验室的 30 个 SPRT 样本用于量化这种新插值法与 ITS-90 之间的比较。分析表明,在相同的子范围内,与 ITS-90 相比,重现性明显提高。从 TPW 到镓熔点的重叠子范围不一致性 (SRI) 峰值从 0.91 mK 降至 0.21 mK。与 ITS-90 相比,新方程 SRI 峰值的平均值和标准偏差都降低了约 4 倍(平均值从 0.20 mK 降至 0.05 mK,标准偏差从 0.32 mK 降至 0.07 mK)。此外,还使用铜块在恒温水浴中比较了四个 SPRT 的数据集,对同一子范围的第 3 类非唯一性(NU3)进行了测定,结果表明,NU3 的范围从 ITS-90 的 -0.15 mK 至 0.25 mK 缩小到新插值方程的 -0.10 mK 至 0.15 mK。不确定度的传播调查表明,新方程在 30 ℃ 至 60 ℃ 的较短区间内仅使固定点的测量不确定度增加了 7%。
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引用次数: 0
Length measurement based on multi-wavelength interferometry using numerous stabilized frequency modes of an optical comb 基于多波长干涉测量法的长度测量,使用光学梳的众多稳定频率模式
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-04 DOI: 10.1088/1681-7575/ad1af1
Jungjae Park, Yoonhee Jang, Jonghan Jin
The electro-optic comb (EO comb) with a relatively wide mode spacing of 25 GHz can be resolved into individual frequency modes with a commercially available high-resolution spectrometer. The EO comb has numerous discrete frequency modes, which can serve as a light source for a monochromatic laser interferometer to realize the meter. In this study, a method for measuring the absolute distances based on the multi-wavelength interferometer principle is proposed and demonstrated by simultaneously implementing 102 monochromatic laser interferometers using an EO comb. A phase shifting technique was used to determine the phase for each frequency mode by precisely translating a reference mirror with a constant interval. The phases of the interference signals for 102 stabilized individual frequency modes were measured by applying the model-based analysis on the phase-shifted interference signals. The absolute distance can be determined using phase values of a wavelength set corresponding to five to seven randomly selected frequency modes. In this study, the absolute distances for round-trip distances of 166 mm and 1316 mm were measured and the measurement uncertainty of each distance was evaluated. Through the uncertainty analysis of the distance measurement, the combined uncertainties of the measured distances in a short and long ranges were evaluated to be 30.1 nm and 211.1 nm, respectively. In addition, for each distance, the consistent measurement results of absolute distances were obtained through four different wavelength sets, which show the flexibility of wavelength selection in this work.
电光梳(EO comb)的模式间距相对较宽,为 25 千兆赫,可利用市售的高分辨率光谱仪将其解析为单个频率模式。环光学梳具有许多离散的频率模式,可以作为单色激光干涉仪的光源来实现测量。本研究提出了一种基于多波长干涉仪原理的绝对距离测量方法,并通过使用环氧乙烷梳同时实施 102 个单色激光干涉仪进行了演示。采用相移技术,通过以恒定间隔精确平移参考镜来确定每个频率模式的相位。通过对相移干涉信号进行基于模型的分析,测量了 102 个稳定的单个频率模式的干涉信号的相位。绝对距离可以通过与随机选择的五到七个频率模式相对应的波长集的相位值来确定。本研究测量了 166 毫米和 1316 毫米往返距离的绝对距离,并评估了每个距离的测量不确定性。通过对距离测量的不确定度分析,估算出短距离和长距离测量距离的综合不确定度分别为 30.1 nm 和 211.1 nm。此外,对于每个距离,通过四组不同的波长,都获得了一致的绝对距离测量结果,这显示了这项工作在波长选择上的灵活性。
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引用次数: 0
A strontium lattice clock with both stability and uncertainty below 5×10−18 稳定性和不确定性均低于 5×10-18 的锶晶格时钟
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-03 DOI: 10.1088/1681-7575/ad1a4c
Jie Li, Xing-Yang Cui, Zhi-Peng Jia, De-Quan Kong, Hai-Wei Yu, Xian-Qing Zhu, Xiao-Yong Liu, De-Zhong Wang, Xiang Zhang, Xin-Yun Huang, Ming-Yi Zhu, Yu-Meng Yang, Yi Hu, Xiang-Pei Liu, Xiaomin Zhai, Peng Liu, Xiao Jiang, Ping Xu, Han-Ning Dai, Yuao Chen, Jian-Wei Pan
We report the realization of the closed-loop operation of an optical lattice clock based on 87Sr atoms. A cavity-stabilized 698 nm laser is used to probe the 1S0→3P0 clock transition of strontium atoms trapped in optical lattices. Therein, we obtain a Fourier-limited Rabi spectrum with 0.6 Hz linewidth. The two transitions from mF=±9/2 ground states are alternatively interrogated to realize the closed-loop operation of the clock, and the clock laser light is frequency-stabilized to the center of the two transitions. Based on the interleaved measurement, the frequency instability of a single optical clock is optimized for the Dick effect, which is demonstrated to be 4.5×10−16/τ , with τ being the averaging time for measurement. Further, we build another similar setup of the strontium lattice clock, which is used for the asynchronous comparison between the two clocks, where the stability is measured as 2.1×10−18 at 47 000 s. Moreover, we carefully calibrate the systematic effects of the Sr1 optical clock, and the total uncertainty is evaluated as 4.4×10−18 .
我们报告了基于 87Sr 原子的光晶格时钟实现闭环运行的情况。我们使用空腔稳定的 698 nm 激光来探测困在光学晶格中的锶原子的 1S0→3P0 时钟转变。我们从中获得了线宽为 0.6 Hz 的傅立叶限幅拉比光谱。从 mF=±9/2 基态开始的两个跃迁被交替询问,以实现时钟的闭环运行,时钟激光被稳频到两个跃迁的中心。在交错测量的基础上,对单个光学时钟的频率不稳定性进行了迪克效应优化,证明其频率不稳定性为 4.5×10-16/τ,τ 为测量的平均时间。此外,我们还建立了另一个类似的锶晶格时钟装置,用于两个时钟之间的异步比较,在 47 000 s 时测得的稳定性为 2.1×10-18。此外,我们还仔细校准了 Sr1 光学时钟的系统效应,总的不确定性被评估为 4.4×10-18 。
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引用次数: 0
Final report, ongoing key comparison BIPM.QM-K1, ozone at ambient level, comparison with NMC-A*STAR, July 2022 最终报告,正在进行的关键比较 BIPM.QM-K1,环境水平的臭氧,与 NMC-A*STAR 的比较,2022 年 7 月
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2024-01-01 DOI: 10.1088/0026-1394/61/1a/08008
Joële Viallon, Faraz Idrees, Philippe Moussay, Robert Wielgosz, Fuuming Kai, Lemuel Joel Kuehsamy, Yuxi Cui, James E Norris, Joseph Hodges
Main textAs part of the ongoing key comparison BIPM.QM-K1, a comparison has been performed between the ozone national standard of Singapore maintained by the National Metrology Centre, A*STAR (NMC, A*STAR) and the common reference standard of the key comparison, maintained by the Bureau International des Poids et Mesures (BIPM), via a transfer standard maintained by the National Institute of Standards and Technology (NIST). The instruments have been compared over a nominal ozone amount-of-substance fraction range of 0 nmol/mol to 500 nmol/mol.To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database https://www.bipm.org/kcdb/.The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).
正文 作为正在进行的关键比对 BIPM.QM-K1 的一部分,对新加坡国家计量中心(NMC, A*STAR)维护的新加坡臭氧国家标准与国际计量局(BIPM)维护的关键比对通用参考标准进行了比对,并通过美国国家标准与技术研究院(NIST)维护的转移标准进行了比对。这些仪器在 0 nmol/mol 至 500 nmol/mol 的标称臭氧物质分数范围内进行了比较。请注意,该文本是出现在 BIPM 关键对比数据库附录 B 中的文本 https://www.bipm.org/kcdb/.The 根据 CIPM 互认安排(CIPM MRA)的规定,最终报告已经过同行评审,并获准由 CCQM 出版。
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引用次数: 0
A Bayesian statistical method for large-scale MEMS-based sensors calibration: a case study on 100 digital accelerometers 基于 MEMS 的大规模传感器校准贝叶斯统计方法:100 个数字加速度计的案例研究
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-12-28 DOI: 10.1088/1681-7575/ad1692
Andrea Prato, Francesca Pennecchi, Gianfranco Genta, Alessandro Schiavi
Low-cost sensors and in particular micro-electro-mechanical systems (MEMS) devices are widely used in many applications, including consumer electronics, healthcare, automotive, and industrial automation. Their large-scale production (typically in the order of millions per week in a single factory) would require the calibration of a huge number of devices that would be costly and time-consuming. A solution can be found in the use of statistical methods in order to (at least partially) substitute for the typical calibration procedures. In this work, we propose a Bayesian method to statistically calibrate large batches of sensors using probabilistic models and prior knowledge. The method involves experimentally calibrating only a small sample of sensors, then infer the number of reliable sensors in the entire batch and assign an appropriate uncertainty to all the sensors. Therefore, it can be considered as a statistical calibration of the batch. The Bayesian nature of this approach allows reducing the number of experimental calibrations by incorporating the prior knowledge coming from the previous calibration of a ‘benchmark’ batch, which is performed ‘once and for all’ and is representative of the whole production process. The application and validation of the method are performed through the calibration of 100 digital MEMS accelerometers. Validation results showed an acceptable agreement between experimental-based bootstrap and theoretical values, with relative differences within ±7%.
低成本传感器,特别是微机电系统(MEMS)设备被广泛应用于许多领域,包括消费电子、医疗保健、汽车和工业自动化。这些设备的大规模生产(通常单个工厂每周生产数百万个)需要对大量设备进行校准,成本高昂且耗时。为了(至少部分)替代典型的校准程序,可以通过使用统计方法来找到解决方案。在这项工作中,我们提出了一种贝叶斯方法,利用概率模型和先验知识对大批传感器进行统计校准。该方法只对少量传感器样本进行实验校准,然后推断出整批传感器中可靠传感器的数量,并为所有传感器分配适当的不确定性。因此,可以将其视为批次的统计校准。这种方法具有贝叶斯性质,可以将以前校准 "基准 "批次时获得的先验知识纳入其中,从而减少实验校准的次数,因为 "基准 "批次的校准是 "一劳永逸 "的,可以代表整个生产过程。通过校准 100 个数字 MEMS 加速计,对该方法进行了应用和验证。验证结果表明,基于实验的自举法与理论值之间的一致性可以接受,相对差异在 ±7% 以内。
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引用次数: 0
On the distinction between SI base units and SI derived units 关于国际单位制基本单位与国际单位制派生单位的区别
IF 2.4 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Pub Date : 2023-12-11 DOI: 10.1088/1681-7575/ad141b
Richard J. C. Brown
This letter discusses the criteria that should be considered when deciding whether or not the distinction between base units and derived units in the International System of Units (SI) is useful, a debate that has been reignited following the 2019 revision of the SI. It is proposed that the correct question to ask is whether the concept of independent quantities, and the dimensional analysis it allows, remains useful—since that is the ultimate origin of the distinction between SI base units and SI derived units. Furthermore, the letter explains that this distinction is not related to whether the defining constants used in the revised SI after 2019 are any more fundamental than they were previously, nor whether the links between defining constants and SI base units are any less direct than they were prior to 2019. Finally, an opinion is offered that the concept of quantity dimensions and dimensional analysis remains useful, and certainly does no harm.
这封信讨论了在决定国际单位制(SI)中基本单位和派生单位之间的区别是否有用时应考虑的标准。信中提出,正确的问题应该是独立量的概念及其所允许的尺寸分析是否仍然有用--因为这是区分国际单位制基本单位和国际单位制派生单位的最终起源。此外,信中还解释说,这种区别与 2019 年后修订的国际单位制中使用的定义常数是否比以前更基本无关,也与定义常数和国际单位制基本单位之间的联系是否不如 2019 年前那么直接无关。最后,有一种观点认为,数量维度和维度分析的概念仍然有用,而且肯定没有坏处。
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引用次数: 0
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Metrologia
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