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RETRACTED: Kelly et al. Delineating Conformational Variability in Small Protein Structures Using Combinatorial Refinement Strategies. Micromachines 2023, 14, 1869. 撤稿:Kelly等人。利用组合优化策略描述小蛋白质结构的构象变异性。微机械2023,14,1869。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-25 DOI: 10.3390/mi16121317
Deborah F Kelly, G M Jonaid, Liam Kaylor, Maria J Solares, Samantha Berry, Liza-Anastasia DiCecco, William Dearnaley, Michael Casasanta

The Journal retracts the article titled "Delineating Conformational Variability in Small Protein Structures Using Combinatorial Refinement Strategies" [...].

该杂志撤回了题为“使用组合优化策略描绘小蛋白质结构的构象变异性”的文章[…]。
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引用次数: 0
A Two-Stage Unet Framework for Sub-Resolution Assist Feature Prediction. 亚分辨率辅助特征预测的两阶段Unet框架。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-20 DOI: 10.3390/mi16111301
Mu Lin, Le Ma, Lisong Dong, Xu Ma

Sub-resolution assist feature (SRAF) is a widely used resolution enhancement technology for improving image contrast and the common process window in advanced lithography processes. However, both model-based SRAF and rule-based SRAF methods suffer from challenges of adaptability or high computational cost. The primary learning-based SRAF method adopts an end-to-end mode, treating the entire mask pattern as a pixel map, and it is difficult to obtain precise geometric parameters for the commonly used Manhattan SRAFs. This paper proposes a two-stage Unet framework to effectively predict the centroid coordinates and dimensions of SRAF polygons. Furthermore, an adaptive hybrid attention mechanism is introduced to dynamically integrate global and local features, thus enhancing the prediction accuracy. Additionally, a warm-up cosine annealing learning rate strategy is adopted to improve the training stability and convergence speed. Simulation results demonstrate that the proposed method accurately and rapidly estimates the SRAF parameters. Compared to traditional neural networks, the proposed method can better predict SRAF patterns, with the mean pattern error and edge placement error values showing the most significant reductions. PE decreases from 25,776.44 to 15,203.33 and EPE from 5.8367 to 3.5283, respectively. This significantly improves the image fidelity of the lithography system.

亚分辨率辅助特征(SRAF)是一种广泛应用于高级光刻工艺的分辨率增强技术,用于提高图像对比度和共同的工艺窗口。然而,基于模型的SRAF方法和基于规则的SRAF方法都存在适应性差和计算成本高的问题。主要的基于学习的SRAF方法采用端到端模式,将整个掩模模式视为像素图,常用的Manhattan SRAF难以获得精确的几何参数。为了有效地预测SRAF多边形的质心坐标和尺寸,提出了一种两阶段Unet框架。引入自适应混合注意机制,动态整合全局特征和局部特征,提高预测精度。此外,采用了预热余弦退火学习率策略,提高了训练稳定性和收敛速度。仿真结果表明,该方法能够准确、快速地估计出SRAF参数。与传统神经网络相比,该方法可以更好地预测SRAF模式,平均模式误差和边缘放置误差值降低最为显著。PE从25776.44降低到15203.33,EPE从5.8367降低到3.5283。这大大提高了光刻系统的图像保真度。
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引用次数: 0
Investigation of Electron Transport Layer Influence on Asymmetric Bipolar Switching in Transparent BST-Based RRAM Devices. 透明bst基RRAM器件中电子传输层对非对称双极开关影响的研究。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-20 DOI: 10.3390/mi16111302
Kai-Huang Chen, Ming-Cheng Kao, Hsin-Chin Chen, Yao-Chin Wang, Chien-Min Cheng, Wei-Min Xu

Ba0.6Sr0.4TiO3 (BST) thin films were deposited on ITO substrates via rf magnetron sputtering, followed by structural and morphological characterization using XRD and FE-SEM. Metal-insulator-metal (MIM) RRAM devices were fabricated by depositing Al top electrodes, and their electrical properties were examined through I-V measurements. The optimized BST films deposited at 40% oxygen concentration exhibited stable resistive switching, with an operating voltage of 3 V, an on/off ratio of 1, and a leakage current of 10-8 A. After rapid thermal annealing at 500 °C, the on/off ratio improved to 2 but leakage increased to 10-3 A. Incorporating an electron transport layer (ETL) effectively suppressed the leakage current to 10-5 A while maintaining the on/off ratio at 2. Moreover, a transition from bipolar to unipolar switching was observed at higher oxygen concentration (60%). These results highlight the role of ETLs in reducing leakage and stabilizing switching characteristics, providing guidance for the development of transparent, low-power, and high-reliability BST-based RRAM devices. This study aims to investigate the role of Ba0.6Sr0.4TiO3 (BST) ferroelectric oxide as a functional switching layer in resistive random-access memory (RRAM) and to evaluate how interface engineering using an electron transport layer (ETL) can improve resistive switching stability, leakage suppression, and device reliability.

采用射频磁控溅射法在ITO衬底上沉积了Ba0.6Sr0.4TiO3 (BST)薄膜,并用XRD和FE-SEM对其进行了结构和形态表征。采用沉积Al顶电极的方法制备了金属-绝缘体-金属(MIM) RRAM器件,并对其电学性能进行了I-V测量。在40%氧浓度下制备的BST薄膜具有稳定的阻性开关,工作电压为3 V,开关比为1,漏电流为10-8 a。在500℃快速热退火后,通/关比提高到2,但漏电流增加到10-3 A。结合电子传输层(ETL)有效地将泄漏电流抑制到10- 5a,同时将通/关比保持在2。此外,在更高的氧浓度(60%)下,观察到从双极到单极转换的转变。这些结果突出了etl在减少泄漏和稳定开关特性方面的作用,为开发透明、低功耗和高可靠性的基于bst的RRAM器件提供了指导。本研究旨在探讨Ba0.6Sr0.4TiO3 (BST)铁电氧化物在电阻性随机存取存储器(RRAM)中作为功能开关层的作用,并评估使用电子传输层(ETL)的界面工程如何提高电阻性开关稳定性、泄漏抑制和器件可靠性。
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引用次数: 0
Structural and Gas-Sensitive Characteristics of In2O3: Effect of Hydrothermal/Solvothermal Synthesis Conditions. 水热/溶剂热合成条件对In2O3结构和气敏特性的影响
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-20 DOI: 10.3390/mi16111299
Mariya I Ikim, Varvara A Demina, Elena Y Spiridonova, Olusegun J Ilegbusi, Leonid I Trakhtenberg

In2O3 nanoparticles were obtained by annealing precursors that had been hydrothermally/solvothermally synthesized at 200 °C using In(NO3)3·4.5H2O as the starting material. Three solvents were used for the synthesis, namely water, alcohol and ethylene glycol. Urea or glycine additives were introduced into the reaction mixtures as stabilizing and structure-forming agents. The nanopowders obtained were characterized using X-ray diffraction, scanning and transmission electron microscopy, low-temperature nitrogen adsorption and X-ray photoelectron spectroscopy. The gas-sensing characteristics of the indium oxide-based sensors were investigated for the detection of hydrogen in air. It has been established that the nature of the solvent determines the phase composition and structure of indium oxide, while organic additives reduce the particle size and increase the specific surface area. It should be noted that the addition of glycine to an alcohol solution of indium nitrate during synthesis produces a phase transformation. The results show that the sensor based on In2O3 synthesized using this mixture has the best hydrogen sensing properties of all the materials considered in this study.

以In(NO3)3·4.5H2O为原料,在200℃下进行水热/溶剂热合成的前驱体退火,得到了纳米In2O3。合成时使用了三种溶剂,即水、醇和乙二醇。在反应混合物中加入尿素或甘氨酸作为稳定剂和成结构剂。采用x射线衍射、扫描电镜、透射电镜、低温氮吸附、x射线光电子能谱等手段对制备的纳米粉体进行了表征。研究了氧化铟基传感器对空气中氢气的气敏特性。已经确定溶剂的性质决定了氧化铟的相组成和结构,而有机添加剂减小了氧化铟的粒径,增加了氧化铟的比表面积。应当注意的是,在合成过程中将甘氨酸加入硝酸铟的醇溶液中会产生相变。结果表明,用该混合物合成的基于In2O3的传感器具有本研究所考虑的所有材料中最好的氢传感性能。
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引用次数: 0
Phenomenological Modeling of Shape Memory Alloys: A Review of Macroscopic Approaches. 形状记忆合金的现象学建模:宏观方法综述。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-20 DOI: 10.3390/mi16111300
Girolamo Costanza, Maria Elisa Tata, Saeed Danaee Barforooshi

Shape Memory Alloys (SMAs) have unique thermomechanical properties, including superelasticity and the shape memory effect, which has led them to be used in a wide range of applications, from biomedical devices to aerospace and civil engineering structures. These behaviors have been addressed by phenomenological models, which represent them by simply establishing stress-strain and transformation characteristics without accounting for the microstructure. In this review article, the main phenomenological modeling examples are categorized and compared, including the main principles of operation, predictions, and limitations under operating thermomechanical loading conditions. In addition, the growing use of SMAs, especially in actuation, damping, vibration control, and energy harvesting, is explored, and the incorporation of modeling frameworks into optimization activities is discussed. The final part of the review deals with open challenges and future research directions, consisting of the development of models that more accurately predict SMAs under cyclic and/or non-proportional loading, a more robust association with commercial computational tools, and exploring the use of SMAs in new interdisciplinary areas. By bridging modeling approaches to application-based concepts, a platform is provided for the advancement of both the scientific development and practical use of shape memory alloys.

形状记忆合金(sma)具有独特的热机械性能,包括超弹性和形状记忆效应,这使得它们在从生物医学设备到航空航天和土木工程结构的广泛应用中得到应用。这些行为已经被现象学模型所解决,这些模型通过简单地建立应力-应变和转变特征来表示它们,而不考虑微观结构。在这篇综述文章中,对主要的现象学建模实例进行了分类和比较,包括主要的操作原理,预测和操作热机械负载条件下的局限性。此外,还探讨了sma在驱动、阻尼、振动控制和能量收集方面的日益增长的应用,并讨论了将建模框架纳入优化活动的问题。综述的最后一部分讨论了开放的挑战和未来的研究方向,包括开发更准确地预测循环和/或非比例载荷下sma的模型,与商业计算工具建立更强大的联系,以及探索sma在新的跨学科领域的应用。通过将建模方法与基于应用的概念相结合,为形状记忆合金的科学发展和实际应用提供了一个平台。
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引用次数: 0
Design of a Multi-Beam Switching Antenna Loaded with a Square Metasurface. 加载方形超表面的多波束交换天线设计。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-20 DOI: 10.3390/mi16111298
Ningchuan Liu, Lin Huang, Lingxiao Huang

Multi-beam and beam-scanning antennas enable extensive communication coverage while mitigating multipath fading and enhancing spectrum utilization efficiency. This paper presents a transmissive metasurface antenna design, which utilizes a microstrip square-ring patch antenna with four feed ports as the excitation source. A 7 × 7 square patch metasurface is positioned above the feed source, facilitating the generation of four independently steerable beams by switching activation among the four feed ports. Operating at 12.6 GHz, the antenna achieves a gain of 10.4 dB. The 3 dB beamwidth of the beams from all four ports exceeds 23°. The proposed design offers advantages of structural simplicity, low profile, and cost-effectiveness. By leveraging transmissive metasurfaces, this approach combines the benefits of low profile and low cost with flexible manipulation of electromagnetic wave radiation, thereby providing a novel methodology for designing multi-beam communication antennas.

多波束和波束扫描天线可以在减少多径衰落和提高频谱利用效率的同时实现广泛的通信覆盖。本文提出了一种传输型超表面天线的设计方案,该天线采用带四个馈电口的微带方环贴片天线作为激励源。一个7 × 7的正方形贴片超表面位于馈源上方,通过在四个馈源端口之间切换激活,促进了四个独立可操纵光束的产生。工作频率为12.6 GHz,天线增益为10.4 dB。4个端口的3db波束宽度均超过23°。提出的设计具有结构简单、低调和成本效益的优点。通过利用传输超表面,该方法结合了低轮廓和低成本的优点以及灵活操纵电磁波辐射,从而为设计多波束通信天线提供了一种新的方法。
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引用次数: 0
Structural Optimization and Simulation of Dual-Frequency Piezoelectric Micromachined Ultrasonic Transducers. 双频压电微机械超声换能器的结构优化与仿真。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-19 DOI: 10.3390/mi16111296
Fengwen Wang, Longlong Cao, Mingliang Jin

Ultrasound transducers are fundamental components in medical imaging systems, impacting resolution, sensitivity, and penetration depth. A key challenge in designing high-performance ultrasound transducers is balancing bandwidth and sensitivity. This study focuses on optimizing the backing layer of a dual-frequency piezoelectric micromachined ultrasound transducer (PMUT) using polydimethylsiloxane (PDMS). COMSOL multi-physics version 6.2 finite element simulations and equivalent circuit modeling were employed to investigate the effects of PDMS backing layer thickness and geometry on frequency response characteristics, impedance matching, and acoustic sensitivity. The optimized PMUT structure demonstrated a significant enhancement in bandwidth, with the -6 dB bandwidth increasing to 92% at both 2.3 MHz and 6.8 MHz frequencies. The PDMS backing layer improved the matching of low- and high-frequency signals, enabling high sensitivity and reduced interface reflection losses. The incorporation of PDMS as the backing layer successfully expands the operational bandwidth of dual-frequency PMUTs while maintaining high sensitivity, offering promising potential for high-performance ultrasound imaging, particularly in medical applications requiring both deep penetration and high-resolution imaging.

超声换能器是医学成像系统的基本组成部分,影响分辨率、灵敏度和穿透深度。设计高性能超声换能器的一个关键挑战是平衡带宽和灵敏度。本文研究了利用聚二甲基硅氧烷(PDMS)对双频压电微机械超声换能器(PMUT)衬底层进行优化。采用COMSOL多物理场6.2版有限元仿真和等效电路建模,研究了PDMS背衬层厚度和几何形状对频率响应特性、阻抗匹配和声灵敏度的影响。优化后的PMUT结构显著提高了带宽,在2.3 MHz和6.8 MHz频率下-6 dB带宽均提高到92%。PDMS衬底层改善了低频和高频信号的匹配,实现了高灵敏度,减少了界面反射损耗。PDMS作为衬底层的结合成功地扩展了双频pmut的工作带宽,同时保持了高灵敏度,为高性能超声成像提供了有希望的潜力,特别是在需要深穿透和高分辨率成像的医疗应用中。
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引用次数: 0
Review on Research Progress of Photoelectrochemical Biosensors. 光电化学生物传感器研究进展综述。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-19 DOI: 10.3390/mi16111293
Yu Zeng, Yuheng Wang, Yaqing Zhang

Photoelectrochemical (PEC) biosensors have emerged as a significant research focus in the fields of bioanalysis and medical diagnostics in recent years due to their high sensitivity, low background noise, and ease of miniaturization. This review summarizes the fundamental principles of PEC biosensors, recent advances in photoactive materials, signal amplification strategies, and typical applications. Photoactive materials serve as the source of the sensor signal and can achieve signal enhancement through strategies such as heterostructure construction, localized surface plasmon resonance (LSPR) effects, and defect engineering. PEC sensors have been widely applied in areas such as cancer liquid biopsy and pathogen detection; however, challenges remain, including material biocompatibility, anti-interference capability in complex samples, and lack of standardized platforms. Future development trends include the design of green and low-toxicity photosensitive materials, integration with microfluidic and wearable devices, and artificial intelligence-assisted signal analysis, which will promote the translation of PEC biosensors toward clinical applications and real-time detection.

光电化学(PEC)生物传感器具有灵敏度高、背景噪声低、易于小型化等优点,近年来已成为生物分析和医学诊断领域的重要研究热点。本文综述了PEC生物传感器的基本原理、光活性材料的最新进展、信号放大策略和典型应用。光活性材料作为传感器信号的来源,可以通过异质结构构建、局部表面等离子体共振(LSPR)效应和缺陷工程等策略实现信号增强。PEC传感器已广泛应用于肿瘤液体活检、病原体检测等领域;然而,挑战仍然存在,包括材料的生物相容性,复杂样品的抗干扰能力,以及缺乏标准化平台。未来的发展趋势包括绿色低毒性光敏材料的设计、与微流控和可穿戴设备的集成、人工智能辅助信号分析等,这将推动PEC生物传感器向临床应用和实时检测的转变。
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引用次数: 0
Multiphysics Measurement Method for Supercapacitors State of Health Determination. 超级电容器健康状态测定的多物理场测量方法。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-19 DOI: 10.3390/mi16111295
Thomas Doucet, Jean-François Mogniotte, Raphaël Amiot, Alaa Hijazi, Pascal Venet, Minh-Quyen Le, Pierre-Jean Cottinet

This work presents a comparative study on the ageing of supercapacitors and a method for monitoring their state of health (SoH) through mechanical deformation. This study aims to evaluate the accelerated ageing behaviours of these systems under specific cycling conditions and temperatures, allowing the establishment of a correlation between SoH and casing deformation in supercapacitors. Experimental ageing tests revealed supercapacitors displayed an initial "burning" phase followed by a linear ageing trend. Strain gauges were employed to measure the mechanical deformation of supercapacitor casings, providing real-time insights into their SoH. Capacitance fading in supercapacitors was modelled using Brunauer-Emmett-Teller (BET) theory, hypothesizing that gas adsorption during ageing significantly contributes to performance decline. Model predictions were validated against experimental data, demonstrating a clear correlation between capacitance fading, internal resistance, remaining energy, and casing deformation. This work highlights the potential of mechanical deformation monitoring as a practical and non-invasive approach for assessing the SoH of supercapacitors.

这项工作提出了超级电容器老化的比较研究,并通过机械变形监测其健康状态(SoH)的方法。本研究旨在评估这些系统在特定循环条件和温度下的加速老化行为,从而建立超级电容器中SoH与套管变形之间的相关性。实验老化测试表明,超级电容器表现出最初的“燃烧”阶段,随后呈线性老化趋势。采用应变计测量超级电容器套管的机械变形,实时了解其SoH。利用brunauer - emmet - teller (BET)理论对超级电容器的电容衰减进行了建模,假设老化过程中的气体吸附是导致性能下降的重要原因。根据实验数据验证了模型预测,表明电容衰减、内阻、剩余能量和套管变形之间存在明显的相关性。这项工作强调了机械变形监测作为评估超级电容器SoH的实用和非侵入性方法的潜力。
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引用次数: 0
A Compact L-Band Reconfigurable Dual-Mode Patch Filter. 一种紧凑的l波段可重构双模贴片滤波器。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-19 DOI: 10.3390/mi16111294
Abdel Fattah Sheta, Majeed A S Alkanhal, Ibrahim Elshafiey

This research presents a novel dual-mode filter design that offers significant advantages in terms of frequency agility and miniaturization compared to conventional fixed multi-resonator filters. The design and implementation of a compact tunable bandpass filter are presented. The basic design structure is based on a slotted non-degenerate dual-mode microstrip square patch. The slots are etched symmetrically, which makes the slotted dual-mode square patch equivalent to a two-coupled-resonator filter. The asymmetrical feed lines enable the excitation of dual resonant modes. The patch length, slot size, and dielectric material properties primarily determine the filter's center frequency and bandwidth. Tunability is achieved by loading the slotted square patch with reversed bias varactor diodes located at the square patch corners, allowing electronic control of the filter center frequency. The design utilizes RT/Duroid 6010.2 laminates with a dielectric constant of 10.2 and a thickness of 0.635 mm. A bias tee at one of the filter ports is used to provide reverse bias to varactor diodes. Simulations and experimental results demonstrate tunable characteristics. Among the attractive features of the proposed design, good levels of insertion loss and impedance matching are noticed in the entire tunable band. The advantages of the proposed design make it well-suited for modern wireless technology applications in communication, radar, and satellite systems.

本研究提出了一种新的双模滤波器设计,与传统的固定多谐振器滤波器相比,它在频率敏捷性和小型化方面具有显着优势。介绍了一种紧凑型可调谐带通滤波器的设计与实现。基本设计结构是基于开槽非简并双模微带方形贴片。槽是对称蚀刻的,这使得有槽的双模方形贴片相当于一个双耦合谐振器滤波器。非对称馈线可以激发双谐振模式。贴片长度、缝隙大小和介电材料特性主要决定了滤波器的中心频率和带宽。可调性是通过在方形贴片的角上加载反向偏置变容二极管来实现的,允许电子控制滤波器的中心频率。本设计采用RT/Duroid 6010.2层压板,介电常数为10.2,厚度为0.635 mm。其中一个滤波器端口的偏置三通用于向变容二极管提供反向偏置。仿真和实验结果表明,该系统具有可调特性。在该设计的吸引人的特点中,在整个可调谐频带中注意到良好的插入损耗和阻抗匹配水平。所提出的设计的优点使其非常适合现代无线技术在通信、雷达和卫星系统中的应用。
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引用次数: 0
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Micromachines
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