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Micro-Mechanical Properties and Deformation Damage Behavior of the Matrix and Primary Carbides in 8Cr4Mo4V Bearing Steel. 8Cr4Mo4V轴承钢基体碳化物和原生碳化物微观力学性能及变形损伤行为
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-15 DOI: 10.3390/mi17010113
Chenhui Sun, Xubo Fan, Xiaoquan Shi, Junjun Liu, Zhihu Zhang, Bohan Zhang, Haitao Liu

8Cr4Mo4V bearing steel is a critical material for main shaft bearings in aero-engine applications. However, the current understanding of the micro-mechanical properties of its matrix and primary carbide phases (vanadium-rich and molybdenum-rich carbides) remains insufficient. This knowledge gap readily induces various forms of deformation damage during grinding, severely compromising the surface integrity of the workpiece. To address this, nanoindentation and nano-scratch techniques were employed to systematically quantify the micro-mechanical properties of each phase and investigate the deformation damage behavior of the steel under load. Results showed that MC carbides exhibited the highest elastic modulus and microhardness, which made them more susceptible to becoming crack initiation sites during grinding. Nano-scratch testing further revealed that crack initiation at carbide edges and localized spalling were the primary damage mechanisms. This study provides a micro-mechanical foundation for controlling the grinding surface quality of 8Cr4Mo4V bearing steel, holding significant implications for optimizing grinding processes, suppressing crack initiation, and elucidating the grinding damage mechanism.

8Cr4Mo4V轴承钢是航空发动机主轴轴承的关键材料。然而,目前对其基体和原生碳化物相(富钒和富钼碳化物)的微观力学性能的了解仍然不足。这种知识差距很容易在磨削过程中引起各种形式的变形损伤,严重损害工件的表面完整性。为了解决这一问题,采用纳米压痕和纳米划痕技术系统地量化了各相的微观力学性能,并研究了钢在载荷作用下的变形损伤行为。结果表明:MC碳化物具有最高的弹性模量和显微硬度,在磨削过程中更容易成为裂纹萌生部位;纳米划伤测试进一步表明,碳化物边缘裂纹萌生和局部剥落是主要的损伤机制。该研究为控制8Cr4Mo4V轴承钢磨削表面质量提供了微观力学基础,对优化磨削工艺、抑制裂纹萌生、阐明磨削损伤机理具有重要意义。
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引用次数: 0
Low Temperature Effect of Resistance Strain Gauge Based on Double-Layer Composite Film. 双层复合薄膜电阻应变片的低温效应。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-15 DOI: 10.3390/mi17010114
Mengqiu Li, Zhiyuan Hu, Fengming Ye, Jiaxiang Wang, Zhuoqing Yang

Strain gauges play a crucial role in numerous fields such as bridge and building structural health monitoring. However, traditional strain gauges generate spurious signals due to the temperature effect, which in turn affects their measurement accuracy. Herein, we propose a resistance strain gauge based on a double-layer composite film, which is characterized by an adjustable resistance temperature coefficient (TCR), an ultra-near-zero temperature effect, and good TCR repeatability. It is precisely through the combination of materials with positive and negative TCR, leveraging their opposing temperature resistance characteristics, that a low temperature effect has been achieved. Compared with the single-layer alloy-based strain gauge, the developed strain gauge based on double-layer composite film has greatly reduced sensitivity to temperature interference, and its TCR can be reduced to a ultra-near-zero value, approximately 0.8 ppm/°C, while the stability of TCR is excellent. In addition, the gauge factor of the strain gauge is 1.83, and it maintains excellent linearity. This work fully highlights the potential application value of the developed strain gauge in stress monitoring of bridges and building structures.

应变计在桥梁、建筑结构健康监测等众多领域发挥着至关重要的作用。然而,由于温度效应,传统的应变片会产生杂散信号,从而影响其测量精度。本文提出了一种基于双层复合薄膜的电阻应变片,其特点是电阻温度系数(TCR)可调、超近零温度效应、TCR重复性好。正是通过将具有正、负TCR的材料结合起来,利用其相反的耐温特性,实现了低温效果。与单层合金基应变片相比,所研制的双层复合薄膜应变片对温度干扰的敏感性大大降低,TCR可降至超近零值,约为0.8 ppm/°C,同时TCR的稳定性极佳。应变片的应变系数为1.83,保持了良好的线性度。本工作充分显示了所研制的应变仪在桥梁和建筑结构应力监测中的潜在应用价值。
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引用次数: 0
High-Resolution Snapshot Multispectral Imaging System for Hazardous Gas Classification and Dispersion Quantification. 用于有害气体分类和弥散量化的高分辨率快照多光谱成像系统。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-14 DOI: 10.3390/mi17010112
Zhi Li, Hanyuan Zhang, Qiang Li, Yuxin Song, Mengyuan Chen, Shijie Liu, Dongjing Li, Chunlai Li, Jianyu Wang, Renbiao Xie

Real-time monitoring of hazardous gas emissions in open environments remains a critical challenge. Conventional spectrometers and filter wheel systems acquire spectral and spatial information sequentially, which limits their ability to capture multiple gas species and dynamic dispersion patterns rapidly. A High-Resolution Snapshot Multispectral Imaging System (HRSMIS) is proposed to integrate high spatial fidelity with multispectral capability for near real-time plume visualization, gas species identification, and concentration retrieval. Operating across the 7-14 μm spectral range, the system employs a dual-path optical configuration in which a high-resolution imaging path and a multispectral snapshot path share a common telescope, allowing for the simultaneous acquisition of fine two-dimensional spatial morphology and comprehensive spectral fingerprint information. Within the multispectral path, two 5×5 microlens arrays (MLAs) combined with a corresponding narrowband filter array generate 25 distinct spectral channels, allowing concurrent detection of up to 25 gas species in a single snapshot. The high-resolution imaging path provides detailed spatial information, facilitating spatio-spectral super-resolution fusion for multispectral data without complex image registration. The HRSMIS demonstrates modulation transfer function (MTF) values of at least 0.40 in the high-resolution channel and 0.29 in the multispectral channel. Monte Carlo tolerance analysis confirms imaging stability, enabling the real-time visualization of gas plumes and the accurate quantification of dispersion dynamics and temporal concentration variations.

开放环境中有害气体排放的实时监测仍然是一项重大挑战。传统的光谱仪和滤光轮系统依次获取光谱和空间信息,这限制了它们快速捕获多种气体和动态色散模式的能力。提出了一种高分辨率快照多光谱成像系统(HRSMIS),该系统集成了高空间保真度和多光谱能力,可实现近实时羽流可视化、气体种类识别和浓度检索。该系统在7-14 μm光谱范围内工作,采用双路光学配置,高分辨率成像路径和多光谱快照路径共享一个望远镜,可以同时获取精细的二维空间形态和全面的光谱指纹信息。在多光谱路径中,两个5×5微透镜阵列(mla)与相应的窄带滤波器阵列相结合,产生25个不同的光谱通道,允许在单个快照中同时检测多达25种气体。高分辨率成像路径提供了详细的空间信息,便于多光谱数据的空间光谱超分辨率融合,无需复杂的图像配准。HRSMIS的调制传递函数(MTF)在高分辨率信道中至少为0.40,在多光谱信道中至少为0.29。蒙特卡罗容差分析证实了成像稳定性,实现了气体羽流的实时可视化,并精确量化了分散动力学和时间浓度变化。
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引用次数: 0
Hafnium-Based Ferroelectric Diodes for Logic-in-Memory Application. 用于逻辑存储器的铪基铁电二极管。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-14 DOI: 10.3390/mi17010108
Shuo Han, Yefan Zhang, Xi Wang, Peiwen Tong, Chuanzhi Liu, Qimiao Zeng, Jindong Liu, Xiao Huang, Qingjiang Li, Rongrong Cao, Wei Wang

Due to the Von Neumann bottleneck of traditional CMOS computing, there is an urgent need to develop in-memory logic devices with low power consumption. In this work, we demonstrate ferroelectric diode devices based on the TiN/Hf0.5Zr0.5O2/HfO2/TiN structure, implementing 16 Boolean logic operations through single-step or multi-step (2-3 steps) cascade and achieving attojoule-level one-bit full-adder computation. The TiN/Hf0.5Zr0.5O2/HfO2/TiN ferroelectric diode exhibits non-destructive readout and bidirectional rectification characteristics, with the conduction mechanism following Schottky emission behavior in the on-state. Based on its bidirectional rectification characteristics, we designed and simulated the circuit scheme of 16 Boolean logic and one-bit full-adder through cascaded operations. Both the input and output logic values are represented in the form of resistance, without the need for additional form conversion circuits. The state writing is performed by pulse-controlled polarization flipping, and the state reading is non-destructive. The logic circuits in this work demonstrate superior performance with ultralow computing power consumption in simulation. This breakthrough establishes a foundation for developing energy-efficient and scalable in-memory computing systems.

由于传统CMOS计算的Von Neumann瓶颈,迫切需要开发低功耗的内存逻辑器件。在这项工作中,我们展示了基于TiN/Hf0.5Zr0.5O2/HfO2/TiN结构的铁电二极管器件,通过单步或多步(2-3步)级联实现16个布尔逻辑运算,并实现了阿焦耳级的一位全加法器计算。TiN/Hf0.5Zr0.5O2/HfO2/TiN铁电二极管具有无损读出和双向整流特性,导通状态下具有遵循肖特基发射行为的导通机制。基于其双向整流特性,通过级联运算,设计并仿真了16布尔逻辑和1位全加法器的电路方案。输入和输出逻辑值都以电阻的形式表示,不需要额外的形式转换电路。状态写入由脉冲控制的极化翻转完成,状态读取是非破坏性的。仿真结果表明,所设计的逻辑电路具有优异的性能和超低的计算功耗。这一突破为开发节能和可扩展的内存计算系统奠定了基础。
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引用次数: 0
MCHB-DETR: An Efficient and Lightweight Inspection Framework for Ink Jet Printing Defects in Semiconductor Packaging. MCHB-DETR:半导体封装中喷墨印刷缺陷的高效轻量级检测框架。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-14 DOI: 10.3390/mi17010109
Yibin Chen, Jiayi He, Zhuohao Shi, Yisong Pan, Weicheng Ou

In semiconductor packaging and microelectronic manufacturing, inkjet printing technology is widely employed in critical processes such as conductive line fabrication and encapsulant dot deposition. However, dynamic printing defects, such as missing droplets and splashing can severely compromise circuit continuity and device reliability. Traditional inspection methods struggle to detect such subtle and low-contrast defects. To address this challenge, we propose MCHB-DETR, a novel lightweight defect detection framework based on RT-DETR, aimed at improving product yield in inkjet printing for semiconductor packaging. MCHB-DETR features a lightweight backbone with enhanced multi-level feature extraction capabilities and a hybrid encoder designed to improve cross-scale and multi-frequency feature fusion. Experimental results on our inkjet dataset show a 29.1% reduction in parameters and a 36.7% reduction in FLOPs, along with improvements of 3.1% in mAP@50 and 3.5% in mAP@50:95. These results demonstrate its superior detection performance while maintaining efficient inference, highlighting its strong potential for enhancing yield in semiconductor packaging.

在半导体封装和微电子制造中,喷墨印刷技术广泛应用于导电线制造和封装点沉积等关键工艺。然而,动态打印缺陷,如缺少液滴和飞溅会严重损害电路的连续性和器件的可靠性。传统的检测方法很难检测到这种细微和低对比度的缺陷。为了解决这一挑战,我们提出了MCHB-DETR,一种基于RT-DETR的新型轻量级缺陷检测框架,旨在提高半导体封装喷墨打印的产品良率。MCHB-DETR具有轻量级骨干,具有增强的多级特征提取能力和混合编码器,旨在改善跨尺度和多频率特征融合。在我们的喷墨数据集上的实验结果显示,参数减少了29.1%,FLOPs减少了36.7%,mAP@50和mAP@50:95分别提高了3.1%和3.5%。这些结果证明了其优越的检测性能,同时保持了高效的推理,突出了其在提高半导体封装产量方面的强大潜力。
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引用次数: 0
A Multi-Beam Phased Array Receiver Front-End with High Performance Ceramic SiP. 采用高性能陶瓷SiP的多波束相控阵接收机前端。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-14 DOI: 10.3390/mi17010110
Haifu Zhang, Li-Xin Guo, Shubo Dun, Xiaoming Li, Xiaolong Xu

This paper presents a compact four-beam dual-polarized phased array with the high performance front-end module based on system-in-package (SiP) technology. By employing high-temperature co-fired ceramic (HTCC) substrates, the proposed design achieves efficient thermal management and high level of integration within a tile-type architecture. The front-end module based on SiP can simultaneously generate four independent beams with switchable left- and right-hand circular polarizations, providing flexible beam control. To verify the proposed method, a Ku-band 256-element phased array receiver with four beams has been designed and experimentally verified using HTCC and SiP process. Operating in 14-14.5 GHz, the proposed low-profile array demonstrates stable radiation characteristics, beam pointing accuracy and excellent beam consistency across the entire frequency range. The measurement results confirm that the SiP-based phased array maintains efficient thermal management, high polarization purity and robust beam-scanning capability, validating its suitability for mobile satellite communication.

提出了一种基于系统级封装(SiP)技术的紧凑四波束双极化相控阵,该相控阵具有高性能前端模块。通过采用高温共烧陶瓷(HTCC)衬底,所提出的设计在瓷砖类型的架构中实现了高效的热管理和高水平的集成。基于SiP的前端模块可以同时产生四个独立的波束,具有可切换的左右圆偏振,提供灵活的波束控制。为了验证所提出的方法,设计了ku波段256元四波束相控阵接收机,并采用HTCC和SiP工艺进行了实验验证。该阵列工作在14-14.5 GHz频段,在整个频率范围内具有稳定的辐射特性、波束指向精度和优异的波束一致性。测量结果证实,基于sip的相控阵保持了高效的热管理、高极化纯度和强大的波束扫描能力,验证了其适用于移动卫星通信。
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引用次数: 0
Device and Circuit Co-Optimization of Split-Controlled Flip-Flops Against Aging Towards Low-Voltage Applications. 面向低电压应用的抗老化分裂控制触发器的器件和电路协同优化。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-14 DOI: 10.3390/mi17010111
Yuexin Zhao, Jingjing Tan, Lin Chen, Hao Zhu, Qingqing Sun

The continued downscaling of transistors has exacerbated aging mechanisms such as bias temperature instability (BTI) and hot-carrier injection (HCI), posing significant reliability challenges for nanoscale integrated circuits. These effects are particularly critical to flip-flops operating at low supply voltages, which are essential for ultra-low-power applications including the Internet of Things (IoT) and biomedical implants. In this work, we address the aging issue in low-voltage Split-Controlled Flip-Flops (SCFFs) by proposing a novel transistor-level mitigation technique specifically tailored to this architecture within a domestic 14 nm process library. Through a detailed analysis of aging-critical transistors, three targeted enhancement strategies are introduced. Simulation results demonstrate that the improved SCFF achieves more than a 60% reduction in PMOS threshold voltage degradation and a 40% reduction in timing delay, while maintaining robust operation at a supply voltage as low as 0.4 V. These results highlight the effectiveness of the proposed approach in mitigating aging effects and enhancing reliability under low-voltage operation.

晶体管的持续缩小加剧了偏置温度不稳定性(BTI)和热载流子注入(HCI)等老化机制,对纳米级集成电路的可靠性提出了重大挑战。这些影响对于在低电源电压下工作的触发器尤其重要,这对于包括物联网(IoT)和生物医学植入物在内的超低功耗应用至关重要。在这项工作中,我们提出了一种新颖的晶体管级缓解技术,专门针对国内14nm工艺库中的这种架构,解决了低压分岔控制触发器(SCFFs)的老化问题。通过对老化临界晶体管的详细分析,介绍了三种有针对性的增强策略。仿真结果表明,改进后的SCFF在电源电压低至0.4 V时仍能保持鲁棒工作,使PMOS阈值电压退化降低60%以上,时间延迟降低40%以上。这些结果突出了该方法在缓解老化效应和提高低压运行可靠性方面的有效性。
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引用次数: 0
Highly Sensitive Detection of Chymotrypsin Using Gold Nanoclusters with Peptide Sensors. 利用金纳米簇与肽传感器高灵敏度检测凝乳胰蛋白酶。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-14 DOI: 10.3390/mi17010107
Siyuan Zhou, Cheng Liu, Haixia Shi, Li Gao

Pancreatic function tests are used to determine the presence of chronic pancreatitis, particularly in the early stage of the disease. Chymotrypsin is an indicator of pancreatic function and is thus related to pancreatic diseases. However, these methods often require specific equipment and cannot always meet on-site analysis requirements. Consequently, a highly sensitive detection method needs to be developed. This research employed graphene oxide modified with NHS sensors and peptides (RRHFFGC: Arginine-Arginine-Histidine-Phenylalanine-Phenylalanine-Glycine-Cysteine) tagged with gold nanoclusters (Au NCs) for the detection of chymotrypsin. The N-Hydroxysuccinimide-(Polyethylene Glycol)4-Dibenzocyclooctyne (NHS-PEG4-DBCO) and graphene oxide (GO)-N3 click reaction yielded GO-NHS material, appropriate for fluorescence quenching. The peptide chain was accurately broken with the introduction of chymotrypsin, and the Au NCs were situated far from the GO-NHS surface. The detection limit was 2.014 pg/mL. The results showed that the detection method had high sensitivity in comparison with the previous studies. This method is relevant to real samples due to its potential efficacy. Therefore, it is a promising method in the biomedical field.

胰腺功能检查用于确定慢性胰腺炎的存在,特别是在疾病的早期阶段。胰凝乳蛋白酶是胰腺功能的指标,因此与胰腺疾病有关。然而,这些方法往往需要特定的设备,并不能总是满足现场分析的要求。因此,需要开发一种高灵敏度的检测方法。本研究采用氧化石墨烯修饰的NHS传感器和标记有金纳米团簇(Au NCs)的肽(RRHFFGC:精氨酸-精氨酸-组氨酸-苯丙氨酸-苯丙氨酸-甘氨酸-半胱氨酸)来检测凝乳胰蛋白酶。n -羟基丁二酰亚胺-(聚乙二醇)4-二苯并环辛基(NHS-PEG4-DBCO)与氧化石墨烯(GO)- n3点击反应生成了适合荧光猝灭的GO- nhs材料。通过引入凝乳胰蛋白酶,肽链被精确地断裂,Au nc位于远离GO-NHS表面的位置。检出限为2.014 pg/mL。结果表明,与以往的研究相比,该检测方法具有较高的灵敏度。由于其潜在的有效性,该方法与实际样品相关。因此,它在生物医学领域是一种很有前途的方法。
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引用次数: 0
A Substrate-Integrated Waveguide Filtering Power Divider with Broadside-Coupled Inner-Meander-Slot Complementary Split-Ring Resonator. 一种带宽边耦合内弯曲槽互补分环谐振器的基板集成波导滤波功率分压器。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-13 DOI: 10.3390/mi17010103
Jinjia Hu, Chen Wang, Yongmao Huang, Shuai Ding, Maurizio Bozzi

In this work, a substrate-integrated waveguide (SIW) filtering power divider with a modified complementary split-ring resonator (CSRR) is reported. Firstly, by integrating the meander-shaped slots with the conventional CSRR, the proposed inner-meander-slot CSRR (IMSCSRR) can enlarge the total length of the defected slot and increase the width of the split, thus enhancing the equivalent capacitance and inductance. In this way, the fundamental resonant frequency of the IMSCSRR can be effectively decreased without enlarging the circuit size, which can generally help to reduce the physical size by over 35%. Subsequently, to further reduce the circuit size, two IMSCSRRs are separately loaded on the top and bottom metal covers to constitute a broadside-coupled IMSCSRR, which is combined with the SIW. To verify the efficacy of the proposed SIW-IMSCSRR unit cell, a two-way filtering power divider is implemented. It combines the band-selection function of a filter and the power-distribution property of a power divider, thereby enhancing system integration and realizing size compactness. Experimental results show that the proposed filtering power divider achieves a center frequency of 3.53 GHz, a bandwidth of about 320 MHz, an in-band insertion loss of (3 + 1.3) dB, an in-band isolation of over 21 dB, and a size reduction of about 30% compared with the design without broadside-coupling, as well as good magnitude and phase variations. All the results indicate that the proposed filtering power divider achieves a good balance between low loss, high isolation, and compact size, which is suitable for system integration applications in microwave scenarios.

在这项工作中,报道了一种基片集成波导(SIW)滤波功率分压器与改进的互补裂环谐振器(CSRR)。首先,本文提出的内弯曲槽型CSRR (IMSCSRR)通过将弯曲槽型与传统的弯曲槽型CSRR集成,可以增大缺陷槽的总长度,增加缝隙的宽度,从而提高等效电容和电感;这样,在不增加电路尺寸的情况下,可以有效地降低IMSCSRR的基频,一般可以使物理尺寸减小35%以上。随后,为了进一步减小电路尺寸,将两个IMSCSRR分别加载在顶部和底部金属盖上,构成一个宽侧耦合的IMSCSRR,并与SIW结合。为了验证所提出的SIW-IMSCSRR单元的有效性,实现了一个双向滤波功率分压器。它结合了滤波器的选带功能和功率分配器的功率分配特性,从而提高了系统的集成度,实现了尺寸的紧凑。实验结果表明,该滤波功率分配器的中心频率为3.53 GHz,带宽约为320 MHz,带内插入损耗为(3 + 1.3)dB,带内隔离大于21 dB,尺寸比无宽带耦合时减小约30%,且具有良好的幅值和相位变化。结果表明,所提出的滤波功率分配器在低损耗、高隔离和紧凑的尺寸之间取得了很好的平衡,适合于微波场景下的系统集成应用。
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引用次数: 0
Emerging Electrode Materials for Next-Generation Electrochemical Devices: A Comprehensive Review. 新一代电化学器件电极材料综述
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-13 DOI: 10.3390/mi17010106
Thirukumaran Periyasamy, Shakila Parveen Asrafali, Jaewoong Lee

The field of electrochemical devices, encompassing energy storage, fuel cells, electrolysis, and sensing, is fundamentally reliant on the electrode materials that govern their performance, efficiency, and sustainability. Traditional materials, while foundational, often face limitations such as restricted reaction kinetics, structural deterioration, and dependence on costly or scarce elements, driving the need for continuous innovation. Emerging electrode materials are designed to overcome these challenges by delivering enhanced reaction activity, superior mechanical robustness, accelerated ion diffusion kinetics, and improved economic feasibility. In energy storage, for example, the shift from conventional graphite in lithium-ion batteries has led to the exploration of silicon-based anodes, offering a theoretical capacity more than tenfold higher despite the challenge of massive volume expansion, which is being mitigated through nanostructuring and carbon composites. Simultaneously, the rise of sodium-ion batteries, appealing due to sodium's abundance, necessitates materials like hard carbon for the anode, as sodium's larger ionic radius prevents efficient intercalation into graphite. In electrocatalysis, the high cost of platinum in fuel cells is being addressed by developing Platinum-Group-Metal-free (PGM-free) catalysts like metal-nitrogen-carbon (M-N-C) materials for the oxygen reduction reaction (ORR). Similarly, for the oxygen evolution reaction (OER) in water electrolysis, cost-effective alternatives such as nickel-iron hydroxides are replacing iridium and ruthenium oxides in alkaline environments. Furthermore, advancements in materials architecture, such as MXenes-two-dimensional transition metal carbides with metallic conductivity and high volumetric capacitance-and Single-Atom Catalysts (SACs)-which maximize metal utilization-are paving the way for significantly improved supercapacitor and catalytic performance. While significant progress has been made, challenges related to fundamental understanding, long-term stability, and the scalability of lab-based synthesis methods remain paramount for widespread commercial deployment. The future trajectory involves rational design leveraging advanced characterization, computational modeling, and machine learning to achieve holistic, system-level optimization for sustainable, next-generation electrochemical devices.

电化学器件领域,包括能量存储、燃料电池、电解和传感,从根本上依赖于控制其性能、效率和可持续性的电极材料。传统材料虽然是基础材料,但往往面临诸如反应动力学受限、结构恶化以及对昂贵或稀缺元素的依赖等限制,这推动了对持续创新的需求。新兴电极材料旨在通过提供增强的反应活性、卓越的机械稳健性、加速的离子扩散动力学和提高的经济可行性来克服这些挑战。例如,在储能方面,锂离子电池从传统石墨电池的转变导致了对硅基阳极的探索,尽管面临大规模体积膨胀的挑战,但理论容量仍高出十倍以上,这一挑战正在通过纳米结构和碳复合材料得到缓解。同时,钠离子电池的兴起,由于钠的丰富而吸引人,需要硬碳等材料作为阳极,因为钠的较大离子半径阻碍了有效嵌入石墨。在电催化领域,无铂族金属(PGM-free)催化剂(如用于氧还原反应(ORR)的金属-氮-碳(M-N-C)材料)的开发正在解决燃料电池中铂的高成本问题。同样,对于水电解中的析氧反应(OER),具有成本效益的替代品,如镍铁氢氧化物,正在取代碱性环境中的铱和钌氧化物。此外,材料结构的进步,如mxenes(具有金属导电性和高容量的二维过渡金属碳化物)和单原子催化剂(SACs)(可以最大限度地利用金属),正在为显著改善超级电容器和催化性能铺平道路。虽然已经取得了重大进展,但与基础理解、长期稳定性和实验室合成方法的可扩展性相关的挑战仍然是广泛商业部署的首要问题。未来的发展轨迹包括利用先进的表征、计算建模和机器学习进行合理设计,以实现可持续的下一代电化学设备的整体、系统级优化。
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引用次数: 0
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Micromachines
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