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The Clausius-Mossotti Factor in Dielectrophoresis: A Critical Appraisal of Its Proposed Role as an 'Electrophysiology Rosetta Stone'. 介电电泳中的克劳修斯-莫索蒂因子:对其作为“电生理学罗塞塔石碑”提出的作用的批判性评价。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-11 DOI: 10.3390/mi17010096
Ronald Pethig

The Clausius-Mossotti (CM) factor underpins the theoretical description of dielectrophoresis (DEP) and is widely used in micro- and nano-scale systems for frequency-dependent particle and cell manipulation. It has further been proposed as an "electrophysiology Rosetta Stone" capable of linking DEP spectra to intrinsic cellular electrical properties. In this paper, the mathematical foundations and interpretive limits of this proposal are critically examined. By analyzing contrast factors derived from Laplace's equation across multiple physical domains, it is shown that the CM functional form is a universal consequence of geometry, material contrast, and boundary conditions in linear Laplacian fields, rather than a feature unique to biological systems. Key modelling assumptions relevant to DEP are reassessed. Deviations from spherical symmetry lead naturally to tensorial contrast factors through geometry-dependent depolarisation coefficients. Complex, frequency-dependent CM factors and associated relaxation times are shown to inevitably arise from the coexistence of dissipative and storage mechanisms under time-varying forcing, independent of particle composition. Membrane surface charge influences DEP response through modified interfacial boundary conditions and effective transport parameters, rather than by introducing an independent driving mechanism. These results indicate that DEP spectra primarily reflect boundary-controlled field-particle coupling. From an inverse-problem perspective, this places fundamental constraints on parameter identifiability in DEP-based characterization. The CM factor remains a powerful and general modelling tool for micromachines and microfluidic systems, but its interpretive scope must be understood within the limits imposed by Laplacian field theory.

克劳修斯-莫索蒂(CM)因子支撑了电介质电泳(DEP)的理论描述,并广泛应用于微纳米级系统中,用于频率依赖的粒子和细胞操作。它还被进一步提出作为一个“电生理学罗塞塔石”,能够将DEP光谱与内在的细胞电学特性联系起来。在本文中,这一建议的数学基础和解释的限制是严格审查。通过分析从拉普拉斯方程推导出的跨多个物理域的对比因子,表明CM函数形式是线性拉普拉斯场中几何、材料对比和边界条件的普遍结果,而不是生物系统独有的特征。重新评估与DEP相关的关键建模假设。偏离球对称自然导致张量对比因子通过几何依赖的去极化系数。复杂的、频率相关的CM因子和相关的弛豫时间不可避免地产生于时变强迫下的耗散和存储机制共存,与粒子组成无关。膜表面电荷通过改变界面边界条件和有效输运参数来影响DEP响应,而不是通过引入独立的驱动机制。这些结果表明,DEP谱主要反映了边界控制的场-粒子耦合。从反问题的角度来看,这对基于dep的表征中的参数可识别性提出了基本约束。CM因子仍然是微机械和微流体系统的一个强大而通用的建模工具,但其解释范围必须在拉普拉斯场论的限制下理解。
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引用次数: 0
Smooth Critical Dimension Compensation Across Photomask Transmittance Discontinuities Enabled by Selective and Direct Laser Patterning Inside Mask. 通过掩膜内的选择性和直接激光图像化实现光掩膜透光率不连续性的光滑临界尺寸补偿。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-11 DOI: 10.3390/mi17010095
Dabin Park, Geumsu Yeom, Sungho Jeong, Junsu Park

A selective laser patterning technique applied inside photomasks as a practical method to mitigate critical-dimension non-uniformity caused by overexposure in large-area lithography systems with segmented illumination was investigated. The geometric characteristics of laser-induced voids were analyzed depending on various laser patterning conditions, and the resulting critical-dimension behavior was evaluated across regions with various transmittance levels, including sharply discontinuous transmittance boundaries. The results show that the void size and morphology can be tuned by adjusting the laser pulse energy, although excessive pulse energy leads to mask fracture, from which we derived appropriate processing windows. Furthermore, photomask transmittance was controllable over a wide range (20-92%) by varying laser parameters, void density, pattern arrangement, and the number of patterned layers. This enabled critical-dimension compensation with nanometer- to tens-of-nanometer-level precision. To examine critical-dimension behavior under abrupt transmittance transitions analogous to overexposure zones, 80% and 50% transmittance regions were placed adjacently. Despite the 30% transmittance difference, critical-dimension variation remained smooth, confirming that sharp transmittance changes do not induce abrupt critical-dimension shifts. Overall, our findings experimentally demonstrate that selective and direct laser patterning inside photomasks is a practical and effective critical-dimension compensation approach for large-area lithography employing segmented illumination systems.

研究了一种应用于掩模内部的选择性激光图纹技术,作为一种实用的方法来缓解大面积分段照明光刻系统中过度曝光引起的临界尺寸不均匀性。分析了不同激光成像条件下激光诱导空洞的几何特征,并对不同透光率区域(包括明显不连续的透光率边界)的临界维行为进行了评估。结果表明,通过调节激光脉冲能量可以调节空洞的大小和形态,但脉冲能量过大会导致掩膜断裂,并由此推导出合适的处理窗口。此外,光掩膜透过率可通过改变激光参数、空洞密度、图案排列和图案层数在较宽的范围内(20-92%)进行控制。这使得关键尺寸补偿具有纳米到几十纳米级的精度。为了研究类似于过度曝光区的透射率突变下的临界维行为,80%和50%的透射率区域相邻放置。尽管透光率相差30%,但临界维数的变化保持平稳,这证实了急剧的透光率变化不会引起临界维数的突然变化。总的来说,我们的研究结果实验表明,选择性和直接激光图案在掩模内是一种实用和有效的关键尺寸补偿方法,用于采用分段照明系统的大面积光刻。
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引用次数: 0
A High-PSRR LDO with Low Noise and Ultra-Low Power Consumption. 一种低噪声、超低功耗的高psrr LDO。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-10 DOI: 10.3390/mi17010091
Nanxiang Guo, Jiagen Cheng, Chenxi Yue, Changtao Chen, Chaoran Liu, Linxi Dong

High-performance low dropout regulator (LDO) chips are core components that provide clean power for high-precision sensors, radio frequency (RF) circuits, low noise amplifiers and other noise-sensitive circuits. In the reported literature, the designed LDO chip has advantages in certain parameters, but it cannot meet all the requirements of a high power supply rejection ratio (PSRR), low output noise and low standby current at the same time, which makes the high-end applications of LDOs greatly limited. In this paper, an LDO chip with high PSRR, low output noise and low standby current has been designed and fabricated. By increasing the loop gain, introducing an improved feedforward path, and adopting isolated power supply, the PSRR of the LDO at different frequency bands is greatly improved. By optimizing the design of the error amplifier (EA) and adding a low-pass filter to filter out the reference noise, the output voltage noise of the LDO is reduced. Within the depletion process and an optimized reference structure, the standby power consumption of the LDO is reduced without damaging the output voltage accuracy. The chip is taped out with SMIC's 0.18 μm/5 V/BCD process. The measured PSRR of the chip is as high as 95dB at a frequency of 1 kHz, and the high-frequency (1 MHz) PSRR is above 45 dB. The amplitude of integrated output noise is below 5.4 μVrms within the frequency range of 10 Hz to 100 KHz. When the load current is zero, the measured standby current is less than 400 nA. The test results indicate that the chip has excellent performance in terms of PSRR, output noise and standby power consumption.

高性能低差稳压器(LDO)芯片是为高精度传感器、射频(RF)电路、低噪声放大器和其他噪声敏感电路提供清洁电源的核心组件。在文献报道中,所设计的LDO芯片在某些参数上具有优势,但无法同时满足高电源抑制比(PSRR)、低输出噪声和低待机电流的所有要求,这极大地限制了LDO的高端应用。本文设计并制作了一种具有高PSRR、低输出噪声和低待机电流的LDO芯片。通过增加环路增益,引入改进的前馈路径,采用隔离电源,大大提高了LDO在不同频段的PSRR。通过优化误差放大器(EA)的设计,并加入低通滤波器滤除参考噪声,降低了LDO的输出电压噪声。在耗尽过程和优化的参考结构中,在不损害输出电压精度的情况下降低了LDO的待机功耗。该芯片采用中芯国际0.18 μm/5 V/BCD工艺封装。该芯片在1khz频率下的实测PSRR高达95dB,其中高频(1mhz) PSRR在45db以上。在10hz ~ 100khz的频率范围内,综合输出噪声的幅值小于5.4 μVrms。当负载电流为零时,测量到的备用电流小于400na。测试结果表明,该芯片在PSRR、输出噪声和待机功耗方面具有优异的性能。
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引用次数: 0
Thermal Management with AlN Passivation in AlGaN/GaN HEMTs with an Air Gap Gate for Improved RF Performance: A Simulation Study. 气隙栅极AlGaN/GaN hemt中AlN钝化的热管理以提高射频性能:模拟研究。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-10 DOI: 10.3390/mi17010092
Young-Hyun Won, Tae-Sung Kim, Jae-Hun Lee, Chae-Yun Lim, Byoung-Gue Min, Dong-Min Kang, Hyun-Seok Kim

This study introduces an air gap gate with AlN passivation to enhance the radio frequency (RF) performance of AlGaN/GaN high-electron-mobility transistors (HEMTs) while addressing thermal challenges. The air gap gate improves RF performance by reducing gate capacitance, resulting in a 23.9% increase in cutoff frequency (35.82 GHz) and enhancing saturation drain current and maximum transconductance by 3.7% and 10.27%, respectively, compared to a 0.15 μm planar gate baseline. However, reduced heat dissipation degrades thermal performance, as reflected in higher thermal resistance and temperature gradients. Incorporating high thermal conductivity AlN passivation mitigates these drawbacks, lowering operating temperatures and improving heat distribution, while maintaining a 17.5% cutoff frequency improvement over the baseline. These results demonstrate that the air gap gate with AlN passivation provides an effective strategy for achieving reliable, high-performance AlGaN/GaN HEMTs under high-frequency and high-power operations.

本研究引入了一种AlN钝化气隙栅极,以提高AlGaN/GaN高电子迁移率晶体管(hemt)的射频(RF)性能,同时解决了热挑战。与0.15 μm平面栅极基准相比,气隙栅极通过减小栅极电容提高射频性能,使截止频率(35.82 GHz)提高23.9%,饱和漏极电流和最大跨导分别提高3.7%和10.27%。然而,减少的散热会降低热性能,这反映在更高的热阻和温度梯度上。采用高导热AlN钝化技术可以减轻这些缺点,降低工作温度,改善热量分布,同时保持17.5%的截止频率比基线提高。这些结果表明,AlN钝化气隙栅极为在高频和高功率操作下实现可靠、高性能的AlGaN/GaN hemt提供了一种有效的策略。
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引用次数: 0
Cationic and Non-Ionic Surfactant-Assisted Morphological Engineering of CoMoO4 for High-Performance Asymmetric Supercapacitors. 高性能非对称超级电容器CoMoO4的阳离子和非离子表面活性剂辅助形态工程。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-09 DOI: 10.3390/mi17010089
Pritam J Morankar, Aviraj M Teli, Chan-Wook Jeon

Precise morphology engineering is essential for enhancing the charge-storage capabilities of cobalt molybdate (CoMoO4). In this study, cobalt molybdate (CoMoO4, abbreviated as CoMo), cobalt molybdate-cetyltrimethylammonium bromide (CoMo-CTAB), and cobalt molybdate-cetyltrimethylammonium bromide/polyethylene glycol (CoMo-CTAB/PEG) electrodes were synthesized through a cationic-nonionic surfactant-assisted hydrothermal route. he introduction of CTAB promoted the formation of well-defined nanoflake structures, whereas the synergistic CTAB/PEG system produced a highly porous and interconnected nanosheet architecture, enabling enhanced electrolyte diffusion and redox accessibility. As a result, the CoMo-CTAB/PEG electrode delivered a high areal capacitance of 10.321 F cm-2 at 10 mA cm-2, markedly outperforming CoMo-CTAB and pristine CoMo electrodes. It also exhibited good rate capability, maintaining 63.64% of its capacitance at 50 mA cm-2. Long-term cycling tests revealed excellent durability, with over 83% capacitance retention after 12,000 cycles and high coulombic efficiency, indicating highly reversible Faradaic behavior. Moreover, an asymmetric pouch-type supercapacitor device (APSD) assembled using the optimized electrode demonstrated robust cycling stability. These findings underscore surfactant-directed morphology modulation as an effective and scalable strategy for developing high-performance CoMoO4-based supercapacitor electrodes.

精确的形貌工程对于提高钼酸钴(CoMoO4)的电荷存储能力至关重要。本研究采用阳离子-非离子表面活性剂辅助水热法制备了钼酸钴(CoMoO4,简称CoMo)、钼酸钴-十六烷基三甲基溴化铵(CoMo- ctab)和钼酸钴-十六烷基三甲基溴化铵/聚乙二醇(CoMo- ctab /PEG)电极。CTAB的引入促进了明确的纳米片结构的形成,而协同CTAB/PEG体系产生了高度多孔和互连的纳米片结构,从而增强了电解质扩散和氧化还原的可及性。因此,CoMo- ctab /PEG电极在10 mA cm-2时提供了10.321 F cm-2的高面电容,明显优于CoMo- ctab和原始CoMo电极。在50 mA cm-2下,其电容保持率为63.64%。长期循环测试显示出优异的耐久性,在12,000次循环后电容保持率超过83%,库仑效率高,表明高度可逆的法拉第行为。此外,使用优化电极组装的非对称袋型超级电容器器件(APSD)表现出强大的循环稳定性。这些发现强调了表面活性剂定向形态调制是开发高性能comoo4基超级电容器电极的有效且可扩展的策略。
{"title":"Cationic and Non-Ionic Surfactant-Assisted Morphological Engineering of CoMoO<sub>4</sub> for High-Performance Asymmetric Supercapacitors.","authors":"Pritam J Morankar, Aviraj M Teli, Chan-Wook Jeon","doi":"10.3390/mi17010089","DOIUrl":"10.3390/mi17010089","url":null,"abstract":"<p><p>Precise morphology engineering is essential for enhancing the charge-storage capabilities of cobalt molybdate (CoMoO<sub>4</sub>). In this study, cobalt molybdate (CoMoO<sub>4</sub>, abbreviated as CoMo), cobalt molybdate-cetyltrimethylammonium bromide (CoMo-CTAB), and cobalt molybdate-cetyltrimethylammonium bromide/polyethylene glycol (CoMo-CTAB/PEG) electrodes were synthesized through a cationic-nonionic surfactant-assisted hydrothermal route. he introduction of CTAB promoted the formation of well-defined nanoflake structures, whereas the synergistic CTAB/PEG system produced a highly porous and interconnected nanosheet architecture, enabling enhanced electrolyte diffusion and redox accessibility. As a result, the CoMo-CTAB/PEG electrode delivered a high areal capacitance of 10.321 F cm<sup>-2</sup> at 10 mA cm<sup>-2</sup>, markedly outperforming CoMo-CTAB and pristine CoMo electrodes. It also exhibited good rate capability, maintaining 63.64% of its capacitance at 50 mA cm<sup>-2</sup>. Long-term cycling tests revealed excellent durability, with over 83% capacitance retention after 12,000 cycles and high coulombic efficiency, indicating highly reversible Faradaic behavior. Moreover, an asymmetric pouch-type supercapacitor device (APSD) assembled using the optimized electrode demonstrated robust cycling stability. These findings underscore surfactant-directed morphology modulation as an effective and scalable strategy for developing high-performance CoMoO<sub>4</sub>-based supercapacitor electrodes.</p>","PeriodicalId":18508,"journal":{"name":"Micromachines","volume":"17 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2026-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12843681/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146064780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cross Comparison Between Thermal Cycling and High Temperature Stress on I/O Connection Elements. I/O连接元件热循环与高温应力的交叉比较
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-09 DOI: 10.3390/mi17010088
Mamta Dhyani, Tsuriel Avraham, Joseph B Bernstein, Emmanuel Bender

This work examines resistance drift in FPGA I/O paths subjected to combined electrical and thermal stress, using a Xilinx Spartan-6 device as a representative platform. A multiplexed measurement approach was employed, in which multiple I/O pins were externally shorted and sequentially activated, enabling precise tracking of voltage, current, and effective series resistance over time, under controlled bias conditions. Two accelerated stress modes were investigated: high-temperature dwell in the range of 80-120 °C and thermal cycling between 80 and 140 °C. Both stress modes exhibited similar sub-linear (power-law) time dependence on resistance change, indicating cumulative degradation behavior. However, Arrhenius analysis revealed a strong contrast in effective activation energy: approximately 0.62 eV for high-temperature dwell and approximately 1.3 eV for thermal cycling. This divergence indicates that distinct physical mechanisms dominate under each stress regime. The lower activation energy is consistent with electrically and thermally driven on-die degradation within the FPGA I/O macro, including bias-related aging of output drivers and pad-level structures. In contrast, the higher activation energy observed under thermal cycling is characteristic of diffusion- and creep-dominated thermo-mechanical damage in package-level interconnects, such as solder joints. These findings demonstrate that resistance-based monitoring of FPGA I/O paths can discriminate between device-dominated and package-dominated aging mechanisms, providing a practical foundation for reliability assessment and self-monitoring methodologies in complex electronic systems.

本研究使用Xilinx Spartan-6器件作为代表性平台,研究了FPGA I/O路径在综合电和热应力下的电阻漂移。采用多路复用测量方法,其中多个I/O引脚外部短路并顺序激活,在可控偏置条件下精确跟踪电压、电流和有效串联电阻。研究了两种加速应力模式:80 ~ 120℃的高温停留模式和80 ~ 140℃的热循环模式。两种应力模式对阻力变化都表现出相似的次线性(幂律)时间依赖性,表明了累积退化行为。然而,Arrhenius分析揭示了有效活化能的强烈对比:高温停留时约为0.62 eV,热循环时约为1.3 eV。这种差异表明,在每种应力状态下,不同的物理机制占主导地位。较低的活化能与FPGA I/O宏中电和热驱动的片上退化一致,包括输出驱动器和盘级结构的偏置相关老化。相比之下,在热循环下观察到的较高活化能是封装级互连(如焊点)中以扩散和蠕变为主的热机械损伤的特征。这些发现表明,基于电阻的FPGA I/O路径监测可以区分器件主导和封装主导的老化机制,为复杂电子系统的可靠性评估和自我监测方法提供了实践基础。
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引用次数: 0
Dual-Electrodes PMUTs on Glasses for Wearable Human Blink Monitoring. 可穿戴式人眼眨眼监测眼镜上的双电极PMUTs。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-09 DOI: 10.3390/mi17010090
Xiao-Xin Liang, Haochen Wu, Yong Wang

Blink monitoring has demonstrated significant application value in fields such as safety assessments, medical monitoring, and intelligent technologies. Traditional eye monitoring methods are limited by restricted adaptability, insufficient comfort, or potential risks. MEMS-based ultrasonic technology, as a non-contact approach, has garnered attention due to its strong environmental adaptability, privacy, and security. However, existing designs require high-sensitivity processing circuits and are incompatible with standard fabrication processes. This work proposes a dual-electrode piezoelectric micro-mechanical ultrasonic transducer (PMUT) design based on aluminum nitride (AlN) piezoelectric thin films, integrated into a glasses device to enable real-time blink activity monitoring. The design successfully identifies blink states through time-of-flight (TOF) pulse-echo technology and dynamic unsupervised learning methods. Fabricated using cost-effective standard multi-user MEMS processes, this device offers distinct merits in terms of wearability comfort, information security, biosafety, and reliability.

瞬态监测在安全评估、医疗监测和智能技术等领域显示出重要的应用价值。传统的眼监测方法存在适应性受限、舒适度不足或存在潜在风险等问题。基于mems的超声技术作为一种非接触式技术,因其具有较强的环境适应性、隐私性和安全性而备受关注。然而,现有的设计需要高灵敏度的处理电路,并且与标准制造工艺不兼容。本研究提出了一种基于氮化铝(AlN)压电薄膜的双电极压电微机械超声换能器(PMUT)设计,将其集成到眼镜器件中,以实现实时眨眼活动监测。该设计通过飞行时间(TOF)脉冲回波技术和动态无监督学习方法成功识别眨眼状态。该器件采用具有成本效益的标准多用户MEMS工艺制造,在可穿戴性、舒适性、信息安全性、生物安全性和可靠性方面具有独特的优点。
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引用次数: 0
Design, Simulation and High Precision Tracking Control of a Piezoelectric Optical Stabilization Platform. 压电光学稳定平台的设计、仿真及高精度跟踪控制。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-08 DOI: 10.3390/mi17010087
Yonggang Yan, Can Cui, Jianjun Cui, Fuming Zhang, Kai Chen, Junjie Huang, Hang Xie, Dengpan Zhang

Optical image stabilization (OIS) is crucial for improving airborne opto-electronic imaging performance under dynamic conditions. This study presents a two-dimensional piezoelectric-driven OIS platform capable of compensating linear image shift errors. A motion platform integrating a bridge amplification mechanism and right-angle guiding beams was developed, and its theoretical model was validated through finite element analysis (FEA). To enhance the platform's repeatability, the hysteresis of the piezoelectric actuator was described using the Bouc-Wen model, and was optimized using a Hybrid Genetic Algorithm and Particle Swarm Optimization (HGAPSO). Experimental results demonstrated that the platform achieves a workspace of 53.92 μm × 53.76 μm, a motion resolution of 30 nm, a maximum coupling error of 2.28%, and a first-order resonant frequency of 356.69 Hz. A composite controller incorporating HGAPSO attained submicron tracking accuracy, with errors of 0.43 μm and 0.47 μm along the X and Y axes, respectively. Strong agreement among theoretical analysis, FEA, and experimental results confirms the platform's precision and effectiveness meeting the requirements of the OIS. This work provides valuable guidance for the development of high-frequency OIS systems in highly dynamic operational environments.

光学稳像技术是提高机载光电动态成像性能的关键技术。本研究提出了一种二维压电驱动的OIS平台,能够补偿线性像移误差。建立了一种将桥梁放大机构与直角导向梁相结合的运动平台,并通过有限元分析对其理论模型进行了验证。为了提高平台的可重复性,采用Bouc-Wen模型描述了压电驱动器的滞后特性,并采用混合遗传算法和粒子群算法(HGAPSO)进行了优化。实验结果表明,该平台工作空间为53.92 μm × 53.76 μm,运动分辨率为30 nm,最大耦合误差为2.28%,一阶谐振频率为356.69 Hz。采用HGAPSO的复合控制器实现了亚微米级的跟踪精度,X轴和Y轴的跟踪误差分别为0.43 μm和0.47 μm。理论分析、有限元分析和实验结果吻合较好,验证了该平台的精度和有效性,满足了OIS的要求。这项工作为高动态操作环境下高频OIS系统的开发提供了有价值的指导。
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引用次数: 0
High-Capacitance Gold Nanoparticles from Rhus coriaria: Green Synthesis, Characterization and Electrochemical Evaluation for Supercapacitor Technologies. 芫荽高电容金纳米颗粒:超级电容器技术的绿色合成、表征和电化学评价。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-08 DOI: 10.3390/mi17010082
Mehmet Firat Baran, Elchin Huseynov, Aziz Eftekhari, Abdulkadir Levent, Erdal Ertaş, Taras Kavetskyy, Ondrej Šauša, Evgeny Katz, Oleh Smutok

The structural and electrochemical properties of gold nanoparticles biosynthesized from Rhus coriaria L. (Rc@AuNPs) were comprehensively investigated and characterized. R. coriaria (sumac) served as a natural gold reducing and capping agent due to its rich polyphenolic and phytochemical composition, enabling the sustainable, low-cost, and environmentally friendly synthesis of Rc@AuNPs. The electrochemical behavior of the hybrid material was evaluated using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). Rc@AuNPs exhibited specific capacitances of 129.48 F/g, 156.32 F/g, and 280.37 F/g in H2SO4, Na2SO4, and KOH electrolytes, respectively, indicating strong potential for supercapacitor and energy-storage applications. GCD analysis further showed Csp values of 107.69 F/g (H2SO4), 133.23 F/g (Na2SO4), and 348.34 F/g (KOH), confirming the highest charge-storage performance in basic media. EIS measurements supported these results, yielding equivalent series resistance (ESR) values of 67.96 Ω in H2SO4, 64.42 Ω in Na2SO4, and a notably lower 24.43 Ω in KOH, consistent with its higher ionic conductivity and more efficient charge transfer. Overall, the superior Csp and low ESR observed in KOH demonstrate the excellent capacitive behavior of Rc@AuNPs. These biosynthesized gold nanoparticles represent a promising and sustainable electrode material for high-performance energy-storage technologies.

对生物合成金纳米粒子(Rc@AuNPs)的结构和电化学性能进行了全面的研究和表征。由于其丰富的多酚和植物化学成分,漆树作为天然的黄金还原和封盖剂,使Rc@AuNPs的合成可持续、低成本和环保。利用循环伏安法(CV)、恒流充放电法(GCD)和电化学阻抗谱法(EIS)对复合材料的电化学行为进行了评价。Rc@AuNPs在H2SO4、Na2SO4和KOH电解质中的比电容分别为129.48 F/g、156.32 F/g和280.37 F/g,表明其在超级电容器和储能方面具有很强的应用潜力。GCD分析进一步显示,Csp值为107.69 F/g (H2SO4), 133.23 F/g (Na2SO4)和348.34 F/g (KOH),证实了基本介质中最高的电荷存储性能。EIS测量支持这些结果,在H2SO4中得到的等效串联电阻(ESR)值为67.96 Ω,在Na2SO4中为64.42 Ω,在KOH中得到的等效串联电阻(ESR)值明显更低,为24.43 Ω,这与KOH具有更高的离子电导率和更有效的电荷转移相一致。总的来说,在KOH中观察到的优越的Csp和低ESR表明Rc@AuNPs具有优异的电容性。这些生物合成的金纳米颗粒代表了一种有前途的、可持续的高性能储能技术电极材料。
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引用次数: 0
Unified Parametric Optimization Framework for Microchannel Fin Geometries in High-Power Processor Cooling. 大功率处理器散热微通道翅片几何形状的统一参数优化框架。
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2026-01-08 DOI: 10.3390/mi17010086
Abtin Ataei

This study presents a unified parametric optimization framework for the thermal design of microchannel spreaders used in high-power processor cooling. The fin geometry is expressed in a shape-agnostic parametric form defined by fin thickness, top and bottom gap widths, and channel height, without prescribing a fixed cross-section. This approach accommodates practical fin profiles ranging from rectangular to tapered and V-shaped, allowing continuous geometric optimization within manufacturability and hydraulic limits. A coupled analytical-numerical model integrates conduction through the spreader base, interfacial resistance across the thermal interface material (TIM), and convection within the coolant channels while enforcing a pressure-drop constraint. The optimization uses a deterministic continuation method with smooth sigmoid mappings and penalty functions to maintain constraint satisfaction and stable convergence across the design space. The total thermal resistance (Rtot) is minimized over spreader conductivities ks=400-2200 W m-1 K-1 (copper to CVD diamond), inlet fluid velocities Uin=0.5-5.5 m s-1, maximum pressure drops of 10-50 kPa, and fluid pass counts Np∈{1,2,3}. The resulting maps of optimized fin dimensions as functions of ks provide continuous design charts that clarify how material conductivity, flow rate, and pass configuration collectively determine the geometry, minimizing total thermal resistance, thereby reducing chip temperature rise for a given heat load.

本研究提出了用于大功率处理器散热的微通道扩展器热设计的统一参数优化框架。翅片的几何形状以一种与形状无关的参数形式表示,由翅片厚度、顶部和底部间隙宽度以及通道高度定义,而没有规定固定的横截面。这种方法适用于从矩形到锥形和v形的实际鳍型,允许在可制造性和水力限制内进行连续的几何优化。耦合分析-数值模型集成了通过扩散器基座的传导、热界面材料(TIM)的界面阻力以及冷却剂通道内的对流,同时强制施加压降约束。优化采用确定性延拓方法,结合光滑的s型映射和惩罚函数,保证了约束满足和整个设计空间的稳定收敛。总热阻(Rtot)在扩展器电导率ks=400-2200 W m-1 K-1(铜到CVD金刚石),入口流体速度un =0.5-5.5 m s-1,最大压降10-50 kPa,流体通过次数Np∈{1,2,3}时最小。优化后的翅片尺寸图作为ks的函数提供了连续的设计图表,阐明了材料的导电性、流速和通道配置如何共同决定几何形状,最大限度地减少总热阻,从而降低给定热负荷下芯片的温升。
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