首页 > 最新文献

Metallurgical Research & Technology最新文献

英文 中文
Achieving stable steelmaking basic oxygen furnace slag through treatment by self-disintegration high pressure process 采用高压自崩解法处理炼钢碱性氧炉渣,达到稳定炼钢碱性氧炉渣的目的
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021020
B. Peng, Wu Yuedong, C. Yue, Yu-Xiang Li
The basic oxygen furnace slag generated during steelmaking can be reused as aggregates in civil engineering because of its chemical composition and technological properties. However, the utilization of steel slag in practical applications is quite low due to its low volume stability. In this work, highly stable slag is obtained by the environmental-friendly self-disintegration high pressure (SDHP) process. In this method, the molten slag is initially crushed to form numerous small bulks. Subsequently, the slag bulks are treated by the self-disintegration process at a high pressure to obtain the highly stable steel slag. Thermodynamic evaluation and experimental investigation reveal that high pressure of steam promotes the hydration reaction. At a pressure of 0.2 MPa, the free lime (f-CaO) content and immersion expansion rate of the steel slag treated by this method are reduced to 1.5% and 0.9%, respectively. Both of these values satisfy the requirements specified in the national standards (GB/T 25029-2010 and GB/T 20491-2006). Moreover, the treatment time is reduced to 1.5 h, which is far lower than the treatment times required for traditional methods.
炼钢过程中产生的碱性氧炉渣具有良好的化学成分和工艺性能,可作为集料在土木工程中重复利用。但由于钢渣的体积稳定性不高,在实际应用中的利用率很低。采用环境友好型高压自崩解(SDHP)工艺获得了高稳定性的矿渣。在这种方法中,熔渣最初被粉碎成许多小块。然后对渣块进行高压自崩解处理,得到高稳定的钢渣。热力学评价和实验研究表明,高压蒸汽促进了水化反应。在0.2 MPa压力下,经该方法处理的钢渣的游离石灰(f-CaO)含量和浸胀率分别降至1.5%和0.9%。这两个值均满足国家标准GB/T 25029-2010和GB/T 20491-2006的要求。处理时间缩短至1.5 h,远低于传统方法所需的处理时间。
{"title":"Achieving stable steelmaking basic oxygen furnace slag through treatment by self-disintegration high pressure process","authors":"B. Peng, Wu Yuedong, C. Yue, Yu-Xiang Li","doi":"10.1051/METAL/2021020","DOIUrl":"https://doi.org/10.1051/METAL/2021020","url":null,"abstract":"The basic oxygen furnace slag generated during steelmaking can be reused as aggregates in civil engineering because of its chemical composition and technological properties. However, the utilization of steel slag in practical applications is quite low due to its low volume stability. In this work, highly stable slag is obtained by the environmental-friendly self-disintegration high pressure (SDHP) process. In this method, the molten slag is initially crushed to form numerous small bulks. Subsequently, the slag bulks are treated by the self-disintegration process at a high pressure to obtain the highly stable steel slag. Thermodynamic evaluation and experimental investigation reveal that high pressure of steam promotes the hydration reaction. At a pressure of 0.2 MPa, the free lime (f-CaO) content and immersion expansion rate of the steel slag treated by this method are reduced to 1.5% and 0.9%, respectively. Both of these values satisfy the requirements specified in the national standards (GB/T 25029-2010 and GB/T 20491-2006). Moreover, the treatment time is reduced to 1.5 h, which is far lower than the treatment times required for traditional methods.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"6 1","pages":"207"},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88325180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effect of the upset pressure on Microstructure and Properties of Friction Welded Joints of 6082 aluminum alloy/304 stainless steel 镦压对6082铝合金/304不锈钢摩擦焊接接头组织和性能的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021067
Gui-peng Lu, Li-zhe Zhao, Wei Liu, Yu-meng Sun, W. Gong
The dissimilar connection between 6082 aluminum alloy and 304 stainless steel was realized by continuous drive friction welding. Microstructures of the joint were studied by optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffractometry (XRD). In the process of continuous drive welding, the intermetallic compounds (IMCs) Fe2Al5 phase was observed at the interface, the formation mechanism of IMC was discussed, and the corresponding analysis model was established. When the upset pressure in the range of 6–10 MPa, the element diffusion distance increases with the increase of upset pressure. The tensile strength of the joint increased firstly and then decreased with the increase of upset pressure. The joint’s maximum tensile strength can reach 234 MPa, and tensile fracture of the joint exhibited brittle-tough mixed fracture characteristics.
通过连续驱动摩擦焊接,实现了6082铝合金与304不锈钢的异型连接。采用光学显微镜(OM)、扫描电镜(SEM)和x射线衍射仪(XRD)对接头的微观组织进行了研究。在连续驱动焊接过程中,在界面处观察到金属间化合物(IMC) Fe2Al5相,探讨了IMC的形成机理,并建立了相应的分析模型。当扰流压力在6 ~ 10 MPa范围内时,元件扩散距离随扰流压力的增大而增大。随着镦压压力的增大,接头的抗拉强度先增大后减小。接头的最大抗拉强度可达234 MPa,接头的拉伸断裂呈现脆韧混合断裂特征。
{"title":"Effect of the upset pressure on Microstructure and Properties of Friction Welded Joints of 6082 aluminum alloy/304 stainless steel","authors":"Gui-peng Lu, Li-zhe Zhao, Wei Liu, Yu-meng Sun, W. Gong","doi":"10.1051/metal/2021067","DOIUrl":"https://doi.org/10.1051/metal/2021067","url":null,"abstract":"The dissimilar connection between 6082 aluminum alloy and 304 stainless steel was realized by continuous drive friction welding. Microstructures of the joint were studied by optical microscopy (OM), scanning electron microscopy (SEM) and X-ray diffractometry (XRD). In the process of continuous drive welding, the intermetallic compounds (IMCs) Fe2Al5 phase was observed at the interface, the formation mechanism of IMC was discussed, and the corresponding analysis model was established. When the upset pressure in the range of 6–10 MPa, the element diffusion distance increases with the increase of upset pressure. The tensile strength of the joint increased firstly and then decreased with the increase of upset pressure. The joint’s maximum tensile strength can reach 234 MPa, and tensile fracture of the joint exhibited brittle-tough mixed fracture characteristics.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"15 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73237843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
BP neural network prediction for Si and S contents in hot metal of COREX process based on mathematical analysis and Deng’s correlation 基于数学分析和邓氏相关的COREX工艺铁水中Si、S含量BP神经网络预测
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021073
Heng Zhou, Yifan Hu, Bingjie Wen, Shengli Wu, M. Kou, Yinsheng Luo
In COREX operation, the Si and S contents in hot metal are relatively high and easy-fluctuating, which is one of the problems affecting the practical operation. Accurate predictions of Si and S contents can provide theoretical references for stabilizing the fluctuations and decreasing the contents of Si and S in hot metal. Therefore, the present work established the prediction model of Si and S contents in hot metal in COREX based on BP neural network. The results show that the root-mean-square errors between the predicted value and actual value for Si and S are 0.098 and 0.0037, respectively. They are 0.070 and 0.0040 when the time-sequence lapse method is adopted, which turns out to be better. Therefore, the model is accurate and reliable to predict the Si and S contents in hot metal in COREX.
在COREX操作中,铁水中Si、S含量较高且易波动,是影响实际操作的问题之一。准确的Si和S含量预测可以为稳定金属热中Si和S含量的波动和降低含量提供理论参考。因此,本文建立了基于BP神经网络的COREX铁水中Si、S含量预测模型。结果表明,Si和S的预测值与实际值的均方根误差分别为0.098和0.0037。采用时序递进法时分别为0.070和0.0040,效果较好。因此,该模型预测COREX铁水中Si、S含量准确可靠。
{"title":"BP neural network prediction for Si and S contents in hot metal of COREX process based on mathematical analysis and Deng’s correlation","authors":"Heng Zhou, Yifan Hu, Bingjie Wen, Shengli Wu, M. Kou, Yinsheng Luo","doi":"10.1051/metal/2021073","DOIUrl":"https://doi.org/10.1051/metal/2021073","url":null,"abstract":"In COREX operation, the Si and S contents in hot metal are relatively high and easy-fluctuating, which is one of the problems affecting the practical operation. Accurate predictions of Si and S contents can provide theoretical references for stabilizing the fluctuations and decreasing the contents of Si and S in hot metal. Therefore, the present work established the prediction model of Si and S contents in hot metal in COREX based on BP neural network. The results show that the root-mean-square errors between the predicted value and actual value for Si and S are 0.098 and 0.0037, respectively. They are 0.070 and 0.0040 when the time-sequence lapse method is adopted, which turns out to be better. Therefore, the model is accurate and reliable to predict the Si and S contents in hot metal in COREX.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"206 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76057715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Performance analysis of hot metal temperature prediction in a blast furnace and expert suggestion system proposal using neural, statistical and fuzzy models 高炉铁水温度预测性能分析及应用神经、统计和模糊模型的专家建议系统方案
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021043
Erdoğan Bozkurt, I. M. Orak, Yasin Tunçkaya
Blast Furnace (BF) production methodology is one of the most complex process of iron & steel plants as it is dependent on multi-variable process inputs and disturbances to be modelled properly. Due to expensive investment costs, it is critical to operate a BF by reducing operational expenses, increasing the performance of raw material and fuel consumptions to optimize overall furnace efficiency and stability, also to maximize the lifetime. The chemical compositions and temperature of hot metal are important indicators while evaluating the operation, therefore, if the future values of hot metal temperature can be predicted in advance instead of subsequent measuring, then the BF staff can take earlier counteractions on several operational parameters such as coke to ore ratio, distribution matrix, oxygen enrichment rate, blast moisture rate, permeability, flame temperature, cold blast temperature, cold blast flow and pulverized coal injection rate, etc. to control the furnace optimally. In this study, Artificial Neural Networks (ANN) model is proposed combined with NARX (Nonlinear autoregressive exogenous model) time series approach to track and predict furnace hot metal temperature by selecting the most suitable process inputs and past values of hot metal temperatures using the real data which is collected from the BF operated in Turkey during 2 months of operation. Various data mining techniques are applied due to requirements of charge cycling and operating speed of the furnace which secures novelty and effectiveness of this study comparing previous articles. Furthermore, a statistical tool, Autoregressive Integrated Moving Average (ARIMA) model, is also executed for comparison. ANN prediction results of 0.92, 8.59 and 0.41 are found very satisfactory comparing ARIMA (1,1,1) model outputs of 0.73, 97.4 and 9.32 for R2 (Coefficient of determination), RMSE (Root mean squared error) and MAPE (Mean absolute percentage error) respectively. Consequently, an expert suggestion system is proposed using fuzzy if-then rules with 5 × 5 probability matrix design using the last predicted HMT value and the average of the last 5 HMT values to decide furnace’s warming or cooling movements state in mid-term and maintain the operational actions interactively in advance.
高炉(BF)生产方法是钢铁工厂最复杂的过程之一,因为它依赖于多变量过程输入和干扰,需要正确建模。由于昂贵的投资成本,通过降低运营费用,提高原料性能和燃料消耗来优化整体炉效率和稳定性,并最大限度地延长使用寿命来运营高炉至关重要。铁水的化学成分和温度是评价运行的重要指标,因此,如果可以提前预测铁水温度的未来值,而不是随后的测量,那么高炉工作人员就可以更早地对焦矿比、分布矩阵、富氧率、高炉含水率、渗透率、火焰温度、冷风温度等几个操作参数采取对策。对冷风流量、喷煤粉速度等进行优化控制。本研究利用土耳其某高炉2个月的实际运行数据,选择最合适的工艺输入和过去的铁水温度值,提出了人工神经网络(ANN)模型与非线性自回归外生模型(NARX)时间序列方法相结合的方法来跟踪和预测炉内铁水温度。由于炉料循环和炉速的要求,采用了多种数据挖掘技术,与以往的研究相比,具有新颖性和有效性。此外,统计工具,自回归综合移动平均(ARIMA)模型,也执行了比较。与ARIMA(1,1,1)模型的R2(决定系数)、RMSE(均方根误差)和MAPE(平均绝对百分比误差)的输出分别为0.73、97.4和9.32相比,人工神经网络的预测结果为0.92、8.59和0.41。在此基础上,提出了一种基于5 × 5概率矩阵设计的模糊if-then规则专家建议系统,利用最后一次预测的HMT值和最后5次HMT值的平均值来决定炉体中期的加温或冷却运动状态,并提前交互式地维持运行动作。
{"title":"Performance analysis of hot metal temperature prediction in a blast furnace and expert suggestion system proposal using neural, statistical and fuzzy models","authors":"Erdoğan Bozkurt, I. M. Orak, Yasin Tunçkaya","doi":"10.1051/METAL/2021043","DOIUrl":"https://doi.org/10.1051/METAL/2021043","url":null,"abstract":"Blast Furnace (BF) production methodology is one of the most complex process of iron & steel plants as it is dependent on multi-variable process inputs and disturbances to be modelled properly. Due to expensive investment costs, it is critical to operate a BF by reducing operational expenses, increasing the performance of raw material and fuel consumptions to optimize overall furnace efficiency and stability, also to maximize the lifetime. The chemical compositions and temperature of hot metal are important indicators while evaluating the operation, therefore, if the future values of hot metal temperature can be predicted in advance instead of subsequent measuring, then the BF staff can take earlier counteractions on several operational parameters such as coke to ore ratio, distribution matrix, oxygen enrichment rate, blast moisture rate, permeability, flame temperature, cold blast temperature, cold blast flow and pulverized coal injection rate, etc. to control the furnace optimally. In this study, Artificial Neural Networks (ANN) model is proposed combined with NARX (Nonlinear autoregressive exogenous model) time series approach to track and predict furnace hot metal temperature by selecting the most suitable process inputs and past values of hot metal temperatures using the real data which is collected from the BF operated in Turkey during 2 months of operation. Various data mining techniques are applied due to requirements of charge cycling and operating speed of the furnace which secures novelty and effectiveness of this study comparing previous articles. Furthermore, a statistical tool, Autoregressive Integrated Moving Average (ARIMA) model, is also executed for comparison. ANN prediction results of 0.92, 8.59 and 0.41 are found very satisfactory comparing ARIMA (1,1,1) model outputs of 0.73, 97.4 and 9.32 for R2 (Coefficient of determination), RMSE (Root mean squared error) and MAPE (Mean absolute percentage error) respectively. Consequently, an expert suggestion system is proposed using fuzzy if-then rules with 5 × 5 probability matrix design using the last predicted HMT value and the average of the last 5 HMT values to decide furnace’s warming or cooling movements state in mid-term and maintain the operational actions interactively in advance.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"74 1","pages":"321"},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74309331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Study of the influence of dithizone as an eco-friendly corrosion inhibitor on the corrosion behaviour of AA7075 aluminium alloy in neutral chloride solution 双硫腙作为环保型缓蚀剂对AA7075铝合金在中性氯溶液中腐蚀行为的影响研究
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021002
M. Acila, H. Bensabra, M. Santamaría
The effect of 1,5-diphenylthiocarbazone (dithizone) as an eco-friendly corrosion inhibitor for protection of AA7075 aluminium alloy in chloride containing aggressive environment was studied by means of weight-loss, electrochemical measurements and Raman spectroscopy. The results indicate that the addition of dithizone decreases significantly the corrosion rate of AA7075 alloy, with efficiency proportional to the inhibitor concentration. The polarization curves show that dithizone works as mixed-type inhibitor to slow down the anodic and cathodic reaction kinetic. The morphology revealed by scanning electron microscopy and the Raman spectroscopy analysis clearly shows that the inhibitor contributes in the formation of a stable protective film on the AA7075 alloy due to the adsorption of dithizone molecules on aluminium alloy surface obeying Langmuir adsorption isotherm.
采用失重、电化学测量和拉曼光谱等方法研究了1,5-二苯基硫脲(dithizone)作为环保型缓蚀剂对含氯侵蚀环境中AA7075铝合金的保护作用。结果表明:双硫腙的加入显著降低了AA7075合金的腐蚀速率,且效果与缓蚀剂浓度成正比;极化曲线表明,双硫腙作为混合型缓蚀剂可减缓阳极和阴极反应动力学。扫描电镜和拉曼光谱的形貌分析表明,双硫腙分子在铝合金表面的吸附服从Langmuir吸附等温线,有助于在AA7075合金表面形成稳定的保护膜。
{"title":"Study of the influence of dithizone as an eco-friendly corrosion inhibitor on the corrosion behaviour of AA7075 aluminium alloy in neutral chloride solution","authors":"M. Acila, H. Bensabra, M. Santamaría","doi":"10.1051/METAL/2021002","DOIUrl":"https://doi.org/10.1051/METAL/2021002","url":null,"abstract":"The effect of 1,5-diphenylthiocarbazone (dithizone) as an eco-friendly corrosion inhibitor for protection of AA7075 aluminium alloy in chloride containing aggressive environment was studied by means of weight-loss, electrochemical measurements and Raman spectroscopy. The results indicate that the addition of dithizone decreases significantly the corrosion rate of AA7075 alloy, with efficiency proportional to the inhibitor concentration. The polarization curves show that dithizone works as mixed-type inhibitor to slow down the anodic and cathodic reaction kinetic. The morphology revealed by scanning electron microscopy and the Raman spectroscopy analysis clearly shows that the inhibitor contributes in the formation of a stable protective film on the AA7075 alloy due to the adsorption of dithizone molecules on aluminium alloy surface obeying Langmuir adsorption isotherm.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"151 1","pages":"203"},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74291181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Evolution of microstructure and texture of ultra-thin non-oriented electrical steel manufactured by CSP CSP法制备超薄无取向电工钢的组织与织构演变
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021079
L. Fan, Meili Qin, Xingyuan Zhao, Zheng-hai Zhu, Li-jun Xiao, Jiao-Huang, Feng-Guo
The evolution of the microstructure and texture of CSP thin-gauge non-oriented silicon steel was investigated by OM, XRD and EBSD. Results show: (1) the equiaxed surface grains with 28.13 µm average grains size accounted for 19.14% of through-thickness, while deformed band structure dominated the center layer and the other maintained at a composite structure with the first two. With the cold-rolled reduction rate enhancing to 91.15%, the stratification structure transformed into a complete fibrous structure. Annealing from 925 °C to 975 °C, the average grain size of the annealing plate similarly increased, which begins with 67.3 µm and ends at 80.58 µm. (2) The texture of the hot-rolled sheets mainly located at Cube and Goss texture, while with the cold-rolled process executing, the type and volume of texture change and finally stabilize at α fiber texture ({110}//RD) with the peak at {114}<110> at 91.15% reductions rate. The {411}<148> texture on the α* fiber line throughout maintained the strongest texture at different annealing temperatures. (3) The initial re-crystallization temperature is in the range of 600–620 °C, and the re-crystallization is roughly completed at 700 °C. Part of {411}<148> oriented grains nucleated at {411}<148> sub-grains originated from α fiber deformed structure, and the others nucleate at the grains boundaries of the deformed α fiber grains or in the inner of {111}<110> and {111}<112> grains. When the re-crystallization was accomplished at 750 °C, {411}<148> oriented grains are significantly larger than other oriented grains compared to 680 °C or the less. (4) Best magnetic properties were obtained at 975 °C with the B50 = 1.506 T and P10/400 = 16.19 W/kg.
采用OM、XRD和EBSD研究了CSP薄型无取向硅钢的组织和织构演变。结果表明:(1)平均晶粒尺寸为28.13µm的等轴表面晶粒占通厚的19.14%,中心层以变形带结构为主,其余与前两者保持复合结构。当冷轧压下率提高到91.15%时,分层组织转变为完整的纤维组织。从925℃退火到975℃,退火板的平均晶粒尺寸也同样增大,从67.3µm开始到80.58µm结束。(2)热轧薄板织构主要以Cube和Goss织构为主,随着冷轧工艺的进行,织构的类型和体积发生变化,最终稳定在α纤维织构({110}//RD),在{114}处达到峰值,还原率为91.15%。α*纤维线上的{411}织构在不同退火温度下均保持最强织构。(3)初始再结晶温度在600 ~ 620℃,700℃时基本完成再结晶。部分{411}取向晶粒在{411}亚晶形核源于α纤维变形组织,其余晶粒在变形α纤维晶粒晶界处或{111}、{111}晶粒内部形核。在750℃下再结晶时,{411}取向晶粒明显大于680℃或更低温度下的其他取向晶粒。(4)在975℃,B50 = 1.506 T, P10/400 = 16.19 W/kg时磁性能最佳。
{"title":"Evolution of microstructure and texture of ultra-thin non-oriented electrical steel manufactured by CSP","authors":"L. Fan, Meili Qin, Xingyuan Zhao, Zheng-hai Zhu, Li-jun Xiao, Jiao-Huang, Feng-Guo","doi":"10.1051/metal/2021079","DOIUrl":"https://doi.org/10.1051/metal/2021079","url":null,"abstract":"The evolution of the microstructure and texture of CSP thin-gauge non-oriented silicon steel was investigated by OM, XRD and EBSD. Results show: (1) the equiaxed surface grains with 28.13 µm average grains size accounted for 19.14% of through-thickness, while deformed band structure dominated the center layer and the other maintained at a composite structure with the first two. With the cold-rolled reduction rate enhancing to 91.15%, the stratification structure transformed into a complete fibrous structure. Annealing from 925 °C to 975 °C, the average grain size of the annealing plate similarly increased, which begins with 67.3 µm and ends at 80.58 µm. (2) The texture of the hot-rolled sheets mainly located at Cube and Goss texture, while with the cold-rolled process executing, the type and volume of texture change and finally stabilize at α fiber texture ({110}//RD) with the peak at {114}<110> at 91.15% reductions rate. The {411}<148> texture on the α* fiber line throughout maintained the strongest texture at different annealing temperatures. (3) The initial re-crystallization temperature is in the range of 600–620 °C, and the re-crystallization is roughly completed at 700 °C. Part of {411}<148> oriented grains nucleated at {411}<148> sub-grains originated from α fiber deformed structure, and the others nucleate at the grains boundaries of the deformed α fiber grains or in the inner of {111}<110> and {111}<112> grains. When the re-crystallization was accomplished at 750 °C, {411}<148> oriented grains are significantly larger than other oriented grains compared to 680 °C or the less. (4) Best magnetic properties were obtained at 975 °C with the B50 = 1.506 T and P10/400 = 16.19 W/kg.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"1 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83165717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic modelling and linear quadratic sliding mode control of a multivariable looper system in hot strip mills 热连轧多变量活套系统的动力学建模与线性二次滑模控制
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2020095
Yin Fang-chen, Wu Xiang-Cheng
This paper introduces a linear quadratic sliding mode control (LQ-SMC) scheme into a looper control system. First, according to a 1700 mm tandem hot mill, the state-space dynamic model of the looper system was established, and then, the optimal control law of the looper system was obtained based on the established model. Finally, the optimal sliding mode and optimal sliding mode control law of the LQ-SMC scheme were designed such that the sliding motion could satisfy the optimal value of the quadratic performance index. Simulation results show that the proposed control scheme has complete robustness to external disturbances that satisfies certain conditions, and the coupling between the looper angle dynamic and strip tension dynamic is also minimized.
本文将线性二次滑模控制(LQ-SMC)方案引入到活套控制系统中。以某1700 mm热连轧机为研究对象,建立了活套系统的状态空间动力学模型,并在此基础上得到了活套系统的最优控制律。最后,设计了LQ-SMC方案的最优滑模和最优滑模控制律,使滑动运动满足二次型性能指标的最优值。仿真结果表明,所提出的控制方案对满足一定条件的外部干扰具有完全的鲁棒性,并且使活套角动态与带钢张力动态之间的耦合最小。
{"title":"Dynamic modelling and linear quadratic sliding mode control of a multivariable looper system in hot strip mills","authors":"Yin Fang-chen, Wu Xiang-Cheng","doi":"10.1051/METAL/2020095","DOIUrl":"https://doi.org/10.1051/METAL/2020095","url":null,"abstract":"This paper introduces a linear quadratic sliding mode control (LQ-SMC) scheme into a looper control system. First, according to a 1700 mm tandem hot mill, the state-space dynamic model of the looper system was established, and then, the optimal control law of the looper system was obtained based on the established model. Finally, the optimal sliding mode and optimal sliding mode control law of the LQ-SMC scheme were designed such that the sliding motion could satisfy the optimal value of the quadratic performance index. Simulation results show that the proposed control scheme has complete robustness to external disturbances that satisfies certain conditions, and the coupling between the looper angle dynamic and strip tension dynamic is also minimized.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"118 1","pages":"215"},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86885953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Comparative analysis of the effect of Ca and Mg-Al modification on the composite inclusions in S50C Die steel Ca和Mg-Al改性对S50C模具钢复合夹杂物影响的对比分析
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021049
Chengying Cao, Gao-feng Wang, Jie Li, Qianghua Tian, Qi Zhu, Ke-nan Ai, Jianxun Fu
At present, the effective ways to improve the cleanliness of S50C die steel are Ca or Mg-Al treatment processes. In order to explore the effect difference of two kinds of modification process of S50C killed steel, evaluate the industrial application prospect of the two processes, and clarify the modification mechanism. In this paper, the advantages of Mg-Al modification are demonstrated from the aspects of theoretical basis and actual sample modification effect. The thermodynamics and kinetics of inclusion precipitation, composition, morphology, and distribution are analyzed. The results show that: the precipitation temperature of MnS in S50C die steel is 1686 K, the corresponding solid-phase rate is 0.98. In Mg-Al modification, when the Al content is 332 ppm, the Mg content should be controlled below 14.1 ppm. When the Al content is higher than 0.02%, the Ca content should be controlled below 28.7 ppm. Kinetic calculations show that the equilibrium shape size of MnS is in the range of 0.3‑1.4 µm. Both modifications increase the nucleation rate of inclusions and control the shape and size of inclusions by pre-precipitation. Ca treatment is preventing the formation of large inclusions by forming calcium aluminate. Mg can provide more uniform nucleation sites and form smaller inclusions.
目前,提高S50C模具钢洁净度的有效途径是Ca或Mg-Al处理工艺。为了探讨S50C钢两种改性工艺的效果差异,评价两种工艺的工业应用前景,阐明改性机理。本文从理论基础和实际样品改性效果两方面论证了Mg-Al改性的优越性。分析了夹杂物析出、组成、形貌和分布的热力学和动力学。结果表明:MnS在S50C模具钢中的析出温度为1686 K,固相速率为0.98;在Mg-Al改性中,当Al含量为332 ppm时,Mg含量应控制在14.1 ppm以下。当Al含量高于0.02%时,Ca含量应控制在28.7 ppm以下。动力学计算表明,MnS的平衡形状尺寸在0.3 ~ 1.4µm之间。这两种变质均通过预沉淀作用提高了夹杂物的成核速率,控制了夹杂物的形状和大小。钙处理通过形成铝酸钙来防止大包裹体的形成。Mg能提供更均匀的核位,形成更小的包裹体。
{"title":"Comparative analysis of the effect of Ca and Mg-Al modification on the composite inclusions in S50C Die steel","authors":"Chengying Cao, Gao-feng Wang, Jie Li, Qianghua Tian, Qi Zhu, Ke-nan Ai, Jianxun Fu","doi":"10.1051/metal/2021049","DOIUrl":"https://doi.org/10.1051/metal/2021049","url":null,"abstract":"At present, the effective ways to improve the cleanliness of S50C die steel are Ca or Mg-Al treatment processes. In order to explore the effect difference of two kinds of modification process of S50C killed steel, evaluate the industrial application prospect of the two processes, and clarify the modification mechanism. In this paper, the advantages of Mg-Al modification are demonstrated from the aspects of theoretical basis and actual sample modification effect. The thermodynamics and kinetics of inclusion precipitation, composition, morphology, and distribution are analyzed. The results show that: the precipitation temperature of MnS in S50C die steel is 1686 K, the corresponding solid-phase rate is 0.98. In Mg-Al modification, when the Al content is 332 ppm, the Mg content should be controlled below 14.1 ppm. When the Al content is higher than 0.02%, the Ca content should be controlled below 28.7 ppm. Kinetic calculations show that the equilibrium shape size of MnS is in the range of 0.3‑1.4 µm. Both modifications increase the nucleation rate of inclusions and control the shape and size of inclusions by pre-precipitation. Ca treatment is preventing the formation of large inclusions by forming calcium aluminate. Mg can provide more uniform nucleation sites and form smaller inclusions.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"26 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77554332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A convolutional neural network-based model for predicting lime utilization ratio in the KR desulfurization process 基于卷积神经网络的KR脱硫过程石灰利用率预测模型
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021074
Size Wu, Jian Yang
In the presented work, desulfurization process parameters and the lime utilization ratio were correlated by data-driven technique, and a convolutional neural network was applied to predict the lime utilization ratio in the Kambara Reactor (KR) desulfurization process. The results show that compared with the support vector regression model and random forest model, the convolutional neural network model achieves the best performance with correlation coefficient value of 0.9964, mean absolute relative error of 0.01229 and root mean squared error of 0.3392%. The sensitivity analysis was carried out to investigate the influence of process parameters on the lime utilization ratio, which shows that the lime weight and the initial sulfur content have the significant effect on the lime utilization ratio. By analyzing the influence of the lime weight on the lime utilization ratio under the current desulfurization process parameters, it can be concluded that decreasing the lime weight from 3256 kg to 2332 kg can increase the lime utilization ratio by about 5%.
采用数据驱动技术,将脱硫工艺参数与石灰利用率进行关联,并应用卷积神经网络对Kambara反应器(KR)脱硫过程中的石灰利用率进行预测。结果表明,与支持向量回归模型和随机森林模型相比,卷积神经网络模型的相关系数值为0.9964,平均绝对相对误差为0.01229,均方根误差为0.3392。通过敏感性分析考察了工艺参数对石灰利用率的影响,结果表明,石灰质量和初始硫含量对石灰利用率有显著影响。通过分析在现有脱硫工艺参数下石灰重对石灰利用率的影响,得出石灰重从3256 kg降低到2332 kg可使石灰利用率提高5%左右的结论。
{"title":"A convolutional neural network-based model for predicting lime utilization ratio in the KR desulfurization process","authors":"Size Wu, Jian Yang","doi":"10.1051/metal/2021074","DOIUrl":"https://doi.org/10.1051/metal/2021074","url":null,"abstract":"In the presented work, desulfurization process parameters and the lime utilization ratio were correlated by data-driven technique, and a convolutional neural network was applied to predict the lime utilization ratio in the Kambara Reactor (KR) desulfurization process. The results show that compared with the support vector regression model and random forest model, the convolutional neural network model achieves the best performance with correlation coefficient value of 0.9964, mean absolute relative error of 0.01229 and root mean squared error of 0.3392%. The sensitivity analysis was carried out to investigate the influence of process parameters on the lime utilization ratio, which shows that the lime weight and the initial sulfur content have the significant effect on the lime utilization ratio. By analyzing the influence of the lime weight on the lime utilization ratio under the current desulfurization process parameters, it can be concluded that decreasing the lime weight from 3256 kg to 2332 kg can increase the lime utilization ratio by about 5%.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"58 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76583831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Mechanical properties and metallurgical characterization of FSPed TIG and TIG welded AA5052-H32/AA5083-H111 dissimilar aluminium alloys AA5052-H32/AA5083-H111异种铝合金的FSPed TIG和TIG焊接力学性能和冶金学表征
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021005
Antony Prabu Dhanaraj, S. Kumarasamy
This work describes the mechanical properties and metallurgical characterization of Friction Stir Processing (FSP) on TIG welded dissimilar AA5052-H32 and AA5083-H111 alloys using ER5356 filler wire. A comparison is drawn between unprocessed TIG weld and FS Processed (FSPed) TIG welded specimen with the identical combination. The fabricated welded joints were investigated By Optical Microscope (OM), Scanning Electron Microscope (SEM) Analysis, Tensile Strength Analysis, and Micro-Hardness testing. The results illustrate the improvement in mechanical properties after FSPed of the TIG welded joint resulting in enhanced tensile strength (224.5 MPa) and hardness (104 HV) in contrast to the unprocessed TIG weld joints with (192.5 MPa) and (70 Hv). In addition, during the mechanical characterization, the FSPed TIG welds show fine grain at the Friction Stir (FS) processed zone with fine grain structures which improves the hardness at the FS zone. The mechanical property of FS joint is superior when compared to the unprocessed TIG weld joint.
本文介绍了采用ER5356焊丝对AA5052-H32和aa5083 - h11异种合金进行TIG焊接的搅拌摩擦处理(FSP)力学性能和冶金学表征。在相同组合下,对未处理TIG焊件和FS处理TIG焊件进行了比较。通过光学显微镜(OM)、扫描电镜(SEM)、拉伸强度分析和显微硬度测试对焊接接头进行了研究。结果表明,与未处理TIG焊接接头的抗拉强度(192.5 MPa)和硬度(70 HV)相比,经过FSPed处理的TIG焊接接头的力学性能得到了改善,抗拉强度(224.5 MPa)和硬度(104 HV)均有所提高。此外,在力学表征过程中,FSPed TIG焊缝在搅拌摩擦(FS)加工区表现出细小的晶粒,具有细小的晶粒组织,从而提高了搅拌摩擦(FS)加工区的硬度。与未加工的TIG焊接接头相比,FS接头的力学性能优越。
{"title":"Mechanical properties and metallurgical characterization of FSPed TIG and TIG welded AA5052-H32/AA5083-H111 dissimilar aluminium alloys","authors":"Antony Prabu Dhanaraj, S. Kumarasamy","doi":"10.1051/METAL/2021005","DOIUrl":"https://doi.org/10.1051/METAL/2021005","url":null,"abstract":"This work describes the mechanical properties and metallurgical characterization of Friction Stir Processing (FSP) on TIG welded dissimilar AA5052-H32 and AA5083-H111 alloys using ER5356 filler wire. A comparison is drawn between unprocessed TIG weld and FS Processed (FSPed) TIG welded specimen with the identical combination. The fabricated welded joints were investigated By Optical Microscope (OM), Scanning Electron Microscope (SEM) Analysis, Tensile Strength Analysis, and Micro-Hardness testing. The results illustrate the improvement in mechanical properties after FSPed of the TIG welded joint resulting in enhanced tensile strength (224.5 MPa) and hardness (104 HV) in contrast to the unprocessed TIG weld joints with (192.5 MPa) and (70 Hv). In addition, during the mechanical characterization, the FSPed TIG welds show fine grain at the Friction Stir (FS) processed zone with fine grain structures which improves the hardness at the FS zone. The mechanical property of FS joint is superior when compared to the unprocessed TIG weld joint.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"35 1","pages":"304"},"PeriodicalIF":1.1,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84544876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
期刊
Metallurgical Research & Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1