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A simplified mathematical model for total temperature rise calculation in non-oriented silicon steel cold rolling deformation zone 无取向硅钢冷轧变形区总温升计算的简化数学模型
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-12-20 DOI: 10.1051/metal/2021095
Guomin Han, Hongbo Li, Yujin Liu, J. Zhang, N. Kong, Zhiyuan Hu, Lei Liu
In tandem cold rolling, the control of the temperature of high-grade non-oriented silicon steel is a difficult problem for its large deformation resistance and the preheating procedure before rolling. And it is complicated to calculate the total temperature rise of rolling deformation zone due to the comprehensive influence of the plastic deformation heat, the friction heat and the contact heat loss. So, to precisely calculate the total temperature rise, firstly, based on the four classical cold rolling force formulas, the initial total temperature rise calculation models are established correspondingly by theoretically analyzing the temperature rise of deformation heat, the temperature rise of friction heat and the temperature drop of contact heat loss; then, the model based on the improved Lian rolling force formula is adopted, which leads to calculated best matching the measured temperature; finally, considering the complex formula calculation of the initial model, based on the influences of different rolling parameters on the total temperature rise, a simplified model for convenient calculation is proposed by the nonlinear regression analysis of the initial model calculation results and main rolling parameters, which is convenient for the actual application by the field technicians.
高档无取向硅钢因其抗变形能力大,且轧制前需预热,因此在冷轧连轧过程中,温度的控制是一个难题。由于塑性变形热、摩擦热和接触热损失的综合影响,轧制变形区总温升的计算比较复杂。因此,为了精确计算总温升,首先,在四种经典冷轧力公式的基础上,通过理论分析变形热温升、摩擦热温升和接触热损失温降,建立了相应的初始总温升计算模型;然后,采用基于改进的连轧力公式的模型,使计算结果与实测温度最匹配;最后,考虑到初始模型公式计算复杂,基于不同轧制参数对总温升的影响,通过对初始模型计算结果与主要轧制参数的非线性回归分析,提出了简化模型,便于计算,便于现场技术人员的实际应用。
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引用次数: 2
Effect of niobium and austenitizing temperature on the microstructures and properties of spray-deposited AISI M3:2 high speed steel 铌和奥氏体化温度对喷镀AISI M3:2高速钢组织和性能的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-12-20 DOI: 10.1051/metal/2021097
Hebin Wang, D. Hong, L. Hou, Li Shen, P. Ou, LiFang Qiu, Zhi-gang Wang, Hong-jin Zhao
The microstructure and properties of niobium-containing AISI M3:2 high speed steels (HSSs) fabricated by spray forming and traditional casting have been investigated. The results show that fine and uniformly-distributed grains without macrosegregation appeared in the as-deposited HSSs that differ from those of as-cast HSSs. Nb mostly appears in primary MC carbides, whereas it contributes less to the formation of M6C carbides. The high stabilization of Nb-rich MC carbides can pin the grain boundaries during high-temperature austenitizing process, thus conferring a fine grains and raising the content of dissolved alloying elements. Enhanced precipitation strengthening and fine dispersion of NbC carbides throughout the matrix contribute to the high hardness and red hardness of Nb-containing HSS.
研究了喷射成形和传统铸造制备含铌AISI M3:2高速钢的组织和性能。结果表明:与铸态合金相比,沉积态合金的晶粒细小、分布均匀,无宏观偏析;Nb主要出现在初生MC碳化物中,而对M6C碳化物的形成贡献较小。在高温奥氏体化过程中,高稳定度的富铌碳化物能够固定晶界,从而获得细小的晶粒,提高合金中溶解元素的含量。NbC碳化物的析出强化和在基体中的精细分散,使含nb高速钢具有较高的硬度和红硬度。
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引用次数: 0
Significant impact of intercritical annealing temperature on microstructure and mechanical properties of Al substituted Si dual phase steel under ultra-rapid heating 临界间退火温度对Al取代Si双相钢超快速加热组织和力学性能的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-07-01 DOI: 10.1051/metal/2021051
Y. Deng, R. Misra
The significant impact of ultra-rapid heating continuous annealing on microstructure and mechanical properties of Al substituted Si dual phase steel under hot-dip galvanized process was studied. The heating rate of 300 °C/s, and different annealing temperatures in the range of 750 °C to 810 °C were explored. The study indicated that the yield and tensile strengths are increased with the increase of intercritical annealing temperature during rapid heating continuous annealing. When the annealing temperature was 780 °C, the steel exhibited good comprehensive properties with yield strength of 574.9 MPa, tensile strength up to 1009 MPa, total elongation of 18.5%. This is attributed to refined microstructure, appropriate proportion of phases, high density of dislocations and finely distributed NbC precipitates. Furthermore, the variations in strength, elongation and strain-hardening behavior of the steel with thermomechanical parameters and the inherent mechanism for strengthening were further discussed in relation to the microstructural features.
研究了超快加热连续退火对热浸镀锌Al取代Si双相钢组织和力学性能的显著影响。研究了300℃/s的升温速率和750 ~ 810℃的不同退火温度。研究表明,在快速加热连续退火过程中,屈服强度和抗拉强度随着临界间退火温度的升高而提高。当退火温度为780℃时,钢的屈服强度为574.9 MPa,抗拉强度为1009 MPa,总伸长率为18.5%,综合性能良好。这主要是由于合金组织精细、相比例适宜、位错密度高、碳化硅析出物分布精细所致。进一步讨论了钢的强度、伸长率和应变硬化性能随热力学参数的变化规律以及强化的内在机理。
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引用次数: 1
Cyclic annealing versus continuous annealing of 20 wt.% chromium white cast iron 循环退火与20 wt连续退火。%铬白口铸铁
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-06-18 DOI: 10.1051/metal/2021044
S. S. Mandal, D. Mondal, K. Ghosh
To destabilize as-cast microstructure of 20 wt.% chromium white iron, cyclic annealing involving repeated austenitization for short duration of 0.6 h at 900, 950, 1000, 1050 and 1100 °C followed by forced air cooling is conducted as an alternative to continuous annealing requiring austenitization for longer period of 4–6 h at the said temperatures followed by furnace cooling. Continuous austenitization destabilizes the austenite matrix through precipitation of secondary carbides and transforms the alloy depleted austenite to pearlite on furnace cooling, thereby reducing the as-cast hardness from HV 669 to HV466. In contrast, repeated austenitization not only destabilizes the austenite matrix through precipitation of secondary carbides followed by its transformation to martensite on forced air cooling, but also causes disintegration of longer eutectic carbides to shorter segments with subsequent increase in hardness to as high as HV 890. Notched impact toughness after both continuous and cyclic annealing remains uniformly at 12.0 J as compared to as-cast value of 6.0 J. Besides, an unexpected rise in abrasive wear resistance after cyclic annealing treatment makes the alloy superior than that obtained by continuous annealing treatment as practiced in industries.
使20wt的铸态组织失稳。%铬白口铁,在900、950、1000、1050和1100℃下重复奥氏体化0.6 h的短时间循环退火,然后进行强制风冷,作为在上述温度下需要奥氏体化4-6 h的长时间连续退火,然后进行炉冷。连续奥氏体化通过次生碳化物的析出破坏奥氏体基体的稳定性,使合金贫奥氏体在炉内冷却时转变为珠光体,从而使铸态硬度从hv669降低到HV466。相反,反复奥氏体化不仅使奥氏体基体析出次生碳化物,并在强制空冷条件下转变为马氏体,使基体不稳定,而且使较长的共晶碳化物崩解成较短的段,硬度随之提高到HV 890。连续退火和循环退火后的缺口冲击韧性均保持在12.0 J,而铸态时的缺口冲击韧性为6.0 J。此外,循环退火处理后的磨料耐磨性意外提高,使合金优于工业上使用的连续退火处理。
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引用次数: 1
Analyses of multi-size particle mixing behavior in an ore pre-reduction rotary kiln by discrete element method 用离散元法分析矿石预还原回转窑中多粒径颗粒混合行为
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-06-17 DOI: 10.1051/metal/2021038
Chenghong Liu, Xueyong Ding
The particle distribution in pre-reduction rotary kiln directly affects the reduction process of iron ore, and in-depth understanding of the mixing behavior is helpful to improve the product quality and productivity. The present work focused on the mixed dynamics of multi-component and multi-size systems in rotary kiln using discrete element method (DEM). We first confirmed that the final particle distribution and mixing degree are independent of the initial particle distribution, and then further discussed the influence of the key operating parameters such as rotating speed, average size ratio and filling degree on mixing behavior. The size segregation pattern of three components shows that the large particles segregated to the outer region, while the small particles were concentrated in the core region, forming an annular distribution with different particle sizes. Furthermore, the results also indicate that the rotational speed and fill degree show strong influence on the mixing time and have little influence on the mixing quality. Conversely, the average size ratio significantly affects on the mixing quality. The particle segregation is suppressed and the coal and iron ore particles are well mixed together for the whole bed when the average size of coal particles is smaller than that of iron ore particle. The findings of this work provide a reference for controlling and optimizing the particle mixing process in pre-reduction rotary kiln.
预还原回转窑中的颗粒分布直接影响铁矿石的还原过程,深入了解其混合行为有助于提高产品质量和生产率。本文采用离散元法研究了回转窑多部件、多尺寸系统的混合动力学问题。首先确定了最终颗粒分布和混合程度与初始颗粒分布无关,然后进一步讨论了转速、平均粒度比和填充度等关键操作参数对混合行为的影响。三组分的粒径偏析规律表明,大颗粒向外区偏析,小颗粒向核心区集中,形成不同粒径的环形分布。转速和填充度对搅拌时间影响较大,对搅拌质量影响较小。相反,平均粒度比对混合质量有显著影响。当煤颗粒的平均粒径小于铁矿颗粒的平均粒径时,颗粒偏析被抑制,煤与铁矿颗粒在整个床层内混合良好。研究结果可为预还原回转窑颗粒混合过程的控制和优化提供参考。
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引用次数: 0
Improvement of carbon segregation in cast bloom and heredity in hot-rolled bar 改进铸坯碳偏析及热轧棒材的遗传
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021072
Mengyun Zhang, Y. Bao, Li-hua Zhao, Xin Li
In this study, the effect of mechanical soft reduction on carbon segregation in the continuous casting of 300 × 400 mm 42CrMo alloy structural steel blooms was comparatively investigated by adjusting the casting speed, which was systematically optimized through numerical simulation. When the casting speed is 0.60 m · min−1, during the soft reduction process, the central solidification structure of the bloom becomes dense, and carbon segregation is improved. Moreover, the distribution of carbon in the samples before and after rolling was analyzed. Combined with the soft reduction process, the uniformity of carbon across the cross section of the bloom /bar distinctly improved for casting speeds of 0.50 m · min−1, 0.55 m · min−1 and 0.60 m · min−1, this was predominantly reflected in the core areas. The effective segregation length proportion of the bloom and rolled bar is approximately 40%. This phenomenon fully verifies the heredity characteristics of the elements in the rolling process.
本研究通过数值模拟系统优化了300 × 400 mm 42CrMo合金结构钢坯的铸造速度,比较研究了机械软还原对铸坯中碳偏析的影响。当浇注速度为0.60 m·min−1时,软还原过程中坯体中心凝固组织致密,碳偏析得到改善。并对轧制前后样品中的碳分布进行了分析。结合软还原工艺,浇注速度为0.50 m·min - 1、0.55 m·min - 1和0.60 m·min - 1时,坯棒截面上碳的均匀性明显改善,主要体现在芯区。坯与轧制棒材的有效偏析长度比例约为40%。这一现象充分验证了轧制过程中各元素的遗传特性。
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引用次数: 2
Influence of lithium amount on vitreous enamel properties 锂用量对玻璃体釉质性能的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021028
A. M. Erayvaz, E. Derun
Lithium is the lightest of all metals and the third element in the periodic table. Recent years, lithium salts have become an important input for the energy industry. Lithium carbonate and hydroxides are the basic building blocks of Li-ion battery production. The usage areas of lithium compounds are not limited to only energy; they are also utilized in heavy-duty machines, in the aluminum industry, in nuclear power plants and for glass, ceramics, frit, and coatings in industrial sectors. Lithium has also been found to be very useful in the development of harder, smoother, and more resistant low-temperature glasses, glazes, and enamels. It is also used in very-low-melting-point vitreous compositions like aluminum enamels, colors, fluxes, and glass-seals. The use of lithium also helps in the development of low-expansion bodies, glazes, and glasses. In this study, it is intended to explore the adherence forces in the steel sheet application of different amounts of lithium in enamel frit composition and to examine surface characteristics such as ease of cleaning, gloss, and color. For chemical characterization, X-ray fluorescence (XRF) spectrometry and color measurements were done with a Minolta CM-700d spectrometer device. Bond adherence tests were performed in accordance with the TS EN 10209 standard.
锂是所有金属中最轻的,也是元素周期表中的第三个元素。近年来,锂盐已成为能源工业的重要投入品。碳酸锂和氢氧化物是锂离子电池生产的基本组成部分。锂化合物的使用领域不仅限于能源;它们还用于重型机械,铝工业,核电站以及工业部门的玻璃,陶瓷,水果和涂料。锂也被发现在开发更硬、更光滑、更耐低温的玻璃、釉料和搪瓷方面非常有用。它也用于非常低熔点的玻璃组合物,如铝搪瓷,颜色,助焊剂和玻璃密封件。锂的使用也有助于低膨胀体、釉料和玻璃的开发。在本研究中,旨在探讨不同数量的锂在搪瓷熔块成分中对钢板的粘附力的影响,并研究表面特性,如易于清洁,光泽度和颜色。为了进行化学表征,使用美能达CM-700d光谱仪进行x射线荧光(XRF)光谱和颜色测量。粘接测试按照TS EN 10209标准进行。
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引用次数: 0
Mean field model of phase transformations in steels during cooling, which predicts evolution of carbon concentration in the austenite 钢在冷却过程中相变的平均场模型,该模型预测了奥氏体中碳浓度的演变
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021046
D. Bachniak, R. Kuziak, D. Szeliga, M. Pietrzyk
The objectives of the paper were twofold. The first was exploring possibility of fast and reliable modelling of phase transformations during cooling of steels, accounting for the evolution of the carbon concentration in the austenite. Existing discrete models require long computing times and their application to optimization of industrial processes is limited. Therefore, a model based on the modified JMAK equation was proposed. Control of the carbon concentration in the austenite during ferritic and bainitic transformations allowed to predict incomplete austenite transformation and occurrence of the retained austenite. Moreover, prediction of the onset of pearlitic transformation after the bainitic was possible. The model was validated by comparison the predictions with the results of physical simulations. Numerical simulations for various industrial processes were performed. Problem of the difference in the incubation time between isothermal and constant cooling rate tests was raised.
这篇论文的目的是双重的。首先是探索在钢冷却过程中快速可靠地建立相变模型的可能性,以解释奥氏体中碳浓度的演变。现有的离散模型需要较长的计算时间,在工业过程优化中的应用受到限制。因此,提出了一种基于修正的JMAK方程的模型。控制铁素体和贝氏体转变过程中奥氏体中的碳浓度可以预测奥氏体的不完全转变和残余奥氏体的出现。此外,还可以预测贝氏体转变后珠光体转变的开始。通过将预测结果与物理模拟结果进行比较,验证了模型的有效性。对各种工业过程进行了数值模拟。提出了等温试验和恒冷速试验孵育时间差异的问题。
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引用次数: 4
Sandwich materials with a crumpled aluminium core 具有皱巴巴的铝芯的夹心材料
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021014
O. Bouaziz, Rabeb Bouafif, Roxanne Massion
Sandwich materials made of two aluminum sheets and a crumpled aluminum core have been manufactured for the first time using a reproducible process. This very specific core aims to drastically improve the elasticity performance indexes of the sandwich. The structure has been studied mainly in bending.
由两块铝板和一个皱褶的铝芯制成的夹心材料首次使用可重复的工艺制造出来。这个非常具体的核心旨在大幅提高三明治的弹性性能指标。对该结构进行了主要的弯曲研究。
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引用次数: 4
Modeling of supersonic jet behavior in the vacuum refining process 真空精炼过程中超音速射流行为的建模
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021004
Zhonghua Sheng, Lianghua Feng, Kun Liu, Bin Yang, Kong Lingzhong
There are two problems to be solved in the numerical simulation of the top blown oxygen vacuum refining process. (1) The two-equation turbulence models underpredict the turbulence mixing shear process for high-temperature gradient jet flows. (2) The high compressibility of the jet in a low vacuum environment. In this study, the SST k-ω turbulence model is modified by the composite function of the compressibility factor and the total temperature gradient. Based on the experimental model of the Kotani vacuum jet, the modified turbulence model was used to simulate the supersonic jet behavior of oxygen lance at different ambient temperatures. The reliability of the model is verified by the semi-empirical formula of Ito and Muchi. The simulation results show that the entrainment rate is an important inducing factor. The potential core length and the supersonic core length at the temperature of 1800 K are 2.5 times and 2.0 times that at the temperature of 285 K, respectively. Besides, based on the ejection model established by Ricou and Spalding, the calculation formula of turbulence entrainment rate at different ambient temperatures is obtained. This research work will benefit greatly to the supersonic jet behavior in Vacuum Refining.
顶吹氧气真空精炼过程的数值模拟需要解决两个问题。(1)双方程湍流模型低估了高温梯度射流的湍流混合剪切过程。(2)射流在低真空环境下的高压缩性。本文采用压缩系数和总温度梯度的复合函数对海表温度k-ω湍流模型进行了修正。在小谷真空射流实验模型的基础上,采用改进的湍流模型模拟了不同环境温度下氧枪的超音速射流行为。用Ito和Muchi的半经验公式验证了模型的可靠性。仿真结果表明,夹带率是一个重要的诱导因素。在1800 K温度下,电势核长度和超音速核长度分别是285 K温度下的2.5倍和2.0倍。此外,基于Ricou和Spalding建立的弹射模型,得到了不同环境温度下湍流夹带率的计算公式。该研究对真空精炼过程中超音速射流的性能研究具有重要意义。
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引用次数: 1
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Metallurgical Research & Technology
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