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Effect of rare earth on inclusion evolution in industrial production of HRB500E steel 稀土对HRB500E钢工业生产中夹杂物演化的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021022
Jian Kang, Yan-chong Yu, Zhang Jinling, Chao Chen, She-bin Wang
The effect of rare earth (RE) on inclusion in HRB500E steel was studied based on plant trials. The results showed that S decreased by 47.6% after 0.0059% RE treatment. In samples without RE treatment, the inclusions change from Al2O3-MnO to ellipsoidal Al2O3-MnO-CaO complex inclusion, and the size of such inclusions is ≤ 2 µm and isolated strip MnS inclusion with the size of ≥ 2 µm. With RE treatment, Al2O3-MnO-CaO inclusions are transformed into spherical or ellipsoidal REAlO3 and REAlO3-MnS. The size of such inclusions is ≈ 1.5 µm and single MnS inclusions were not found. The number density and size of inclusions changed significantly after RE treatment. Thermodynamic calculations show that the Gibbs free energy of RE inclusions is more negative and more stable. The transformation model of inclusions is established to illustrate the modification of inclusions during the smelting process.
通过现场试验,研究了稀土对HRB500E钢夹杂物的影响。结果表明:0.0059% RE处理后S降低47.6%;在未进行RE处理的样品中,包裹体由Al2O3-MnO变为椭圆形Al2O3-MnO- cao络合物包裹体,包裹体尺寸≤2µm,孤立条形MnS包裹体尺寸≥2µm。稀土处理后,Al2O3-MnO-CaO包裹体转变为球形或椭球状的REAlO3和REAlO3- mns。这些包裹体的尺寸为≈1.5µm,未发现单个MnS包裹体。稀土处理后,夹杂物的数量、密度和大小发生了显著变化。热力学计算表明,稀土包裹体的吉布斯自由能更负且更稳定。为了说明熔炼过程中夹杂物的变化,建立了夹杂物的转化模型。
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引用次数: 5
Enhancement of boron removal from metallurgical-grade silicon by titanium addition during slag refining 渣精炼过程中加入钛对冶金级硅除硼的促进作用
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021085
Ya-qiong Li, Lifeng Zhang, Ligang Liu
The effects of titanium addition (0 wt.%, 0.2 wt.%, and 0.5 wt.%) on the boron removal from metallurgical-grade silicon during slag refining have been studied. According to the findings, the addition of Ti improved the removal of 92.5 wt.% B with 0.5 wt.% Ti addition compared to 79.4 wt.% B removal without Ti addition. Furthermore, acid leaching reduced excess Ti to 27 ppmw.
添加钛(0 wt。%, 0.2 wt。研究了矿渣精炼过程中冶金级硅中硼的去除效果(%和0.5 wt.%)。结果表明,Ti的加入提高了92.5 wt的去除率。% B, 0.5 wt。% Ti添加量与79.4 wt相比。不加Ti的% B去除率。此外,酸浸将过量钛降低到27 ppmw。
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引用次数: 0
Recent advances of silicon wafer cutting technology for photovoltaic industry 光伏产业硅片切割技术的最新进展
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021091
Chang-yong Chen, Meng Sun, Xiao-qing Chen, Yi Wang, Zhouhua Jiang, Jianan Zhou
Using ultra-fine wire saw to cut solar grade silicon wafer is a very precise technology. In the past 20 years, researchers have done a lot of research and made great progress. The cutting method of silicon rod has developed from single line cutting to multi line simultaneous cutting, which greatly improves the production efficiency and the yield of silicon rod. However, the problems of high cutting loss, low cutting efficiency, and large surface damage of silicon wafer need to be solved; The surface of wire saw line has developed from smooth surface to coated diamond abrasive, which greatly improves the service life of wire saw line; The method of coated diamond abrasive on the surface of wire saw line has developed from resin consolidation to electroplating consolidation, which greatly improves the service life of wire saw line it improves the firmness of the coating; The arrangement of wire saw wire has developed from single wire to multi wire stranding, which makes the wire saw wire can cut large-size silicon rod; The minimum thickness of silicon wafer that can be cut is about 100–140 µm according to the perspective of stress analysis, while the excetive value should be located by more research.
使用超细线锯切割太阳能级硅片是一项非常精密的技术。在过去的20年里,研究人员做了大量的研究,取得了很大的进展。硅棒的切割方法从单线切割发展到多线同时切割,大大提高了硅棒的生产效率和成品率。但是,硅片切割损耗高、切割效率低、表面损伤大等问题需要解决;线锯线表面由光滑表面发展到涂覆金刚石磨料,大大提高了线锯线的使用寿命;金刚石磨料在线锯线表面涂覆的方法已从树脂固结发展到电镀固结,大大提高了线锯线的使用寿命,提高了涂层的牢固度;线锯线的排列方式由单线发展到多线绞合,使得线锯线可以切割大尺寸硅棒;从应力分析的角度来看,可切割硅片的最小厚度约为100-140µm,其执行值需进一步研究确定。
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引用次数: 1
Identification of crystal plasticity parameters for a non-irradiated and irradiated A508 bainite steel 未辐照和辐照A508贝氏体钢晶体塑性参数的确定
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021006
C. Nguyen, G. Cailletaud, F. Barbe, B. Marini, D. Nguyen, H. Phan
This paper presents the identification of dislocation-density-based crystal plasticity parameters for a A508 Cl3 bainite steel in non-irradiated and irradiated states and at different temperatures. The representative volume element for the identification process is a cube containing 1000 steel grains represented by a Voronoi mosaic discretized by finite elements. The grains are assigned crystallographic orientations corresponding to an isotropic texture. The crystal constitutive model is based on a plastic flow law, a hardening law, and a law of evolution of dislocation densities. Modeling parameters are determined by a two-step calculation with two different crystal structures: (1) using a simple structure with 343 identical grains to identify 7 parameters, (2) using a Voronoi tessellation of 1000 grains to refine the parameters. Thereafter, the calculated stress-strain curves are compared with experimental stress-strain curves. The results show that the simulated stress-strain curves are in good agreement with those of experiments, highlighting the reliability of the proposed procedure to account for the significant effects of irradiation and temperature.
本文研究了a508cl3贝氏体钢在未辐照和辐照状态及不同温度下的位错密度晶体塑性参数的确定。识别过程的代表性体积单元是一个包含1000个钢粒的立方体,由有限元离散的Voronoi马赛克表示。晶粒被指定为与各向同性织构相对应的晶体取向。晶体本构模型基于塑性流动规律、硬化规律和位错密度演化规律。建模参数通过两种不同晶体结构的两步计算确定:(1)使用具有343个相同晶粒的简单结构识别7个参数,(2)使用1000个晶粒的Voronoi镶嵌来细化参数。然后,将计算得到的应力-应变曲线与实验得到的应力-应变曲线进行对比。结果表明,模拟的应力-应变曲线与实验结果吻合较好,突出了所提出的程序在考虑辐照和温度显著影响时的可靠性。
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引用次数: 1
Effect of tool pin geometry on microstructure and mechanical properties of friction stir spot welds of 7075-T651 aluminium alloy 刀销几何形状对7075-T651铝合金搅拌摩擦点焊组织和力学性能的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2020093
O. Ekinci, Z. Balalan
7075-T651 aluminium alloy sheets were overlapped and friction stir spot welded using two welding tools having different pin geometries (one with a conical pin and other with a triangular pin) and 800, 1200 and 1600 revolution per minute (rpm) tool rotation speeds at a constant tool plunge and removal speed of 7.3 mm/min, tool plunge depth of 3.8 mm and tool dwell time of 5 s. Microstructure, Vickers microhardness, tensile shear strength, fracture surface after tensile shear test and impact energy of the produced friction stir spot welds were examined. As a result, the welds made via triangular pin tool had considerably higher tensile shear loads than the welds made via conical pin tool since the weld bond widths (stir zones) of the welds made via triangular pin tool were larger. The strongest welds made at 1200 rpm for conical pin tool and triangular pin tool. The tensile shear loads of the welds increased significantly when tool rotation speed increased from 800 to 1200 rpm for both welding tools and then decreased slightly for triangular pin tool and dramatically for conical pin tool with further increasing tool rotation speed from 1200 to 1600 rpm. Maximum tensile shear load of 7.776 kN and impact energy of 16 J obtained in the weld made at 1200 rpm using triangular pin tool. The welds made at 800 rpm had lowest impact energy. The lowest hardness values found in the heat affected zones of the welds. Circumferential fracture mode for conical pin tool welds and nugget pull-out fracture mode for triangular pin tool welds observed after tensile tests.
7075-T651铝合金板材采用两种不同销形(一种为锥形销,另一种为三角形销)、800、1200和1600转/分钟(rpm)的焊接工具进行重叠和搅拌摩擦点焊,刀具的恒定插入和取出速度为7.3 mm/min,刀具插入深度为3.8 mm,刀具停留时间为5 s。对所制备的搅拌摩擦点焊的显微组织、维氏显微硬度、拉伸剪切强度、拉伸剪切后断口形貌及冲击能进行了检测。结果表明,由于三角形销工具焊接焊缝的焊缝结合宽度(搅拌区)更大,三角形销工具焊接焊缝的拉伸剪切载荷明显高于锥形销工具焊接焊缝。锥形销工具和三角形销工具的最强焊接速度为1200转/分。当刀具转速从800转/分增加到1200转/分时,两种焊接工具的焊缝拉伸剪切载荷均显著增加,当刀具转速从1200转/分进一步增加到1600转/分时,三角形销工具的焊缝拉伸剪切载荷略有下降,锥形销工具的焊缝拉伸剪切载荷显著下降。使用三角销工具在1200转/分速度下焊接时获得的最大拉伸剪切载荷为7.776 kN,冲击能为16 J。在800转/分的速度下焊接的冲击能量最低。在焊缝的热影响区发现的最低硬度值。拉伸试验观察到锥形销工具焊缝的周向断裂模式和三角形销工具焊缝的核块拉出断裂模式。
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引用次数: 1
Sensitivity analysis, identification and validation of the dislocation density-based model for metallic materials 基于位错密度的金属材料模型的灵敏度分析、识别与验证
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021037
D. Szeliga, Natalia Czyżewska, Konrad Klimczak, J. Kusiak, Pawel M. Morkisz, P. Oprocha, M. Pietrzyk, Paweł Przybyłowicz
Microstructure evolution model based on the differential equation describing evolution of dislocations was proposed. Sensitivity analysis was performed and parameters with the strongest influence on the output of the model were revealed. Identification of the model coefficients was performed for various metallic materials using inverse analysis for experimental data. The model was implemented in the finite element code and simulations of various hot forming processes were performed.
提出了基于位错演化微分方程的微观组织演化模型。进行敏感性分析,找出对模型输出影响最大的参数。通过对实验数据的逆分析,确定了不同金属材料的模型系数。在有限元程序中实现了该模型,并对各种热成形过程进行了仿真。
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引用次数: 4
An investigation on electrical discharge metal matrix coating of ZE41A magnesium alloy ZE41A镁合金放电金属基体涂层的研究
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021034
U. Elaiyarasan, V. Satheeshkumar, C. Senthilkumar
The present paper studied the experimental investigation on electrical discharge coating of ZE41A magnesium alloy (EDC) with tungsten carbide-copper (WC/Cu) powder metallurgy (PM) electrode. In order to attain the surface characteristics, three parameters were selected such as compaction load, current and pulse on time. Response characteristics such as material transfer rate (MTR) and surface roughness (Ra) were considered in this study. Central composite design in response surface methodology was applied to conduct experiments. Empirical models were developed for MTR and SR. AVOVA test was conducted to identify the most influence parameters. Additionally, optimized parameters were identified by response surface optimizer. It is observed that the current play a vital role in increasing the MTR and minimize the SR of the coated surface followed by compaction load and pulse on time. Various studies such as scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were carried out on the coated surface. Bulk mass deposition and bigger craters were observed in the surface coated with 150 MPa and 3A respectively.
采用碳化钨-铜(WC/Cu)粉末冶金(PM)电极对ZE41A镁合金(EDC)进行了放电涂层的实验研究。为了获得表面特性,选取了压实载荷、电流和脉冲接通时间三个参数。响应特性,如材料传输速率(MTR)和表面粗糙度(Ra)在本研究中被考虑。采用响应面法中的中心复合设计进行试验。建立了MTR和sr的实证模型,并进行了AVOVA检验,以确定影响最大的参数。利用响应面优化器对优化参数进行了辨识。结果表明,电流对提高涂层表面的MTR和减小涂层表面的SR起着至关重要的作用,其次是压实载荷和脉冲准时。对涂层表面进行了扫描电镜(SEM)和能谱分析(EDS)等研究。在150mpa和3A的涂层表面分别观察到大量的物质沉积和较大的陨石坑。
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引用次数: 5
Coal macerals and their separation methodologies – A review 煤矿物及其分离方法。综述
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021023
D. Nag, Govind Dubey, P. S. Dash, S. Mohapatra
Macerals are microscopically recognizable organic entities found in coal. On the basis of their optical properties they are classified into three categories, liptinite, vitrinite, and inertinite. Reactive macerals, Vitrinite and liptinite, are responsible for the thermoplastic nature of coal during coke formation. It is also found that these macerals can be used for making some high valued products such as carbon fiber, BTX, liquefaction and gasification feedstock. There are various methods applied by different researchers for coal maceral separation method. This review aims to discuss the various properties of coal macerals and the different methodologies adopted for their separation.
矿物是在煤中发现的微观可识别的有机实体。根据其光学性质,可将其分为三大类:脂质组、镜质组和惰质组。反应性显微物质,镜质组和脂质组,在焦炭形成过程中对煤的热塑性性质负责。还发现这些矿物可用于制造碳纤维、BTX、液化和气化原料等高附加值产品。不同的研究者采用了不同的方法进行煤显微分选。本文综述了煤矿物的各种性质以及分离煤矿物的不同方法。
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引用次数: 7
Parametric effect on material removal rate and surface roughness of electrical discharge machined magnesium alloy 参数对电火花加工镁合金材料去除率和表面粗糙度的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/metal/2021089
Narayanasamy Ananthi, U. Elaiyarasan, V. Satheeshkumar, C. Senthilkumar, S. Sathiyamurthy, K. Nallathambi
Magnesium and its alloys play a vital role in various applications such as automobile, aircraft, biomedical and military etc. Mg alloys have superior characteristics such as light weight, high strength, good damping capacity and easily castability etc. Eventhough it has attractive range of properties, the machining of magnesium alloys using conventional machining methods is difficult. To overcome that issue, non traditional machining is considered as a potential process. EDM is an electro thermal process extensively used for machining hard materials. In this investigation, the ZE41A magnesium alloy is machined using EDM with copper electrode. In order to improve surface characteristics such as material removal rate (MRR) and surface roughness (SR), various parameters namely current, pulse on time and pulse off time were selected. The regression values of MRR and SR are 97.20% and 99.62% respectively indicating an empirical relationship between the parameters and responses. Pulse off time was found as a significant parameter on the response followed by pulse on time and current. MRR and SR increased with increasing current, pulse on time and pulse off time. At a current of 5A, the produced spark density is high so that the removed quantity of material from the workpiece is high. At a pulse on time of 95 μs, the spark intensity is high affecting the local temperature in the machined zone, and hence MRR increases. SR drastically increases at increasing current. At higher current, large size crater are observed on the machined surface that made the surface rough, and hence SR increases.
镁及其合金在汽车、飞机、生物医学和军事等领域发挥着重要作用。镁合金具有重量轻、强度高、阻尼性能好、易铸造等优点。尽管镁合金具有一系列吸引人的性能,但用传统的加工方法加工镁合金是困难的。为了克服这一问题,非传统加工被认为是一种潜在的加工方法。电火花加工是一种广泛用于加工硬质材料的电热加工方法。在本研究中,采用铜电极电火花加工ZE41A镁合金。为了提高材料去除率(MRR)和表面粗糙度(SR)等表面特性,选择了电流、脉冲导通时间和脉冲关断时间等参数。MRR和SR的回归值分别为97.20%和99.62%,表明参数与响应之间存在经验关系。脉冲关闭时间是影响响应的重要参数,其次是脉冲关闭时间和电流。MRR和SR随电流、脉冲导通时间和脉冲关断时间的增大而增大。在5A的电流下,产生的火花密度很高,因此从工件上去除的材料量很高。脉冲开启时间为95 μs时,火花强度高,影响加工区域局部温度,MRR增大。随着电流的增大,SR急剧增大。在较大的电流下,在加工表面上观察到大尺寸的凹坑,使表面粗糙,因此SR增加。
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引用次数: 0
Impurity removal from brass alloy by slag refining treatment 炉渣精炼法去除黄铜合金杂质
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.1051/METAL/2021017
Ya-qiong Li, Lifeng Zhang, Xinyu Cai, Ying Zhang, Ligang Liu, Zhen-Hua Zhao
Impurity removal from Cu-Zn (brass) alloy is an important issue for copper feedstock production. This study investigated brass alloy purification through the slag refining process using two kinds of agents, namely Cu2 O and ZnO. The results showed that using ZnO as the slag to purify brass alloy for 1 h can remove impurities, such as Al, Pb, Fe, Ca, and Si, among which the removal efficiencies of Si reached to 60%. After the ZnO slag refining, the Zn loss ratio was only approximately 2%; thus, the brass alloy composition remained stable. The slag refining process using ZnO-contained slag did not only realize brass purification, but also maintained the brass composition stability.
铜锌(黄铜)合金中杂质的去除是铜原料生产中的一个重要问题。本研究采用氧化铜和氧化锌两种助剂对铜合金进行渣精炼工艺提纯。结果表明,以ZnO为渣净化黄铜合金1 h,可以去除Al、Pb、Fe、Ca、Si等杂质,其中Si的去除率达到60%。ZnO渣精炼后,锌损失率仅为2%左右;因此,黄铜合金成分保持稳定。采用含锌炉渣精炼工艺,既实现了黄铜的提纯,又保持了黄铜成分的稳定。
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引用次数: 6
期刊
Metallurgical Research & Technology
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