Nanomaterials最新文献

Lead (Pb) is a highly toxic heavy metal that causes significant health hazards and environmental damage. Thus, the detection and removal of Pb²⁺ ions in freshwater sources are imperative for safeguarding public health and the environment. Moreover, the transformation of single resources into multiple high-value products is vital for achieving sustainable development goals (SDGs). In this regard, the present work focused on the preparation of two efficient materials, i.e., biochar (R-BC) and carbon dots (R-CDs) from a single resource (rice straw), via a novel approach by using extraction and hydrothermal process. The various microscopic and spectroscopy techniques confirmed the formation of porous structure and spherical morphology of R-BC and R-CDs, respectively. FTIR analysis confirmed the presence of hydroxyl (-OH), carboxyl (-COO) and amine (N-H) groups on the R-CDs' surface. The obtained blue luminescent R-CDs were employed as chemosensors for the detection of Pb²⁺ ions. The sensor exhibited a strong linear correlation over a concentration range of 1 µM to 100 µM, with a limit of detection (LOD) of 0.11 µM. Furthermore, the BET analysis of R-BC indicated a surface area of 1.71 m²/g and a monolayer volume of 0.0081 cm³/g, supporting its adsorption potential for Pb²⁺. The R-BC showed excellent removal efficiency of 77.61%. The adsorption process followed the Langmuir isotherm model and second-order kinetics. Therefore, the dual use of rice straw-derived provides a cost-effective, environmentally friendly solution for Pb²⁺ detection and remediation to accomplish the SDGs.

This study explored the influence of graphene oxide (GO) on morphological and mechanical properties of Nafion^® 115 membranes with the objective of enhancing the mechanical properties of the most widely employed membrane in Proton Exchange Membrane Water Electrolyzers (PEMWE) applications. The membrane surface was modified by ultrasonically spraying a GO solution and different annealing temperatures were tested. Scanning Electron Microscopy (SEM) cross-sectional images revealed that annealing the composite membranes was sufficient to favor an interaction between the graphene oxide and the surface of the Nafion^® membranes. The GO covering only 35% of the membrane surface increased the composite's wettability from hydrophobic (105.2°) to a highly hydrophilic angle (84.4°) while slightly reducing membrane swelling. Tensile tests depicted an increase in both the strain levels and tensile loads before breaking. The samples with GO presented remarkable mechanical properties when the annealing time and temperature increased; while the Nafion^® control samples failed at elongations of 95% and 98%, their counterparts with GO on the surface achieved elongations of 248% and 191% when annealed at 80 °C and 110 °C respectively, demonstrating that the presence of GO mechanically stabilizes the membranes under tension. In exchange, the presence of GO altered the smoothness of the membrane surface going from an average 1.4 nm before the printing to values ranging from 8.4 to 10.2 nm depending on the annealing conditions which could affect the quality of the subsequent catalyst layer printing. Overall, the polymer's electrical insulation was unaffected, making the Nafion^®-GO blend a more robust material than those traditionally used.

The spread of multidrug-resistant microbes has made it necessary and urgent to develop new strategies to deal with the infections they cause. Some of these are based on nanotechnology, which has revolutionized many fields in medicine. Evaluating the safety and efficacy of these new antimicrobial strategies requires testing in animal models before being tested in clinical trials. In this context, Galleria mellonella could represent a valid alternative to traditional mammalian and non-mammalian animal models, due to its low cost, ease of handling, and valuable biological properties to investigate host-pathogen interactions. The purpose of this review is to provide an updated overview of the literature concerning the use of G. mellonella larvae as an animal model to evaluate safety and efficacy of nanoparticles and nanomaterials, particularly, of those that are used or are under investigation to combat microbial pathogens.

This study presents a novel reflective fiber Fabry-Perot (F-P) salinity sensor. The sensor employs a femtosecond laser to fabricate an open liquid cavity, facilitating the unobstructed ingress and egress of the liquid, thereby enabling the direct involvement of the liquid in light transmission. Variations in the refractive index of the liquid induce corresponding changes in the effective refractive index of the optical path, which subsequently influences the output spectrum. The dimensions and quality of the optical fiber are meticulously regulated through a combination of femtosecond laser cutting and chemical polishing, significantly enhancing the mechanical strength and sensitivity of the sensor's overall structure. Experimental results indicate that the sensor achieves salinity sensitivity of 0.288 nm/% within a salinity range of 0% to 25%. Furthermore, the temperature sensitivity is measured at a minimal 0.015 nm/°C, allowing us to neglect temperature effects. The device is characterized by its compact size, straightforward structure, high mechanical robustness, ease of production, and excellent reproducibility. It demonstrates considerable potential for sensing applications in the domains of biomedicine and chemical engineering.

Cancer diagnostics often faces challenges, such as invasiveness, high costs, and limited sensitivity for early detection, emphasizing the need for improved approaches. We present a surface-enhanced Raman scattering (SERS)-based platform leveraging inverted pyramid SU-8 nanostructured substrates fabricated via nanoimprint lithography. These substrates, characterized by sharp apices and edges, are further functionalized with (3-aminopropyl)triethoxysilane (APTES), enabling the uniform self-assembly of AuNPs to create a highly favorable configuration for enhanced SERS analysis. Performance testing of the substrates using malachite green (MG) as a model analyte demonstrated excellent detection capabilities, achieving a limit of detection as low as 10^-12 M. Building on these results, the SERS platform was adapted for the sensitive and specific detection of hyaluronic acid (HA), a key biomarker associated with inflammation and cancer progression. The system employs a sandwich immunoassay configuration, with substrates functionalized with antibodies to capture HA molecules and 4-MBA-labeled SERS tags for detection. This setup achieved an ultra-sensitive detection limit of 10^-11 g/mL for HA. Comprehensive characterization confirmed the uniformity and reproducibility of the SERS substrates, while validation in complex biological matrices demonstrated their robustness and reliability, highlighting their potential in cancer diagnostics and biomarker detection.

This paper investigates the thermal effects in fused-tapered passive optical fibers under near-infrared absorption. The thermal effect is primarily caused by impurities, such as OH-, which absorb incident light and generate heat. Using the finite element method, the volume changes during fiber tapering were simulated, influencing power density and thermal distribution. The heat conduction equation and ray optics were employed to analyze the thermal distribution in tapered fibers and signal combiners. Results show that at 5 kW power, the temperature peak for a single fiber reaches 316.73 °C, while for bundled fibers, the temperature rises significantly as the bundle configuration increases from 7 × 1 to 61 × 1, peaking at 453.09 °C-an increase of 171.6%. Variations in tapering ratio and length also notably affect the thermal behavior. Increasing the tapering ratio from 5 to 8 results in a 52.5% temperature rise, while doubling the taper length from 25 mm to 50 mm reduces the temperature peak by 59.1%. These findings offer important insights for the design and optimization of high-power optical fiber combiners and their heat dissipation structures.

Heavy metals are life-threatening pollutions because of their great toxicity, long-term persistence in nature and their bioaccumulation in living organisms. In this work, we performed multivariate curve resolution-alternating least squares analysis of UV-Vis raw spectra received by a colorimetric sensor constructed on mercaptoundecanoic acid functionalized silver nanoparticles (AgNPs@11MUA) to detect Cd²⁺, Cu²⁺, Mn²⁺, Ni²⁺, and Zn²⁺ in water. This combined approach allowed the rapid identification and quantification of multiple heavy metals and showed adequate sensitivity and selectivity, thus representing a promising analytical and computational method for both laboratory and field applications such as environmental safety and public health monitoring.

Developing switchable and multifunctional metasurfaces is essential for high-integration photonics. However, most previous studies encountered challenges such as limited degrees of freedom, simple tuning of predefined functionality, and complicated control systems. Here, we develop a general strategy to construct switchable and multifunctional metasurfaces. Two spin-modulated wave-controls are enabled by the proposed high-efficiency metasurface, which is designed using both resonant and geometric phases. Furthermore, the switchable wavefront tailoring can also be achieved by flexibly altering the lattice constant and reforming the phase retardation of the metasurfaces based on the "rotating square" (RS) kirigami technique. As a proof of concept, a kirigami metasurface is designed that successfully demonstrates dynamic controls of three-channel beam steering. In addition, another kirigami metasurface is built for realizing tri-channel complex wavefront engineering, including straight beam focusing, tilted beam focusing, and anomalous reflection. By altering the polarization of input waves as well as transformation states, the functionality of the metadevice can be switched flexibly among three different channels. Microwave experiments show good agreement with full-wave simulations, clearly demonstrating the performance of the metadevices. This strategy exhibits advantages such as flexible control, low cost, and multiple and switchable functionalities, providing a new pathway for achieving switchable wavefront engineering.

Nonlinear optics, a critical branch of modern optics, presents unique potential in the study of two-dimensional (2D) magnetic materials. These materials, characterized by their ultra-thin geometry, long-range magnetic order, and diverse electronic properties, serve as an exceptional platform for exploring nonlinear optical effects. Under strong light fields, 2D magnetic materials exhibit significant nonlinear optical responses, enabling advancements in novel optoelectronic devices. This paper outlines the principles of nonlinear optics and the magnetic structures of 2D materials, reviews recent progress in nonlinear optical studies, including magnetic structure detection and nonlinear optical imaging, and highlights their role in probing magnetic properties by combining second harmonic generation (SHG) and multispectral integration. Finally, we discuss the prospects and challenges for applying nonlinear optics to 2D magnetic materials, emphasizing their potential in next-generation photonic and spintronic devices.

Two porphyrin-based polymeric frameworks, SnP-BTC and SnP-BTB, as visible light photocatalysts for wastewater remediation were prepared by the solvothermal reaction of trans-dihydroxo-[5,15,10,20-tetrakis(phenyl)porphyrinato]tin(IV) (SnP) with 1,3,5-benzenetricarboxylic acid (H₃BTC) and 1,3,5-tris(4-carboxyphenyl)benzene (H₃BTB), respectively. The strong bond between the carboxylic acid group of H₃BTC and H₃BTB with the axial hydroxyl moiety of SnP leads to the formation of highly stable polymeric architectures. Incorporating the carboxylic acid group onto the surface of SnP changes the conformational frameworks as well as produces rigid structural transformation that includes permanent porosity, good thermodynamic stability, interesting morphology, and excellent photocatalytic degradation activity against AM dye and TC antibiotic under visible light irradiation. The photocatalytic degradation activities of AM dye were found to be 95% by SnP-BTB and 87% by SnP-BTC within 80 min. Within 60 min of visible light exposure, the photocatalytic degradation activities of TC antibiotic were found to be 70% by SnP-BTB and 60% by SnP-BTC. The enhanced catalytic photodegradation performances of SnP-BTB and SnP-BTC were attributed to the synergistic effect between SnP and carboxylic acid groups. The carboxylic acid connectors strongly resist the separation of SnP from the surface of SnP-BTB and SnP-BTC during the photodegradation experiments. Therefore, the high degradation rate and low catalyst loading make SnP-BTB or SnP-BTC more efficient than other reported catalysts. Thus, the present investigations on the porphyrin-based photocatalysts hold great promise in tackling the treatment of dyeing wastewater.