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Diffusion mechanisms of fast lithium-ion conductors 快速锂离子导体的扩散机制
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-12 DOI: 10.1038/s41578-024-00715-9
KyuJung Jun, Yu Chen, Grace Wei, Xiaochen Yang, Gerbrand Ceder

The quest for next-generation energy-storage technologies has pivoted towards all-solid-state batteries, primarily owing to their potential for enhanced safety and energy density. At the centre of this promising technology lie inorganic lithium superionic conductors, which facilitate rapid ion transport comparable to that in their liquid counterparts. Despite their promise, the limited availability of materials that both achieve superionic conductivity and fulfil all practical requirements necessitates the discovery of novel conductors. This Review comprehensively explores the diverse structural and chemical factors that improve ionic conductivity and the atomistic mechanism by which each factor affects it. We emphasize the importance of a dual approach: using structural factors to enable high-conducting prototypes, and chemical factors to further optimize the ionic conductivity. From these insights, we distil over 40 years of conductor development history to the key concepts that paved the way for today’s leading superionic conductors. In detailing the trajectory of ionic conduction advancements, this Review not only charts the progress in the field but also proposes a strategic approach for researchers to efficiently innovate with the ultimate goal of realizing the promise of all-solid-state batteries.

人们对下一代储能技术的追求已转向全固态电池,这主要是由于它们具有提高安全性和能量密度的潜力。这项前景广阔的技术的核心是无机锂超离子导体,它能促进离子的快速传输,其传输速度可与液态导体媲美。尽管前景广阔,但既能实现超离子导电性又能满足所有实际要求的材料却十分有限,因此有必要发现新型导体。本综述全面探讨了提高离子导电性的各种结构和化学因素,以及每个因素对其产生影响的原子机制。我们强调双重方法的重要性:利用结构因素实现高导电性原型,利用化学因素进一步优化离子导电性。从这些见解中,我们提炼出了导体 40 多年的发展历史,以及为今天领先的超离子导体铺平道路的关键概念。通过详细介绍离子导体的发展轨迹,本综述不仅描绘了该领域的进展,还为研究人员提出了高效创新的战略方法,最终目标是实现全固态电池的前景。
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引用次数: 0
Towards the holistic design of alloys with large language models 利用大型语言模型实现合金的整体设计
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-12 DOI: 10.1038/s41578-024-00726-6
Zongrui Pei, Junqi Yin, Jörg Neugebauer, Anubhav Jain
Large language models are very effective at solving general tasks, but can also be useful in materials design and extracting and using information from the scientific literature and unstructured corpora. In the domain of alloy design and manufacturing, they can expedite the materials design process and enable the inclusion of holistic criteria.
大型语言模型在解决一般任务方面非常有效,但在材料设计以及从科学文献和非结构化语料库中提取和使用信息方面也很有用。在合金设计和制造领域,大语言模型可以加快材料设计过程,并能够纳入整体标准。
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引用次数: 0
Robots that evolve on demand 按需进化的机器人
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-12 DOI: 10.1038/s41578-024-00711-z
Robert Baines, Frank Fish, Josh Bongard, Rebecca Kramer-Bottiglio

Now more than ever, researchers are rethinking the way robots are designed and controlled — from the algorithms that govern their actions to the very atomic structure of the materials they are made from. In this Perspective, we collect and comment on recent efforts towards multipurpose machines that use shape-morphing materials and components to adapt to changing environments. To frame our discussion, we point out biological adaptation strategies that have been adopted by robots across different sizes and timescales. This contextualization segways into the notion of adaptive morphogenesis, which is formally defined as a design strategy in which adaptive robot morphology and behaviours are realized through unified structural and actuation systems. However, since its introduction, the term has been more colloquially used to describe ‘evolution on demand’. We set out by giving examples of current systems that exhibit adaptive morphogenesis. Then, outlining projected key application areas of adaptive morphogenesis helps to scope the challenges and possibilities on the road to realizing future systems. We conclude by proposing performance metrics for benchmarking this emerging field. With this Perspective, we hope to spur dialogue among materials scientists, roboticists and biologists, and provide an objective lens through which we can analyse progress towards robots with rapidly mutable features that eclipse what is possible in biological processes.

现在,研究人员比以往任何时候都在重新思考机器人的设计和控制方式--从控制机器人行动的算法到机器人材料的原子结构。在本《视角》中,我们收集并评论了最近在多用途机器方面所做的努力,这些机器使用可变形的材料和部件来适应不断变化的环境。为了确定讨论的框架,我们指出了不同大小和时间尺度的机器人所采用的生物适应策略。适应性形态发生被正式定义为一种设计策略,通过统一的结构和执行系统实现机器人的适应性形态和行为。然而,自引入以来,该术语更多地被用来描述 "按需进化"。我们首先举例说明了当前展示自适应形态发生的系统。然后,概述自适应形态发生的预计关键应用领域,以帮助确定实现未来系统道路上的挑战和可能性。最后,我们提出了衡量这一新兴领域的性能指标。我们希望通过这一视角,促进材料科学家、机器人专家和生物学家之间的对话,并提供一个客观的视角,让我们能够分析机器人在实现快速变异功能方面取得的进展。
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引用次数: 0
Atmospheric water vapour as a potential water source and its impact on energy systems 作为潜在水源的大气水蒸气及其对能源系统的影响
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-11 DOI: 10.1038/s41578-024-00727-5
Fredrik Edström, Per Dahlbäck
Atmospheric water vapour, an abundant yet underutilized resource, may hold potential as a new water source but is held back by its high enthalpy of condensation. This property also contributes to a negative feedback loop between cooling systems and greenhouse gases, accelerating global warming.
大气中的水蒸气是一种丰富但未得到充分利用的资源,可能具有作为新水源的潜力,但却因其高凝结焓而受到阻碍。这一特性还造成了冷却系统与温室气体之间的负反馈循环,加速了全球变暖。
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引用次数: 0
Emerging photovoltaics for onboard space applications 用于机载空间应用的新兴光伏技术
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1038/s41578-024-00723-9
Anita Wing Yi Ho-Baillie, Stephen Bremner, Ceri Brenner, Iver H. Cairns, Laura Granados-Caro, Gavin Conibeer, Jasmyn Curry, Nicholas Ekins-Daukes, Douglas Griffin, Tik Lun Leung, Md Arafat Mahmud, David McKenzie, Stefania Peracchi, Santosh Shrestha, David Wilt
Thin-film solar cells are promising for providing cost-effective and reliable power in space, especially in multi-junction applications. To enhance efficiency, robustness and integration, advancements at the cell level must be combined with improvements in assembly and panel design. Ensuring that solar cells can provide sustained performance is also essential for minimizing space debris.
薄膜太阳能电池有望在太空中提供经济、可靠的电力,特别是在多结应用中。为了提高效率、坚固性和集成度,电池层面的进步必须与装配和面板设计的改进相结合。确保太阳能电池能够提供持续的性能,对于最大限度地减少空间碎片也至关重要。
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引用次数: 0
From nitrate to ammonia using high-entropy single-atom nanocages 利用高熵单原子纳米笼从硝酸盐到氨气
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-04 DOI: 10.1038/s41578-024-00724-8
Rita Leones
An article in Nature Communications presents an adaptable and scalable approach to synthesize high-entropy single-atom nanocage catalysts for efficient ammonia electrosynthesis.
自然-通讯》(Nature Communications)上的一篇文章介绍了一种适应性强、可扩展的方法,用于合成高效氨电合成的高熵单原子纳米笼催化剂。
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引用次数: 0
Fishing for uranium 捕捞铀矿
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-02 DOI: 10.1038/s41578-024-00722-w
Ariane Vartanian
An article in the Journal of the American Chemical Society reports porous photocatalytic nanowires that extract record amounts of uranium from seawater, a step closer to tapping the ocean’s vast uranium reserves for nuclear energy.
美国化学学会杂志》上的一篇文章报道,多孔光催化纳米线可从海水中提取创纪录数量的铀,这距离将海洋中的大量铀储备用于核能开发又近了一步。
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引用次数: 0
Performance metrics for shape-morphing devices 成型设备的性能指标
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-02 DOI: 10.1038/s41578-024-00714-w
Jue Wang, Alex Chortos

Shape-morphing devices, with their capacity to undergo structural transformations, are on the verge of revolutionizing multiple domains, from human–machine interfaces to biomedical and aerospace applications. This Perspective classifies shape-morphing devices into two categories: pattern-to-pattern shape-morphing devices that deform from a starting shape to a predefined set of one or more deformed shapes, and programmable shape-morphing devices that can morph into different shapes on demand. We highlight the need for standardized assessment approaches to compare the performance of different shape-morphing devices and introduce an array of proposed metrics that are tailored to assess the functionality of these devices at the material, device and system levels. Notably, we propose a mathematical metric to quantify the complexity of a surface and a set of standard surfaces for evaluating programmable shape-morphing devices, providing objective benchmarks for this expanding field.

形状变形设备具有结构变形能力,即将给从人机界面到生物医学和航空航天应用等多个领域带来革命性变化。本视角将形状变形设备分为两类:从一个起始形状变形为一组预定义的一个或多个变形形状的模式到模式形状变形设备,以及可按需变形为不同形状的可编程形状变形设备。我们强调需要标准化的评估方法来比较不同形状变形设备的性能,并介绍了一系列为评估这些设备在材料、设备和系统层面的功能而量身定制的指标。值得注意的是,我们提出了量化表面复杂性的数学指标和一套用于评估可编程形状变形设备的标准表面,为这一不断扩大的领域提供了客观基准。
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引用次数: 0
Non-collinear antiferromagnetic spintronics 非共线反铁磁自旋电子学
IF 83.5 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-29 DOI: 10.1038/s41578-024-00706-w
Berthold H. Rimmler, Banabir Pal, Stuart S. P. Parkin

Spintronics aims to go beyond the charge-based paradigm of silicon-based microelectronics by utilizing the spin degree of freedom for memory, storage and computing applications. State-of-the-art spintronic devices rely on the manipulation of magnetic textures by spin torques that are generated from electrical currents within ferromagnets (FMs) (spin-transfer torque) or proximal heavy metals (spin-orbit torque). Although these concepts have led to important commercial applications, the use of FMs poses challenges owing to their stray fields, relatively slow dynamics and limited thermal stability. To overcome these challenges, new materials are needed, especially those that display negligible stray fields such as antiferromagnets (AFs). In this regard, synthetic AFs have been vitally important since their use in the very first spintronic field sensors and memories. Collinear AFs have found applications in stabilizing magnetic textures via interfacial exchange bias. Going beyond these classes of AFs, the family of non-collinear AFs (NCAFs) with triangular spin textures has attractive properties, some of them even reminiscent of FMs. These include, for example, large anomalous Hall and Nernst effects, and substantial magneto-optical responses, despite their nearly fully compensated magnetization. Thus, one can anticipate their use in substituting FMs in future spintronic devices. Furthermore, these novel AFs convert electrical currents to spin currents with unique symmetries, which may allow for new ways to manipulate spin textures. Here, we review recent developments in non-collinear antiferromagnetic spintronics. Emphasis is placed on spin current generation, switching of spin textures and applications in magnetic random access memory and racetrack memory, as well as so-far unexplored materials. We show that although key components of spintronic devices based on NCAFs have been demonstrated, a wide range of potential materials remain to be explored and many open questions remain to be answered. Thus, the field of NCAFs is a vibrant and exciting subfield of spintronics with much potential for next-generation memory and computing technologies.

自旋电子学旨在超越硅基微电子学以电荷为基础的模式,利用自旋自由度进行记忆、存储和计算应用。最先进的自旋电子器件依靠铁磁体(FMs)(自旋转移力矩)或近端重金属(自旋轨道力矩)内电流产生的自旋力矩来操纵磁性纹理。尽管这些概念已经带来了重要的商业应用,但由于铁磁体的杂散场、相对较慢的动态和有限的热稳定性,使用铁磁体面临着挑战。为了克服这些挑战,我们需要新的材料,特别是那些能显示可忽略不计的杂散场的材料,例如反铁磁体(AFs)。在这方面,合成反铁磁体自用于最早的自旋电子场传感器和存储器以来,一直发挥着至关重要的作用。Collinear AFs 通过界面交换偏压在稳定磁性纹理方面得到了应用。除了这些类型的 AFs 之外,具有三角形自旋纹理的非共线 AFs(NCAFs)家族也具有诱人的特性,其中一些甚至让人联想到调频。例如,这些特性包括巨大的反常霍尔效应和内斯特效应,以及巨大的磁光响应,尽管它们的磁化几乎是完全补偿的。因此,我们可以预见它们在未来的自旋电子设备中将取代调频。此外,这些新型 AF 还能将电流转换为具有独特对称性的自旋电流,从而为操纵自旋纹理提供新的方法。在此,我们回顾了非共轭反铁磁自旋电子学的最新发展。重点是自旋电流的产生、自旋纹理的切换、在磁性随机存取存储器和赛道存储器中的应用,以及迄今尚未探索的材料。我们的研究表明,虽然基于 NCAF 的自旋电子器件的关键部件已经得到证实,但仍有大量潜在材料有待探索,许多未决问题仍有待解答。因此,NCAFs 领域是自旋电子学中一个充满活力和令人兴奋的子领域,在下一代存储器和计算技术方面潜力巨大。
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引用次数: 0
Magnetoelectric oscillations go giant in a van der Waals multiferroic 范德瓦尔斯多铁氧体中的磁电振荡变得巨大
IF 79.8 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-27 DOI: 10.1038/s41578-024-00719-5
Giulia Pacchioni
An article in Nature reports the observation of giant terahertz magnetoelectric oscillations in a van der Waals multiferroic and presents a theoretical model that elucidates their origin.
自然》(Nature)杂志上的一篇文章报道了在范德瓦尔斯多铁氧体中观察到的巨太赫兹磁电振荡,并提出了一个理论模型来阐明其起源。
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引用次数: 0
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Nature Reviews Materials
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