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Universal millimeter-wave noise source based on a multi-mode chaotic laser 基于多模混沌激光器的通用毫米波噪声源
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-20 DOI: 10.1016/j.optlastec.2024.111818

We propose and experimentally demonstrate a universal millimeter-wave noise source based on an optically injected multi-mode chaotic laser. The wideband multi-mode chaotic lights are sliced, amplified and then converted into continuous-wave noise through a photodetector. In our approach, the center frequency and the excess noise ratio of the generated noise signal can be easily adjusted by controlling the sliced spectral numbers and intensities, respectively. Moreover, pulsed noise can also be obtained by introducing an amplitude modulation as a chopper. In our proof-of-concept experiments, we successfully generate 140–220 GHz and 220–390 GHz broadband noise signals with a tunable excess noise ratio up to 52.42 dB. We also validate the tunability of the operation frequency though generating three narrow-band noise signals with center frequencies at 140 GHz, 252 GHz, and 364 GHz, respectively. Furthermore, the generation of pulse noise with durations of 500 ns and 0.5 ns per period are experimentally demonstrated. These results confirm that our proposed universal noise source is a promising candidate for multiple application scenarios.

我们提出并通过实验演示了一种基于光学注入多模混沌激光的通用毫米波噪声源。宽带多模混沌光被切片、放大,然后通过光电探测器转换成连续波噪声。在我们的方法中,产生的噪声信号的中心频率和过噪比可分别通过控制切片光谱数和强度轻松调节。此外,还可以通过引入振幅调制作为斩波器来获得脉冲噪声。在概念验证实验中,我们成功生成了 140-220 GHz 和 220-390 GHz 的宽带噪声信号,其可调过量噪声比高达 52.42 dB。我们还通过产生三个中心频率分别为 140 GHz、252 GHz 和 364 GHz 的窄带噪声信号,验证了工作频率的可调性。此外,我们还在实验中演示了产生持续时间为 500 ns 和每周期 0.5 ns 的脉冲噪声。这些结果证实,我们提出的通用噪声源在多种应用场景中都大有可为。
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引用次数: 0
Crack characteristics of pulsed laser brazed diamond grinding wheel 脉冲激光钎焊金刚石砂轮的裂纹特性
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-20 DOI: 10.1016/j.optlastec.2024.111830

Experiments on pulsed laser brazing of diamond grinding wheels were carried out in this paper. The crack characteristics and residual stress of brazed layer were detected and evaluated. The influence laws of pulse width, frequency, diamond mixing ratio, number of stacked layers, powder thickness and preheating temperature on crack characteristics were investigated. The pulsed laser characteristic coefficients (peak pulse power density/pulse interval time) and the correlation law between thermal stresses and cracks are discussed. The results show that the pulse width and frequency of the pulsed laser affect the cracking rate by varying the energy input and the time between pulses. The existence of a suitable value for the pulse characteristic coefficient corresponding to pulse width and frequency corresponds to a lower cracking rate. Thermal stress variations due to changes in process conditions at different diamond percentages, number of stacked layers, and preheating temperatures are the main causes of crack rate variations. Cracking is not only affected by thermal stresses, but also by the quality of the formed surface when pulsed laser brazing diamond to nickel–chromium alloy brazing material. For example, the main reason for the variation in cracking rate is the change in the morphology of the molded surface due to the variation in the thickness of the powder spread at different variations in the thickness of the powder spread.

本文进行了金刚石砂轮脉冲激光钎焊实验。对钎焊层的裂纹特征和残余应力进行了检测和评估。研究了脉冲宽度、频率、金刚石混合比、堆叠层数、粉末厚度和预热温度对裂纹特征的影响规律。讨论了脉冲激光特性系数(脉冲峰值功率密度/脉冲间隔时间)以及热应力和裂纹之间的相关规律。结果表明,通过改变能量输入和脉冲间隔时间,脉冲激光的脉宽和频率会影响开裂率。与脉冲宽度和频率相对应的脉冲特性系数的合适值对应于较低的开裂率。不同金刚石百分比、堆叠层数和预热温度下的工艺条件变化所导致的热应力变化是开裂率变化的主要原因。脉冲激光钎焊金刚石和镍铬合金钎料时,开裂不仅受热应力的影响,还受成型表面质量的影响。例如,开裂率变化的主要原因是在不同的铺粉厚度变化情况下,铺粉厚度的变化导致成型表面形态的变化。
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引用次数: 0
Thermo-mechanical coupling effect induced morphology evolution in laser stripping anti-erosion TiN coatings 激光剥离抗侵蚀 TiN 涂层中的热机械耦合效应诱导形貌演变
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-20 DOI: 10.1016/j.optlastec.2024.111817

Laser stripping has emerged as a pivotal technique for repairing anti-erosion coatings in the aviation and armored vehicle industries. This process entails complex thermodynamic interactions that remain incompletely explored. Unraveling the intricacies of the stripping mechanism, especially the evolution of surface morphology, is essential for advancing its industrial utility. This study characterizes the laser stripping effect on TiN anti-erosion coatings using confocal microscopy, scanning electron microscopy, and energy dispersive spectrometer. Notably, at an energy density threshold of approximately 102 J/cm2, pulsed lasers are observed to induce a distinctive hydrodynamic surface morphology, marked by parallel asymmetric grooves. This phenomenon is accompanied by a redistribution of surface elements and a decrease in nitrogen content. To dissect the underlying mechanisms, we have developed simulation models that integrate principles of heat transfer and fluid dynamics. These models reveal that the high-temperature decomposition and vaporization of TiN, coupled with the ejection of molten material due to vapor recoil pressure, are central to the stripping process. Additionally, the formation of asymmetric groove profiles is predominantly attributed to the nonlinear superposition effect from overlapping laser spots.

激光剥离已成为航空和装甲车辆工业修复抗侵蚀涂层的关键技术。这一过程涉及复杂的热力学相互作用,而对这一过程的探索还很不够。揭示剥离机理的复杂性,尤其是表面形态的演变,对于提高其工业实用性至关重要。本研究利用共聚焦显微镜、扫描电子显微镜和能量色散光谱仪描述了激光对 TiN 防侵蚀涂层的剥离效应。值得注意的是,在能量密度阈值约为 102 J/cm2 时,可观察到脉冲激光诱导出一种独特的流体力学表面形态,以平行的不对称沟槽为标志。这一现象伴随着表面元素的重新分布和氮含量的减少。为了剖析其基本机制,我们开发了结合传热学和流体动力学原理的模拟模型。这些模型显示,TiN 的高温分解和汽化,加上蒸汽反冲压力导致的熔融材料喷射,是剥离过程的核心。此外,不对称沟槽轮廓的形成主要归因于重叠激光光斑的非线性叠加效应。
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引用次数: 0
Laser-induced in-situ electrohydrodynamic jet printing of micro/nanoscale hierarchical structure 激光诱导原位电流体动力喷射打印微/纳米级分层结构
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-20 DOI: 10.1016/j.optlastec.2024.111812

With the rapid advancement of micro/nanoscale devices, there is a growing demand for hierarchical micro/nano porous-structure, particularly in fields of high-performance sensors, electrochemical energy storage, and photocatalysis. The fabrication methods for hierarchical micro/nano-porous structures have been limited by complex processes and high costs, making further development and application difficult. In this paper, a novel strategy of laser-induced in-situ electrohydrodynamic jet (E-Jet) printing of hierarchical micro/nano-porous structures was proposed. Based on the mechanism of high-energy laser beam induction on the jet, it successfully fabricated hierarchical porous ZnO structures from nanoscale to dozens of microns. The jet size focusing and solidification behavior were analyzed by combining experimental and simulative exploration. The resultant effects of the thermal field, flow field, and laser field on the spatial temperature distribution and the jetting morphology were examined. Furthermore, the laser-induced influence on the morphology of the printed micro/nano-porous ZnO structures was explored. Meanwhile, the performance of micro/nano-porous ZnO photoelectric sensors printed by E-Jet under different laser powers was investigated. The laser-induced in-situ E-Jet printing method provided an innovative pattern for the high-resolution additive manufacturing of hierarchical porous structures, demonstrating its potential for applications in advanced material and high-performance devices.

随着微米/纳米级器件的快速发展,对分层微米/纳米多孔结构的需求日益增长,尤其是在高性能传感器、电化学储能和光催化等领域。分层微/纳米多孔结构的制造方法受限于复杂的工艺和高昂的成本,使得进一步的开发和应用变得困难。本文提出了一种激光诱导原位电流体动力喷射(E-Jet)打印分层微/纳米多孔结构的新策略。基于高能激光束在射流上的感应机制,成功制备了从纳米级到数十微米的分层多孔氧化锌结构。结合实验和模拟探索,分析了射流尺寸聚焦和凝固行为。研究了热场、流场和激光场对空间温度分布和喷射形态的影响。此外,还探讨了激光对印刷微/纳米多孔氧化锌结构形态的影响。同时,研究了不同激光功率下 E-Jet 打印的微/纳米多孔 ZnO 光电传感器的性能。激光诱导原位 E-Jet 打印方法为高分辨率增材制造分层多孔结构提供了一种创新模式,展示了其在先进材料和高性能器件中的应用潜力。
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引用次数: 0
Welding between rough copper foil and silica glass using green femtosecond laser 使用绿色飞秒激光在粗糙铜箔和硅玻璃之间进行焊接
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-20 DOI: 10.1016/j.optlastec.2024.111804

The assembly of glass and copper micro devices is widely applied in modern manufacturing industries. Laser welding is an efficient technique. However, weld defects and instability resulting from the low laser absorptivity of copper remain significant challenges. Surface roughness also poses a limitation for optical contact during welding preprocessing. In this work, femtosecond pulse and green light from the second harmonic generation were combined to increase the copper absorptivity. The silica glass and rough copper foil were effectively welded. Under the optimized parameters, a maximum shear strength of 17.19 MPa was obtained. The electron and lattice temperatures during the welding process were simulated using two-temperature model. The microscopical mechanism, element diffusion, and chemical reaction were investigated. A modified region in the glass was formed due to excessive laser energy and scattered subsequent laser pulses. Cu–O-Si bonds were detected on the welds. Welding stability at various temperatures was characterized, with shear strength maintained at approximately 12 MPa after thermal cycling from 0 to 100 °C and heating at 150 °C. This study demonstrated that effective and stable welding of silica glass and rough copper foil can be achieved using green femtosecond lasers.

玻璃和铜微型设备的组装广泛应用于现代制造业。激光焊接是一种高效的技术。然而,由于铜对激光的吸收率较低,焊接缺陷和不稳定性仍然是重大挑战。表面粗糙度也限制了焊接预处理过程中的光学接触。在这项工作中,飞秒脉冲和二次谐波产生的绿光相结合,提高了铜的吸收率。硅玻璃和粗糙铜箔得到了有效焊接。在优化参数下,获得了 17.19 兆帕的最大剪切强度。利用双温模型模拟了焊接过程中的电子温度和晶格温度。研究了微观机理、元素扩散和化学反应。由于过高的激光能量和散射的后续激光脉冲,在玻璃中形成了一个改性区域。在焊缝上检测到了 Cu-O-Si 键。在不同温度下的焊接稳定性得到了表征,在 0 至 100 °C 的热循环和 150 °C 的加热过程中,剪切强度保持在约 12 MPa。这项研究表明,使用绿色飞秒激光可以实现硅玻璃和粗糙铜箔的有效、稳定焊接。
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引用次数: 0
Realization of nonvolatile polarization switch based on right-angle Sb2S3 embedded in 4H-SiC waveguide 基于嵌入 4H-SiC 波导的直角 Sb2S3 的非易失性偏振开关的实现
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-20 DOI: 10.1016/j.optlastec.2024.111826

A nonvolatile polarization switch is proposed numerically assisted by right-angle Sb2S3 inlaid in a strip 4H-SiC waveguide. The polarization of incident light can be engineered by the phase states of Sb2S3. When the Sb2S3 is crystalline, a TE0-TM0 polarization conversion is achieved with insertion loss (IL) of 0.22 dB and polarization conversion efficiency (PCE) of 98.36 % at the wavelength of 1550 nm. As long as the Sb2S3 is switched to the amorphous state, the polarization conversion effect becomes negligible with IL < 0.014 dB and PCE < 3.16 % across 1500–1600 nm waveband. Moreover, the robustness analysis demonstrates that the proposed structure maintains its functionality within ± 10 nm deviations of Δh, Δw, Δl, and Δd. The low-loss Sb2S3-assisted polarization switch offers a novel methodology for nonvolatile switching to programmable integrated optics, which can be deployed in polarization manipulation and neuromorphic optical computing.

通过在条状 4H-SiC 波导中镶嵌直角 Sb2S3,以数值方法提出了一种非易失性偏振开关。入射光的偏振可以通过 Sb2S3 的相态来设计。当 Sb2S3 为晶体状时,可实现 TE0-TM0 偏振转换,插入损耗(IL)为 0.22 dB,波长为 1550 nm 时的偏振转换效率(PCE)为 98.36 %。只要将 Sb2S3 转换为非晶态,偏振转换效果就会变得微不足道,在 1500-1600 nm 波段的插入损耗为 0.014 dB,偏振转换效率为 3.16 %。此外,鲁棒性分析表明,所提出的结构在 Δh、Δw、Δl 和 Δd 的 ± 10 nm 偏差范围内都能保持其功能。低损耗 Sb2S3 辅助偏振开关为可编程集成光学器件的非易失性开关提供了一种新方法,可用于偏振操作和神经形态光学计算。
{"title":"Realization of nonvolatile polarization switch based on right-angle Sb2S3 embedded in 4H-SiC waveguide","authors":"","doi":"10.1016/j.optlastec.2024.111826","DOIUrl":"10.1016/j.optlastec.2024.111826","url":null,"abstract":"<div><p>A nonvolatile polarization switch is proposed numerically assisted by right-angle Sb<sub>2</sub>S<sub>3</sub> inlaid in a strip 4H-SiC waveguide. The polarization of incident light can be engineered by the phase states of Sb<sub>2</sub>S<sub>3</sub>. When the Sb<sub>2</sub>S<sub>3</sub> is crystalline, a TE0-TM0 polarization conversion is achieved with insertion loss (IL) of 0.22 dB and polarization conversion efficiency (PCE) of 98.36 % at the wavelength of 1550 nm. As long as the Sb<sub>2</sub>S<sub>3</sub> is switched to the amorphous state, the polarization conversion effect becomes negligible with IL &lt; 0.014 dB and PCE &lt; 3.16 % across 1500–1600 nm waveband. Moreover, the robustness analysis demonstrates that the proposed structure maintains its functionality within ± 10 nm deviations of Δ<em>h</em>, Δ<em>w</em>, Δ<em>l</em>, and Δ<em>d</em>. The low-loss Sb<sub>2</sub>S<sub>3</sub>-assisted polarization switch offers a novel methodology for nonvolatile switching to programmable integrated optics, which can be deployed in polarization manipulation and neuromorphic optical computing.</p></div>","PeriodicalId":19511,"journal":{"name":"Optics and Laser Technology","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142272586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultra-flat NIR-to-MIR supercontinuum source with all-silica fibers based on rectangular NLP pumping 基于矩形 NLP 泵浦的全硅光纤超平近红外-近红外超连续光源
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-19 DOI: 10.1016/j.optlastec.2024.111791

We present, for the first time, a watt-level ultra-flat all-silica fiber supercontinuum (SC) source spanning from the near-infrared (NIR) to mid-infrared (MIR) region with negligible pump residuals. This SC source is pumped by amplified 1.57-μm rectangular noise-like pulses (NLPs), whose broad spectral and flat-top temporal characteristics enhance the spectral flatness and coverage of SC spectra. By cascading a piece of highly nonlinear silica fiber (HNLF), a SC ranging from 0.91 to 2.92 µm is obtained with a 3-dB bandwidth of ∼ 716.1 nm, a 10-dB bandwidth of ∼ 1533.6 nm, and an average power of 2.08 W. To our best knowledge, the spectral coverage, 3-dB, and 10-dB bandwidths represent the highest achieved levels for a watt-level all-silica fiber SC source covering the range from the NIR to MIR. Our system offers a simple and easily implemented solution for an ultra-flat NIR-to-MIR SC source, promising significant applications in optical coherence tomography and chemical detection.

我们首次提出了一种瓦级超平全二氧化硅光纤超连续(SC)光源,其光谱范围从近红外(NIR)到中红外(MIR),泵浦残余可忽略不计。这种超连续波源由放大的 1.57μm 矩形类噪声脉冲(NLP)泵浦,其宽光谱和平顶时间特性提高了超连续波光谱的光谱平坦度和覆盖范围。通过级联一段高非线性硅光纤(HNLF),可获得 0.91 至 2.92 µm 的 SC,其 3 分贝带宽为 ∼ 716.1 nm,10 分贝带宽为 ∼ 1533.6 nm,平均功率为 2.08 W。据我们所知,我们的光谱覆盖率、3 分贝和 10 分贝带宽代表了瓦级全硅石光纤 SC 光源在近红外到中红外范围内达到的最高水平。我们的系统为超平近红外到中近红外 SC 光源提供了一个简单、易于实现的解决方案,有望在光学相干断层扫描和化学检测领域得到广泛应用。
{"title":"Ultra-flat NIR-to-MIR supercontinuum source with all-silica fibers based on rectangular NLP pumping","authors":"","doi":"10.1016/j.optlastec.2024.111791","DOIUrl":"10.1016/j.optlastec.2024.111791","url":null,"abstract":"<div><p>We present, for the first time, a watt-level ultra-flat all-silica fiber supercontinuum (SC) source spanning from the near-infrared (NIR) to mid-infrared (MIR) region with negligible pump residuals. This SC source is pumped by amplified 1.57-μm rectangular noise-like pulses (NLPs), whose broad spectral and flat-top temporal characteristics enhance the spectral flatness and coverage of SC spectra. By cascading a piece of highly nonlinear silica fiber (HNLF), a SC ranging from 0.91 to 2.92 µm is obtained with a 3-dB bandwidth of ∼ 716.1 nm, a 10-dB bandwidth of ∼ 1533.6 nm, and an average power of 2.08 W. To our best knowledge, the spectral coverage, 3-dB, and 10-dB bandwidths represent the highest achieved levels for a watt-level all-silica fiber SC source covering the range from the NIR to MIR. Our system offers a simple and easily implemented solution for an ultra-flat NIR-to-MIR SC source, promising significant applications in optical coherence tomography and chemical detection.</p></div>","PeriodicalId":19511,"journal":{"name":"Optics and Laser Technology","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Porous silicon photoluminescence enhancement by silver dendrites registered with multiphoton microscopy 用多光子显微镜记录银树枝状体对多孔硅光致发光的增强作用
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-19 DOI: 10.1016/j.optlastec.2024.111825

The photoluminescence enhancement of a composite structure on porous silicon with surface-grown silver dendrites was discovered in this study. Silver dendrites are plasmonic antennas that exhibit a slight amplification effect. The small improvement of penetrating light intensity resulted in a significant increase in two-photon absorption, culminating in a remarkable increase in the photoluminescence intensity of the porous silicon material. The manifold enhancement of two-photon absorption was demonstrated by theoretical calculations of its probability.

本研究发现了多孔硅上的复合结构与表面生长的银树枝的光致发光增强效应。银树枝状突起是一种等离子体天线,具有轻微的放大效应。穿透光强度的微小提高导致双光子吸收的显著增加,最终使多孔硅材料的光致发光强度显著提高。通过对双光子吸收概率的理论计算,证明了双光子吸收的成倍增强。
{"title":"Porous silicon photoluminescence enhancement by silver dendrites registered with multiphoton microscopy","authors":"","doi":"10.1016/j.optlastec.2024.111825","DOIUrl":"10.1016/j.optlastec.2024.111825","url":null,"abstract":"<div><p>The photoluminescence enhancement of a composite structure on porous silicon with surface-grown silver dendrites was discovered in this study. Silver dendrites are plasmonic antennas that exhibit a slight amplification effect. The small improvement of penetrating light intensity resulted in a significant increase in two-photon absorption, culminating in a remarkable increase in the photoluminescence intensity of the porous silicon material. The manifold enhancement of two-photon absorption was demonstrated by theoretical calculations of its probability.</p></div>","PeriodicalId":19511,"journal":{"name":"Optics and Laser Technology","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strong modification of double-pulsed femtosecond laser to reinforce anticorrosion of Al alloy surface 利用双脉冲飞秒激光强化铝合金表面的防腐性能
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-19 DOI: 10.1016/j.optlastec.2024.111800

Aiming at the uncertainties and limitations in the laser modification of material surfaces for the corrosion protection, we here exploit a method of double-pulsed femtosecond laser processing with variable picosecond time delays, to effectively reinforce the anticorrosion performance of aluminum alloys. Compared with the traditional single-beam femtosecond laser irradiation, the adoption of double-pulsed laser irradiation especially with the optimal time delay of 50 ps, can decrease about 16 times in the magnitude of the corrosion current density, associated with the increase by 77.8 mV and 23 times in the corrosion potential and the impedance, respectively. The comprehensive insight analyses reveal that such an enhanced anticorrosion phenomenon is originated from the strong modification of the chemical and phase compositions on the metal surface, thus resulting in the higher degree of in-situ material oxidation with a prominent feature of the amorphous state, which can be evidenced not only in the shallow outer-layer surface but also extending to the deep inner-layer region. The significant roles of these laser modifications can be well elucidated by the proposed scenario.

针对激光对材料表面进行防腐改性时存在的不确定性和局限性,我们在此利用可变皮秒时间延迟的双脉冲飞秒激光加工方法,有效地增强了铝合金的防腐性能。与传统的单束飞秒激光辐照相比,采用双脉冲激光辐照,尤其是最佳时延为 50 ps 时,可使腐蚀电流密度降低约 16 倍,腐蚀电位和阻抗分别提高 77.8 mV 和 23 倍。综合洞察分析表明,这种增强的防腐现象源于金属表面化学成分和相组成的强烈改变,从而导致材料原位氧化程度提高,非晶态特征突出,不仅表现在浅外层表面,还延伸到深内层区域。所提出的方案可以很好地阐明这些激光改性的重要作用。
{"title":"Strong modification of double-pulsed femtosecond laser to reinforce anticorrosion of Al alloy surface","authors":"","doi":"10.1016/j.optlastec.2024.111800","DOIUrl":"10.1016/j.optlastec.2024.111800","url":null,"abstract":"<div><p>Aiming at the uncertainties and limitations in the laser modification of material surfaces for the corrosion protection, we here exploit a method of double-pulsed femtosecond laser processing with variable picosecond time delays, to effectively reinforce the anticorrosion performance of aluminum alloys. Compared with the traditional single-beam femtosecond laser irradiation, the adoption of double-pulsed laser irradiation especially with the optimal time delay of 50 ps, can decrease about 16 times in the magnitude of the corrosion current density, associated with the increase by 77.8 mV and 23 times in the corrosion potential and the impedance, respectively. The comprehensive insight analyses reveal that such an enhanced anticorrosion phenomenon is originated from the strong modification of the chemical and phase compositions on the metal surface, thus resulting in the higher degree of in-situ material oxidation with a prominent feature of the amorphous state, which can be evidenced not only in the shallow outer-layer surface but also extending to the deep inner-layer region. The significant roles of these laser modifications can be well elucidated by the proposed scenario.</p></div>","PeriodicalId":19511,"journal":{"name":"Optics and Laser Technology","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142247483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergetic red emitting Sm3+, Eu3+, Pr3+ triple doped K2Ba2(PO3)5 luminescent glasses: An approach towards highly intense red emitting phosphor for LED and display devices applications 协同红色发光 Sm3+、Eu3+、Pr3+ 三掺杂 K2Ba2(PO3)5 发光玻璃:为 LED 和显示设备应用开发高强度红色发光荧光粉的方法
IF 4.6 2区 物理与天体物理 Q1 OPTICS Pub Date : 2024-09-19 DOI: 10.1016/j.optlastec.2024.111796

Phosphites are being recognized as the new emerging candidates for luminescence in the modern era. In the proposed research article, Sm3+ to Pr3+ to Eu3+ doped K2Ba2(PO3)5 (KBP) glasses synthesized utilizing melt quenching technique. Through the use of XRD confirmed the amorphous nature of glass sample. SEM is employed to analyze the morphology and elemental composition of the prepared sample. The sample shows orange-red emission in the phosphor on energy transfer with the Sm3+ to Pr3+ to Eu3+. This highly instance red emitting phosphor has color purity of more than 99 %. These all results confirm that the prepared glasses are potential candidate for WLEDs, display applications, smart window applications and red emitting glasses for plant cultivation applications.

磷酸盐被认为是当代新兴的发光候选材料。本研究文章利用熔体淬火技术合成了掺杂 Sm3+ 至 Pr3+ 至 Eu3+ 的 K2Ba2(PO3)5 (KBP) 玻璃。通过 XRD 确认了玻璃样品的无定形性质。扫描电镜用于分析制备样品的形态和元素组成。在 Sm3+ 到 Pr3+ 再到 Eu3+ 的能量转移过程中,该样品的荧光粉发出橙红色的光。这种高实例红色发光荧光粉的颜色纯度超过 99%。所有这些结果都证实,所制备的玻璃是 WLED、显示应用、智能窗应用和植物栽培应用红色发光玻璃的潜在候选材料。
{"title":"Synergetic red emitting Sm3+, Eu3+, Pr3+ triple doped K2Ba2(PO3)5 luminescent glasses: An approach towards highly intense red emitting phosphor for LED and display devices applications","authors":"","doi":"10.1016/j.optlastec.2024.111796","DOIUrl":"10.1016/j.optlastec.2024.111796","url":null,"abstract":"<div><p>Phosphites are being recognized as the new emerging candidates for luminescence in the modern era. In the proposed research article, Sm<sup>3+</sup> to Pr<sup>3+</sup> to Eu<sup>3+</sup> doped K<sub>2</sub>Ba<sub>2</sub>(PO<sub>3</sub>)<sub>5</sub> (KBP) glasses synthesized utilizing melt quenching technique. Through the use of XRD confirmed the amorphous nature of glass sample. SEM is employed to analyze the morphology and elemental composition of the prepared sample. The sample shows orange-red emission in the phosphor on energy transfer with the Sm<sup>3+</sup> to Pr<sup>3+</sup> to Eu<sup>3+</sup>. This highly instance red emitting phosphor has color purity of more than 99 %. These all results confirm that the prepared glasses are potential candidate for WLEDs, display applications, smart window applications and red emitting glasses for plant cultivation applications.</p></div>","PeriodicalId":19511,"journal":{"name":"Optics and Laser Technology","volume":null,"pages":null},"PeriodicalIF":4.6,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142241562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Optics and Laser Technology
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