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Removal of 2,6-dichloro-1,4-benzoquinone Precursors during Advanced Water Purification Process 高级水净化工艺中2,6-二氯-1,4-苯醌前体的去除
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-01-03 DOI: 10.1080/01919512.2021.2014333
T. Nakai, K. Kosaka, M. Asami, M. Akiba
ABSTRACT The fates of 2,6-dichloro-1,4-benzoquinone (DCBQ) precursors were evaluated according to their formation potentials (FPs) upon chlorination during ozone/biological activated carbon treatment at two water purification plants (WPPs). DCBQ-FP levels in raw waters were 19 and 21 ng/L. DCBQ-FPs were slightly reduced by coagulation, sedimentation, and rapid filtration, but to < 8 ng/L by ozonation, in contrast to changes in absorbance at 260 nm and trihalomethane (THM)-FPs. DCBQ-FPs of water after sedimentation at WPP and secondary effluents at sewage treatment plants were decreased to a much greater extent than total THM-FPs at low ozone doses. Thus, ozonation is effective for removal of DCBQ precursors.
根据臭氧/生物活性炭处理过程中2,6-二氯-1,4-苯醌(DCBQ)前体在氯化作用下的形成势(FPs),对其命运进行了评价。原水DCBQ-FP含量分别为19和21 ng/L。经混凝、沉淀和快速过滤后,DCBQ-FPs略有降低,但经臭氧氧化后,DCBQ-FPs < 8 ng/L,与260 nm吸光度和三卤甲烷(THM)-FPs的变化相反。在低臭氧剂量下,WPP沉淀后的水和污水处理厂二次出水的DCBQ-FPs比总THM-FPs下降的幅度要大得多。因此,臭氧氧化对DCBQ前体的去除是有效的。
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引用次数: 0
Surface Dielectric Barrier Discharge in a Cylindrical Configuration – Effect of Airflow Orientation to the Microdischarges 圆柱形表面介质阻挡放电——气流方向对微放电的影响
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-12-29 DOI: 10.1080/01919512.2021.2016369
J. Mikeš, S. Pekárek, O. Hanuš
ABSTRACT This paper is devoted to studying the effect of airflow orientation on the microdischarges of the surface dielectric barrier discharge in cylindrical configuration through varying air input into the discharge chamber, the number of input nozzles, and the geometry of the active electrode. The air is supplied into the discharge chamber tangentially, radially, or axially through one or four input nozzles. Air input into the discharge chamber and the number of input nozzles determine the airflow regime. We used two active electrode geometries that are the axial strips or azimuthal rings. The change of active electrode geometry from rings to strips affects the orientation of microdischarges with respect to the airflow. For the discharge, the variation of air inputs and the number of input nozzles influences the flow regime in the discharge chamber, which, together with the active electrode geometry, affects the temperature field distribution in the chamber. These factors play an important role in plasmachemical processes leading to the discharge generation of various species, such as ozone. It is found that, for the maximum effect of airflow on discharge ozone generation, the streamlines should be uniformly distributed in the discharge chamber and predominantly oriented perpendicular to the majority of microdischarges.
本文通过改变放电腔的空气输入量、输入喷嘴的数量和活性电极的几何形状,研究了气流方向对圆柱形表面介质阻挡放电微放电的影响。空气通过一个或四个输入喷嘴切向,径向或轴向供应到排出室。进入排气室的空气和输入喷嘴的数量决定了气流的状态。我们使用了两种有源电极几何形状,即轴带或方位环。主动电极的几何形状从环形到条状的变化影响了微放电相对于气流的方向。在放电过程中,空气输入量和输入喷嘴数量的变化会影响放电室内的流态,而流态与活动电极的几何形状一起影响放电室内的温度场分布。这些因素在等离子体化学过程中起着重要作用,导致各种物质(如臭氧)的排放产生。研究发现,为了使气流对放电臭氧产生的影响达到最大,流线应均匀分布在放电室内,并且主要垂直于大多数微放电方向。
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引用次数: 0
Effect of Elevated Tropospheric Ozone on Vigna Mungo L. Varieties 对流层臭氧升高对芒哥品种的影响
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-12-12 DOI: 10.1080/01919512.2021.2009332
P. Dhevagi, A. Ramya, S. Priyatharshini, R. Poornima
ABSTRACT Tropospheric ozone (O3) is widely recognized as the most critical, regional atmospheric pollutant causing significant losses to agricultural productivity due to its phytotoxicity over agricultural areas and is expected to increase in future. In view of rising tropospheric ozone concentration over Indian regions, the present study aimed to evaluate the effect of elevated ozone stress on pulse crop blackgram (Vigna mungo L.), which contributes the major share of protein. The blackgram varieties namely CO 6, VBN 1, VBN 2, VBN 3, VBN 5, VBN 6, VBN 7, and VBN 8 were grown in open top chambers and factorial completely randomized block design was followed. The plants were exposed to elevated ozone concentration (50 and 100 ppb) from 10.00 h to 17.00 h over 10 days at flowering stage, with a weighted average ozone concentration of 50.1 and 101.2 ppb. Both the elevated ozone treatments significantly affected the plant physiological, biochemical, growth, and yield traits of all test varieties. On an average across eight blackgram varieties, decrease in chlorophyll content by 33.83 and 42.41%, stomatal conductance by 28.25 and 40.51% and photosynthetic rate by 29.43 and 42.30% exposed to 50 and 100 ppb ozone were observed, respectively. Correspondingly, the number of pods per plant decreased by 30.82 and 32.65%, 100 grain weight by 7.75 and 21.23% and plant weight by 16.03 and 21.23%, respectively, which were significant at 5% level. Furthermore in the observed traits, significantly higher reduction was observed in VBN3, while the least reduction was observed in VBN8. The path analysis displayed that all the observed physiological, biochemical, growth, and yield traits positively regulated the yield except leaf injury percentage, malondialdehyde, and proline content. The principal component analysis of two elevated ozone treatments confirmed VBN8 as ozone tolerant and VBN3 as ozone sensitive variety. Hence, cultivation of VBN8 variety at ozone hotspot regions would be the best option to overcome ozone induced yield loss.
对流层臭氧(O3)被广泛认为是最关键的区域性大气污染物,由于其对农业地区的植物毒性而对农业生产力造成重大损失,并且预计未来会增加。鉴于印度地区对流层臭氧浓度上升,本研究旨在评估臭氧胁迫升高对脉冲作物黑豆(Vigna mungo L.)的影响,黑豆是蛋白质的主要来源。选用co6、VBN 1、VBN 2、VBN 3、VBN 5、VBN 6、VBN 7和VBN 8为黑图品种,采用全随机区组设计。花期10 d内臭氧浓度分别为50和100 ppb,处理时间为10.00 ~ 17.00 h,臭氧加权平均浓度分别为50.1和101.2 ppb。两种臭氧处理对所有试验品种的植株生理生化、生长和产量性状均有显著影响。在50和100 ppb臭氧处理下,8个黑革品种的叶绿素含量、气孔导度和光合速率分别下降了33.83%和42.41%、28.25%和40.51%、29.43%和42.30%。在5%水平下,单株荚果数、百粒重和单株重分别减少30.82%和32.65%、7.75%和21.23%,单株重分别减少16.03和21.23%,差异均显著。此外,在观察到的性状中,VBN3的减少幅度显著高于VBN8,而VBN8的减少幅度最小。通径分析表明,除叶片伤害率、丙二醛和脯氨酸含量外,其余生理、生化、生长和产量性状均对产量有正向调节作用。两种臭氧处理的主成分分析证实VBN8为臭氧耐受性品种,VBN3为臭氧敏感性品种。因此,在臭氧热点地区种植VBN8品种将是克服臭氧诱导产量损失的最佳选择。
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引用次数: 8
Role of Ozone in Post-Harvest Disinfection and Processing of Horticultural Crops: A Review 臭氧在园艺作物采后消毒和加工中的作用综述
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-11-01 DOI: 10.1080/01919512.2021.1994367
S. Vijay Rakesh Reddy, D. S. Sudhakar Rao, R.R. Sharma, P. Preethi, R. Pandiselvam
ABSTRACT Consumers’ awareness toward nutritionally superior foods and improved knowledge of human health have enhanced the inclusion of fruits and vegetables as an integral part of regular dietary intake. However, concerns regarding the safety and quality of foods especially with reference to the outbreak of foodborne illnesses cause a major complication in the consumption of fruits and vegetables. Other major concerns, besides the safety of food from foodborne pathogens, include spoilage due to microbes and chemical pesticide residues. Traditionally, fresh fruits and vegetables are sanitized using chemicals, viz., chlorine, peracetic acid, electrolyzed water, hydrogen peroxide, etc. All these chemicals have been proven to exhibit ill effects over the consumers and the environment over a period of time, and thus, there is a great need for a safe alternative technique, which is eco-friendly and sustainable industrially. Ozone treatment is one such green technology available with multiple benefits such as antimicrobial nature, shelf life extension, pesticide residue removal, starch modification, waste water treatment, and many other industrial applications. It was also approved by FDA as a Generally Recognized As Safe (GRAS) sanitizer because of its eco-friendly nature (degradation into nonharmful oxygen after a short half-life) in addition to its inherent antimicrobial and antiethylene activity. This review focouses on ozone, its mode of action, and its applications in different horticultural crops with potential industrial use.
消费者对营养优良食品的认识和对人体健康知识的提高,使水果和蔬菜成为日常饮食摄入的一个组成部分。然而,对食品安全和质量的关注,特别是对食源性疾病爆发的关注,在水果和蔬菜的消费中造成了严重的并发症。除了食源性病原体对食品安全的影响外,其他主要问题还包括微生物和化学农药残留造成的食品变质。传统上,新鲜的水果和蔬菜是用化学品消毒的,即氯、过氧乙酸、电解水、过氧化氢等。所有这些化学物质都被证明在一段时间内会对消费者和环境产生不良影响,因此,非常需要一种安全的替代技术,这种技术既环保又能在工业上可持续发展。臭氧处理是一种绿色技术,具有多种优点,如抗菌性质,延长保质期,去除农药残留,淀粉改性,废水处理和许多其他工业应用。它还被FDA批准为公认的安全(GRAS)消毒剂,因为它的环保性质(在短半衰期后降解为无害的氧气)以及其固有的抗菌和抗乙烯活性。本文综述了臭氧及其作用方式,以及臭氧在具有工业应用潜力的不同园艺作物中的应用。
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引用次数: 16
Elimination of Diethylenetriaminepentaacetic Acid from Effluents from Pharmaceutical Production by Ozonation 臭氧氧化法去除制药废水中的二乙烯三胺五乙酸
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-10-06 DOI: 10.1080/01919512.2021.1983409
Fares Daoud, S. Zühlke, M. Spiteller, O. Kayser
ABSTRACT During production of diethylenetriaminepentaacetic acid (DTPA), process waste water is generated in several production stages. Process wastewater is usually disposed of via waste water treatment plants. However, due to low biodegradability of DTPA in conventional waste water treatment, incineration constitutes the current method of choice. The main disadvantage of incineration is high consumption of primary energy sources leading to substantial emission of carbon dioxide (CO2). Thus, an alternative method of process waste water treatment was investigated, which consists of an initial application of ozone and a subsequent biological treatment. In 2009, preliminary laboratory experiments were conducted to evaluate the elimination of DTPA in process waste water. Based on the initial results, the responsible authorities granted approval for large-scale ozonation of DTPA-containing wastewater in 2011. Additional laboratory scale experiments were carried out to assess the elimination of the target compound and the generation of its main transformation products using liquid chromatography – high resolution mass spectrometry. Through application of the postulated method, the concentration of DTPA and its derivatives can be reduced to levels assuring safe discharge into the receiving water. Additionally, a comparison of CO2 emissions showed that ozonation is an ecological alternative to incineration and, most likely, an economical as well, based on the local prices of primary energy sources.
在二乙烯三胺五乙酸(DTPA)的生产过程中,有几个生产阶段会产生工艺废水。工艺废水通常通过废水处理厂处理。然而,由于DTPA在常规废水处理中的生物降解性较低,因此焚烧是目前的首选方法。焚烧的主要缺点是一次能源消耗高,导致大量的二氧化碳排放。因此,研究了一种工艺废水处理的替代方法,该方法由臭氧的初始应用和随后的生物处理组成。2009年,进行了初步的实验室实验,以评估工艺废水中DTPA的消除情况。根据初步结果,主管部门于2011年批准了对含dtpa的废水进行大规模臭氧化处理。另外还进行了实验室规模的实验,以评估使用液相色谱-高分辨率质谱法消除目标化合物及其主要转化产物的产生。通过应用假定的方法,可以将DTPA及其衍生物的浓度降低到保证安全排放到接收水中的水平。此外,对二氧化碳排放量的比较表明,臭氧化是一种替代焚烧的生态方法,而且根据当地初级能源的价格,很可能也是一种经济方法。
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引用次数: 0
Ozone Dissolved in Water: An Innovative Tool for the Production of Young Plants in Grapevine Nurseries? 溶解在水中的臭氧:葡萄藤苗圃幼株生产的创新工具?
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-10-05 DOI: 10.1080/01919512.2021.1984203
Ana Romeo-Oliván, M. Pagès, Coralie Breton, F. Lagarde, Hubert Cros, O. Yobrégat, F. Violleau, A. Jacques
ABSTRACT Grapevine trunk diseases can infect nursery plants at different stages of propagation. Here, we evaluated the efficiency of aqueous ozone against two fungi associated with trunk diseases (Phaeoacremonium minimum and Phaeomoniella chlamydospora). The effect of ozone on the plant growth is also studied. Aqueous ozone completely suppressed spore germination in vitro. In planta fungal development was reduced six weeks post-inoculation. In the nursery, ozone treatment was comparable to the usual chemical treatment. Irrigation with aqueous ozone had no negative effects on plant growth. These anti-fungal properties and the absence of phytotoxicity make ozone a promising alternative for controlling microbial infection in nurseries.
葡萄树干病害可在苗木繁殖的不同阶段侵染。在这里,我们评估了水臭氧对两种与树干疾病相关的真菌(最小白僵菌和衣孢白僵菌)的效率。研究了臭氧对植物生长的影响。水溶液臭氧完全抑制孢子的体外萌发。在植物中,接种后6周真菌发育减少。在苗圃中,臭氧处理与通常的化学处理相当。臭氧水灌溉对植物生长无不良影响。这些抗真菌特性和没有植物毒性使臭氧成为控制苗圃微生物感染的有希望的替代品。
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引用次数: 6
Water-dissolved Ozone Mediates Optimization of Biotechnological Seed Production of Colocasia esculenta (L.) Schott 水溶臭氧对土芋籽生物技术制种的优化调控Schott
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-10-04 DOI: 10.1080/01919512.2021.1984207
Milagros Basail Pérez, José Efraín González, Vaniert Ventura Chavez, Rosa Elena González Vazquez, O. Portal
ABSTRACT Taro is a food source for many people in tropical countries. The use of biotechnological techniques for seed production is an alternative that allows obtaining propagation material of higher phytosanitary quality. During the taro in vitro propagation it is of great importance to increase the efficiency of the protocols that are affected mainly by the incidence of microbial contamination and low multiplication coefficients. At the initiation stage, 100% of taro apical meristems sprouted with the immersion in water-dissolved ozone at 2 ppm for 15 min. Furthermore, the microbial contamination was eliminated and the explants showed better quality, increasing the multiplication coefficient in the subsequent subcultures. The disinfection strategy applied allowed to rise the number of taro explants by more than three times, increasing the economic efficiency of the process.
芋头是热带国家许多人的食物来源。使用生物技术生产种子是一种替代方法,可以获得更高植物检疫质量的繁殖材料。在芋头离体繁殖过程中,提高主要受微生物污染和繁殖系数低影响的方案的效率具有重要意义。在萌发阶段,2 ppm水溶臭氧浸泡15 min,芋头根尖分生组织萌发率达到100%,且微生物污染消除,外植体质量较好,继代培养增殖系数提高。采用的消毒策略使芋头外植体数量增加了三倍以上,提高了该过程的经济效率。
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引用次数: 0
Determination of the Effects of Different Aqueous Ozone Doses and Temperature on Germination and Seedling Development of Vetch Seeds 不同臭氧水处理剂量和温度对紫薇种子萌发和幼苗发育影响的测定
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-10-04 DOI: 10.1080/01919512.2021.1984204
Ö. Uslu, A. Erol, O. Gedik, Fatma Akbay
ABSTRACT Various effects of ozone treatment on seed germination and development are known. This feature of ozone has gained more importance in recent years. On the other hand, it is reported that ozone used in excessive amounts causes adverse effects. The method of application of ozone and the results obtained vary according to the material used. In this study, two different vetch species (hairy vetch and common vetch), for 30 minutes four different ozone doses application [control (0.40 g/m3), 1.60 g/m3, 2.80 g/m3, 4.00 g/m3] and three different temperatures (10, 15 and 20 °C) were examined. As a result of applications; germination rate, radicle length, plumule length, seedling length, seedling fresh weight, seedling dry weight and vigor index values were calculated. It was determined that plumule length, seedling length, seedling fresh weight and vigor index values of the species were affected by ozone doses and temperature applications. Also, it was determined that the cultivar ˟ temperature ˟ ozone dose interaction had significant effects on the length of the radicle (P < 0.01) and the seedling fresh weight (P < 0.05). According to the results of the study; it has been determined that the applications of ozonized water up to 2.80 g/m3 positively affect the germination, radicle and seedling development of hairy vetch and common vetch seeds compared to the control. Besides, it was observed that the highest dose, 4.00 g/m3 dose, negatively affected the same parameters. It was found that the effect of temperature and ozone dose applications were significant on germination and seedling development.
臭氧处理对种子萌发和发育的各种影响是已知的。近年来,臭氧的这一特性越来越受到重视。另一方面,据报道,过量使用臭氧会产生不良影响。使用臭氧的方法和得到的结果因所用材料的不同而不同。本研究以两种不同种类的野豌豆(毛羽野豌豆和普通野豌豆)为研究对象,在30分钟内分别施用4种不同臭氧剂量[对照(0.40 g/m3)、1.60 g/m3、2.80 g/m3、4.00 g/m3]和3种不同温度(10、15和20℃)。作为申请的结果;计算发芽率、胚根长、胚珠长、幼苗长、幼苗鲜重、干重和活力指数。结果表明,臭氧剂量和温度对该树种的胚轴长、幼苗长、幼苗鲜重和活力指数均有影响。同时,˟温度˟臭氧剂量互作对根长(P < 0.01)和幼苗鲜重(P < 0.05)有显著影响。根据研究结果;结果表明,与对照相比,施用2.80 g/m3的臭氧水对野豌豆和普通野豌豆种子的萌发、胚根和幼苗发育均有积极影响。此外,观察到最高剂量4.00 g/m3对相同参数有负影响。结果表明,施用温度和臭氧剂量对种子萌发和幼苗发育有显著影响。
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引用次数: 0
Aqueous Ozone Sanitization System for Fresh Produce: Design, Development, and Optimization of Process Parameters for Minimally Processed Onion 新鲜农产品臭氧水消毒系统:设计、开发和优化最小加工洋葱的工艺参数
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-28 DOI: 10.1080/01919512.2021.1984206
Raouf Aslam, M. S. Alam, R. Pandiselvam
ABSTRACT The study was carried out to design and develop an ozonation treatment system for the sanitization of fresh produce before storage. The developed system was evaluated for minimally processed onions based on the kinetics of degradation, application methods, homogeneity of dissolution, and specific energy consumption. The sanitization process was then optimized for cut onion slices using a Box-Behnken design under Response Surface Methodology to study the effects of ozone concentration (1–5 ppm), exposure time (3–8 min), and aqueous pH (3–5) on microbial log reductions, pyruvate content, color change, and overall acceptability. The results obtained showed that degradation kinetics of dissolved ozone followed a first-order reaction with a half-life of 18.23 min. Among the different methods of ozone application tested at 5 ppm ozone concentration, the splashing method yielded the highest microbial log reductions (5.04) followed by dipping (4.5) and spraying (4.22) methods. For the sanitization of cut slices of onion, it was observed that aqueous ozone at 5 ppm concentration splashed on the surfaces for 8 min and an aqueous pH of 3.01 yielded optimized sanitization, whereas microbial log reductions, pyruvate content, and overall acceptability were recorded as 5.6 log reductions, 0.127 µM/mL, and 8.2, respectively. Overall, the system was found to be effective for the sanitization of minimally processed onions.
摘要:本研究旨在设计和开发一套臭氧处理系统,用于保鲜农产品的储藏前消毒。基于降解动力学、应用方法、溶解均匀性和比能量消耗,对所开发的系统进行了最低加工洋葱的评价。然后采用响应面法的Box-Behnken设计优化洋葱切片的消毒工艺,研究臭氧浓度(1 - 5ppm)、暴露时间(3 - 8min)和水溶液pH (3 - 5min)对微生物对数减少、丙酮酸含量、颜色变化和总体可接受性的影响。结果表明,溶解臭氧的降解动力学遵循一级反应,半衰期为18.23 min。在臭氧浓度为5 ppm时,不同的臭氧施用方法中,溅射法的微生物对数降低率最高(5.04),其次是浸渍法(4.5)和喷雾法(4.22)。对于洋葱切片的卫生处理,我们观察到,在5 ppm浓度的臭氧水溶液在表面溅落8分钟,水溶液pH为3.01时,获得了最佳的卫生处理,而微生物对数减少量、丙酮酸含量和总体可接受度分别为5.6对数减少量、0.127 μ M/mL和8.2。总的来说,该系统被发现对最低限度加工洋葱的消毒是有效的。
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引用次数: 13
Ozonated Water Preparation in Dental Offices: Estimation of Ozone Gas Solubility Ratio – Optimum Configurations and Practical Guidelines 牙科诊所的臭氧水制备:臭氧气体溶解度比的估计。最佳配置和实用指南
IF 2.7 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2021-09-26 DOI: 10.1080/01919512.2021.1983410
F. Sabbah, W. Domb
ABSTRACT Dentists wish to prepare enough volume to meet the dental office ozonated water consumption and to reach the desired concentration in the least amount of ozonation time. Several factors affect ozone gas mass transfer in water and the corresponding ozonated water concentration can be measured with analytical or direct in-line monitoring methods. An alternative, ozone gas solubility ratio (SR) may be used as a reference to predict ozonated water concentration. SR of 0.25 is often cited in the literature, but it can vary between 0.2 and 0.4 according to different ozonation configurations and parameters. A total of 70 tests were performed using different ozonation configurations which are commonly used in dental practice. Ozone concentration in water was measured and the SR was calculated. SR varied between 0.13 and 0.4. To our knowledge, this study has never been carried out before and aims to propose practical guidelines on selecting the optimum water ozonation configurations in dental practice, as well as to calculate their corresponding dissolved ozone concentration.
牙医希望准备足够的体积来满足牙科办公室臭氧化水的消耗,并在最少的臭氧化时间内达到所需的浓度。几个因素影响臭氧气体在水中的传质,相应的臭氧化水浓度可以通过分析或直接在线监测方法测量。另一种方法,臭氧气体溶解度比(SR)可作为预测臭氧化水浓度的参考。在文献中经常引用0.25的SR,但根据不同的臭氧化配置和参数,SR可以在0.2 - 0.4之间变化。共进行了70次测试,使用不同的臭氧化配置,通常用于牙科实践。测定了水中臭氧浓度,并计算了SR。SR在0.13 ~ 0.4之间变化。据我们所知,本研究之前从未进行过,旨在为牙科实践中选择最佳水臭氧化配置提供实用指南,并计算其相应的溶解臭氧浓度。
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引用次数: 0
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Ozone: Science & Engineering
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