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Ore-finding criteria of a hydrothermal-overprint sandstone-hosted uranium deposit: A case study from the southern Songliao Basin, China 热液叠印砂岩型铀矿床找矿标准——以松辽盆地南部为例
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107069
Qingchun Li , Hui Rong , Minqiang Cao , Anjing Man , Jianxin Shao , Qiwei Wang , Junxing Ren
The Qianjiadian uranium deposit in the southern Songliao Basin provides a good case study of the ore-finding criteria for sandstone-hosted uranium deposits overprinted by hydrothermal events. The uranium-bearing series within a braided river delta sedimentary system is characterized by large-scale sandstone interbedded with thin mudstone layers. The epigenetic oxidation in uranium reservoirs is represented by red sandstone and yellow sandstone. The red color unit is unevenly developed and often cuts through the bedding. The types of rocks that appear successively along the direction of decreasing oxidation are red sandstone, yellow sandstone, gray-white sandstone, gray ore-bearing sandstone, and primary gray sandstone. The hydrothermal alteration in uranium reservoirs is characterized by the occurrence of scheelite, brannerite, chalcopyrite, sphalerite, galena, and ankerite. Accordingly, the uranium ore bodies are mainly formed in the transition position from braided distributary channels and crevasse deltas to perennial interdistributary bays, and they are mainly distributed in the areas where the proportion of oxidized sand bodies is 0–20%. Hydrothermal fluids associated with basic dikes may cause uranium enrichment. The criteria for discovering new uranium deposits are primarily based on the type of sedimentary environment, interlayer oxidation, and presence of a hydrothermal overprint. Both the sandstone interbedded with dark mudstone and the oxidation–reduction transition are favorable for uranium mineralization, and the area affected by hydrothermal fluids related to basic dikes is a place to search for high-grade ore bodies. The findings of this study may potentially contribute to more efficient exploration strategies for sandstone-hosted uranium deposits overprinted by hydrothermal fluids.
松辽盆地南部前家店铀矿床为热液叠印砂岩型铀矿床的找矿标准提供了很好的研究实例。辫状河三角洲沉积体系中的含铀系列具有大型砂岩与薄泥岩互层的特征。铀储集层的表成氧化作用以红砂岩和黄砂岩为代表。红色单位发育不均匀,经常穿过垫层。沿递减氧化方向依次出现的岩石类型为红砂岩、黄砂岩、灰白色砂岩、灰色含矿砂岩和原生灰色砂岩。铀矿热液蚀变以白钨矿、银铜矿、黄铜矿、闪锌矿、方铅矿和铁白云矿的赋存为特征。据此,铀矿体主要形成于辫状分流河道、断陷三角洲向多年生分流间湾过渡的位置,主要分布在氧化砂体比例为0 ~ 20%的地区。与基性岩脉相关的热液可能导致铀富集。发现新铀矿床的标准主要基于沉积环境类型、层间氧化和热液叠印的存在。砂岩与暗色泥岩互层及氧化还原转变均有利于铀矿化,与基性脉相关的热液流体影响区域是寻找高品位矿体的场所。本研究的发现可能有助于为热液覆盖的砂岩型铀矿床提供更有效的勘探策略。
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引用次数: 0
Dating and geochemical constraints on the origin and regional exploration of the Dayinshan deposit, east China 中国东部大荫山矿床成因的地球化学约束及区域勘探
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107101
Zi-Teng Li , Xiao-Yong Yang , Qi Chen , Qin-Qin Shen , Yang Cai , Ke Shi
The Dayinshan porphyry–skarn gold-polymetallic deposit, located within the Northern Zhejiang Metallogenic District, is situated at the tectonic junction between the Middle-lower Yangtze River metallogenic belt (MLYB) and the Qin-Hang metallogenic belt (Q-HB). However, the metallogenic age, genetic mechanism, and regional tectonic significance of this deposit are still poorly constrained. Based on detailed field investigations, this study conducted U–Pb dating of zircon and garnet from drill core ZKH101, combined with in situ trace element analyses of pyrite, zircon, and garnet, together with whole-rock major and trace element geochemical analyses and Isocon-based mass balance calculations on altered rocks. The results reveal two magmatic episodes at 144–136 Ma and 133–129 Ma, with the mineralization age constrained to ∼ 137 Ma, consistent with the Early Cretaceous Cu–Au metallogenic event in the MLYB. The geochemical characteristics of the mineralized intrusions are transitional between normal arc rocks and adakitic rocks, formed in a setting of partial melting of a thickened lower crust. This indicates thatthe Dayinshan deposit shows a closer affinity to the MLYB than to the Q-HB, and should be regarded as part of the transitional zone at the southeastern margin of the MLYB. Isocon analysis further reveals significant mobilization and re-enrichment of ore-forming elements in the alteration system: strong influx of Mo (mass gain up to + 872.38 %) in the potassic zone, and systematic enrichment of ore-forming elements in the sericitic + propylitic alteration zones, indicating a typical porphyry–skarn mineralization mechanism. Future exploration should focus on intrusions older than 135 Ma with ΔFMQ > +1 in the mining area and the southern volcanic-covered region.
大银山斑岩-矽卡岩型金多金属矿床位于浙北成矿区内,位于长江中下游成矿带(MLYB)与秦航成矿带(Q-HB)的构造交界处。但目前对该矿床的成矿时代、成因机制及区域构造意义仍知之甚少。在详细野外调查的基础上,对ZKH101岩心进行了锆石和石榴石U-Pb定年,结合黄铁矿、锆石和石榴石的原位微量元素分析,以及全岩主微量元素地球化学分析和蚀变岩isocon质量平衡计算。结果揭示了144 ~ 136 Ma和133 ~ 129 Ma两个岩浆期,成矿年龄限定在 ~ 137 Ma,与早白垩世MLYB铜金成矿事件一致。矿化侵入体的地球化学特征介于正常弧岩和埃达克岩之间,形成于下地壳增厚的部分熔融环境。这表明大银山矿床与MLYB的亲缘关系比与Q-HB的亲缘关系更密切,应视为MLYB东南边缘过渡带的一部分。等同位素分析进一步揭示了蚀变体系中成矿元素的明显活化和再富集作用:钾质带Mo大量流入(质量增加 + 872.38 %),绢云母质 + 丙质蚀变带成矿元素系统富集,显示了典型的斑岩-矽卡岩成矿机制。矿区及南部火山覆盖区应重点寻找年龄在135 Ma以上的ΔFMQ >; +1侵入体。
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引用次数: 0
Geochronology and geochemistry of the Wulanwusu P-Fe deposit, northern North China Craton: Evidence for a genetic link to the Paleoproterozoic anorthosite-mangerite-charnockite-granite (AMCG) suite 华北克拉通北部乌兰乌苏P-Fe矿床的年代学和地球化学:与古元古代斜长岩-锰铁-绿绿岩-花岗岩(AMCG)组的成因联系证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107079
Xuan Wu , Li-Xing Li , Jing-Wen Mao , Hou-Min Li , Yu-Bo Ma , Yi Wang , Yang Dai , Xiao-Hui Wang
Phosphate deposits of both sedimentary and igneous origins are the most important sources of phosphorus in the world. Neoarchean metamorphic series-hosted apatite-magnetite deposits in the northern North China Craton (NCC) are important sources of P and Fe. However, the genesis of some deposits remains controversial, as they are proposed to have formed through sedimentary-metamorphic processes in the phosphorus-deficient Neoarchean environment. The Wulanwusu P-Fe deposit in the Jianping area is a typical example, with the P-Fe mineralization typically composed of plagioclase, amphibole, biotite, apatite and Fe-Ti oxides. This study aims to constrain the geological controls on P-Fe mineralization through petrographic, geochronological, and geochemical analyses of P-Fe ores. Zircon U-Pb geochronology yielded a weighted crystallization age at 1730 ± 6 Ma, precisely constraining the timing of mineralization to the late Paleoproterozoic. Petrographic observations, whole-rock and apatite geochemistry collectively indicate that the mineralization is associated with a mafic magmatic event, supporting its classification as a late Paleoproterozoic igneous P-Fe deposit. Our results clearly rule out a previously suggested link between P-Fe mineralization and metamorphosed Neoarchean volcano-sedimentary rocks. The Nd-Hf isotopic compositions suggest that the parental magma was derived from an enriched subcontinental lithospheric mantle source. Combined with geochronological and geochemical evidence, these results indicate that the formation of the Wulanwusu P-Fe deposit is linked to the late Paleoproterozoic AMCG suite magmatism in the northern NCC and occurred in a post-collisional extensional stage following the convergence of the eastern and western blocks of the NCC.
沉积磷矿和火成岩磷矿是世界上最重要的磷矿。华北克拉通北部新太古代变质系磷灰石-磁铁矿矿床是重要的铁、磷来源。然而,一些矿床的成因仍然存在争议,因为它们被认为是在缺磷的新太古代环境中通过沉积变质作用形成的。建平乌兰乌苏P-Fe矿床为典型,其P-Fe矿化主要由斜长石、角闪孔、黑云母、磷灰石和Fe-Ti氧化物组成。本研究旨在通过对P-Fe矿石的岩相学、年代学和地球化学分析来约束P-Fe成矿的地质控制。锆石U-Pb年代学的加权结晶年龄为1730±6 Ma,精确地将成矿时间限定在晚古元古代。岩石学观测、全岩地球化学和磷灰石地球化学共同表明成矿作用与基性岩浆事件有关,支持其归类为晚古元古代火成岩P-Fe矿床。我们的结果清楚地排除了先前提出的P-Fe矿化与变质的新太古代火山沉积岩之间的联系。Nd-Hf同位素组成表明母岩浆来源于富集的次大陆岩石圈地幔源。结合地质年代学和地球化学证据,认为乌兰乌苏磷铁矿的形成与北陆块北部晚古元古代AMCG套岩浆活动有关,发生在东、西陆块汇合后的碰撞后伸展阶段。
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引用次数: 0
Metallogenic electromagnetism study reveals the pegmatite rare metal mineral system in Koktokay, Altai, Western China 成矿电磁学研究揭示了阿尔泰Koktokay地区伟晶岩稀有金属矿物体系
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107084
Lanfang He , Ping Shen , Liang Li , Sihao Wang , Xiaochi Liu , Rujun Chen , Kezhang Qin
The Koktokay (KOK) pegmatite field in the Altai Metallogenic Belt in Xinjiang is one of the largest beryllium mines in the world, as well as an important lithium, niobium, and tantalum deposit for China. The KOK No. 3 pegmatite ring is a very typical pegmatite ring among the world’s pegmatite systems. Great progress has been achieved in studies of the KOK rare metal ore deposit, but the metallogenic model and controlling structure of the deposit remain controversial. In addition, the prospects of mineral resources in the KOK district and vicinity are unclear. In this study, we propose a metallogenic model for understanding the rare metal mineral system of the KOK based on an metallogenic electromagnetism study using multiscale electromagnetic exploration and petro-electromagnetism analyses. The geo-electrical structure of the shallow part (to 1,000 m) and deep part (to 30 km) of the KOK rare metal mining district are explored through audio magnetotelluric sounding (AMT) and broadband frequency magnetotelluric sounding (BMT). The results of petro-electromagnetism analyses (complex impedance measurements) of rock samples show that the KOK pegmatite has low-resistivity properties. Resistivity contour maps at iso-depths of 200 m and 400 m from AMT exploration show that a high-resistivity granite mass surrounds the KOK pegmatite field. The pegmatite, along with the wall rocks, are characterized as medium to relatively low resistivity. The BMT results reveal low-resistivity bodies within a depth range of 15–30 km in the southern part of the KOK pegmatite field, which are speculated to reflect residual magma chambers based on the comprehensive interpretation from geophysical, geochemical and geological analysis. The BMT results also indicate resistivity differences between the pathway from the speculated ancient magma chambers to the terminal mineral deposits and surrounding rocks. The source of this system is speculated as a magma chamber, which features low resistivity and lies in the lower crust of the south of the No. 3 pegmatite deposit. Geochemical analysis results indicate that the rare metal pegmatite has experienced highly differentiated evolution. Based on a comprehensive understanding of the geophysical observations and geochemical constraints, we conclude that the mineral system of the rare metal pegmatite at the KOK is controlled by a magmatic system. The KOK No. 3 pegmatite deposit lies in the north of the pegmatite field. We suggest that the south of the KOK pegmatite field also has favorable resource potential.
新疆阿尔泰成矿带的Koktokay伟晶岩田是世界上最大的铍矿之一,也是中国重要的锂、铌、钽矿床。KOK 3号伟晶岩环是世界伟晶岩体系中非常典型的伟晶岩环。KOK稀有金属矿床的研究取得了很大进展,但其成矿模式和控矿构造仍存在争议。此外,角区及邻近地区的矿产资源前景尚不明朗。在多尺度电磁勘探和油气电磁分析的基础上,提出了认识KOK稀有金属矿物系统的成矿电磁学模型。利用音频大地电磁测深(AMT)和宽带频率大地电磁测深(BMT)对KOK稀有金属矿区浅部(~ 1000 m)和深部(~ 30 km)的地电结构进行了勘探。岩石样品的石油电磁分析(复阻抗测量)结果表明,KOK伟晶岩具有低电阻率特性。AMT探测的等深200 m和400 m电阻率等值线图显示,KOK伟晶岩田周围有一个高电阻率花岗岩块体。伟晶岩与围岩具有中至相对低电阻率特征。BMT结果显示,KOK菱晶岩田南部15 ~ 30 km范围内存在低电阻率体,综合物探、化探和地质分析,推测其为残余岩浆房。BMT结果还显示了推测的古岩浆房至终端矿床的路径和围岩之间的电阻率差异。推测该系统的来源为岩浆房,岩浆房位于3号伟晶岩矿床南部的下地壳,具有低电阻率的特征。地球化学分析结果表明,该稀有金属伟晶岩经历了高度分化的演化过程。综合地球物理观测资料和地球化学约束条件,认为该区稀有金属伟晶岩的矿物系统受岩浆系统控制。角3号伟晶岩矿床位于伟晶岩田北侧。我们认为,KOK伟晶岩田南部也具有良好的资源潜力。
{"title":"Metallogenic electromagnetism study reveals the pegmatite rare metal mineral system in Koktokay, Altai, Western China","authors":"Lanfang He ,&nbsp;Ping Shen ,&nbsp;Liang Li ,&nbsp;Sihao Wang ,&nbsp;Xiaochi Liu ,&nbsp;Rujun Chen ,&nbsp;Kezhang Qin","doi":"10.1016/j.oregeorev.2025.107084","DOIUrl":"10.1016/j.oregeorev.2025.107084","url":null,"abstract":"<div><div>The Koktokay (KOK) pegmatite field in the Altai Metallogenic Belt in Xinjiang is one of the largest beryllium mines in the world, as well as an important lithium, niobium, and tantalum deposit for China. The KOK No. 3 pegmatite ring is a very typical pegmatite ring among the world’s pegmatite systems. Great progress has been achieved in studies of the KOK rare metal ore deposit, but the metallogenic model and controlling structure of the deposit remain controversial. In addition, the prospects of mineral resources in the KOK district and vicinity are unclear. In this study, we propose a metallogenic model for understanding the rare metal mineral system of the KOK based on an metallogenic electromagnetism study using multiscale electromagnetic exploration and petro-electromagnetism analyses. The geo-electrical structure of the shallow part (to 1,000 m) and deep part (to 30 km) of the KOK rare metal mining district are explored through audio magnetotelluric sounding (AMT) and broadband frequency magnetotelluric sounding (BMT). The results of petro-electromagnetism analyses (complex impedance measurements) of rock samples show that the KOK pegmatite has low-resistivity properties. Resistivity contour maps at <em>iso</em>-depths of 200 m and 400 m from AMT exploration show that a high-resistivity granite mass surrounds the KOK pegmatite field. The pegmatite, along with the wall rocks, are characterized as medium to relatively low resistivity. The BMT results reveal low-resistivity bodies within a depth range of 15–30 km in the southern part of the KOK pegmatite field, which are speculated to reflect residual magma chambers based on the comprehensive interpretation from geophysical, geochemical and geological analysis. The BMT results also indicate resistivity differences between the pathway from the speculated ancient magma chambers to the terminal mineral deposits and surrounding rocks. The source of this system is speculated as a magma chamber, which features low resistivity and lies in the lower crust of the south of the No. 3 pegmatite deposit. Geochemical analysis results indicate that the rare metal pegmatite has experienced highly differentiated evolution. Based on a comprehensive understanding of the geophysical observations and geochemical constraints, we conclude that the mineral system of the rare metal pegmatite at the KOK is controlled by a magmatic system. The KOK No. 3 pegmatite deposit lies in the north of the pegmatite field. We suggest that the south of the KOK pegmatite field also has favorable resource potential.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"188 ","pages":"Article 107084"},"PeriodicalIF":3.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unraveling the petrogenetic links: Late Jurassic Barren Granites, W-bearing granites, and Nb-Ta-Li- mineralized granites in Yichun Mining District, South China 揭示了宜春矿区晚侏罗世秃花岗岩、含w花岗岩和铌-塔-利成矿花岗岩的成因联系
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107061
Yu-Fang Zhong , Yuan-Yuan Liu , Chang-Qian Ma , Kai-Pei Lu , Lian-Xun Wang
Large volumes of Late Mesozoic granites are exposed in South China, associated with extensive polymetallic (W, Sn, U, Ni, Ta, Li, REE) mineralization. However, the genetic relationships between barren granitoids and variously mineralized granitoids within a composite pluton require further research. Additionally, in a certain mining district, the genetic relationships among adjacent, contemporaneous plutons are poorly constrained. Some of these plutons are barren, while others host tungsten deposits, and still others contain Nb-Ta deposits. In this study, we focus on three Late Jurassic granite plutons in the Yichun mining district, and conduct a comprehensive investigation of these plutons. This includes LA-ICP-MS zircon and monazite U-Pb dating, as well as analyses of zircon Hf isotopes and trace elements, whole-rock geochemistry, and Nd isotopes on representative granite samples. Based on our new data and previously published studies, and from the insights of the mush model and magma plumbing systems, we propose the following key inferences: (1) Multiple emplacements of magma batches drove extensive in-situ differentiation within a magma reservoir. (2) Highly fractionated granites and main-phase granitoids within a composite pluton may have been derived from different magma reservoirs; more evolved magmas likely originated from a deeper magma reservoir. (3) The degree of magmatic evolution serves as a crucial factor governing the diversity of W and Ta-Nb mineralization within rare-metal granites. (4) In South China, extremely fractionated granitoids can serve as important indicators for tungsten (W) deposit exploration, and the Yichun district remains prospective for large-scale tungsten deposits at depth. This study provides critical insights into the evolution of granitic magmas and their associated metallogenic processes, thus holding important implications for regional mineralization exploration.
华南地区出露大量晚中生代花岗岩,并伴有广泛的多金属(W、Sn、U、Ni、Ta、Li、REE)成矿作用。然而,在复合岩体中,贫花岗岩类与各种矿化花岗岩类之间的成因关系有待进一步研究。此外,在某矿区,邻近的同生岩体之间的成因关系约束较差。其中一些岩体是贫瘠的,而另一些则含有钨矿床,还有一些含有铌钽矿床。本文以伊春矿区3个晚侏罗世花岗岩体为研究对象,对其进行了综合研究。这包括LA-ICP-MS锆石和独居石U-Pb定年,以及锆石Hf同位素和微量元素分析,全岩地球化学分析,以及代表性花岗岩样品的Nd同位素。根据我们的新数据和先前发表的研究成果,并从浆液模型和岩浆管道系统的见解出发,我们提出了以下关键推论:(1)岩浆批的多次侵位驱动了岩浆储层内广泛的原位分异。(2)复合岩体内的高分异花岗岩和主相花岗岩可能来源于不同的岩浆储层;更进化的岩浆可能起源于更深的岩浆储层。(3)岩浆演化程度是控制稀有金属花岗岩中W和Ta-Nb矿化多样性的关键因素。(4)华南地区极分异花岗岩类可作为钨矿找矿的重要指示物,宜春地区具有深部大规模钨矿远景。该研究为该区花岗岩岩浆演化及其相关成矿过程提供了重要的认识,对区域成矿勘探具有重要意义。
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引用次数: 0
Spatio-temporal distribution patterns, genesis, metallogenic regularity, and prospects of global potash resources 全球钾肥资源时空分布格局、成因、成矿规律及远景展望
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107100
HuiHui Rao , JiaXin Luo , MaoYong He , YuanYuan Cheng , Hong Chang , Zhengyan Li , Jin Wen , Yinggao Liu , Jinrui Chen
<div><div>Potash, a strategic mineral resource that impacts the development of global agriculture and industry, has received considerable attention regarding its worldwide distribution, genesis, and exploration prospects. Influenced by various tectonic events and climatic changes throughout geological history, the distribution of potash resources exhibits significant spatio-temporal characteristics. Potash deposits have been documented in a variety of basin types globally, including stable cratonic basins, continental rift systems, foreland basins, intermontane depressions, and other tectonic settings. The metallogenic epochs range from the Cambrian of the Paleozoic to the Quaternary of the Cenozoic, with potash formation primarily occurring in the Paleozoic, followed by the Mesozoic, and the least quantity formed in the Cenozoic. Based on the unique metallogenic environments and occurrence characteristics of these mineral deposits, potash deposits can be classified into three main types: marine, continental, and marine-continental transitional facies. Among them, marine potash deposits are large in scale and mainly formed in stable cratonic basins. Continental potash deposits, on the other hand, are smaller in scale and mostly distributed in intermountain depression basins within continents, and primarily characterized by salt lake potash. Marine-continental transitional potash deposits exhibit both marine and continental features, are mostly distributed in continental rifts or marine-continental transitional zones, and have complex metallogenic processes. Previous studies indicate that potash deposit formation results from the interplay of multiple ore-controlling factors, including tectonics, paleoclimate conditions, material sources, paleogeographic environment, and marine geochemistry. The metallogenic regularity is primarily determined by the interaction of the three dynamic systems of “tectonics-climate--material source” in specific spatio-temporal context. As a result, potash deposits across different global regions and geological periods generally exhibit significant diversity in metallogenic patterns, reflecting their unique mineralization environments and evolutionary histories of tectonic processes. This heterogeneity in genetic mechanisms means that a single metallogenic model cannot universally explain the formation of all global potash deposits. Consequently, worldwide potash exploration faces substantial challenges. Moreover, the specificity of these mineralization mechanisms further exacerbates the highly uneven distribution of global potash resources, creating severe challenges for countries with urgent food security needs in achieving sustainable potash supply. Consequently, building upon existing resource development, it is necessary to systematically enhance potash exploration potential and ensure sustainable supply capacity through deep potash exploration, AI-powered predictions, rational utilization of unexploited potassium
钾肥作为一种影响全球农业和工业发展的战略性矿产资源,其在全球的分布、成因和勘探前景受到了广泛关注。在整个地质历史中,受各种构造事件和气候变化的影响,钾肥资源的分布呈现出明显的时空特征。在全球范围内,各种类型的盆地都有钾矿床的记录,包括稳定的克拉通盆地、大陆裂谷系统、前陆盆地、山间坳陷和其他构造环境。成矿时期为古生代寒武系至新生代第四纪,古生代钾矿形成为主,中生代次之,新生代钾矿形成量最少。根据这些矿床独特的成矿环境和赋存特征,将钾肥矿床划分为海相、陆相和海陆过渡相三种主要类型。其中海相钾肥矿床规模较大,主要形成于稳定的克拉通盆地。陆相钾肥矿床规模较小,多分布于大陆内的山间坳陷盆地,以盐湖钾肥为主。海陆过渡型钾肥矿床具有海相和陆相双重特征,多分布于陆相裂谷或海陆过渡带,成矿过程复杂。前人的研究表明,钾矿床的形成是构造、古气候条件、物质来源、古地理环境和海洋地球化学等多种控矿因素共同作用的结果。成矿规律主要由特定时空背景下“构造-气候-物质源”三大动力系统的相互作用决定。因此,全球不同地区、不同地质时期的钾肥矿床在成矿模式上普遍表现出显著的多样性,反映了其独特的成矿环境和构造演化历史。这种成因机制的异质性意味着单一的成矿模式不能普遍地解释全球所有钾肥矿床的形成。因此,全球钾肥勘探面临着重大挑战。此外,这些矿化机制的特殊性进一步加剧了全球钾肥资源分布的高度不均衡,给有迫切粮食安全需求的国家在实现可持续钾肥供应方面带来了严峻挑战。因此,有必要在现有资源开发的基础上,通过深部钾盐勘探、人工智能预测、合理利用未开发钾盐矿床和寻找未发现钾盐矿床,以及勘探技术体系创新,系统地增强钾盐勘探潜力,确保可持续供应能力。这需要在成矿理论创新、探测技术发展、综合预测模型等方面取得系统突破,推动钾肥资源勘查向精密化、智能化、可持续性方向发展,最终建立资源安全与生态平衡相平衡的全球钾肥供应新框架。
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引用次数: 0
Metallogenic age and fluid evolution of the Baituyingzi W-polymetallic deposit, northern margin of North China Craton: constraints from wolframite U–Pb chronology and scheelite geochemistry 华北克拉通北缘白土营子钨多金属矿床成矿时代与流体演化:来自黑钨矿U-Pb年代学和白钨矿地球化学的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107089
Xiaodan Liu , Guanglai Li , Xiaofei Hao , Shicheng Wang , Jialin Zhong , Yongle Yang , Ji Zhang , Chao Huang
The Baituyingzi tungsten-polymetallic deposit, located on the northern margin of the North China Craton, is the region's only large-scale tungsten deposit. This deposit features two distinct mineralization types: porphyry-style molybdenum (Mo) mineralization and tungsten (W) mineralization within silicified fracture zones. This study focuses on the tungsten mineralization within silicified fracture zones in which wolframite is the primary ore mineral, with subordinate scheelite. Wolframite crystallized during the oxide stage exhibited Fe/Mn molar ratios of 0.04–0.44. U–Pb dating of wolframite yielded a low-intercept Tera-Wasserburg age of 222.2 ± 4.1 Ma. This indicates that the deposit is one of the few large-scale tungsten deposits formed during the Indosinian period in China. The scheelite in the deposit can be classified into four distinct generations, each exhibiting unique geochemical characteristics. Sch-I is notably enriched in Nb and Na but depleted in Sr and Mo. It displays high total rare earth element (REE) contents with negligible light-to-heavy REE fractionation (LREE/HREE = 0.92–1.15) and a weak negative Eu anomaly (δEu = 0.67–0.88). With the evolution of fluids, the Nb and Na contents Sch-II and Sch-III gradually decrease, while Sr and Mo contents show an overall significant increase. The total REE content decreases to 44.19 ppm–296.24 ppm (Sch-II) and 12.29 ppm–115.02 ppm (Sch-III), exhibiting a positive Eu anomaly. In Sch-Ⅳ, the REE content further decreases, Sr content also declines, while Mo content increases significantly (Mo/W ratio: 0.48–1.46), with some phases transitioning to powellite (W). During this stage, Mo extensively substitutes for W and incorporates into the scheelite structure.
A comprehensive geochemical and geochronological data analysis indicates that the Baituyingzi W polymetallic deposit synchronized with the Indosinian orogeny (222.2 ± 4.1 Ma) following the final closure of the Paleo-Asian Ocean along the NCC-Siberia collision zone. Mineralisation occurred during post-collisional extensional tectonics, with ore-forming fluids evolving from reduced to oxidized conditions during the main metallogenic stage. Late-stage meteoric fluids remobilised Mo from earlier porphyry mineralisation, triggering scheelite dissolution-reprecipitation and subsequent tungstite–molybdenite formation.
白土营子钨多金属矿床位于华北克拉通北缘,是该区唯一的大型钨矿床。该矿床具有两种明显的成矿类型:斑岩型钼矿化和硅化破碎带内的钨矿化。研究了以黑钨矿为主,白钨矿为辅的硅化破碎带钨矿化特征。氧化阶段结晶的黑钨矿Fe/Mn摩尔比为0.04 ~ 0.44。对黑钨矿进行U-Pb测年,得到低截距Tera-Wasserburg年龄为222.2±4.1 Ma。这表明该矿床是中国为数不多的形成于印支期的大型钨矿之一。矿床中的白钨矿可划分为4代,每代都表现出独特的地球化学特征。Sch-I富集Nb和Na,富集Sr和Mo,总稀土元素(REE)含量高,轻重稀土分异(LREE/HREE = 0.92 ~ 1.15)可忽略不计,Eu呈弱负异常(δEu = 0.67 ~ 0.88)。随着流体演化,Nb、Na、Sch-II、Sch-III含量逐渐降低,Sr、Mo含量整体呈显著升高趋势。稀土元素总含量分别为44.19 ppm ~ 296.24 ppm (Sch-II)和12.29 ppm ~ 115.02 ppm (Sch-III),呈Eu正异常。在Sch-Ⅳ中,REE含量进一步降低,Sr含量也下降,Mo含量显著增加(Mo/W比值为0.48 ~ 1.46),部分相转变为powellite (W)。在这一阶段,Mo广泛取代W并融入白钨矿结构中。综合地球化学和年代资料分析表明,白图英子W型多金属矿床与古亚洲洋最终闭合后的印支造山运动(222.2±4.1 Ma)同步。成矿作用发生在碰撞后伸展构造时期,成矿流体在主要成矿阶段由还原状态演化为氧化状态。晚期的大气流体从早期斑岩矿化中重新吸收了Mo,引发白钨矿溶解-再沉淀和随后的钨辉钼矿形成。
{"title":"Metallogenic age and fluid evolution of the Baituyingzi W-polymetallic deposit, northern margin of North China Craton: constraints from wolframite U–Pb chronology and scheelite geochemistry","authors":"Xiaodan Liu ,&nbsp;Guanglai Li ,&nbsp;Xiaofei Hao ,&nbsp;Shicheng Wang ,&nbsp;Jialin Zhong ,&nbsp;Yongle Yang ,&nbsp;Ji Zhang ,&nbsp;Chao Huang","doi":"10.1016/j.oregeorev.2025.107089","DOIUrl":"10.1016/j.oregeorev.2025.107089","url":null,"abstract":"<div><div>The Baituyingzi tungsten-polymetallic deposit, located on the northern margin of the North China Craton, is the region's only large-scale tungsten deposit. This deposit features two distinct mineralization types: porphyry-style molybdenum (Mo) mineralization and tungsten (W) mineralization within silicified fracture zones. This study focuses on the tungsten mineralization within silicified fracture zones in which wolframite is the primary ore mineral, with subordinate scheelite. Wolframite crystallized during the oxide stage exhibited Fe/Mn molar ratios of 0.04–0.44. U–Pb dating of wolframite yielded a low-intercept Tera-Wasserburg age of 222.2 ± 4.1 Ma. This indicates that the deposit is one of the few large-scale tungsten deposits formed during the Indosinian period in China. The scheelite in the deposit can be classified into four distinct generations, each exhibiting unique geochemical characteristics. Sch-I is notably enriched in Nb and Na but depleted in Sr and Mo. It displays high total rare earth element (REE) contents with negligible light-to-heavy REE fractionation (LREE/HREE = 0.92–1.15) and a weak negative Eu anomaly (δEu = 0.67–0.88). With the evolution of fluids, the Nb and Na contents Sch-II and Sch-III gradually decrease, while Sr and Mo contents show an overall significant increase. The total REE content decreases to 44.19 ppm–296.24 ppm (Sch-II) and 12.29 ppm–115.02 ppm (Sch-III), exhibiting a positive Eu anomaly. In Sch-Ⅳ, the REE content further decreases, Sr content also declines, while Mo content increases significantly (Mo/W ratio: 0.48–1.46), with some phases transitioning to powellite (W). During this stage, Mo extensively substitutes for W and incorporates into the scheelite structure.</div><div>A comprehensive geochemical and geochronological data analysis indicates that the Baituyingzi W polymetallic deposit synchronized with the Indosinian orogeny (222.2 ± 4.1 Ma) following the final closure of the Paleo-Asian Ocean along the NCC-Siberia collision zone. Mineralisation occurred during post-collisional extensional tectonics, with ore-forming fluids evolving from reduced to oxidized conditions during the main metallogenic stage. Late-stage meteoric fluids remobilised Mo from earlier porphyry mineralisation, triggering scheelite dissolution-reprecipitation and subsequent tungstite–molybdenite formation.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"188 ","pages":"Article 107089"},"PeriodicalIF":3.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the fractal characteristics of sediment element geochemistry in the Qiongdongnan Basin and its implications for gas hydrates 琼东南盆地沉积物元素地球化学分形特征及其对天然气水合物的启示
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107087
Yan Zhang , Junxi Feng , Qing Chen
The offshore slope of Qiongdongnan Basin represent a highly prospective zone for gas-hydrate prospecting in the northern South China Sea. The geochemical characteristics of sediment elements in this area provide significant insights into deep methane migration and hydrate formation. Traditional methods for hydrate identification, such as bottom simulating reflectors and gas geochemistry, often suffer from limited accuracy and non-unique responses. This study introduces multifractal theory and local singularity analysis to systematically investigate the fractal characteristics of sediment element distribution from an element geochemical perspective, as well as their implications for in the exploration of gas hydrates. Based on data from major, trace, and rare earth elements in surface sediment samples in an area for gas hydrate investigation in the Qiongdongnan Basin, and considering the regional geological context, we find that the distribution of sediment elements exhibits pronounced multifractal characteristics. The multifractal spectrum (f(α)) parameters effectively characterize the complexity of element spatial distribution, revealing the evolution of sediment sources and depositional environments. Specifically, the upper layer is dominated by authigenic marine sediments, reflecting a stable depositional environment; the middle layer represents a transition from authigenic marine sediments to terrigenous clastic deposits; while the lower layer indicates a mixture of both, suggesting the influence of multi-phase sedimentation and fluid activity. Local singularity analysis further identified regions with low singularity indices (α) that are highly coupled with enrichment zones of elements such as Ca and Sr. These regions may be associated with redox interfaces related to methane leakage and exhibit a high spatial overlap with known hydrate sampling locations, indicating that fractal parameters can serve as effective geochemical indicators for identifying hydrate accumulation zones. This research combines fractal theory with element geochemistry of sediments, providing a new quantitative approach and methodological support for gas hydrate exploration in the Qiongdongnan Basin, and significantly enhances our understanding of the mechanisms of hydrate formation in the northern South China Sea.
琼东南盆地近海斜坡区是南海北部天然气水合物勘探的远景区。本区沉积物元素地球化学特征对研究深部甲烷运移和水合物形成具有重要意义。传统的水合物识别方法,如底部模拟反射器和气体地球化学,往往存在精度有限和非唯一响应的问题。本文引入多重分形理论和局部奇异分析,从元素地球化学的角度系统研究了沉积元素分布的分形特征及其对天然气水合物勘探的启示。通过对琼东南盆地某天然气水合物调查区表层沉积物样品中主要元素、微量元素和稀土元素的分析,结合区域地质背景,发现沉积物元素的分布具有明显的多重分形特征。多重分形谱(f(α))参数有效表征了元素空间分布的复杂性,揭示了沉积源和沉积环境的演化。其中,上层以自生海相沉积为主,沉积环境稳定;中间层为自生海相沉积向陆源碎屑沉积过渡;而下层则是两者的混合,表明多相沉积和流体活动的影响。局部奇异性分析进一步发现了与Ca、sr等元素富集带高度耦合的低奇异指数(α)区域,这些区域可能与甲烷泄漏相关的氧化还原界面有关,且与已知水合物采样位置具有较高的空间重叠,表明分形参数可以作为识别水合物富集带的有效地球化学指标。本研究将分形理论与沉积物元素地球化学相结合,为琼东南盆地天然气水合物勘探提供了新的定量方法和方法支持,显著提高了对南海北部水合物形成机制的认识。
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引用次数: 0
Delineation of new mineral prospects using ZY1-02D data in the Chitral Region, Hindukush, NW Pakistan 利用ZY1-02D数据在巴基斯坦西北部Hindukush的Chitral地区圈定新的矿产远景
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107096
Nazir Ul Islam , Lei Liu , Zhenhua Guo , Yasir Shaheen Khalil , Said Mukhtar Ahmad
Recent advancements in hyperspectral remote sensing have revolutionized mineral detection and enhanced the precision of lithological mapping. The Chitral region, situated in the northwest of Pakistan’s collisional belt, is characterized by the Hindukush mountainous terrain and emerges as a prominent metallogenic zone. The regional structural trend of the region hosts a diverse array of significant mineral potentials, i.e., iron ore bodies, orogenic gold occurrences, polymetallic veins, and copper mineralization, which offers an exciting opportunity to explore these economic mineral. To assess these potentials, this research utilizes ZY1-02D hyperspectral data to delineate mineral information for identifying prospective alteration zones in the Chitral area. We applied False Color Composite (FCC), Mixture Tuned Matched Filtering (MTMF), Spectral Angle Mapper (SAM), and Spectral Index (SI) techniques to ZY1-02D data to detect alteration minerals and delineate prospective zones. The analysis of ZY1-02D data enabled the identification of muscovite/sericite, kaolinite, epidote, chlorite, and calcite, highlighting significant mineralogical changes linked to alteration events. The alteration mineral maps generated from ZY1-02D data align well with established deposits and field assessments, which reveal copper and iron oxide mineralization at four specific spots, i.e., Sewakhth, Chitral City along Jughur Gol, Drosh, and Maroi area. This study highlights the efficacy of ZY1-02D data in enhancing mineral exploration and lithological mapping, providing significant insights for the geoscientific community and advancing the development of remote sensing applications in geological research.
高光谱遥感技术的最新进展使矿物探测发生了革命性的变化,提高了岩性制图的精度。吉德拉尔地区位于巴基斯坦碰撞带的西北部,以兴都库什山脉地形为特征,是一个突出的成矿带。该地区的区域构造趋势具有多种重要的矿产潜力,即铁矿体、造山带金矿、多金属矿脉和铜矿化,为勘探这些经济矿产提供了令人兴奋的机会。为了评估这些潜力,本研究利用ZY1-02D高光谱数据圈定矿物信息,以识别Chitral地区的潜在蚀变带。我们将假彩色合成(FCC)、混合调谐匹配滤波(MTMF)、光谱角成像仪(SAM)和光谱指数(SI)技术应用于ZY1-02D数据,以检测蚀变矿物并圈定远景带。通过对ZY1-02D数据的分析,可以识别出白云母/绢云母、高岭石、绿泥石和方解石,突出了与蚀变事件相关的重要矿物学变化。由ZY1-02D数据生成的蚀变矿物图与已建立的矿床和现场评估相吻合,显示了四个特定地点的铜和氧化铁矿化,即Sewakhth, Chitral City沿Jughur Gol, Drosh和Maroi地区。本研究突出了ZY1-02D数据在加强矿产勘查和岩性填图方面的有效性,为地球科学界提供了重要的见解,推动了遥感在地质研究中的应用。
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引用次数: 0
Depositional age and metallogenic model of K-bearing sand-gravel brine in pediment alluvial fans of the northern Qaidam Basin, Tibetan Plateau 柴达木盆地北部山墙冲积扇含钾砂砾卤水沉积时代及成矿模式
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107098
Tianyuan Chen , Qishun Fan , Guang Han , Jiubo Liu , Hongkui Bai , Qing Miao , Xiaodong Zhang , Haiyi Bu , Haotian Yang , Yixuan Wang , Tongyan Lü
The K-bearing sand-gravel brine (SGB) deposits have been discovered in the large pediment alluvial fans in the northern and western Qaidam Basin (QB) on the northern Tibetan Plateau (TP). The metallogenic model of the brine deposits remains controversial. In particular, the formation age of the reservoir and its formation mechanism are still unclear. In this study, by utilizing lithological logging, K-content profiling, and multi-dating (OSL, ESR, TCN) of three deep cores, we refined the reservoir chronology and metallogenic model of the new SGB deposits in the Mahai Basin, northern QB. Some key conclusions include: 1) The SGB reservoir was deposited during the Middle Pleistocene (1.1–0.3 Ma), which was driven by the combination of Kunhuang tectonic movement and mid-Pleistocene transition climatic events (1.2–0.6 Ma). 2) A hypothesis was proposed that the sedimentation of salt layers in the terminal salt lakes is later than the formation of alluvial fan in a closed sub-playa. This assumption is verified by the forming ages of fan-lake (salts) in the Dalangtan and Mahai playas. Combining with the spatial-temporary evolution of the anti-S shape on the playas in the QB, we proposed that the age and scales of salt-forming in the respective sub-playa can indicate the depositional age and extent of corresponding SGB. 3) The northward migration of the depocenter in the Mahai Basin, driven by tectonic tilting, led to the lateral migration of brines and the subsequent formation of K-bearing SGB deposits within the pediment alluvial fan reservoirs. 4) The metallogenic model of the fan-lake system in the QB can serve as a theoretical foundation for prospecting deep brine resources in the pediment alluvial fans of various playas, both now and in the future.
在青藏高原北部柴达木盆地北部和西部的大型山墙冲积扇中发现了含钾砂砾卤水矿床。卤水矿床的成矿模式仍有争议。特别是储层的形成年龄及其形成机制尚不清楚。利用岩性测井、钾含量剖面和多测年(OSL、ESR、TCN)技术,对青海省北部马海盆地SGB新矿床的储集年代学和成矿模式进行了研究。主要结论包括:1)SGB储层形成于中更新世(1.1 ~ 0.3 Ma),受昆黄构造运动和中更新世过渡性气候事件(1.2 ~ 0.6 Ma)共同作用。2)提出了终端盐湖盐层沉积晚于封闭次盐湖冲积扇形成的假设。大浪滩和马海盆地扇湖(盐)的形成时代证实了这一假设。结合秦岭坳陷各亚盆上反s形的时空演化,提出各亚盆的成盐年龄和成盐规模可以指示相应亚盆的沉积年龄和程度。3)马海盆地沉积中心在构造倾斜的作用下向北迁移,导致咸水侧向迁移,在山墙冲积扇储层内形成含钾SGB矿床。4)该盆地扇湖体系的成矿模式可为今后和现在在各盆地坡面冲积扇寻找深部盐水资源提供理论依据。
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Ore Geology Reviews
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