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Genesis of high-quality igneous phosphate ore from anorthosite-hosted mafic and ultramafic rocks of the newly discovered Bégin-Lamarche Fe-Ti-P deposit, Grenville Province, Canada 加拿大Grenville省b<s:1> - lamarche铁钛磷矿中高质量火成岩磷矿成因
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-06 DOI: 10.1016/j.oregeorev.2026.107138
Sandeep Banerjee , Peir K. Pufahl , Sarah A.S. Dare , Jean-Philippe Arguin
Anorthosite-hosted igneous phosphate ore satisfies future demands for high-quality phosphate (apatite) for green technologies, such as lithium ferro phosphate (LFP) batteries. The newly discovered Bégin-Lamarche Fe-Ti-P deposit in the central Grenville Province, Canada, is hosted in the Proterozoic Lac-Saint-Jean Anorthositic Suite (∼1157 to 1142 Ma) – one of the world’s largest anorthosite massifs. The deposit extends ∼2.5 km along a NNE-SSW axis with a thickness of ∼200 to 400 m. The deposit contains multiple layers of oxide-apatite ultramafic (OAUM) and oxide-apatite mafic (OAM) mineralization, with some parts reaching unusually high amounts of fluorapatite (up to 86 vol%). The OAUM rocks commonly contain a higher amount of fluorapatite (18–86 %) than that of the OAM rocks (up to 26 %). Both OAUM (∼0 % plagioclase) and OAM (∼4–69 ‰ plagioclase) rocks contain variable amounts of olivine, orthopyroxene, amphibole, biotite, ilmenite, and magnetite. The positive correlations between the Cl as well as REE + Y contents in fluorapatite and the Mg# of coexisting orthopyroxene indicate that fluorapatite with low Cl and REE + Y contents crystallized during the late stages of magma crystallization. A high amount of fluorapatite crystallization during the initial stages of magma crystallization decreased the Cl and REE + Y concentrations of the late-stage magma. Therefore, the Mg# of orthopyroxene provides an exploration tool for targeting the desirable low Cl-phosphate ore in this type of deposit. Furthermore, low Al2O3 contents (0.88–2.47 wt%) of orthopyroxene from the mineralized rocks of the deposit indicate that the magma crystallized at mid-low crustal levels (≤3.1 kbar, i.e., ≤11.7 km). The early crystallizing OAUM rocks (∼0 % plagioclase) with high fluorapatite contents (18–86 %) indicate that the absence of plagioclase among the crystallizing phases helped maintain a high calcium (Ca) content in the magma. The high Ca content ultimately kept the required P2O5 content low enough for apatite saturation, which facilitated apatite crystallization for a longer duration, with a high volume at the initial stages of crystallization. Similar to other anorthosite (or mafic rock)-hosted phosphate deposits of the Grenville Province, the deposit represents a high-quality, environmentally friendly phosphate ore with a low amount of sulfide minerals (<1 vol%), Pb (≤11 ppm), Th (≤2 ppm), and U (≤2 ppm).
斜长岩火成岩磷矿石满足未来绿色技术对高品质磷灰石的需求,如磷酸铁锂(LFP)电池。加拿大中部格伦维尔省新发现的bsamkin - lamarche Fe-Ti-P矿床位于元古宙Lac-Saint-Jean斜长岩套(~ 1157 ~ 1142 Ma)中,这是世界上最大的斜长岩块之一。矿床沿NNE-SSW轴延伸~ 2.5 km,厚度为~ 200 ~ 400 m。该矿床含有多层氧化-磷灰石超镁铁性(OAUM)和氧化-磷灰石基性(OAM)矿化,某些部分的氟磷灰石含量异常高(高达86%)。OAUM岩石通常比OAM岩石含有更多的氟磷灰石(18 - 86%)(高达26%)。OAUM(~ 0%斜长石)和OAM(~ 4-69‰斜长石)岩石均含有不同数量的橄榄石、正辉石、角闪孔、黑云母、钛铁矿和磁铁矿。氟磷灰石中的Cl和REE + Y含量与共存正辉石的Mg#呈正相关,表明低Cl和REE + Y含量的氟磷灰石在岩浆结晶后期结晶。岩浆结晶初期大量的氟磷灰石结晶降低了后期岩浆的Cl和REE + Y浓度。因此,正辉石的mg#为该类型矿床寻找理想的低cl -磷矿提供了勘探工具。此外,矿化岩石中正辉石Al2O3含量低(0.88-2.47 wt%),表明岩浆在中低地壳水平(≤3.1 kbar,即≤11.7 km)结晶。早期结晶的OAUM岩石(~ 0%斜长石)具有高氟磷灰石含量(18 - 86%),表明结晶相中斜长石的缺失有助于保持岩浆中高钙含量。高Ca含量最终使磷灰石所需的P2O5含量保持在足够低的水平,使磷灰石达到饱和状态,从而有利于磷灰石结晶持续更长的时间,在结晶初期具有较高的体积。与Grenville省的其他斜长岩(或基性岩)磷矿相似,该矿床是一种高品质、环保的磷矿,硫化物矿物含量低(<1 vol%), Pb(≤11 ppm)、Th(≤2 ppm)和U(≤2 ppm)。
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引用次数: 0
HyperMinNet: A hypergraph-based framework incorporating high-order relationships for mineral prospectivity mapping HyperMinNet:一个基于超图的框架,包含用于矿产远景映射的高阶关系
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-05 DOI: 10.1016/j.oregeorev.2026.107157
Ying Yang , Li Wen , Changjie Cao , Yunhe Li , Bingli Liu , Yunhui Kong , Cheng Li , Zhongli Zhou
Mineral Prospectivity Mapping (MPM) is a fundamental task in geosciences for identifying regions with high mineral potential. High-order geological associations are intrinsic to mineralization processes, yet have not been explicitly represented or effectively mined in existing studies, even though mineralization often arises from the joint influence of multiple geological factors interacting in complex ways. To address this problem, this study introduces HyperMinNet, a hypergraph-based framework for modeling and discovering high-order relationships in MPM. In HyperMinNet, hyperedges are constructed across both spatial and attribute domains to capture multi-factor geological associations. The Density-Based Spatial Clustering of Applications with Noise (DBSCAN) algorithm plays a central role in grouping geologically related units, thereby highlighting complex, spatially coherent associations beyond simple pairwise relationships. To further enhance the model’s ability to recognize informative geological patterns, an attention mechanism is employed to adaptively focus on critical associations, while a center loss function mitigates the influence of limited positive mineralization samples by enhancing the distinctiveness of learned representations. Experiments conducted in the Lhasa region demonstrate the effectiveness of the proposed framework, where HyperMinNet achieved an accuracy of 0.9042 and an Area Under the Curve (AUC) of 0.9511, confirming its strong potential in advancing mineral prospectivity mapping.
矿产远景填图(MPM)是地球科学中一项识别高矿产潜力区域的基本任务。高阶地质关联是成矿过程所固有的,但在现有研究中尚未明确表示或有效挖掘,尽管成矿往往是由多种地质因素以复杂方式相互作用的共同影响产生的。为了解决这个问题,本研究引入了HyperMinNet,这是一个基于超图的框架,用于在MPM中建模和发现高阶关系。在HyperMinNet中,跨空间和属性域构建超边缘以捕获多因素地质关联。基于密度的噪声应用空间聚类(DBSCAN)算法在分组地质相关单元中起着核心作用,从而突出了复杂的、空间上连贯的关联,而不是简单的两两关系。为了进一步增强模型识别信息地质模式的能力,采用了一种注意力机制来自适应地关注关键关联,而中心损失函数通过增强学习表征的独特性来减轻有限正矿化样本的影响。在拉萨地区进行的实验证明了该框架的有效性,HyperMinNet的精度为0.9042,曲线下面积(AUC)为0.9511,证实了其在推进矿产找矿制图方面的强大潜力。
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引用次数: 0
Magmatism and mineralization in the Sangye-Qulong magmatic section, Southern Tibet 藏南桑冶—曲陇岩浆剖面岩浆作用与成矿作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-08 DOI: 10.1016/j.oregeorev.2026.107161
Leilei Dong , Huawei Li , Zhiming Yang
The Sangye-Qulong magmatic section in the Gangdese belt of southern Tibet records magmatic evolution spanning from oceanic subduction to continental collision. This work combines zircon U-Pb geochronology, whole-rock geochemistry, and Sr-Nd isotopes from pre-, syn-, and post-collisional intrusions along a ∼ 60 km NE-SW section. Results reveal that the Cretaceous high-Mg diorites originated through partial melting of oceanic slab, while the low-Mg adakitic granitoids (91.6 ± 1.5 Ma) were formed via lower crust melting. Syn-collisional Paleocene-Eocene granitoids (64.1–52.5 Ma) originated from juvenile lower crust during slab rollback. Miocene adakitic granitoids were derived from the thickened lower crust, and dioritic enclaves (16.5 ± 0.2 Ma) show a mixing trend between lower crust adakitic melts and Indian continental crust.
The Cretaceous rocks are hydrous and oxidized, associated with the Kelu Cu-Au mineralization. The scarcity of mineralization in syn-collisional rocks is largely linked to their limited water content and low oxygen fugacity. The Miocene rocks related to the Qulong porphyry deposit have the highest Sr/Y, V/Sc, Eu/Eu*/Y ratios and most enriched Sr-Nd isotopes, indicating high magmatic water content, oxygen fugacity, and the greater involvement of the Indian continental material. These findings demonstrate the Indian continental slab’s crucial role in the formation of post-collisional porphyry deposits.
藏南冈底斯带桑溪-曲陇岩浆剖面记录了从大洋俯冲到大陆碰撞的岩浆演化过程。这项工作结合了锆石U-Pb年代学、全岩地球化学和Sr-Nd同位素,这些同位素来自沿NE-SW ~ 60 km剖面的碰撞前、同步和碰撞后侵入体。结果表明,白垩系高镁闪长岩形成于洋板部分熔融作用,低镁阿达奇花岗岩(91.6±1.5 Ma)形成于下地壳熔融作用。同碰撞古新世—始新世花岗岩类(64.1 ~ 52.5 Ma)起源于板块回退时期的下地壳幼体。中新世埃达质花岗岩类来源于增厚的下地壳,闪长岩包体(16.5±0.2 Ma)表现出下地壳埃达质熔体与印度大陆地壳混合的趋势。白垩系岩石具有含水氧化特征,与克鲁铜金成矿作用有关。同碰撞岩石中矿化的缺乏主要与它们有限的含水量和低氧逸度有关。与曲龙斑岩矿床相关的中新世岩石Sr/Y、V/Sc、Eu/Eu*/Y比值最高,Sr- nd同位素最富集,表明岩浆水含量高,氧逸度高,印度大陆物质参与程度较大。这些发现证明了印度大陆板块在碰撞后斑岩矿床形成中的关键作用。
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引用次数: 0
Magnetotelluric signatures for deep copper exploration in North Xinjiang, China: Revealing controls of deposit type and sulfide content on geophysical responses 新疆北部深部铜矿的大地电磁特征:揭示矿床类型和硫化物含量对地球物理响应的控制
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-06 DOI: 10.1016/j.oregeorev.2026.107162
Aolin Pan , Aimin Du , Tiebing Liu , Lei Meng , Changhao Li , Changming Yu
Discriminating deep-seated orebodies across diverse copper deposit types remains a challenge in exploration geophysics, largely due to highly variable sulfide mineralization styles and complex host-rock settings. To address this, we conducted an integrated geological–geophysical study that combines deposit geological models with high-frequency audio magnetotelluric (AMT) surveys using the Stratagem EH4 system. Three representative copper deposits in North Xinjiang, China, were examined: the Ashele deposit (volcanogenic massive sulfide, VMS-type, high-grade massive sulfides), the Hongguleleng deposit (Manto-type, moderate-grade vein-style sulfides), and the Baogutu deposit (porphyry-type, low-grade disseminated sulfides).
Geological cross-sections and laboratory measurements of rock electrical properties were integrated to constrain two-dimensional (2D) inversions of the AMT data. The results reveal distinct resistivity signatures for three deposit types: very low resistivity anomalies (10–100 Ω·m) characterize VMS mineralization, moderate resistivity anomalies (100–300 Ω·m) correspond to Manto-type vein systems, and relatively higher yet significant resistivity anomalies (100–1000 Ω·m) are associated with disseminated porphyry mineralization. Furthermore, a series of concealed resistivity anomalies were delineated adjacent to and beneath known orebodies at all three deposits, identifying promising targets for deep exploration. Based on these findings, we propose three resistivity structural patterns: a “lens-over-feeder” geometry for VMS deposits, a “stratabound conductive slab” for Manto-type deposits, and a “conductive ring” structure for porphyry systems. This integrated geology–geophysics approach provides a practical framework for enhancing the detection and targeting of concealed copper mineralization in North Xinjiang and other similar terrains worldwide.
在不同类型的铜矿床中识别深部矿体仍然是勘探地球物理中的一个挑战,这主要是由于硫化物矿化样式的高度变化和复杂的主岩环境。为了解决这个问题,我们进行了一项综合地质地球物理研究,将矿床地质模型与使用Stratagem EH4系统的高频音频大地电磁(AMT)调查相结合。对新疆北部具有代表性的3个铜矿床进行了勘查:阿舍勒铜矿床(火山成因块状硫化物,vms型,高品位块状硫化物)、红古乐冷铜矿床(曼托型,中品位脉状硫化物)和包谷图铜矿床(斑岩型,低品位浸染型硫化物)。将地质剖面和岩石电性的实验室测量结果结合起来,约束AMT数据的二维(2D)反演。结果表明,3种矿床类型具有明显的电阻率特征:极低电阻率异常(10-100 Ω·m)代表VMS矿化特征,中电阻率异常(100-300 Ω·m)代表manto型脉系特征,较高且显著的电阻率异常(100-1000 Ω·m)代表浸染斑岩矿化特征。此外,在三个矿床已知矿体的邻近和下方圈定了一系列隐伏电阻率异常,确定了深部勘探的有利靶区。基于这些发现,我们提出了3种电阻率结构模式:VMS矿床为“透镜-过馈线”结构,manto型矿床为“层控导电板”结构,斑岩体系为“导电环”结构。该方法为加强新疆北部及世界范围内类似地区隐伏铜矿的探测与找矿提供了实用框架。
{"title":"Magnetotelluric signatures for deep copper exploration in North Xinjiang, China: Revealing controls of deposit type and sulfide content on geophysical responses","authors":"Aolin Pan ,&nbsp;Aimin Du ,&nbsp;Tiebing Liu ,&nbsp;Lei Meng ,&nbsp;Changhao Li ,&nbsp;Changming Yu","doi":"10.1016/j.oregeorev.2026.107162","DOIUrl":"10.1016/j.oregeorev.2026.107162","url":null,"abstract":"<div><div>Discriminating deep-seated orebodies across diverse copper deposit types remains a challenge in exploration geophysics, largely due to highly variable sulfide mineralization styles and complex host-rock settings. To address this, we conducted an integrated geological–geophysical study that combines deposit geological models with high-frequency audio magnetotelluric (AMT) surveys using the Stratagem EH4 system. Three representative copper deposits in North Xinjiang, China, were examined: the Ashele deposit (volcanogenic massive sulfide, VMS-type, high-grade massive sulfides), the Hongguleleng deposit (Manto-type, moderate-grade vein-style sulfides), and the Baogutu deposit (porphyry-type, low-grade disseminated sulfides).</div><div>Geological cross-sections and laboratory measurements of rock electrical properties were integrated to constrain two-dimensional (2D) inversions of the AMT data. The results reveal distinct resistivity signatures for three deposit types: very low resistivity anomalies (10–100 Ω·m) characterize VMS mineralization, moderate resistivity anomalies (100–300 Ω·m) correspond to Manto-type vein systems, and relatively higher yet significant resistivity anomalies (100–1000 Ω·m) are associated with disseminated porphyry mineralization. Furthermore, a series of concealed resistivity anomalies were delineated adjacent to and beneath known orebodies at all three deposits, identifying promising targets for deep exploration. Based on these findings, we propose three resistivity structural patterns: a “lens-over-feeder” geometry for VMS deposits, a “stratabound conductive slab” for Manto-type deposits, and a “conductive ring” structure for porphyry systems. This integrated geology–geophysics approach provides a practical framework for enhancing the detection and targeting of concealed copper mineralization in North Xinjiang and other similar terrains worldwide.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107162"},"PeriodicalIF":3.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146192535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magmatic and hydrothermal superimposition in Nb-Ta-Li mineralization at the Hailuoling deposit, South China: Records from columbite-tantalite chronology and mica chemistry 海螺岭铌钽利成矿的岩浆和热液叠加作用:来自铌钽矿年代学和云母化学的记录
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 Epub Date: 2026-01-09 DOI: 10.1016/j.oregeorev.2025.107083
Yu Zhou , Yong Zhang , Zhe Xu , Fangrong Zhang , Jiayong Pan , Haotong Dai , Fushen Zhang , Wei Wan , Bin He , Cong Liu
The Hailuoling Nb–Ta deposit in the Wuyi metallogenic belt of South China represents a typical granite-related rare-metal system that has recently been recognized to host associated Li mineralization. To constrain its metallogenic evolution, we integrate petrological, geochronological, and geochemical data. LA–ICP–MS U–Pb dating of monazite and columbite–tantalite indicates that the porphyritic biotite monzogranite crystallized at 147.2 ± 1.9 Ma, whereas Nb–Ta mineralization occurred at 144.4 ± 2.1 Ma, both during the Late Jurassic–Early Cretaceous transition. Li-bearing micas including protolithionite, zinnwaldite, lithium phengite, and lithium muscovite, in mineralized granite replace primary biotite, feldspar, and quartz and display irregular grain boundaries and well-developed compositional zoning, providing textural evidence for hydrothermal metasomatism. Mica compositions define a systematic evolutionary trend characterized by increasing SiO2 and decreasing FeO contents, while trace element data reveal an initial enrichment followed by depletion of Li, Nb, and Ta. These features support a two-stage model involving an early post-magmatic hydrothermalism stage followed by a later hydrothermal metasomatism stage. Hydrothermal micas are characterized by Nb/Ta ratios of 0.5–2.5 and K/Rb ratios of 8–12. Comparative analyses with micas from unmineralized granites and from the Maoping and Xianghualing deposits highlights the necessity of overprinting by late-stage magmatic–hydrothermal fluids, in combination with external fluid input, to achieve economically significant rare-metal enrichment in early intrusions that did not independently reach ore-forming thresholds. We conclude that the interplay between magmatic differentiation and hydrothermal overprinting is critical for the mobilization and concentration of rare metals in certain granitic systems.
华南武夷成矿带海洛岭铌钽矿床是一个典型的花岗岩相关稀有金属成矿系统,近年来已被确认为伴生李矿化。为了限定其成矿演化,我们综合了岩石学、年代学和地球化学资料。LA-ICP-MS U-Pb定年表明,斑岩型黑云母二长花岗岩的结晶时间为147.2±1.9 Ma,铌钽矿化时间为144.4±2.1 Ma,均发生在晚侏罗世-早白垩世过渡时期。矿化花岗岩中的原橄榄岩、锌walite、锂云母、锂白云母等含锂云母代替原生黑云母、长石和石英,晶界不规则,成分分带发育,为热液交代提供了结构证据。云母的组成呈现出SiO2含量增加、FeO含量减少的系统演化趋势,微量元素数据则呈现出Li、Nb、Ta等元素先富集后富集的变化趋势。这些特征支持两阶段模式,即早期岩浆后热液作用阶段和后期热液交代阶段。热液云母的Nb/Ta比值为0.5 ~ 2.5,K/Rb比值为8 ~ 12。通过与未矿化花岗岩云母和茂坪、香花岭矿床云母的对比分析,认为晚期岩浆-热液流体的套印,结合外部流体输入,在未独立达到成矿阈值的早期侵入体中实现具有经济意义的稀有金属富集是必要的。岩浆分异和热液套印的相互作用对某些花岗岩体系中稀有金属的富集和活化起着至关重要的作用。
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引用次数: 0
(U-Th)/He thermochronology constraints on Cenozoic exhumation of Ke’eryin lithium ore field, eastern Tibet (U-Th)/He热年代学对藏东柯尔音锂矿田新生代发掘的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 Epub Date: 2026-01-22 DOI: 10.1016/j.oregeorev.2026.107133
Jingbo Sun , Wen Chen , Kezhang Qin , Shuangfeng Zhao , Ze Shen , Bin Zhang , Wen Zhang
The Ke’eryin lithium ore field, located in the east of Songpan-Ganzi orogenic belt of Tibetan Plateau, is an important lithium-producing field hosting multiple pegmatite deposits in large to super-large scale. A more complete exhumation history of this ore field is required, and favorable prospecting locations need further identification. Here, we applied (U-Th)/He dating combined with a vertical profile sampling strategy to quantitatively constrain the exhumation process of the Ke’eryin lithium ore field. Zircon (U-Th)/He (ZHe) data and thermal history modeling reveal fast cooling during ∼28–24 Ma, linked to crustal shortening during the India-Eurasia collision. This phase removed ∼3.3 km of overburden, reducing burial depths from ∼5.3 km to ∼2 km. Age-elevation relationships of apatite (U-Th)/He (AHe) combined with thermal history modeling reveal rapid cooling at ∼15 Ma. This rapid cooling episode resulted from the regional uplift and exhumation, with amplification by river incision. The hanging wall (north) experienced greater denudation than the footwall (south), making the footwall a more favorable prospecting area. Combining the zircon and apatite (U-Th)/He data, we calculate a total erosion amount of approximately ∼5 km in the Ke’eryin lithium ore field since the Late Oligocene.
柯尔银锂矿田位于青藏高原松潘—甘孜造山带东段,是我国重要的大型至超大型多伟晶岩矿床产锂田。需要对该矿田进行更完整的发掘历史,并进一步确定有利的找矿位置。本文采用(U-Th)/He定年法结合垂直剖面采样策略,对柯尔银锂矿田的发掘过程进行了定量约束。锆石(U-Th)/He(喆)数据和热历史模拟显示,在~ 28-24 Ma期间,印度-欧亚大陆碰撞期间地壳缩短,导致了快速冷却。这一阶段移除了约3.3公里的覆盖层,将掩埋深度从约5.3公里减少到约2公里。结合热历史模型,磷灰石(U-Th)/He (AHe)的年龄-海拔关系显示在~ 15 Ma时快速冷却。这一快速降温事件是由区域隆升和挖掘引起的,并有河流切割的放大作用。上盘(北)的剥蚀程度大于下盘(南),下盘为有利找矿区。结合锆石和磷灰石(U-Th)/He数据,计算了晚渐新世以来柯二阴锂矿田的总侵蚀量约为~ 5 km。
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引用次数: 0
Mg isotopes and TIMA tracing the mantle source and mineralization process at Bayan Obo Nb-REE-Fe deposit, China 白云鄂博铌稀土铁矿床地幔源及成矿过程的Mg同位素和TIMA示踪
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 Epub Date: 2026-01-16 DOI: 10.1016/j.oregeorev.2026.107127
Qingyan Tang , Zhuoming Li , Chi Zhao , Yan Zhang , Hailong Jin , Biao Chen , Yanjiang Liu , Tianyu Qin , Tengda Yang , Min Qiao , Xinrui Bai , Zeyu Ma
The presence of carbonate materials in the mantle source of carbonatites has long been debated. TIMA and Mg isotope are conducted to reveal the genesis of carbonatites and Bayan Obo Nb-REE-Fe deposit. The δ26Mg values of dolomite carbonatite dykes are lighter than those of the normal mantle, ranging from −0.83 ‰ to −0.43 ‰. The δ26Mg values show marked variation in both coarse-grained dolomite carbonatites (ranging from −0.71 ‰ to −0.03 ‰) and Nb-REE-Fe ores, with the latter exhibiting a broader isotopic range from −0.72 ‰ to +0.31 ‰. Fenite has a δ26Mg value of −0.19 ‰, while limestones display the lowest δ26Mg values overall, with a narrow range of −1.88 ‰ to −1.86 ‰. This study indicates that Bayan Obo carbonatites originated from the low-degree partial melting of carbonated peridotites. The ancient carbonate materials were introduced into the mantle source via decarbonation. Whole-rock δ26Mg values are controlled by multiple mineral phases rather than a single phase. The mantle source, magmatic differentiation processes and subsequent hydrothermal fluid metasomatism collectively influence the Mg isotope compositions in the Bayan Obo area. The δ26Mg values below the mantle value may result from minerals enriched in light Mg isotopes. Therefore, ancient carbonatites also involve the addition of carbonate materials. Element correlations suggest that acidic conditions favor the migration and enrichment of Nb and REE, whereas alkaline conditions promote the migration and enrichment of REE but are unfavourable for Nb migration.
碳酸盐岩地幔源中是否存在碳酸盐物质一直是人们争论的焦点。利用TIMA和Mg同位素揭示了碳酸盐岩和白云鄂博铌稀土铁矿床的成因。白云岩碳酸岩岩脉的δ26Mg值较正常地幔的δ26Mg值轻,范围为- 0.83‰~ - 0.43‰。粗粒白云岩碳酸盐(- 0.71‰~ - 0.03‰)和Nb-REE-Fe矿石的δ26Mg值变化明显,其中Nb-REE-Fe矿石的δ26Mg值变化范围较广,为- 0.72‰~ +0.31‰。灰岩的δ26Mg值为- 0.19‰,灰岩δ26Mg值最低,范围在- 1.88‰~ - 1.86‰之间。研究表明,白云鄂博碳酸岩起源于碳酸化橄榄岩的低程度部分熔融作用。古碳酸盐物质通过脱碳作用进入地幔源区。全岩δ26Mg值受多个矿物相控制,而非单一矿物相。地幔源、岩浆分异过程及后续热液交代作用共同影响了白云鄂博地区镁同位素组成。低于地幔值的δ26Mg值可能是由富含轻Mg同位素的矿物形成的。因此,古碳酸盐岩还涉及碳酸盐物质的添加。元素对比表明,酸性条件有利于Nb和REE的迁移富集,而碱性条件有利于REE的迁移富集,不利于Nb的迁移。
{"title":"Mg isotopes and TIMA tracing the mantle source and mineralization process at Bayan Obo Nb-REE-Fe deposit, China","authors":"Qingyan Tang ,&nbsp;Zhuoming Li ,&nbsp;Chi Zhao ,&nbsp;Yan Zhang ,&nbsp;Hailong Jin ,&nbsp;Biao Chen ,&nbsp;Yanjiang Liu ,&nbsp;Tianyu Qin ,&nbsp;Tengda Yang ,&nbsp;Min Qiao ,&nbsp;Xinrui Bai ,&nbsp;Zeyu Ma","doi":"10.1016/j.oregeorev.2026.107127","DOIUrl":"10.1016/j.oregeorev.2026.107127","url":null,"abstract":"<div><div>The presence of carbonate materials in the mantle source of carbonatites has long been debated. TIMA and Mg isotope are conducted to reveal the genesis of carbonatites and Bayan Obo Nb-REE-Fe deposit. The δ<sup>26</sup>Mg values of dolomite carbonatite dykes are lighter than those of the normal mantle, ranging from −0.83 ‰ to −0.43 ‰. The δ<sup>26</sup>Mg values show marked variation in both coarse-grained dolomite carbonatites (ranging from −0.71 ‰ to −0.03 ‰) and Nb-REE-Fe ores, with the latter exhibiting a broader isotopic range from −0.72 ‰ to +0.31 ‰. Fenite has a δ<sup>26</sup>Mg value of −0.19 ‰, while limestones display the lowest δ<sup>26</sup>Mg values overall, with a narrow range of −1.88 ‰ to −1.86 ‰. This study indicates that Bayan Obo carbonatites originated from the low-degree partial melting of carbonated peridotites. The ancient carbonate materials were introduced into the mantle source via decarbonation. Whole-rock δ<sup>26</sup>Mg values are controlled by multiple mineral phases rather than a single phase. The mantle source, magmatic differentiation processes and subsequent hydrothermal fluid metasomatism collectively influence the Mg isotope compositions in the Bayan Obo area. The δ<sup>26</sup>Mg values below the mantle value may result from minerals enriched in light Mg isotopes. Therefore, ancient carbonatites also involve the addition of carbonate materials. Element correlations suggest that acidic conditions favor the migration and enrichment of Nb and REE, whereas alkaline conditions promote the migration and enrichment of REE but are unfavourable for Nb migration.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107127"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling hydrothermal center in the Xiayu Ag-Pb-Zn-Au Orefield, central China: Insights from geology evidence and ore grade characteristic 揭示下峪银铅锌金矿区热液中心:地质证据与矿石品位特征
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 Epub Date: 2026-01-18 DOI: 10.1016/j.oregeorev.2026.107116
Lei Zhu , Min Liu , Xiuquan Wang , Wei Jian , Jingwen Mao , Yongfei Tian , Li Jiang , Yongqi Su
The Xiayu orefield, situated within the Xiong’ershan ore concentration area of the southern margin of the North China Craton, is an important polymetallic production region. Recent studies suggest that the steeply dipping Ag-Pb-Zn-Au veins belong to a magmatic-hydrothermal system related to unexposed intrusions. The hydrothermal center and associated metal zoning, however, remain unclear. Addressing these knowledge gaps is essential for elucidating ore-forming processes and refining regional exploration strategies. This study addresses these issues through a statistical analysis of 436,003 ore grades, integrated with field and petrographic investigations. Our results reveal clear patterns of metal zoning that show a hydrothermal center is located under the southwestern part of Haopinggou deposit in the Xiayu orefield. Samples from this orefield clearly exhibit six paragenetic stages, in which sphalerite precipitation was followed by gold and lead mineralization, which in turn preceded the formation of chalcopyrite and argentite, with native silver occurring in the final stage. Based on these stages, we employed characteristic metal ratios to provide evidence for elemental zonings: Au/Ag, Zn/Ag, and Pb/Ag ratios increase toward the southwestern Haopinggou deposit. These variations reflect the sequential deposition of ore minerals, which is jointly governed by mineralization stages, decreasing temperature gradients, and intensifying fluid-rock interaction distal to the hydrothermal center. The observation aligns with the geological features of the Xiayu orefield, specifically the presence and spatial configuration of breccia pipes. This interpretation is further substantiated by a synthesis of existing fluid inclusion information, hydrothermal alteration assemblages, and geochronological constraints. These findings demonstrate the utility of statistical analysis methodologies in mineral exploration, providing a robust framework for identifying hydrothermal centers and delineating exploration targets.
下峪矿田位于华北克拉通南缘熊儿山矿集中区内,是一个重要的多金属生产区。近年来的研究表明,急倾银铅锌金脉属岩浆热液系统,与未暴露的侵入体有关。然而,热液中心和相关的金属带仍然不清楚。解决这些知识差距对于阐明成矿过程和完善区域勘探策略至关重要。本研究通过对436,003个矿石品位的统计分析,结合现场和岩石学调查,解决了这些问题。结果表明,下峪矿田郝坪沟矿床西南下部存在热液中心。该矿田样品明显表现出6个共生阶段,闪锌矿沉淀后,金、铅成矿,继而形成黄铜矿和银辉铁矿,在最后阶段出现天然银。在此基础上,利用特征金属比值为元素分带提供依据:Au/Ag、Zn/Ag、Pb/Ag比值向郝坪沟矿床西南方向呈递增趋势。这些变化反映了矿石矿物的顺序沉积,受成矿阶段、温度梯度降低和热液中心远端流体-岩石相互作用加剧的共同控制。观测结果与下峪矿田的地质特征吻合,特别是角砾岩管的存在和空间构型。现有流体包裹体信息、热液蚀变组合和地质年代学约束进一步证实了这一解释。这些发现证明了统计分析方法在矿产勘探中的实用性,为识别热液中心和圈定勘探目标提供了一个强有力的框架。
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引用次数: 0
Petrophysical signature of the Salobo IOCG deposit: Insights into lithology, hydrothermal alteration, and mineralization Salobo IOCG矿床的岩石物理特征:岩性、热液蚀变和成矿作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 Epub Date: 2026-01-19 DOI: 10.1016/j.oregeorev.2026.107119
Moriá Caroline de Araújo , Adalene Moreira Silva , Catarina Labouré Bemfica Toledo , Daniel Shkromada de Oliveira , Victor Nogueira , Juliana Araújo , Edvaldo Gomes Farias , Lucas Nunes Morais
The integration of petrophysical and mineralogical data is essential for understanding variations in the physical properties of hydrothermally altered rocks. In this study, petrophysical data were combined with mineralogical analyses obtained through TIMA (TESCAN Integrated Mineral Analyzer), QEMSCAN (Quantitative Evaluation of Minerals by Scanning Electron Microscopy), and LIBS (Laser-Induced Breakdown Spectroscopy core scanner) to characterize the petrophysical footprint of the Salobo IOCG (Iron Oxide Copper-Gold) deposit. The analysis and interpretation of rock physical properties and mineral mapping data reveal that the Salobo alteration zones exhibit distinct petrophysical signatures. The calcic-sodic alteration zone is characterized by low density (∼2.89 g/cm3), low magnetic susceptibility (∼0.091 SI), and moderate resistivity (∼2781 Ω.m). A newly identified Ca-Fe-K subzone marks the transition from Ca-Na to Fe- and K-enriched systems, presenting a slight increase in resistivity (∼2958 Ω.m). Iron enrichment zones display systematic transitions, progressing from grunerite-dominated associations to almandine-rich zones and magnetite precipitation. These zones are distinguished by high density (>30 g/cm3), elevated magnetic susceptibility (up to 7.516 SI), and increased chargeability (∼62.2–89.7 mV/V). The K-Fe subzone and its advanced forms are characterized mainly by almandine and biotite, along with intense late chloritization that significantly affects petrophysical signatures. Potassic alteration displays a strong decrease in resistivity (∼1658 Ω.m), attributed to biotite and sulfides. This study highlights the importance of integrating multi-source data to enhance the understanding of mineral systems through mineralogical and petrophysical datasets. Petrophysical properties, controlled by mineral composition, provide insights into Salobo’s geophysical signature and petrophysical footprint. Thus, a schematic model was developed to illustrate the petrophysical signature of each subzone hydrothermal alteration zone, linking variations in density, magnetic susceptibility, resistivity, and chargeability to mineralogical data. The presented methodology provides a framework applicable to other IOCG deposits, similar systems, and potential targets, enhancing exploration efficiency and providing valuable strategies for advancing mineral exploration on a broader scale.
岩石物理和矿物学数据的整合对于理解热液蚀变岩的物理性质变化至关重要。在这项研究中,岩石物理数据与通过TIMA (TESCAN集成矿物分析仪)、QEMSCAN(扫描电子显微镜矿物定量评价)和LIBS(激光诱导击穿光谱岩心扫描仪)获得的矿物学分析相结合,表征了Salobo(氧化铁铜金矿)矿床的岩石物理足迹。岩石物性分析与解释和矿物填图资料表明,萨洛博蚀变带具有明显的岩石物性特征。钙钠蚀变带具有低密度(~ 2.89 g/cm3)、低磁化率(~ 0.091 SI)、中等电阻率(~ 2781 Ω.m)的特征。新发现的Ca-Fe-K亚带标志着从Ca-Na到富Fe和富k体系的转变,呈现出电阻率的轻微增加(~ 2958 Ω.m)。富铁带呈现出从绿铜矿为主的组合到富铝带和磁铁矿沉淀的系统转变。这些区域的特点是高密度(>30 g/cm3)、磁化率升高(高达7.516 SI)和可充电性增加(~ 62.2-89.7 mV/V)。钾铁亚带及其晚期形态主要以铝榴石和黑云母为特征,并伴有强烈的晚期绿泥化作用,对岩石物性特征有显著影响。钾蚀变显示出电阻率的强烈下降(~ 1658 Ω.m),归因于黑云母和硫化物。该研究强调了通过矿物学和岩石物理数据集整合多源数据以增强对矿物系统理解的重要性。岩石物理性质由矿物组成控制,为Salobo的地球物理特征和岩石物理足迹提供了深入了解。因此,建立了一个示意图模型来说明每个亚带热液蚀变带的岩石物理特征,将密度、磁化率、电阻率和电荷率的变化与矿物学数据联系起来。所提出的方法提供了一个适用于其他IOCG矿床、类似系统和潜在目标的框架,提高了勘探效率,并为在更大范围内推进矿产勘探提供了有价值的策略。
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引用次数: 0
Petrogenesis of the Ke’eryin Li-rich granitic rocks and its implications for Li-mineralization in the eastern Songpan-Garzê Orogenic Belt, China Songpan-Garzê造山带东部柯尔寅富锂花岗质岩石成因及其对锂矿化的指示意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 Epub Date: 2026-01-19 DOI: 10.1016/j.oregeorev.2026.107102
Lingfang Wu , Qingguo Zhai , Yue Tang , Peiyuan Hu , Yiming Liu , Jinyong Li , Ning Yang , Sheng Chang
The Songpan–Garzê Orogenic Belt is a world-famous Li mineralization belt in China, but the petrogenesis and source of the Li-rich granitic rocks remain unclear. To address this issue, we investigated the Li-rich granitic rocks from the Ke’eryin, located in the eastern part of the Songpan–Garzê Orogenic Belt. Zircon U–Pb dating yielded crystallization ages for a two-mica granite (205 ± 1 Ma), aplite (204 ± 2 Ma), spodumene-free pegmatite (203 ± 1 Ma) and spodumene-bearing pegmatite (206 ± 2 Ma), indicating a roughly coeval magmatic-hydrothermal activity. Systematic decreases in Nb/Ta and Zr/Hf ratios, combined with negative correlations between CaO, Al2O3, P2O5, MgO, and SiO2, reveal progressive magmatic differentiation from granite through to aplite and finally the pegmatites. The distinct Sn enrichment in the spodumene-bearing pegmatite records a transition from an early H2O-poor to a late water-rich magmatic system. All rocks display elevated Rb/Sr and Rb/Ba ratios, along with uniform Sr–Nd isotopic signatures that resemble those of Triassic metapelites (87Sr/86Sri = 0.7030 ∼ 0.7148, εNd(t) = −9.2 ∼ −7.3). Therefore, the Ke’eryin Li-rich granitic rocks were generated through muscovite-dehydration melting of a metapelitic source, and progressive magmatic differentiation subsequently concentrated Li and other rare metals.
Songpan-Garzê造山带是中国著名的锂成矿带,但其富锂花岗质岩石成因及来源尚不清楚。为了解决这一问题,我们对位于Songpan-Garzê造山带东部的柯尔银富锂花岗岩进行了研究。锆石U-Pb定年结果显示,两云母花岗岩(205±1 Ma)、长石(204±2 Ma)、无锂辉石伟晶岩(203±1 Ma)和含锂辉石伟晶岩(206±2 Ma)的结晶年龄大致相同,表明岩浆-热液活动大致相同。Nb/Ta和Zr/Hf比值的系统性下降,以及CaO、Al2O3、P2O5、MgO和SiO2之间的负相关关系,表明岩浆分异从花岗岩到长石,最后是伟晶岩。含锂辉石伟晶岩中明显的锡富集标志着早期贫水岩浆系统向晚期富水岩浆系统的转变。所有岩石Rb/Sr和Rb/Ba比值均升高,Sr - nd同位素特征一致,与三叠纪变质岩相似(87Sr/86Sri = 0.7030 ~ 0.7148, εNd(t) =−9.2 ~−7.3)。因此,柯尔隐富锂花岗质岩石是由变质长岩源区的白云母—脱水熔融作用形成的,岩浆分异过程使锂等稀有金属富集。
{"title":"Petrogenesis of the Ke’eryin Li-rich granitic rocks and its implications for Li-mineralization in the eastern Songpan-Garzê Orogenic Belt, China","authors":"Lingfang Wu ,&nbsp;Qingguo Zhai ,&nbsp;Yue Tang ,&nbsp;Peiyuan Hu ,&nbsp;Yiming Liu ,&nbsp;Jinyong Li ,&nbsp;Ning Yang ,&nbsp;Sheng Chang","doi":"10.1016/j.oregeorev.2026.107102","DOIUrl":"10.1016/j.oregeorev.2026.107102","url":null,"abstract":"<div><div>The Songpan–Garzê Orogenic Belt is a world-famous Li mineralization belt in China, but the petrogenesis and source of the Li-rich granitic rocks remain unclear. To address this issue, we investigated the Li-rich granitic rocks from the Ke’eryin, located in the eastern part of the Songpan–Garzê Orogenic Belt. Zircon U–Pb dating yielded crystallization ages for a two-mica granite (205 ± 1 Ma), aplite (204 ± 2 Ma), spodumene-free pegmatite (203 ± 1 Ma) and spodumene-bearing pegmatite (206 ± 2 Ma), indicating a roughly coeval magmatic-hydrothermal activity. Systematic decreases in Nb/Ta and Zr/Hf ratios, combined with negative correlations between CaO, Al<sub>2</sub>O<sub>3</sub>, P<sub>2</sub>O<sub>5</sub>, MgO, and SiO<sub>2</sub>, reveal progressive magmatic differentiation from granite through to aplite and finally the pegmatites. The distinct Sn enrichment in the spodumene-bearing pegmatite records a transition from an early H<sub>2</sub>O-poor to a late water-rich magmatic system. All rocks display elevated Rb/Sr and Rb/Ba ratios, along with uniform Sr–Nd isotopic signatures that resemble those of Triassic metapelites (<sup>87</sup>Sr/<sup>86</sup>Sr<sub>i</sub> = 0.7030 ∼ 0.7148, ε<sub>Nd</sub>(<em>t</em>) = −9.2 ∼ −7.3). Therefore, the Ke’eryin Li-rich granitic rocks were generated through muscovite-dehydration melting of a metapelitic source, and progressive magmatic differentiation subsequently concentrated Li and other rare metals.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107102"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146039405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Ore Geology Reviews
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