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Geochemical and geochronological constraints on granitoids from the Chambishi-Nkana Basin, Zambian Copperbelt 赞比亚铜带Chambishi-Nkana盆地花岗岩类的地球化学和年代学约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107139
Hu Qiaofan , Mo Jiangping , Wei Zhiwei , Qiu ZhengJie , Fang Ke , Zhou Shouyu , Huang Xueqiang , Liu Yaohui , Liu Wei , Li Jiacai , Wang Ailin
This study focuses on the granitic intrusions in the Chambishi-Nkana Basin of the Zambian Copperbelt, aiming to reveal their genesis, tectonic setting, emplacement age, and relationship with Cu-Co mineralization. LA-ICP-MS zircon U-Pb dating shows that the Chambishi granite formed at approximately 1951 Ma, and the Nchanga granite crystallized at approximately 890 Ma. Geochemical analyses indicate that these rocks are peraluminous S-type granites, characterized by high A/CNK values (>1.3), enrichment in light rare earth elements, and significant negative Eu anomalies (Eu/Eu*=21.38–38.28). Zircon Lu-Hf isotopic data suggest that the Chambishi granite originated from the mixing of mantle and crust-derived melts during the collision between the Bangweulu Block and the Tanzania Craton, while the Nchanga granite formed from crustal anatexis without significant mantle input in an intraplate rift environment associated with the breakup of Rodinia in the Neoproterozoic. Molybdenite Re-Os dating reveals that hydrothermal cross-cutting vein-type Cu-Mo mineralization occurred at approximately 496 Ma, coinciding with basin inversion during the late stage of the Lufilian collisional orogeny—this age only represents the timing of the late vein-type mineralization, not the entire mineralization history of the deposit. This study confirms that the late Lufilian orogeny provided tectonic channels for hydrothermal migration, and granitic intrusions provided favorable structural channels for hydrothermal migration, while tectonic-thermal effects of the late Lufilian orogeny supplied the necessary thermal driving force, jointly controlling the formation of hydrothermal cross-cutting vein-type Cu-Mo mineralization. The sedimentary layered Cu-Co mineralization is controlled by the Neoproterozoic sedimentary environment, and its specific formation age requires further dating of sulfides (e.g., carrollite) in the layered mineralization. By integrating geochronological and geochemical data, this research establishes a temporal framework for magmatic events, tectonic evolution, and mineralization in the Zambian Copperbelt, highlighting the critical control of regional tectonic-magmatic activities on Cu-Co mineralization.
本文以赞比亚铜带Chambishi-Nkana盆地的花岗质侵入岩为研究对象,旨在揭示其成因、构造背景、侵位时代及其与Cu-Co矿化的关系。LA-ICP-MS锆石U-Pb测年表明谦比希花岗岩形成时间约为1951 Ma,恩昌加花岗岩结晶时间约为890 Ma。地球化学分析表明,这些岩石为过铝质s型花岗岩,具有高A/CNK值(>1.3)、富集轻稀土元素、显著负Eu异常(Eu/Eu*=21.38 ~ 38.28)的特征。锆石Lu-Hf同位素数据表明,谦比希花岗岩形成于Bangweulu地块与坦桑尼亚克拉通碰撞过程中地幔与壳源熔体的混合,而Nchanga花岗岩形成于新元古代与Rodinia分裂相关的板内裂谷环境中没有明显地幔输入的地壳深熔。辉钼矿Re-Os测年结果表明,热液横切脉状铜钼成矿发生在496 Ma左右,与陆菲连碰撞造山晚期的盆地反转相吻合,该年龄仅代表脉状晚期成矿的时间,不能代表矿床的全部成矿史。研究证实,晚鲁菲连造山运动为热液运移提供了构造通道,花岗岩侵入体为热液运移提供了有利的构造通道,而晚鲁菲连造山运动的构造-热效应提供了必要的热驱动力,共同控制了热液横切脉型铜钼矿化的形成。沉积层状铜钴矿化受新元古代沉积环境控制,其具体形成年代需要进一步确定层状矿化中硫化物(如卡罗尔石)的年代。结合地质年代学和地球化学资料,建立了赞比亚铜带岩浆事件、构造演化和成矿作用的时间框架,突出了区域构造岩浆活动对铜钴成矿作用的关键控制作用。
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引用次数: 0
Advanced SOTEM survey for the exploration of low-sulphidation epithermal gold: Insights from Lvyuan, eastern Junggar, China 准噶尔东部绿原地区低硫化浅成热液金超前SOTEM勘查研究
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107140
Weiying Chen , Xiaoyin Ma , Quanhui Guo , Pengfei Lv
The investigation of low-sulfidation epithermal gold deposits presents significant challenges due to their intricate geological frameworks and frequently obscured mineralization. This research details the implementation of the short-offset transient electromagnetic method (SOTEM) to concurrently invert resistivity and chargeability parameters within the Lvyuan Gold Deposit located in Eastern Junggar, China. Utilizing a grounded-wire source alongside dual-base-frequency transmission, high-fidelity electromagnetic data were collected across ten survey lines encompassing the No. 7 alteration zone. One-dimensional inversion of the transient electromagnetic responses elucidated detailed subsurface electrical structures to depths of approximately one kilometer, facilitating the identification of fault systems and alteration zones linked to gold mineralization. Measurements of rock physical properties substantiated that elevated chargeability values (>20%) combined with moderate to low resistivity (<300 Ω·m) are strongly indicative of hydrothermally altered lithologies, particularly those exhibiting pyritization and limonitization. Integration of these geophysical results with drilling data confirmed that mineralized bodies predominantly occur within shallow zones characterized by low resistivity and high chargeability proximal to fault structures. Consequently, four prospective target areas were delineated, underscoring the effectiveness of SOTEM in delineating alteration zones and informing subsequent exploration efforts for epithermal gold deposits.
低硫化浅成热液型金矿床地质格架复杂,矿化模糊,为其研究带来了重大挑战。本文详细介绍了利用短偏移瞬变电磁法(SOTEM)反演准噶尔东部绿园金矿的电阻率和电荷率参数。利用接地线源和双基频传输,在7号改造区周围的10条测量线上收集了高保真电磁数据。瞬变电磁响应的一维反演揭示了深度约1公里的详细地下电性结构,有助于识别与金矿化有关的断裂系统和蚀变带。岩石物理性质测量证实,较高的电荷率值(>20%)和中至低电阻率(<300 Ω·m)强烈表明热液蚀变岩性,特别是黄铁矿化和褐铁矿化。将这些地球物理结果与钻井数据相结合,证实矿化体主要分布在断层构造近端低电阻率和高电荷率的浅层带内。在此基础上,圈定了4个远景靶区,突出了瞬变电磁法圈定蚀变带的有效性,为后续的浅成低温热液金矿找矿提供了依据。
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引用次数: 0
Formation of the Zarshuran gold deposit in northwest Iran resulted from the mixing of fertile magmatic fluids with basinal brines: Evidence from sulfide trace elements and sulfur isotopes 伊朗西北部扎尔舒兰金矿床的形成是由丰富的岩浆流体与盆地盐水混合形成的:来自硫化物微量元素和硫同位素的证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107126
Shu Yang , Hongrui Zhang , Zhiming Yang , Pinghua Liu , Mehraj Aghazadeh , Zengqian Hou , Tiannan Yang , Zahra Badrzadeh
Zarshuran is the largest gold deposit in the Middle East. However, the sources of ore-forming materials at Zarshuran remain poorly understood. This study presents detailed descriptions of paragenetic sequence, in situ calcite U-Pb data, sulfide trace elements and sulfur isotope data to trace the sources of ore-forming materials and track the ore-forming processes. Calcite U-Pb results suggest the gold mineralization occurred during ca. 21–12.0 Ma. Five stages of mineralization can be divided at Zarshuran. They are characterized by pyrite grains with different textures. LA-ICP-MS analyses of the different types of pyrite demonstrate that Au is enriched in ore-stage Ⅰ, ore-stage Ⅱ, and late-ore stage. LA-ICP-MS analyses of the different types of sphalerite show an increasing trend for In and Sn contents but a decreasing trend for Ge and Tl contents from Sp1a to Sp1c. The S isotope compositions of sulfides from different stages yield positive values, suggesting these sulfides were precipitated by thermochemical sulfate reduction. Most δ34S values of sulfide minerals of the ore-stages are in the ranges between magmatic sulfur and redbeds sulfates sulfur, suggesting contributions of magmatic and basinal materials during mineralization. The shift of δ34S values during late-ore stage indicates the addition of Miocene seawater sulfates sulfur. We propose the Zarshuran gold mineralization was formed by mixing of magmatic fluids with basinal brines during the exhumation of the Iman Khan metamorphic core complex (MCC). The development of MCC and coeval fertile magmatism and basinal brine flow are important for exploration of Zarshuran-type gold ores.
扎舒兰是中东最大的金矿。然而,对扎树然成矿物质的来源仍然知之甚少。通过对共生序列、方解石U-Pb原位数据、硫化物微量元素和硫同位素数据的详细描述,追踪成矿物质来源和成矿过程。方解石U-Pb结果表明金矿化发生在约21 ~ 12.0 Ma。扎树然矿化可分为5期。它们的特点是黄铁矿颗粒具有不同的质地。不同类型黄铁矿的LA-ICP-MS分析表明,金富集于矿级Ⅰ、矿级Ⅱ和矿后期。不同类型闪锌矿的LA-ICP-MS分析表明,从Sp1a到Sp1c阶段,In和Sn含量呈上升趋势,Ge和Tl含量呈下降趋势。不同阶段硫化物的S同位素组成均为正值,表明这些硫化物是由硫酸盐热化学还原沉淀而成。各矿段硫化物矿物的δ34S值大多介于岩浆硫和红层硫酸盐硫之间,表明岩浆和盆地物质在成矿过程中起作用。矿石后期δ34S值的变化表明中新世海水硫酸盐硫的加入。本文认为,扎树然金矿化是在伊曼汗变质核杂岩(MCC)发掘过程中岩浆流体与盆地卤水混合作用形成的。中冶盆地的发育、同时期富岩浆活动和盆地卤水流的形成对扎树兰型金矿的找矿具有重要意义。
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引用次数: 0
Provenance of Permian Li-rich Karst bauxite in western Guangxi, China: Evidence from geochemistry, zircon U-Pb and Hf isotopic compositions of contemporaneous-heterophase tuffaceous rocks 桂西二叠系富锂岩溶铝土矿物源:来自同时期辉灰岩的地球化学证据、锆石U-Pb和Hf同位素组成
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107134
Jianqi Xu , Baocheng Pang , Guanghui Lu , Chongjin Pang , Jianwen Yang , Dongsheng Yang , Shuangqiu Yao , Haipeng Xu
Karst bauxite deposits are an important potential lithium resource, distinct from grantie-pegmatite, brine, and volcanic-sedimentary lithium. Pingguo Li-rich karst bauxite deposits in Youjiang Basin, South China represent major deposits hosted in the Heshan Formation deposited on the Late Permian carbonate platform. Contemporaneous-heterophase tuffaceous rocks of the Upper Permian Linghao Formation distribute widely surrounding the Pingguo Carbonate Platform. The tuffaceous rocks provide a definitive tracer for the provenance of Li-rich karst bauxite deposits. Integrated geochemical, zircon U-Pb chronology, and in situ Hf isotopic analyses reveal that both tuffaceous rocks and Pingguo Li-rich karst bauxite deposits formed synchronously at ∼ 259 Ma from the same source. The correlations of Zr-Hf, Nb-Ta, and Th/Sc-Zr/Sc confirm the genetic relation between tuffaceous rocks and Li-rich karst bauxite. Zircon trace elements fingerprint arc-related signature of the parent source. Critically, the Hf isotope compositions of the tuff (εHf(t)≈-4.0, TDM2≈1.5 Ga) indicate unequivocally with the Paleo-Tethyan magmatic arc, demonstrating that volcanic ash derived from Paleo Tethys. The provenance of Li-rich karst bauxite deposits in Pingguo Carbonate Platform was volcanic ash from Paleo-Tethyan arc. The volcanic ash covered the carbonate platform during the latest Middle Permian and early Late Permian and resulted in the formation of Li-rich karst bauxite, revealing the Paleo-Tethyan arc as the main source for the significant deposits.
岩溶铝土矿不同于花岗伟晶岩锂、卤水锂和火山沉积锂,是一种重要的潜在锂资源。中国南方右江盆地平果富锂岩溶铝土矿是晚二叠世碳酸盐岩台地上鹤山组的主要赋存矿床。平果碳酸盐岩台地周围广泛分布着上二叠统灵好组同期异相凝灰岩。凝灰质岩为富锂岩溶铝土矿矿床的物源提供了明确的示踪剂。综合地球化学、锆石U-Pb年代学和原位Hf同位素分析表明,凝灰质岩和平果富锂岩溶铝土矿床在~ 259 Ma时形成于同一源区。Zr-Hf、Nb-Ta和Th/Sc- zr /Sc的对比证实了凝灰岩与富锂岩溶铝土矿的成因关系。母源锆石微量元素指纹弧相关特征。重要的是,凝灰岩的Hf同位素组成(εHf(t)≈-4.0,TDM2≈1.5 Ga)与古特提斯岩浆弧具有明确的对应关系,表明火山灰来源于古特提斯岩浆弧。平果碳酸盐岩台地富锂岩溶铝土矿床物源为古特提斯弧火山岩。中二叠世晚期和晚二叠世早期火山灰覆盖碳酸盐岩台地,形成富锂岩溶铝土矿,揭示了古特提斯弧是重要矿床的主要来源。
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引用次数: 0
Petrophysical properties of the Lakkeh-Siah iron oxide-apatite mineralization and host rocks Lakkeh-Siah氧化铁磷灰石矿化与寄主岩的岩石物理性质
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107146
Mohsen Shirkhani , Majid Ghaderi , Nematollah Rashidnejad-Omran
This study investigates the relationship between physical properties, metasomatism, and iron oxide-apatite (IOA) mineralization in the Lakkeh-Siah deposit, located in the Central Iran structural zone. The research integrates petrophysical, geochemical, and geophysical analyses to characterize rock units, assess mineralization controls, and develop an exploration model. The mineralized and metasomatized rocks exhibit higher density (avg. 3458 kg/m3) and magnetic susceptibility (up to 12,000 × 10−6 SI) than barren sedimentary and volcanic rocks. Calcic metasomatism (actinolite, tremolite, magnetite) enhances magnetic susceptibility, while argillic/sericitic alteration reduces it. Bivariate plots (density vs. susceptibility, Q-ratio) effectively discriminate lithologies and mineralization zones. Borehole logging confirms that high-grade iron zones correlate with elevated magnetic susceptibility and conductivity, influenced by sulfide presence. The study establishes a petrophysical database for exploration, demonstrating that integrated physical property analysis improves targeting accuracy in IOA deposits.
本文研究了伊朗中部构造带Lakkeh-Siah矿床物性、交代作用与氧化铁磷灰石(IOA)矿化的关系。该研究整合了岩石物理、地球化学和地球物理分析,以表征岩石单元,评估矿化控制,并开发勘探模型。矿化和交代岩石的密度(平均3458 kg/m3)和磁化率(高达12000 × 10 - 6 SI)高于贫瘠的沉积岩和火山岩。钙交代作用(放光石、透闪石、磁铁矿)增强磁化率,而泥质/绢云母蚀变则降低磁化率。二元图(密度与磁化率、q比)能有效区分岩性和矿化带。井眼测井证实,受硫化物存在的影响,高品位铁带与磁化率和导电性升高相关。该研究为勘探建立了岩石物性数据库,表明综合物性分析提高了IOA矿床的找准精度。
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引用次数: 0
Iron oxide copper–gold (IOCG) deposits – A review (part 2): fluid, metal and sulfur sources and ore genesis 氧化铁铜金(IOCG)矿床综述(第2部分):流体、金属和硫源及矿床成因
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107120
Roger G. Skirrow
Genetic models for the formation of iron oxide copper–gold (IOCG) deposits have been debated since recognition of the class, with proposed ore fluid origins ranging from non-magmatic basinal to magmatic-hydrothermal, with or without fluid mixing. This review reassesses previous models by synthesising and re-interpreting fluid geochemical and stable and radiogenic isotope data for IOCG deposits worldwide. These data are integrated with previously compiled information for 10 IOCG provinces to build a new and holistic model of IOCG deposit genesis.
Although many gaps in data remain, previous disparate models can be reconciled and key features of most major IOCG deposits explained by mixing of fluids sourced from both (meta)sedimentary ± (meta)volcanic basins and from magmas. The roles of these fluids as carriers of Cu-Au differ, however, between IOCG deposits in Precambrian orogenic to post-orogenic versus Mesozoic magmatic arc settings. Relatively limited fluid geochemical and isotope data for Mesozoic arc-hosted IOCG deposits are consistent with formation of most ores from Cu-Au-bearing magmatic-hydrothermal fluids that mixed with Na-Ca-rich oxidised basin-derived brines.
In contrast, and based on variably comprehensive datasets, the Cu-Au ore fluids forming most IOCG deposits in Precambrian orogenic and post-orogenic settings are interpreted to have been Ca-Fe-Ba-rich evolved basin-derived brines ± metamorphic fluids that leached metals from Na-Ca-altered and mafic rock sequences. These generally low-sulfur fluids mixed with a second fluid, commonly of magmatic-hydrothermal origin, that carried sulfur and other volatiles (CO2 ± P ± B ± F) as well as Fe and K ± Mo, to form most major IOCG deposits.
氧化铁铜金(IOCG)矿床形成的成因模式自发现以来一直存在争议,提出的矿石流体来源从非岩浆盆地到岩浆热液,有或没有流体混合。本文通过综合和重新解释全球IOCG矿床的流体地球化学、稳定同位素和放射性同位素数据,对以前的模型进行了重新评估。将这些数据与先前编制的10个IOCG省的信息相结合,建立了一个新的、整体的IOCG矿床成因模型。尽管数据中仍然存在许多空白,但以前不同的模型可以调和,并且大多数主要IOCG矿床的关键特征可以通过来自(元)沉积±(元)火山盆地和岩浆的混合流体来解释。然而,这些流体作为Cu-Au载体的作用在前寒武纪造山带到后造山带和中生代岩浆弧环境下的IOCG矿床之间是不同的。中生代弧型IOCG矿床的流体地球化学和同位素数据相对有限,与大多数矿石来自含cu - au的岩浆热液流体与富na - ca的氧化盆地衍生卤水混合形成相一致。相比之下,基于不同的综合数据集,在前寒武纪造山和造山后环境下,大多数IOCG矿床的铜金矿石流体被解释为富含ca - fe - ba的演化盆地衍生盐水±变质流体,这些流体从na - ca蚀变和基性岩石层序中浸出金属。这些低硫流体与第二种流体混合,通常是岩浆热液,携带硫和其他挥发物(CO2±P±B±F)以及铁和K±Mo,形成了大多数主要的IOCG矿床。
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引用次数: 0
Zircon geochronology, geochemistry, and Hf isotopes of granites in the Yazigou skarn Cu–Pb–Zn deposit: Insights into Triassic skarn mineralization potential in the Qimantagh area, Qinghai Province, NW China 雅兹沟矽卡岩型铜铅锌矿床花岗岩锆石年代学、地球化学及Hf同位素特征:青海省祁曼塔格地区三叠系矽卡岩成矿潜力
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107136
Jiale Wang , Xiang Sun , Changhai Luo , Yong Fu , Weiming Ma , Tong Pei , Ke Xiao
The Triassic period has been suggested to be the main metallogenic epoch in the Qimantagh area of Qinghai Province. However, the porphyry copper mineralization potential of this region remains poorly constrained. Here we present zircon U–Pb ages, trace-element data, and Hf isotopic compositions from granites in the Yazigou skarn Cu–Pb–Zn deposit. The zircon U–Pb age of the mineralization-related K-feldspar granitic porphyry at Yazigou is 230 ± 2 Ma, whereas the granodiorite yields an age of 416.7 ± 4.2 Ma. The K-feldspar granitic porphyry exhibits εHf(t) values of -0.4 to +4.0 and two-stage Hf model ages (TDM2) of 1.0–1.3 Ga, suggesting derivation from melting of Mesoproterozoic to crust, accompanied by minor contributions from mantle material. Zircon trace element signatures further indicate highly magmatic oxygen fugacity (ΔFMQ = +1.0 to +2.3), consistent with typical of oxidized skarn systems. The extremely low Eu anomalies (0.01–0.03) suggest that the magma system underwent intense plagioclase fractional crystallization, implying a low water content. Although the Yazigou deposit shares a similar magma source with other metallic deposits in the Qimantagh region, comparison with the Eu anomalies of Tibet porphyry Cu deposits suggests that the low water content resulted in its limited mineralization potential.
三叠纪是青海祁曼塔地区的主要成矿期。然而,该区斑岩型铜矿的成矿潜力仍未得到很好的约束。本文报道了雅兹沟矽卡岩型铜铅锌矿花岗岩的锆石U-Pb年龄、微量元素数据和Hf同位素组成。崖沟钾长石花岗斑岩锆石U-Pb年龄为230±2 Ma,花岗闪长岩锆石U-Pb年龄为416.7±4.2 Ma。钾长石花岗斑岩的εHf(t)值为-0.4 ~ +4.0,两阶段Hf模式年龄(TDM2)为1.0 ~ 1.3 Ga,表明其源自中元古代的地壳熔融,并伴有少量地幔物质的贡献。锆石微量元素特征进一步表明岩浆氧逸度高(ΔFMQ = +1.0 ~ +2.3),与典型氧化矽卡岩体系一致。极低的Eu异常(0.01 ~ 0.03)表明岩浆系统经历了强烈的斜长石分馏结晶,表明其含水量较低。虽然雅兹沟矿床与齐曼塔格地区其他金属矿床具有相似的岩浆来源,但与西藏斑岩型铜矿的Eu异常对比表明,低含水量导致其成矿潜力有限。
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引用次数: 0
Determination of the trapping temperatures and pressures of high-internal pressure CO2-bearing boiling fluid inclusion assemblages in the carbonatite-related REE deposit at Weishan, Shandong Province, China 山东微山碳酸盐岩相关稀土矿床高内压含co2沸腾流体包裹体组合的圈闭温度和压力测定
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107151
Shenghu Li , Yuxin Xiong , Dapeng Li , Xuefeng Yu , Taitao Liang , Rongjun Li , Zhiming Wang , Xiangxian Ma , Zengsheng Li , Naijie Chi , Yingyu Xue , Guodong Chen , Chuanyuan Zhuo , Ge Hu
Carbonatite-related rare earth element (REE) deposits are the world’s primary source of light REEs. The Weishan deposit in Shandong Province, China—ranked third in the country in rare earth oxide reserves—exemplifies such mineralization. Petrographic studies reveal abundant CO2-bearing fluid inclusions in its high-grade ore bodies. Due to their high-internal pressure, these inclusions frequently decrepitate or leak when heated on conventional heating-freezing stages (e.g., the Linkam THMSG600) at atmospheric pressure, preventing the acquisition of total homogenization temperature (Th,tot) data. This limitation has hindered understanding of the evolutionary process and thermodynamic properties of the ore-forming fluids. To address this, we employed a hydrothermal diamond anvil cell (HDAC) to perform high pressure microthermometry on CO2-bearing boiling fluid inclusion assemblages (FIAs) from the Weishan deposit. By maintaining external pressure on the high-internal pressure fluid inclusions throughout heating, we successfully obtained the Th,tots and introduced a newly established two fitted lines intersection method to correct the Th,tots measured with the HDAC, minimizing the influence of external pressures on the measured Th,tots. As a result, the trapping temperatures and pressures of the CO2-bearing boiling FIAs in the Weishan deposit were determined to be 682–692 °C and 646–734 MPa, respectively. These results define the temperature and pressure conditions under which depressurization immiscibility and fluid exsolution occurred within the magmatic system, and confirmed the existence of CO2-bearing supercritical fluids in the deposit. In the future, the experimental method established herein is well-suited for thermodynamic measurements of CO2-bearing boiling FIAs in carbonatite-related REE deposits, which often contain high-internal pressure fluid inclusions with complex multicomponent system such as H2O-Na2SO4-Na2CO3–CO2.
碳酸盐岩相关稀土矿床是世界上轻稀土的主要来源。中国山东省的微山矿床(稀土氧化物储量居全国第三)就是这种矿化的例证。岩石学研究表明,高品位矿体中富含含二氧化碳流体包裹体。由于其内部高压,这些包裹体在常规的加热-冷冻阶段(例如Linkam THMSG600)在常压下加热时经常发生老化或泄漏,从而阻碍了总均质温度(Th,tot)数据的获取。这一局限性阻碍了对成矿流体演化过程和热力学性质的认识。为了解决这一问题,我们采用热液金刚石砧池(HDAC)对微山矿床含co2沸腾流体包裹体组合(FIAs)进行了高压显微测温。通过在加热过程中保持外部压力对高内压流体包裹体的作用,我们成功地获得了Th,tot,并引入了一种新建立的两条拟合线相交法来校正HDAC测量的Th,tot,tot,最小化了外部压力对测量的Th,tot的影响。结果表明,微山矿床含co2沸腾体的圈闭温度为682 ~ 692℃,圈闭压力为646 ~ 734 MPa。这些结果明确了岩浆体系内发生减压、不混溶和流体析出的温度和压力条件,确认了矿床中存在含co2的超临界流体。在未来,本文建立的实验方法非常适合于碳酸盐岩相关稀土矿床中含co2沸腾FIAs的热力学测量,这些矿床通常含有高内压流体包裹体,具有H2O-Na2SO4-Na2CO3-CO2等复杂的多组分体系。
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引用次数: 0
Ore genesis of the Kuhsiah-e-Urmak base-metal epithermal deposit, Iran 伊朗Kuhsiah-e-Urmak贱金属浅成热液矿床矿床成因
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107142
Amirabbas Karbalaeiramezanali , Faranak Feizi , Alireza Jafari Rad , Mohammad Lotfi , David R. Lentz
This study investigates the mineralization characteristics and ore genesis of the Kuhsiah-e-Urmak area in the central Urumieh-Dokhtar Magmatic Belt, Iran, through fluid inclusion and isotope analyses. The intrusive units in the region, which are hosted within a marginally older volcanic series, reflect a transitional geodynamic environment, with the Kuh-Ghadeh diorite (∼18 Ma) showing arc-related features and the Marfioun tonalite (∼18 Ma) displaying a mix of arc and slab break-off characteristics, indicating an evolution from arc-related to post-arc slab failure regimes. Mineralization at the Kuhsiah-e-Urmak deposit occurs in two stages: Stage 1 (hypogene), marked by chalcopyrite-pyrite-bornite-sphalerite-galena-tetrahedrite with quartz-calcite, and Stage 2 (hypogene to supergene), characterized by chalcocite-digenite-covellite-goethite-maghemite-malachite with hematite-limonite ± jarosite ± illite. Fluid inclusion studies reveal low- to intermediate-temperature (191–230°C) and low- to medium-salinity (4–8.5 wt%) Stage 1 fluids. Stable isotope results indicate that the strongly negative δ34S values of sulfides and the significantly higher δ34S values of barite reflect reduction of seawater- or evaporite-derived sulfate, rather than sulfur input from magmatic volatiles. The magnitude of sulfur isotope fractionation is inconsistent with thermochemical sulfate reduction and instead supports microbial sulfate reduction and/or multistage sulfur cycling as the dominant sulfur-generating processes. The δ18O and δ13C values further record extensive fluid–rock interaction with meteoric waters and limestones in the region. Fluid inclusion salinity–temperature trends exhibit a positive correlation, consistent with dilution of hydrothermal fluids by infiltrating meteoric water. Stage 1 mineralization was driven by high-temperature magmatic hydrothermal fluids, while Stage 2 resulted from progressive mixing with cooler meteoric waters at shallow crustal levels to supergene weathering. These findings classify the Kuhsiah-e-Urmak deposit as a low-sulfidation epithermal Cu (Ag–Pb–Zn) deposit, and highlight the dominant role of seawater- or evaporite-derived oxidized sulfur and meteoric water mixing in the evolution of its hydrothermal system.
通过流体包裹体和同位素分析,研究了伊朗乌尔姆-多赫塔尔岩浆带中部库夏-鄂尔马克地区的成矿特征和矿床成因。该地区的侵入单元位于一个稍老的火山系列中,反映了一个过渡性的地球动力学环境,Kuh-Ghadeh闪长岩(~ 18 Ma)表现出弧相关特征,Marfioun闪长岩(~ 18 Ma)表现出弧和板块断裂的混合特征,表明从弧相关到弧后板块断裂的演变。kuhsiahe - urmak矿床的成矿作用分为两个阶段:第1阶段(下第三纪),以黄铜矿—黄铁矿—斑铜矿—闪锌矿—方解石—方晶石为标志;第2阶段(下第三纪—上第三纪),以辉铜矿—闪锌矿—橄榄岩—针铁矿—磁赤铁矿—孔雀石为标志,以赤铁矿—褐铁矿±黄铁矾±伊利石为标志。流体包裹体研究揭示了低至中温(191-230°C)和低至中盐度(4-8.5 wt%)的一级流体。稳定同位素结果表明,硫化物的强烈负δ34S值和重晶石的显著高δ34S值反映了海水或蒸发岩来源的硫酸盐的减少,而不是岩浆挥发物输入的硫。硫同位素分馏的大小与热化学硫酸盐还原不一致,相反,支持微生物硫酸盐还原和/或多级硫循环是主要的硫生成过程。δ18O和δ13C值进一步记录了该地区与大气水和灰岩的广泛的流体-岩石相互作用。流体包裹体盐度-温度趋势呈正相关,与大气水渗透对热液流体的稀释作用一致。第1阶段成矿作用主要由高温岩浆热液驱动,第2阶段成矿作用主要由地壳浅层较冷的大气水逐渐混合到表生风化作用驱动。这些发现将Kuhsiah-e-Urmak矿床划分为低硫化度低温热液型Cu (Ag-Pb-Zn)矿床,并强调了海水或蒸发岩氧化硫与大气水混合在其热液系统演化中的主导作用。
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引用次数: 0
Origin and evolution of the ore-forming fluids in the giant Dongping wolframite–quartz vein–type deposit in the Jiangnan Orogen, South China: fluid inclusions and H–O isotopic constraints 江南造山带东平巨型黑钨矿-石英脉型矿床成矿流体成因与演化:流体包裹体与氢氧同位素约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-02-01 DOI: 10.1016/j.oregeorev.2026.107104
Jie Tan , Shi-Wen Yang , Chang Xu , Jian-Jun Lu , Xi-Hui Cheng , Ruo-Yan Kong , Bin Yu , Fa-Sheng Lou
Tungsten (W) is an indispensable strategic resource, and the wolframite–quartz vein–type deposit is an important W deposit type. However, the origin and delicate evolutionary process of the ore-forming fluids and the decisive mechanism of the wolframite precipitation for wolframite–quartz vein–type deposits still lack precise constraints. The Dongping W deposit is the sole giant wolframite–quartz vein–type deposit in the Jiangnan Orogen, South China, with 214,000 tons of WO3. Based on the cross-cutting relationships and petrographic observations, four alteration and ore-forming stages and corresponding quartz were identified: (Ⅰ) pre-ore alteration (e.g., biotitization, silicification, greisenization, and tourmalinization) (Qtz), (Ⅱ) wolframite–quartz (Qtz), (Ⅲ) quartz–sulfide (Qtz), and (Ⅳ) fluorite–carbonate (Qtz) stages. Three types of fluid inclusions can be identified: liquid–rich two–phase (Type Ⅰ), vapor–rich two–phase (Type Ⅱ), and liquid inclusions (Type Ⅲ). Minor CH4 can be detected in the inclusions from Qtz and Qtz, indicating that the initial fluids are probably relatively reduced. The fluids responsible for the pre-ore alteration and wolframite–quartz stages are both medium–higher temperature and salinity, and then evolve into ones with medium–lower temperature and salinity during the post-ore two stages. The δDv-SMOW and δ18Ov-SMOW values of Qtz and Qtz range from –80.4‰ to –62.0‰ and 10.22‰ to 13.44‰, respectively, suggesting dominantly magma-derived fluids. The δDv-SMOW and δ18Ov-SMOW values in the post-ore Qtz and Qtz vary from –76.3‰ to –69.4‰ and 7.63‰ to 13.92‰, respectively, and δ18Ov-SMOW values are lower than those in the foregoing two stages, implying the addition of meteoric water. Together, these data indicate that at least two pulsed fluids exsolution events occurred in the Dongping deposit: one during the pre-ore alteration stage and another during the wolframite–quartz stage. The fluid evolution displays a complex process: the initially exsolved reduced fluids from the Yanshanian hidden S-type granite produced pre-ore alteration; subsequently, cooling of second-pulsed exsolved magmatic fluids caused wolframite precipitation followed by quartz; with the evolution of the fluids and increasing involvement of meteoric water, the evolved fluids ultimately form the quartz–sulfide and fluorite–carbonate mineral assemblages. Our study shows that fluid cooling is decisive for the wolframite precipitation in the Dongping deposit. This contribution elucidates the delicate fluid evolution process of the Dongping deposit, providing new insights into the origin of giant wolframite–quartz vein–type deposits.
钨是不可或缺的战略资源,黑钨矿-石英脉型矿床是重要的钨矿床类型。然而,对于黑钨矿-石英脉型矿床成矿流体的成因和精细演化过程,以及黑钨矿沉淀的决定性机制,仍缺乏精确的约束。东平钨矿是华南江南造山带唯一的巨型黑钨矿-石英脉型矿床,含WO3 21.4万吨。根据岩石学观察,确定了4个蚀变成矿阶段和相应的石英:(Ⅰ)矿前蚀变(如生物石化、硅化、灰岩化和电气石化)(QtzⅠ)、(Ⅱ)黑钨矿-石英(QtzⅡ)、(Ⅲ)石英-硫化物(QtzⅢ)和(Ⅳ)萤石-碳酸盐(QtzⅣ)阶段。流体包裹体可分为富液两相(Ⅰ型)、富气两相(Ⅱ型)和液体包裹体(Ⅲ型)三种类型。在QtzⅠ和QtzⅡ的包裹体中可以检测到少量CH4,表明初始流体可能相对减少。成矿前蚀变阶段和黑钨矿—石英阶段流体均为中高温高矿化度阶段,成矿后两个阶段流体演化为中低温低矿化度阶段。石英Ⅰ和Ⅱ的δDv-SMOW值介于-80.4‰~ -62.0‰之间,δ18Ov-SMOW值介于10.22‰~ 13.44‰之间,以岩浆流体为主。矿石后石英Ⅲ和石英Ⅳ的δDv-SMOW和δ18Ov-SMOW值分别在-76.3‰~ -69.4‰和7.63‰~ 13.92‰之间变化,δ18Ov-SMOW值比前两个阶段的δ18Ov-SMOW值要低,说明有大气水的加入。这些资料表明,东平矿床至少发生过两次脉冲流体溶出事件,一次发生在矿前蚀变阶段,另一次发生在黑钨矿-石英阶段。流体演化过程复杂:燕山期隐伏s型花岗岩初始溶蚀还原流体产生成矿前蚀变;随后,第二脉冲溶蚀岩浆流体冷却导致黑钨矿沉淀,其次是石英;随着流体的演化和大气水的参与,演化流体最终形成石英-硫化物和萤石-碳酸盐矿物组合。研究表明,流体冷却对东平黑钨矿沉积起决定性作用。这一贡献阐明了东平矿床的精细流体演化过程,为巨型黑钨矿-石英脉型矿床的成因提供了新的认识。
{"title":"Origin and evolution of the ore-forming fluids in the giant Dongping wolframite–quartz vein–type deposit in the Jiangnan Orogen, South China: fluid inclusions and H–O isotopic constraints","authors":"Jie Tan ,&nbsp;Shi-Wen Yang ,&nbsp;Chang Xu ,&nbsp;Jian-Jun Lu ,&nbsp;Xi-Hui Cheng ,&nbsp;Ruo-Yan Kong ,&nbsp;Bin Yu ,&nbsp;Fa-Sheng Lou","doi":"10.1016/j.oregeorev.2026.107104","DOIUrl":"10.1016/j.oregeorev.2026.107104","url":null,"abstract":"<div><div>Tungsten (W) is an indispensable strategic resource, and the wolframite–quartz vein–type deposit is an important W deposit type. However, the origin and delicate evolutionary process of the ore-forming fluids and the decisive mechanism of the wolframite precipitation for wolframite–quartz vein–type deposits still lack precise constraints. The Dongping W deposit is the sole giant wolframite–quartz vein–type deposit in the Jiangnan Orogen, South China, with 214,000 tons of WO<sub>3</sub>. Based on the cross-cutting relationships and petrographic observations, four alteration and ore-forming stages and corresponding quartz were identified: (Ⅰ) pre-ore alteration (e.g., biotitization, silicification, greisenization, and tourmalinization) (Qtz<sub>Ⅰ</sub>), (Ⅱ) wolframite–quartz (Qtz<sub>Ⅱ</sub>), (Ⅲ) quartz–sulfide (Qtz<sub>Ⅲ</sub>), and (Ⅳ) fluorite–carbonate (Qtz<sub>Ⅳ</sub>) stages. Three types of fluid inclusions can be identified: liquid–rich two–phase (Type Ⅰ), vapor–rich two–phase (Type Ⅱ), and liquid inclusions (Type Ⅲ). Minor CH<sub>4</sub> can be detected in the inclusions from Qtz<sub>Ⅰ</sub> and Qtz<sub>Ⅱ</sub>, indicating that the initial fluids are probably relatively reduced. The fluids responsible for the pre-ore alteration and wolframite–quartz stages are both medium–higher temperature and salinity, and then evolve into ones with medium–lower temperature and salinity during the post-ore two stages. The δD<sub>v-SMOW</sub> and δ<sup>18</sup>O<sub>v-SMOW</sub> values of Qtz<sub>Ⅰ</sub> and Qtz<sub>Ⅱ</sub> range from –80.4‰ to –62.0‰ and 10.22‰ to 13.44‰, respectively, suggesting dominantly magma-derived fluids. The δD<sub>v-SMOW</sub> and δ<sup>18</sup>O<sub>v-SMOW</sub> values in the post-ore Qtz<sub>Ⅲ</sub> and Qtz<sub>Ⅳ</sub> vary from –76.3‰ to –69.4‰ and 7.63‰ to 13.92‰, respectively, and δ<sup>18</sup>O<sub>v-SMOW</sub> values are lower than those in the foregoing two stages, implying the addition of meteoric water. Together, these data indicate that at least two pulsed fluids exsolution events occurred in the Dongping deposit: one during the pre-ore alteration stage and another during the wolframite–quartz stage. The fluid evolution displays a complex process: the initially exsolved reduced fluids from the Yanshanian hidden S-type granite produced pre-ore alteration; subsequently, cooling of second-pulsed exsolved magmatic fluids caused wolframite precipitation followed by quartz; with the evolution of the fluids and increasing involvement of meteoric water, the evolved fluids ultimately form the quartz–sulfide and fluorite–carbonate mineral assemblages. Our study shows that fluid cooling is decisive for the wolframite precipitation in the Dongping deposit. This contribution elucidates the delicate fluid evolution process of the Dongping deposit, providing new insights into the origin of giant wolframite–quartz vein–type deposits.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107104"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Ore Geology Reviews
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