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High-temperature uranium mineralization in the Jiling Na-metasomatism uranium deposit, northwest China: Evidence from the isotope and element of rutile and apatite 鸡岭钠交代铀矿床高温铀成矿作用:来自金红石和磷灰石同位素和元素的证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-19 DOI: 10.1016/j.oregeorev.2026.107118
Xin-Yi Zhou , Kai-Xing Wang , Chi-Da Yu , Gui Wang , Xiao-Dong Liu , Wei Wang , Li-Qiang Sun , Wen-Heng Liu
The Jiling uranium deposit in Northwest China, which was previously considered a low-temperature system, presents evidence of high-temperature mineralization at depth. Petrographic analysis, elemental composition, and U–Pb dating of syn-ore hydrothermal rutile and apatite from this deposit were investigated in this study. Three distinct rutile types, each of which formed from a different precursor mineral, were identified: Rt-1 from altered Ti-rich magnetite, Rt-2 from ilmenite, and Rt-3 from biotite. These hydrothermal rutile types are contemporaneous with uraninite and apatite in the deposit. The three rutile types exhibit distinct rare earth element (REE) patterns. Rt-1 has a low REE content with light rare earth element (LREE) enrichment, and Rt-2 has a high REE content with a flat pattern. In contrast, Rt-3 shows an LREE-enriched pattern. These variations suggest that the REE signature of each rutile type is inherited from its precursor minerals. Furthermore, all three rutile types are enriched in high-field-strength elements (HFSEs). This enrichment was likely driven by the high-temperature, halogen- and CO2-bearing magmatic fluids responsible for their formation. In situ U–Pb isotope dating of hydrothermal rutile and apatite yields weighted mean ages of 432 ± 6 Ma and 435 ± 3 Ma, respectively. This study demonstrates that rutile and apatite can be used as robust tool for tracing uranium mineralization.
滇西北鸡岭铀矿床在深部具有高温成矿作用,以往被认为是低温体系。对该矿床的同矿热液金红石和磷灰石进行了岩石学分析、元素组成和U-Pb定年研究。三种不同的金红石类型,每一种都是由不同的前体矿物形成的,被鉴定出来:Rt-1来自蚀变富钛磁铁矿,Rt-2来自钛铁矿,Rt-3来自黑云母。这些热液金红石类型与矿床中的铀矿和磷灰石同生。三种金红石类型均表现出不同的稀土元素模式。Rt-1稀土元素含量低,轻稀土元素富集;Rt-2稀土元素含量高,稀土元素含量呈扁平状;相反,Rt-3表现为lree富集模式。这些变化表明,每种金红石类型的稀土元素特征都继承自其前体矿物。此外,三种金红石类型均富含高场强元素(hfse)。这种富集很可能是由形成它们的高温、含卤素和二氧化碳的岩浆流体驱动的。热液金红石和磷灰石的原位U-Pb同位素定年结果加权平均年龄分别为432±6 Ma和435±3 Ma。研究结果表明,金红石和磷灰石可作为铀矿化的有力示踪工具。
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引用次数: 0
Magmatic evolution and chromite mineralization in the Gayahe ultramafic Complex, East Kunlun orogenic Belt, western China 东昆仑造山带加雅河超镁铁性杂岩岩浆演化与铬铁矿成矿作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-19 DOI: 10.1016/j.oregeorev.2026.107125
Wen-Qi Ren , Shao-Yong Jiang , Hailin Xie , Bin Wang , Wei Wang , Hui-Min Su
Integrating chromite–silicate geochemistry with apatite U–Pb geochronology, this study deciphers the magmatic evolution and chromite mineralization of the Gayahe ultramafic complex in the East Kunlun Orogenic Belt. Newly identified massive chromitites occur within serpentinite, dunite, olivine pyroxenite, and pyroxenite. Apatite U–Pb dating yields an age of 430 ± 17 Ma, placing their formation in the Early Silurian during a major pulse of mantle-derived magmatism. Chromite from massive chromitite is characterized by high Cr# (70.2–80.6), low TiO2, and trace-element patterns marked by relative Zn–Co–Mn enrichment and pronounced Sc depletion, indicating crystallization from a low-Ti parental melt consistent with forearc boninitic magmatism. Systematic contrasts among chromite types show that re-equilibration chiefly overprinted low-modal-abundance chromite in serpentinite and other ultramafic host rocks, whereas the multivalent-element chemistry of chromite from massive chromitite samples preserves near-primary melt signatures. Coexisting olivine shows high Mg# and Ni contents, consistent with crystallization from a depleted mantle-derived melt. Field, petrographic, and geochemical evidence collectively indicates that the Gayahe chromitite formed in an Early Silurian subduction-related arc setting, where chromite–silicate crystal-mush accumulation followed by gravitational settling generated the massive chromitite layers. These findings refine the petrogenesis of the Gayahe ultramafic complex and establish a geochemical framework for identifying high-Cr chromitite associated with boninite-series magmatism in comparable orogenic belts.
结合铬硅酸盐地球化学和磷灰石U-Pb年代学,研究了东昆仑造山带加亚河超镁质杂岩的岩浆演化和铬铁矿成矿作用。新发现的块状铬铁矿体产于蛇纹岩、灰岩、橄榄辉石岩和辉石岩中。磷灰石U-Pb测年结果显示其年龄为430±17 Ma,形成于早志留世幔源岩浆活动大脉冲时期。块状铬铁矿中的铬铁矿具有高Cr#(70.2 ~ 80.6)、低TiO2、微量元素模式(Zn-Co-Mn相对富集、Sc明显亏缺)的特征,表明其结晶来自于低ti母熔体,与弧前煌质岩浆作用一致。铬铁矿类型的系统对比表明,再平衡主要覆盖了蛇纹岩和其他超镁质寄主岩中的低模态丰度铬铁矿,而块状铬铁矿样品中的铬铁矿的多价元素化学特征保留了近原生熔体特征。共存橄榄石显示出较高的Mg#和Ni含量,与枯竭幔源熔体的结晶一致。野外、岩石学和地球化学证据共同表明,加亚河铬铁矿形成于早志留世俯冲弧环境中,在此环境中,铬铁矿-硅酸盐晶体-泥状堆积和重力沉降形成了块状铬铁矿层。这些发现细化了加亚河超镁铁性杂岩的岩石成因,并建立了一个地球化学框架,用于识别与类似造山带中辉锑矿系岩浆作用相关的高铬铬铁矿。
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引用次数: 0
Unveiling hydrothermal center in the Xiayu Ag-Pb-Zn-Au Orefield, central China: Insights from geology evidence and ore grade characteristic 揭示下峪银铅锌金矿区热液中心:地质证据与矿石品位特征
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-18 DOI: 10.1016/j.oregeorev.2026.107116
Lei Zhu , Min Liu , Xiuquan Wang , Wei Jian , Jingwen Mao , Yongfei Tian , Li Jiang , Yongqi Su
The Xiayu orefield, situated within the Xiong’ershan ore concentration area of the southern margin of the North China Craton, is an important polymetallic production region. Recent studies suggest that the steeply dipping Ag-Pb-Zn-Au veins belong to a magmatic-hydrothermal system related to unexposed intrusions. The hydrothermal center and associated metal zoning, however, remain unclear. Addressing these knowledge gaps is essential for elucidating ore-forming processes and refining regional exploration strategies. This study addresses these issues through a statistical analysis of 436,003 ore grades, integrated with field and petrographic investigations. Our results reveal clear patterns of metal zoning that show a hydrothermal center is located under the southwestern part of Haopinggou deposit in the Xiayu orefield. Samples from this orefield clearly exhibit six paragenetic stages, in which sphalerite precipitation was followed by gold and lead mineralization, which in turn preceded the formation of chalcopyrite and argentite, with native silver occurring in the final stage. Based on these stages, we employed characteristic metal ratios to provide evidence for elemental zonings: Au/Ag, Zn/Ag, and Pb/Ag ratios increase toward the southwestern Haopinggou deposit. These variations reflect the sequential deposition of ore minerals, which is jointly governed by mineralization stages, decreasing temperature gradients, and intensifying fluid-rock interaction distal to the hydrothermal center. The observation aligns with the geological features of the Xiayu orefield, specifically the presence and spatial configuration of breccia pipes. This interpretation is further substantiated by a synthesis of existing fluid inclusion information, hydrothermal alteration assemblages, and geochronological constraints. These findings demonstrate the utility of statistical analysis methodologies in mineral exploration, providing a robust framework for identifying hydrothermal centers and delineating exploration targets.
下峪矿田位于华北克拉通南缘熊儿山矿集中区内,是一个重要的多金属生产区。近年来的研究表明,急倾银铅锌金脉属岩浆热液系统,与未暴露的侵入体有关。然而,热液中心和相关的金属带仍然不清楚。解决这些知识差距对于阐明成矿过程和完善区域勘探策略至关重要。本研究通过对436,003个矿石品位的统计分析,结合现场和岩石学调查,解决了这些问题。结果表明,下峪矿田郝坪沟矿床西南下部存在热液中心。该矿田样品明显表现出6个共生阶段,闪锌矿沉淀后,金、铅成矿,继而形成黄铜矿和银辉铁矿,在最后阶段出现天然银。在此基础上,利用特征金属比值为元素分带提供依据:Au/Ag、Zn/Ag、Pb/Ag比值向郝坪沟矿床西南方向呈递增趋势。这些变化反映了矿石矿物的顺序沉积,受成矿阶段、温度梯度降低和热液中心远端流体-岩石相互作用加剧的共同控制。观测结果与下峪矿田的地质特征吻合,特别是角砾岩管的存在和空间构型。现有流体包裹体信息、热液蚀变组合和地质年代学约束进一步证实了这一解释。这些发现证明了统计分析方法在矿产勘探中的实用性,为识别热液中心和圈定勘探目标提供了一个强有力的框架。
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引用次数: 0
Genesis of the Linghou Cu–Zn polymetallic deposit, South China: Constraints from geological, mineralogical, geochronological and sulfur isotope data 华南灵州铜锌多金属矿床成因:地质、矿物学、年代学和硫同位素资料的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-18 DOI: 10.1016/j.oregeorev.2026.107121
Wei Zheng , Kelei Chu , Bo Xing
Stratiform Cu deposits represent significant source of copper worldwide and have long been the subject of extensive scientific research. However, their origins remain highly debated. To address this key issue, we carried out a comprehensive investigation of the Linghou deposit in South China—a typical stratiform Cu deposit—utilizing microanalytical mineralogy and in situ sulfur isotope analysis of the main ore minerals, together with high-precision geochronology of genetically related hydrothermal apatite.
Hydrothermal apatite spatially and temporally associated with copper mineralization in the Linghou stratiform ores yields a lower intercept U–Pb age of 161.0 ± 4.6 Ma (MSWD = 1.09), consistent with ages obtained from the granodiorite porphyry in the deposit. Microtextural and thermometric analyses of coexisting chalcopyrite and sphalerite indicate formation temperatures of 255–303 °C, characteristic of magmatic-hydrothermal systems. The sulfur isotope compositions of sulfide minerals exhibit a narrow δ34S range of +0.68 ‰ to +2.80 ‰, further supporting a genetic relationship with granitic magmatism.
Integrated geological evidence indicates that the Linghou deposit represents a Late Jurassic Cu-polymetallic skarn system. These findings not only resolve the long-standing genetic controversy of this deposit type but also highlight the considerable exploration potential for magmatic-hydrothermal Cu-polymetallic systems along the Qin-Hang metallogenic belt. The combined application of high-precision geochronology, microscale mineral chemistry, and detailed metal source tracing provides critical constraints for understanding ore-forming mechanisms, refining genetic classifications, and establishing robust metallogenic frameworks.
层状铜矿床是世界范围内铜的重要来源,长期以来一直是广泛科学研究的主题。然而,它们的起源仍然备受争议。为了解决这一关键问题,我们利用微量分析矿物学和主要矿石矿物原位硫同位素分析,以及与成因相关的热液磷灰石高精度年代学,对华南灵侯矿床进行了全面调查。灵侯层状矿石中与铜成矿有关的热液磷灰石的截距U-Pb年龄为161.0±4.6 Ma (MSWD = 1.09),与矿床花岗闪长斑岩的年龄一致。同时存在的黄铜矿和闪锌矿的显微结构和温度分析表明,形成温度为255 ~ 303℃,具有岩浆-热液系统的特征。硫化物矿物硫同位素组成δ34S范围窄,δ34S范围为+0.68‰~ +2.80‰,进一步支持了与花岗岩浆作用的成因关系。综合地质证据表明,灵厚矿床为晚侏罗世铜多金属矽卡岩体系。这些发现不仅解决了长期以来对该矿床类型成因的争论,而且突出了秦航成矿带岩浆-热液铜多金属系统的巨大找矿潜力。高精度地质年代学、微尺度矿物化学和详细金属源示踪的结合应用,为理解成矿机制、完善成矿分类和建立稳健的成矿框架提供了关键约束。
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引用次数: 0
In-situ geochronology and geochemistry of allanite, monazite and calcite in the Yushishan metasedimentary rock-hosted Nb-Ta-REE deposit (NW China) 玉石山变质沉积岩含铌钽稀土矿床allanite、monazite和方解石的原位年代学及地球化学特征
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-18 DOI: 10.1016/j.oregeorev.2026.107128
Cheng-Lai Deng, Shao-Yong Jiang, Hui-Min Su, Wei Chen, Tao Liu
The newly discovered Yushishan Nb-Ta-REE deposit is hosted by metasedimentary rocks (mainly leptynite) in the South Qilian orogen, northwestern China. However, key aspects of this deposit, including the precise timing of rare earth element (REE) mineralization, its metallogenic history, and the mechanisms driving REE enrichment, remain poorly constrained. This study integrates in-situ U-Pb geochronology of REE-rich minerals (allanite and monazite), in-situ geochemical and C-Sr isotopic analyses of calcite, and whole-rock Sr-Nd-Pb isotopic compositions to elucidate the deposit’s genesis. In-situ U-Pb dating of monazite and allanite constrains the timing of REE mineralization to ∼490 Ma, indicating a genetic connection between REE mineralization and regional alkaline intrusions. Petrological and geochemical characteristics identify four types of calcites (Cal-1 to Cal-4) from aegirine-augite syenite, syenite and mineralized leptynite. Cal-1 and Cal-3, characterized by higher (La/Lu)N ratios, are inferred to derive from magmatic fluids, whereas Cal-2 and Cal-4 likely originate from metamorphic fluids. Additionally, petrological and geochemical evidence confirms a hydrothermal origin for monazite and allanite in mineralized leptynite, highlighting the critical role of hydrothermal fluids in mineralization. Calcite C-Sr isotopic compositions indicate that ore-forming fluids incorporated components from both host rock marble and ancient strata (e.g. Daken Daban Group). Whole-rock Sr-Nd isotopes reveal a shared magma source for alkaline intrusions and leptynite, pointing to a hybridized lithospheric mantle-derived reservoir as the primary source of ore-forming materials. The metallogenic history of the Yushishan deposit is divided into two key stages: (1) a Neoproterozoic pre-enrichment stage (∼830 Ma) involving REE-enriched alkaline volcanism, which laid the foundation for subsequent mineralization; and (2) an Early Paleozoic metallogenic event (∼490 Ma) triggered by the northward subduction of the North Qilian Block beneath the Central Qilian Block. This subduction event induced asthenospheric upwelling, promoting partial melting of the lithospheric mantle to generate Nb-Ta-REE-rich melts. These melts mixed with lower crustal melts and intruded into the Aoyougou Formation leptynites. Subsequent magmatic-hydrothermal fluids then remobilized pre-existing REE reservoirs in the leptynite, culminating in REE mineralization. This multistage model underscores the combined role of magmatic-hydrothermal and metamorphic-hydrothermal systems in the activation, transport, and deposition of REEs in the Yushishan deposit.
在南祁连造山带新发现的雨石山铌钽稀土矿床赋存于变质沉积岩(主要为细斑岩)中。然而,该矿床的关键方面,包括稀土元素(REE)成矿的精确时间、成矿历史和驱动REE富集的机制,仍然知之甚少。本研究结合富ree矿物(allanite和monazite)的原位U-Pb年代学、方解石的原位地球化学和C-Sr同位素分析以及全岩Sr-Nd-Pb同位素组成来阐明矿床的成因。单独居石和allanite的原位U-Pb测年将稀土矿化时间限制在~ 490 Ma,表明稀土矿化与区域碱性侵入体之间存在成因联系。岩石学和地球化学特征鉴定出4种方解石类型(Cal-1 ~ Cal-4),分别为铝辉石正长岩、正长岩和矿化细斑岩。Cal-1和Cal-3的(La/Lu)N比值较高,可能来源于岩浆流体,Cal-2和Cal-4可能来源于变质流体。此外,岩石学和地球化学证据证实了矿化瘦铁矿中独居石和allanite的热液成因,突出了热液流体在成矿中的关键作用。方解石C-Sr同位素组成表明,成矿流体中既有主岩大理岩成分,也有古地层(如大肯大坂群)成分。全岩Sr-Nd同位素显示碱性侵入岩与细斑岩具有共同的岩浆源,表明混合岩石圈幔源储层是成矿物质的主要来源。鱼石山矿床成矿史分为两个关键阶段:(1)新元古代前富集阶段(~ 830 Ma),为成矿奠定了基础,为富集稀土的碱性火山作用奠定了基础;(2)北祁连地块在中祁连地块下向北俯冲所引发的早古生代成矿事件(~ 490 Ma)。这一俯冲事件诱发软流圈上升流,促使岩石圈地幔部分熔融生成富铌钽稀土熔体。这些熔体与下地壳熔体混合,侵入到奥油沟组细斑岩中。随后的岩浆-热液流体重新激活了瘦铁矿中已有的稀土储层,最终导致稀土矿化。该多阶段模式强调了岩浆-热液系统和变质-热液系统在玉石山矿床稀土活化、输运和沉积过程中的共同作用。
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引用次数: 0
Complex magmatic processes recorded by zoned clinopyroxene in the Wajilitag mafic–ultramafic intrusion of the Permian Tarim Large Igneous Province, northwest China 塔里木二叠系大火成岩省瓦吉里塔格基性-超基性侵入岩中分带斜辉石岩记录的复杂岩浆过程
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-18 DOI: 10.1016/j.oregeorev.2026.107124
Yan Luan , Zhen-Ye Zhang , Yi-Jun Wang , Xiao-Hui Sun , Matthew J. Brzozowski , Chang-Zhi Wu
The Wajilitag intrusion is one of the most important mafic–ultramafic layered intrusions in the Tarim Large Igneous Province (LIP) as it hosts significant Fe–Ti–V mineralization. Despite this, the ubiquitous zoned clinopyroxene in this intrusion have largely been overlooked, limiting our understanding of the magmatic processes by which it formed. Here, we utilize major- and trace-element compositions of clinopyroxene to assess the petrogenetic evolution of Wajilitag, including the pressure–temperature conditions of crystallization, the magmatic processes by which it evolved, and the processes that led to the formation of Fe–Ti–V mineralization. Four types of zoned clinopyroxene are identified based on texture and zoning patterns. Type 1 clinopyroxene is characterized by abrupt zones and contains rounded, irregularly resorbed high-Mg cores (Mg# = 80.5–85.2) surrounded by low-Mg rims (Mg# = 66.1–77.5). Type 2–1 clinopyroxene is characterized by oscillatory zoning in which the mantle (Mg# = 73.8–80.3) has notably higher Mg contents than the core (Mg# = 72.7–77.1) and rim (Mg# = 70.7–75.1). Type 2–2 clinopyroxene exhibits normal zoning, in which Mg# and Cr contents gradually decrease from the core through the mantle to the rim. Type 3 clinopyroxene displays prism sector ({-111}) and hourglass sector ({010} and {110}) zoning, the presence of which implies a low to moderate degree of undercooling (ΔT = 40–51 °C). Type 4 clinopyroxene is euhedral and exhibits complex zoning (Mg# = 70.7–77.7). Clinopyroxene-only thermobarometry for mafic rocks at Wajilitag delineate two distinct magma reservoirs — (1) a deep, high-temperature magma chamber at ∼ 9.9 km depth and (2) a shallow, low-temperature magma chamber at ∼ 5.9 km depth. The parental magma in the deep chamber was likely more primitive than that in the shallow chamber, forming the Cr–Mg-rich core of type 1 clinopyroxene; the more evolved nature of the magma in the shallow chamber formed Cr–Ni-depleted clinopyroxenes represented by clinopyroxene types 2–4 and the rim of type 1. The H2O contents of the parental magmas range from 1.3–2.3 wt% (average = 1.8 wt%) in the deep magma chamber and 0.8–3.0 wt% (average = 2.0 wt%) in the shallow chamber. Iron–Ti oxides in the Wajilitag intrusion crystallized from an Fe–Ti-rich, oxidized, and hydrous magma at pressures and temperatures of 0.4–1.6 kbar and 1096–1137℃, respectively, and then accumulated during magma replenishment and vigorous convection. The complex textural and compositional characteristics of clinopyroxene at Wajilitag indicate that the intrusion represents an open magmatic plumbing system beneath the Tarim LIP that was periodically replenished by evolved and hydrous magmas.
瓦吉里塔格岩体是塔里木大火成岩省(LIP)最重要的基性-超基性层状岩体之一,具有显著的铁-钛-钒成矿作用。尽管如此,这种侵入岩中普遍存在的分带斜辉石在很大程度上被忽视了,限制了我们对其形成的岩浆过程的理解。本文利用斜辉石的主量元素和微量元素组成对瓦吉里塔格的成岩演化进行了评价,包括结晶的压力-温度条件、演化的岩浆过程以及导致Fe-Ti-V矿化形成的过程。根据构造和分带格局,将斜辉石划分为4种类型。1型斜辉石以突兀带为特征,含有圆形、不规则吸收的高镁岩心(Mg# = 80.5-85.2)和低镁岩心(Mg# = 66.1-77.5)。2-1型斜辉石具有震荡带的特征,其中地幔(Mg# = 73.8 ~ 80.3)的Mg含量明显高于地核(Mg# = 72.7 ~ 77.1)和边缘(Mg# = 70.7 ~ 75.1)。2-2型斜辉石呈现正常的分带特征,Mg#和Cr含量由岩心经地幔至岩缘逐渐降低。3型斜辉石呈棱柱状({-111})和沙漏状({010}和{110})分带,表明过冷程度低至中等(ΔT = 40-51°C)。4型斜辉石为自面体,分带复杂(mg# = 70.7 ~ 77.7)。瓦吉里塔格基性岩石的斜辉石热气压测定圈定了两个不同的岩浆储层:(1)深度为~ 9.9 km的深部高温岩浆房和(2)深度为~ 5.9 km的浅层低温岩浆房。深室母岩浆可能比浅室原始,形成1型斜辉石富cr - mg核;浅室岩浆的演化性质较好,形成了以2-4型斜辉石和1型斜辉石为代表的贫铬镍斜辉石。母岩浆的水含量在深部岩浆房中为1.3 ~ 2.3 wt%(平均1.8 wt%),在浅部岩浆房中为0.8 ~ 3.0 wt%(平均2.0 wt%)。瓦吉里塔格岩体中的铁-钛氧化物分别在0.4 ~ 1.6 kbar和1096 ~ 1137℃的压力和温度下由富铁-钛、氧化和含水岩浆结晶而成,并在岩浆补给和剧烈对流过程中积累。瓦吉里塔格斜辉石复杂的结构和组成特征表明,该侵入体代表了塔里木盆地下一个开放的岩浆管道系统,该系统周期性地补充了演化和含水岩浆。
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引用次数: 0
Cu-Au vein-type mineralization in the Danyore Valley, Kohistan arc, northern Pakistan: Insights from geochemistry, geochronology, and sulfide alteration 巴基斯坦北部Kohistan弧Danyore谷铜金脉型矿化:来自地球化学、地质年代学和硫化物蚀变的见解
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-17 DOI: 10.1016/j.oregeorev.2025.107091
Iqtidar Hussain , Huan Li , Mohamed Faisal , Asad Khan , Mohammad Naseer , Jubril Izge Hassan , Hasnain Ali
The Kohistan terrane of northern Pakistan, one of the largest Cretaceous island-arc complexes, is well documented in terms of tectono-magmatic evolution, yet its metallogenic framework remains poorly constrained. The Danyore Valley in Gilgit-Baltistan hosts Cu-Au-bearing quartz veins associated with Mesozoic gabbro-diorite intrusions of the Ladakh-Kohistan arc. The age, petrogenesis, and ore-forming processes of this system have not previously been established. Here, we integrate field observations, petrography, whole-rock geochemistry, LA-ICP-MS zircon U-Pb geochronology, zircon and sulfide geochemistry, and S-Pb isotopic data to constrain the evolution of the host rocks and the origin of mineralization. Zircon U–Pb dating indicates Early Cretaceous crystallization ages (∼110 Ma) for the host rocks, while geochemical signatures reveal a calc-alkaline arc affinity, derived from a depleted mantle source metasomatized by slab-derived fluids and modified through fractional crystallization in a continental margin setting. The sulfide mineralization occurs in NW- and NE-trending quartz veins dominated by chalcopyrite, pyrite, and bornite with notable gold enrichment, accompanied by phyllic, propylitic, and carbonatization alteration. Sulfur and lead isotope compositions suggest mixed mantle and crustal sources, including contributions from granitoids of the Kohistan Batholith. Collectively, these results demonstrate that the Danyore Valley mineralization represents an Early Cretaceous, structurally controlled, arc-related Cu–Au vein system, thereby reducing metallogenic uncertainty within the Kohistan terrane and highlighting its exploration potential.
巴基斯坦北部的Kohistan地体是白垩纪最大的岛弧复合体之一,在构造-岩浆演化方面有很好的记录,但其成矿框架仍不明确。该体系的年龄、成岩作用和成矿过程尚未确定。综合野外观测、岩石学、全岩地球化学、LA-ICP-MS锆石U-Pb年代学、锆石和硫化物地球化学、S-Pb同位素等资料,对寄主岩石演化和成矿成因进行了研究。锆石U-Pb测年显示了寄主岩石的早白垩世结晶年龄(~ 110 Ma),而地球化学特征显示了钙碱性弧亲和关系,这一亲和关系来自于一个衰竭的地幔源,该地幔源被板块衍生流体交代,并在大陆边缘环境中经过分离结晶修饰。硫化物矿化发生在以黄铜矿、黄铁矿、斑铜矿为主的NW、ne向石英脉中,金矿富集显著,并伴有叶基、丙基、碳酸化蚀变。硫和铅的同位素组成表明地幔和地壳的混合来源,包括科希斯坦基的花岗岩类的贡献。综上所述,这些结果表明,Danyore Valley矿化代表了早白垩世,构造控制,弧形相关的铜金脉系统,从而降低了Kohistan地体内成矿的不确定性,突出了其找矿潜力。
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引用次数: 0
In situ compositions and sulfur isotopes of the copper sulfides from the Jiama giant copper polymetallic deposit: implications for ore-forming material sources, gold enrichment mechanism and mineral exploration 甲玛巨型铜多金属矿床铜硫化物原位组成及硫同位素:成矿物质来源、金富集机制及找矿意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-11 DOI: 10.1016/j.oregeorev.2025.107095
Fenghua Gu , Xiang Fang , Juxing Tang , Pan Tang , Hongjin Chen , Aorigele Zhou , Miao Sun , Zhengkun Yang
The Jiama giant copper polymetallic deposit is one of the most important deposits in the Gangdise metallogenic belt, which consists of hornfels-type Cu-Mo, skarn-type Cu-polymetallic, porphyry-type Mo-Cu, and distal vein-type Au orebodies with associated Ag, W, and Bi mineralizations. This deposit develops a large number of copper sulfides, such as bornite, juxingite and chalcopyrite. This study carried out LA-ICP-MS and EPMA analyses on the aforementioned copper sulfides to (1) assess the elements’ partitioning and distribution pattern in the mineral assemblage, (2) trace the ore-forming material source, (3) decipher the metallogenetic physicochemical environment, and (4) ascertain the gold enrichment mechanism. The study results show that both bornite and juxingite are enriched in Bi, in particular with the juxingite, whose Bi peak content reaches 80425 ppm. Besides, as the most important gold carrier in the Jiama deposit, bornite contains significantly more Au and Ag contents than those in other sulfides, and the content of Bi, Au and Ag in bornite shows a decreasing trend from the distal skarn to the proximal skarn. In contrast to bornite and juxingite, chalcopyrite possesses much lower Bi, Au and Ag contents. Elemental correlation analysis shows that the contents of Au and Ag in bornite and chalcopyrite are positively correlated with those of the elements, such as Bi, Te and Se, which could be indicative of the spatial location of mineralization. The δ34S values of the most sulfide samples in Jiama deposit range from −3.42 to −0.9, which are similar to those in the porphyry of the Gangdise metallogenic belt, indicating an ore-forming material source of the neogenic lower crust with addition of the mantle-derived materials. Locally, some bornite samples possess much lower δ34S values (−7.52 to −6.81), which implies that there maybe a mixing of the organic sulfur from the wall rocks of the Linbuzong Formation or sulfur isotope fractionation caused by cooling. The formation temperature of bornite-chalcopyrite assemblages ranges from 236℃ to 345℃, and the mineral assemblages reveal that the log fS2 was greater than −12 during the main stage of skarn mineralization, while the fS2 was less than −11 during the late mineralization of skarn. The gold enrichment in bornite and juxingite was closely relevant to existence of the Bi-Au melt. During the mineralization process, Bi melts scavenged Au from hydrothermal fluids, and the fluctuation of oxygen fugacity led to precipitation of the Bi-Au melts and enrichment of gold in bornite. With the temperature cooling, the juxingite exsolved from the bornite and captured the residual gold in the fluid.
甲玛巨型铜多金属矿床是冈底斯成矿带的重要矿床之一,由角状铜钼矿体、矽卡岩型铜多金属矿体、斑岩型钼铜矿体和远脉型金矿体组成,并伴有银、钨、铋成矿作用。该矿床发育有大量的铜硫化物,如斑铜矿、榴辉矿和黄铜矿。本研究对上述铜硫化物进行了LA-ICP-MS和EPMA分析,以(1)评估矿物组合中元素的分配和分布规律,(2)追踪成矿物质来源,(3)解读成矿物理化学环境,(4)确定金的富集机制。研究结果表明,斑岩和橄榄石均富集Bi,其中橄榄石的Bi峰值含量可达80425 ppm。此外,作为甲玛矿床中最重要的金载体,斑岩中Au和Ag的含量明显高于其他硫化物,且斑岩中Bi、Au和Ag的含量从远矽卡岩向近矽卡岩呈下降趋势。黄铜矿的Bi、Au和Ag含量远低于斑铜矿和珠光石。元素相关性分析表明,斑铜矿和黄铜矿中Au、Ag的含量与Bi、Te、Se等元素的含量呈正相关,可以指示成矿的空间位置。甲玛矿床多数硫化物样品的δ34S值在−3.42 ~−0.9之间,与冈底斯成矿带斑岩的δ34S值相近,表明成矿物质来源为新近期下地壳,并加入了幔源物质。局部斑岩样品δ34S值较低(−7.52 ~−6.81),说明可能有林布宗组围岩有机硫的混合作用或冷却引起的硫同位素分馏作用。斑铜矿-黄铜矿组合的形成温度范围为236 ~ 345℃,矿物组合显示矽卡岩成矿主阶段的fS2大于−12,而矽卡岩成矿晚期的fS2小于−11。斑岩和橄榄岩中的金富集与Bi-Au熔体的存在密切相关。成矿过程中,Bi熔体从热液中清除Au,氧逸度的波动导致Bi-Au熔体沉淀,金在斑岩中富集。随着温度的降低,珠光石从斑铜矿中析出,并捕获了流体中的残余金。
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引用次数: 0
Magmatic and hydrothermal superimposition in Nb-Ta-Li mineralization at the Hailuoling deposit, South China: Records from columbite-tantalite chronology and mica chemistry 海螺岭铌钽利成矿的岩浆和热液叠加作用:来自铌钽矿年代学和云母化学的记录
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-09 DOI: 10.1016/j.oregeorev.2025.107083
Yu Zhou , Yong Zhang , Zhe Xu , Fangrong Zhang , Jiayong Pan , Haotong Dai , Fushen Zhang , Wei Wan , Bin He , Cong Liu
The Hailuoling Nb–Ta deposit in the Wuyi metallogenic belt of South China represents a typical granite-related rare-metal system that has recently been recognized to host associated Li mineralization. To constrain its metallogenic evolution, we integrate petrological, geochronological, and geochemical data. LA–ICP–MS U–Pb dating of monazite and columbite–tantalite indicates that the porphyritic biotite monzogranite crystallized at 147.2 ± 1.9 Ma, whereas Nb–Ta mineralization occurred at 144.4 ± 2.1 Ma, both during the Late Jurassic–Early Cretaceous transition. Li-bearing micas including protolithionite, zinnwaldite, lithium phengite, and lithium muscovite, in mineralized granite replace primary biotite, feldspar, and quartz and display irregular grain boundaries and well-developed compositional zoning, providing textural evidence for hydrothermal metasomatism. Mica compositions define a systematic evolutionary trend characterized by increasing SiO2 and decreasing FeO contents, while trace element data reveal an initial enrichment followed by depletion of Li, Nb, and Ta. These features support a two-stage model involving an early post-magmatic hydrothermalism stage followed by a later hydrothermal metasomatism stage. Hydrothermal micas are characterized by Nb/Ta ratios of 0.5–2.5 and K/Rb ratios of 8–12. Comparative analyses with micas from unmineralized granites and from the Maoping and Xianghualing deposits highlights the necessity of overprinting by late-stage magmatic–hydrothermal fluids, in combination with external fluid input, to achieve economically significant rare-metal enrichment in early intrusions that did not independently reach ore-forming thresholds. We conclude that the interplay between magmatic differentiation and hydrothermal overprinting is critical for the mobilization and concentration of rare metals in certain granitic systems.
华南武夷成矿带海洛岭铌钽矿床是一个典型的花岗岩相关稀有金属成矿系统,近年来已被确认为伴生李矿化。为了限定其成矿演化,我们综合了岩石学、年代学和地球化学资料。LA-ICP-MS U-Pb定年表明,斑岩型黑云母二长花岗岩的结晶时间为147.2±1.9 Ma,铌钽矿化时间为144.4±2.1 Ma,均发生在晚侏罗世-早白垩世过渡时期。矿化花岗岩中的原橄榄岩、锌walite、锂云母、锂白云母等含锂云母代替原生黑云母、长石和石英,晶界不规则,成分分带发育,为热液交代提供了结构证据。云母的组成呈现出SiO2含量增加、FeO含量减少的系统演化趋势,微量元素数据则呈现出Li、Nb、Ta等元素先富集后富集的变化趋势。这些特征支持两阶段模式,即早期岩浆后热液作用阶段和后期热液交代阶段。热液云母的Nb/Ta比值为0.5 ~ 2.5,K/Rb比值为8 ~ 12。通过与未矿化花岗岩云母和茂坪、香花岭矿床云母的对比分析,认为晚期岩浆-热液流体的套印,结合外部流体输入,在未独立达到成矿阈值的早期侵入体中实现具有经济意义的稀有金属富集是必要的。岩浆分异和热液套印的相互作用对某些花岗岩体系中稀有金属的富集和活化起着至关重要的作用。
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引用次数: 0
Why Middle Jurassic coal seams generally lack volcanic-ash-altered kaolinitic layers and critical metals enrichment compared to the Carboniferous-Permian in the Ordos Basin, North China? 鄂尔多斯盆地中侏罗统煤层为何普遍缺乏火山-灰岩蚀变高岭石层和临界金属富集?
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-05 DOI: 10.1016/j.oregeorev.2026.107108
Shuai Zhang, Xiaomeng Sun, Xi Xu, Qinfu Liu
The North China Craton (NCC) experiences two major coal-forming episodes: the Late Carboniferous–Early Permian and the Early–Middle Jurassic. Despite the tectonically active setting of the NCC during the Middle Jurassic, volcanic-ash-altered kaolinitic layers and an enrichment of critical metals are notably lacking in Middle Jurassic coal seams relative to those of the Carboniferous–Permian, and the causes of this disparity remain unclear. This study investigates the contributions of inorganic inputs during peat accumulation and the influence of hydrothermal activity on Middle Jurassic coal seams in the Ordos Basin, aiming to clarify the geological controls underlying this disparity. The clastic materials of the coal and partings were derived from the weathering of uplifts around Ordos Basin, without a critical metals-rich source rocks therein. The peat accumulation during the Middle Jurassic did not coincide with intensive magmatic events in adjacent tectonic domains (Mongol–Okhotsk, Paleo-Pacific, and Bangong-Nujiang Tethys), resulting in limited volcanic ash input. Although the No. 6 coal seam contains XRD-detectable apatite, it is authigenic, forming during peat deposition or early diagenesis, and is not significantly enriched in rare earth elements. Moreover, the intense Late Jurassic–Early Cretaceous magmatic–hydrothermal activity linked to rollback of the subducted Paleo-Pacific Plate in the eastern NCC did not extend to the Ordos Basin. Therefore, the lack of volcanic-ash-altered kaolinitic layers and an enrichment of critical metals in the Middle Jurassic coal seams is primarily attributed to the limited supply of critical metal-enriched detrital material and volcanic ash, and negligible hydrothermal influence during and after peat accumulation.
华北克拉通经历了晚石炭世—早二叠世和早中侏罗世两个主要成煤期。尽管北中侏罗统在中侏罗统时期构造活跃,但与石炭-二叠纪相比,中侏罗统煤层明显缺乏火山-火山灰蚀变高岭石层和关键金属的富集,造成这种差异的原因尚不清楚。本文研究了鄂尔多斯盆地中侏罗统煤成藏过程中无机输入的贡献和热液活动对煤层的影响,旨在阐明这种差异背后的地质控制因素。煤的碎屑物质来源于鄂尔多斯盆地周围隆起的风化作用,其中没有关键的富金属烃源岩。中侏罗统泥炭堆积与邻近构造域(蒙古-鄂霍次克、古太平洋和班公-怒江特提斯)岩浆活动不一致,导致火山灰输入有限。6号煤层虽然含有xrd可探测到的磷灰石,但属于自生,形成于泥炭沉积或早期成岩过程中,稀土元素含量不明显。此外,晚侏罗世-早白垩世强烈的岩浆热液活动与北西带东部俯冲的古太平洋板块回退有关,但并未延伸到鄂尔多斯盆地。因此,中侏罗统煤层缺乏火山灰蚀变高岭石层和富集关键金属的主要原因是富集关键金属的碎屑物质和火山灰的供应有限,而泥炭成藏期间和之后的热液影响可以忽略不计。
{"title":"Why Middle Jurassic coal seams generally lack volcanic-ash-altered kaolinitic layers and critical metals enrichment compared to the Carboniferous-Permian in the Ordos Basin, North China?","authors":"Shuai Zhang,&nbsp;Xiaomeng Sun,&nbsp;Xi Xu,&nbsp;Qinfu Liu","doi":"10.1016/j.oregeorev.2026.107108","DOIUrl":"10.1016/j.oregeorev.2026.107108","url":null,"abstract":"<div><div>The North China Craton (NCC) experiences two major coal-forming episodes: the Late Carboniferous–Early Permian and the Early–Middle Jurassic. Despite the tectonically active setting of the NCC during the Middle Jurassic, volcanic-ash-altered kaolinitic layers and an enrichment of critical metals are notably lacking in Middle Jurassic coal seams relative to those of the Carboniferous–Permian, and the causes of this disparity remain unclear. This study investigates the contributions of inorganic inputs during peat accumulation and the influence of hydrothermal activity on Middle Jurassic coal seams in the Ordos Basin, aiming to clarify the geological controls underlying this disparity. The clastic materials of the coal and partings were derived from the weathering of uplifts around Ordos Basin, without a critical metals-rich source rocks therein. The peat accumulation during the Middle Jurassic did not coincide with intensive magmatic events in adjacent tectonic domains (Mongol–Okhotsk, Paleo-Pacific, and Bangong-Nujiang Tethys), resulting in limited volcanic ash input. Although the No. 6 coal seam contains XRD-detectable apatite, it is authigenic, forming during peat deposition or early diagenesis, and is not significantly enriched in rare earth elements. Moreover, the intense Late Jurassic–Early Cretaceous magmatic–hydrothermal activity linked to rollback of the subducted Paleo-Pacific Plate in the eastern NCC did not extend to the Ordos Basin. Therefore, the lack of volcanic-ash-altered kaolinitic layers and an enrichment of critical metals in the Middle Jurassic coal seams is primarily attributed to the limited supply of critical metal-enriched detrital material and volcanic ash, and negligible hydrothermal influence during and after peat accumulation.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107108"},"PeriodicalIF":3.6,"publicationDate":"2026-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145950195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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