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Fluid inclusion composition reveals mineralization potential of the Mogutu skarn deposit, NE China 流体包裹体组成揭示了中国东北木古图夕卡岩矿床的成矿潜力
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-14 DOI: 10.1016/j.oregeorev.2026.107178
Yixin Li , Qihai Shu , Zifeng He , Xudong Niu , Jiajun Liu , Siyuan Liu , Shuqi Wen
The growing global demand for mineral resources underscores the increasing importance of intrusion-related hydrothermal deposits as the major sources of numerous metals such as Cu, Mo, Sn, and W. While magmatic-hydrothermal systems are widespread, determining their ore-forming capability and establishing methods to assess their potential remain key challenges for mineral exploration. Ore-related fluids trapped in fluid inclusions at relatively high temperatures predating mineralization preserve the pristine geochemical signatures of magmatic exsolution, serving as an ideal tool for addressing the above issues. In this study, the fluid inclusions in the pegmatite quartz from an Early Cretaceous alkali-feldspar granite, the causative intrusion of the Mogutu skarn deposit in NE China, were analyzed using laser ablation-inductively coupled plasma-mass spectrometry. The results have been used to demonstrate how fluid compositions can be applied to evaluate the fertility of the hydrothermal system. The Mogutu fluids exhibit elevated concentrations of Sn (560 ppm) and Ag (78 ppm) compared to Sn- or Ag-barren systems, but are depleted in Cu (540 ppm) relative to typical Cu-mineralized systems. The concentrations of Fe (3.2 wt%), Zn (5,700 ppm), and Pb (2,950 ppm) are comparable to both those Fe/Zn-Pb deposits and barren systems. The results align with the occurrence of economic Sn-Ag ores in the Mogutu skarn, while the Fe mineralization likely benefited significantly from an additional contribution from the Fe-rich wallrocks (e.g., andesite). Mass balance calculation further reveals the high endowment of Zn-Pb but low W-Mo, consistent with the widespread Zn-Pb ores but no W-Mo mineralization in Mogutu and the surrounding region. This study demonstrates that fluid inclusion composition is a reliable geochemical indicator for assessing mineralization potential, thereby enhancing predictive accuracy in magmatic-hydrothermal prospectivity.
随着全球对矿产资源需求的不断增长,与侵入体相关的热液矿床作为铜、钼、锡和钨等多种金属的主要来源日益重要。岩浆热液系统分布广泛,确定其成矿能力并建立评估其潜力的方法仍然是矿产勘探的关键挑战。成矿前相对高温下包裹体中的含矿流体保存了岩浆溶蚀的原始地球化学特征,是解决上述问题的理想工具。本文采用激光烧蚀-电感耦合等离子体质谱分析了中国东北莫古图矽卡岩矿床成因侵入物——早白垩世碱长石花岗岩伟晶岩石英中的流体包裹体。这些结果已被用来证明如何应用流体成分来评估热液系统的肥力。Mogutu流体中Sn (560ppm)和Ag (78ppm)的含量高于无锡或无银体系,但Cu (540ppm)含量低于典型的铜矿化体系。铁(3.2 wt%)、锌(5700 ppm)和铅(2950 ppm)的浓度与这些铁/锌-铅矿床和贫瘠体系相当。结果与Mogutu矽卡岩中存在经济的Sn-Ag矿石相一致,而铁矿化可能受益于富铁围岩(如安山岩)的额外贡献。质量平衡计算进一步揭示了木古图及周边地区锌铅赋存量高、W-Mo赋存量低的特征,与该区广泛存在锌铅矿而W-Mo矿化不明显相吻合。研究表明,流体包裹体组成是评价成矿潜力的可靠地球化学指标,可提高岩浆-热液找矿预测精度。
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引用次数: 0
Discovery of a suspected intrusion-related polymetallic Mo-Bi-Te-Au vein-stockwork system in the southern Chilean Andes: The Trapananda prospect, Patagonia, Chile 智利南部安第斯山脉疑似侵入相关的多金属Mo-Bi-Te-Au脉网系统的发现:智利巴塔哥尼亚的Trapananda远景区
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-22 DOI: 10.1016/j.oregeorev.2026.107132
Marcos Zentilli , Jacob Hanley , Juan Valdes-Edwards
The Trapananda prospect in Rio Soler, Aysén, XIth Region, Patagonia, Chile, contains quartz-molybdenum (Mo)-bismuth (Bi)-tellurium (Te)-gold (Au) vein arrays within, and near, a granite apophysis of the North Patagonian Batholith that intrudes carbonaceous metasedimentary rocks (phyllites and schists) of Late Paleozoic to Triassic age. It was first interpreted as a porphyry-type Mo deposit, and some of the quartz vein arrays have some similarities with those in metamorphogenic turbidite-hosted orogenic Au deposits. However, the Trapananda mineralization is comprised of molybdenite, native bismuth, and Bi-Te-S sulfosalts suggesting a different genetic model. The dating of molybdenite by the Re-Os isotopic method yielded a model age of 143.5 (±0.6) Ma (late Jurassic), confirming a genetic association with the adjoining batholith. Two-phase fluid inclusions in quartz show no evidence of boiling (phase separation) but are coeval with molybdenite, Bi-Te-S sulfosalt minerals, and trails of Bi-Te-S semi-metal melt inclusions. The fluid inclusions have an average salinity of 13.4 wt% eq. NaCl and Th of 210°C (n = 39 inclusions in 8 fluid inclusion assemblages). Fluid inclusions were trapped between ∼270 and ∼400°C at a minimum P of 0.7–2 kbar kbar (min ∼2.5–7 km depth), constrained by integrating isochore data with Bi-Te-S phase relation compositional constraints for fluid-coeval semi-metal melt inclusions. Together with the fluid inclusion systematics, the geochemistry of the igneous rocks, the vein textures, mineralogy and metal association (Mo-Bi-Te-Au) including semi-metal melts (which may have played a role in concentrating Au), and the stable isotope systematics (quartz δ18OVSMOW + 10 ‰; sulfide-sulfosalt δ34SVCDT −0.1 to −1.0 ‰; host schist δ13CVPDB = –22 ‰) at the Trapananda occurrence are most compatible with metasediment-hosted, reduced intrusion-related Au system (RIRGS). However, some features are not consistent with this classification and thus, an intrusion-related polymetallic type of mineralization is favoured as a more general classification. Importantly, this type of Mo-Bi-Te-Au mineralized system has not previously documented in Chile. The lack of native Au and abundance of Bi-Te-S sulfosalt minerals that may contain dissolved “invisible Au”, concentrated during the suspected migration of semi-metal melts, may explain why the deposit eluded discovery by traditional prospecting (panning) methods in this remote, glaciated region.
智利巴塔哥尼亚XIth地区ays Soler里约热内卢的Trapananda远景区,在侵入晚古生代至三叠纪碳质变质沉积岩(千层岩和片岩)的北巴塔哥尼亚基花岗岩顶突内及其附近,含有石英-钼(Mo)-铋(Bi)-碲(Te)-金(Au)脉阵。初步解释为斑岩型钼矿床,部分石英脉列与变质浊积岩型造山带金矿有相似之处。然而,特拉帕南达矿化由辉钼矿、天然铋和Bi-Te-S硫酸盐组成,表明其成因模式不同。辉钼矿的Re-Os同位素测年模型年龄为143.5(±0.6)Ma(晚侏罗世),证实了其与邻近岩基的遗传关联。石英中的两相流体包裹体没有沸腾(相分离)的迹象,但与辉钼矿、Bi-Te-S亚硫酸盐矿物和Bi-Te-S半金属熔体包裹体的痕迹相同。流体包裹体的平均盐度为13.4 wt%, NaCl和Th为210°C(8个流体包裹体组合中的39个包裹体)。流体包裹体在~ 270 ~ ~ 400°C之间被捕获,最小P值为0.7 ~ 2 kbar kbar(最小深度为~ 2.5 ~ 7 km),受流体-同步半金属熔体包裹体的Bi-Te-S相关系成分约束积分等差数据的约束。结合流体包裹体系统,特拉普南达产状火成岩地球化学、脉体结构、矿物学和金属组合(Mo-Bi-Te-Au)(含半金属熔体)(可能在富集Au过程中起作用)以及稳定同位素系统(石英δ18OVSMOW + 10‰;硫化物-亚硫酸盐δ34SVCDT−0.1 ~−1.0‰;主片岩δ13CVPDB = -22‰)与变质沉积为主、侵入体相关的还原型Au系统(RIRGS)最为相容。然而,有些特征与这种分类不一致,因此,与侵入体有关的多金属矿化类型被认为是更一般的分类。重要的是,这种类型的Mo-Bi-Te-Au矿化系统以前在智利没有记录。缺乏天然Au和丰富的Bi-Te-S亚硫酸盐矿物,可能含有溶解的“看不见的Au”,在可疑的半金属熔体迁移过程中集中,可能解释了为什么在这个偏远的冰川地区,传统的勘探(淘金)方法无法发现该矿床。
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引用次数: 0
Early paleozoic Rb mineralization in South China: Geochronology and geochemistry of Xianglushan Rb-rich granite in the Yuechengling batholith, South China 华南早古生代Rb成矿作用:岳城岭相庐山富Rb花岗岩年代学及地球化学特征
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-11 DOI: 10.1016/j.oregeorev.2026.107164
Yupeng Huo , Meng Feng , Chuan Zhao , Wei Fu , Zuohai Feng , Chunzeng Wang
Rubidium (Rb) deposits in South China are typically associated with highly evolved Yanshanian or Indosinian granites, while Rb mineralization related to Caledonian granites remains poorly documented. The occurrence state and enrichment mechanism of Rb in Caledonian granite is still unclear. This study investigates a newly discovered Rb-rich granite at Xianglushan within the Yuechengling batholith, South China. The Xianglushan Rb-rich granite exhibits a magmatic-hydrothermal sequence that evolves from monzogranite through monzogranite (K-feldspar alteration) to albitized granite. LA-ICP-MS U-Pb dating of zircon and cassiterite from the Xianglushan Rb-rich granite yielded concordia ages of 416.6 ± 3.5 Ma and 415.9 ± 2.4 Ma, respectively. Zircon εHf(t) values (−6.9 to −3.6) and TDM2 model ages (1.65–1.90 Ga) indicate the magma was derived from the partial melting of Paleoproterozoic crustal material. Compared to barren Caledonian granites in Yuechengling, the Xianglushan Rb-rich granite is weakly to strongly peraluminous, with high SiO2, DI, TE1,3 values and non-CHARAC behavior in element pairs (Zr/Hf, Nb/Ta, Y/Ho, K/Rb). These characteristics indicate that they experienced highly fractionated evolution and melt-fluid interaction, which promoted the enrichment of Rb. Muscovite and K-feldspar are the primary host minerals for Rb resources. The Rb-rich magmatic (Ms-1) and hydrothermal muscovite (Ms-2 and Ms-3) mainly occur in muscovite monzogranite and altered granite, respectively. Ms-1 exhibits the highest Rb content, ranging from 7603 to 8249 ppm, while Rb contents gradually decrease from Ms-2 to Ms-3. This study reveals that the Caledonian granite could enriche Rb during both magmatic and hydrothermal stages. Early and extensive magmatic muscovite precipitation reduces the Rb content of the residual fluids.
华南地区铷(Rb)矿床通常与高度演化的燕山期或印支期花岗岩有关,而与加里东期花岗岩有关的Rb成矿作用文献较少。加里东期花岗岩Rb的赋存状态和富集机制尚不清楚。本文研究了在中国南方岳城岭岩基相庐山新发现的一种富铷花岗岩。象庐山富铷花岗岩表现为岩浆-热液序列,由二长花岗岩经二长花岗岩(钾长石蚀变)演化至钠长化花岗岩。LA-ICP-MS U-Pb测年结果显示,象庐山富铷花岗岩锆石和锡石的年龄分别为416.6±3.5 Ma和415.9±2.4 Ma。锆石εHf(t)值(−6.9 ~−3.6)和TDM2模式年龄(1.65 ~ 1.90 Ga)表明岩浆来源于古元古代地壳物质的部分熔融。与岳城岭加里东期花岗岩相比,相庐山富铷花岗岩具有弱至强过铝质特征,具有较高的SiO2、DI、TE1、3值,元素对(Zr/Hf、Nb/Ta、Y/Ho、K/Rb)具有非charac行为。这些特征表明它们经历了高度分馏演化和熔体-流体相互作用,促进了Rb的富集。白云母和钾长石是Rb资源的主要寄主矿物。富铷岩浆(Ms-1)和热液白云母(Ms-2和Ms-3)分别主要产于白云母二长花岗岩和蚀变花岗岩中。Ms-1中Rb含量最高,为7603 ~ 8249ppm, Ms-2至Ms-3中Rb含量逐渐降低。研究表明,加里东期花岗岩在岩浆期和热液期均可富集Rb。早期广泛的岩浆白云母沉淀降低了残余流体Rb含量。
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引用次数: 0
Genesis of the Bairendaba Ag-Zn-Pb deposit and its linkage to the Weilasituo Sn-polymetallic deposit, southern Great Xing’an Range, Northeast China 大兴安岭南部白仁坝银铅锌矿床成因及其与韦拉斯沱锡多金属矿床的联系
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-11 DOI: 10.1016/j.oregeorev.2026.107174
Ming-Yu Cao , Sha-Sha Yang , Hui-Min Su , Tao-Jie Dai , Jia-Qi Xu , Xin-Tong Dong
The Weilasituo–Bairendaba district in the southern Great Xing’an Range hosts one of Northeast China’s most representative polymetallic vein systems, yet the genetic relationship between its Sn-W-Li and Ag-Zn-Pb mineralization remains unresolved. This study integrates new geochronological, geochemical, and isotopic data to clarify the link between the Bairendaba Ag-Zn-Pb and Weilasituo Sn-polymetallic deposits and to constrain the evolution of their ore-forming fluids. The mineralization at Bairendaba comprises three main stages: an early Cu-Zn, a middle Pb-Zn-Ag, and a late Ag-rich stage. In situ LA-ICP-MS U-Pb dating of newly discovered wolframite from the early Cu-Zn stage yielded an age of 133.1 ± 3.3 Ma, consistent with the mineralization age of nearby Weilasituo Sn-polymetallic deposit (135–141 Ma), indicating a shared Early Cretaceous metallogenic event. Systematic trace-element variations in sphalerite (e.g., decreasing In, Se; increasing Cd, Ge; rising Zn/Cd and Ga/In ratios) and wolframite (decreasing Nb-Ta concentrations with distance) from Weilasituo to Bairendaba record progressive fluid cooling and distal metal precipitation from a common magmatic-hydrothermal system. H-O isotope data from Weilasituo to Bairendaba (δ18Ofluid: 5.3 to −6.3‰; δD: −125.9 to −110.5‰), confirm that the hydrothermal fluids evolved from magmatic-dominated (early high-temperature and salinity) to meteoric-influenced (lower-temperature and salinity) conditions. Carbon and S isotopes (δ13C = -18.2 to −6.9‰; δ34S = -3.3 to + 0.3‰) of Bairendaba further indicate late-stage organic carbon input from host gneiss and a uniform magmatic sulfur source. Collectively, the Bairendaba deposit is classified as a medium-temperature magmatic-hydrothermal vein system, genetically linked to the Weilasituo deposit. It represents the distal, medium-temperature expression of a unified Sn-W-Li-Cu-Pb-Zn-Ag magmatic–hydrothermal system centered on the Weilasituo intrusion, characterized by temperature-controlled mineralization zonation across the district.
大兴安岭南部的韦拉斯图—白莲坝地区是中国东北地区最具代表性的多金属脉系之一,但其Sn-W-Li矿化与Ag-Zn-Pb矿化的成因关系尚不明确。本研究综合了新的年代学、地球化学和同位素资料,阐明了百人坝银锌铅矿床与韦拉斯托锡多金属矿床之间的联系,并对其成矿流体的演化进行了约束。白仁坝成矿主要分为三个阶段:早期Cu-Zn阶段、中期Pb-Zn-Ag阶段和晚期富银阶段。新发现的早Cu-Zn阶段黑钨矿原位LA-ICP-MS U-Pb定年结果为133.1±3.3 Ma,与附近韦拉斯托锡多金属矿床的成矿年龄(135 ~ 141 Ma)一致,表明两者在早白垩世有共同的成矿事件。从韦拉斯托到白莲坝,闪锌矿和黑钨矿中微量元素的系统性变化(in、Se降低,Cd、Ge升高,Zn/Cd和Ga/ in比值升高)和铌- ta浓度随距离降低)记录了同一岩浆-热液体系的流体冷却过程和远端金属沉淀过程。韦拉斯沱—白伦巴的H-O同位素(δ18Ofluid: 5.3 ~−6.3‰;δD:−125.9 ~−110.5‰)数据证实了热液流体由岩浆主导(早期高温、盐度)向大气影响(低温、盐度)的演化过程。白连坝的碳、硫同位素(δ13C = -18.2 ~−6.9‰,δ34S = -3.3 ~ + 0.3‰)进一步表明,白连坝晚期有机碳输入来自寄主片麻岩和均匀岩浆硫源。白连坝矿床总体上属于中温岩浆-热液脉系,与韦拉斯沱矿床有成因联系。代表了以魏拉斯托岩体为中心的统一的Sn-W-Li-Cu-Pb-Zn-Ag岩浆热液系统的远端中温表现,具有全区控温矿化带的特征。
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引用次数: 0
Isotope records of carbon, oxygen and sulfur reveal the role of sulfate evaporites in the formation of Sakatti Cu-Ni-PGE sulfide ore, Central Lapland Greenstone belt, Finland 碳、氧、硫同位素记录揭示了硫酸盐蒸发岩在芬兰中部拉普兰绿岩带Sakatti Cu-Ni-PGE硫化矿形成中的作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-09 DOI: 10.1016/j.oregeorev.2026.107159
Henri M.A. Höytiä , Juha A. Karhu , Petri T. Peltonen , Hugh O’Brien , Tapio Halkoaho , Minna Myllyperkiö
Stable isotope ratios of carbon, oxygen and sulfur have been used since the 1950́s to understand the formation of magmatic and hydrothermal ore deposits. They are particularly useful in tracing the origin and differentiation of phases involved in ore-forming processes. For many sulfide ore deposits, tracking the source of sulfur is important for decoding the genesis of a deposit and to understand the mineralizing systems regionally and globally. We studied the isotopic composition of carbon (δ13C), oxygen (δ18O) in wall rock carbonates, and sulfur (δ33S and δ34S) in sulfide ore and wall rock sulfates in the Paleoproterozoic Sakatti Cu-Ni-PGE sulfide deposit in the Central Lapland Greenstone Belt, northern Finland. The results suggest emplacement of a komatiitic olivine cumulate body into a c. 2.2–2.05 Ga evaporite sequence, which appears to have provided most of the crustal sulfur in the Sakatti sulfide ore body. Mechanisms of the incorporation of sulfate sulfur to mafic-ultramafic magmas have been recently advanced and recognized in many base-precious metal camps. Tracking the prior presence of evaporites can be cryptic, as they tend to be camouflaged in the geological record over lengthy time scales. Assimilation of sedimentary sulfur typically shifts sulfur isotope signatures away from mantle values towards the values of assimilated crustal sulfur. However, the shift in sulfur isotope signature of the resulting sulfides can be surprisingly subtle, only showing small deviations from mantle values. Sulfur isotopes can also be homogenized by the presence of coexisting fluids leading to a well-mixed δ34S signature, as demonstrated by the limited range of the bulk of the δ34S values (2-4 ‰) measured from the Sakatti deposit. The assimilation of evaporitic material might also play an important role in the formation of Cu (± Pd ± Au ± Ag)-dominated ores in many other magmatic Ni-Cu-PGE deposits.
自20世纪50年代以来,碳、氧和硫的稳定同位素比率已被用于了解岩浆和热液矿床的形成。它们在追踪成矿过程中所涉及的相的起源和分异方面特别有用。对于许多硫化物矿床来说,追踪硫的来源对于解码矿床的成因以及了解区域和全球的成矿系统非常重要。研究了芬兰北部拉普兰中部绿岩带中古元古代Sakatti Cu-Ni-PGE硫化物矿床围岩碳酸盐岩中碳(δ13C)、氧(δ18O)、硫化物矿石和围岩硫酸盐中硫(δ33S和δ34S)的同位素组成。结果表明,在约2.2 ~ 2.05 Ga的蒸发岩层序中,存在一个科马马质橄榄石堆积体,该蒸发岩层序提供了Sakatti硫化物矿体中大部分的地壳硫。硫酸盐硫与镁铁质-超镁铁质岩浆结合的机制近年来在许多碱基贵金属营地得到了提出和确认。追踪蒸发岩之前的存在可能是神秘的,因为它们往往在漫长的时间尺度上伪装在地质记录中。沉积硫的同化通常使硫同位素特征从地幔值转向同化的地壳硫值。然而,由此产生的硫化物的硫同位素特征的变化可能非常微妙,只显示出与地幔值的微小偏差。硫同位素的均一化也可以通过共存流体的存在导致较好的混合δ34S特征,这可以从Sakatti矿床测量的大部分δ34S值(2 ~ 4‰)的有限范围得到证明。蒸发物质的同化作用也可能对其他岩浆型镍铜铂矿床中Cu(±Pd±Au±Ag)为主矿石的形成起重要作用。
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引用次数: 0
Magmatic volatiles and seawater contributions to the formation of the Huangtupo VMS deposit, Eastern Tianshan, NW China 岩浆挥发物和海水对东天山黄土坡VMS矿床形成的贡献
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-09 DOI: 10.1016/j.oregeorev.2026.107155
Wendong Zhang, Xuebing Zhang, Xinran Gui, Jinghao Wang
The Huangtupo Cu–Zn deposit in the Eastern Tianshan, NW China, is a Paleozoic arc-related volcanogenic massive sulfide (VMS) system characterized by well-developed vertical and lateral metal zonation. Trace-element and sulfur isotope (δ34S) variations in pyrite record temporal changes in sulfur sources, metal transport, and hydrothermal fluid evolution during formation of the Huangtupo VMS system.
Pre-ore massive pyrite (Py1) shows dominantly positive δ34S values (+0.75‰ to +4.72‰) and relatively low median trace-metal contents, indicating precipitation from seawater-dominated hydrothermal fluids with minor magmatic overprinting. Syn-ore pyrite from massive and brecciated Cu–Zn ores (Py2a–Py2b) represents the principal ore-forming stage and is enriched in magmatic volatile–related metals (Cu, As, Se, Sb, Au, Tl, and Bi) together with the most negative δ34S values (down to −3.49‰), reflecting strong magmatic volatile input and sulfur derived from SO2 disproportionation, with subordinate seawater mixing. Syn-ore pyrite from silicified and barite-bearing disseminated ores (Py2c–Py2d) displays lower volatile-metal contents and uniformly positive δ34S values (+0.53‰ to +1.92‰), indicating waning magmatic influence and increasing control of seawater-derived fluids.
Late epigenetic vein-type pyrite (Py3) is metal-poor, has the highest δ34S values (+2.62‰ to +4.57‰), and exhibits anomalously high Co/Ni ratios (17.56–165.04) together with very low As contents. These features indicate precipitation from cooler, seawater-dominated and more oxidizing fluids, in which oxygen fugacity exerted a stronger control than temperature on trace-element partitioning, marking a waning and noneconomic stage of the hydrothermal system.
Overall, pyrite trace-element and sulfur isotope systematics document a progressive evolution from early seawater-dominated mineralization, through a magmatic volatile–driven main ore stage, to late oxidizing seawater overprinting, highlighting the critical role of magmatic degassing and seawater mixing in the formation of arc-related VMS systems.
东天山黄土坡铜锌矿床是一个古生代与弧相关的火山块状硫化物(VMS)系统,其垂直和横向金属分带发育。黄铁矿微量元素和硫同位素(δ34S)变化记录了黄土坡VMS系统形成过程中硫源、金属输运和热液流体演化的时间变化。矿前块状黄铁矿(Py1) δ34S值主要为正(+0.75‰~ +4.72‰),微量金属含量中值相对较低,表明成矿流体以海水为主,岩浆套印较少。斑状和角砾型铜锌矿(Py2a-Py2b)的正矿石黄铁矿为主要成矿阶段,富含岩浆挥发性相关金属(Cu、As、Se、Sb、Au、Tl、Bi), δ34S值最负(低至- 3.49‰),反映岩浆挥发性输入强烈,硫来源于SO2的不化,海水混合次要。硅化和含重晶石浸染型矿石(Py2c-Py2d)的同矿黄铁矿挥发性金属含量较低,δ34S值均为正(+0.53‰~ +1.92‰),表明岩浆作用减弱,海水流体控制作用增强。晚后生脉状黄铁矿(Py3)贫金属,δ34S值最高(+2.62‰~ +4.57‰),Co/Ni比值异常高(17.56 ~ 165.04),As含量极低。这些特征表明,热液系统的沉淀来自温度较低、以海水为主、氧化性较强的流体,其中氧逸度对微量元素分配的控制作用强于温度,标志着热液系统处于衰退期和非经济阶段。总体而言,黄铁矿微量元素和硫同位素系统记录了从早期以海水为主的成矿作用,经过岩浆挥发驱动的主矿阶段,再到晚期氧化海水套印的渐进演化过程,突出了岩浆脱气和海水混合在弧相关VMS系统形成中的关键作用。
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引用次数: 0
Geochemical and mineralogical characteristics of six ore types of Main and Eastern orebodies in the Bayan Obo deposit: A combined PMF and SEM-EDS analysis 白云鄂博矿床主、东矿体6种矿石类型地球化学矿物学特征:PMF与SEM-EDS联合分析
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-01-31 DOI: 10.1016/j.oregeorev.2026.107150
Yanling Sun , Xueqiu Wang , Qinghai Hu , Jian Zhou , Mingjun Xie , Xiuming Jing
The Bayan Obo deposit in northern China is the world’s largest source of REE, with substantial Fe and Nb resources. Although different ore types in the deposit have long been recognized, their high mineralogical diversity has hindered systematic evaluation of elemental associations and quantitative characterization of REE geochemistry. In this study, we integrate Positive Matrix Factorization (PMF) of multi-element geochemical datasets with Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS) mineral identification to quantify elemental assemblages and mineralogical characteristics, and further analyze the REE patterns across ores representing these known types. Six distinct elemental association groups are identified, dominated respectively by: dolomite-type (MgO-CaO-Mn-Co-Sr-Zn), amphibole-type (SiO2-MgO-K2O-Na2O-Th-Zn-Co-V), aegirine-REE type (Na2O-SiO2-TFe2O3-FeO-REE-Pb-Ti), iron oxide-type (TFe2O3-FeO-Co-Mn-Th), fluorite-REE type (CaO-F-Nb-P-REE), and barite-REE type ores (Ba-S-Ti-Sr-Pb-REE-Nb-Th-U). Significant variability in REE contents and fractionation patterns was observed across ore types. Barite-REE, fluorite-REE, and aegirine-REE type ores exhibit the highest total REE concentrations (9.54 wt%, 7.74 wt%, and 5.94 wt%, respectively), coupled with pronounced LREE enrichment, as indicated by elevated (La/Yb) CN ratios of 4964, 1598, and 1572. In contrast, dolomite-type and iron oxide-type ores exhibit moderate REE enrichment (2.45 wt% and 2.34 wt%, respectively), while amphibole-type ores contain the lowest REE contents (0.663 wt%), but display significantly higher proportions of Nd and MREE. Negative Eu anomalies (average δEu = 0.621–0.798) observed in nearly all ore types suggest that extensive hydrothermal alteration has significantly influenced REE distribution. These results establish a geochemical framework for identifying elemental association patterns and refining the understanding of REE distribution in the Bayan Obo deposit.
中国北部的白云鄂博矿床是世界上最大的稀土资源来源,具有丰富的铁和铌资源。虽然矿床中矿石类型不同,但其矿物学多样性高,妨碍了元素组合的系统评价和稀土地球化学定量表征。在本研究中,我们将多元素地球化学数据集的正矩阵分解(PMF)与扫描电镜-能谱(SEM-EDS)矿物鉴定相结合,量化元素组合和矿物学特征,并进一步分析代表这些已知类型的矿石的REE模式。鉴定出6个不同的元素组合族,分别以白云岩型(MgO-CaO-Mn-Co-Sr-Zn)、角闪石型(sio2 - mgo - k20 - na20 - th - zn - co - v)、稀土型(na20 - sio2 - tfe2o3 - feo - ree - pb - ti)、氧化铁型(TFe2O3-FeO-Co-Mn-Th)、萤石型稀土(CaO-F-Nb-P-REE)和重晶石型稀土(Ba-S-Ti-Sr-Pb-REE-Nb-Th-U)为主。不同矿石类型的稀土元素含量和分馏模式存在显著差异。重晶石-REE、萤石-REE和铝基-REE型矿石显示出最高的总REE浓度(分别为9.54 wt%、7.74 wt%和5.94 wt%),并伴随着明显的轻稀土富集,(La/Yb) CN比值分别为4964、1598和1572。白云岩型和氧化铁型矿石稀土元素富集程度中等(分别为2.45 wt%和2.34 wt%),角闪岩型矿石稀土元素含量最低(0.663 wt%),但Nd和MREE含量明显较高。几乎所有矿石类型均出现负Eu异常(平均δEu = 0.621 ~ 0.798),表明广泛的热液蚀变对稀土元素分布有显著影响。这些结果为识别白云鄂博矿床元素组合模式和完善对稀土元素分布的认识建立了地球化学框架。
{"title":"Geochemical and mineralogical characteristics of six ore types of Main and Eastern orebodies in the Bayan Obo deposit: A combined PMF and SEM-EDS analysis","authors":"Yanling Sun ,&nbsp;Xueqiu Wang ,&nbsp;Qinghai Hu ,&nbsp;Jian Zhou ,&nbsp;Mingjun Xie ,&nbsp;Xiuming Jing","doi":"10.1016/j.oregeorev.2026.107150","DOIUrl":"10.1016/j.oregeorev.2026.107150","url":null,"abstract":"<div><div>The Bayan Obo deposit in northern China is the world’s largest source of REE, with substantial Fe and Nb resources. Although different ore types in the deposit have long been recognized, their high mineralogical diversity has hindered systematic evaluation of elemental associations and quantitative characterization of REE geochemistry. In this study, we integrate Positive Matrix Factorization (PMF) of multi-element geochemical datasets with Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS) mineral identification to quantify elemental assemblages and mineralogical characteristics, and further analyze the REE patterns across ores representing these known types. Six distinct elemental association groups are identified, dominated respectively by: dolomite-type (MgO-CaO-Mn-Co-Sr-Zn), amphibole-type (SiO<sub>2</sub>-MgO-K<sub>2</sub>O-Na<sub>2</sub>O-Th-Zn-Co-V), aegirine-REE type (Na<sub>2</sub>O-SiO<sub>2</sub>-TFe<sub>2</sub>O<sub>3</sub>-FeO-REE-Pb-Ti), iron oxide-type (TFe<sub>2</sub>O<sub>3</sub>-FeO-Co-Mn-Th), fluorite-REE type (CaO-F-Nb-P-REE), and barite-REE type ores (Ba-S-Ti-Sr-Pb-REE-Nb-Th-U). Significant variability in REE contents and fractionation patterns was observed across ore types. Barite-REE, fluorite-REE, and aegirine-REE type ores exhibit the highest total REE concentrations (9.54 wt%, 7.74 wt%, and 5.94 wt%, respectively), coupled with pronounced LREE enrichment, as indicated by elevated (La/Yb) <sub>CN</sub> ratios of 4964, 1598, and 1572. In contrast, dolomite-type and iron oxide-type ores exhibit moderate REE enrichment (2.45 wt% and 2.34 wt%, respectively), while amphibole-type ores contain the lowest REE contents (0.663 wt%), but display significantly higher proportions of Nd and MREE. Negative Eu anomalies (average δEu = 0.621–0.798) observed in nearly all ore types suggest that extensive hydrothermal alteration has significantly influenced REE distribution. These results establish a geochemical framework for identifying elemental association patterns and refining the understanding of REE distribution in the Bayan Obo deposit.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107150"},"PeriodicalIF":3.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146192595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochronology constrains Early Cretaceous gold mineralization in the Baiyun gold deposit, Liaodong Peninsula 辽东半岛白云金矿床早白垩世金矿化的地质年代学制约
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-10 DOI: 10.1016/j.oregeorev.2026.107172
Zhe-Xin Cai , Hao-Cheng Yu , Hai-Zhong Bao , Thomas Bader , Tao Cui , Ya-Peng Li , Zong-Yi Feng , Shan-Shan Li , Nan Ju , Nikolai A. Goryachev , Kun-Feng Qiu
The Baiyun gold deposit in the Liaodong Peninsula, North China Craton, contains > 120 t of gold, but its mineralization age and genesis remain contentious. To constrain the timing of gold mineralization, we conducted in-situ LA-ICP-MS U-Pb dating of monazite and rutile from gold ores, together with zircon from mineralized dikes. U-Pb dating of monazite yielded a concordia age of 1806.0 ± 38 Ma, which we interpret as Paleoproterozoic regional metamorphism instead of hydrothermal mineralization. Rutile yielded two age populations at 1083.0 ± 37 Ma and 389.0 ± 30 Ma, attributed to Mesoproterozoic and Paleozoic tectono-thermal events, respectively. Zircon yielded crystallization ages of 232.0 ± 2.0 Ma for diorite porphyrite dike, 225.9 ± 1.2 Ma for granodiorite dike, and 121.68 ± 0.48 Ma for granite dike. Field and petrographic evidence indicate that all dated dikes predate gold mineralization. Therefore, the youngest magmatic zircon provides a maximum constraint on the timing of mineralization. Within the established regional geochronological framework, the data suggest that gold mineralization at Baiyun most plausibly occurred during the Early Cretaceous (ca. 120 Ma). To further elucidate its origin, we compare mineralization age, geodynamics, ore-forming fluid characteristics, and sources of gold-related metals and sulfur with those of well-characterized Jiaodong-type gold deposits. This comparison supports that Baiyun represents an Early Cretaceous Jiaodong-type mineral system, formed during lithospheric thinning driven by rollback of the Paleo-Pacific plate.
华北克拉通辽东半岛白云金矿床含金量达120 t,但其成矿时代和成因仍有争议。为了确定金矿化的时间,我们对金矿中的独居石和金红石以及矿化岩脉中的锆石进行了原位LA-ICP-MS U-Pb测年。单氮石U-Pb测年结果显示,其年龄为1806.0±38 Ma,为古元古代区域变质作用,而非热液成矿作用。金红石有1083.0±37 Ma和389.0±30 Ma两个年龄群,分别属于中元古代和古生代构造-热事件。锆石结晶年龄为闪长玢岩脉232.0±2.0 Ma,花岗闪长岩脉225.9±1.2 Ma,花岗岩脉121.68±0.48 Ma。野外和岩石学证据表明,这些岩脉的年代都早于金矿化。因此,最年轻的岩浆锆石对成矿时间提供了最大限度的约束。在已建立的区域年代学框架内,白云区金矿化最可能发生在早白垩世(约120 Ma)。为了进一步阐明其成因,我们将成矿年龄、地球动力学、成矿流体特征以及金相关金属和硫的来源与特征良好的胶东型金矿床进行了比较。这一对比结果支持白云为早白垩世胶东型矿物体系,形成于古太平洋板块回退推动的岩石圈减薄过程中。
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引用次数: 0
Geochronology and genesis of the sedimentary rock-hosted Lunshan gold deposit in the Ningzhen district, Jiangsu Province: evidence from zircon and fluid inclusion microanalysis 江苏宁镇地区伦山金矿沉积岩年代学及成因:锆石和流体包裹体微分析证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-23 DOI: 10.1016/j.oregeorev.2026.107184
Chen Zhang , Jun-Yi Pan , Ling-Qiang Yin , Ming-Sen Fan , Jun-Ying Ding , Wen-Chao Su , Pei Ni
The Lunshan gold deposit, located in the Ningzhen district of the Middle-Lower Yangtze River Metallogenic Belt, represents the largest gold deposit in Jiangsu Province. It exhibits distinctive sedimentary rock-hosted mineralization within siltstone-shale sequences and shows transition from early Au to late Pb-Zn ore stages which are intimately linked to silicification and sericitization alteration, and are spatially associated with cryptobreccias. Despite its economic significance, the lack of robust constraints on its mineralization age, ore-forming fluid characteristics, and genetic type severely restrict the exploration and prospecting in deep and peripheral area. This study presents the first LA-ICP-MS zircon U-Pb age of pre- and post-ore igneous rocks, and precisely brackets the Lunshan gold mineralization within 105–103 Ma. This age correlates with exposed porphyry-skarn Cu-Mo-Fe deposits within the Ningzhen district. Zircon from the gold-associated dioritic dykes shows elevated Ce/Ui×Ti and 104 × (EuN/Eu*)YbN ratios. These trace element signatures indicate a deep, oxidized, hydrous, and fertile magma source with potential to form porphyry deposits. Integrated fluid inclusion microthermometry and LA-ICP-MS analysis reveal that the ore-forming fluid originated from deep, single-sourced magmatic fluid. Reconstruction of the complete hydrothermal ore process reveals that gold and base metal mineralization are controlled by divergent fluid evolution pathways. Gold mineralization is primarily driven by fluid boiling linked to cryptobreccias and local carbonaceous reduction within the host strata. These processes efficiently remove H2S from fluids, destabilizing Au-HS complexes and eventually triggering gold precipitation. In contrast, Pb-Zn mineralization is formed mainly via fluid mixing between magmatic fluid and meteoric water, which decreases the salinity and temperature of fluids, destabilizing Pb/Zn-Cl complexes, and leads to Pb-Zn deposition. The integrated evidences suggest the Lunshan gold deposit being a distal sedimentary rock-hosted epithermal endmember of a deep-seated porphyry system. This genetic model may shed light on further gold-polymetallic mineral exploration in the Ningzhen district.
伦山金矿床位于长江中下游成矿带宁镇地区,是江苏省最大的金矿床。在粉砂岩-页岩层序中具有明显的沉积岩矿化特征,呈现出早期金矿到晚期铅锌矿阶段的过渡,与硅化和绢云母化蚀变密切相关,在空间上与隐角砾岩相关。尽管具有重要的经济意义,但其成矿年龄、成矿流体特征、成因类型等方面缺乏强有力的约束,严重制约了深部和外围地区的找矿工作。本文首次给出了成矿前后火成岩的LA-ICP-MS锆石U-Pb年龄,并精确圈定了105 ~ 103 Ma范围内的伦山金矿化。该年龄与宁镇地区出露斑岩-夕卡岩型铜钼铁矿床有关。与金伴生闪长岩脉的锆石Ce/Ui×Ti和104 × (EuN/Eu*)YbN比值升高。这些微量元素特征表明,这是一个深部、氧化、含水、肥沃的岩浆源,具有形成斑岩矿床的潜力。流体包裹体显微测温和LA-ICP-MS分析表明,成矿流体来源于深部单源岩浆流体。对完整热液成矿过程的重建表明,金和贱金属成矿受发散的流体演化路径控制。金矿化主要由与隐隐藻有关的流体沸腾和寄主地层内局部碳质还原驱动。这些过程有效地去除流体中的H2S,破坏Au-HS配合物的稳定,最终引发金的沉淀。岩浆流体与大气水的混合作用使流体盐度和温度降低,破坏了Pb/Zn-Cl配合物的稳定,导致Pb- zn沉积。综合证据表明,仑山金矿床是深部斑岩体系的远端沉积岩成矿浅成热液端段。这一成因模式对宁镇地区进一步找金多金属矿产具有指导意义。
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引用次数: 0
Scheelite geochemistry constrains the origin of W mineralization in the Laojunshan district, Southeast Yunnnan, China: Comparative studies from the Nanyangtian, Changtian and Saxi deposits 滇东南老君山地区钨矿化成因的白钨矿地球化学约束——以南阳田、长田和萨溪矿床为例
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-03-01 Epub Date: 2026-02-14 DOI: 10.1016/j.oregeorev.2026.107179
Zi-Chao Tang , Xiao-Yu Zhao , Ming-Guo Deng , Wen-Chang Li , Ying-Hua Chen , Qing-Ge Zhang , Ding-Cai Zhang
The Laojunshan district in southeastern Yunnan is a critical Sn-W metallogenic district in China, with multi-episode and multi-type W mineralization. However, the comparative studies were lacking to reveal the genetic relationship among these W deposits. In this study, scheelites from three representative W deposits (Nanyangtian, Saxi and Changtian) in this district were collected for in situ trace element and Sr Nd isotopic analyses, with the aim of constraining differences in material sources and ore forming physicochemical conditions.
In the Nanyangtian deposit, six scheelite types (Sch A-1, Sch A-2, Sch B, Sch C, Sch D-1 and Sch D-2) were identified, corresponding to distinct mineralization stages including prograde skarn stage, retrograde skarn stage, quartz-sulfide stage and quartz-scheelite vein stage. Cathodoluminescence (CL) imaging shows two substages within the Sch A (Sch A-1 and Sch A-2) and rim overgrowths of Sch D-1 on Sch C. The diverse REE patterns and Eu anomalies imply that the oxygen fugacity evolution of the ore-forming fluids at Nanyangtian followed a decrease–increase–decrease trend, with a predominantly reducing fluid environment. This result is further confirmed by the low Mo contents and the lack of positive δCe–δEu correlations. Similarly, scheelite from Saxi (Sch SX) and Changtian (Sch CT) display positive Eu anomalies and low Mo concentrations, indicating a generally low oxygen fugacity condition of W mineralization across the Laojunshan district. The variations in initial 87Sr/86Sr ratios among different scheelite types at Nanyangtian likely resulted from different levels of wall rock contamination, and the linear isotopic trend excluded the superimposition of multi-episode mineralization events. All (87Sr/86Sr)i values of scheelite (0.71465–0.72956 at Nanyangtian, 0.71261–0.72227 at Saxi and 0.72505–0.72710 at Changtian) overlap with the field of the Early Cretaceous Laojunshan granite (0.71301–0.74172). Integrating Y/Ho ratios, εNd(t) values of scheelite, and recent geochronological data, we infer that although formed at different ages, the Nanyangtian and Saxi deposits share a common deep seated source with the Laojunshan granite, whereas the Changtian deposit was derived directly from the granite.
滇东南老君山地区是中国重要的锡钨成矿区,具有多期次、多类型的成矿作用。然而,这些钨矿床之间的成因关系还缺乏比较研究。本文收集了该区3个代表性W矿床(南阳田、萨溪和长田)的白钨矿,对其进行了原位微量元素和Sr Nd同位素分析,以制约其物质来源和成矿物理化学条件的差异。南阳天矿床确定了6种白钨矿类型(Sch A-1、Sch A-2、Sch B、Sch C、Sch D-1和Sch D-2),对应着不同的成矿阶段,包括顺行矽卡岩阶段、逆行矽卡岩阶段、石英-硫化物阶段和石英-白钨矿脉阶段。阴极发光(CL)成像显示在Sch A-1和Sch A-2两个亚阶段以及Sch D-1在Sch c上的边缘过度生长,不同的REE模式和Eu异常表明南阳天成矿流体的氧逸度演化呈减少-增加-减少的趋势,流体环境以还原为主。Mo含量低,δCe -δEu不存在正相关关系,进一步证实了这一结果。同样,萨溪(SX)和长田(CT)白钨矿也呈现出Eu正异常和低Mo浓度,表明整个老君山地区W矿化的氧逸度普遍较低。南阳天不同白钨矿类型初始87Sr/86Sr比值的差异可能是围岩污染程度不同所致,线性同位素趋势排除了多期成矿事件的叠加作用。白钨矿(0.71465 ~ 0.72956)、(0.71261 ~ 0.72227)、(0.72505 ~ 0.72710)与早白垩世老君山花岗岩(0.71301 ~ 0.74172)均有重合。综合白钨矿的Y/Ho比值、εNd(t)值和近期的年代学资料,我们认为南阳田和萨西矿床虽然形成的年代不同,但与老君山花岗岩有着共同的深部源,而长田矿床则直接来源于花岗岩。
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Ore Geology Reviews
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