Pub Date : 2026-02-05DOI: 10.1016/j.oregeorev.2026.107157
Ying Yang , Li Wen , Changjie Cao , Yunhe Li , Bingli Liu , Yunhui Kong , Cheng Li , Zhongli Zhou
Mineral Prospectivity Mapping (MPM) is a fundamental task in geosciences for identifying regions with high mineral potential. High-order geological associations are intrinsic to mineralization processes, yet have not been explicitly represented or effectively mined in existing studies, even though mineralization often arises from the joint influence of multiple geological factors interacting in complex ways. To address this problem, this study introduces HyperMinNet, a hypergraph-based framework for modeling and discovering high-order relationships in MPM. In HyperMinNet, hyperedges are constructed across both spatial and attribute domains to capture multi-factor geological associations. The Density-Based Spatial Clustering of Applications with Noise (DBSCAN) algorithm plays a central role in grouping geologically related units, thereby highlighting complex, spatially coherent associations beyond simple pairwise relationships. To further enhance the model’s ability to recognize informative geological patterns, an attention mechanism is employed to adaptively focus on critical associations, while a center loss function mitigates the influence of limited positive mineralization samples by enhancing the distinctiveness of learned representations. Experiments conducted in the Lhasa region demonstrate the effectiveness of the proposed framework, where HyperMinNet achieved an accuracy of 0.9042 and an Area Under the Curve (AUC) of 0.9511, confirming its strong potential in advancing mineral prospectivity mapping.
{"title":"HyperMinNet: A hypergraph-based framework incorporating high-order relationships for mineral prospectivity mapping","authors":"Ying Yang , Li Wen , Changjie Cao , Yunhe Li , Bingli Liu , Yunhui Kong , Cheng Li , Zhongli Zhou","doi":"10.1016/j.oregeorev.2026.107157","DOIUrl":"10.1016/j.oregeorev.2026.107157","url":null,"abstract":"<div><div>Mineral Prospectivity Mapping (MPM) is a fundamental task in geosciences for identifying regions with high mineral potential. High-order geological associations are intrinsic to mineralization processes, yet have not been explicitly represented or effectively mined in existing studies, even though mineralization often arises from the joint influence of multiple geological factors interacting in complex ways. To address this problem, this study introduces HyperMinNet, a hypergraph-based framework for modeling and discovering high-order relationships in MPM. In HyperMinNet, hyperedges are constructed across both spatial and attribute domains to capture multi-factor geological associations. The Density-Based Spatial Clustering of Applications with Noise (DBSCAN) algorithm plays a central role in grouping geologically related units, thereby highlighting complex, spatially coherent associations beyond simple pairwise relationships. To further enhance the model’s ability to recognize informative geological patterns, an attention mechanism is employed to adaptively focus on critical associations, while a center loss function mitigates the influence of limited positive mineralization samples by enhancing the distinctiveness of learned representations. Experiments conducted in the Lhasa region demonstrate the effectiveness of the proposed framework, where HyperMinNet achieved an accuracy of 0.9042 and an Area Under the Curve (AUC) of 0.9511, confirming its strong potential in advancing mineral prospectivity mapping.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107157"},"PeriodicalIF":3.6,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146192523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-04DOI: 10.1016/j.oregeorev.2026.107156
Liu Xuemin , Wu Xu , Yang Yuanliang , Yue Dabin , Liao Xingjian , Zhao Pufeng , Wang Guozhi , Liu Bingli
While the magmatic source and evolution significantly influence rare metal mineralization in pegmatites, a critical unresolved question remains: within the same mining district, some spatially close pegmatites are mineralized while others are not. This highlights the existence of other crucial factors governing pegmatite mineralization. Tourmaline, a common borosilicate mineral in pegmatite systems, serves as a key indicator for deciphering mineralization processes. We studied the tourmaline from the Murong Li deposit (Asia’s largest single-vein Li deposit) using geochemistry, boron isotopes, and mineralogy. Three types were identified: BP-Tur (tourmaline in barren pegmatite), FP-Tur (tourmaline in fertile pegmatite), and AC-Tur (tourmaline in altered country rock). BP-Tur and FP-Tur exhibit pronounced zoning textures, indicating magmatic-hydrothermal formation. BP-Tur crystallized in a low-salinity, high-ƒO2, fluid-rich setting. In contrast, FP-Tur formed under initially low ƒO2 and low salinity, with both parameters increasing during later crystallization. AC-Tur is fine-grained, non-zoned and formed in a low-temperature, high-pressure, high-salinity, and high-ƒO2 environment. Its heavier δ11B values stem from 11B-enriched magmatic fluids. Systematic boron isotope variations across growth zones in BP-Tur and FP-Tur record magmatic evolution under open and closed conditions, respectively. This interpretation is corroborated by higher estimated pressures for FP-Tur relative to BP-Tur, consistent with fluid loss and pressure decrease in open systems. Unlike previous studies, we find no direct correlation between the contents of Li, Sn, Nb, or Ta in tourmaline and mineralization. Instead, the closure of the magmatic system is a critical control on Li mineralization.
{"title":"Pegmatite evolution and mineralization: insights from tourmaline geochemistry and boron isotopes","authors":"Liu Xuemin , Wu Xu , Yang Yuanliang , Yue Dabin , Liao Xingjian , Zhao Pufeng , Wang Guozhi , Liu Bingli","doi":"10.1016/j.oregeorev.2026.107156","DOIUrl":"10.1016/j.oregeorev.2026.107156","url":null,"abstract":"<div><div>While the magmatic source and evolution significantly influence rare metal mineralization in pegmatites, a critical unresolved question remains: within the same mining district, some spatially close pegmatites are mineralized while others are not. This highlights the existence of other crucial factors governing pegmatite mineralization. Tourmaline, a common borosilicate mineral in pegmatite systems, serves as a key indicator for deciphering mineralization processes. We studied the tourmaline from the Murong Li deposit (Asia’s largest single-vein Li deposit) using geochemistry, boron isotopes, and mineralogy. Three types were identified: BP-Tur (tourmaline in barren pegmatite), FP-Tur (tourmaline in fertile pegmatite), and AC-Tur (tourmaline in altered country rock). BP-Tur and FP-Tur exhibit pronounced zoning textures, indicating magmatic-hydrothermal formation. BP-Tur crystallized in a low-salinity, high-ƒO<sub>2</sub>, fluid-rich setting. In contrast, FP-Tur formed under initially low ƒO<sub>2</sub> and low salinity, with both parameters increasing during later crystallization. AC-Tur is fine-grained, non-zoned and formed in a low-temperature, high-pressure, high-salinity, and high-ƒO<sub>2</sub> environment. Its heavier δ<sup>11</sup>B values stem from <sup>11</sup>B-enriched magmatic fluids. Systematic boron isotope variations across growth zones in BP-Tur and FP-Tur record magmatic evolution under open and closed conditions, respectively. This interpretation is corroborated by higher estimated pressures for FP-Tur relative to BP-Tur, consistent with fluid loss and pressure decrease in open systems. Unlike previous studies, we find no direct correlation between the contents of Li, Sn, Nb, or Ta in tourmaline and mineralization. Instead, the closure of the magmatic system is a critical control on Li mineralization.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107156"},"PeriodicalIF":3.6,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-03DOI: 10.1016/j.oregeorev.2026.107154
Shanshan Ru , Guo Li , Chuandong Xue , Feng Li
The Dapingzhang Cu − Au polymetallic deposit is a large volcanogenic massive sulfide (VMS) deposit formed during the Proto − Tethyan stage in western Yunnan Province, SW China, and exhibits a stratified distribution with upper massive orebodies (V1) and lower veinlet orebodies (V2). Au − rich orebodies predominantly occur within the massive orebodies near the 16# exploration line. This study investigates the microstructures, trace elemental, and sulfur isotopic compositions of pyrite, chalcopyrite, and sphalerite from the Au − rich orebodies at 1150 m and 1130 m levels to constrain the Au-bearing hydrothermal fluid sources, migration, and ore genesis. Four pyrite types were identified, representing three mineralization stages: (1) early-stage Py1 − 1 with sedimentary-formed strawberry − like textures; (2) late-stage Py1 − 2 formed through Py1 − 1 aggregation into irregular or euhedral crystals; and (3) Py2 (first-order zoning on Py1 − 2) and Py3 (second-order zoning on Py2). All Py1 − 2, Py2, and Py3 are hydrothermal in origin. Trace elemental composition reveals higher Sb concentrations in pyrite at the 1150 m level compared to those at the 1130 m level, with similar concentrating trends of Cu, Pb, Au, and Se. Evolutionary sequence analysis shows increasing Cu and Au concentrations but decreasing Co and Se concentrations in Py1 − 2, Py2, and Py3 across both the 1150 m and 1130 m levels. All pyrites are enriched in Au, Cu, Pb, Zn, and Sb but are depleted in Co, Ni, Tl, Se, Ti, and Sn. Sulfur isotope values (δ34S = − 2.63 to + 1.12‰) of pyrite, chalcopyrite, and sphalerite suggest a magmatic sulfur affinity. Gold mineralization is associated with E − W-trending ore-conducting faults. Au − rich fluids migrated upward through fractures, leaching Py1 − 1 to form inclusion textures and causing localized recrystallization that produced Au − enriched Py1 − 2. Continuous fluid replenishment generated Au − rich Py2. Since Py2 − forming fluids were not fully consumed, Py3 − forming fluids added more Au, reaching supersaturation and precipitating native gold and calaverite within Py2 − Py3 intergrowths and fractures. Sustained fluid supply ultimately formed the Au − rich orebodies.
{"title":"In situ trace element and sulfur isotope characteristics of pyrite from the Dapingzhang Cu − Au polymetallic deposit: Insights into Au mineralization processes","authors":"Shanshan Ru , Guo Li , Chuandong Xue , Feng Li","doi":"10.1016/j.oregeorev.2026.107154","DOIUrl":"10.1016/j.oregeorev.2026.107154","url":null,"abstract":"<div><div>The Dapingzhang Cu − Au polymetallic deposit is a large volcanogenic massive sulfide (VMS) deposit formed during the Proto − Tethyan stage in western Yunnan Province, SW China, and exhibits a stratified distribution with upper massive orebodies (V1) and lower veinlet orebodies (V2). Au − rich orebodies predominantly occur within the massive orebodies near the 16<sup>#</sup> exploration line. This study investigates the microstructures, trace elemental, and sulfur isotopic compositions of pyrite, chalcopyrite, and sphalerite from the Au − rich orebodies at 1150 m and 1130 m levels to constrain the Au-bearing hydrothermal fluid sources, migration, and ore genesis. Four pyrite types were identified, representing three mineralization stages: (1) early-stage Py1 − 1 with sedimentary-formed strawberry − like textures; (2) late-stage Py1 − 2 formed through Py1 − 1 aggregation into irregular or euhedral crystals; and (3) Py2 (first-order zoning on Py1 − 2) and Py3 (second-order zoning on Py2). All Py1 − 2, Py2, and Py3 are hydrothermal in origin. Trace elemental composition reveals higher Sb concentrations in pyrite at the 1150 m level compared to those at the 1130 m level, with similar concentrating trends of Cu, Pb, Au, and Se. Evolutionary sequence analysis shows increasing Cu and Au concentrations but decreasing Co and Se concentrations in Py1 − 2, Py2, and Py3 across both the 1150 m and 1130 m levels. All pyrites are enriched in Au, Cu, Pb, Zn, and Sb but are depleted in Co, Ni, Tl, Se, Ti, and Sn. Sulfur isotope values (δ<sup>34</sup>S = − 2.63 to + 1.12‰) of pyrite, chalcopyrite, and sphalerite suggest a magmatic sulfur affinity. Gold mineralization is associated with E − W-trending ore-conducting faults. Au − rich fluids migrated upward through fractures, leaching Py1 − 1 to form inclusion textures and causing localized recrystallization that produced Au − enriched Py1 − 2. Continuous fluid replenishment generated Au − rich Py2. Since Py2 − forming fluids were not fully consumed, Py3 − forming fluids added more Au, reaching supersaturation and precipitating native gold and calaverite within Py2 − Py3 intergrowths and fractures. Sustained fluid supply ultimately formed the Au − rich orebodies.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"190 ","pages":"Article 107154"},"PeriodicalIF":3.6,"publicationDate":"2026-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107133
Jingbo Sun , Wen Chen , Kezhang Qin , Shuangfeng Zhao , Ze Shen , Bin Zhang , Wen Zhang
The Ke’eryin lithium ore field, located in the east of Songpan-Ganzi orogenic belt of Tibetan Plateau, is an important lithium-producing field hosting multiple pegmatite deposits in large to super-large scale. A more complete exhumation history of this ore field is required, and favorable prospecting locations need further identification. Here, we applied (U-Th)/He dating combined with a vertical profile sampling strategy to quantitatively constrain the exhumation process of the Ke’eryin lithium ore field. Zircon (U-Th)/He (ZHe) data and thermal history modeling reveal fast cooling during ∼28–24 Ma, linked to crustal shortening during the India-Eurasia collision. This phase removed ∼3.3 km of overburden, reducing burial depths from ∼5.3 km to ∼2 km. Age-elevation relationships of apatite (U-Th)/He (AHe) combined with thermal history modeling reveal rapid cooling at ∼15 Ma. This rapid cooling episode resulted from the regional uplift and exhumation, with amplification by river incision. The hanging wall (north) experienced greater denudation than the footwall (south), making the footwall a more favorable prospecting area. Combining the zircon and apatite (U-Th)/He data, we calculate a total erosion amount of approximately ∼5 km in the Ke’eryin lithium ore field since the Late Oligocene.
{"title":"(U-Th)/He thermochronology constraints on Cenozoic exhumation of Ke’eryin lithium ore field, eastern Tibet","authors":"Jingbo Sun , Wen Chen , Kezhang Qin , Shuangfeng Zhao , Ze Shen , Bin Zhang , Wen Zhang","doi":"10.1016/j.oregeorev.2026.107133","DOIUrl":"10.1016/j.oregeorev.2026.107133","url":null,"abstract":"<div><div>The Ke’eryin lithium ore field, located in the east of Songpan-Ganzi orogenic belt of Tibetan Plateau, is an important lithium-producing field hosting multiple pegmatite deposits in large to super-large scale. A more complete exhumation history of this ore field is required, and favorable prospecting locations need further identification. Here, we applied (U-Th)/He dating combined with a vertical profile sampling strategy to quantitatively constrain the exhumation process of the Ke’eryin lithium ore field. Zircon (U-Th)/He (ZHe) data and thermal history modeling reveal fast cooling during ∼28–24 Ma, linked to crustal shortening during the India-Eurasia collision. This phase removed ∼3.3 km of overburden, reducing burial depths from ∼5.3 km to ∼2 km. Age-elevation relationships of apatite (U-Th)/He (AHe) combined with thermal history modeling reveal rapid cooling at ∼15 Ma. This rapid cooling episode resulted from the regional uplift and exhumation, with amplification by river incision. The hanging wall (north) experienced greater denudation than the footwall (south), making the footwall a more favorable prospecting area. Combining the zircon and apatite (U-Th)/He data, we calculate a total erosion amount of approximately ∼5 km in the Ke’eryin lithium ore field since the Late Oligocene.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107133"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107127
Qingyan Tang , Zhuoming Li , Chi Zhao , Yan Zhang , Hailong Jin , Biao Chen , Yanjiang Liu , Tianyu Qin , Tengda Yang , Min Qiao , Xinrui Bai , Zeyu Ma
The presence of carbonate materials in the mantle source of carbonatites has long been debated. TIMA and Mg isotope are conducted to reveal the genesis of carbonatites and Bayan Obo Nb-REE-Fe deposit. The δ26Mg values of dolomite carbonatite dykes are lighter than those of the normal mantle, ranging from −0.83 ‰ to −0.43 ‰. The δ26Mg values show marked variation in both coarse-grained dolomite carbonatites (ranging from −0.71 ‰ to −0.03 ‰) and Nb-REE-Fe ores, with the latter exhibiting a broader isotopic range from −0.72 ‰ to +0.31 ‰. Fenite has a δ26Mg value of −0.19 ‰, while limestones display the lowest δ26Mg values overall, with a narrow range of −1.88 ‰ to −1.86 ‰. This study indicates that Bayan Obo carbonatites originated from the low-degree partial melting of carbonated peridotites. The ancient carbonate materials were introduced into the mantle source via decarbonation. Whole-rock δ26Mg values are controlled by multiple mineral phases rather than a single phase. The mantle source, magmatic differentiation processes and subsequent hydrothermal fluid metasomatism collectively influence the Mg isotope compositions in the Bayan Obo area. The δ26Mg values below the mantle value may result from minerals enriched in light Mg isotopes. Therefore, ancient carbonatites also involve the addition of carbonate materials. Element correlations suggest that acidic conditions favor the migration and enrichment of Nb and REE, whereas alkaline conditions promote the migration and enrichment of REE but are unfavourable for Nb migration.
{"title":"Mg isotopes and TIMA tracing the mantle source and mineralization process at Bayan Obo Nb-REE-Fe deposit, China","authors":"Qingyan Tang , Zhuoming Li , Chi Zhao , Yan Zhang , Hailong Jin , Biao Chen , Yanjiang Liu , Tianyu Qin , Tengda Yang , Min Qiao , Xinrui Bai , Zeyu Ma","doi":"10.1016/j.oregeorev.2026.107127","DOIUrl":"10.1016/j.oregeorev.2026.107127","url":null,"abstract":"<div><div>The presence of carbonate materials in the mantle source of carbonatites has long been debated. TIMA and Mg isotope are conducted to reveal the genesis of carbonatites and Bayan Obo Nb-REE-Fe deposit. The δ<sup>26</sup>Mg values of dolomite carbonatite dykes are lighter than those of the normal mantle, ranging from −0.83 ‰ to −0.43 ‰. The δ<sup>26</sup>Mg values show marked variation in both coarse-grained dolomite carbonatites (ranging from −0.71 ‰ to −0.03 ‰) and Nb-REE-Fe ores, with the latter exhibiting a broader isotopic range from −0.72 ‰ to +0.31 ‰. Fenite has a δ<sup>26</sup>Mg value of −0.19 ‰, while limestones display the lowest δ<sup>26</sup>Mg values overall, with a narrow range of −1.88 ‰ to −1.86 ‰. This study indicates that Bayan Obo carbonatites originated from the low-degree partial melting of carbonated peridotites. The ancient carbonate materials were introduced into the mantle source via decarbonation. Whole-rock δ<sup>26</sup>Mg values are controlled by multiple mineral phases rather than a single phase. The mantle source, magmatic differentiation processes and subsequent hydrothermal fluid metasomatism collectively influence the Mg isotope compositions in the Bayan Obo area. The δ<sup>26</sup>Mg values below the mantle value may result from minerals enriched in light Mg isotopes. Therefore, ancient carbonatites also involve the addition of carbonate materials. Element correlations suggest that acidic conditions favor the migration and enrichment of Nb and REE, whereas alkaline conditions promote the migration and enrichment of REE but are unfavourable for Nb migration.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107127"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107103
Sun Bin , Tian Peng , Yan Yongfeng , Liu Yi , Kong Zhigang , Yang Guangshu
{"title":"Corrigendum to “Skarn geochronology and genesis of the Wanlongshan Zn-Sn polymetallic deposit in southeast Yunnan: constraints from garnet and sphalerite composition, and in-situ S isotopes”. [Ore Geol. Rev. 185 (2025) 106776]","authors":"Sun Bin , Tian Peng , Yan Yongfeng , Liu Yi , Kong Zhigang , Yang Guangshu","doi":"10.1016/j.oregeorev.2026.107103","DOIUrl":"10.1016/j.oregeorev.2026.107103","url":null,"abstract":"","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107103"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107130
Xin Hu , Hui Rong , Shihu Kang , Jun Ning , Guolong Tang , Liangliang Zhang , Shusong Ma
Ankerite cements in the Hailijin uranium deposit of the southern Songliao Basin serve as an excellent carrier for uranium mineralization. This study aims to characterize the morphology, contents, fluid inclusions, and elemental-isotopic compositions of the ankerite cements within the uranium reservoirs, and then reveals genesis of the ankerite and its relationship with uranium mineralization. In red sandstone, the ankerite is predominantly euhedral granular with an average content of 0.92 %. In yellow sandstone, it occurs as euhedral to subhedral crystals (average content: 0.62 %). In gray-white barren sandstone, it is mainly colloidal or granular, with an average content of 0.97 %. In mineralized sandstone, the ankerite exists in colloidal or granular form and has the highest average content (1.61 %). In primary gray sandstone, it appears as euhedral to subhedral crystals (average content: 0.94 %). Fluid inclusions in the ankerite yield homogenization temperatures of 140–180 °C (Th) and salinities of 8–12 wt% NaCl equiv. Sc, V, U, Zn, and Y exhibit remarkable enrichment in the ankerite, while Li, Cu, Rb, Ga, Zr, Nb, Ba, and Hf display systematic depletion patterns. The rare earth elements of ankerite generally exhibit the characteristics of light rare earth element depletion and heavy rare earth element enrichment. Ce/La ranges from 1.3 to 2.645, with an average value of 1.816, and Eu anomaly value (δEu) fluctuates between 0.881 and 1.093, with an average of 1.014. 87Sr/86Sr values of the ankerite range from 0.70598 to 0.70779, with an average value of 0.70748. The study indicates that the ankerite likely forms in hydrothermal fluids associated with basic dike intrusion. As temperature decreases, the ankerite and uranium minerals sequentially precipitate from these hydrothermal fluids. This study reveals the mechanism of hydrothermal fluids participating in mineralization of sandstone-hosted uranium deposits.
{"title":"Genesis of ankerite and its relationship with uranium mineralization in the Hailijin uranium deposit, southern Songliao Basin, China","authors":"Xin Hu , Hui Rong , Shihu Kang , Jun Ning , Guolong Tang , Liangliang Zhang , Shusong Ma","doi":"10.1016/j.oregeorev.2026.107130","DOIUrl":"10.1016/j.oregeorev.2026.107130","url":null,"abstract":"<div><div>Ankerite cements in the Hailijin uranium deposit of the southern Songliao Basin serve as an excellent carrier for uranium mineralization. This study aims to characterize the morphology, contents, fluid inclusions, and elemental-isotopic compositions of the ankerite cements within the uranium reservoirs, and then reveals genesis of the ankerite and its relationship with uranium mineralization. In red sandstone, the ankerite is predominantly euhedral granular with an average content of 0.92 %. In yellow sandstone, it occurs as euhedral to subhedral crystals (average content: 0.62 %). In gray-white barren sandstone, it is mainly colloidal or granular, with an average content of 0.97 %. In mineralized sandstone, the ankerite exists in colloidal or granular form and has the highest average content (1.61 %). In primary gray sandstone, it appears as euhedral to subhedral crystals (average content: 0.94 %). Fluid inclusions in the ankerite yield homogenization temperatures of 140–180 °C (Th) and salinities of 8–12 wt% NaCl equiv. Sc, V, U, Zn, and Y exhibit remarkable enrichment in the ankerite, while Li, Cu, Rb, Ga, Zr, Nb, Ba, and Hf display systematic depletion patterns. The rare earth elements of ankerite generally exhibit the characteristics of light rare earth element depletion and heavy rare earth element enrichment. Ce/La ranges from 1.3 to 2.645, with an average value of 1.816, and Eu anomaly value (δEu) fluctuates between 0.881 and 1.093, with an average of 1.014. <sup>87</sup>Sr/<sup>86</sup>Sr values of the ankerite range from 0.70598 to 0.70779, with an average value of 0.70748. The study indicates that the ankerite likely forms in hydrothermal fluids associated with basic dike intrusion. As temperature decreases, the ankerite and uranium minerals sequentially precipitate from these hydrothermal fluids. This study reveals the mechanism of hydrothermal fluids participating in mineralization of sandstone-hosted uranium deposits.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107130"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107141
Xiangfa Song , Degao Zhai , Xiaolin Wang , Jinchao Wu , Zhi Zhang , Wei Chen , Zijun Qiu , Qingqing Zhao , Jiajun Liu
Located in the eastern segment of the Yarlung–Tsangpo suture zone (YTSZ), the Bangbu deposit formed during the subduction–collision evolution of the Himalayan–Tibetan orogen and constitutes a significant example of hydrothermal gold mineralization in this tectonic setting. Pyrite has commonly been employed to trace ore-forming processes in orogenic gold systems, but the role of coexisting sphalerite as an additional tracer mineral remains insufficiently investigated. This study presents a comprehensive geochemical characterization of sphalerite occurring with ore-stage pyrite in quartz–sulfide veins from the Bangbu deposit, and places these results in the context of a global dataset covering sphalerite from diverse mineralization environments. Compared with sphalerite from other deposit types, the Bangbu sphalerite is characterized by elevated Cd but depleted Ga, Mn and Sn. Both PLS-DA and its orthogonal variant (OPLS-DA) show that sphalerite from Bangbu represents a distinct geochemical cluster that is readily separable from typical magmatic–hydrothermal systems. Application of the GGIMFis geothermometer to the Bangbu sphalerite yields temperatures of 230–260 °C (peak at ∼250 °C), while the corresponding lgfS2 values of –14.5 to –12.4 point to intermediate- to low-sulfidation conditions. These parameters are consistent with medium to low temperature, low salinity, CO2-rich fluids and show no clear evidence for a significant magmatic or mantle-derived fluid component, and instead pointing to a predominantly metamorphic fluid origin. Coexisting sphalerite and pyrite display narrowly distributed δ34S values of ∼+2‰ and near-equilibrium isotopic fractionation, and their sulfur isotope compositions are lighter than those of sulfides in the surrounding low-grade metamorphic strata. This discrepancy with a simple metamorphic devolatilization model, together with the observation that δ34S values fall within the range expected for sulfur released by slab-derived fluids, supports a significant sub-crustal fluid contribution and indicates that a single metamorphic devolatilization model cannot fully explain the gold mineralization. Integrating constraints from trace element compositions, temperature estimates, sulfur fugacity and sulfur isotopes, this study proposes a two-stage genetic model for the Bangbu deposit, including subduction-related devolatilization pre-enrichment and metamorphic reactivation. The results demonstrate that ore-stage sphalerite provides independent constraints on the ore-forming conditions and fluid sources of orogenic gold deposits, and represents an important complement to traditional pyrite-based tracer systems.
{"title":"Orogenic gold mineralization constrained by sphalerite geochemistry: evidence from the Bangbu deposit, Tibet, SW China","authors":"Xiangfa Song , Degao Zhai , Xiaolin Wang , Jinchao Wu , Zhi Zhang , Wei Chen , Zijun Qiu , Qingqing Zhao , Jiajun Liu","doi":"10.1016/j.oregeorev.2026.107141","DOIUrl":"10.1016/j.oregeorev.2026.107141","url":null,"abstract":"<div><div>Located in the eastern segment of the Yarlung–Tsangpo suture zone (YTSZ), the Bangbu deposit formed during the subduction–collision evolution of the Himalayan–Tibetan orogen and constitutes a significant example of hydrothermal gold mineralization in this tectonic setting. Pyrite has commonly been employed to trace ore-forming processes in orogenic gold systems, but the role of coexisting sphalerite as an additional tracer mineral remains insufficiently investigated. This study presents a comprehensive geochemical characterization of sphalerite occurring with ore-stage pyrite in quartz–sulfide veins from the Bangbu deposit, and places these results in the context of a global dataset covering sphalerite from diverse mineralization environments. Compared with sphalerite from other deposit types, the Bangbu sphalerite is characterized by elevated Cd but depleted Ga, Mn and Sn. Both PLS-DA and its orthogonal variant (OPLS-DA) show that sphalerite from Bangbu represents a distinct geochemical cluster that is readily separable from typical magmatic–hydrothermal systems. Application of the GGIMFis geothermometer to the Bangbu sphalerite yields temperatures of 230–260 °C (peak at ∼250 °C), while the corresponding lg<em>f</em>S<sub>2</sub> values of –14.5 to –12.4 point to intermediate- to low-sulfidation conditions. These parameters are consistent with medium to low temperature, low salinity, CO<sub>2</sub>-rich fluids and show no clear evidence for a significant magmatic or mantle-derived fluid component, and instead pointing to a predominantly metamorphic fluid origin. Coexisting sphalerite and pyrite display narrowly distributed <em>δ</em><sup>34</sup>S values of ∼+2‰ and near-equilibrium isotopic fractionation, and their sulfur isotope compositions are lighter than those of sulfides in the surrounding low-grade metamorphic strata. This discrepancy with a simple metamorphic devolatilization model, together with the observation that <em>δ</em><sup>34</sup>S values fall within the range expected for sulfur released by slab-derived fluids, supports a significant sub-crustal fluid contribution and indicates that a single metamorphic devolatilization model cannot fully explain the gold mineralization. Integrating constraints from trace element compositions, temperature estimates, sulfur fugacity and sulfur isotopes, this study proposes a two-stage genetic model for the Bangbu deposit, including subduction-related devolatilization pre-enrichment and metamorphic reactivation. The results demonstrate that ore-stage sphalerite provides independent constraints on the ore-forming conditions and fluid sources of orogenic gold deposits, and represents an important complement to traditional pyrite-based tracer systems.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107141"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146079447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107152
Jinchao Wu , Degao Zhai , Zhi Zhang , Jiajun Liu , Jian-Feng Gao , Xiangfa Song , Zijun Qiu , Qingqing Zhao , Gang Zhao
The Jienagepu Au-Sb deposit, recently identified in the eastern Tethyan Himalayan Sequence (THS), southern Tibet, shows considerable resource potential in this Sb-Au metallogenic domain. Although numerous local Sb-Au ore bodies hosted in Mesozoic weakly metamorphosed slate have been identified and investigated, the sources of regional Sb and Au resources and the properties of the ore-forming fluids in this unique orogenic setting remain highly controversial. To address these issues, in situ trace element and sulfur isotope analyses were performed on pyrite from the gold-base metal sulfides mineralization stage (II) of the Jienagepu deposit. Trace element analyses indicate that pyrite contains high concentrations of Ni, Cu, As, and Sb, whereas the concentrations of Zn, Se, and Ag are relatively low. Except for minor Sb-(Ni/As)-bearing inclusions, most trace elements, including gold, are hosted within pyrite as solid solutions. The newly obtained in situ sulfur isotope data for pyrite (δ34S = 5.0‰-8.0‰; average = 6.2‰), in comparison with regional S isotopic reservoirs, suggest that the slate strata were the main sulfur source. In situ geochemical results for pyrite further indicate that the Jienagepu ore-forming fluids were mainly meteoric with a minor magmatic water, and were characterized by low temperature (<300 °C) and low salinity (<9 wt% NaCl equiv). Combined with previous studies, we propose that, in a Miocene post-collisional extensional setting, meteoric-dominated geothermal fluids, driven by heat from coeval felsic magmatism, circulated at shallow levels, leaching ore-forming elements from the slate strata and then migrating along N-S-trending faults, ultimately forming the giant Sb-Au resources of southern Tibet. This study provides important insights for understanding the Sb-Au enrichment in post-collisional settings and for guiding regional Sb-Au ore exploration.
{"title":"In situ geochemical investigations of pyrite constraining Au-Sb mineralization in the Jienagepu deposit, southern Tibet, China","authors":"Jinchao Wu , Degao Zhai , Zhi Zhang , Jiajun Liu , Jian-Feng Gao , Xiangfa Song , Zijun Qiu , Qingqing Zhao , Gang Zhao","doi":"10.1016/j.oregeorev.2026.107152","DOIUrl":"10.1016/j.oregeorev.2026.107152","url":null,"abstract":"<div><div>The Jienagepu Au-Sb deposit, recently identified in the eastern Tethyan Himalayan Sequence (THS), southern Tibet, shows considerable resource potential in this Sb-Au metallogenic domain. Although numerous local Sb-Au ore bodies hosted in Mesozoic weakly metamorphosed slate have been identified and investigated, the sources of regional Sb and Au resources and the properties of the ore-forming fluids in this unique orogenic setting remain highly controversial. To address these issues, <em>in situ</em> trace element and sulfur isotope analyses were performed on pyrite from the gold-base metal sulfides mineralization stage (II) of the Jienagepu deposit. Trace element analyses indicate that pyrite contains high concentrations of Ni, Cu, As, and Sb, whereas the concentrations of Zn, Se, and Ag are relatively low. Except for minor Sb-(Ni/As)-bearing inclusions, most trace elements, including gold, are hosted within pyrite as solid solutions. The newly obtained <em>in situ</em> sulfur isotope data for pyrite (δ<sup>34</sup>S = 5.0‰-8.0‰; average = 6.2‰), in comparison with regional S isotopic reservoirs, suggest that the slate strata were the main sulfur source. <em>In situ</em> geochemical results for pyrite further indicate that the Jienagepu ore-forming fluids were mainly meteoric with a minor magmatic water, and were characterized by low temperature (<300 °C) and low salinity (<9 wt% NaCl equiv). Combined with previous studies, we propose that, in a Miocene post-collisional extensional setting, meteoric-dominated geothermal fluids, driven by heat from coeval felsic magmatism, circulated at shallow levels, leaching ore-forming elements from the slate strata and then migrating along N-S-trending faults, ultimately forming the giant Sb-Au resources of southern Tibet. This study provides important insights for understanding the Sb-Au enrichment in post-collisional settings and for guiding regional Sb-Au ore exploration.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107152"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-02-01DOI: 10.1016/j.oregeorev.2026.107145
Qingxuan Wang , Shuo Wang , Zhengping Yan , Wenyuan Li , Yunhua Liu , Huali Guo , Jinhua Du , Yingxing Huang , Tianhong Gao , Zihe Chen
Highly fractionated intrusions plays a key role in the formation of numerous types of ore metal deposits. For example, many large-scale Au deposits are associated with highly fractionated intermediate–silicic intrusions. Since the introduction of Au deposit classification types such as intrusion-related, magmatic, and magmatic–hydrothermal Au deposits, an increasing number of studies have focused on the coupled relationships between magmatic processes (e.g., melt segregation, differentiation, and evolution) and Au mineralization. The magmatism not only provides the energy and ore-forming materials for Au mineralization, but also leads to significant Au enrichment by magmatic fractionation and evolution. Consequently, studies on magmatic fractionation-related mineralization should not be confined to ore types such as W–Sn and rare metals. This paper systematically reviews the nature of Au deposits genetically linked to highly fractionated magmas and discusses the key controls on anomalous Au enrichment during magmatic fractionation. The gold-mineralizing magmas are derived mainly from regions near the crust–mantle boundary. Metasomatic overprinting of the lithospheric mantle and enrichment of the lower crust by metallic elements, fluids, and volatiles from subducted slabs are preconditions for subsequent auriferous mineralization processes. The parental rocks of these Au deposits generally have a high O fugacity and are fractionated I-type or magnetite-series granites that have an affinity with the high-K calc-alkaline series, in which physicochemical parameters such as the O fugacity regulate the S speciation in the magmas and Au distribution. Furthermore, the timing of Au-bearing metallic sulfide saturation in the magmas and subsequent exsolution into the fluid phase is one of the critical controls on Au transportation into the shallow crust and its subsequent deposition in economically viable concentrations. Such Au deposits form mainly in transitional tectonic settings associated with slab subduction (e.g., slab rollback, break off) or during the transition from collisional to post-collisional tectonic settings. The physicochemical processes that govern melt segregation, differentiation, and Au enrichment from the magma source regions to final ore deposition have significant implications for understanding anomalous Au concentration mechanisms. The interrelationships among physicochemical parameters are the critical factor in understanding the coupling relationship between the melt-fluid evolution and Au mineralization, and therefore warrant further investigation.
{"title":"Review of the relationship between highly fractionated intrusions and gold mineralization","authors":"Qingxuan Wang , Shuo Wang , Zhengping Yan , Wenyuan Li , Yunhua Liu , Huali Guo , Jinhua Du , Yingxing Huang , Tianhong Gao , Zihe Chen","doi":"10.1016/j.oregeorev.2026.107145","DOIUrl":"10.1016/j.oregeorev.2026.107145","url":null,"abstract":"<div><div>Highly fractionated intrusions plays a key role in the formation of numerous types of ore metal deposits. For example, many large-scale Au deposits are associated with highly fractionated intermediate–silicic intrusions. Since the introduction of Au deposit classification types such as intrusion-related, magmatic, and magmatic–hydrothermal Au deposits, an increasing number of studies have focused on the coupled relationships between magmatic processes (e.g., melt segregation, differentiation, and evolution) and Au mineralization. The magmatism not only provides the energy and ore-forming materials for Au mineralization, but also leads to significant Au enrichment by magmatic fractionation and evolution. Consequently, studies on magmatic fractionation-related mineralization should not be confined to ore types such as W–Sn and rare metals. This paper systematically reviews the nature of Au deposits genetically linked to highly fractionated magmas and discusses the key controls on anomalous Au enrichment during magmatic fractionation. The gold-mineralizing magmas are derived mainly from regions near the crust–mantle boundary. Metasomatic overprinting of the lithospheric mantle and enrichment of the lower crust by metallic elements, fluids, and volatiles from subducted slabs are preconditions for subsequent auriferous mineralization processes. The parental rocks of these Au deposits generally have a high O fugacity and are fractionated I-type or magnetite-series granites that have an affinity with the high-K calc-alkaline series, in which physicochemical parameters such as the O fugacity regulate the S speciation in the magmas and Au distribution. Furthermore, the timing of Au-bearing metallic sulfide saturation in the magmas and subsequent exsolution into the fluid phase is one of the critical controls on Au transportation into the shallow crust and its subsequent deposition in economically viable concentrations. Such Au deposits form mainly in transitional tectonic settings associated with slab subduction (e.g., slab rollback, break off) or during the transition from collisional to post-collisional tectonic settings. The physicochemical processes that govern melt segregation, differentiation, and Au enrichment from the magma source regions to final ore deposition have significant implications for understanding anomalous Au concentration mechanisms. The interrelationships among physicochemical parameters are the critical factor in understanding the coupling relationship between the melt-fluid evolution and Au mineralization, and therefore warrant further investigation.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"189 ","pages":"Article 107145"},"PeriodicalIF":3.6,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}