Ore Geology Reviews最新文献

{"title":"Multi-stage granite and granitic pegmatites in the eastern North Qinling orogen: Petrogenesis, geodynamic setting, and metallogenic potential","authors":"Guochao Chen ,&nbsp;Xiaofei Zhang ,&nbsp;Xianzhi Pei ,&nbsp;Ruibao Li ,&nbsp;Zuochen Li ,&nbsp;Junqi Wei ,&nbsp;Rongzhen Zhang","doi":"10.1016/j.oregeorev.2025.106487","DOIUrl":"10.1016/j.oregeorev.2025.106487","url":null,"abstract":"<div><div>Numerous granitic pegmatite dikes intrude the Wuduoshan batholith in the eastern North Qinling orogen (NQ). However, the petrogenesis, interrelationships, and geodynamic setting of these granitoids and associated dikes remain poorly understood. This study investigates the Erlangchuan and Sikeshu plutons and their related dikes in the Qinling orogen, central China, through integrated petrographic, whole-rock geochemical, zircon U-Pb geochronological, and Lu-Hf isotopic analyses. Zircon U-Pb dating yielded crystallization ages of 430.8 ± 2.0 Ma for the Erlangchuan monzogranites, 415.2 ± 1.7 Ma for associated biotite granitic pegmatites, 416.9 ± 2.2 Ma for associated aplite dikes, and 403.6 ± 4.7 Ma for Sikeshu muscovite granitic pegmatites. All samples display geochemical characteristics consistent with a crustal origin, showing enrichment of large-ion lithophile elements (LILE; e.g., Rb, Th, Ba, and Cs) and depletion of high field strength elements (HFSE; e.g., Nb, Ta, and Ti). The granitic dikes exhibit higher SiO₂ contents compared to their respective host plutons: the K-rich Erlangchuan monzogranites and the Na-rich, two-mica Sikeshu granites. Zircon Lu-Hf isotopic data reveal higher ε_Hf(t) values for the Erlangchuan monzogranites (average = +2.6) compared to the associated biotite pegmatites (+2.0), aplites (+1.6), and the Sikeshu muscovite pegmatites (+0.9). The ε_Hf(t) values of both plutons and their dikes fall between those of the Qinling Group and juvenile mafic crust, suggesting derivation from a mixed source. Variations in ε_Hf(t) values likely reflect differing proportions of these two endmembers. The Erlangchuan monzogranites formed via partial melting of the lower crust, triggered by mafic magma underplating during Shangdan Ocean subduction. The Sikeshu two-mica granites, associated aplites, and biotite pegmatites likely formed during subsequent collision and slab break-off. Finally, the Sikeshu muscovite pegmatites may represent a later magmatic pulse related to post-collisional lithospheric delamination. Regionally, granitic pegmatites in the eastern NQ define three distinct age peaks at 437 Ma, 413 Ma, and 367 Ma. These pegmatites can be broadly classified into two series: (1) a rare metal-bearing series, predominantly located in the northern eastern NQ, enriched in Nb, Ta, Be, Rb, Li, and Cs, and characterized by negative ε_Hf(t) values indicative of a Qinling Group source; and (2) a U-bearing series, primarily found in the southern eastern NQ, positive or slightly negative ε_Hf(t) values, suggesting derivation from a mixed Qinling Group and juvenile crustal source.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"178 ","pages":"Article 106487"},"PeriodicalIF":3.2,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143289839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Formation of the Miocene Weixi Sb-polymetallic mineralization in the Sanjiang Region, SW China: Insights from fluid inclusions, S-He-Ar isotopes, and zircon U-Pb geochronology","authors":"Yue-Fu Liu ,&nbsp;Hua-Wen Qi ,&nbsp;Wen-Jie Lin ,&nbsp;Lin-Kun Qi","doi":"10.1016/j.oregeorev.2025.106486","DOIUrl":"10.1016/j.oregeorev.2025.106486","url":null,"abstract":"<div><div>The Weixi Sb-polymetallic orefield (&gt;0.2 Mt Sb) in the Sanjiang metallogenic belt (northwestern Yunnan, SW China), represents a distinct type of Sb-polymetallic mineralization. Here, we examine the ore-fluid properties, source, and metallogenic process by analyzing the fluid inclusions, S-He-Ar isotopes, and zircon U-Pb age of three representative deposits (Shangnuluo, Baiji, and Hagudi) in the orefield. Early pyrite-molybdenite mineralizing fluids in the Baiji deposit contain A-type (liquid H₂O), B-type (gaseous CO₂), C-type (H₂O-CO₂), and D-type (solid-bearing) inclusions, showing a CO₂-rich, high-salinity (30.6–36 wt% NaCleqv.) fluid at medium–high temperatures (177–442°C), with metal precipitation primarily driven by fluid boiling. In the late sphalerite-galena-zinckenite-stibnite-calcite-quartz stage (Baiji), A-, B-, and C-type inclusions indicate lower temperatures (186–276.6°C) and salinity (0.35–12.4 wt% NaCleqv.), where metal deposition is controlled by fluid mixing. The Hagudi ore fluids are of medium–low temperature (150–368°C) and salinity (3.2–21.2 wt% NaCleqv.), contain primarily A-type (with some B-type) inclusions, with cooling and mixing being the main ore-forming mechanism. The Shangnuluo ore fluids are of medium temperature and low salinity, contain mainly A-, B-, and C-type inclusions (NaCl-H₂O-CO₂ fluid system), with immiscibility driving the metal precipitation. These fluid characteristics resemble typical orogenic or magmatic-hydrothermal ore fluids rather than basin-type ore fluids. He-Ar isotopes suggest a primarily crustal fluid origin with minimal mantle contribution. In-situ sulfur isotopes (Shangnuluo: −13.04 to −2.90 ‰; Baiji: −1.60 to 6.65 ‰; Hagudi: −2.48 to − 1.54 ‰) imply a magmatic and Permian formation source at Shangnuluo, magmatic and Jurassic formation source at Baiji, and a primarily magmatic source at Hagudi. Zircon U-Pb dating places the formation of ore-hosting quartz porphyry at Hagudi in the Late Permian (252.7 ± 2.4 Ma). The quartz porphyry was formed before the Miocene mineralization event (∼13 Ma) and potentially provided ore-hosting space for the Miocene mineralization.</div><div>Integrating our new data with previous studies on regional tectonics and magmatism, we speculate that the Weixi Sb-polymetallic mineralization is closely linked to concealed Miocene crustal magmatism. Ore-forming fluids migrated along faults into various stratigraphic levels, and metal precipitation was triggered by fluid immiscibility, cooling, and dilution by formation or meteoric water.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"178 ","pages":"Article 106486"},"PeriodicalIF":3.2,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143422209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ore-forming process and ore genesis of the Wangu gold deposit in the Jiangnan orogenic Belt, South China: Constraints from pyrite textures, trace elements and in-situ sulfur isotopes composition","authors":"Minghui Chen ,&nbsp;Yongjun Shao ,&nbsp;Yongshun Li ,&nbsp;Zhongfa Liu ,&nbsp;Ke Chen ,&nbsp;Mingpeng He ,&nbsp;ZhaoHua Chen","doi":"10.1016/j.oregeorev.2025.106485","DOIUrl":"10.1016/j.oregeorev.2025.106485","url":null,"abstract":"&lt;div&gt;&lt;div&gt;The Jiangnan Orogenic Belt is an Au–Sb–W polymetallic metallogenic belt located between the Yangtze Block and Cathaysian Block, with a total proven gold resource exceeding 970 tons (t). The Wangu gold deposit (85 t Au @ 6.8 g/t) is one of the most representative gold deposits in northeastern Hunan Province, which is located in the central of the Jiangnan Orogenic Belt. Similar to many gold deposits in this region, multi-stage tectonic-magmatic-thermal events resulted in a complicated and confusing metallogenic process and genesis. Six pyrite types (Py-1 to Py-6) from five mineralization stages (Stage Ⅰ to Ⅴ) were systematically classified through detailed field investigation and sample observation in the Wangu gold deposit. Coarse-grained pyrite (Py-1) disseminated in slate has more dissolution holes in its core and a relatively homogeneous edge; milky white quartz veins crosscut slate, with a small amount of medium to fine grained pyrite (Py-2) disseminated in coarse-grained quartz; quartz-scheelite veins crosscut milky white quartz, but no other sulfides; medium- to coarse-grained pyrite (Py-3a) disseminated in altered slate far from the auriferous quartz veins is replaced by arsenopyrite, while the medium-grained pyrite (Py-3b) and arsenopyrite near the auriferous quartz veins are replaced by chalcopyrite, sphalerite, and galena; medium- to fine-grained pyrite (Py-4), arsenopyrite, and quartz-sericite veins crosscut quartz-scheelite veins; fine-grained quartz-pyrite (Py-5) veins crosscut quartz and sericite, typically having a granularity of less than 30 μm; calcite, quartz and pyrite (Py-6) veins crosscut quartz, muscovite and chlorite. The Au and As contents of Py-1, Py-2 and Py-6 are much lower than those of Py-3 (a, b), Py-4, and Py-5, and Au mineralization mainly occurs in altered slate and quartz-sulfide veins. Almost all types of pyrites have a lower Co/Ni ratio (&lt;1.0) and a higher As/Sb ratio (&gt;20), and are closely related to quartz, sericite, chlorite, calcite, and other hydrothermal minerals, indicating that they are of mainly hydrothermal origin. The presence of a large number of gold-bearing sulfides in altered slate indicate that wall-rock sulfidation and fluid boiling are the main precipitation mechanisms of Au in the Wangu goldfield. The δ&lt;sup&gt;34&lt;/sup&gt;S values of Py-1 (–11.33 to –10.42 ‰), Py-3 (3a: –9.68 to –6.98 ‰; 3b: –10.14 to –8.48 ‰) and Py-4 (–11.48 to –6.75 ‰) are similar, indicating that their sulfur may have been derived from metamorphic sedimentary strata (similar to the Lengjiaxi Group), and the relatively high δ&lt;sup&gt;34&lt;/sup&gt;S values (–5.69 to –2.66 ‰) of Py-2 may imply that its sulfur is predominantly from the deep ore-causative magmas (or magmatic sulfur involved). However, the lowest δ&lt;sup&gt;34&lt;/sup&gt;S values (–38.49 to –37.53 ‰) of Py-6 may reflect the reduction of metamorphic sulfur by bacteria. Py-1 and Py-2 (Au-poor and As-poor) have different sulfur sources, while Py-3 (a, b), Py-4, and Py-5 (Au-","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"178 ","pages":"Article 106485"},"PeriodicalIF":3.2,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143387215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Failed genesis of a Fe-skarn deposit caused by redox states of intrusion and wall rocks (Torre di Rio, Island of Elba, Italy)","authors":"Paolo S. Garofalo ,&nbsp;Daniele Redi ,&nbsp;Nikita Malafeevskiy ,&nbsp;Gunnar Schwarz ,&nbsp;Christoph Neff ,&nbsp;Peter Keresztes Schmidt ,&nbsp;Detlef Günther","doi":"10.1016/j.oregeorev.2025.106446","DOIUrl":"10.1016/j.oregeorev.2025.106446","url":null,"abstract":"&lt;div&gt;&lt;div&gt;The Torre di Rio skarn (Island of Elba, Italy) is a pyroxene-ilvaite-epidote skarn that hosts a Fe-oxide mineralization and is the type locality of the mineral &lt;em&gt;ilvaite&lt;/em&gt;. In contrast with other Fe deposits of the island, it belongs to a group of subeconomic skarns. We combine surface mapping, petrographic data, scanning electron microscope and electron probe microanalyses, fluid inclusion microthermometry, elemental imaging by Laser Ablation-Inductively Coupled Plasma - Time of Flight Mass Spectrometry (LA-ICP-TOFMS), and fluid-mineral equilibria to compare the genesis of this skarn with that of typical economic skarns.&lt;/div&gt;&lt;div&gt;Fieldwork shows that Torre di Rio consist of ilvaite-, ilvaite-pyroxene, and pyroxene-epidote zones. The epidote-rich zone is in contact with the wall rocks, i.e., a sequence of pelites, marls, marbles, and other sedimentary lithologies. The 6.53–5.9 Ma Porto Azzurro monzogranite is the reduced (ilmenite-bearing) causative intrusion of the skarn, which induced contact metamorphism in the wall rocks at 6.7–6.2 Ma. Torre di Rio formed within the biotite-white mica-chlorite metamorphic zone, a few hundred meters from the contact with Porto Azzurro.&lt;/div&gt;&lt;div&gt;Within the skarn, ilvaite and pyroxenes are both euhedral and arranged in rosettes and spheroids. Ilvaite has a consistent chemical composition with a significant Mn enrichment close to the wall rocks, and pyroxene is hedenbergitic. The epidote is euhedral and occurs as epidote s.s. and allanite-(Ce). Late phases are albite, annite, phengite, chlorite, quartz, calcite, and chalcedony. Magnetite and hematite form spheroid textures or are finely mixed. Euhedral pyrrhotite and pyrite host native Bi and Pb.&lt;/div&gt;&lt;div&gt;Seventeen calcite- and quartz-hosted fluid inclusion assemblages from the ilvaite skarn zones are associated with the magnetite and hematite aggregates. At room temperature, all assemblages are two-phase (L-V). Fourteen of them show constant phase proportions and three show variable proportions. The assemblages with constant phase proportions have salinities between 0.8 and 17.0 mass% NaCleq and homogenize by bubble disappearance between c. 150 and 300 °C. The assemblages with variable phase proportions homogenize by bubble and liquid disappearance between 280 and 330 °C.&lt;/div&gt;&lt;div&gt;Element imaging by LA-ICP-TOFMS of ilvaite and quartz from skarn spheroids shows that several lithophile (e.g., Al, Mg) and siderophile (e.g., As, Ge, Ga, In, Sb) trace elements occur at concentrations between c. 20 μg/g and 1 wt%.&lt;/div&gt;&lt;div&gt;We interpret our dataset as a product of a shallow skarn that formed under extremely reducing conditions, which were controlled by the redox nature of both Porto Azzurro and wall rocks. At these conditions, supersaturation of pyroxenes and ilvaite within the skarn was achieved as a result of phase separation, cooling, and mixing of batches of heterogeneous and homogeneous ore fluids at about 350–150 °C. A Fe-skarn deposit failed ","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106446"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Petrogenesis of the Dapingtianshan intrusive complex, South China: Geochemistry, zircon U-Pb geochronology, Sr-Nd-Hf-O isotopes, and implications for geodynamic setting and mineralization","authors":"Gang Chen ,&nbsp;M. Santosh ,&nbsp;Changhui Ke ,&nbsp;Maohong Chen ,&nbsp;Rui Ge","doi":"10.1016/j.oregeorev.2025.106449","DOIUrl":"10.1016/j.oregeorev.2025.106449","url":null,"abstract":"<div><div>The petrogenesis, tectonic setting and associated mineralization of magmatic suites associated with the subduction of the Paleo-Pacific plate have been topics of considerable debate. Hence, we explore the Dapingtianshan intrusive complex in South China, a composite intrusion with granodiorite in the margin and monzonite in the core. Geochemical features indicate typical I-type and high-K calc-alkaline characteristics, including abundant mafic microgranular enclaves (MMEs). Zircon U–Pb ages of 96.9 ± 0.3 Ma and 96.2 ± 2.9 Ma for the monzonite and MMEs suggest coeval magmatism. Biotite from both exhibits similar compositions, crystallizing at 700–750 °C. The monzonite and MMEs are metaluminous (A/CNK = 0.68–1.05), with trace element patterns showing enrichments in Rb, U, and Nd and depletions in Ba, Nb, Sr, P, and Ti. Chondrite-normalized REE distribution patterns reveal LREE enrichment and negative Eu anomalies. Zircon analyses show monzonite εHf(t) values of −2.4 to 0.6 and δ¹⁸O values of 5.6 to 8.6. MMEs exhibit εHf(t) values of −3.0 to 3.6. Sr-Nd isotopes suggest isotopic equilibrium during magma mixing, with (87Sr/86Sr)i of 0.70831 to 0.71426 and εNd(t) of −5.6 to −4.6. Findings suggest magma involvement of partial melts from the Mesoproterozoic metamorphic basement and enriched lithospheric mantle metasomatized by sediment-related melts linked to the subduction of the Pacific plate. Combining these results, we propose that the Dapingtianshan complex potentially hosts magmatic-hydrothermal Au–Ag–Cu–Pb–Zn metallogenic systems. The study hints at the extension of the Cu–Au metallogenic belt from the Dayaoshan area to the Qin-Hang metallogenic belt and South China.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106449"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pyrite geochemistry for deposit type prediction and exploration in the Golden Triangle, northwest British Columbia, Canada","authors":"Christopher J.M. Lawley ,&nbsp;Duane C. Petts ,&nbsp;Well-Shen Lee ,&nbsp;Stefanie Brueckner","doi":"10.1016/j.oregeorev.2025.106447","DOIUrl":"10.1016/j.oregeorev.2025.106447","url":null,"abstract":"<div><div>Mineral exploration in remote mountain belts represents an exceptional challenge due to high operational costs, limited accessibility, and complex geology. New tools are urgently needed to improve discovery rates in these types of highly prospective but challenging mineral exploration frontiers. Herein we apply deep learning to predict deposit types in a rugged and remote part of northwest British Columbia (Canada) based on laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis of pyrite to address that knowledge gap. The combined pyrite dataset represents four mineral deposit types at various stages of development, including porphyry copper-gold (i.e., Galore Creek, Copper Canyon, Kerr, Mitchell, Sulphurets, Iron Cap), epithermal gold-silver (i.e., Brucejack), magmatic nickel-copper (i.e., E&amp;L), and volcanogenic massive sulphide copper-lead-zinc (i.e., A6). Trace element mapping, spot analysis, and quantitative mineralogy are applied to characterize the petrogenetic context and composition of each pyrite sample. Geochemical data were first pre-processed with principal component analysis and autoencoders to extract new features from the training data. The pre-processed pyrite data were then combined to train a series of feed-forward artificial neural networks to predict deposit types. The preferred deep learning classification model yields an overall accuracy of 99% for a subset of pyrite analyses that were not included in the training process. We then apply that classifier to show that hydrothermally altered rocks from early-stage mineral exploration projects (i.e., Dok and Yeti) are most likely related to porphyry copper-gold mineralization based on the composition of pyrite. Statistical analysis of the model results further demonstrates that pyrite morphology, texture, grain size, and paragenesis are important predictors of deposit type when combined with trace element concentrations and the new latent variables identified by the preferred autoencoder. We suggest that the pyrite library and modelling methodology can be used to support early-stage mineral targeting in remote exploration frontiers that are prospective for a range of deposit types.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106447"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quartz geochemical constraints on the origin of stratabound deposits, Eastern China: Insights from the Xinqiao deposit","authors":"Shuling Song ,&nbsp;Yu Zhang ,&nbsp;Ke Chen ,&nbsp;Hongjie Shen ,&nbsp;Hongtao Zhao ,&nbsp;Lianjie Zhao","doi":"10.1016/j.oregeorev.2025.106474","DOIUrl":"10.1016/j.oregeorev.2025.106474","url":null,"abstract":"<div><div>Stratabound deposits with origin-undetermined footwall quartz-pyrite stockwork mineralization in the Middle-Lower Yangtze River Valley metallogenic belt (Eastern China) have uncertain metallogenic models. The Xinqiao deposit, a notable example in the Tongling ore district, provides an ideal case for studying the footwall stockwork mineralization to elucidate the origin of the stratiform mineralization. Cathodoluminescent imaging reveals three generations of quartz within the Xinqiao stockwork mineralization: homogeneous quartz (Qz1), oscillatory-zoned quartz (Qz2) coexisting with pyrite and enclosing Qz1, and weakly oscillatory-zoned quartz (Qz3) replacing Qz2. Quartz trace elements geochemistry (high Al (65.1–2849 ppm) and Ti (3.10–90.9 ppm), low Mn (0.980–20.0 ppm), As (1.56–10.2 ppm), and Sb (0.123–5.21 ppm)), combined with quartz-pyrite assemblage, suggests a magmatic-hydrothermal origin for the stockwork mineralization linked to the Early Cretaceous Jitou stock. Variations in Ti, Ge/Ti, and Al contents across three quartz generations indicate a temperature increase from Qz1 to Qz2 (&gt;400 ℃), followed by a decrease (&lt;350 ℃) during Qz3 formation, accompanied by a continuous pH decline. The injection of high-temperature magmatic-hydrothermal fluid would trigger the rapid crystallization of Qz1 with high trace elements (e.g., Fe, Cu, Zn, and Pb) during initial infiltration and hydraulic fracturing. A subsequent fluid pulse with minor meteoric water precipitate pyrite and Qz2, while meteoric water dominance during a waning magmatic-hydrothermal system led to Qz3 formation. These findings highlight the utility of quartz textures and trace element geochemistry in reconstructing the mineralization history and providing insights into the ore genesis in stratabound deposits within the Middle-Lower Yangtze River Valley metallogenic belt and similar metallogenic settings globally.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106474"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Lengshuikeng porphyry type Ag-Pb-Zn-Cd deposit: Insights from magmatism-mineralization timing sequence, chemical composition and in-situ Pb isotope of sulfide","authors":"Lifei Yang ,&nbsp;Zherong Liu ,&nbsp;Zenghua Li ,&nbsp;Yongpeng Ouyang ,&nbsp;Qi Chen ,&nbsp;Bin Du ,&nbsp;Rubin Zhang ,&nbsp;Huijuan Zhang ,&nbsp;Chaowei Luo ,&nbsp;Jin Guo","doi":"10.1016/j.oregeorev.2025.106460","DOIUrl":"10.1016/j.oregeorev.2025.106460","url":null,"abstract":"<div><div>The Lengshuikeng deposit is a significant Ag-Pb-Zn-Cd deposits in the Gan-Hang Tectonic Belt (GHTB). Understanding its genesis is crucial for revealing the relationship between the tectonic evolution and the mineralization in this region. However, the metallogenesis of the Lengshuikeng deposit has remained unclear. To address this issue, a systematic analysis of chronological data, mineralogy, lithology, chemistry of sphalerite, and in-situ Pb isotope of the sulfides from the Lengshuikeng deposit are conducted to explore the relationship between magmatism and mineralization, metal sources, and ore-forming feature. The magmatism consists of two major stages: the Late Jurassic (Daguding Formation and a large scale of granite porphyry) and the Early Cretaceous (E’huling Formation and minor acid dyke). The mineralization age is restricted near 155 Ma, which is in keeping with the granite porphyry (158.0 ± 1.0–154.3 ± 3.0 Ma). The sulfides in the major stage (Gn-Sp(−Aca)-Py) (²⁰⁸Pb/²⁰⁴Pb: 38.07–38.44, ²⁰⁷Pb/²⁰⁴Pb: 15.48–15.62, ²⁰⁶Pb/²⁰⁴Pb: 17.68–17.90, ²³⁸U/²⁰⁴Pb (μ): 9.32–9.58, ²³²U/²⁰⁴Pb (ω): 38.06–40.16) exhibit consistent Pb isotopes with most of the granite porphyry and minor crystal tuff, which indicates that the metals primarily came from the granite porphyry. The crystal temperature of sphalerite is focused on 300–350°C. In consideration of C, H, and O isotopes in previous works, the hydrothermal fluid was primarily derived from the granite porphyry at a high temperature stage. Combined with the trace elements of sphalerite (relatively high Cu, Fe, In, Cd, low Ge and Mn) and the genesis diagrams (based on In, Ga, Ge, Fe, Cd, and Mn), this deposit is classified as a porphyry type deposit. Geochemical data, Nd isotopes in previous works and in-situ Pb isotopes (△β-△γ; V₁-V₂) from this research suggest that the granite porphyry and crystal tuff mainly emplaced by partial melting of the Neoproterozoic basement in compressive setting at the GHTB, resulting from the subduction of the Pacific Plate to the South China Craton. A comprehensive metallogenic model is defined, involving the tectonic setting, the genesis of granite porphyry, ore-controlling factors, and the mineralization process.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106460"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reply to Comment on “Baddeleyite U-Pb age and Hf isotopes, and constraints on genesis of the Panzhihua carbonatite in SW China” by Arndt, Ganino and Li","authors":"Shengwei Wang ,&nbsp;Xiaoming Sun ,&nbsp;Yanguang Li ,&nbsp;Li Xu ,&nbsp;Yu Fu ,&nbsp;Cong Feng ,&nbsp;Guodong Xu ,&nbsp;Zhizhong Hu ,&nbsp;Guotao Ma ,&nbsp;Shenglin Lu","doi":"10.1016/j.oregeorev.2024.106428","DOIUrl":"10.1016/j.oregeorev.2024.106428","url":null,"abstract":"<div><div>The calcareous rocks adjacent to the Panzhihua intrusion were considered as carbonatite rather than marbles/skarns based on detailed field mapping and profile survey. <span><span>Arndt et al. (2023)</span></span> presented data and figures to compare the difference of trace elements of carbonatite between Panzhihua (they called “dolomite” or “marble”) and other areas in the world and maintained their genesis interpretation. However, carbonatite and carbonate can’t be well distinguished by the trace elements and Hf isotope, because that only approximately 20 % occurrences of global carbonatites contain high contents of rare earth elements. The mineral composition, major element, Ni (avg. 1011.91 ppm), Cr (avg. 1762.73 ppm), and ∑PGE (avg. 12.95 ppm) contents of the dark ultramafic enclaves hosted in the white calcareous rocks indicate that they are mantle-derived xenoliths rather than dolerite (or gabbro and diabase) or metamorphosed peridotite. The large number of mantle xenoliths also implies that their surrounding rock is more likely to be mantle-derived magmatic rock (i.e. carbonatite) rather than skarn. Furthermore, from melanocratic xenolith core and leucocratic surrounding carbonatite to middle zebra rocks, only physical rather than chemical change (i.e. contact metamorphism) happened due to without obvious mineral composition variation.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106428"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143148342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The origin of lithium in hydrothermally overprinted Li-rich strata in the Mesoproterozoic Wumishan Formation: Insights from radiogenic and stable isotopes","authors":"Fei Xu ,&nbsp;Hanjie Wen ,&nbsp;Hefan Liu ,&nbsp;Ni Tao ,&nbsp;Yu Chen ,&nbsp;Jianghao Yan ,&nbsp;Baoqiang Zhao","doi":"10.1016/j.oregeorev.2025.106448","DOIUrl":"10.1016/j.oregeorev.2025.106448","url":null,"abstract":"<div><div>Significant lithium (Li) enrichment has been observed in specific strata of the Mesoproterozoic Wumishan Formation in North China, yet the mechanisms and origins of this enrichment remain contentious. Our previous mineralogical microscopic studies suggested that post-depositional hydrothermal fluids are crucial for Li enrichment; however, a lack of macroscale geological evidence, such as metasomatic textures, necessitating further isotopic investigation. This study compares the geochemical characteristics of Li-rich and Li-poor samples, utilizing Sr-Nd-Pb and Li isotopes, along with major and trace elements, to elucidate the enrichment mechanisms and sources of Li. Nd isotopic data reveal that the primary sedimentary sources of the Wumishan Formation strata are predominantly felsic components (ε_Nd(0): –15.64 to –24.83), with an contributions from basic weathering products (ε_Nd(t): –8.13 to 2.63). However, the Li-rich samples exhibit anomalously high enrichments of Sr (⁸⁷Sr/⁸⁶Sr: 0.7340–0.7844) and Pb isotopes (²⁰⁶Pb/²⁰⁴Pb: 18.939–32.520; ²⁰⁷Pb/²⁰⁴Pb: 15.822–17.087; ²⁰⁸Pb/²⁰⁴Pb: 38.311–49.381), along with homogeneous positive δ⁷Li values (+5.59 ‰ to + 6.93 ‰). The pronounced enrichment of radiogenic Sr and Pb isotopes, coupled with the absence of Li isotopic fractionation in clay minerals, strongly support the hypothesis that Li enrichment is associated with post-depositional hydrothermal alteration. Additionally, positive correlations between Li and trace elements (e.g., F and Rb), further reinforce this association rather than suggesting a link to chemical weathering. High ⁸⁷Sr/⁸⁶Sr and ²⁰⁸Pb/²⁰⁴Pb ratios, along with positive δ⁷Li values, imply that Li likely originates from the leaching of surrounding rocks. Conversely, differences in Sr, Nd, Pb, and Li isotopes between diorite and diabase confirm minimal contribution from magmatic sources. This study provides new insights into the genesis of Li-rich strata in the Wumishan Formation, further supporting our previous mineralogical evidence and offering significant geological implications for their exploration and exploitation.</div></div>","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"177 ","pages":"Article 106448"},"PeriodicalIF":3.2,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143149624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}