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SWIR spectroscopy and mineral chemistry of Li-bearing micas in NW Jiangxi: Implications for the genesis and exploration of granite-related Li deposits 赣西北含锂云母的SWIR光谱及矿物化学特征:对花岗岩相关锂矿床成因及找矿意义
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107086
Yan Zhou , Jiandong Sun , Longming Li , Feipeng Fan , Guangfu Xing , Liancun Xiu , Weimin Guo , Kai Yang , Haili Li , Xuehui Zhang
The granite-related Li deposit has emerged as a significant source of lithium metal globally, thanks to advancements in the metallurgical process of Li-bearing micas. The total proven Li2O reserve of granite-type in the Northwest Jiangxi of China is over 9.2 Mt. To gain deeper insights into the evolution, enrichment mechanisms, and exploration indicators of Li-rich micas, short wavelength infrared (SWIR) spectroscopy, EPMA, and LA-ICP-MS analyses were conducted at the Dagang Li deposit, the Yashan Li-Nb-Ta deposit, and the Ganfang prospecting area. Obvious zoning textures were observed in the white mica of Dagang and Ganfang, with a compositional shift from magmatic Li-Fe mica and zinnwaldite in the core to post-magmatic hydrothermal Li-Fe mica at the edge. Meanwhile, Yashan’s white micas show core-rim textures, with the core dominated by magmatic lepidolite with minor altered Li-Fe mica on the rim. The Li, Si, Rb, and F contents of all white micas show similar varied trends, indicating comparable geochemical behaviors, with Li showing a positive linear relationship with Si. The substitution of Li for Al and Fe in the octahedral site played a crucial role in the Li supernormal enrichment during the granitic fractionation and evolution. However, post-magmatic hydrothermal alteration can potentially decrease the Li grade. Notably, the Yashan granite exhibits a higher degree of evolution compared to the Dagang and Ganfang granites. The coupling of the SWIR parameters with the chemical composition of Li-rich micas holds the potential for establishing exploration indicators for Li. Specifically, the Li-rich mica exhibits distinctive absorption at 550 and 960 nm, along with a lower Al-OH absorption peak position (Pos2200) than common muscovite. The absorption depth at 960 nm can be used to assess Li enrichment and identify lepidolite, while the Pos2200 value can reflect the substitution relationship between Li and Al.
由于含锂云母的冶金工艺的进步,与花岗岩相关的锂矿床已成为全球锂金属的重要来源。为深入了解富锂云母的演化、富集机制和找矿指标,对赣西地区大港李矿、丫山Li- nb - ta矿和赣方找矿区进行了波长红外光谱、EPMA和LA-ICP-MS等分析。大港和甘方白色云母具有明显的分带结构,其组成由岩心的岩浆期锂铁云母和锌walite向边缘岩浆期后热液期锂铁云母转变。崖山白色云母呈核-缘结构,岩心以岩浆云母为主,边缘有少量蚀变的Li-Fe云母。所有白色云母中Li、Si、Rb和F的含量变化趋势相似,具有相似的地球化学行为,Li与Si呈正线性关系。在花岗岩分馏演化过程中,八面体位置上Li取代Al和Fe对Li的超常富集起着至关重要的作用。岩浆期后热液蚀变可能降低锂品位。值得注意的是,丫山花岗岩的演化程度高于大港和甘方花岗岩。SWIR参数与富Li云母化学组成的耦合,为建立Li的找矿指标提供了可能。具体来说,富锂云母在550和960 nm处表现出独特的吸收,并且比普通白云母的Al-OH吸收峰位置(Pos2200)更低。960 nm处的吸收深度可用于评价Li富集程度和鉴定锂云母,Pos2200值可反映Li和Al之间的取代关系。
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引用次数: 0
Genesis of the Paleoproterozoic Heiyuting Fe deposit in the Jiao-Liao-Ji Belt, North China Craton: Constraints from geochronology and geochemistry 华北克拉通胶辽基带古元古代黑玉亭铁矿成因:地球化学和年代学的约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2026.107107
Xiao-Hui Wang , Yu-Bo Ma , Xiu-Ling Zhao , Li-Xing Li , Hou-Min Li , Yi Wang , Yang Dai , Xuan Wu , Xiao-Yang Fan , Xi-Long Liu
Paleoproterozoic metamorphic rock series are widely distributed and hosts several iron deposits. The Heiyuting iron (Fe) deposit is hosted by typical Paleoproterozoic leptite of the Li’eryu Formation and represents a key example for constraining the mineralization process of Paleoproterozoic iron deposits within the Liaohe Group. This type of deposit has great exploration potential, but the precise timing of iron mineralization, the sources of ore-forming materials, and iron mineralization processes remain unclear. We conducted zircon and monazite U-Pb geochronology together with monazite electron probe microanalysis (EPMA) to constrain iron mineralization. Zircon cores from the migmatitic granite yield an age of 2174 ± 23 Ma, representing protolith formation, whereas the rims yield 1892 ± 14 Ma, consistent with ∼ 1900 Ma granulite-facies metamorphism. Monazite grains associated with magnetite yielded an age of 1848 ± 5 Ma, constraining Fe mineralization and coinciding with regional partial melting (1870–1840 Ma). Monazites observed under back-scattered electron (BSE) imaging show embayed structures and concentric coronas composed of apatite, allanite, and epidote. Based on the major-, trace-, and REE-element compositions of monazite, a metamorphic-hydrothermal origin is suggested. We propose that the apatite-allanite-epidote coronas developed on early-formed monazite through disequilibrium reactions with F-Ca-Fe-Si-Al-rich fluids during the retrograde metamorphic stage. The Li’eryu Formation and the 2.2–2.1 Ga magmatism provided the primary sources of iron. The iron was subsequently concentrated by hydrothermal activity during late metamorphism-anatexis at ∼ 1850 Ma. Our results refine the age, source, and mechanisms of iron mineralization in the Heiyuting Fe deposit, provide geochronological and geochemical constraints for similar deposits, and highlight the role of regional metamorphism-anatexis in polymetallic enrichment.
古元古代变质岩系分布广泛,拥有多处铁矿床。黑玉亭铁矿为典型的李尔玉组古元古代轻铁矿赋存,是制约辽河群古元古代铁矿成矿过程的重要例证。该类型矿床具有较大的找矿潜力,但其成矿时间、成矿物质来源及成矿过程尚不明确。利用锆石和独居石U-Pb年代学和独居石电子探针微量分析(EPMA)对铁矿进行了约束。混染花岗岩的锆石岩心年龄为2174±23 Ma,代表原岩形成,而边缘年龄为1892±14 Ma,符合~ 1900 Ma麻粒岩相变质作用。与磁铁矿相关的独居石颗粒的年龄为1848±5 Ma,限制了铁的成矿作用,与区域部分熔融(1870-1840 Ma)相吻合。在背散射电子(BSE)成像下观察到的独居石显示出由磷灰石、allanite和绿帘石组成的椭圆形结构和同心日冕。单独居石的主量、微量和ree元素组成表明其成因为变质热液。我们认为,早期独居石与富f - ca - fe - si -al流体在逆变质阶段发生不平衡反应,形成磷灰石-allanite-绿帘石冕状。黎洱峪组和2.2 ~ 2.1 Ga岩浆活动是铁的主要来源。铁随后在~ 1850 Ma的晚变质-深熔过程中被热液活动浓缩。研究结果细化了黑玉亭铁矿的成矿年龄、成矿来源和成矿机制,为类似矿床提供了年代学和地球化学约束条件,并突出了区域变质-深熔作用在多金属富集中的作用。
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引用次数: 0
Unveiling late cretaceous Sn mineralization in the southern Baoshan Block, SW China: evidence from U–Pb dating and trace element analysis of cassiterite in the Dalong deposit 揭示宝山地块南部晚白垩世锡矿化:来自大龙矿床锡石U-Pb定年和微量元素分析的证据
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107067
Chuanyu Zhang , Meng Yang , Jianze Sha , Wanting Li , Haijun Yu , Shusheng Yang , Yongyan Lu
The Baoshan Block is considered an integral part of the northern continuation of the world-class Southeast Asian Sn Belt. Its exceptional metallogenic geological settings make it a prime focus for Sn prospecting and exploration. In recent years, several Sn deposits have been successively discovered in the northern Baoshan Block, with formation ages clustering around 77–76 Ma, consistent with the metallogenic peak (∼80 Ma) of the Southeast Asian Sn Belt. However, despite its intermediary position, owing to the lack of outcrops of Late Cretaceous granites, Sn deposits in the southern Baoshan block remain unexplored. The scarcity of reliable geochronological data in this area severely constrains genetic models for mineralization and hinders effective exploration planning. This study presents the first high-precision cassiterite U-Pb ages (77.0 ± 1.4 Ma and 78.6 ± 4.2 Ma) for the newly discovered Dalong Sn deposit in the southern Baoshan Block, which was previously attributed to Triassic magmatism. Cassiterite from the Dalong deposit is enriched in Ti, W, and Fe, but depleted in Nb, Ta, Zr, and Mn, with high Nb/Ta ratios (3.16–545, with an average of 7.26). These geochemical signatures, combined with deposit geological characteristics, support a model in which the Dalong Sn deposit is a hydrothermal vein system sourced from Late Cretaceous concealed granites, formed during Neo-Tethyan subduction-induced back-arc extension. The results reveal that among the four Sn mineralization episodes in the Tengchong-Baoshan Block (Early Cretaceous: 124–118 Ma; Late Cretaceous: 79–69 Ma; Early Eocene: 52–47 Ma; and Oligocene: 33–22 Ma), the Late Cretaceous Sn mineralization was spatially the most extensive, forming a coherent belt from the Southeast Asian Sn Belt northward through the Baoshan Block (both southern and northern parts) and into the Tengchong Block. We propose that future ore exploration in the Baoshan Block should prioritize the concealed Late Cretaceous granites and associated Sn mineralization.
宝山地块被认为是世界级东南亚锡带北延的组成部分。得天独厚的成矿地质条件,使其成为我国找矿找锡的重点地区。近年来,在宝山地块北部先后发现了几处锡矿床,其形成年龄集中在77 ~ 76 Ma,与东南亚锡带成矿高峰(~ 80 Ma)一致。然而,尽管处于中间位置,但由于缺乏晚白垩世花岗岩露头,宝山地块南部的锡矿床仍未被发现。该地区缺乏可靠的地质年代学资料,严重制约了成矿成因模型的建立,阻碍了有效的勘探规划。本文首次对宝山地块南部新发现的大隆锡矿床进行了高精度锡石U-Pb年龄测定(77.0±1.4 Ma和78.6±4.2 Ma),前人认为该矿床为三叠纪岩浆作用所致。大隆矿锡石富Ti、W、Fe,贫Nb、Ta、Zr、Mn,具有较高的Nb/Ta比值(3.16 ~ 545,平均7.26)。这些地球化学特征结合矿床地质特征,支持大龙锡矿床为晚白垩世隐伏花岗岩热液脉系,形成于新特提斯俯冲诱发弧后伸展时期。结果表明,在腾冲-宝山地块的4期(早白垩世124 ~ 118 Ma、晚白垩世79 ~ 69 Ma、早始新世52 ~ 47 Ma、渐新世33 ~ 22 Ma)中,晚白垩世的锡矿化在空间上最为广泛,形成了一条从东南亚锡带向北经宝山地块(南、北)进入腾冲地块的连贯带。建议宝山地块今后找矿应优先找隐伏晚白垩世花岗岩及其伴生锡成矿。
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引用次数: 0
3D mineral prospectivity modeling for concealed gold deposits based on 3DCNN and numerical modeling of ore-forming process in the Wuhe area, Anhui Province, China 基于3DCNN的隐伏金矿三维找矿模拟及成矿过程数值模拟
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107075
Xiaohui Li , Shengfei Ye , Feng Yuan , Deyuan Meng , Jiajia Zhang , Xuhuang Miao , Ying Xiao , Xiangling Li , Can Ge , Chaojie Zheng , Zhiqiang Wang , Yue Li
The Wuhe area is located in the southeastern margin of the North China Craton (NCC), adjacent to the Dabie–Sulu orogenic belt. It is considered an extension of the Zhaoyuan–Yexian gold belt to the west of the Tan–Lu Fault Zone. However, only a limited number of small- to medium-sized deposits have been discovered thus far in the Wuhe area. Recently, three-dimensional mineral prospectivity modeling (3DMPM) has become a powerful tool for targeting deep concealed deposits. The generation of 3D predictive maps associated with mineralization is a crucial step in 3DMPM. The numerical modeling of ore-forming process has gradually been integrated into 3DMPM. Numerical modeling can provide useful predictive information for 3DMPM. However, better ways to integrate these additional 3D predictive maps during 3DMPM require further exploration and research. Besides, the 3D convolutional neural network (3DCNN) model has demonstrated excellent data fusion capabilities when applied to 3DMPM for Skarn-type ore deposits. However, the application of 3DCNN in mineral prospectivity modeling for lode gold deposits has not yet been explored. Therefore, this study initially adopts the implicit 3D geological modeling method to build 3D geological models. Subsequently, 3D spatial analysis and numerical modeling are employed to generate 3D predictive maps. Finally, a 3DCNN model incorporating a spatial attention mechanism and an Inception module (MSAM-3DCNN) is employed to integrate the 3D predictive maps and delineate several highly prospective areas for future exploration. The high prospectivity areas not only delineate the data-driven deposits but also include the other deposits in the Wuhe area which demonstrates that the methods employed in this paper can map the mineral prospectivity of lode gold deposits efficiently. Numerical modeling can provide a series of 3D maps that significantly enhance the effectiveness of the 3DMPM, especially in modeling the potential mineralization of the lode gold deposits, where 3D predictive maps are limited. The MSAM-3DCNN model has significant advantages in multi-source predictive data integration compared to the Logistic Regression (LR) and Random Forest (RF) models, particularly by integrating more 3D maps generated by numerical modeling.
五河地区位于华北克拉通东南缘,毗邻大别-苏鲁造山带。它被认为是郯庐断裂带西侧招远—邺县金带的延伸。然而,迄今为止,在五河地区只发现了有限的中小型矿床。近年来,三维找矿建模(3DMPM)已成为找准深部隐伏矿床的有力工具。生成与矿化相关的三维预测图是3DMPM的关键步骤。成矿过程的数值模拟已逐渐融入三维点法中。数值模拟可以为3DMPM提供有用的预测信息。然而,在3DMPM期间整合这些额外的3D预测地图的更好方法需要进一步的探索和研究。此外,将三维卷积神经网络(3DCNN)模型应用于夕卡岩型矿床的3DMPM中,显示出良好的数据融合能力。然而,3DCNN在矿脉金矿找矿建模中的应用尚未见探索。因此,本研究初步采用隐式三维地质建模方法建立三维地质模型。随后,利用三维空间分析和数值模拟生成三维预测图。最后,采用一个包含空间注意机制和盗梦模块的3DCNN模型(MSAM-3DCNN)来整合3D预测地图,并描绘出未来勘探的几个极具前景的区域。高找矿区不仅圈定了数据驱动型矿床,而且还圈定了五河地区的其他矿床,表明本文所采用的方法可以有效地圈定矿脉金矿床的找矿远景。数值模拟可以提供一系列的三维地图,大大提高了3DMPM的有效性,特别是在模拟矿脉金矿床的潜在成矿作用方面,3D预测地图是有限的。与Logistic回归(LR)和随机森林(RF)模型相比,MSAM-3DCNN模型在多源预测数据集成方面具有显著优势,特别是在集成数值模拟生成的更多3D地图方面。
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引用次数: 0
Petrogenesis and metallogenesis of the Kalatage mafic intrusions associated with Fe–Ti oxide ores in the Eastern Tianshan, Central Asian Orogenic Belt 中亚造山带东天山与铁钛氧化物矿相关的钾化基性侵入体的岩石成因及成矿作用
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107071
Yu Shi , Yu-Wang Wang , Lie-Meng Chen , Guo-Chao Zhou , Qi-Gui Mao , Cheng-Biao Leng , Shui-Long Wang
Small-scale layered mafic intrusions hosting Fe–Ti oxide ores within orogenic belts are unconventional, and their geodynamic background, petrogenesis and metallogenic mechanisms remain poorly understood. To address this issue, our study focuses on investigating two recently discovered layered mafic Shaxi and Shaxinan intrusions from Eastern Tianshan belt in the Central Asian Orogenic Belt (CAOB). The Shaxi and Shaxinan intrusions are characterized as layered gabbro, intricately composed of alternating strata of hornblende gabbro and gabbro. Notably, the Fe–Ti oxide ores are specifically hosted within the basal sections of the hornblende gabbro layers. The zircon U–Pb dating yields an age of 307.9 ± 4.0 Ma for the Shaxi gabbro, which is coeval with the Shaxinan intrusion and Late Carboniferous mafic magmatism in East Tianshan. Both intrusions are tholeiitic and exhibit enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILE, e.g., Ba and U), and high field strength elements (HFSE, e.g., Nb and Zr) with obvious positive Eu anomalies. The Shaxi and Shaxinan intrusions have limited ranges of the εNd(t) values from 1.78 to 1.86 and 2.07 to 2.29 respectively but a relatively high (87Sr/86Sr)i from 0.7072 to 0.7075 and from 0.7067 to 0.7069, respectively. In combination with previous studies, our new geochemical and isotopic data suggest that the parental magmas of the Shaxi and Shaxinan intrusions likely originated from the partial melting of a metasomatized lithospheric mantle, a process that was likely initiated by the influx of hot, rising asthenospheric melts. The Shaxi and Shaxinan intrusions display highly differentiated chemical signatures, indicating their parental magmas underwent intense fractional crystallization, leading the residual melts enriched in ore-forming elements and H2O. During ascent and emplacement, these magmas likely assimilated country rocks of the Xingxingxia Group, introducing additional H2O and CO2 into the system. This contamination elevated magmatic oxygen fugacity and played a key role in the formation of Fe–Ti oxide deposits.
造山带内含铁钛氧化物矿的小型层状基性侵入体是非常规的,其地球动力学背景、岩石成因和成矿机制尚不清楚。为了解决这一问题,本文重点研究了中亚造山带(CAOB)东天山带新近发现的两个层状基性岩体沙溪和沙新南。沙溪、沙溪岩体为层状辉长岩,由角闪辉长岩与辉长岩交替地层复杂组成。值得注意的是,铁钛氧化物矿石特别赋存于角闪石辉长岩的基底部分。锆石U-Pb定年结果表明,沙溪辉长岩的年龄为307.9±4.0 Ma,与沙溪南岩体和东天山晚石炭世基性岩浆活动同时代。两种侵入体均为拉斑岩,均富集轻稀土元素(LREE)、大离子亲石元素(LILE,如Ba、U)和高场强元素(HFSE,如Nb、Zr),且Eu正异常明显。沙溪岩体和沙溪岩体的εNd(t)值范围较窄,分别为1.78 ~ 1.86和2.07 ~ 2.29,但εNd(t)值较高,分别为0.7072 ~ 0.7075和0.7067 ~ 0.7069。结合前人的研究,我们新的地球化学和同位素数据表明,沙溪和沙溪南侵入岩的母岩浆可能起源于交代岩石圈地幔的部分熔融,这一过程可能是由热的上升软流圈熔体的涌入引起的。沙溪岩体和沙溪岩体具有高度分化的化学特征,表明母岩岩浆经历了强烈的分离结晶,导致残余熔体富集成矿元素和水。在上升和侵位过程中,这些岩浆可能吸收了星星峡群的乡村岩石,向系统中引入了额外的H2O和CO2。这种污染提高了岩浆氧逸度,并在铁钛氧化物矿床的形成中发挥了关键作用。
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引用次数: 0
In situ sulfur isotopic and thermodynamic constraints on the magmatic evolution and Metallogenesis of the Jinchuan Ni–Cu sulfide Deposit, China 金川镍铜硫化物矿床岩浆演化与成矿的原位硫同位素及热力学约束
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107038
Zhenjiang Wang , Chao Wang , Yannan Wang , Zhenmin Jin
The world-class Jinchuan magmatic Ni-Cu sulfide deposit in China represents a globally significant source for nickel (Ni) and platinum-group elements (PGEs). However, the sulfur source and the magmatic evolution responsible for ore formation in the Jinchuan intrusion remain controversial. Field evidence for crustal marble assimilation, along with oxygen fugacity (relative to the fayalite–magnetite–quartz buffer, ΔFMQ) estimates from olivine-spinel (−2.1 – +2.4) and olivine-sulfide oxybarometry (−1.1 – +0.3), suggests a redox transition from reduced to oxidized conditions during early-stage magma evolution. This interpretation is further corroborated by thermodynamic modeling using rhyolite-MELTS. Major element compositional variations within the intrusion, combined with thermodynamic simulations, indicate that magma evolution was dominated by olivine, orthopyroxene, and clinopyroxene crystallization. Our modeling further implies that the lower crustal assimilation, followed by incorporation of ∼ 10 – 15 % marble, played a critical role in the deposit’s formation. NanoSIMS analyses of magmatic sulfide ores reveal a broad δ34S range (−5.3 ‰ to + 4.5 ‰; n = 56). We interpret this variability as resulting from the combined effects of magma redox state transition, magmatic-hydrothermal fluid activity, and potential incorporation of crustal sulfur during the main metallogenic stage. In contrast, Cr-spinel-hosted sulfide inclusions preserve mantle-like sulfur isotope signatures (δ34S =  − 2.0 ‰ to + 2.1 ‰; n = 18) and restricted S/Se ratios (2,007 – 4,860). These observations suggest minimal external sulfur contribution during the early differentiation sequence of the Jinchuan parental magma. Numerical modeling reveals that during the redox state transition, the sulfur solubility contrast between magma liquidus and orthopyroxene crystallization temperatures increases dramatically from 0.01 wt% to 0.15 wt% (sulfide saturation), even 0.24 wt% (sulfate saturation). This significant enhancement in sulfur solubility substantially reduces the magma volume required for deposit formation. Collectively, our findings propose that redox state transitions in magmatic systems could serve as a critical mechanism for enhancing the mineralization potential of parental magmas to form Ni-Cu sulfide deposits.
中国金川岩浆镍铜硫化物矿床是全球重要的镍和铂族元素(PGEs)矿床。但对金川侵入体硫源及成矿岩浆演化仍有争议。根据橄榄石-尖晶石(- 2.1 - +2.4)和橄榄石-硫化物氧压测量(- 1.1 - +0.3)估算的地壳大理岩同化的现场证据以及氧逸度(相对于铁矾石-磁铁矿-石英缓冲带,ΔFMQ)表明,在早期岩浆演化过程中,从还原到氧化状态发生了氧化还原转变。流纹岩熔体热力学模型进一步证实了这一解释。岩体内主要元素组成变化结合热力学模拟表明,岩浆演化以橄榄石、正辉石和斜辉石结晶为主。我们的模型进一步表明,下地壳的同化作用,以及随后的10 - 15%大理岩的掺入,在矿床的形成中发挥了关键作用。岩浆岩硫化物矿石的纳米sims分析显示其δ34S范围较宽(−5.3‰~ + 4.5‰,n = 56)。我们认为这种变化是岩浆氧化还原状态转变、岩浆-热液流体活动和主要成矿阶段地壳硫的潜在掺入共同作用的结果。而含铬尖晶石硫化物包裹体则保留了地幔样硫同位素特征(δ34S =−2.0‰~ + 2.1‰,n = 18)和限制S/Se比值(2007 ~ 4860)。这些观测结果表明,在金川母岩浆早期分异序列中,外部硫的贡献很小。数值模拟表明,在氧化还原状态转变过程中,岩浆液和正辉石结晶温度之间的硫溶解度对比从0.01 wt%(硫化物饱和度)急剧增加到0.15 wt%(硫酸盐饱和度),甚至增加到0.24 wt%(硫酸盐饱和度)。硫溶解度的显著提高大大减少了矿床形成所需的岩浆体积。总之,我们的研究结果表明,岩浆系统中的氧化还原态转变可能是增强母岩浆成矿潜力形成镍铜硫化物矿床的关键机制。
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引用次数: 0
Genesis of the Luanchuan serpentine jade, East Qinling, China: Insights from petrology, geochemistry, and U-Pb geochronology 东秦岭栾川蛇纹石玉石的成因:岩石学、地球化学和U-Pb年代学的启示
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2026-01-01 DOI: 10.1016/j.oregeorev.2025.107090
Cun Zhang , Fan Yang , Leon Bagas , Xuhuang Zhang , Nan Ma , Xinyi Zhu , Rongbin Zhang
<div><div>The Luanchuan jade deposit in the East Qinling Orogen, central China provides crucial clues to the tectonic evolutionary processes of the southern margin of the North China Block (NCB). The jade is primarily composed of serpentine jade with subordinate associated nephrite/tremolite jade, where the former is distinctly in contact with metamorphosed gabbro. Significant debate remains, however, regarding the jade types’ spatial and temporal distribution and genesis. In this study, we integrate petrography, X-ray powder diffraction, geochemistry, S-Sr isotopes, and zircon U-Pb geochronology to elucidate the mineralogy, mineralisation processes, and tectonic setting of major serpentine jade occurrences. Our findings indicate that the ore bodies primarily underwent serpentine alteration, characterised by the mineral assemblage serpentine (antigorite)–dolomite–calcite–diopside–chlorite–pyrite. Pyrite shows a narrow range of δ<sup>34</sup>S value from 3.4 to 5.6 ‰, coupled with a Co/Ni ratio varying between 1.83 and 12.6, indicative of a magmatic-hydrothermal origin. Whole-rock geochemistry of the jade samples is characterised by a strongly negative Eu anomaly, a slight Ce anomaly, enrichment in light rare earth elements (LREEs), flat heavy rare earth elements (HREEs) patterns, along with significant U and Th enrichments, but depletion in Rb, Ba, Nb, and other trace elements. These characteristics indicate a close genetic link between the serpentine jade and its host dolomitic marble. Geochemical characteristics (Th/U, δU, and δCe ratios) indicate that the jade was formed in an oxidized environment, while the whole-rock Sr/Ba, Zr/Hf, and Nb/Ta ratios depict its formation in an alkaline formation environment. The <sup>87</sup>Sr/<sup>86</sup>Sr values in the jade samples range from 0.706459 to 0.709109, typical of marine Sr components pointing to inheritance from metasedimentary components. Zircon U-Pb dating of the metagabbro yields a concordant age of 860 ± 8 Ma (interpreted as the crystallisation age) revealing a significant mid-Neoproterozoic magmatic event. In contrast, U-Pb dating of metamorphic zircon (with Th/U ratios of 0.02–0.24) from the jade (serpentinised marble) yields an upper intercept age of 1924 ± 14 Ma. The date is interpreted as corresponding to a Paleoproterozoic tectono-thermal event that triggered the regional metamorphism of marine carbonate rocks into dolomitic marble. Integrated geological investigations reveal that the Mg and Ca at the Luanchuan serpentine jade were primarily derived from dolomitic marble. While the sources of SiO<sub>2</sub> and H<sub>2</sub>O were associated with both metamorphic fluids and mafic magmatism, further confirmed by the comparatively close ratios of Eu/Sm and Sm/Nd between the metagabbro and samples of the Luanchuan serpentine jade. Our study emphasizes that the serpentine jade deposit primarily formed through multiple tectonic episodes, during which basic magmatic-hydrothermal fluids int
东秦岭造山带栾川玉石矿床为研究华北地块南缘构造演化过程提供了重要线索。玉石以蛇纹石玉石为主,伴生软玉/透闪石玉石,其中前者与变质辉长岩有明显接触。然而,关于玉石类型的时空分布和成因仍存在重大争议。在这项研究中,我们综合岩石学、x射线粉末衍射、地球化学、S-Sr同位素和锆石U-Pb年代学来阐明蛇纹玉主要产状的矿物学、矿化过程和构造背景。研究结果表明,矿体主要发生了蛇纹石蚀变,其矿物组合特征为蛇纹石(反长辉岩)-白云石-方解石-透辉石-绿泥石-黄铁矿。黄铁矿δ34S值在3.4 ~ 5.6‰之间,Co/Ni比值在1.83 ~ 12.6之间,属于岩浆-热液成因。玉石样品的全岩地球化学特征为Eu负异常强烈,Ce异常轻微,轻稀土元素(lree)富集,重稀土元素(hree)平坦,U、Th富集,Rb、Ba、Nb等微量元素富集。这些特征表明蛇纹玉与其寄主白云岩大理岩具有密切的成因联系。地球化学特征(Th/U、δU和δCe比值)表明该玉石形成于氧化环境,全岩Sr/Ba、Zr/Hf和Nb/Ta比值表明其形成于碱性环境。玉石样品87Sr/86Sr值在0.706459 ~ 0.709109之间,具有典型的海相Sr成分,表明其继承自元沉积成分。变质长岩的锆石U-Pb年龄为860±8 Ma(解释为结晶年龄),显示了一次重要的中新元古代岩浆活动。相比之下,对玉石(蛇纹大理石)变质锆石(Th/U比值为0.02 ~ 0.24)的U- pb定年得到的上截距年龄为1924±14 Ma。该日期对应于古元古代构造-热事件,引发海相碳酸盐岩区域变质为白云质大理岩。综合地质调查表明,栾川蛇纹石玉石中的镁、钙主要来源于白云岩大理岩。而SiO2和H2O的来源则与变质流体和基性岩浆作用有关,并通过变质长岩与栾川蛇纹石玉石样品之间较为接近的Eu/Sm和Sm/Nd比值进一步证实。研究认为,栾川蛇纹玉石矿床主要形成于多期构造作用,其中基性岩浆-热液流体与变质作用相互作用,其侵位年龄约为860 Ma,可解释栾川蛇纹玉石形成的年龄上限。
{"title":"Genesis of the Luanchuan serpentine jade, East Qinling, China: Insights from petrology, geochemistry, and U-Pb geochronology","authors":"Cun Zhang ,&nbsp;Fan Yang ,&nbsp;Leon Bagas ,&nbsp;Xuhuang Zhang ,&nbsp;Nan Ma ,&nbsp;Xinyi Zhu ,&nbsp;Rongbin Zhang","doi":"10.1016/j.oregeorev.2025.107090","DOIUrl":"10.1016/j.oregeorev.2025.107090","url":null,"abstract":"&lt;div&gt;&lt;div&gt;The Luanchuan jade deposit in the East Qinling Orogen, central China provides crucial clues to the tectonic evolutionary processes of the southern margin of the North China Block (NCB). The jade is primarily composed of serpentine jade with subordinate associated nephrite/tremolite jade, where the former is distinctly in contact with metamorphosed gabbro. Significant debate remains, however, regarding the jade types’ spatial and temporal distribution and genesis. In this study, we integrate petrography, X-ray powder diffraction, geochemistry, S-Sr isotopes, and zircon U-Pb geochronology to elucidate the mineralogy, mineralisation processes, and tectonic setting of major serpentine jade occurrences. Our findings indicate that the ore bodies primarily underwent serpentine alteration, characterised by the mineral assemblage serpentine (antigorite)–dolomite–calcite–diopside–chlorite–pyrite. Pyrite shows a narrow range of δ&lt;sup&gt;34&lt;/sup&gt;S value from 3.4 to 5.6 ‰, coupled with a Co/Ni ratio varying between 1.83 and 12.6, indicative of a magmatic-hydrothermal origin. Whole-rock geochemistry of the jade samples is characterised by a strongly negative Eu anomaly, a slight Ce anomaly, enrichment in light rare earth elements (LREEs), flat heavy rare earth elements (HREEs) patterns, along with significant U and Th enrichments, but depletion in Rb, Ba, Nb, and other trace elements. These characteristics indicate a close genetic link between the serpentine jade and its host dolomitic marble. Geochemical characteristics (Th/U, δU, and δCe ratios) indicate that the jade was formed in an oxidized environment, while the whole-rock Sr/Ba, Zr/Hf, and Nb/Ta ratios depict its formation in an alkaline formation environment. The &lt;sup&gt;87&lt;/sup&gt;Sr/&lt;sup&gt;86&lt;/sup&gt;Sr values in the jade samples range from 0.706459 to 0.709109, typical of marine Sr components pointing to inheritance from metasedimentary components. Zircon U-Pb dating of the metagabbro yields a concordant age of 860 ± 8 Ma (interpreted as the crystallisation age) revealing a significant mid-Neoproterozoic magmatic event. In contrast, U-Pb dating of metamorphic zircon (with Th/U ratios of 0.02–0.24) from the jade (serpentinised marble) yields an upper intercept age of 1924 ± 14 Ma. The date is interpreted as corresponding to a Paleoproterozoic tectono-thermal event that triggered the regional metamorphism of marine carbonate rocks into dolomitic marble. Integrated geological investigations reveal that the Mg and Ca at the Luanchuan serpentine jade were primarily derived from dolomitic marble. While the sources of SiO&lt;sub&gt;2&lt;/sub&gt; and H&lt;sub&gt;2&lt;/sub&gt;O were associated with both metamorphic fluids and mafic magmatism, further confirmed by the comparatively close ratios of Eu/Sm and Sm/Nd between the metagabbro and samples of the Luanchuan serpentine jade. Our study emphasizes that the serpentine jade deposit primarily formed through multiple tectonic episodes, during which basic magmatic-hydrothermal fluids int","PeriodicalId":19644,"journal":{"name":"Ore Geology Reviews","volume":"188 ","pages":"Article 107090"},"PeriodicalIF":3.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sm-Nd geochronology of the Hoxbulak Zn-Pb deposit in Xinjiang (NW China) and its link to Paleogene Mississippi Valley-type mineralization in the Tethyan domain 新疆霍克斯布拉克铅锌矿床的Sm-Nd年代学及其与特提斯域古近系密西西比河谷型成矿作用的联系
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-31 DOI: 10.1016/j.oregeorev.2025.107092
Ying Wang , Zhaochong Zhang , Shu Zhang , Zhiguo Cheng , He Huang
Sediment-hosted Zn-Pb deposits are the most important global source of Pb and Zn, yet their genesis and timing remain central questions in economic geology. Direct geochronological constraints are often difficult to obtain due to the general absence of suitable datable minerals, hindering the understanding of ore-forming processes and regional metallogenic models. The Hoxbulak Zn-Pb deposit in Xinjiang, a typical sediment-hosted Zn-Pb deposit in the southwestern Tianshan Mountains of the Central Asian metallogenic domain, has long been controversial with respect to its genetic type and mineralization age, primarily focusing on whether it is related to adjacent Permian magmatism and whether it formed syngenetically or epigenetically. In this study, we conducted precise Sm-Nd isochron dating of sphalerite, galena, and associated calcite/dolomite from the main mineralization stage, yielding a mineralization age of 55 ± 2 Ma. This result indicates that the deposit formed during the Paleogene and shows no genetic relationship with the neighboring Permian Hoxbulak pluton (261.5 ± 2.7 Ma; 273.6 ± 2.0 Ma and 274.8 ± 1.5 Ma), supporting its classification as an epigenetic Mississippi Valley-type (MVT) deposit. Integrated regional structural analysis suggests that this mineralization event was likely controlled by transpression tectonics triggered during the initial India-Eurasia collision (∼60–50 Ma). Our findings demonstrate that the Hoxbulak deposit represents a critical northwestern extension of the Tethyan MVT metallogenic belt (spanning Yunnan-Tibet-Xinjiang) and serves as its easternmost component within the Central Asian metallogenic domain—linking the classic Tethyan MVT system with the interior of the Central Asian Orogenic Belt. This study provides important constraints for exploring Paleogene MVT-type Zn-Pb deposits in Late Paleozoic carbonate formations of the South Tianshan, offering significant insights into the metallogenic patterns of Zn-Pb deposits in the junction zone between the Tethyan and Central Asian orogenic belts.
沉积型铅锌矿床是全球最重要的铅锌来源,但其成因和成矿时间仍是经济地质学的核心问题。由于普遍缺乏合适的年代矿物,往往难以获得直接的地质年代学约束,从而阻碍了对成矿过程和区域成矿模式的理解。新疆霍克斯布拉克铅锌矿床是中亚成矿带西南天山地区典型的沉积型铅锌矿床,其成因类型和成矿时代一直存在争议,主要集中在其是否与邻近的二叠纪岩浆作用有关,是同生形成还是表生形成。在这项研究中,我们对主要成矿阶段的闪锌矿、方铅矿和伴生方解石/白云石进行了精确的Sm-Nd等时线测年,得出成矿年龄为55±2 Ma。结果表明,该矿床形成于古近纪,与邻近的二叠纪Hoxbulak岩体(261.5±2.7 Ma、273.6±2.0 Ma和274.8±1.5 Ma)无成因关系,属于后成因密西西比河谷型(MVT)矿床。综合区域构造分析认为,该成矿事件可能受印度-欧亚碰撞初期(~ 60-50 Ma)引发的逆压构造控制。研究结果表明,Hoxbulak矿床是特提斯MVT成矿带(横跨云南-西藏-新疆)的一个关键的西北延伸,是特提斯MVT成矿带在中亚成矿域中最东端的组成部分,将特提斯MVT系统与中亚造山带内部连接起来。该研究为南天山晚古生代碳酸盐岩地层中寻找古近系mvt型铅锌矿床提供了重要的约束条件,对特提斯造山带与中亚造山带交界带的铅锌矿床成矿模式有重要的认识。
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引用次数: 0
Indium distribution and substitution mechanisms in the skarn mineralization process of world-class Dulong Sn–Zn–In deposit, Yunnan Province (Southwest China) 世界级云南独龙锡锌矿床夕卡岩成矿过程中铟的分布及替代机制
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-28 DOI: 10.1016/j.oregeorev.2025.107085
Liang Li , Shucheng Tan , Zheng Liu , Jingxian Meng , Jianyu Yang , Yuguo Zhou , Xiaohu He , Jiang Zhu , Hailong He , Qinghe Yan , Hui Ye
As a representative deposit of indium (indium)-rich skarn mineralization systems, the Dulong world-class Sn-Zn-In deposit offers an ideal natural laboratory for investigating the occurrence patterns, spatial distribution, and substitution mechanisms of indium through systematic in-situ analysis using EPMA and LA-ICP-MS. Our analytical results reveal significant and selective enrichment of indium in minerals, governed by complex substitution mechanisms. Indium preferentially concentrates in sphalerite, cassiterite, and chalcopyrite, while other minerals (e.g., magnetite, arsenopyrite, and pyrrhotite) exhibit anomalously elevated indium contents. However, the predominance of sphalerite in the deposit inhibits the formation of discrete indium mineral phases. The incorporation of indium primarily occurs through isomorphic substitution involving multiple coupled mechanisms, including: (i) (Cu, Ag)+ + In3+ ↔ 2(Zn, Fe)2+ in sphalerite and chalcopyrite; (ii) In3+ ↔ Fe3+ in cassiterite and chalcopyrite; (iii) In3+ + Sn4+ ↔ Fe2+ + (Nb, Ta)5+ in cassiterite; (iv) Ag+ + Sn2+ + In3+ ↔ 3Zn2+ in chalcopyrite. During skarn mineralization processes, the distribution and enrichment of indium are principally controlled by four key factors: (i) crystallographic constraints of host minerals, (ii) physicochemical properties of ore-forming fluids, (iii) thermodynamic conditions, and (iv) specific substitution mechanisms. Indium preferentially partitions into minerals with tetrahedral coordination sites and those formed under high-temperature conditions. Furthermore, sulfur-rich hydrothermal systems with elevated sulfur fugacity demonstrate enhanced indium enrichment capacity. Temporally, indium enrichment exhibits distinct stage-specific characteristics, with principal concentration occurring in oxide-stage cassiterite and early sulfide-stage Fe-rich sphalerite and chalcopyrite developed under high sulfur fugacity conditions. We provide critical insights into the microscale occurrence states and atomic-scale substitution mechanisms of indium in the Dulong deposit. By systematically elucidating the geochemical behavior and enrichment processes of indium during skarn mineralization, our findings advance the understanding of critical metal enrichment mechanisms and expand the theoretical framework of skarn deposit formation.
独龙世界级Sn-Zn-In矿床作为富铟矽卡岩成矿系统的代表矿床,通过系统的EPMA和LA-ICP-MS原位分析,为研究铟的赋存形态、空间分布和替代机制提供了理想的天然实验室。我们的分析结果揭示了铟在矿物中的显著和选择性富集,由复杂的取代机制控制。铟优先富集在闪锌矿、锡石和黄铜矿中,而其他矿物(如磁铁矿、毒砂和磁黄铁矿)的铟含量异常升高。然而,闪锌矿在矿床中的优势抑制了离散铟矿物相的形成。铟的加入主要是通过涉及多种耦合机制的同构取代发生的,包括:(i)闪锌矿和黄铜矿中的(Cu, Ag)+ + In3+↔2(Zn, Fe)2+;锡铁矿和黄铜矿中的In3+↔Fe3+;(iii)锡石中的in3++ Sn4+↔fe2++ (Nb, Ta)5+;(iv)黄铜矿中的Ag+ + Sn2+ + In3+↔3Zn2+。在矽卡岩成矿过程中,铟的分布和富集主要受4个关键因素的控制:(1)寄主矿物的晶体约束;(2)成矿流体的物理化学性质;(3)热力学条件;(4)特定的取代机制。铟优先划分为具有四面体配位的矿物和高温条件下形成的矿物。此外,硫逸度提高的富硫热液系统表现出增强的铟富集能力。时间上,铟的富集表现出明显的阶段特征,主要富集在高硫逸度条件下的氧化期锡石和早期硫化物期富铁闪锌矿和黄铜矿中。我们对独龙矿床中铟的微尺度赋存状态和原子尺度取代机制提供了重要的见解。系统阐明了矽卡岩成矿过程中铟的地球化学行为和富集过程,促进了对矽卡岩成矿关键金属富集机制的认识,拓展了矽卡岩矿床形成的理论框架。
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引用次数: 0
Integrated gravity and magnetic data for epithermal deposit target area identification: A case study from the Shuangjianzishan Region, Inner Mongolia 重磁综合资料在浅成低温热液矿床靶区识别中的应用——以内蒙古双尖子山地区为例
IF 3.6 2区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-18 DOI: 10.1016/j.oregeorev.2025.107073
Zhengyuan Jia, Luofan Xiong, Gang Zhang, Guibin Zhang
In deep-seated and concealed mineral exploration, variations in ore-forming systems lead to significant differences in geophysical responses, driven by contrasting structural and petrophysical characteristics. For instance, epithermal deposits typically occur as veins or disseminated bodies, and their scale, geometry, and spatial distribution strongly influence gravity and magnetic anomalies. Consequently, single-method geophysical approaches often fail to accurately delineate prospecting targets. This study investigates the Shuangjianzishan ore district in southeastern Inner Mongolia, China, using a combination of multi-scale edge detection and 3D gravity and magnetic inversion to analyze ore-forming processes and assess mineral prospectivity. Laboratory measurements of rock physical properties were used to establish quantitative relationships between density and magnetic susceptibility, providing a foundation for lithological discrimination. Multi-scale edge detection revealed structural boundaries and ore-controlling faults at various depths. The three-dimensional density and susceptibility models derived from the inversion of gravity and magnetic data, when integrated with petrophysical statistical analysis, enabled the identification of key lithological units such as ore-hosting strata and intrusive rocks. A 3D lithological model was constructed, from which a conceptual epithermal mineralization model was derived to guide exploration targeting. The results show that major structural boundaries align with known faults, and the inversion models correlate well with confirmed ore bodies. Several delineated prospective zones coincide with known mineralization, confirming the reliability of the proposed method. Additionally, five previously unidentified high-potential zones were recognized. This study enhances the understanding of the genesis of the Shuangjianzishan deposit and offers an effective technical framework for exploring similar concealed epithermal systems in the southeastern Greater Khingan Range.
在深部和隐伏找矿中,由于构造和岩石物理特征的差异,成矿系统的变化导致了地球物理响应的显著差异。例如,浅成热液矿床通常呈脉状或浸染状,其规模、几何形状和空间分布强烈影响重磁异常。因此,单一方法的地球物理方法往往不能准确地圈定找矿目标。以内蒙古东南部双尖子山矿区为研究对象,采用多尺度边缘检测与三维重磁反演相结合的方法,分析成矿过程,评价找矿前景。通过对岩石物理性质的实验室测量,建立了密度与磁化率之间的定量关系,为岩性判别提供了基础。多尺度边缘检测揭示了不同深度的构造边界和控矿断裂。利用重磁数据反演的三维密度和磁化率模型与岩石物理统计分析相结合,可以识别出含矿层和侵入岩等关键岩性单元。建立了三维岩性模型,推导了浅成热液成矿概念模型,指导了找矿方向。结果表明,主要构造边界与已知断层排列一致,反演模型与已确认的矿体吻合良好。几个圈定的远景带与已知矿化相吻合,证实了所提出方法的可靠性。此外,还发现了五个以前未识别的高电位区域。该研究增强了对双尖子山矿床成因的认识,为大兴安岭东南部类似隐伏浅成热液系统的勘探提供了有效的技术框架。
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Ore Geology Reviews
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