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The impact of fossil energy technological progress on sectoral implied energy intensity: Evidence from the U.S. shale gas revolution 化石能源技术进步对行业隐含能源强度的影响:来自美国页岩气革命的证据
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-12-13 DOI: 10.1016/j.petsci.2025.12.017
Xiang-Yu Kong, Hong Li, Bang-Rui Wu
This paper investigates how sectoral implied energy intensity responds to energy technology progress, using the U.S. shale gas revolution—the most significant energy breakthrough of the 21st century—as a quasi-natural experiment. Using industry-level input-output and trade data, we implement a difference-in-differences (DID) strategy to identify the effects. We find that the shale revolution, on average, increases sectoral implied energy intensity in countries with higher natural gas import demand. The results are robust to alternative specifications, multiple fixed effects, parallel-trend checks, and placebo tests. Mechanism analysis suggests that the rise in implied energy intensity is driven by increased natural gas imports and intensified competition among gas-exporting countries. Heterogeneity analysis further reveals that skill-intensive sectors, transportation, public services, and environmental industries are more responsive to the shale gas technology shock. These findings underscore the spillover effects of the revolution not only on global trade patterns but also on sectoral energy use, highlighting the need for enhanced coordination in energy technology development and energy security strategies.
本文以美国页岩气革命(21世纪最重要的能源突破)为准自然实验,研究了行业隐含能源强度如何响应能源技术进步。利用行业层面的投入产出和贸易数据,我们实施了差异中差异(DID)策略来识别影响。我们发现,在天然气进口需求较高的国家,页岩气革命平均提高了行业隐含的能源强度。结果是稳健的替代规格,多个固定效应,平行趋势检查,和安慰剂测试。机制分析表明,隐含能源强度的上升是由天然气进口增加和天然气出口国之间竞争加剧驱动的。异质性分析进一步表明,技能密集型行业、交通运输、公共服务和环境行业对页岩气技术冲击的响应更大。这些调查结果强调了革命不仅对全球贸易格局而且对部门能源使用的溢出效应,突出了加强能源技术发展和能源安全战略协调的必要性。
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引用次数: 0
Changes in the effective absolute permeability of hydrate-bearing sands during isotropic loading and unloading 各向同性加载和卸载过程中含水砂岩有效绝对渗透率的变化
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-10-16 DOI: 10.1016/j.petsci.2025.10.009
Hui-Long Ma , Xiu-Li Feng , Le-Le Liu , An Zhang , Dong Wang
The effective stress of marine sediments frequently shifts owing to natural or anthropogenic factors, and a broad spectrum of processes fundamentally require accounting for sediment responses to such changes. Marine sediments hosting natural gas hydrates have been regarded as a prospective energy reservoir, and depressurization-driven production efficiency hinges largely on the effective absolute permeability of hydrate-bearing strata. Yet, how this permeability evolves during depressurization remains unresolved, and whether pore-hosted hydrates impede or enhance it remains ambiguous. This study probes the permeability response of hydrate-bearing sands to cyclic loading through isotropic compression/swelling and water flow tests. Results reveal that methane hydrate presence curbs the void-ratio decline yet amplifies the effective-void-ratio reduction during isotropic loading. The effective absolute permeability of hydrate-bearing sands declines with rising hydrate saturation and increasing mean effective stress, and permeability stress sensitivity intensifies at higher hydrate saturations and lower mean effective stresses. The introduced model accurately predicts void-ratio changes during isotropic loading and unloading. Coefficients for strengthening, normal filling, and enhanced filling effects are introduced and quantified to disentangle the positive and negative influences of methane hydrate, with the negative filling effect exceeding the positive strengthening effect by one order of magnitude for quartz sands.
由于自然或人为因素,海洋沉积物的有效应力经常发生变化,广泛的过程从根本上要求考虑沉积物对这种变化的反应。含天然气水合物的海相沉积物被认为是一种有前景的能源储层,而降压开采效率在很大程度上取决于含水合物地层的有效绝对渗透率。然而,在减压过程中,渗透率是如何演变的,以及孔隙水合物是阻碍还是增强了渗透率,这些问题仍未得到解决。通过各向同性压缩/膨胀试验和水流试验,探讨了含水砂岩渗透率对循环加载的响应。结果表明,在各向同性加载过程中,甲烷水合物的存在抑制了孔隙率的下降,但放大了有效孔隙率的下降。含水砂岩的有效绝对渗透率随水合物饱和度的升高和平均有效应力的增大而减小,渗透率应力敏感性随水合物饱和度的升高和平均有效应力的减小而增强。该模型准确地预测了各向同性加载和卸载过程中空隙率的变化。引入并量化了强化效应、正常充填效应和强化充填效应的系数,理清了甲烷水合物的正负影响,发现石英砂的负充填效应比正强化效应高出一个数量级。
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引用次数: 0
Study on the phase behavior and minimum miscible pressure of CO2-shale oil in nanopores with confinement effect 具有约束效应的co2 -页岩油纳米孔相行为及最小混相压力研究
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-25 DOI: 10.1016/j.petsci.2025.11.039
Ying Xiong , Peng-Fei Chen , Wan-Fen Pu , Rui Jiang , Qin Pang
CO2 injection is a significant enhanced oil recovery method in shale oil reservoirs and facilitates the mitigation of CO2 emissions. However, the phase behavior and miscibility process of light shale oil and CO2 system in shale reservoirs with widely distributed nanopores remain uncertain. Based on the thermodynamic equilibrium theory and the modified Peng-Robinson equation of state (PR-EOS), a confined fluid model considering the effect of nanoconfinement (critical property shift and adsorption) and capillarity was used to study the phase diagram and thermodynamic property of shale oil-CO2 mixtures. The validity of the fluid model in bulk and in nanopores was verified with the pressure-volume-temperature (PVT) experiments and literature data, respectively. The interfacial tension (IFT) and minimum miscible pressure (MMP) were determined by the Parachor model and IFT vanishing method (VIT), respectively. The effects of pore sizes, temperature and injected gas type and compositions on the IFT and MMP was comprehensively investigated. The result shows that the nanoconfinement effect causes the two-phase region in the phase diagram of reservoir fluids to contract and enhances the ability of CO2 and light components to enter smaller pores, thus reducing the bubble point pressure, oil density, oil viscosity and IFT of shale oil-CO2 mixtures in nanopores. The nanoconfinement effect is more pronounced in pore radius of less than 50 nm, with roughly 16% reduction in the MMP of shale oil-CO2 mixtures. Temperature has a negative effect on the IFT and MMP of shale oil-CO2 mixtures due to the decreased solubility of CO2 under high temperature. The miscibility of CO2 and shale oil is improved by propane (C3H8) and ethane (C2H6), while decreased by methane (CH4).
注CO2是页岩油藏提高采收率的重要方法,有利于减少CO2的排放。然而,在纳米孔广泛分布的页岩储层中,轻质页岩油与CO2体系的相行为和混相过程仍然不确定。基于热力学平衡理论和修正的Peng-Robinson状态方程(PR-EOS),建立了考虑纳米约束(临界性质转移和吸附)和毛毛细管效应的密闭流体模型,研究了页岩油-二氧化碳混合物的相图和热力学性质。分别通过压力-体积-温度(PVT)实验和文献数据验证了体积流体模型和纳米孔流体模型的有效性。界面张力(IFT)和最小混相压力(MMP)分别由Parachor模型和IFT消失法(VIT)确定。综合考察了孔隙大小、温度、注入气体类型和成分对IFT和MMP的影响。结果表明,纳米约束效应使储层流体相图中的两相区域收缩,增强了CO2和轻组分进入较小孔隙的能力,从而降低了页岩油-CO2混合物在纳米孔隙中的泡点压力、油密度、油粘度和IFT。在孔隙半径小于50 nm时,纳米约束效应更为明显,页岩油-二氧化碳混合物的MMP降低了约16%。温度对页岩油-CO2混合物的IFT和MMP有负面影响,这是由于CO2在高温下溶解度降低。丙烷(C3H8)和乙烷(C2H6)改善了CO2与页岩油的混相,甲烷(CH4)降低了CO2与页岩油的混相。
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引用次数: 0
A more efficient subsidy policy for CO2 enhanced oil recovery: Insights from a vertically integrated business model 更有效的二氧化碳提高采收率补贴政策:来自垂直整合商业模式的见解
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-28 DOI: 10.1016/j.petsci.2025.11.040
Liang-Yu Xia , Yao Wu , Yue-Mei Zhang
Although carbon dioxide enhanced oil recovery (CO2-EOR) is a technically and economically viable option within carbon capture, utilization, and storage (CCUS), its transition from demonstration to commercial application still requires subsidies. Existing research mainly focuses on carbon capture, overlooking the impact of stakeholder interest distribution and subsidy demand differences across the industrial chain. To address this issue, we first investigated the factors influencing subsidy requirements for CO2-EOR projects under a vertically integrated business model. Utilizing the dynamic feedback relationships among these factors, we developed a system dynamics model to assess subsidy demand. Considering CO2-EOR decision flexibility, we used real options analysis to evaluate the value of flexible decisions. Simulation identified three key factors for subsidy stratification: capture method, reservoir depth, and oil displacement efficiency. By calculating from the economic break-even point, we defined subsidy thresholds and developed a graded scheme linked to crude oil prices, considering their impact on policy effectiveness. Using the subsidy intensity of Section 45Q tax credit as a reference for simulation, the results indicate that when crude oil prices reach a certain level, the subsidy demand for projects can drop to zero. Differentiated subsidies reduced the amount required to achieve the same policy objectives by 25%, significantly enhancing policy efficiency.
虽然二氧化碳提高采收率(CO2-EOR)在碳捕集、利用和封存(CCUS)技术上和经济上都是可行的选择,但从示范到商业应用的过渡仍然需要补贴。现有的研究主要集中在碳捕集上,忽视了产业链上利益相关者利益分配和补贴需求差异的影响。为了解决这一问题,我们首先研究了垂直整合商业模式下二氧化碳提高采收率项目补贴需求的影响因素。利用这些因素之间的动态反馈关系,我们建立了一个系统动力学模型来评估补贴需求。考虑到CO2-EOR决策的灵活性,我们使用实物期权分析来评估灵活决策的价值。模拟确定了补贴分层的三个关键因素:捕获方法、油藏深度和驱油效率。通过计算经济盈亏平衡点,我们定义了补贴门槛,并制定了一个与原油价格挂钩的分级方案,考虑了它们对政策有效性的影响。以45Q节税收抵免补贴强度为参考进行模拟,结果表明,当原油价格达到一定水平时,项目补贴需求可以降至零。差别化补贴使实现相同政策目标所需的补贴减少了25%,显著提高了政策效率。
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引用次数: 0
A novel NMR methodology for the quantitative characterization of solid organic matter in shale oil 一种新的核磁共振定量表征页岩油中固体有机质的方法
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-08 DOI: 10.1016/j.petsci.2025.11.009
Chen-Yu Xu , Ran-Hong Xie , Jiang-Feng Guo , Xiang-Yu Wang , Li-Zhi Xiao , Guo-Wen Jin , Bo-Chuan Jin , Xiao-Long Ju
Continental shale oil reservoirs in China, particularly those of low to medium maturity, contain a high proportion of untransformed solid organic matter (SOM). The SOM plays a critical role as a potential oil and gas resource. Nuclear magnetic resonance (NMR) is a powerful technique for the evaluation of shale oil reservoirs. However, it is challenging for conventional T1-T2 measurement methods to fully capture signals from ultra-short relaxation components such as SOM, due to the measurement deficiency caused by NMR instruments. To this end, the free induction decay (FID) and inversion recovery FID (IR-FID) pulse sequences are introduced, and two novel methods are proposed for quantitative characterization of SOM. The first method, Method I, employs the signal amplitude difference between T2 and T1-T2 spectra to obtain the SOM content. The second, Method II, directly quantifies the SOM signal from the T1-T2 spectrum. A novel parameter, the ratio of T1/T2 to T1/T2, is also proposed to refine the identification of SOM in the T1-T2 spectrum. The effectiveness of the proposed methods is validated by strong correlations with four geochemical parameters indicative of SOM content. The results from Method I show significantly improved correlations with all four geochemical parameters compared to the conventional T1-T2 method. The results from Method II show excellent correlations with parameters from step-by-step (SBS) Rock-Eval pyrolysis, reaching coefficients of determination (R2) as high as 0.8958 and 0.8828. This method also shows strong numerical consistency with the geochemical parameters, specifically with (S1–2b + S2-1+S2-2). Method II is therefore highly suitable for quantitatively evaluating the total solid hydrogen content, including solid petroleum hydrocarbons, bitumen, and kerogen. This work achieves, for the first time, the precise quantification of SOM at the core scale, providing a high-precision, large-scale, and non-destructive approach for evaluating the resource potential of shale oil reservoirs.
中国陆相页岩油储层,特别是中、低成熟度页岩油,其未转化固体有机质(SOM)含量较高。SOM作为一种潜在的油气资源起着至关重要的作用。核磁共振(NMR)技术是页岩油储层评价的有力手段。然而,由于核磁共振仪器的测量缺陷,传统的T1-T2测量方法难以完全捕获来自SOM等超短弛豫组分的信号。为此,引入了自由感应衰减(FID)和反演恢复FID (IR-FID)脉冲序列,并提出了两种定量表征SOM的新方法。第一种方法,方法1,利用T2 *和T1-T2谱之间的信号幅度差来获得SOM含量。第二种,方法II,直接量化来自T1-T2 *频谱的SOM信号。本文还提出了一个新的参数,即T1/T2 *与T1/T2之比,以改进T1-T2光谱中SOM的识别。通过与4个指示SOM含量的地球化学参数的强相关性,验证了该方法的有效性。与传统的T1-T2方法相比,方法1与4个地球化学参数的相关性显著提高。方法二的结果与分步热解(SBS)热解参数具有良好的相关性,决定系数(R2)分别高达0.8958和0.8828。该方法与地球化学参数(S1-2b + S2-1+S2-2)具有较强的数值一致性。因此,方法二非常适合于定量评价固体总氢含量,包括固体石油烃、沥青和干酪根。这项工作首次在岩心尺度上实现了SOM的精确量化,为评估页岩油藏的资源潜力提供了一种高精度、大规模、非破坏性的方法。
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引用次数: 0
Mechanism and influencing factors of electroosmosis-driven residual water drainage in soft coal seams during coalbed methane recovery 煤层气采出过程中软煤层电渗透驱留水机理及影响因素
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-10-25 DOI: 10.1016/j.petsci.2025.10.021
Jun-Qing Guo , Peng-Hui Liu , De-Zhi Sun , Chun-Sheng Lu , Yu-Qing Wang , Wei Li
Soft coal seams with low porosity are prone to water-blocking during mid to late stages of coalbed methane production, reducing gas recovery. To address this, an electroosmosis-driven drainage strategy was proposed in this paper, based on the charged properties of soft coal in water. Three coal ranks (anthracite, coking coal, and long-flame coal) were tested using a custom electroosmotic drainage device. Electrical properties were characterized, and the effects of potential gradients on drainage were analyzed. Fluorescent particle tracing and Fourier-transform infrared spectroscopy were used to explore residual water migration. It is shown that electroosmosis can significantly enhance drainage across all coal ranks. For coking and long-flame coals, drainage increases with voltage before stabilizing; anthracite exhibits peaked at 4 V/cm. The fluorescent tracing reveals water coalescence and migration. Long-flame coal shows best, linked to optimal higher hydroxyl content and electronegativity. Electroosmotic force, governed by pH, hydroxyl content, and field strength, enables directional water transport. Finally, an engineering design is suggested to reduce water-blocking and enhance coalbed methane recovery.
低孔隙度软煤层在煤层气开采中后期容易发生水堵,降低瓦斯采收率。为了解决这一问题,本文提出了一种基于软煤在水中带电特性的电渗透驱动排水策略。使用特制的电渗排水装置对三种煤系(无烟煤、炼焦煤和长焰煤)进行了测试。表征了电学性能,分析了电位梯度对排水的影响。利用荧光粒子示踪和傅里叶变换红外光谱研究了残余水的迁移。结果表明,电渗透能显著提高各煤系的排水性。对于焦化煤和长焰煤,排水量在稳定前随电压增大而增大;无烟煤的峰值为4 V/cm。荧光示踪显示了水的聚并和迁移。长焰煤表现最好,羟基含量和电负性较高。电渗透力由pH值、羟基含量和电场强度控制,可以实现定向水输送。最后提出了减少水堵、提高煤层气采收率的工程设计方案。
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引用次数: 0
A machine learning method for evaluating shale gas production based on the TCN-PgInformer model 基于TCN-PgInformer模型的页岩气产量评估机器学习方法
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-13 DOI: 10.1016/j.petsci.2025.11.022
Hao-Yu Zhang , Wen-Sheng Wu , Zhang-Xin Chen , Benjieming Liu
Since shale gas is a valuable energy resource, effective planning for its extraction and utilization depends on precise forecasting of gas well production. Conventional models need long computation time, a wide range of geological and fluid data, and suffer from unstable predictions. To develop a low-cost, intelligent, and reliable forecast system for shale gas production, a hybrid Temporal Convolutional Network-Policy Gradient Informer (TCN-PgInformer) model was constructed for multivariate production prediction research. This model is based on the Informer model of its own unique self-attention mechanism, which lowers the temporal complexity of conventional self-attention technique while increasing the model’s accuracy. Meanwhile, to completely avoid the gradient vanishing problem, the dilated convolutions of TCN structure are employed to extract the long-term dependency relationships. Ultimately, a policy gradient (Pg) algorithm is introduced to enhance the parameter training speed. The results indicate that the daily gas production may be accurately predicted by TCN-PgInformer model. A detailed performance comparison was carried out among TCN-PgInformer, CNN, GRU and CNN-LSTM models in the literature. The comparison demonstrates that the suggested TCN-PgInformer model outperforms existing techniques. For four different gas production stages, the MAPE/RMSE error of other models is 2–12 times higher than that of the TCN-PgInformer model, while the R2 accuracy of TCN-PgInformer model can be as high as 1 time higher than other models. Therefore, the designed model has excellent applicability, which offers reference and guidance for shale gas development.
由于页岩气是一种宝贵的能源资源,因此对其开采和利用的有效规划取决于对气井产量的精确预测。传统模型计算时间长,地质和流体数据范围广,预测结果不稳定。为了开发低成本、智能、可靠的页岩气产量预测系统,构建了一种混合时间卷积网络策略梯度信息(TCN-PgInformer)模型,用于多变量产量预测研究。该模型基于具有独特自注意机制的Informer模型,降低了传统自注意技术的时间复杂度,同时提高了模型的准确性。同时,为了完全避免梯度消失问题,利用TCN结构的扩张卷积提取长期依赖关系。最后,引入策略梯度(Pg)算法来提高参数的训练速度。结果表明,TCN-PgInformer模型可以较准确地预测天然气日产量。对文献中TCN-PgInformer、CNN、GRU和CNN- lstm模型进行了详细的性能比较。比较表明,提出的TCN-PgInformer模型优于现有的技术。对于4个不同产气阶段,其他模型的MAPE/RMSE误差比TCN-PgInformer模型高2-12倍,而TCN-PgInformer模型的R2精度可高达1倍。因此,所设计的模型具有良好的适用性,可为页岩气开发提供参考和指导。
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引用次数: 0
OFC 离岸金融中心
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2026-03-04 DOI: 10.1016/S1995-8226(26)00058-0
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引用次数: 0
Fracture response patterns in deep to ultra-deep tight sandstones: A comparison based on core and borehole images 深层至超深层致密砂岩裂缝响应模式:基于岩心和井眼图像的比较
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-09-17 DOI: 10.1016/j.petsci.2025.09.021
Yu Du , Hu-Cheng Deng , Xiao-Fei Hu , Hao-Tian Zhang , Hong-Hui Wang , Cui-Li Wang , Mao-Xin Liu , Chen-Yang Zhao , Shang-Rong Guo , Zi-Yun Zheng
Natural fractures serve as the primary storage spaces and flow pathways in deep to ultra-deep tight sandstone reservoirs, directly influencing hydrocarbon accumulation, preservation, and production. Borehole images offer intuitive, continuous, and high-resolution identification of natural fractures along the entire borehole. However, relying solely on complete sinusoidal curves from borehole images for fracture identification may lead to omissions, as it overlooks cases where these curves are incomplete or truncated. To address the problems and deficiencies in fracture identification, this study systematically classifies borehole image feature patterns based on core-to-log spatial position restoring. A bidirectional comparison is conducted between natural fractures in cores and the fracture image features in borehole images. A quantitative relationship between fracture dip angle, thin layer thickness and borehole radius was established, accompanied by a mathematical expression describing the fracture curve morphology was proposed. These findings enabled the development of an imaging response pattern for natural fractures in deep and ultra-deep tight sandstone reservoirs, incorporating key parameters such as dip angle, through-layer connectivity, and spatial position within the borehole. In the Bashijiqike–Baxigai tight-sandstone reservoirs of the Bozi–Dabei area, we estimate that approximately 24% of core-observed fractures display distinct linear-pattern features on borehole images, whereas approximately 91% of borehole images features can be correlated with fractures observed in core. Fracture identification rates for natural fractures increased by 17% in water-based mud and by 3% in oil-based mud through the application of the natural fracture image response pattern. Moreover, this study analyzes the deviations in the matching between core fractures and image features. Finally, we further discuss the common sources of error in natural fracture identification using borehole images from multiple perspectives, including missing core responses, inconsistencies between core and borehole image features, distortion of fracture chord curve, inaccurate fracture count, misclassification of fractures, and variations in interpretation under different mud systems. The research addresses the blind spots of traditional methods in fracture identification within thin layers, not only enhancing the detection rate of natural fractures but also further improving the accuracy of fracture recognition. At the same time, it will contribute to the optimization of fracture characterization, reservoir evaluation, and production forecasting, providing a more reliable data foundation for exploration and development under complex geological conditions.
天然裂缝是深层至超深层致密砂岩储层的主要储集空间和流动通道,直接影响油气的聚集、保存和生产。井眼图像可以直观、连续、高分辨率地识别整个井眼的天然裂缝。然而,仅仅依靠井眼图像中的完整正弦曲线来识别裂缝可能会导致遗漏,因为它忽略了这些曲线不完整或截断的情况。针对裂缝识别中存在的问题和不足,本研究基于岩心-测井空间位置恢复对井眼图像特征模式进行了系统分类。将岩心中的天然裂缝与井眼图像中的裂缝图像特征进行双向比较。建立了裂缝倾角、薄层厚度和井眼半径之间的定量关系,并提出了描述裂缝曲线形态的数学表达式。这些发现有助于开发深层和超深层致密砂岩储层天然裂缝的成像响应模式,包括倾角、层间连通性和井内空间位置等关键参数。在渤子—大北地区巴什基奇克—巴西盖致密砂岩储层中,约24%的岩心观测裂缝在钻孔图像上表现出明显的线性特征,约91%的钻孔图像特征与岩心观测裂缝具有相关性。通过应用天然裂缝图像响应模式,在水基泥浆中对天然裂缝的识别率提高了17%,在油基泥浆中提高了3%。此外,本文还分析了岩心裂缝与图像特征匹配的偏差。最后,我们进一步讨论了多角度井眼图像识别天然裂缝的常见误差来源,包括岩心响应缺失、岩心与井眼图像特征不一致、裂缝弦曲线失真、裂缝计数不准确、裂缝分类错误以及不同泥浆体系下解释的差异。该研究解决了传统方法在薄层裂缝识别中的盲点,既提高了天然裂缝的检出率,又进一步提高了裂缝识别的准确性。同时有助于裂缝表征、储层评价和产量预测的优化,为复杂地质条件下的勘探开发提供更可靠的数据基础。
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引用次数: 0
Geochemical characteristics and sources of natural gas in the Upper Paleozoic limestone strata, Ordos Basin 鄂尔多斯盆地上古生界灰岩地层地球化学特征及天然气来源
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-10-17 DOI: 10.1016/j.petsci.2025.10.008
Wen Zhang , Qian-Ping Wang , Wen-Hui Liu , Ping-Ping Shi , Hou-Yong Luo , Peng Liu , Xiao-Yan Chen , Qian Zhang , Xiao-Feng Wang , Dong-Dong Zhang , Yi-Ran Wang , Fu-Qi Li
The discovery of high-yield industrial gas flows in the limestone layer of the Permian Taiyuan Formation in the Ordos Basin highlights promising prospects for natural gas exploration and has positioned this region as a key exploration area. However, research on the origin and distribution of natural gas in the Taiyuan Limestone Formation, especially its hydrocarbon generation potential and whether these organically enriched limestones can serve as effective source rocks, remains limited. In this study, we aimed to analyse the composition and carbon isotopes of the Upper Palaeozoic Taiyuan Limestone Formation natural gas, including propane-specific isotopes. The isotopic data were compared with coal-type gases from the corresponding strata and oil-type gases from the Lower Palaeozoic carbonate strata. Natural gas in the Upper Palaeozoic Taiyuan Limestone Formation was markedly distinct from the ‘self-generated and self-accumulated’ oil-type gas in the Lower Palaeozoic subsalt strata, indicating no obvious correlation between the two gases. The results did not support the notion that large-scale natural gas accumulations in the Lower Palaeozoic carbonate formations could be originated from Upper Palaeozoic limestone source rocks. The natural gas in the Upper Palaeozoic Taiyuan Limestone Formation was highly consistent with the typical coal-type gas from the Upper Paleozoic. The geochemical characteristics of the natural gas in the region were consistent with that of conventional natural gas, the position-specific isotopic composition of propane ΔC−T values had a narrow, positive. This showed that the gas in the Taiyuan Limestone Formation was derived from type III kerogen, and propane mainly generated through the n-C3H7 free radical pathway. Geochemical analyses of the Taiyuan Limestone source rocks, such as the determination of total organic carbon, kerogen carbon isotopes, organic macerals. Combined with the geochemical analysis of natural gas, it revealed low abundance of organic matter but good kerogen types, predominantly type II–III, at a late to high-maturity evolution stage. Although the formation had certain hydrocarbon generation potential, it falls short of the hydrocarbon generation capacity of the Carboniferous–Permian coal measure source rocks. At present, there is no large–scale hydrocarbon generation, and it is not enough to provide hydrocarbon for the Lower Paleozoic.
鄂尔多斯盆地二叠系太原组灰岩中高产工业气流的发现,凸显了天然气勘探的良好前景,将该地区定位为重点勘探区。然而,对于太原灰岩组天然气的成因和分布,特别是其生烃潜力以及这些有机富集灰岩能否作为有效烃源岩的研究仍然有限。本研究旨在分析上古生界太原灰岩组天然气的组成和碳同位素,包括丙烷同位素。将同位素资料与相应地层的煤型气和下古生代碳酸盐岩的油型气进行了对比。上古生界太原灰岩组天然气与下古生界盐下地层“自生自聚集”的油型天然气明显不同,两者之间没有明显的相关性。研究结果不支持下古生界碳酸盐岩地层大规模天然气聚集来源于上古生界灰岩烃源岩的观点。上古生界太原灰岩组天然气与典型的上古生界煤型气高度一致。该区天然气地球化学特征与常规天然气基本一致,丙烷的位置同位素组成ΔC−T值呈窄正。说明太原灰岩组天然气主要来源于ⅲ型干酪根,丙烷主要通过n-C3H7自由基途径生成。对太原灰岩烃源岩进行了地球化学分析,包括总有机碳、干酪根碳同位素、有机显微组分的测定。结合天然气地球化学分析,该区有机质丰度较低,干酪根类型较好,处于晚至高成熟演化阶段,以II-III型为主。虽然具有一定的生烃潜力,但与石炭系—二叠系煤系烃源岩的生烃能力相比尚有差距。目前尚无大规模生烃活动,不足以为下古生界提供油气。
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Petroleum Science
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