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Experimental study of reservoir damage of water-based fracturing fluids prepared by different polymers 不同聚合物制备的水基压裂液对储层损害的实验研究
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.06.001
Fracturing operations can effectively improve the production of low-permeable reservoirs. The performance of fracturing fluids directly affects the fracturing efficiency and back flow capacity. As polymer-based fracturing fluids (such as guar gum (GG), polyacrylamide (HPAM), etc.) are high-viscosity fluids formed by viscosifiers and crosslinking agents, the degree of gel breakage after the fracturing operation directly influences the damage degree to the reservoir matrix and the mobility of oil angd gas produced from the reservoir into the wellbore. This study compared the viscosity, molecular weight, and particle size of the fracturing fluid after gel breakage prepared by GG and HPAM as viscosifiers, as well as evaluate their damage to the core. Results show that the viscosities of the gel-breaking fluid increased with the concentration of the viscosifier for both the HPAM-based and GG-based fracturing fluids. For the breaking fluid with the same viscosity, the molecular weight in the HPAM-based gel-breaking fluid was much larger than that in the GG-based system. Moreover, for the gel-breaking fluid with the same viscosity, the molecular particle size of the residual polymers in the HPAM-based system was smaller than that in the GG-based system. The damage to the core with the permeability of 1 × 10−3 μm2 caused by both the HPAM-based and GG-based gel-breaking fluids decreased with the increase in the solution viscosity. For the gel-breaking fluid systems with the same viscosity (i.e., 2–4 mPa s), the damage of HPAM-based fracturing fluid to low-permeability cores was greater than the GG-based fracturing fluid (45.6%–80.2%) since it had a smaller molecular particle size, ranging from 66.2% to 77.0%. This paper proposed that the damage caused by hydraulic fracturing in rock cores was related to the partilce size of residual polymers in gel-breaking solution, rather than its molecular weight. It was helpful for screening and optimizing viscosifiers used in hydraulic fracturing process.
压裂作业可以有效提高低渗透储层的产量。压裂液的性能直接影响压裂效率和回流能力。由于聚合物型压裂液(如瓜尔胶(GG)、聚丙烯酰胺(HPAM)等)是由增粘剂和交联剂形成的高粘度流体,压裂作业后凝胶的破碎程度直接影响对储层基质的破坏程度以及从储层产出的油气进入井筒的流动性。本研究比较了以 GG 和 HPAM 为增粘剂制备的压裂液破胶后的粘度、分子量和粒径,并评估了它们对岩心的损害程度。结果表明,无论是基于 HPAM 还是基于 GG 的压裂液,凝胶破裂液的粘度都随着增粘剂浓度的增加而增加。对于粘度相同的压裂液,HPAM 基凝胶压裂液的分子量远大于 GG 基体系。此外,在相同粘度的凝胶破裂液中,HPAM 基体系中残留聚合物的分子粒径小于 GG 基体系。随着溶液粘度的增加,HPAM 型和 GG 型凝胶破坏液对渗透率为 1 × 10-3 μm2 的岩心造成的破坏都有所减少。在粘度相同(即 2-4 mPa s)的凝胶破胶液体系中,由于 HPAM 型压裂液的分子粒径较小,其对低渗透率岩心的破坏程度(45.6%-80.2%)大于 GG 型压裂液(66.2%-77.0%)。本文提出,水力压裂对岩心的破坏与凝胶破裂溶液中残留聚合物的粒径有关,而不是与其分子量有关。这有助于筛选和优化水力压裂工艺中使用的增粘剂。
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引用次数: 0
The impact of industrial transformation on green economic efficiency: New evidence based on energy use 工业转型对绿色经济效率的影响:基于能源使用的新证据
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-10-01 DOI: 10.1016/j.petsci.2024.03.004
Developing a green economy is key to achieving the 2030 Sustainable Development Goals. This paper uses the SBM-GML index, which includes non-desired outputs, to measure the trend of regional green economic efficiency changes and analyze the impact mechanism and realization path of industrial transformation on green economic efficiency. The research results show that advanced industrial structure has a positive influence on green economic efficiency nationwide, while energy utilization structure and energy utilization efficiency have positive partial intermediary effects in the influence path; industrial structure rationalization is also significantly positively related to green economic efficiency nationwide, and the mediating effect of energy utilization is positive. The impact of industrial transformation on green economic efficiency has regional heterogeneity, and the mediating effect of energy use also differs. Among them, the impact effect in the eastern region is basically consistent with the national sample, but is negative in the central and western regions. This paper proposes countermeasures in terms of adjusting the industrial structure, improving energy efficiency, and perfecting industrial and energy policies, which can provide theoretical and practical references for promoting the transformation and upgrading of regional industrial structure, optimizing energy utilization, and advancing the efficiency of the national and regional green economy.
发展绿色经济是实现 2030 年可持续发展目标的关键。本文利用包含非期望产出的SBM-GML指数测算区域绿色经济效率变化趋势,分析产业转型对绿色经济效率的影响机理和实现路径。研究结果表明,产业结构高级化对全国绿色经济效率具有正向影响,能源利用结构和能源利用效率在影响路径中具有正向部分中介效应;产业结构合理化与全国绿色经济效率也显著正相关,能源利用的中介效应为正。产业转型对绿色经济效益的影响具有区域异质性,能源利用的中介效应也存在差异。其中,东部地区的影响效应与全国样本基本一致,但中西部地区为负。本文从调整产业结构、提高能源利用效率、完善产业和能源政策等方面提出了对策建议,可为促进区域产业结构转型升级、优化能源利用、提升国家和区域绿色经济效率提供理论和实践参考。
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引用次数: 0
Mobilization of tight oil by spontaneous imbibition of surfactants 通过表面活性剂的自发浸润开采致密油
IF 5.6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-29 DOI: 10.1016/j.petsci.2024.08.010
Ming-Chen Ding, Xin-Fang Xue, Ye-Fei Wang, Chu-Han Zhang, Shi-Ze Qiu
A series of spontaneous imbibition (SI) tests of tight oil were performed, together with oil distribution scans by computed tomography (CT) and nuclear magnetic resonance (NMR). Thus, the best surfactants to optimize the SI effect were obtained, the basic requirements to surfactants for efficient SI were determined, and the oil mobilization by SI revealed. The results show that anionic surfactants significantly outperform non-ionic, cationic, and zwitterionic ones in SI process. Excellent systems can be further obtained by mixing anionic surfactants with others (e.g. 1:1 mixtures of AES:EHSB). The requirements to interfacial properties of surfactants for achieving efficient SI at permeabilities of 0.05, 0.5, and 5.0 mD are: 10 mN/m, < 40°; 10–10 mN/m, < 55°; and 10–10 mN/m, < 70°, respectively. Although a high oil recovery of 38.5% by SI was achieved in small cylindrical cores (2.5 cm × 3.0 cm), the joint SI and CT tests in larger, cube-shaped cores (5.0 cm × 5.0 cm × 5.0 cm) showed that the SI process could only remove the oil from the outermost few millimeters of the cores with permeabilities of 0.05 and 0.1 mD, indicating the great difficulty encountered for their development. The NMR showed that the SI treatment preferentially removed oil from smaller pores rather than medium or large pores.
对致密油进行了一系列自发浸润(SI)试验,并通过计算机断层扫描(CT)和核磁共振(NMR)对油分布进行了扫描。因此,获得了优化 SI 效果的最佳表面活性剂,确定了高效 SI 对表面活性剂的基本要求,并揭示了 SI 的石油动用情况。结果表明,阴离子表面活性剂在 SI 过程中的表现明显优于非离子、阳离子和齐聚物表面活性剂。通过将阴离子表面活性剂与其他表面活性剂混合(如 AES:EHSB 的 1:1 混合物),可进一步获得优异的体系。在渗透率为 0.05、0.5 和 5.0 mD 时,要实现高效的 SI,对表面活性剂界面特性的要求如下:分别为 10 mN/m,< 40°;10-10 mN/m,< 55°;10-10 mN/m,< 70°。虽然在小型圆柱形岩芯(2.5 厘米 × 3.0 厘米)中,SI 工艺的石油采收率高达 38.5%,但在大型立方体岩芯(5.0 厘米 × 5.0 厘米 × 5.0 厘米)中进行的 SI 和 CT 联合试验表明,SI 工艺只能清除渗透率为 0.05 和 0.1 mD 的岩芯最外层几毫米的石油,这表明其开发遇到了很大困难。核磁共振显示,SI 处理更倾向于清除较小孔隙中的油,而不是中孔或大孔隙中的油。
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引用次数: 0
Multi-fracture growth behavior during TPDF in a horizontal well of multi-clustered perforations: An experimental research 多簇射孔水平井 TPDF 过程中的多裂缝生长行为:实验研究
IF 5.6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-21 DOI: 10.1016/j.petsci.2024.08.003
Yu-Shi Zou, Can Yang, Shi-Cheng Zhang, Xin-Fang Ma, Yan-Chao Li, Long-Qing Zou
Temporary plugging and diverting fracturing (TPDF), involving inner-fracture temporary plugging (IFTP) and inner-stage temporary plugging (ISTP), has been proposed as a widely applied technique in China, for promoting the uniform initiation and propagation of multi-clustered hydraulic fractures (HFs) in a horizontal well of the shale oil/gas reservoirs. However, how the key plugging parameters controlling the multi-fracture growth and the pumping pressure response during TPDF in shale with dense bedding planes (BPs) and natural fractures (NFs) is still unclear, which limits the optimization of TPDF scheme. In this paper, a series of TPDF simulation experiments within a stage of multi-cluster in a horizontal well were carried out on outcrops of Longmaxi Formation shale using a large-scale true tri-axial fracturing simulation system, combined with the acoustic emission (AE) monitor and computed tomography (CT) scanning techniques. Each experiment was divided into three stages, including the conventional fracturing (CF), IFTP and ISTP. Multi-fracture initiation and propagation behavior, and the dominant controlling parameters were examined, containing the particle sizes, concentration of temporary plugging agent (TPA), and cluster number. The results showed that the number of transverse HFs (THFs) and the overall complexity of fracture morphology increase with the increase in TPA concentration and perforation cluster number. Obviously, the required concentration of TPA is positively correlated with the cluster number. Higher peak values and continuous fluctuations of pumping pressure during TPDF may indicate the creation of diversion fractures. The creation of standard THFs during CF is favorable to the creation of diversion fractures during TPDF. Moreover, the activation of BPs nearby the wellbore during CF is unfavorable to the subsequent pressure buildup during TPDF, resulting in poor plugging and diverting effect. Notably, under the strike-slip fault stress regime, the diversion of THFs is not likely during IFTP, which is similar as the results of ISTP to initiate mainly the un-initiated or under-propagated perforation clusters. Three typical pressure curve types during TPDF can be summarized to briefly identify the hydraulic fracture diversion effects, including good (multiple branches or/and THFs can be newly created), fair (HF initiation along the slightly opened BPs and then activating the NFs), and bad (HF initiation along the largely opened BPs and then connecting with the NFs).
临时封堵与分流压裂(TPDF)包括内部裂缝临时封堵(IFTP)和内部阶段临时封堵(ISTP),是一种在中国广泛应用的技术,用于促进页岩油气藏水平井中多簇水力裂缝(HFs)的均匀萌发和传播。然而,在具有致密基底面(BPs)和天然裂缝(NFs)的页岩中,TPDF过程中如何控制多裂缝生长和泵压响应的关键堵塞参数仍不清楚,这限制了TPDF方案的优化。本文利用大型真实三轴压裂模拟系统,结合声发射(AE)监测和计算机断层扫描(CT)技术,在龙马溪地层页岩露头进行了一系列水平井多簇阶段TPDF模拟实验。每次实验分为三个阶段,包括常规压裂(CF)、IFTP 和 ISTP。研究了多重压裂的起始和扩展行为,以及主要的控制参数,包括颗粒尺寸、暂堵剂(TPA)浓度和集束数。结果表明,随着 TPA 浓度和穿孔簇数的增加,横向高频(THF)的数量和断口形态的整体复杂性也随之增加。显然,所需的 TPA 浓度与簇数呈正相关。TPDF期间较高的峰值和持续波动的泵压可能表明产生了分流裂缝。CF期间标准THF的形成有利于TPDF期间分流裂缝的形成。此外,CF期间井筒附近BPs的激活不利于TPDF期间的后续压力积累,导致堵塞和分流效果不佳。值得注意的是,在走向-滑动断层应力机制下,IFTP期间THFs的分流可能性不大,这与ISTP主要启动未启动或未充分推进的射孔群的结果类似。在 TPDF 过程中,可以总结出三种典型的压力曲线类型,以简要识别水力压裂分流效果,包括良好(可以新产生多个分支或/和 THF)、一般(沿轻微打开的 BPs 启动高频,然后激活 NFs)和不良(沿基本打开的 BPs 启动高频,然后与 NFs 连接)。
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引用次数: 0
Investigation of interaction behavior between hydraulic fractures and gravels in heterogeneous glutenite using a grain-based discrete element method 利用基于晶粒的离散元方法研究异质糯米岩中水力断裂与砾石之间的相互作用行为
IF 5.6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-17 DOI: 10.1016/j.petsci.2024.08.004
Zhao-Peng Zhang, Yu-Shi Zou, Hai-Yan Zhu, Shi-Cheng Zhang
The glutenite reservoir is strongly heterogeneous due to the random distribution of gravels, making it challenging to perform hydraulic fracturing effectively. To solve this issue, it is essential to study interaction behavior between hydraulic fractures (HFs) and gravels. A coupled hydro-mechanical model is proposed for HF propagation in glutenite using a grain-based discrete element method. This paper first investigates the dynamic evolution of HFs in glutenite, then analyzes the influences of various factors such as horizontal stress difference (Δ), minimum horizontal stress (), gravel content (), gravel size (), and stiffness ratio of gravel to matrix () on HF propagation geometries. Results show that penetrating the gravel is the primary HF-gravel interaction behavior, which follows sequential and staggered initiation modes. Bypassing the gravel is the secondary behavior, which obeys the sequential initiation mode and occurs when the orientation of the gravel boundary is inclined to the maximum horizontal stress (). An offset along the gravel boundary is usually formed while penetrating gravels, and the offsets may cause fracture widths to decrease by 37.8%–84.4%. Even if stress dominates the direction of HF propagation, HFs still tend to deflect within gravels. The deviation angle from decreases with rising Δ and increases with the increase of and . Additionally, intra-gravel shear HFs (IGS-HFs) are prone to be generated in coarse-grained glutenite under high Δ, while more gravel-bypassing shear HFs (GBS-HFs) tend to be created in argillaceous glutenite with high than in sandy glutenite with low . The findings above prompt the emergence of a novel HF propagation pattern in glutenite, which helps to understand the real HF geometries and to provide theoretical guidance for treatments in the field.
由于砾石的随机分布,糯米质储层具有很强的异质性,这给有效实施水力压裂带来了挑战。要解决这一问题,必须研究水力压裂(HF)与砾石之间的相互作用行为。本文采用基于晶粒的离散元方法,针对高频在砾岩中的传播提出了一种水力机械耦合模型。本文首先研究了高频在谷朊岩中的动态演化,然后分析了水平应力差(Δ)、最小水平应力()、砾石含量()、砾石粒度()以及砾石与基质的刚度比()等各种因素对高频传播几何形状的影响。结果表明,穿透砾石是高频与砾石相互作用的主要行为,遵循顺序和交错起始模式。绕过砾石是次要行为,遵循顺序启动模式,发生在砾石边界方向与最大水平应力()倾斜时。在穿透砾石时,通常会沿着砾石边界形成偏移,偏移可能导致断裂宽度减少 37.8%-84.4%。即使应力主导高频的传播方向,高频在砾石内部仍有偏移的趋势。与 Δ 的偏角随着 Δ 的增大而减小,并随着 Δ 和 Δ 的增大而增大。此外,在高Δ条件下,粗粒谷维岩中容易产生砾石内剪切高频(IGS-HFs),而在高Δ条件下,砾石绕过剪切高频(GBS-HFs)往往多于低Δ条件下的砂质谷维岩。上述发现提示了一种新的高频传播模式,有助于理解真实的高频几何形状,并为现场处理提供理论指导。
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引用次数: 0
Production decline curve analysis of shale oil wells: A case study of Bakken, Eagle Ford and Permian 页岩油井产量下降曲线分析:巴肯、鹰滩和二叠纪案例研究
IF 5.6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-07 DOI: 10.1016/j.petsci.2024.07.029
Hui-Ying Tang, Ge He, Ying-Ying Ni, Da Huo, Yu-Long Zhao, Liang Xue, Lie-Hui Zhang
The shale revolution has turned the United States from an oil importer into an oil exporter. The success of shale oil production in the U.S. has inspired many countries, including China, to begin the exploitation and development of shale oil resources. In this study, the production curves of over 30,000 shale oil wells in the Bakken, Eagle Ford (EF), and Permian are systematically analyzed to provide reference and guidance for future shale oil development. To find out the most suitable decline curve models for shale oil wells, fifteen models and a new fitting method are tested on wells with production history over 6 years. Interestingly, all basins show similar results despite of their varieties in geological conditions: stretched exponential production decline (SEPD) + Arps model provides most accurate prediction of estimated ultimate recovery (EUR) for wells with over 2 years' production, while the Arps model can be used before the two years’ switch point. With the EUR calculated by decline curve analysis, we further construct simple regression models for different basins to predict the EUR quickly and early. This work helps us better understand the production of shale oil wells, as well as provide important suggestions for the choices of models for shale oil production prediction.
页岩革命使美国从石油进口国变成了石油出口国。美国页岩油生产的成功激励了包括中国在内的许多国家开始开采和开发页岩油资源。本研究系统分析了巴肯(Bakken)、老鹰福特(EF)和二叠纪(Permian)3 万多口页岩油井的产量曲线,为未来页岩油开发提供参考和指导。为了找出最适合页岩油井的递减曲线模型,对生产历史超过 6 年的油井测试了 15 个模型和一种新的拟合方法。有趣的是,尽管地质条件各不相同,但所有盆地都显示出相似的结果:拉伸指数产量递减(SEPD)+ Arps 模型能最准确地预测生产超过两年的油井的估计最终采收率(EUR),而 Arps 模型可在两年转换点之前使用。利用递减曲线分析计算出的最终采收率,我们进一步构建了不同盆地的简单回归模型,以快速、尽早地预测最终采收率。这项工作有助于我们更好地理解页岩油井的产量,并为页岩油产量预测模型的选择提供重要建议。
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引用次数: 0
Exploring the impact of economic growth and energy consumption on SO2 emissions in China based on the Environmental Kuznets Curve hypothesis 基于环境库兹涅茨曲线假说探讨中国经济增长和能源消耗对二氧化硫排放的影响
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.01.019

This study aims to analysis the influence of economic growth (EG) and energy consumption (EC) on sulfur dioxide emissions (SE) in China. Accordingly, this study explores the link between EG, EC, and SE for 30 provinces in China over the span of 2000–2019. This study also analyzes cross-sectional dependence tests, panel unit root tests, Westerlund panel cointegration tests, Dumitrescu-Hurlin (D-H) causality tests. According to the test results, there is an inverted U-shaped association between EG and SE, and the assumption of the Environmental Kuznets Curve (EKC) is verified. The signs of EG and EC in the fixed effect (FE) and random effect (RE) methods are in line with those in the dynamic ordinary least squares (DOLS), fully modified ordinary least squares (FMOLS) and autoregressive distributed lag (ARDL) estimators. Moreover, the results verified that EC can obviously positive impact the SE. To reduce SE in China, government and policymakers can improve air quality by developing cleaner energy sources and improving energy efficiency. This requires the comprehensive use of policies, regulations, economic incentives, and public participation to promote sustainable development.

本研究旨在分析中国经济增长(EG)和能源消耗(EC)对二氧化硫排放(SE)的影响。因此,本研究探讨了 2000-2019 年间中国 30 个省份的经济增长、能源消耗和二氧化硫排放之间的联系。本研究还分析了截面依存检验、面板单位根检验、Westerlund 面板协整检验、Dumitrescu-Hurlin(D-H)因果检验。检验结果表明,EG 与 SE 之间存在倒 U 型关联,验证了环境库兹涅茨曲线(EKC)假设。在固定效应(FE)和随机效应(RE)方法中,EG 和 EC 的符号与 DOLS、FMOLS 和 ARDL 估计中的符号一致。此外,结果还验证了 EC 对 SE 有明显的正向影响。为了降低中国的 SE,政府和政策制定者可以通过发展清洁能源和提高能源效率来改善空气质量。这需要综合运用政策、法规、经济激励和公众参与等手段,促进可持续发展。
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引用次数: 0
Research progress on micro-force measurement of a hydrate particle system 水合物颗粒系统微力测量的研究进展
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.017

It remains a great challenge to understand the hydrates involved in phenomena in practical oil and gas systems. The adhesion forces between hydrate particles, between hydrate particles and pipe walls, and between hydrate particles and reservoir particles are essential factors that control the behaviors of clathrate hydrates in different applications. In this review, we summarize the typical micro-force measurement apparatus and methods utilized to study hydrate particle systems. In addition, the adhesion test results, the related understandings, and the applied numerical calculation models are systematically discussed.

了解实际油气系统中的水合物现象仍然是一项巨大的挑战。水合物颗粒之间、水合物颗粒与管壁之间以及水合物颗粒与储层颗粒之间的粘附力是控制不同应用中凝结水合物行为的重要因素。在本综述中,我们总结了用于研究水合物颗粒系统的典型微力测量仪器和方法。此外,还系统讨论了粘附测试结果、相关理解和应用的数值计算模型。
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引用次数: 0
Sand control mechanism of radial well filled with phase change material in hydrate reservoir 水合物储层中充填相变材料的径向井的防砂机制
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.04.008

Radial well filled with phase change material has been proposed as a novel sand control method for hydrate exploitation. In order to reveal the sand control mechanism, CFD-DEM coupling method is applied to simulate the migration, settlement, and blockage processes of sand particles in the radial well. The obtained results indicate that three scenarios have been recognized for sand particles passing through sand control medium, based on the diameter ratio of sand control medium to sand particle (Dd): fully passing (Dd = 8.75–22.5), partially passing and partially blocked (Dd = 3.18–5.63), and completely blocked (Dd = 2.18–3.21). After being captured by the sand control medium, sand particles can block pores, which increases fluid flow resistance and causes a certain pressure difference in the radial well. The pressure in the radial well should be lower than the hydrate phase equilibrium pressure during sand control design, for the purpose of promoting hydrate decomposition, and sand capture. The length of the radial well should be optimized based on the reservoir pore pressure, production pressure difference, bottom hole pressure, and the pressure gradient in the radial well. It should be noticed that the sand control medium leads to a decrease in permeability after sand particles captured. Even the permeability is reduced to several hundred millidarcy, it is still sufficient to ensure the effective flow of gas and water after hydrate decomposition. Increasing fluid velocity reduces the blocking capacity of the sand control medium, mainly because of deterioration in bridging between sand particles.

有人提出用相变材料填充径向井作为一种新型水合物开采防砂方法。为了揭示防砂机理,采用 CFD-DEM 耦合方法模拟了砂粒在径向井中的迁移、沉降和堵塞过程。结果表明,根据控砂介质与砂粒的直径比(Dd),砂粒通过控砂介质时有三种情况:完全通过(Dd = 8.75-22.5)、部分通过和部分堵塞(Dd = 3.18-5.63)以及完全堵塞(Dd = 2.18-3.21)。砂粒被防砂介质捕获后,会堵塞孔隙,增加流体流动阻力,并在径向井中造成一定的压力差。在防砂设计时,径向井内的压力应低于水合物相平衡压力,以促进水合物分解和砂粒捕获。径向井的长度应根据储层孔隙压力、生产压差、井底压力以及径向井的压力梯度进行优化。需要注意的是,防砂介质在捕获砂粒后会导致渗透率下降。即使渗透率降低到几百毫达西,也足以保证水合物分解后气体和水的有效流动。流体速度的增加会降低防砂介质的阻塞能力,这主要是因为砂粒之间的桥接作用减弱。
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引用次数: 0
Natural rubber latex as a potential additive for water-based drilling fluids 作为水基钻井液潜在添加剂的天然胶乳
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.04.012

The environmental hazards and "carbon footprint" of oil and gas drilling can be significantly reduced by replacing traditional petroleum-based chemical additives with natural materials derived from plants and animals. This paper explored for the first time the interaction mechanism between natural rubber latex (NRL) and bentonite suspensions (BTs) through a series of characterization experiments, as well as the potential applications in water-based drilling fluids (WBDF). The gel viscoelasticity experiments showed that NRL could decrease the consistency coefficient (k) and flow index (n) of BTs, and enhance the shear thinning performance of BTs as pseudo-plastic fluids. In addition, 0.5 w/v% NRL not only increased the critical yield stress and strengthened the structural strength between the bentonite particles, but also facilitated the compatibility of pressure loss and flow efficiency. The evaluation of colloidal stability and WBDF performance indicated that NRL particles could promote the hydration and charge stability on the surface of BTs particles, and optimize the particle size distribution and flow resistance of WBDF under the "intercalation-exfoliation-encapsulation" synergistic interaction. Moreover, NRL can improve the rheological properties of WBDF at high temperatures (<150 °C), and form a dense blocking layer by bridging and sealing the pores and cracks of the filter cake, which ultimately reduces the permeability of the cake and the filtration loss of WBDF.

用动植物提取的天然材料取代传统的石油基化学添加剂,可以大大减少石油和天然气钻井对环境的危害和 "碳足迹"。本文通过一系列表征实验,首次探讨了天然胶乳(NRL)与膨润土悬浮液(BTs)之间的相互作用机理,以及在水基钻井液(WBDF)中的潜在应用。凝胶粘弹性实验表明,NRL 可以降低 BTs 的稠度系数()和流动指数(),并增强 BTs 作为假塑性流体的剪切稀化性能。此外,0.5 w/v% 的 NRL 不仅能提高临界屈服应力,增强膨润土颗粒间的结构强度,还能促进压力损失和流动效率的相容性。胶体稳定性和 WBDF 性能评价表明,NRL 颗粒可促进 BTs 颗粒表面的水化和电荷稳定性,在 "插层-剥离-包封 "协同作用下优化 WBDF 的粒度分布和流动阻力。此外,NRL 还能改善 WBDF 在高温(<150 ℃)下的流变特性,并通过桥接和密封滤饼的孔隙和裂缝形成致密的阻挡层,最终降低滤饼的渗透性和 WBDF 的过滤损耗。
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