首页 > 最新文献

Petroleum Science最新文献

英文 中文
OFC OFC
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/S1995-8226(24)00214-0
{"title":"OFC","authors":"","doi":"10.1016/S1995-8226(24)00214-0","DOIUrl":"10.1016/S1995-8226(24)00214-0","url":null,"abstract":"","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Page OFC"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624002140/pdfft?md5=8fd7feac2f44ae86b26214a3b8217ed0&pid=1-s2.0-S1995822624002140-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142050061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs 大陆页岩油藏原位转换中的流体生产数值评估
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.05.025

In-situ conversion presents a promising technique for exploiting continental oil shale formations, characterized by highly fractured organic-rich rock. A 3D in-situ conversion model, which incorporates a discrete fracture network, is developed using a self-developed thermal-flow-chemical (TFC) simulator. Analysis of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages. The findings indicate that kerogen decomposition increases fluid pressure, activating fractures and subsequently enhancing permeability. A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes, highlighting that increasing heating power correlates with higher cumulative fluid production. Activated fractures, with heightened permeability, facilitate the mobility of heavy oil toward production wells but hinder its cracking, thereby limiting light hydrocarbon production. Additionally, energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization, especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating.

原位转换技术是开发大陆油页岩地层的一项前景广阔的技术,该地层的特点是富含有机质的岩石断裂程度高。利用自主开发的热-流-化学(TFC)模拟器,开发了一个包含离散断裂网络的三维原位转换模型。对模型的分析阐明了原位转化过程的三个阶段,并根据流体的最终阶段将流体转化为三种不同的结果。研究结果表明,角质分解会增加流体压力,激活裂缝,进而提高渗透率。对活化裂缝渗透率和加热功率的综合分析揭示了四种不同的生产模式,突出表明加热功率的增加与更高的累积流体产量相关。活化裂缝具有更高的渗透性,有利于重油向生产井流动,但阻碍了重油的裂解,从而限制了轻烃的生产。此外,能效研究证明了就地转换在能源利用方面的可行性,特别是在考虑利用风能和太阳能等高波动能源的剩余能量提供加热时。
{"title":"Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs","authors":"","doi":"10.1016/j.petsci.2024.05.025","DOIUrl":"10.1016/j.petsci.2024.05.025","url":null,"abstract":"<div><p>In-situ conversion presents a promising technique for exploiting continental oil shale formations, characterized by highly fractured organic-rich rock. A 3D in-situ conversion model, which incorporates a discrete fracture network, is developed using a self-developed thermal-flow-chemical (TFC) simulator. Analysis of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages. The findings indicate that kerogen decomposition increases fluid pressure, activating fractures and subsequently enhancing permeability. A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes, highlighting that increasing heating power correlates with higher cumulative fluid production. Activated fractures, with heightened permeability, facilitate the mobility of heavy oil toward production wells but hinder its cracking, thereby limiting light hydrocarbon production. Additionally, energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization, especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2485-2501"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624001559/pdfft?md5=e077223e7565e5f6acb7baa64ab3d660&pid=1-s2.0-S1995822624001559-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141512036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Overview of computation strategies on the dispersion analysis for explicit finite difference solution of acoustic wave equation 声波方程显式有限差分解法频散分析计算策略概述
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.02.003

Finite-difference (FD) method is the most extensively employed numerical modeling technique. Nevertheless, when using the FD method to simulate the seismic wave propagation, the large spatial or temporal sampling interval can lead to dispersion errors and numerical instability. In the FD scheme, the key factor in determining both dispersion errors and stability is the selection of the FD weights. Thus, How to obtain appropriate FD weights to guarantee a stable numerical modeling process with minimum dispersion error is critical. The FD weights computation strategies can be classified into three types based on different computational ideologies, window function strategy, optimization strategy, and Taylor expansion strategy. In this paper, we provide a comprehensive overview of these three strategies by presenting their fundamental theories. We conduct a set of comparative analyses of their strengths and weaknesses through various analysis tests and numerical modelings. According to these comparisons, we provide two potential research directions of this field: Firstly, the development of a computational strategy for FD weights that enhances stability; Secondly, obtaining FD weights that exhibit a wide bandwidth while minimizing dispersion errors.

有限差分法(FD)是应用最广泛的数值建模技术。然而,在使用有限差分法模拟地震波传播时,较大的空间或时间采样间隔可能会导致频散误差和数值不稳定性。在 FD 方案中,决定频散误差和稳定性的关键因素是 FD 权重的选择。因此,如何获得合适的 FD 权重,以保证数值建模过程稳定且离散误差最小至关重要。根据计算思想的不同,FD 权重计算策略可分为三类:窗函数策略、优化策略和泰勒展开策略。本文通过介绍这三种策略的基本理论,对其进行了全面概述。我们通过各种分析测试和数值建模对它们的优缺点进行了比较分析。根据这些比较,我们提出了该领域的两个潜在研究方向:首先,开发一种能增强稳定性的 FD 权重计算策略;其次,获得既能展现宽带宽又能最大限度减少分散误差的 FD 权重。
{"title":"Overview of computation strategies on the dispersion analysis for explicit finite difference solution of acoustic wave equation","authors":"","doi":"10.1016/j.petsci.2024.02.003","DOIUrl":"10.1016/j.petsci.2024.02.003","url":null,"abstract":"<div><p>Finite-difference (FD) method is the most extensively employed numerical modeling technique. Nevertheless, when using the FD method to simulate the seismic wave propagation, the large spatial or temporal sampling interval can lead to dispersion errors and numerical instability. In the FD scheme, the key factor in determining both dispersion errors and stability is the selection of the FD weights. Thus, How to obtain appropriate FD weights to guarantee a stable numerical modeling process with minimum dispersion error is critical. The FD weights computation strategies can be classified into three types based on different computational ideologies, window function strategy, optimization strategy, and Taylor expansion strategy. In this paper, we provide a comprehensive overview of these three strategies by presenting their fundamental theories. We conduct a set of comparative analyses of their strengths and weaknesses through various analysis tests and numerical modelings. According to these comparisons, we provide two potential research directions of this field: Firstly, the development of a computational strategy for FD weights that enhances stability; Secondly, obtaining FD weights that exhibit a wide bandwidth while minimizing dispersion errors.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2311-2328"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000396/pdfft?md5=b83e2b723ecfee24aa4bf76004b8903a&pid=1-s2.0-S1995822624000396-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139767259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimized parameters of downhole all-metal PDM based on genetic algorithm 基于遗传算法的井下全金属 PDM 参数优化
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.022

Currently, deep drilling operates under extreme conditions of high temperature and high pressure, demanding more from subterranean power motors. The all-metal positive displacement motor, known for its robust performance, is a critical choice for such drilling. The dimensions of the PDM are crucial for its performance output. To enhance this, optimization of the motor's profile using a genetic algorithm has been undertaken. The design process begins with the computation of the initial stator and rotor curves based on the equations for a screw cycloid. These curves are then refined using the least squares method for a precise fit. Following this, the PDM's mathematical model is optimized, and motor friction is assessed. The genetic algorithm process involves encoding variations and managing crossovers to optimize objective functions, including the isometric radius coefficient, eccentricity distance parameter, overflow area, and maximum slip speed. This optimization yields the ideal profile parameters that enhance the motor's output. Comparative analyses of the initial and optimized output characteristics were conducted, focusing on the effects of the isometric radius coefficient and overflow area on the motor's performance. Results indicate that the optimized motor's overflow area increased by 6.9%, while its rotational speed reduced by 6.58%. The torque, as tested by Infocus, saw substantial improvements of 38.8%. This optimization provides a theoretical foundation for improving the output characteristics of all-metal PDMs and supports the ongoing development and research of PDM technology.

目前,深井钻探是在高温高压的极端条件下进行的,对地下动力电机提出了更高的要求。全金属正排量电机以其坚固耐用的性能著称,是此类钻探的关键选择。PDM 的尺寸对其性能输出至关重要。为了提高性能,我们采用遗传算法对电机外形进行了优化。设计过程首先是根据螺旋摆线方程计算初始定子和转子曲线。然后使用最小二乘法对这些曲线进行细化,以实现精确拟合。之后,对 PDM 的数学模型进行优化,并对电机摩擦进行评估。遗传算法过程包括编码变化和交叉管理,以优化目标函数,包括等距半径系数、偏心距参数、溢流面积和最大滑移速度。通过优化,可获得理想的轮廓参数,从而提高电机的输出功率。对初始输出特性和优化输出特性进行了比较分析,重点分析了等距半径系数和溢流面积对电机性能的影响。结果表明,优化后电机的溢流面积增加了 6.9%,而转速降低了 6.58%。经 Infocus 测试,扭矩大幅提高了 38.8%。这一优化为改善全金属 PDM 的输出特性提供了理论基础,并为 PDM 技术的持续开发和研究提供了支持。
{"title":"Optimized parameters of downhole all-metal PDM based on genetic algorithm","authors":"","doi":"10.1016/j.petsci.2024.03.022","DOIUrl":"10.1016/j.petsci.2024.03.022","url":null,"abstract":"<div><p>Currently, deep drilling operates under extreme conditions of high temperature and high pressure, demanding more from subterranean power motors. The all-metal positive displacement motor, known for its robust performance, is a critical choice for such drilling. The dimensions of the PDM are crucial for its performance output. To enhance this, optimization of the motor's profile using a genetic algorithm has been undertaken. The design process begins with the computation of the initial stator and rotor curves based on the equations for a screw cycloid. These curves are then refined using the least squares method for a precise fit. Following this, the PDM's mathematical model is optimized, and motor friction is assessed. The genetic algorithm process involves encoding variations and managing crossovers to optimize objective functions, including the isometric radius coefficient, eccentricity distance parameter, overflow area, and maximum slip speed. This optimization yields the ideal profile parameters that enhance the motor's output. Comparative analyses of the initial and optimized output characteristics were conducted, focusing on the effects of the isometric radius coefficient and overflow area on the motor's performance. Results indicate that the optimized motor's overflow area increased by 6.9%, while its rotational speed reduced by 6.58%. The torque, as tested by Infocus, saw substantial improvements of 38.8%. This optimization provides a theoretical foundation for improving the output characteristics of all-metal PDMs and supports the ongoing development and research of PDM technology.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2663-2676"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000943/pdfft?md5=27d62322d914914f9cdde68ae7de5b17&pid=1-s2.0-S1995822624000943-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140402982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A semi-analytical pressure and rate transient analysis model for inner boundary and propped fractures exhibiting dynamic behavior under long-term production conditions 针对长期生产条件下表现出动态行为的内边界和支撑裂缝的半解析压力和速率瞬态分析模型
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.04.005

The loss of hydrocarbon production caused by the dynamic behavior of the inner boundary and propped fractures under long-term production conditions has been widely reported in recent studies. However, the quantitative relationships for the variations of the inner boundary and propped fractures have not been determined and incorporated in the semi-analytical models for the pressure and rate transient analysis. This work focuses on describing the variations of the inner boundary and propped fractures and capturing the typical characteristics from the pressure transient curves.

A generalized semi-analytical model was developed to characterize the dynamic behavior of the inner boundary and propped fractures under long-term production conditions. The pressure-dependent length shrinkage coefficients, which quantify the length changes of the inner zone and propped fractures, are modified and incorporated into this multi-zone semi-analytical model. With simultaneous numerical iterations and numerical inversions in Laplace and real-time space, the transient solutions to pressure and rate behavior are determined in just a few seconds. The dynamic behavior of the inner boundary and propped fractures on transient pressure curves is divided into five periods: fracture bilinear flow (FR1), dynamic PFs flow (FR2), inner-area linear flow (FR3), dynamic inner boundary flow (FR4), and outer-area dominated linear flow (FR5). The early hump during FR2 period and a positive upward shift during FR4 period are captured on the log-log pressure transient curves, reflecting the dynamic behavior of the inner boundary and propped fractures during the long-term production period.

The transient pressure behavior will exhibit greater positive upward trend and the flow rate will be lower with the shrinkage of the inner boundary. The pressure derivative curve will be upward earlier as the inner boundary shrinks more rapidly. The lower permeability caused by the closure of un-propped fractures in the inner zone results in greater upward in pressure derivative curves. If the permeability loss for the dynamic behavior of the inner boundary caused by the closure of un-propped fractures is neglected, the flow rate will be overestimated in the later production period.

最近的研究广泛报道了在长期生产条件下,内边界和支撑裂缝的动态行为造成的碳氢化合物产量损失。然而,尚未确定内边界和支撑裂缝变化的定量关系,也未将其纳入压力和速率瞬态分析的半解析模型中。这项工作的重点是描述内边界和支撑裂缝的变化,并从压力瞬态曲线中捕捉典型特征。建立了一个通用的半分析模型,以描述长期生产条件下内边界和支撑裂缝的动态行为。与压力相关的长度收缩系数可量化内界和支撑裂缝的长度变化,该模型对其进行了修改,并将其纳入多区半分析模型。通过拉普拉斯和实时空间的同步数值迭代和数值反演,压力和速率行为的瞬态解在几秒钟内就能确定。内边界和支撑裂缝在瞬态压力曲线上的动态行为分为五个时期:裂缝双线性流动(FR1)、动态 PFs 流动(FR2)、内区域线性流动(FR3)、动态内边界流动(FR4)和外区域主导线性流动(FR5)。对数-对数压力瞬态曲线捕捉到了 FR2 期间的早期驼峰和 FR4 期间的正向上移,反映了长期生产期间内边界和支撑裂缝的动态行为。随着内边界的快速收缩,压力导数曲线将提前向上。由于内部区域未挤压裂缝的闭合导致渗透率降低,从而使压力导数曲线的上升幅度增大。如果忽略未挤压裂缝闭合造成的内边界动态行为的渗透率损失,后期生产时期的流量将被高估。
{"title":"A semi-analytical pressure and rate transient analysis model for inner boundary and propped fractures exhibiting dynamic behavior under long-term production conditions","authors":"","doi":"10.1016/j.petsci.2024.04.005","DOIUrl":"10.1016/j.petsci.2024.04.005","url":null,"abstract":"<div><p>The loss of hydrocarbon production caused by the dynamic behavior of the inner boundary and propped fractures under long-term production conditions has been widely reported in recent studies. However, the quantitative relationships for the variations of the inner boundary and propped fractures have not been determined and incorporated in the semi-analytical models for the pressure and rate transient analysis. This work focuses on describing the variations of the inner boundary and propped fractures and capturing the typical characteristics from the pressure transient curves.</p><p>A generalized semi-analytical model was developed to characterize the dynamic behavior of the inner boundary and propped fractures under long-term production conditions. The pressure-dependent length shrinkage coefficients, which quantify the length changes of the inner zone and propped fractures, are modified and incorporated into this multi-zone semi-analytical model. With simultaneous numerical iterations and numerical inversions in Laplace and real-time space, the transient solutions to pressure and rate behavior are determined in just a few seconds. The dynamic behavior of the inner boundary and propped fractures on transient pressure curves is divided into five periods: fracture bilinear flow (FR1), dynamic PFs flow (FR2), inner-area linear flow (FR3), dynamic inner boundary flow (FR4), and outer-area dominated linear flow (FR5). The early hump during FR2 period and a positive upward shift during FR4 period are captured on the log-log pressure transient curves, reflecting the dynamic behavior of the inner boundary and propped fractures during the long-term production period.</p><p>The transient pressure behavior will exhibit greater positive upward trend and the flow rate will be lower with the shrinkage of the inner boundary. The pressure derivative curve will be upward earlier as the inner boundary shrinks more rapidly. The lower permeability caused by the closure of un-propped fractures in the inner zone results in greater upward in pressure derivative curves. If the permeability loss for the dynamic behavior of the inner boundary caused by the closure of un-propped fractures is neglected, the flow rate will be overestimated in the later production period.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2520-2535"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624001043/pdfft?md5=02350abf59cbadb86c17f8e4eedd3d22&pid=1-s2.0-S1995822624001043-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140792724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acoustic characterization of hydrate formation and decomposition in clay-bearing sediments 含粘土沉积物中水合物形成和分解的声学特征
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.06.008

Understanding the acoustic characteristics of hydrates in various sediments is crucial for hydrate resource detection and safe and efficient exploitation, as hydrate occurrence patterns vary greatly in different sediments. In this work, sediments with different bentonite contents, water saturations, and types were prepared to investigate the characteristics of P-wave velocity (reflecting the magnitude of hydrate saturation in the sediment) and amplitude (reflecting the degree of hydrate-sediment cementation) during hydrate formation and depressurization. During hydrate formation, the P-wave velocity and amplitude have similar trends. As clay content increases, the P-wave velocity increase rates quickened. On the other hand, the increased rate of P-wave velocity slows down with the increase of water saturation in the clay-bearing sediments. Comparing various types of sediment shows that the water absorption and swelling of bentonite reduce the pore space, speeding up the cementation of the hydrate with the sediment and increasing P-wave velocity at a faster rate. Correspondence between P-wave velocity and hydrate saturation is strongly related to sediment type, clay content, and water saturation. The rapidly decreasing amplitude in the early stage of hydrate depressurization indicates that hydrate in clay-bearing sediments is weakly cemented to the sediments, which is prone to stratigraphic instability. The findings of this study offer guidance for hydrate resource assessments in clay-bearing sediments as well as geologic risk estimations during hydrate mining.

由于水合物在不同沉积物中的出现模式千差万别,因此了解各种沉积物中水合物的声学特征对于水合物资源探测和安全高效开采至关重要。在这项工作中,制备了不同膨润土含量、含水饱和度和类型的沉积物,以研究水合物形成和减压过程中的 P 波速度(反映沉积物中水合物饱和度的大小)和振幅(反映水合物与沉积物胶结的程度)特征。在水合物形成过程中,P 波速度和振幅具有相似的趋势。随着粘土含量的增加,P 波速度的增加速率加快。另一方面,随着含粘土沉积物中水饱和度的增加,P 波速度的增加速率减慢。对各种类型沉积物的比较表明,膨润土的吸水膨胀减少了孔隙空间,加快了水合物与沉积物的胶结,从而加快了 P 波速度的增加。P 波速度与水合物饱和度之间的对应关系与沉积物类型、粘土含量和含水饱和度密切相关。水合物减压早期振幅迅速减小,表明含粘土沉积物中的水合物与沉积物的胶结程度较弱,容易造成地层不稳定。这项研究的结果为含粘土沉积物中的水合物资源评估以及水合物开采过程中的地质风险评估提供了指导。
{"title":"Acoustic characterization of hydrate formation and decomposition in clay-bearing sediments","authors":"","doi":"10.1016/j.petsci.2024.06.008","DOIUrl":"10.1016/j.petsci.2024.06.008","url":null,"abstract":"<div><p>Understanding the acoustic characteristics of hydrates in various sediments is crucial for hydrate resource detection and safe and efficient exploitation, as hydrate occurrence patterns vary greatly in different sediments. In this work, sediments with different bentonite contents, water saturations, and types were prepared to investigate the characteristics of P-wave velocity (reflecting the magnitude of hydrate saturation in the sediment) and amplitude (reflecting the degree of hydrate-sediment cementation) during hydrate formation and depressurization. During hydrate formation, the P-wave velocity and amplitude have similar trends. As clay content increases, the P-wave velocity increase rates quickened. On the other hand, the increased rate of P-wave velocity slows down with the increase of water saturation in the clay-bearing sediments. Comparing various types of sediment shows that the water absorption and swelling of bentonite reduce the pore space, speeding up the cementation of the hydrate with the sediment and increasing P-wave velocity at a faster rate. Correspondence between P-wave velocity and hydrate saturation is strongly related to sediment type, clay content, and water saturation. The rapidly decreasing amplitude in the early stage of hydrate depressurization indicates that hydrate in clay-bearing sediments is weakly cemented to the sediments, which is prone to stratigraphic instability. The findings of this study offer guidance for hydrate resource assessments in clay-bearing sediments as well as geologic risk estimations during hydrate mining.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2830-2838"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624001663/pdfft?md5=41438931db878125755694daf1241c64&pid=1-s2.0-S1995822624001663-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141398467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on the solid particle erosion wear of pipe steel for hydraulic fracturing based on experiments and numerical simulations 基于实验和数值模拟的水力压裂钢管固体颗粒侵蚀磨损研究
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.03.019

Erosion wear is a common failure mode in the oil and gas industry. In the hydraulic fracturing, the fracturing pipes are not only in high-pressure working environment, but also suffer from the impact of the high-speed solid particles in the fracturing fluid. Beneath such complex conditions, the vulnerable components of the pipe system are prone to perforation or even burst accidents, which has become one of the most serious risks at the fracturing site. Unfortunately, it is not yet fully understood the erosion mechanism of pipe steel for hydraulic fracturing. Therefore, this article provides a detailed analysis of the erosion behavior of fracturing pipes under complex working conditions based on experiments and numerical simulations. Firstly, we conducted erosion experiments on AISI 4135 steel for fracturing pipes to investigate the erosion characteristics of the material. The effects of impact angle, flow velocity and applied stress on erosion wear were comprehensively considered. Then a particle impact dynamic model of erosion wear was developed based on the experimental parameters, and the evolution process of particle erosion under different impact angles, impact velocities and applied stress was analyzed. By combining the erosion characteristics, the micro-structure of the eroded area, and the micro-mechanics of erosion damage, the erosion mechanism of pipe steel under fracturing conditions was studied in detail for the first time. Under high-pressure operating conditions, it was demonstrated through experiments and numerical simulations that the size of the micro-defects in the eroded area increased as the applied stress increased, resulting in more severe erosion wear of fracturing pipes.

腐蚀磨损是石油天然气行业常见的一种失效模式。在水力压裂过程中,压裂管道不仅处于高压的工作环境中,还要承受压裂液中高速固体颗粒的冲击。在如此复杂的条件下,管道系统的易损部件很容易发生穿孔甚至爆裂事故,这已成为压裂现场最严重的风险之一。遗憾的是,人们对水力压裂钢管的侵蚀机理尚未完全了解。因此,本文基于实验和数值模拟,详细分析了压裂钢管在复杂工况下的侵蚀行为。首先,我们对压裂管用钢 AISI 4135 进行了侵蚀实验,研究材料的侵蚀特性。综合考虑了冲击角、流速和外加应力对侵蚀磨损的影响。然后根据实验参数建立了侵蚀磨损的颗粒冲击动态模型,分析了不同冲击角、冲击速度和外加应力下颗粒侵蚀的演变过程。结合侵蚀特征、侵蚀区域的微观结构和侵蚀损伤的微观力学,首次详细研究了管道钢在断裂条件下的侵蚀机理。在高压工作条件下,通过实验和数值模拟证明,随着外加应力的增加,侵蚀区域的微缺陷尺寸也随之增大,从而导致压裂管道的侵蚀磨损更加严重。
{"title":"Research on the solid particle erosion wear of pipe steel for hydraulic fracturing based on experiments and numerical simulations","authors":"","doi":"10.1016/j.petsci.2024.03.019","DOIUrl":"10.1016/j.petsci.2024.03.019","url":null,"abstract":"<div><p>Erosion wear is a common failure mode in the oil and gas industry. In the hydraulic fracturing, the fracturing pipes are not only in high-pressure working environment, but also suffer from the impact of the high-speed solid particles in the fracturing fluid. Beneath such complex conditions, the vulnerable components of the pipe system are prone to perforation or even burst accidents, which has become one of the most serious risks at the fracturing site. Unfortunately, it is not yet fully understood the erosion mechanism of pipe steel for hydraulic fracturing. Therefore, this article provides a detailed analysis of the erosion behavior of fracturing pipes under complex working conditions based on experiments and numerical simulations. Firstly, we conducted erosion experiments on AISI 4135 steel for fracturing pipes to investigate the erosion characteristics of the material. The effects of impact angle, flow velocity and applied stress on erosion wear were comprehensively considered. Then a particle impact dynamic model of erosion wear was developed based on the experimental parameters, and the evolution process of particle erosion under different impact angles, impact velocities and applied stress was analyzed. By combining the erosion characteristics, the micro-structure of the eroded area, and the micro-mechanics of erosion damage, the erosion mechanism of pipe steel under fracturing conditions was studied in detail for the first time. Under high-pressure operating conditions, it was demonstrated through experiments and numerical simulations that the size of the micro-defects in the eroded area increased as the applied stress increased, resulting in more severe erosion wear of fracturing pipes.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2779-2792"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000888/pdfft?md5=835163f7c3651f81f97cf357211ea73c&pid=1-s2.0-S1995822624000888-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140405542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intelligent responsive self-assembled micro-nanocapsules: Used to delay gel gelation time 智能响应自组装微纳胶囊:用于延迟凝胶凝胶时间
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.04.011

In the application of polymer gels to profile control and water shutoff, the gelation time will directly determine whether the gel can “go further” in the formation, but the most of the methods for delaying gel gelation time are complicated or have low responsiveness. There is an urgent need for an effective method for delaying gel gelation time with intelligent response. Inspired by the slow-release effect of drug capsules, this paper uses the self-assembly effect of gas-phase hydrophobic SiO2 in aqueous solution as a capsule to prepare an intelligent responsive self-assembled micro-nanocapsules. The capsule slowly releases the cross-linking agent under the stimulation of external conditions such as temperature and pH value, thus delaying gel gelation time. When the pH value is 2 and the concentration of gas-phase hydrophobic SiO2 particles is 10%, the gelation time of the capsule gel system at 30, 60, 90, and 120 °C is 12.5, 13.2, 15.2, and 21.1 times longer than that of the gel system without containing capsule, respectively. Compared with other methods, the yield stress of the gel without containing capsules was 78 Pa, and the yield stress after the addition of capsules was 322 Pa. The intelligent responsive self-assembled micro-nanocapsules prepared by gas-phase hydrophobic silica nanoparticles can not only delay the gel gelation time, but also increase the gel strength. The slow release of cross-linking agent from capsule provides an effective method for prolongating the gelation time of polymer gels.

在聚合物凝胶应用于剖面控制和关水时,凝胶化时间将直接决定凝胶能否在地层中 "走得更远",但大多数延迟凝胶化时间的方法都比较复杂或响应速度较低。因此,我们亟需一种能有效延迟凝胶凝固时间并能智能响应的方法。受药物胶囊缓释效应的启发,本文利用气相疏水 SiO2 在水溶液中的自组装效应作为胶囊,制备了一种智能响应的自组装微纳米胶囊。胶囊在温度、pH 值等外界条件的刺激下缓慢释放交联剂,从而延缓凝胶的凝胶化时间。当 pH 值为 2,气相疏水 SiO2 粒子的浓度为 10%时,胶囊凝胶体系在 30、60、90 和 120 °C 下的凝胶化时间分别是不含胶囊凝胶体系的 12.5、13.2、15.2 和 21.1 倍。与其他方法相比,不含胶囊的凝胶屈服应力为 78 Pa,而添加胶囊后的屈服应力为 322 Pa。气相疏水二氧化硅纳米颗粒制备的智能响应自组装微纳米胶囊不仅能延缓凝胶凝固时间,还能提高凝胶强度。胶囊中交联剂的缓慢释放为延长聚合物凝胶的凝胶化时间提供了一种有效的方法。
{"title":"Intelligent responsive self-assembled micro-nanocapsules: Used to delay gel gelation time","authors":"","doi":"10.1016/j.petsci.2024.04.011","DOIUrl":"10.1016/j.petsci.2024.04.011","url":null,"abstract":"<div><p>In the application of polymer gels to profile control and water shutoff, the gelation time will directly determine whether the gel can “go further” in the formation, but the most of the methods for delaying gel gelation time are complicated or have low responsiveness. There is an urgent need for an effective method for delaying gel gelation time with intelligent response. Inspired by the slow-release effect of drug capsules, this paper uses the self-assembly effect of gas-phase hydrophobic SiO<sub>2</sub> in aqueous solution as a capsule to prepare an intelligent responsive self-assembled micro-nanocapsules. The capsule slowly releases the cross-linking agent under the stimulation of external conditions such as temperature and pH value, thus delaying gel gelation time. When the pH value is 2 and the concentration of gas-phase hydrophobic SiO<sub>2</sub> particles is 10%, the gelation time of the capsule gel system at 30, 60, 90, and 120 °C is 12.5, 13.2, 15.2, and 21.1 times longer than that of the gel system without containing capsule, respectively. Compared with other methods, the yield stress of the gel without containing capsules was 78 Pa, and the yield stress after the addition of capsules was 322 Pa. The intelligent responsive self-assembled micro-nanocapsules prepared by gas-phase hydrophobic silica nanoparticles can not only delay the gel gelation time, but also increase the gel strength. The slow release of cross-linking agent from capsule provides an effective method for prolongating the gelation time of polymer gels.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2433-2443"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624001109/pdfft?md5=a7357775bdc7ca1a70733bc5a0007358&pid=1-s2.0-S1995822624001109-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140768381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel dandelion-based bionic proppant and its transportation mechanism in different types of fractures 基于蒲公英的新型仿生支撑剂及其在不同类型裂缝中的迁移机制
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.02.001

Low-permeability reservoirs are generally characterized by low porosity and low permeability. Obtaining high production using the traditional method is technologically challenging because it yields a low reservoir recovery factor. In recent years, hydraulic fracturing technology is widely applied for efficiently exploiting and developing low-permeability reservoirs using a low-viscosity fluid as a fracturing fluid. However, the transportation of the proppant is inefficient in the low-viscosity fluid, and the proppant has a low piling-up height in fracture channels. These key challenges restrict the fluid (natural gas or oil) flow in fracture channels and their functional flow areas, reducing the profits of hydrocarbon exploitation. This study aimed to explore and develop a novel dandelion-bionic proppant by modifying the surface of the proppant and the fiber. Its structure was similar to that of dandelion seeds, and it had high transport and stacking efficiency in low-viscosity liquids compared with the traditional proppant.

Moreover, the transportation efficiency of this newly developed proppant was investigated experimentally using six different types of fracture models (tortuous fracture model, rough fracture model, narrow fracture model, complex fracture model, large-scale single fracture model, and small-scale single fracture model). Experimental results indicated that, compared with the traditional proppant, the transportation efficiency and the packing area of the dandelion-based bionic proppant significantly improved in tap water or low-viscosity fluid. Compared with the traditional proppant, the dandelion-based bionic proppant had 0.1–4 times longer transportation length, 0.3–5 times higher piling-up height, and 2–10 times larger placement area. The newly developed proppant also had some other extraordinary features. The tortuosity of the fracture did not influence the transportation of the novel proppant. This proppant could easily enter the branch fracture and narrow fracture with a high packing area in rough surface fractures. Based on the aforementioned characteristics, this novel proppant technique could improve the proppant transportation efficiency in the low-viscosity fracturing fluid and increase the ability of the proppant to enter the secondary fracture. This study might provide a new solution for effectively exploiting low-permeability hydrocarbon reservoirs.

低渗透油藏一般具有低孔隙度和低渗透率的特点。由于油藏采收率较低,使用传统方法获得高产量在技术上具有挑战性。近年来,水力压裂技术得到广泛应用,使用低粘度流体作为压裂液,有效开采和开发低渗透储层。然而,支撑剂在低粘度流体中的运输效率较低,支撑剂在压裂通道中的成桩高度较低。这些关键挑战限制了流体(天然气或石油)在压裂通道及其功能流动区域的流动,降低了油气开采的利润。本研究旨在通过改变支撑剂和纤维的表面,探索和开发一种新型蒲公英仿生支撑剂。此外,还利用六种不同的压裂模型(曲折压裂模型、粗糙压裂模型、狭窄压裂模型、复杂压裂模型、大尺度单一压裂模型和小尺度单一压裂模型)对这种新开发的支撑剂的输送效率进行了实验研究。实验结果表明,与传统支撑剂相比,蒲公英基仿生支撑剂在自来水或低粘度流体中的输送效率和填料面积均有显著提高。与传统支撑剂相比,蒲公英基仿生支撑剂的输送长度延长了 0.1-4 倍,打桩高度提高了 0.3-5 倍,铺放面积扩大了 2-10 倍。新开发的支撑剂还具有其他一些非凡的特点。裂缝的曲折性并不影响新型支撑剂的输送。这种支撑剂很容易进入分支裂缝和狭窄裂缝,在粗糙表面裂缝中具有很高的填料面积。基于上述特点,这种新型支撑剂技术可以提高支撑剂在低粘度压裂液中的输送效率,并增强支撑剂进入次级裂缝的能力。这项研究可能会为有效开采低渗透油气藏提供一种新的解决方案。
{"title":"A novel dandelion-based bionic proppant and its transportation mechanism in different types of fractures","authors":"","doi":"10.1016/j.petsci.2024.02.001","DOIUrl":"10.1016/j.petsci.2024.02.001","url":null,"abstract":"<div><p>Low-permeability reservoirs are generally characterized by low porosity and low permeability. Obtaining high production using the traditional method is technologically challenging because it yields a low reservoir recovery factor. In recent years, hydraulic fracturing technology is widely applied for efficiently exploiting and developing low-permeability reservoirs using a low-viscosity fluid as a fracturing fluid. However, the transportation of the proppant is inefficient in the low-viscosity fluid, and the proppant has a low piling-up height in fracture channels. These key challenges restrict the fluid (natural gas or oil) flow in fracture channels and their functional flow areas, reducing the profits of hydrocarbon exploitation. This study aimed to explore and develop a novel dandelion-bionic proppant by modifying the surface of the proppant and the fiber. Its structure was similar to that of dandelion seeds, and it had high transport and stacking efficiency in low-viscosity liquids compared with the traditional proppant.</p><p>Moreover, the transportation efficiency of this newly developed proppant was investigated experimentally using six different types of fracture models (tortuous fracture model, rough fracture model, narrow fracture model, complex fracture model, large-scale single fracture model, and small-scale single fracture model). Experimental results indicated that, compared with the traditional proppant, the transportation efficiency and the packing area of the dandelion-based bionic proppant significantly improved in tap water or low-viscosity fluid. Compared with the traditional proppant, the dandelion-based bionic proppant had 0.1–4 times longer transportation length, 0.3–5 times higher piling-up height, and 2–10 times larger placement area. The newly developed proppant also had some other extraordinary features. The tortuosity of the fracture did not influence the transportation of the novel proppant. This proppant could easily enter the branch fracture and narrow fracture with a high packing area in rough surface fractures. Based on the aforementioned characteristics, this novel proppant technique could improve the proppant transportation efficiency in the low-viscosity fracturing fluid and increase the ability of the proppant to enter the secondary fracture. This study might provide a new solution for effectively exploiting low-permeability hydrocarbon reservoirs.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2583-2599"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000372/pdfft?md5=bdcdc4be8ced98313204a8fe2395ac25&pid=1-s2.0-S1995822624000372-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139767104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reliability analysis of carbon fiber rod-reinforced umbilical cable under tension using an improved sampling method 利用改进的取样方法分析碳纤维杆增强脐带电缆在拉力作用下的可靠性
IF 6 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.petsci.2024.02.016

The umbilical cable is a vital component of subsea production systems that provide power, chemical agents, control signals et al., and its requirement for reliability is exceedingly high. However, as the umbilical cable is a composite structure comprising multiple functional units, the reliability analysis of such cables involves numerous parameters that can impact calculation efficiency. In this paper, the reliability analysis of a new kind of umbilical cable with carbon fiber rod under tension is analyzed. The global dynamic analytical model is first established to determine the maximum tension load, then the local analytical model of umbilical cable including each unit are constructed by finite element method (FEM). Based on the mechanical analytical model, the reliability of umbilical cable under tension load is studied using response surface method (RSM) and Monte Carlo method. During the calculation process, a new tangent plane sampling method to calculate the response surface function (RSF) is proposed in this paper, which could make sampling points faster come close to the RSF curve, and it is proved that the calculation efficiency increases about 33% comparing with traditional method.

脐带缆是海底生产系统的重要组成部分,用于提供电力、化学制剂、控制信号等,其可靠性要求极高。然而,由于脐带缆是一种由多个功能单元组成的复合结构,对其进行可靠性分析时会涉及众多可能影响计算效率的参数。本文分析了一种新型碳纤维杆脐带缆在拉力作用下的可靠性分析。首先建立全局动态分析模型以确定最大拉力载荷,然后通过有限元法(FEM)建立包括各单元在内的脐带缆局部分析模型。在力学分析模型的基础上,采用响应面法(RSM)和蒙特卡罗法研究了脐带缆在张力载荷下的可靠性。在计算过程中,本文提出了一种新的切平面采样方法来计算响应面函数(RSF),该方法能使采样点更快地接近 RSF 曲线,并证明计算效率比传统方法提高了约 33%。
{"title":"Reliability analysis of carbon fiber rod-reinforced umbilical cable under tension using an improved sampling method","authors":"","doi":"10.1016/j.petsci.2024.02.016","DOIUrl":"10.1016/j.petsci.2024.02.016","url":null,"abstract":"<div><p>The umbilical cable is a vital component of subsea production systems that provide power, chemical agents, control signals et al., and its requirement for reliability is exceedingly high. However, as the umbilical cable is a composite structure comprising multiple functional units, the reliability analysis of such cables involves numerous parameters that can impact calculation efficiency. In this paper, the reliability analysis of a new kind of umbilical cable with carbon fiber rod under tension is analyzed. The global dynamic analytical model is first established to determine the maximum tension load, then the local analytical model of umbilical cable including each unit are constructed by finite element method (FEM). Based on the mechanical analytical model, the reliability of umbilical cable under tension load is studied using response surface method (RSM) and Monte Carlo method. During the calculation process, a new tangent plane sampling method to calculate the response surface function (RSF) is proposed in this paper, which could make sampling points faster come close to the RSF curve, and it is proved that the calculation efficiency increases about 33% comparing with traditional method.</p></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"21 4","pages":"Pages 2769-2778"},"PeriodicalIF":6.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1995822624000529/pdfft?md5=1f4939ca43a78c73b322c6a085ecea88&pid=1-s2.0-S1995822624000529-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140044787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Petroleum Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1