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High-pressure Cr3+ R-line luminescence of zoisite and kyanite: a probe of octahedral site distortion 黝帘石和蓝晶石的高压Cr3+ r线发光:八面体位畸变的探测
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-08-02 DOI: 10.1007/s00269-022-01211-8
Earl F. O’Bannon III, Quentin Williams

The Cr3+ luminescence spectra of zoisite and kyanite, two geologically important minerals, were studied up to 40 and 20 GPa, respectively, in various pressure media. Cr3+ substitutes into the octahedral aluminum sites in both minerals and the R-line luminescence is a particularly sensitive site-specific probe of the octahedral Al site. Unlike many previous studies where Cr3+ luminescence was utilized, both these minerals have multiple highly distorted octahedral sites resulting in very large splitting of their R-lines, ~ 300 cm−1 in zoisite and ~ 360 cm−1 in kyanite (for reference, ruby is 29 cm−1). For zoisite, the R-line splitting increases as pressure increases and more than triples from its ambient value by 40 GPa, while the R-line splitting in kyanite from the M1 and M2 sites does not change when compressed in a Ne pressure medium up to 20 GPa. We do not observe evidence of any phase transitions in either zoisite or kyanite across the pressure range of these new luminescence measurements. We present some high-pressure luminescence results where kyanite was known to be bridged between the diamond anvils and show how these spectra illustrate the different effect of uniaxial relative to hydrostatic stress on luminescence spectra.

研究了具有重要地质意义的黝帘石和蓝晶石在40 GPa和20 GPa压力下的Cr3+发光光谱。在这两种矿物中,Cr3+取代了八面体铝的位置,而r线发光是一种特别敏感的八面体铝位置特异性探针。与之前许多利用Cr3+发光的研究不同,这两种矿物都有多个高度扭曲的八面体位点,导致它们的r线分裂非常大,在黝帘石中~ 300 cm−1,在蓝晶石中~ 360 cm−1(作为参考,红宝石为29 cm−1)。对于黝帘石,r -线分裂随着压力的增加而增加,比其环境值增加了40 GPa以上,而蓝晶石中M1和M2位点的r -线分裂在Ne压力介质中压缩到20 GPa时没有变化。在这些新的发光测量的压力范围内,我们没有观察到任何黝帘石或蓝晶石相变的证据。我们提出了一些高压发光结果,其中蓝晶石已知是桥接在金刚石砧之间,并展示了这些光谱如何说明单轴相对于静水应力对发光光谱的不同影响。
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引用次数: 1
GeoSoilEnviroCARS (Sector 13) at the Advanced Photon Source: a comprehensive synchrotron radiation facility for Earth science research at ambient and extreme conditions 先进光子源的GeoSoilEnviroCARS(第13区):用于环境和极端条件下地球科学研究的综合同步辐射设施
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-26 DOI: 10.1007/s00269-022-01207-4
S. R. Sutton, M. L. Rivers, S. Chariton, P. J. Eng, A. Lanzirotti, M. Newville, T. Officer, V. B. Prakapenka, Y. J. Ryu, J. E. Stubbs, S. Tkachev, Y. Wang, A. Wanhala, J. Xu, M. Xu, T. Yu, D. Zhang

GeoSoilEnviroCARS (GSECARS) is a comprehensive analytical laboratory for Earth and environmental science research using X-ray beams from the Advanced Photon Source, Argonne National Laboratory. State-of-the-art instruments are available for (1) high-pressure/high- or low-temperature diffraction, total scattering, and spectroscopy (Brillouin, Raman, and VIS-IR) using the laser heated diamond anvil cell (DAC); (2) high-pressure/high-temperature diffraction, scattering, and imaging as well as acoustic emission (AE) and ultrasonics using the large-volume press (LVP); (3) powder, single crystal, and surface/interface diffraction; (4) X-ray absorption fine structure spectroscopy; (5) X-ray fluorescence microprobe analysis; and (6) microtomography. Experiments are facilitated by senior level staff who collaborate on all aspects of the analytical work including experiment design, sample preparation, data collection, data interpretation, and publication preparation. Both technical and scientific synergies occur as a result of the intimate association of the various techniques and scientists experienced in the applications of synchrotron radiation to Earth, environmental, and planetary science problems. The facility includes state-of-the-art instrumentation designed and built in-house, including custom X-ray optics, online and offline laser-based systems, specialized sample environments and positioning systems, as well as pixel-array and multi-crystal energy dispersive X-ray detectors, which are available to be shared among the experimental stations.

GeoSoilEnviroCARS (GSECARS)是一个综合分析实验室,用于地球和环境科学研究,使用来自阿贡国家实验室先进光子源的x射线束。最先进的仪器可用于(1)高压/高温或低温衍射,全散射和光谱(布里渊,拉曼和VIS-IR)使用激光加热金刚石砧细胞(DAC);(2)利用大体积压机(LVP)进行高压/高温衍射、散射和成像以及声发射(AE)和超声波;(3)粉末、单晶和表面/界面衍射;(4) x射线吸收精细结构光谱;(5) x射线荧光显微探针分析;(6)显微断层扫描。实验由高级工作人员协助,他们在分析工作的各个方面进行合作,包括实验设计、样品制备、数据收集、数据解释和出版物准备。由于在同步辐射应用于地球、环境和行星科学问题方面经验丰富的各种技术和科学家之间的密切联系,技术和科学的协同作用都会发生。该设施包括内部设计和建造的最先进的仪器,包括定制x射线光学,在线和离线激光系统,专门的样品环境和定位系统,以及像素阵列和多晶体能量色散x射线探测器,这些都可以在实验站之间共享。
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引用次数: 1
Atomic and microstructural origin of banded colours in purple-blue variety of agate from Yozgat Province, Turkey 土耳其尤兹加特省紫蓝色玛瑙带状颜色的原子和微观结构来源
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-26 DOI: 10.1007/s00269-022-01208-3
Roberto Lorenzi, Andrea Zullino, Valentina Gagliardi, Loredana Prosperi, Alberto Paleari, Ilaria Adamo

Agates from Yozgat province are appreciated on the gem market for their white and purple-blue banded colours. In this study, we present a detailed investigation aimed at the identification of the atomic and structural origin of this peculiar colouration of chalcedony. X-ray diffraction and Raman spectroscopy revealed the presence of fine grains of quartz and moganite with a preferential accumulation of the latter in the blue bands. Near-infrared diffuse absorption spectra show overtones of hydroxyls vibrations at 1425, 1900, and 2250 nm. In the visible, the broad absorption at about 500 nm, as well as its behaviour at low temperatures, is compatible with the optical activity of iron impurities in quartz matrices, such as that observed in amethysts. Peak intensities and shapes are very similar for spectra collected in blue and white bands. Accordingly, trace-element composition from laser ablation inductively coupled mass spectrometry confirmed that the two regions have similar Fe content. The perceived changes in band colours are indeed originated by differences in microstructural arrangement and size of the grains visualised through scanning electron microscopy. White and blue stripes have grains of about 5 µm and 300 nm in size, respectively, resulting in an accentuated scattering component for the white bands. Therefore, the unique purple-blue shades typical of Yozgat agates are a combination of iron-related colour centres and scattering effect.

来自尤兹加特省的玛瑙因其白色和紫蓝色条纹颜色而在宝石市场上受到赞赏。在这项研究中,我们提出了一项详细的调查,旨在鉴定这种特殊颜色的玉髓的原子和结构起源。x射线衍射和拉曼光谱显示石英和莫干石的细颗粒存在,后者在蓝带中优先堆积。近红外漫射吸收光谱在1425,1900和2250nm处显示羟基振动的泛音。在可见光下,约500 nm处的广泛吸收,以及它在低温下的行为,与石英基体中铁杂质的光学活性相容,例如在紫水晶中观察到的。在蓝色和白色波段收集的光谱的峰强度和形状非常相似。因此,激光烧蚀电感耦合质谱的微量元素组成证实了两个区域具有相似的铁含量。所感知到的波段颜色变化确实是由扫描电子显微镜观察到的晶粒的微观结构排列和大小的差异引起的。白色条纹和蓝色条纹的晶粒尺寸分别约为5µm和300 nm,导致白色条纹的散射分量增强。因此,尤兹伽特玛瑙特有的紫蓝色色调是铁相关色心和散射效果的结合。
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引用次数: 0
Fast anisotropic Mg and H diffusion in wet forsterite 镁和氢在镁橄榄石中的快速各向异性扩散
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-25 DOI: 10.1007/s00269-022-01204-7
Joshua M. R. Muir, Feiwu Zhang, Andrew M. Walker

Adding hydrogen to forsterite strongly increases the diffusion rate of Mg, but the reason for this is unclear. As Mg diffusion in forsterite can influence its electrical conductivity, understanding this process is important. In this study we use density functional theory to predict the diffusivity of H-bearing Mg vacancies and we find that they are around 1000 times slower than H-free Mg vacancies. H-bearing Mg vacancies are many orders of magnitude more concentrated than H-free Mg vacancies, however, and diffusion is a combination of diffusivity and defect concentration. Overall, the presence of hydrated Mg vacancies is predicted to cause a large (multiple orders of magnitude) increase in both diffusion rate and diffusional anisotropy with a strong preference for diffusion in the [001] direction predicted. In models of experimental data, the effect of water concentration on diffusion is often described by a constant best-fitting exponent. Our results suggest that this exponent will vary between 0.5 and 1.6 across common experimental conditions with pressure decreasing and temperature increasing this exponent. These results suggest that Mg diffusion in forsterite could vary considerably throughout upper mantle conditions in ways that cannot be captured with a simple single-exponent model. Comparisons to measures of hydrogen diffusivity suggest that the diffusion of hydrated Mg vacancies also controls the diffusion of hydrogen in (iron-free) forsterite and that our conclusions above also apply to hydrogen diffusion rates and anisotropy. We also find that cation diffusivity likely cannot explain experimental measurements of the effect of water on electrical conductivity in olivine.

向刚石中加入氢能显著提高Mg的扩散速率,但其原因尚不清楚。由于镁在橄榄石中的扩散会影响其导电性,因此了解这一过程非常重要。在这项研究中,我们使用密度泛函理论来预测含h Mg空位的扩散率,我们发现它们比不含h的Mg空位慢1000倍左右。含h的Mg空位比不含h的Mg空位集中了许多个数量级,而扩散是扩散率和缺陷浓度的结合。总的来说,预计水合Mg空位的存在会导致扩散速率和扩散各向异性的大幅(多个数量级)增加,并强烈倾向于向预测的[001]方向扩散。在实验数据模型中,水浓度对扩散的影响通常用一个常数的最佳拟合指数来描述。我们的结果表明,在常见的实验条件下,随着压力的降低和温度的升高,该指数将在0.5到1.6之间变化。这些结果表明,镁在整个上地幔中的扩散可能会发生很大的变化,而这种变化无法用简单的单指数模型来捕捉。与氢扩散率的比较表明,水合Mg空位的扩散也控制氢在(无铁)forsterite中的扩散,我们的结论也适用于氢扩散率和各向异性。我们还发现,阳离子扩散率可能不能解释水对橄榄石电导率影响的实验测量。
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引用次数: 2
Ultimate mechanical properties of enstatite 顽火辉石的极限力学性能
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-11 DOI: 10.1007/s00269-022-01206-5
Karine Gouriet, Pascal Roussel, Philippe Carrez, Patrick Cordier

The ultimate mechanical properties of MgSiO3 orthoenstatite (OEN), as characterized here by the ideal strengths, have been calculated under tensile and shear loadings using first-principles calculations. Both ideal tensile strength (ITS) and shear strength (ISS) are computed by applying homogeneous strain increments along high-symmetry directions ([100], [010], and [001]) and low index shear planes ((100), (010), and (001)) of the orthorhombic lattice. We show that the ultimate mechanical properties of OEN are highly anisotropic during tensile loading, with ITS ranging from 4.5 GPa along [001] to 8.7 GPa along [100], and quite isotropic during the shear loading with ISS ranging from 7.4 to 8.9 GPa. During tensile test along [100] and [001], a modified structure close to OEN has been found. This modified structure is more stable than OEN under stress (or strain). We have characterized its elastic and ultimate properties under tensile loading. With ITS ranging from 7.6 GPa along [010] to 25.6 GPa along [001], this modified structure appears to be very anisotropic with exceptional strength along [001].

本文用第一性原理计算方法计算了MgSiO3正顽辉石(OEN)在拉伸和剪切载荷下的极限力学性能,并以理想强度为特征。理想抗拉强度(ITS)和抗剪强度(ISS)都是通过沿正交晶格的高对称方向([100]、[010]和[001])和低指数剪切面((100)、(010)和(001))施加均匀应变增量来计算的。研究表明,OEN的极限力学性能在拉伸加载期间具有高度的各向异性,ITS沿[001]在4.5 GPa至8.7 GPa之间,ITS沿[100]在剪切加载期间具有相当的各向同性,ISS在7.4至8.9 GPa之间。在沿[100]和[001]的拉伸试验中,发现了一种接近OEN的改性结构。这种改进的结构在应力(或应变)下比OEN更稳定。我们表征了它在拉伸载荷下的弹性和极限性能。ITS范围从[010]沿线的7.6 GPa到[001]沿线的25.6 GPa,这种改进的结构似乎具有很强的各向异性,在[001]沿线具有优异的强度。
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引用次数: 0
Application of the double-difference relocation method to acoustic emission events in high-pressure deformation experiments 双差定位方法在高压变形实验声发射事件中的应用
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-06 DOI: 10.1007/s00269-022-01203-8
Timothy Officer, Lupei Zhu, Ziyu Li, Tony Yu, David R. Edey, Yanbin Wang

A methodology has been developed, detailing the theory and workflow, for applying the double-difference relocation method to acoustic emission (AE) event location in high-pressure/high-temperature deformation experiments in the multi-anvil apparatus. The process is predicated on the fact that events originating from a common source region will traverse similar ray paths from the source to the receiver and display similar waveforms in seismograms. This implies their travel-time difference results only from their spatial offset and any velocity heterogeneity along the ray path is negated. To demonstrate the efficacy of this approach we applied it to a transformational faulting experiment on the isostructural olivine analogue Mg2GeO4 under controlled deformation at 2.5 GPa and 700 °C while simultaneously monitoring stress, strain, and acoustic activity. Waveforms from all 1456 AE events were cross-correlated to measure differential arrival times and construct multiplet groups of similar events. In total, 110 multiplets were identified whose size is dominated by two large groups containing 272 and 202 events. Relocation of these two multiplets using the double-difference method significantly reduces event separation and improves location uncertainty by more than an order of magnitude when compared to absolute location techniques whose uncertainty rivals that of the sample size. In particular, event locations of the two largest multiplets reveal two dense clusters whose spatial geometry closely mirrors that of macroscopic faulting displayed in computerized tomography images of the recovered sample. In this way, we are able to link specific faults with their associated AE events, which would otherwise not be possible using traditional absolute location methods.

提出了一种将双差定位方法应用于多砧装置高压/高温形变实验声发射事件定位的方法,详细介绍了该方法的原理和工作流程。这个过程是基于这样一个事实,即来自一个共同震源区域的事件将从震源到接收器穿越相似的射线路径,并在地震图中显示相似的波形。这意味着它们的走时差异仅来自它们的空间偏移,并且沿着射线路径的任何速度非均质性都是否定的。为了证明该方法的有效性,我们将其应用于等构造橄榄石类似物Mg2GeO4的转换断层实验,该实验在2.5 GPa和700°C的控制变形下进行,同时监测应力、应变和声活动。所有1456个AE事件的波形相互关联,以测量不同的到达时间,并构建多个类似事件组。总共鉴定出110个多胞胎,其大小由两大组主导,其中包含272和202个事件。与不确定性与样本量相当的绝对定位技术相比,使用双差方法对这两个多胞胎进行重新定位可以显著减少事件分离,并将定位不确定性提高一个数量级以上。特别是,两个最大的多胞胎的事件位置揭示了两个密集的集群,其空间几何形状与恢复样本的计算机断层扫描图像中显示的宏观断层密切相关。通过这种方式,我们能够将特定的断层与其相关的声发射事件联系起来,否则使用传统的绝对定位方法是不可能的。
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引用次数: 1
Grain growth inhibited during grain size-sensitive creep in polycrystalline ice: an energy dissipation-rate perspective 多晶冰晶粒尺寸敏感蠕变过程中晶粒生长受到抑制:能量耗散率的视角
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-02 DOI: 10.1007/s00269-022-01202-9
Tess E. Caswell, Reid F. Cooper

Experiments in which two identical polycrystalline ice Ih specimens are simultaneously subjected to the same time–temperature history while one of the specimens is actively deformed via grain size-sensitive (GSS) creep demonstrate distinctly different microstructural evolution: for particular ranges of starting grain size and differential stress, grains do not grow in the deforming specimen. Ice Ih specimens having initial, uniform grain sizes in the range d = 6–63 μm were tested in pairs that were subjected to identical time–temperature conditions (durations t = 4–12 days; T = 240 K) but of which only one was subjected to differential stress (σ1 = 0.25–1.85 MPa; σ3 = 0). Comparing specimens within a pair, for those with coarser initial grain size, the deformed specimens exhibit suppressed or no grain growth. Our results are interpreted from the perspective of nonequilibrium thermodynamics, specifically comparing the energy dissipation rates associated with both grain growth and plastic flow: if the rate of energy dissipation associated with flow exceeds that of grain growth, the grains will not grow. An examination of the limited database on GSS flow and grain growth in silicates conforms to our analysis. The results are applied to the question of the mechanical evolution of terrestrial glaciers and to the ice-rich shells of the outer satellites.

实验中,两个相同的多晶冰Ih试样同时受到相同的时间-温度历史,而其中一个试样通过晶粒尺寸敏感(GSS)蠕变进行主动变形,结果显示出明显不同的微观组织演变:在特定的起始晶粒尺寸和差应力范围内,变形试样中的晶粒不生长。初始晶粒尺寸在d = 6-63 μm范围内均匀的冰Ih试样在相同的时间-温度条件下成对进行测试(持续时间t = 4-12天;T = 240 K),但其中只有一个受到差应力(σ1 = 0.25 ~ 1.85 MPa;σ3 = 0)。在一对试样中,对于初始晶粒尺寸较粗的试样,变形试样的晶粒生长受到抑制或不生长。我们的结果是从非平衡热力学的角度来解释的,具体比较了与晶粒生长和塑性流动相关的能量耗散率:如果与流动相关的能量耗散率超过晶粒生长的能量耗散率,则晶粒不会长大。对硅酸盐中GSS流动和晶粒生长的有限数据库的检查符合我们的分析。这些结果应用于陆地冰川的力学演化问题和外层卫星的富冰壳问题。
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引用次数: 0
Equation of state of elbaite at high pressure up to 21.1 GPa and room temperature elbaite在21.1 GPa高压和室温下的状态方程
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-07-02 DOI: 10.1007/s00269-022-01201-w
Wei Chen, Shijie Huang, Zhilin Ye, Jiamei Song, Shanrong Zhang, Mengzeng Wu, Dawei Fan, Wenge Zhou

The equation of the state of a natural elbaite sample has been investigated at room temperature and up to 21.1 GPa for the first time using in situ synchrotron X-ray diffraction in this study. No phase transition is observed on elbaite over the experimental pressure range. The pressure–volume data were fitted by the third-order Birch-Murnaghan equation of state (EoS) with the zero-pressure unit-cell volume V0 = 1540.7 (6) Å3, the zero-pressure bulk modulus KT0 = 114.7 (7) GPa, and its pressure derivative K'T0 = 4.2 (1), while obtained V0 = 1540.1 (4) Å3 and KT0 = 116.4 (4) GPa when fixed K'T0 = 4. Furthermore, the axial compressional behavior of elbaite was also fitted with a linearized third-order Birch-Murnaghan EoS, the obtained axial moduli for a-axis and c-axis are Ka0 = 201 (4) GPa and Kc0 = 60 (1) GPa, respectively. The axial compressibilities of a-axis and c-axis are βa = 1.66 × 10–3 GPa−1 and βc = 5.56 × 10–3 GPa−1 with an anisotropic ratio of βa: βc = 0.30: 1.00, which shows an intense axial compression anisotropy. The potential influencing factors on the bulk moduli and the anisotropic linear compressibilities of tourmalines were further discussed.

本文首次利用原位同步x射线衍射技术,在室温和21.1 GPa下研究了天然elbaite样品的状态方程。在实验压力范围内,未观察到elbaite的相变。压力-体积数据采用三阶Birch-Murnaghan状态方程(EoS)拟合,零压单元格体积V0 = 1540.7 (6) Å3,零压体积模量KT0 = 114.7 (7) GPa,压力导数K'T0 = 4.2(1),固定K'T0 = 4时,得到V0 = 1540.1 (4) Å3, KT0 = 116.4 (4) GPa。此外,利用三阶Birch-Murnaghan方程拟合了elbaite的轴向压缩行为,得到了a轴和c轴的轴向模量分别为k0 = 201 (4) GPa和k0 = 60 (1) GPa。a轴和c轴的轴向压缩性分别为βa = 1.66 × 10-3 GPa−1和βc = 5.56 × 10-3 GPa−1,各向异性比为βa: βc = 0.30: 1.00,表现出强烈的轴向压缩各向异性。进一步讨论了电气石体积模量和各向异性线性压缩率的潜在影响因素。
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引用次数: 1
High-pressure behaviour of stellerite: single-crystal X-ray diffraction study 辉钼矿的高压行为:单晶x射线衍射研究
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-06-29 DOI: 10.1007/s00269-022-01205-6
Yurii V. Seryotkin

The high-pressure (HP) behavior of natural stellerite |Ca4.00Na0.16 (H2O)32| [Al8.16Si27.84O72] has been studied by single-crystal X-ray diffraction using a diamond-anvil cell under pressures up to 4.5 GPa, with a 4:1 ethanol:water mixture and paraffin as pressure-transmitting media. The changes in the structure of stellerite at high pressures, especially the STI framework deformation, are similar to those in Na-rich stilbite |Ca4.00Na1.47 (H2O)30| [Al9.47Si26.53O72]. Both stilbite and stellerite udergo pressure-induced hydration, in which H2O molecules first occupy partly vacant sites and then the initially vacant positions. Some difference in the behavior of the two minerals is due to the presence of Na+ cations in stilbite. Sodium occupies positions in the 10-membered ring and prevents H2O molecules from penetrating near the ring center. Meanwhile, both stellerite and stilbite can fill the initially vacant sites in the 8-membered ring at high pressures. The pressure-induced changes, including the reduction of H2O sites in the cation coordination and a total number of H2O molecules, are less significant in Na-bearing stilbite than in stellerite.

采用金刚石砧池,以4:1乙醇:水混合物和石蜡为传压介质,用单晶x射线衍射研究了天然辉沸石|Ca4.00Na0.16 (H2O)32| [Al8.16Si27.84O72]在4.5 GPa高压下的高压(HP)行为。在高压下,星辉石的结构变化,特别是STI框架变形与富na静晶岩|Ca4.00Na1.47 (H2O)30| [Al9.47Si26.53O72]相似。静沸石和辉钼矿都经历了压力诱导水化,水分子首先占据部分空位,然后占据最初的空位。这两种矿物在行为上的一些差异是由于静止岩中Na+阳离子的存在。钠占据了10元环的位置,阻止水分子在环中心附近穿透。同时,在高压下,星辉石和静辉石都能填补8元环中最初的空位。压力诱导的变化,包括阳离子配位中H2O位点的减少和H2O分子总数的减少,在含钠的静晶石中没有在辉钼矿中明显。
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引用次数: 0
Thermal annealing of fission and ion tracks in epidote 绿帘石裂变和离子径迹的热退火
IF 1.4 4区 地球科学 Q3 Earth and Planetary Sciences Pub Date : 2022-06-29 DOI: 10.1007/s00269-022-01200-x
Wagner M. Nakasuga, Weixing Li, Chien-Hung Chen, Trevor A. Dumitru, Vladimir A. Skuratov, Rodney C. Ewing

Fission tracks are used for geologic age-dating and for the reconstruction of thermal histories of Earth’s upper crust. However, there remains a gap in the understanding between the atomic-scale annealing mechanism of latent (unetched) fission tracks and the observations of etched tracks at the micrometer scale. This is because the structure of latent fission tracks is lost during the leaching process. We have conducted the first comparison of the thermal-annealing behavior of latent and etched tracks in epidote, using transmission electron microscopy (TEM) and optical microscopy, respectively. For high-resolution TEM observations, we used ion tracks instead of fission tracks to control the density of tracks, and we demonstrated that latent ion tracks are amorphous in epidote. The reduction in diameters of latent tracks is insignificant after thermal annealing at 800 °C for 24 h, indicating that the track diameter does not appear to change substantially until the final stage of annealing. The optical observations show that the parallel etched ion-induced tracks have a lower track density reduction rate at or below 500 °C and an accelerated reduction rate above 500 °C as compared with randomly oriented fission tracks. However, the two types of tracks display a comparable thermal-annealing behavior as evidenced by the fit of the two curves for the normalized density of ion and fission tracks as a function of temperature with the same equation but with different fitting parameters. Thus, ion-induced tracks can be used to simulate fission tracks in epidote and provide a basis for understanding the annealing of latent and etched tracks.

裂变轨迹用于地质年代测定和重建地球上地壳的热历史。然而,对于潜在(未蚀刻)裂变径迹的原子尺度退火机制与蚀刻径迹在微米尺度上的观察结果之间的理解仍然存在差距。这是因为潜裂变径迹的结构在浸出过程中丢失了。我们分别使用透射电子显微镜(TEM)和光学显微镜对绿帘石中潜伏径迹和蚀刻径迹的热退火行为进行了首次比较。对于高分辨率的TEM观测,我们使用离子径迹代替裂变径迹来控制径迹的密度,并且我们证明了潜伏离子径迹在绿帘石中是无定形的。在800℃热处理24 h后,隐径迹直径的减小不显著,表明径迹直径直到退火的最后阶段才出现实质性的变化。光学观察表明,与随机取向的裂变径迹相比,平行蚀刻离子诱导径迹在500℃及以下具有较低的径迹密度还原率,而在500℃以上具有加速的径迹还原率。然而,离子和裂变径迹的归一化密度随温度的变化曲线具有相同的拟合方程,但拟合参数不同,这两种类型的径迹表现出相当的热退火行为。因此,离子诱导径迹可以用来模拟绿帘石中的裂变径迹,并为理解隐迹和蚀刻径迹的退火提供了基础。
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Physics and Chemistry of Minerals
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