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Dielectric properties of K(Ta0.55Nb0.45)O3 single crystal K(Ta0.55Nb0.45)O3单晶的介电性能
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297842
P. Bednyakov, N. Setter, D. Rytz
Dielectric properties of K(Ta0,55Nb0,45)O3 [KTN] single crystals with <;100>; and <;011>; crystallographic orientation were studied. Temperature dependencies of dielectric permittivity of monodomain and polydomain crystals of these orientations are compared.
K(Ta0,55Nb0,45)O3 [KTN]单晶的介电性能和;研究了晶体取向。比较了这些取向的单畴晶体和多畴晶体介电常数的温度依赖性。
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引用次数: 0
Effective dielectric response of anisotropic grains of close-packed structure 密排结构各向异性晶粒的有效介电响应
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297865
A. Klíč, I. Rychetský
Polycrystal modeled as close-packed uniaxial grains (crystallites) of various orientaions can be described using the spectral representation. It is formally similar to the isotropic 2-component composite, but with different meaning of structural characteristics. In particular, the volume fraction used in composites is replaced with the spacial mean value of crystallite orientations. It is illustrated on the simple example, that the structural quantities depends on the true volume fractions and also on the orientations of grains.
以各种取向的紧密排列的单轴晶粒(晶体)为模型的多晶可以用谱表示来描述。它在形式上类似于各向同性双组分复合材料,但具有不同的结构特征含义。特别是,复合材料中使用的体积分数被晶体取向的空间平均值所取代。通过一个简单的例子说明,结构量取决于真实体积分数,也取决于晶粒的取向。
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引用次数: 0
Magnetoelectric effect in soft composite materials 软复合材料中的磁电效应
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297753
B. Rožič, S. Gyergyek, Z. Kutnjak, M. Jagodič, S. Kralj, M. Jagodič, Z. Jagličić, V. Tzitzios
By using the SQUID susceptometer the existence of an indirect magnetoelectricity in a soft composite material prepared as a mixture of a ferroelectric liquid crystal (FLC) and magnetic nanoparticles (MNPs) was verified. It is shown that the orientation of MNPs is directly coupled to the FLC molecular director field. Such coupling allows the possibility of indirect coupling between the MNP's magnetization and FLC's polarization. This demonstrates the possibility to engineer the soft magnetoelectrics from mixtures of magnetic nanoparticles and ferroelectric liquid crystals.
利用SQUID电纳计验证了铁电液晶(FLC)和磁性纳米颗粒(MNPs)混合制备的软复合材料中存在间接磁电。结果表明,MNPs的取向与FLC分子导向场直接耦合。这种耦合使得MNP的磁化强度和FLC的极化之间存在间接耦合的可能性。这证明了利用磁性纳米颗粒和铁电液晶的混合物来设计软磁电的可能性。
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引用次数: 1
Ferroelectric-ferromagnetic composites based on PZT type ceramic and NiZnFe ferrite 基于PZT型陶瓷和NiZnFe铁氧体的铁电-铁磁复合材料
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297841
D. Bochenek, P. Niemiec, P. Wawrzała, A. Chrobak
In the work, the ferroelectric-ferromagnetic composites were obtained on the basis of a ferroelectric powder of PZT type. Admixtured compositions of PZT type powders constituted ferroelectric, ferroelectric powder (90% of amount), whereas nickel-zinc ferrite (Ni1-xZnxFe2O4) was the magnetic content in the composite (10% of amount). Synthesizing the composite content was performed using compact sintering in the solid phase, while densification of the synthesized composite powder using the conventional sintering method. X-ray, tests, as well as microstructure, dielectric, magnetic and electric hysteresis loop tests were carried out. The tests showed existence of correlation between a magnetic and electric subsystems in the ferroelectric-ferromagnetic composites. Thanks to ferroelectric and magnetic properties of the composites obtained, materials of such type may be applied in new memory types.
在PZT型铁电粉末的基础上,制备了铁电-铁磁复合材料。PZT型粉末的混合成分为铁电性粉末,铁电性粉末占总量的90%,磁性成分为镍锌铁氧体(Ni1-xZnxFe2O4)占总量的10%。复合材料含量的合成采用固相致密烧结方法,合成的复合粉体采用常规烧结方法致密化。进行了x射线、测试以及微观结构、介电、磁和电滞回线测试。试验表明,铁电-铁磁复合材料中存在磁性子系统和电子系统之间的相关性。由于所获得的复合材料的铁电性和磁性,这种类型的材料可以应用于新的存储类型。
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引用次数: 0
Strain control for optimization of piezoelectric energy harvesting 压电能量收集优化的应变控制
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297749
M. S. Woo, S. Hong, H. Jung, C. Yang, D. Song, T. Sung
A novel piezoelectric energy harvesting module with controllable strain was designed to allow investigations into the correlations among strain, frequency, and output power. Specifically, although conventional vibration modules allow control over strain only through variation in tip mass, the proposed module allows more accurate strain control through adjustment of the displacement of the free end of the cantilever (5-45 mm). Experiments showed that both types of modules exhibit an increase in open circuit output voltage with strain, but the piezoelectric material fails at severe strain. In addition, it was confirmed that the proposed module design can keep the output voltage constant by controlling the strain, which allows investigation into the relationship between frequency and output power. Thus, at constant strain, the matching impedance was found to be low at high frequency. Therefore, optimum conditions for harvesting maximum power are high frequency and the largest strain that does not damage the piezoelectric material.
为了研究应变、频率和输出功率之间的关系,设计了一种具有可控应变的新型压电能量收集模块。具体来说,虽然传统的振动模块只能通过尖端质量的变化来控制应变,但该模块可以通过调整悬臂自由端的位移(5-45毫米)来实现更精确的应变控制。实验表明,两种模组的开路输出电压均随应变的增加而增加,但压电材料在严重应变下失效。此外,还证实了所提出的模块设计可以通过控制应变来保持输出电压恒定,从而可以研究频率与输出功率之间的关系。因此,在恒定应变下,匹配阻抗在高频处较低。因此,获取最大功率的最佳条件是高频率和不损坏压电材料的最大应变。
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引用次数: 0
Wettability of the PMMA surface caused by its polarization due to UV radiation PMMA表面的润湿性是由紫外线辐射引起的极化引起的
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297719
Y. Dekhtyar, A. Griva, L. Lancere, B. Andersons, E. Sansonetti
Wettability of the poly methyl methacrylate (PMMA) surface defines its biocompatibility being essential factor for biomedical applications. The processed surface degrades in time therefore the prostheses/lens should be repaired to keep the patient at a high life quality level. However the most common methods can be considered as sophisticated (plasma treatment, laser treatment, etc.). The research presents novel result on the PMMA surface wettability engineering by means of non-ionizing ultraviolet radiation (200-400nm). Results (electron work function (φ), photoelectron emission spectra, optical absorption) show alteration from hydrophobic to hydrophilic surface behaviour. Both the surface (photoelectron emission) and the bulk (optical absorption) interacting centres were influenced by radiation showing maximum effect after 45 minutes of irradiation.
聚甲基丙烯酸甲酯(PMMA)表面的润湿性决定了其生物相容性是生物医学应用的重要因素。处理过的表面会及时降解,因此应该修复假体/晶状体,以保持患者的高生活质量水平。然而,最常见的方法可以被认为是复杂的(等离子体治疗,激光治疗等)。本研究提出了利用非电离紫外辐射(200-400nm)进行PMMA表面润湿性工程的新成果。结果(电子功函数(φ)、光电子发射光谱、光学吸收)表明表面行为由疏水性转变为亲水性。表面(光电子发射)和体(光吸收)相互作用中心都受到辐射的影响,辐照45分钟后效果最大。
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引用次数: 1
Pizeoelectric epitaxial sol-gel Pb(Zr0.52Ti0.48)O3 film on Si(001) Si(001)上的压电外延溶胶-凝胶Pb(Zr0.52Ti0.48)O3薄膜
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297812
S. Yin, G. Le Rhun, E. Defay, B. Vilquin, G. Niu, Y. Robach, C. Drăgoi, L. Trupina, L. Pintilie
Epitaxial Pb(Zr0.52Ti0.48)O3 (PZT) thin film has been successfully integrated on Si(001) substrate by sol-gel method. SrTiO3 (STO) layer deposited on Si by Molecular Beam Epitaxy (MBE) acts as a template layer in this study to avoid the formation of amorphous SiO2, and allows the chemical compatibility for further epitaxial growth. For bottom electrode, SrRuO3 (SRO) layer grown by Pulsed Laser Deposition (PLD) on STO/Si was used. Epitaxial single crystalline growth of PZT film after Rapid Thermal Annealing (RTA) at 650°C was evidenced by X-Ray Diffraction (XRD). The following relationship in the heterostructure was deduced: [110] PZT (001) // [110] SRO (001) // [110] STO (001) // [100] Si (001). A clear piezoelectric response of the film was observed by Piezoresponse Force Microscope (PFM). Moreover, the structural STO quality was proved to have a major impact on the electrical properties of PZT films.
采用溶胶-凝胶法将Pb(Zr0.52Ti0.48)O3 (PZT)薄膜成功集成在Si(001)衬底上。通过分子束外延(Molecular Beam Epitaxy, MBE)沉积在Si上的SrTiO3 (STO)层在本研究中作为模板层,避免了非晶态SiO2的形成,并允许进一步外延生长的化学相容性。底电极采用脉冲激光沉积法(PLD)在STO/Si上生长SrRuO3 (SRO)层。x射线衍射(XRD)证实了650℃快速热退火(RTA)后PZT薄膜外延单晶生长。在异质结构中推导出如下关系:[110]PZT (001) // [110] SRO (001) // [110] STO (001) // [100] Si(001)。通过压电响应力显微镜(PFM)观察到薄膜具有明显的压电响应。此外,结构STO质量对PZT薄膜的电学性能有重要影响。
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引用次数: 0
Role of interfaces in nanostructured CoFe2O4 films 界面在纳米结构CoFe2O4薄膜中的作用
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297866
A. Axelsson, F. Aguesse, N. Alford, M. Valant
In bulk ceramics, interfaces between adjacent materials can be neglected when evaluating the individual functional properties on the macroscale. However, in nanostructured materials, a region described as an interfacial region can comprise up to 10% of the total volume. By traditional XRD and SEM these regions may be hard to describe. Here we present how a combination of non destructive material analysis and property analysis brings knowledge of the chemistry at the interfaces and microstructure in the film. Epitaxial thin film CoFe2O4 were grown on several growth templates such as SrTiO3, LaAlO3, BaTiO3 and MgO as to vary the interfacial region and subsequent growth mechanism. The chemical stability and crystallographic matching between the magnetic film and the dielectric growth template are discussed where dramatic changes of the functional properties of these nanoscale structures demonstrate that the interfaces have a deleterious effect on the properties.
在块状陶瓷中,当在宏观尺度上评估单个功能特性时,相邻材料之间的界面可以被忽略。然而,在纳米结构材料中,被描述为界面区域的区域可以占到总体积的10%。用传统的XRD和SEM很难描述这些区域。在这里,我们展示了无损材料分析和性能分析的结合如何带来界面化学和薄膜微观结构的知识。在SrTiO3、LaAlO3、BaTiO3和MgO等生长模板上生长CoFe2O4外延薄膜,以改变界面区域和随后的生长机制。讨论了磁性薄膜和介电生长模板之间的化学稳定性和晶体学匹配,这些纳米结构的功能特性的急剧变化表明界面对性能有有害影响。
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引用次数: 0
An investigation into the electrical properties of doped barium titanate using EIS 掺杂钛酸钡电学性能的EIS研究
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297809
G. Dale, J. McLaughlin, M. Conway
Barium titanate has been doped with rare earth oxides (Erbium, Holmium, Gadolinium and Yttrium) in an attempt to understand the effect on the reliability of the dielectric material for multilayer capacitor applications. The morphology of the samples used was characterized using scanning electron microscopy (SEM) with EDAX used to confirm the presence of each rare earth ions. It is suggested that incorporation of rare earth ions into the BaTiO3 is as a result of ionic radius, resulting in varying grain growth and electrical properties. The change in reliability and electrical properties of the capacitor can be attributed to overall distribution of rare earth oxides and their occupation site within the dielectric.
钛酸钡掺杂了稀土氧化物(铒、钬、钆和钇),试图了解对多层电容器应用的介电材料可靠性的影响。用扫描电子显微镜(SEM)对样品的形貌进行了表征,并用EDAX确认了每种稀土离子的存在。结果表明,稀土离子掺入BaTiO3是由于离子半径的影响,导致晶粒生长和电学性能发生变化。电容器的可靠性和电性能的变化可归因于稀土氧化物的总体分布及其在电介质中的占据位置。
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引用次数: 2
Development of a photoconductive piezoelectronic material from composite of P(VDF-TrFE) and TiOPc P(VDF-TrFE)与TiOPc复合光导压电材料的研制
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297743
Wen-Chih Chang, An-Bang Wang, Chih-Kung Lee, W. Ko, Han-Lung Chen, Chih-Ting Lin
In recent years, the optical properties of piezoelectric materials have attracted much interest. We developed a new photoconductive piezoelectric material by integrating P(VDF-TrFE) and TiOPc to create a new composite. This new composite material not only retains good piezoelectric efficiency but also possesses high sensitivity to visible light. We analyzed photoconductivity before and after light illumination at different wavelengths to confirm the potential benefits and advantages of this newly developed material. An equivalent circuit of a P(VDF-TrFE) & TiOPc composite was simulated and verified experimentally. Our results show that our P(VDF-TrFE) & TiOPc composite can be applied to microfluidic chips for particle manipulation. The experimental results establish the basic material properties and the electrical model for future modification.
近年来,压电材料的光学特性引起了人们的广泛关注。我们通过将P(VDF-TrFE)和TiOPc集成成一种新型复合材料,开发了一种新型光导压电材料。这种新型复合材料不仅保持了良好的压电效率,而且对可见光具有很高的灵敏度。我们分析了不同波长光照射前后的光电性,以证实这种新材料的潜在效益和优势。仿真了P(VDF-TrFE) & TiOPc复合材料的等效电路,并进行了实验验证。我们的研究结果表明,我们的P(VDF-TrFE) & TiOPc复合材料可以应用于微流控芯片中进行粒子操作。实验结果建立了材料的基本性质和电学模型,为今后的修正提供了基础。
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引用次数: 5
期刊
Proceedings of ISAF-ECAPD-PFM 2012
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