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Local polarization in strontium barium niobate (SBN) epitaxial thin films investigated using Kelvin Force Microscopy (KFM) 开尔文力显微镜(KFM)研究铌酸锶钡(SBN)外延薄膜的局部极化
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297795
M. Cuniot-Ponsard
The Kelvin Force Microscopy technique is exploited to obtain quantitative information on the local polarization dependences in strontium barium niobate epitaxial thin films.
利用开尔文力显微镜技术获得了铌酸锶钡外延薄膜局部极化依赖的定量信息。
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引用次数: 0
Potential barrier at the ferroelectric grain boundary due to asymmetric screening of depolarization fields 退极化场不对称筛选导致的铁电晶界势垒
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297727
Y. Genenko, O. Hirsch, P. Erhart
Electric depolarization fields generated by a stripe domain structure in ferroelectrics are considered within a semiconductor model. Field screening due to electronic band bending and due to presence of intrinsic defects leads to the building of asymmetric space charge regions near the grain boundary. This in turn results in the formation of a potential barrier between the grain surface and its interior.
在半导体模型中考虑了铁电体中由条纹畴结构产生的去极化场。由于电子能带弯曲和本征缺陷的存在而产生的场屏蔽导致在晶界附近形成不对称空间电荷区。这反过来又导致在颗粒表面和内部之间形成电位屏障。
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引用次数: 0
Ferroelectric and dielectric properties of bismuth ferrite based thin films by Pulsed Laser Deposition 脉冲激光沉积铋铁氧体基薄膜的铁电性能和介电性能
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297782
R. Rivera, M. Hejazi, A. Safari
BiFeO3 (BFO) has stimulated a great interest in recent years for its room temperature multiferroic behavior with very high remnant polarization. However, the leakage current of BFO films is very high. To lower the leakage current, we have developed thin films with following target compositions on SrRuO3 buffered on SrTiO3 substrate by Pulsed Laser Deposition (PLD): (A) BiFeO3, (B) 0.88Bi0.5Na0.5TiO3-0.08Bi0.5K0.5TiO3-0.04BaTiO3, (C) 0.6BiFeO3-0.4(Bi0.5K0.5TiO3) The phase, growth orientation, microstructural characterization and electrical properties were investigated as a function of deposition parameters. The epitaxial bi-layered 300nm BNT-BKT-BT/BFO thin films (150nm each) exhibited ferroelectric behavior as: 2Pr = 44.0 μC.cm-2, 2Ec = 200 kV.cm-1 and K = 140. Thin films with a composition of 0.6BFO-0.4BKT have also been deposited with different oxygen pressures of 300-500 mTorr. Preliminary results of 0.6BFO-0.4BKT films show that the leakage current can be suppressed by about 4 orders of magnitude which in turn improves the ferroelectric and dielectric properties of the films. It is observed that the remnant polarization increases from 8 to 19 μC.cm-2 as the oxygen pressure is changed from 500 to 300mtorr.
BiFeO3 (BFO)具有很高的残余极化率和室温多铁性,近年来引起了人们的极大兴趣。然而,BFO薄膜的泄漏电流非常大。为了降低漏电流,我们利用脉冲激光沉积(PLD)在SrRuO3衬底上制备了具有以下目标成分的薄膜:(A) BiFeO3, (B) 0.88Bi0.5Na0.5TiO3-0.08Bi0.5K0.5TiO3-0.04BaTiO3, (C) 0.6BiFeO3-0.4(Bi0.5K0.5TiO3)。研究了沉积参数对相、生长取向、微观结构表征和电学性能的影响。外延双层300nm BNT-BKT-BT/BFO薄膜(各150nm)在2Pr = 44.0 μC时表现出铁电行为。cm-2, 2Ec = 200kv。cm-1, K = 140。在300-500 mTorr不同的氧压力下,也沉积了成分为0.6BFO-0.4BKT的薄膜。对0.6BFO-0.4BKT薄膜的初步研究结果表明,泄漏电流可被抑制约4个数量级,从而提高了薄膜的铁电性能和介电性能。残余极化从8 μC增加到19 μC。当氧气压力从500到300mtorr变化时Cm-2。
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引用次数: 0
Design and modelling of a ring-shape Recurve piezoelectric actuator 环形弯曲压电驱动器的设计与建模
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297784
G. Beckers, L. Pirnay, B. Dehez
Piezoelectric materials show interesting properties for developing actuators but most of the times they must be integrated in a stroke amplification structure. This paper presents a ring-shape Recurve structure that allows better integration in a mechatronics system as well as a good stroke. Two models based on Euler-Bernoulli beams theory are provided. Both consider only a bending load and the piezoelectric effect but one is a straight beam and the other is a curved beam. A finite-element model is used to show the limits of the hypothesis.
压电材料在开发执行器方面表现出了令人感兴趣的特性,但大多数情况下,它们必须集成在冲程放大结构中。本文提出了一种环形的Recurve结构,可以更好地集成在机电一体化系统中,并具有良好的行程。给出了基于欧拉-伯努利梁理论的两种模型。两者都只考虑弯曲载荷和压电效应,但一个是直梁,另一个是弯曲梁。用一个有限元模型来说明假设的局限性。
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引用次数: 1
Thickness dependence of structure and piezoelectric properties at nanoscale of polycrystalline PZT thin films 多晶PZT薄膜结构与纳米级压电性能的厚度依赖性
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297844
E. Araújo, E. C. Lima, I. Bdikin, A. Kholkin
Lead zirconate titanate Pb(Zr0.50Ti0.50)O3 (PZT) thin films were deposited by a polymeric chemical method on Pt(111)/Ti/SiO2/Si substrates to understand the mechanisms of phase transformations and the effect of film thickness on the structure, dielectric and piezoelectric properties in these films. PZT films pyrolyzed at temperatures higher than 350°C present a coexistence of pyrochlore and perovskite phases, while only perovskite phase grows in films pyrolyzed at temperatures lower than 300°C. For pyrochlore-free PZT thin films, a small (100) orientation tendency near the film-substrate interface was observed. Finally, we demonstrate the existence of a self-polarization effect in the studied PZT thin films. Results suggest that Schottky barriers and/or mechanical coupling near the film substrate interface are not primarily responsible for the observed self-polarization effect in our films.
采用聚合化学方法在Pt(111)/Ti/SiO2/Si衬底上沉积了锆钛酸铅(Pb(Zr0.50Ti0.50)O3 (PZT)薄膜,研究了薄膜的相变机理以及薄膜厚度对薄膜结构、介电和压电性能的影响。在350℃以上热解的PZT薄膜中,焦绿石相和钙钛矿相共存,而在300℃以下热解的薄膜中,只有钙钛矿相生长。对于无焦绿石的PZT薄膜,在薄膜-衬底界面附近观察到一个小的(100)取向趋势。最后,我们证明了所研究的PZT薄膜中存在自极化效应。结果表明,薄膜衬底界面附近的肖特基势垒和/或机械耦合并不是薄膜中观察到的自极化效应的主要原因。
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引用次数: 0
Reduction of temperature coefficient of frequency in LiTaO3 single crystals for surface acoustic wave applications 表面声波应用中LiTaO3单晶频率温度系数的降低
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297858
A. Bartasyte, O. Elmazria, M. Gonzalez, L. Bouvot, E. Blampain, P. Boulet
Temperature coefficient of frequency of LiTaO3 single crystals was tuned by changing the Li stoichiometry. For this purpose, congruent 36°Y cut crystals, available commercially, were treated by vapor transport equilibration and temperature coefficient of frequency of surface acoustic waves propagating along X-axis as a function of Li concentration was studied. The temperature coefficient of frequency of -7 ppm/° was achieved for surface acoustic waves propagating in the crystals containing 49.43 mol % of Li2O.
通过改变锂的化学计量来调节LiTaO3单晶的频率温度系数。为此,采用蒸汽输运平衡法对市售的36°Y切割晶体进行了处理,并研究了沿x轴传播的表面声波频率温度系数随Li浓度的变化规律。在含Li2O浓度为49.43 mol %的晶体中,表面声波传播的温度系数为-7 ppm/°。
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引用次数: 2
Modeling of the hyteresys loop of a ferroïc single cristal ferroïc单晶滞回环的建模
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297825
M. Ragheb, R. Renoud, C. Borderon, H. Gundel
We propose a description of the non-linear response of a ferroïc single crystal to the action of an ac constraint, here an electric field, by examining the polarization. For that, we use the model we have develop to describe the movement of the domain walls [1]. We establish the equation of the polarization or of the strain as a function of the time and we deduce the expression of the hysteresis loop. The equation consists of two parts. The first one is related to dynamical processes. It allows both to consider the instantaneous response of the ferroelectric (real part of the dielectric constant) that the delay caused by losses during the switching of the dipoles (imaginary part of the dielectric constant). The frequency and the amplitude dependencies of the slope of loop are included in the description. The second part represents the static contribution. It is described by a nonlinear function which it is the best description of the saturation function. This model allows us to obtain the expressions for the coercive and the remnant values as a function of the frequency and the amplitude of the ac applied constraint. Predictions of the model for single crystals are in well agreement with experimental data.
我们提出了一个描述的非线性响应的ferroïc单晶的交流约束,这里是电场的作用,通过检查极化。为此,我们使用我们开发的模型来描述畴壁的运动[1]。建立了应变的极化方程和应变随时间的函数方程,推导了磁滞回线的表达式。这个方程由两部分组成。第一个与动态过程有关。它允许两者考虑铁电的瞬时响应(介电常数的实部),即偶极子切换过程中损失引起的延迟(介电常数的虚部)。回路斜率的频率依赖性和幅值依赖性都包含在描述中。第二部分表示静态贡献。它由一个非线性函数来描述,它是饱和函数的最佳描述。该模型使我们能够得到强制值和残余值作为施加约束的频率和幅度的函数的表达式。该模型对单晶的预测与实验数据吻合较好。
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引用次数: 0
Ferroelectric and magnetic properties of Fe-doped BaTiO3 thin films grown by the pulsed laser deposition 脉冲激光沉积fe掺杂BaTiO3薄膜的铁电性和磁性
Pub Date : 2012-07-09 DOI: 10.1063/1.4801965
E. Ramana, Bo Wha Lee, Chang Uk Jung, Sang Mo Yang, Ranju Jung, M. Jung
Fe-doped BaTiO3 thin films were grown on (001) oriented SrTiO3 substrates using pulsed-laser deposition technique. These films had a single-phase character and good epitaxial relationship with the substrate. Polarization-electric field (P-E) hysteresis revealed a saturated polarization with a remnant polarization (Pr) of 13.5 μC/cm2 for 10 mol% Fe-doped BaTiO3 films. Further increase of composition resulted in the large leakage currents and reduction of polarization. The piezoelectric domain switching in the films was confirmed by local hysteresis using piezoelectric force microscopy measurements. The Fe-doped BaTiO3 thin films exhibited room temperature ferromagnetism, and the magnetization value increased with increasing Fe concentration. Our results demonstrated that the addition of Fe ≤10 mol% in BaTiO3 induce the ferromagnetism and the switchable ferroelectric state.
采用脉冲激光沉积技术在(001)取向的SrTiO3衬底上生长了掺杂铁的BaTiO3薄膜。这些薄膜具有单相特性,与衬底具有良好的外延关系。10 mol% fe掺杂的BaTiO3薄膜呈现饱和极化,残余极化(Pr)为13.5 μC/cm2。成分的进一步增加导致泄漏电流增大,极化减小。利用压电力显微镜测量的局部迟滞证实了薄膜中的压电畴切换。Fe掺杂的BaTiO3薄膜表现出室温铁磁性,磁化值随Fe浓度的增加而增加。结果表明,在BaTiO3中加入Fe≤10 mol%可诱导铁磁性和可切换铁电态。
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引用次数: 41
Fabrication of ridge waveguides in LiNbO3 LiNbO3中脊波导的制备
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297792
B. Weigand, M. Stolze, F. Rubel, J. L’huillier, A. Lenhard, C. Becher, S. Wolff
We have fabricated ridge waveguides in lithium niobate with sidewall roughness of 14 nm (rms) and sidewall angles of more than 71°. The use of thick electroplated metal masks for reactive ion etching (RIE) makes it possible to manufacture ridge structures with several microns in height. For light confinement towards the substrate we investigate direct heterobonding techniques. Due to the expected low transmission losses we envision future applications in the field of quantum optics.
我们已经在铌酸锂材料中制备了边壁粗糙度为14 nm (rms),边壁角大于71°的脊波导。使用厚电镀金属掩模进行反应离子蚀刻(RIE),可以制造高度为几微米的脊结构。对于衬底的光约束,我们研究了直接杂键技术。由于预期的低传输损耗,我们展望了未来在量子光学领域的应用。
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引用次数: 11
Electrophoretic growth of Lead Titanate nanotubes 钛酸铅纳米管的电泳生长
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297718
M. Lanki, A. Nourmohammadi, M. Feiz
In the current research, we have utilized sol-gel electrophoresis technique to grow Lead Titanate (PbTiO3) nanotubes in porous anodic alumina template channels. The templates were prepared through two-step anodizing of pure aluminum foils in phosphoric acid. The porous templates were filled with a highly stabilized PbTiO3 sol prepared using titanium tetra-butoxide and lead acetate trihydrate, as the Ti and Pb precursors. A DC electric field was applied to drive the sol into the template channels. Tube formation was realized after etching of the template pores with 5wt. % caustic soda solution. Sol-gel electrophoresis method has already been used for preparing PbTiO3 thin films and nanowires, and by using it, high quality and more condenses layers than other usual sol-gel methods have been produced. But, to the best of our knowledge, this method has not been used for growth of PbTiO3 nanotubes. The heat treatment condition was evaluated based on the simultaneous thermal analysis (STA) results of the prepared and crystallization of the tetragonal perovskite structure by the X-ray diffraction (XRD) of the grown nanotubes. Scanning electron microscopy (SEM) investigations showed that close-packed PbTiO3 nanotubes have been grown in the template channels.
在本研究中,我们利用溶胶凝胶电泳技术在多孔阳极氧化铝模板通道中生长钛酸铅(PbTiO3)纳米管。采用磷酸阳极氧化法制备了纯铝箔模板。用四丁氧化钛和三水合乙酸铅作为钛和铅的前驱体制备了高度稳定的PbTiO3溶胶填充多孔模板。利用直流电场驱动溶胶进入模板通道。用5wt蚀刻模板孔后,实现了管的形成。%烧碱溶液。溶胶-凝胶电泳法已被用于制备PbTiO3薄膜和纳米线,与其他常用的溶胶-凝胶方法相比,可以制备出高质量和更多的凝聚态层。但是,据我们所知,这种方法还没有被用于PbTiO3纳米管的生长。通过x射线衍射(XRD)对纳米管的制备和结晶过程进行同步热分析(STA),评价了热处理条件。扫描电镜(SEM)研究表明,在模板通道中生长出密实排列的PbTiO3纳米管。
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引用次数: 1
期刊
Proceedings of ISAF-ECAPD-PFM 2012
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