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A New Architecture for High-Channel Color Router Using Optical Diffractive Neural Networks 基于衍射神经网络的高通道彩色路由器新架构
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202502721
Haodong Zhu, Ruiqi Yin, Zhengyu Chen, Yunxi Xiang, Ming Zhao, Zhenyu Yang
In multispectral imaging, traditional color filter arrays have long been constrained by an inherent limitation: the difficulty in achieving both high spectral accuracy and high optical efficiency simultaneously. To overcome this challenge, this paper applies the optical diffractive neural network (ODNN) to the Multi-channel color Router (MCR), proposing a novel MCR-ODNN architecture. MCR-ODNN uses multi-layer diffractive surfaces to achieve efficient spectral splitting and spatial routing of incident light, significantly enhancing multi-channel spectral separation capability while maintaining high optical energy efficiency. It supports a number of color routing channels far exceeding currently reported results. Research indicates that the multi-layer diffractive structure can effectively suppress inter-channel crosstalk, although its efficiency decays exponentially with an increasing number of layers. Furthermore, increasing the number of diffraction layers provides a greater performance improvement than increasing the neuron density within a single layer. This paper successfully fabricated and validated a 4-channel MCR-ODNN, with experimental measurements showing strong agreement with simulation data. This research provides an innovative technical pathway for high-fidelity color imaging and holds broad application prospects.
在多光谱成像中,传统的彩色滤光片阵列难以同时实现高光谱精度和高光效率。为了克服这一挑战,本文将光学衍射神经网络(ODNN)应用于多通道彩色路由器(MCR),提出了一种新的MCR-ODNN架构。MCR-ODNN采用多层衍射面实现了入射光的高效分光和空间路由,在保持高光能量效率的同时显著增强了多通道分光能力。它支持许多颜色路由通道,远远超过目前报道的结果。研究表明,多层衍射结构可以有效抑制信道间串扰,但其效率随着层数的增加呈指数衰减。此外,增加衍射层的数量比增加单层内的神经元密度提供了更大的性能改进。本文成功地制作并验证了一个4通道MCR-ODNN,实验测量结果与仿真数据吻合较好。本研究为高保真彩色成像提供了一条创新的技术途径,具有广阔的应用前景。
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引用次数: 0
Manipulation of Photonic Topological Edge and Corner States via Trivial Claddings 利用琐碎包层对光子拓扑边缘和角态的操纵
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202500685
Hai‐Xiao Wang, Li Liang, Shuai Shao, Shiwei Tang, Junhui Hu, Yin Poo, Jian‐Hua Jiang
Crystalline symmetry offers a powerful tool to realize photonic topological phases, in which additional trivial claddings are typically required to confine topological boundary states. However, the utility of the trivial cladding in manipulating topological waves is often overlooked. Here, we demonstrate two topologically distinct kagome photonic crystals (KPCs) based on different crystalline symmetries: ‐symmetric KPCs exhibit a quantum spin Hall phase, while ‐symmetric KPCs serve as trivial cladding. By tuning the geometric parameter of the trivial cladding, we observe that a pair of topological interface states featured with pseudospin‐momentum locking undergoes a phase transition, accompanied by the appearance and disappearance of corner states in a finite hexagonal supercell. Such a geometry‐induced band inversion is characterized by a sign change in the Dirac mass of the topological interface states and holds potential for applications such as rainbow trapping. Furthermore, we experimentally demonstrate that the corner states, which are a hallmark of higher‐order topology, also depend critically on the trivial cladding. Our work highlights the crucial role of trivial claddings on the formation of topological boundary states, and offers a novel approach for their manipulation.
晶体对称为实现光子拓扑相提供了一个强大的工具,在光子拓扑相中,通常需要额外的琐碎包层来限制拓扑边界态。然而,平凡包层在操纵拓扑波中的作用往往被忽视。在这里,我们展示了基于不同晶体对称性的两种拓扑结构不同的kagome光子晶体(KPCs):‐对称的KPCs表现出量子自旋霍尔相,而‐对称的KPCs作为平凡的包层。通过调整平凡包层的几何参数,我们观察到一对具有伪自旋动量锁定特征的拓扑界面态在有限六边形超级单体中经历了相变,并伴随着角态的出现和消失。这种几何诱导的能带反转以拓扑界面态狄拉克质量的符号变化为特征,具有彩虹捕获等应用的潜力。此外,我们通过实验证明,作为高阶拓扑标志的角态也严重依赖于平凡包层。我们的工作强调了琐碎包层在拓扑边界态形成中的关键作用,并提供了一种新的方法来操纵它们。
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引用次数: 0
A Hardware-Aware Photonic Spiking-DDPG Reinforcement Learning Architecture for Continuous Control 用于连续控制的硬件感知光子脉冲- ddpg强化学习体系结构
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202502481
Xintao Zeng, Shuiying Xiang, Haowen Zhao, Yanan Han, Wanting Yu, Zhiquan Huang, Shangxuan Shi, Xingxing Guo, Yahui Zhang, Yuechun Shi, Yue Hao
Reinforcement learning (RL) is vital for continuous decision-making in tasks such as robotic control and autonomous driving, yet conventional electronic hardware suffers from high energy consumption and latency due to the von Neumann bottleneck. In this paper, we propose a photonic spiking deep deterministic policy gradient (spiking-DDPG) RL architecture and demonstrate its hardware implementation on a photonic spiking neuromorphic chip (PSNC). The PSNC consists of a Mach–Zehnder interferometer (MZI)-based photonic synaptic array and distributed feedback laser with saturable absorber (DFB-SA)-based photonic spiking neuron arrays, arranged symmetrically on both sides, enabling complete spiking neuron functionality and scalable photonic spiking neural networks (PSNNs). We deploy the PSNN Actor on the PSNC and combine it with an artificial neural network (ANN)-based Critic to form the spiking-DDPG architecture. On the Pendulum-v1 and MountainCarContinuous-v0 continuous control tasks, the scores achieved were −275 and 90, respectively. The estimated energy consumption is 494.07 pJ/inf with an inference latency of 388.74 ps/inf, nearly an order of magnitude better than electronic counterparts. These results demonstrate that the photonic spiking-DDPG architecture enables ultrafast, energy-efficient RL for continuous control, offering a promising route toward real-time decision-making in robotics and autonomous systems.
强化学习(RL)对于机器人控制和自动驾驶等任务中的持续决策至关重要,但由于冯·诺伊曼瓶颈,传统的电子硬件存在高能耗和延迟问题。本文提出了一种光子尖峰深度确定性策略梯度(spike - ddpg) RL架构,并演示了其在光子尖峰神经形态芯片(PSNC)上的硬件实现。PSNC由基于Mach-Zehnder干涉仪(MZI)的光子突触阵列和分布反馈激光器组成,两侧对称排列的基于饱和吸收体(DFB-SA)的光子峰值神经元阵列,实现了完整的峰值神经元功能和可扩展的光子峰值神经网络(psnn)。我们将PSNN Actor部署在PSNC上,并将其与基于人工神经网络(ANN)的Critic相结合,形成了spiking-DDPG架构。在Pendulum-v1和MountainCarContinuous-v0连续控制任务中,得分分别为- 275和90。估计的能量消耗为494.07 pJ/inf,推理延迟为388.74 ps/inf,几乎比电子同行好一个数量级。这些结果表明,光子脉冲- ddpg架构实现了超快速、节能的RL连续控制,为机器人和自主系统的实时决策提供了一条有前途的途径。
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引用次数: 0
Tensorized Quantum Genetic Algorithm With Selective Evolution Strategy for Thin-Film Optical Inverse Problems 薄膜光学反问题的选择性演化张张化量子遗传算法
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202501880
Shuo Liu, Xiuguo Chen, Shiyuan Liu
Multilayer thin films are fundamental components of photonic and optoelectronic technologies, yet their inverse design and characterization remain limited by the trade-off between exploration of the solution space and computational cost. This paper proposes a tensorized quantum genetic algorithm (tQGA) with a selective evolution strategy, in which each individual evolves independently toward probabilistically chosen targets, maintaining diversity while ensuring stable convergence, and thereby enhancing optimization performance. A tensorized implementation further enables parallel updates of the population and simultaneous optical calculations for all solutions within each generation, achieving a 60–90× speedup over conventional frameworks, and up to 300–500× with GPU acceleration. The proposed tQGA is validated across three representative thin-film design and characterization tasks, consistently demonstrating superior accuracy, robustness, and computational efficiency. These results clearly demonstrate the significant potential of tQGA as a general and efficient framework for addressing inverse problems in thin-film optics.
多层薄膜是光子和光电子技术的基本组成部分,但其反向设计和表征仍然受到探索解决空间和计算成本之间权衡的限制。本文提出了一种具有选择性进化策略的张张化量子遗传算法(tQGA),其中每个个体向概率选择的目标独立进化,在保证稳定收敛的同时保持多样性,从而提高优化性能。张紧化的实现进一步实现了人口的并行更新和每一代所有解决方案的同步光学计算,比传统框架实现了60 - 90倍的加速,GPU加速可达300 - 500倍。提出的tQGA在三个具有代表性的薄膜设计和表征任务中进行了验证,始终显示出卓越的准确性,鲁棒性和计算效率。这些结果清楚地表明tQGA作为解决薄膜光学逆问题的通用和有效框架的巨大潜力。
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引用次数: 0
Advances in Position-Momentum Entanglement: A Versatile Tool for Quantum Technologies 位置-动量纠缠的进展:量子技术的通用工具
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202501358
Satyajeet Patil, Rajshree Swarnkar, Jonas L. Moos, Sebastian Töpfer, Sergio Tovar-Pérez, Jorge Fuenzalida, Markus Gräfe
Position-momentum entanglement is a versatile high-dimensional resource in quantum optics. From fundamental tests of reality to applications in quantum technologies, spatial entanglement has experienced significant growth in recent years. In this review, we explore these advances, beginning with the generation of spatial entanglement, followed by various types of measurements for certifying entanglement, and concluding with different quantum-based applications. We conclude the review with a discussion and outlook of the field.
位动量纠缠是量子光学中一种用途广泛的高维资源。从现实的基本测试到量子技术的应用,空间纠缠近年来经历了显著的增长。在这篇综述中,我们探讨了这些进展,从空间纠缠的产生开始,然后是各种类型的测量来证明纠缠,最后是不同的基于量子的应用。最后,我们对该领域进行了讨论和展望。
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引用次数: 0
Programmable Dual‐Mode Ultrafast All‐Optical Switching via Symmetry‐Broken Plasmonic Metasurface 基于对称破缺等离子体超表面的可编程双模超快全光开关
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202502756
Renxian Gao, Yufei Wang, Yaxin Wang, Yongjun Zhang, Jiahong Wen, Wenbin Chen, Runhong He, Ming‐De Li, Xiaoyu Zhao
All‐optical switches are fundamental to high‐speed information processing, yet their operational speeds are typically constrained by intrinsic material relaxation processes. Here, we demonstrate that the temporal trajectory of an ultrafast all‐optical switch can be deterministically programmed by pump polarization within a symmetry‐broken plasmonic metasurface. Femtosecond pump‐probe measurements identify two reversible operational regimes within a single meta‐atom, spanning a sub‐picosecond fast mode of 237 fs and a picosecond‐scale slow mode of 3.05 ps. A self‐consistent multiphysics framework, which couples electromagnetic field localization, nonequilibrium electron‐lattice energy exchange, and transient Drude renormalization, reveals that pump polarization dictates the nanoscale topology of optical absorption, thereby selectively activating distinct microscopic dielectric modulation pathways. Under one polarization state, absorption is strongly confined to nanoscale tips, triggering a localized, electron‐dominated nonequilibrium response that enables switching on a sub‐picosecond timescale. In contrast, orthogonal pumping redistributes energy toward extended regions of the meta‐atom, suppressing the tip‐confined electronic channel and promoting a lattice‐assisted relaxation process. These findings establish polarization‐controlled spatial mode engineering as a general principle for programming ultrafast optical dynamics, paving the way for reconfigurable photonic devices with in situ tunable temporal functionality.
全光开关是高速信息处理的基础,但其运行速度通常受到固有材料弛豫过程的限制。在这里,我们证明了超快全光开关的时间轨迹可以通过对称破缺等离子体超表面内的泵浦极化确定地编程。飞秒泵浦探针测量在单个元原子内确定了两种可逆的操作模式,跨越亚皮秒237 fs的快速模式和皮秒3.05 ps的慢模式。一个自一致的多物理场框架,耦合电磁场定位、非平衡电子晶格能量交换和瞬态德鲁德重整化,揭示了泵浦极化决定了光吸收的纳米级拓扑结构。从而选择性地激活不同的微观介质调制途径。在一种极化状态下,吸收被强烈地限制在纳米尺度的尖端,触发局部的、电子主导的非平衡响应,从而实现亚皮秒时间尺度的开关。相反,正交泵浦将能量重新分配到元原子的扩展区域,抑制了尖端受限的电子通道,促进了晶格辅助的弛豫过程。这些发现确立了偏振控制空间模式工程作为编程超快光学动力学的一般原则,为具有原位可调时间功能的可重构光子器件铺平了道路。
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引用次数: 0
Suppression of Ion Migration With a Composite Polymer Film in Perovskite Single‐crystal Photodetectors for Sensitive and Stable X‐Ray Imaging 复合聚合物薄膜对钙钛矿单晶探测器中离子迁移的抑制,用于灵敏和稳定的X射线成像
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202501802
Lu Xue, Yuxuan Du, Yuwei Li, Jingda Zhao, Xin Wang, Chengjun Liu, Damian Chinedu Onwudiwe, Byung Seong Bae, Mehmet ERTUĞRUL, Ying Zhu, Wei Lei, Xiaobing Zhang
Organic‐inorganic halide perovskite materials have demonstrated exceptional potential for X‐ray detection due to their high X‐ray attenuation coefficient and large mobility‐lifetime product. However, severe ion migration leads to signal current baseline drift and increased noise, limiting the imaging performance. In this work, we report a new mechanism by introducing a lattice‐matched MABr–PMMA composite polymer film, fabricated through a solution‐processed epitaxial growth method. The formation of a PN heterojunction, enabled by electron donation from the MABr component, not only provides efficient surface passivation but also effectively suppresses ion migration in MAPbBr 3 perovskite single crystals (SCs). Consequently, the X‐ray detector exhibits an ultralow baseline drift of 2.4 × 10 −6 nA cm −1 s −1 V −1 under a high electric field of 1000 V cm −1 , comparable to that of 2D perovskite SCs. It also achieves a high sensitivity of 1.46 × 10 5 µC Gyair −1 cm −2 and a low detection limit of 51.2 nGyair s −1 . Moreover, the device also demonstrates excellent stability and reliability under various demanding operational conditions, including high‐dose irradiation, high‐temperature, long‐term high biasing, and long‐term air exposure storage. In addition, the detector delivers high‐resolution and real‐time X‐ray imaging, highlighting its potential for high‐resolution integrated X‐ray imaging array applications.
有机-无机卤化物钙钛矿材料由于其高X射线衰减系数和大迁移率寿命产物,在X射线探测方面表现出了非凡的潜力。然而,严重的离子迁移导致信号电流基线漂移和噪声增加,限制了成像性能。在这项工作中,我们报告了一种新的机制,通过引入一种晶格匹配的MABr-PMMA复合聚合物薄膜,通过溶液加工外延生长方法制备。通过MABr组分的电子捐赠,形成PN异质结,不仅提供了有效的表面钝化,而且有效地抑制了mapbbr3钙钛矿单晶(SCs)中的离子迁移。因此,X射线探测器在1000 V cm−1的高电场下表现出2.4 × 10−6 nA cm−1 s−1 V−1的超低基线漂移,与2D钙钛矿SCs相当。该方法具有1.46 × 10 5µC Gyair - 1 cm - 2的高灵敏度和51.2 nGyair s - 1的低检测限。此外,该装置在各种苛刻的操作条件下也表现出优异的稳定性和可靠性,包括高剂量辐照、高温、长期高偏置和长期空气暴露储存。此外,该探测器提供高分辨率和实时X射线成像,突出了其高分辨率集成X射线成像阵列应用的潜力。
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引用次数: 0
Plasmonic Hot-Carrier Transfer in WO3-x–Bi2O2Se Heterostructures for Ultrafast Optical Switching 超快光交换中WO3-x-Bi2O2Se异质结构的等离子体热载流子转移
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202502525
Junting Liu, Hongkun Nie, Yankai Cheng, Xinlei Zhang, Jiawen Lv, Lulu Dong, Shande Liu, Junpeng Lu, Zhenhua Ni, Baitao Zhang
Bi2O2Se nanoplates, a semiconductor saturable absorber (SA) characterized by strong nonlinear absorption and excellent stability, are typically hindered by scattering losses introduced during defect modulation. In this study, by combining with a non-metallic semiconductor WO3-x, the WO3-x/Bi2O2Se plasmonic heterostructure is developed to sufficiently overcome the aforementioned limitations. The as-developed heterostructure SA is applied for 1040 nm Yb,Y:CaF2-SrF2 mode-locked lasers, realizing ultrashort pulses of ∼364 fs at a significantly reduced absorbed pump threshold of 2.02 W and an average output power of 424 mW. Finite-difference time-domain (FDTD) simulations, transient absorption spectroscopy, and open-aperture Z-scan measurements collectively reveal that hot-carrier transfer mediated by localized surface plasmon resonance significantly promotes Auger recombination in Bi2O2Se, thereby shortening carrier lifetimes. This effect is particularly pronounced at 1050 nm, manifesting as a substantial increase in the nonlinear absorption coefficient from −(507 ± 4) to −(1587 ± 14) cm MW−1. The resultant plasmon-enhanced nonlinear optical response facilitates the realization of ultrafast pulses from a mode-locked laser operating at lower thresholds and narrower pulse widths.
Bi2O2Se纳米板是一种具有强非线性吸收和优异稳定性的半导体可饱和吸收材料,但在缺陷调制过程中会受到散射损失的影响。在本研究中,通过与非金属半导体WO3-x结合,开发了WO3-x/Bi2O2Se等离子异质结构,充分克服了上述局限性。该异质结构SA应用于1040 nm的Yb,Y:CaF2-SrF2锁模激光器,实现了~ 364 fs的超短脉冲,吸收泵浦阈值显著降低为2.02 W,平均输出功率为424 mW。时域有限差分(FDTD)模拟、瞬态吸收光谱和开孔z扫描测量共同表明,局部表面等离子体共振介导的热载子转移显著促进了Bi2O2Se中的俄歇复合,从而缩短了载流子寿命。这种效应在1050 nm处特别明显,表现为非线性吸收系数从-(507±4)到-(1587±14)cm MW−1的大幅增加。由此产生的等离子体增强非线性光学响应有助于实现锁模激光器在较低阈值和较窄脉冲宽度下的超快脉冲。
{"title":"Plasmonic Hot-Carrier Transfer in WO3-x–Bi2O2Se Heterostructures for Ultrafast Optical Switching","authors":"Junting Liu, Hongkun Nie, Yankai Cheng, Xinlei Zhang, Jiawen Lv, Lulu Dong, Shande Liu, Junpeng Lu, Zhenhua Ni, Baitao Zhang","doi":"10.1002/lpor.202502525","DOIUrl":"https://doi.org/10.1002/lpor.202502525","url":null,"abstract":"Bi<sub>2</sub>O<sub>2</sub>Se nanoplates, a semiconductor saturable absorber (SA) characterized by strong nonlinear absorption and excellent stability, are typically hindered by scattering losses introduced during defect modulation. In this study, by combining with a non-metallic semiconductor WO<sub>3-x</sub>, the WO<sub>3-x</sub>/Bi<sub>2</sub>O<sub>2</sub>Se plasmonic heterostructure is developed to sufficiently overcome the aforementioned limitations. The as-developed heterostructure SA is applied for 1040 nm Yb,Y:CaF<sub>2</sub>-SrF<sub>2</sub> mode-locked lasers, realizing ultrashort pulses of ∼364 fs at a significantly reduced absorbed pump threshold of 2.02 W and an average output power of 424 mW. Finite-difference time-domain (FDTD) simulations, transient absorption spectroscopy, and open-aperture Z-scan measurements collectively reveal that hot-carrier transfer mediated by localized surface plasmon resonance significantly promotes Auger recombination in Bi<sub>2</sub>O<sub>2</sub>Se, thereby shortening carrier lifetimes. This effect is particularly pronounced at 1050 nm, manifesting as a substantial increase in the nonlinear absorption coefficient from −(507 ± 4) to −(1587 ± 14) cm MW<sup>−1</sup>. The resultant plasmon-enhanced nonlinear optical response facilitates the realization of ultrafast pulses from a mode-locked laser operating at lower thresholds and narrower pulse widths.","PeriodicalId":204,"journal":{"name":"Laser & Photonics Reviews","volume":"93 1","pages":""},"PeriodicalIF":11.0,"publicationDate":"2026-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146089251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microscopic 3D Surface Imaging With Annular Spectrum Sampling Parallel Single-Pixel Imaging: Resistant to Global Illumination 微观三维表面成像与环形光谱采样并行单像素成像:抗全局照明
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202502609
Chengmin Liu, Feifei Chen, Biao Li, Zhengdong Chen, Yongfu Wen, Qican Zhang, Zhoujie Wu
The trend toward device miniaturization and precision manufacturing poses challenges for microscopic 3D surface imaging under global illumination, due to the strong inter-reflections and subsurface scattering. Conventional structured-light methods often fail in dealing with such conditions because of their inherent point-to-point triangulation rule. Here, we propose a global illumination-resistant microscopic 3D surface imaging technique based on annular spectrum sampling parallel single-pixel imaging (ASS-PSI). By exploiting the point-to-plane imaging ability of single-pixel detection and establishing the global illumination response (GIR) model, the mixed direct and global illumination components can be effectively separated at each camera pixel. Furthermore, an annular spectrum sampling strategy is proposed to mitigate the impact of structured light on illumination interference while enhancing measurement efficiency. With discarding unstable low-frequency illumination, fewer spectrum coefficients yield higher accuracy, turning “less” into “more” under harsh conditions. Experimental results under strong inter-reflection and subsurface scattering conditions demonstrate that ASS-PSI achieves superior robustness compared to the conventional approaches. These advances make ASS-PSI a promising solution for robust microscopic 3D imaging in advanced manufacturing and biomedical applications.
器件小型化和精密制造的趋势给全局照明下的微观三维表面成像带来了挑战,因为它们具有强烈的相互反射和次表面散射。传统的结构光方法由于其固有的点对点三角剖分规则,往往无法处理这种情况。在此,我们提出了一种基于环形光谱采样并行单像素成像(ASS-PSI)的全局抗光照微观三维表面成像技术。利用单像素检测的点对平面成像能力,建立全局光照响应(GIR)模型,可以在每个相机像素处有效分离混合直接和全局光照分量。此外,提出了一种环形光谱采样策略,以减轻结构光对照明干扰的影响,同时提高测量效率。通过摒弃不稳定的低频照明,更少的光谱系数产生更高的精度,在恶劣条件下将“少”变为“多”。在强间反射和次表面散射条件下的实验结果表明,与传统方法相比,ASS-PSI具有更好的鲁棒性。这些进步使ASS-PSI成为先进制造和生物医学应用中强大的微观3D成像解决方案。
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引用次数: 0
Thermally Driven Eu2+ Site-Selective Occupation Enables Narrow-Band Green Emission in an Oxolithoaluminate Phosphor for Backlight Display Applications 热驱动的Eu2+位置选择性占用使背光显示应用的氧基铝酸盐荧光粉中的窄带绿色发射成为可能
IF 11 1区 物理与天体物理 Q1 OPTICS Pub Date : 2026-01-31 DOI: 10.1002/lpor.202502302
Chenyang Zhan, Zihao Wang, Sisi Liang, Haomiao Zhu
Developing narrow-band green phosphors via selective site occupancy engineering remains challenging for wide-color-gamut displays. While Eu2+-doped UCr4C4-type nitride and oxynitride lithoaluminates exhibit narrow-band emission and high thermal stability, their emission spectra are confined to red–orange region due to the pronounced nephelauxetic effect of N3− ions. To address this limitation, we design a nitrogen-free oxolithoaluminate phosphor, Sr5/6Li17/6-xAl7/6-xZn2xO4:Eu2+ (SLAZO:Eu2+), synthesized via a stepwise solid-state reaction with Zn2+ doping ensuring phase stabilization. Crucially, elevating the sintering temperature from 780°C to 870°C confined Eu2+ occupancy from dispersed Sr1–Sr5 sites (distorted [SrO8] cubes) to larger Sr2a/b and Sr3a/b sites, thereby transforming emission from dual-band yellow–green to a singular narrow-band green peak at 528 nm. The optimized phosphor exhibits a narrow full-width-at-half-maximum (FWHM) of 51 nm (1784 cm−1) under 400 nm excitation. It has an internal/external quantum yield of 41.6%/20.1% and maintains 54.2% of its emission intensity at 150°C relative to 25°C. A white LED device fabricated with SLAZO:Eu2+, K2TiF6:Mn4+, and a 450 nm blue chip achieves a color gamut covering 97.4% of the National Television System Committee standard. This study demonstrates thermally-driven site-selective occupation as an effective strategy for emission tuning and validates SLAZO:Eu2+ as a promising narrow-band green emitter for next-generation displays.
通过选择性占位工程开发窄带绿色荧光粉对于宽色域显示仍然具有挑战性。Eu2+掺杂的ucr4c4型氮化物和氧氮化石铝酸盐具有窄带发射和高热稳定性,但由于N3−离子的显着的散射效应,其发射光谱被限制在红橙区。为了解决这一限制,我们设计了一种无氮的氧基铝酸盐荧光粉,Sr5/6Li17/6-xAl7/6-xZn2xO4:Eu2+ (SLAZO:Eu2+),通过Zn2+掺杂的逐步固相反应合成。关键是,将烧结温度从780°C提高到870°C,限制了Eu2+从分散的Sr1-Sr5位点(扭曲的[SrO8]立方体)占据到更大的Sr2a/b和Sr3a/b位点,从而将发射从双频黄绿色转变为528 nm的单一窄带绿色峰值。优化后的荧光粉在400 nm激发下的半最大全宽(FWHM)为51 nm (1784 cm−1)。它的内/外量子产率为41.6%/20.1%,相对于25°C,在150°C时保持了54.2%的发射强度。由SLAZO:Eu2+, K2TiF6:Mn4+和450nm蓝芯片制成的白光LED器件的色域覆盖了国家电视系统委员会标准的97.4%。本研究证明了热驱动的位置选择性占用是一种有效的发射调谐策略,并验证了SLAZO:Eu2+作为下一代显示器的有前途的窄带绿色发射器。
{"title":"Thermally Driven Eu2+ Site-Selective Occupation Enables Narrow-Band Green Emission in an Oxolithoaluminate Phosphor for Backlight Display Applications","authors":"Chenyang Zhan, Zihao Wang, Sisi Liang, Haomiao Zhu","doi":"10.1002/lpor.202502302","DOIUrl":"https://doi.org/10.1002/lpor.202502302","url":null,"abstract":"Developing narrow-band green phosphors via selective site occupancy engineering remains challenging for wide-color-gamut displays. While Eu<sup>2+</sup>-doped UCr<sub>4</sub>C<sub>4</sub>-type nitride and oxynitride lithoaluminates exhibit narrow-band emission and high thermal stability, their emission spectra are confined to red–orange region due to the pronounced nephelauxetic effect of N<sup>3−</sup> ions. To address this limitation, we design a nitrogen-free oxolithoaluminate phosphor, Sr<sub>5/6</sub>Li<sub>17/6-</sub><i><sub>x</sub></i>Al<sub>7/6-</sub><i><sub>x</sub></i>Zn<sub>2</sub><i><sub>x</sub></i>O<sub>4</sub>:Eu<sup>2+</sup> (SLAZO:Eu<sup>2+</sup>), synthesized via a stepwise solid-state reaction with Zn<sup>2+</sup> doping ensuring phase stabilization. Crucially, elevating the sintering temperature from 780°C to 870°C confined Eu<sup>2+</sup> occupancy from dispersed Sr1–Sr5 sites (distorted [SrO<sub>8</sub>] cubes) to larger Sr2a/b and Sr3a/b sites, thereby transforming emission from dual-band yellow–green to a singular narrow-band green peak at 528 nm. The optimized phosphor exhibits a narrow full-width-at-half-maximum (FWHM) of 51 nm (1784 cm<sup>−1</sup>) under 400 nm excitation. It has an internal/external quantum yield of 41.6%/20.1% and maintains 54.2% of its emission intensity at 150°C relative to 25°C. A white LED device fabricated with SLAZO:Eu<sup>2</sup><sup>+</sup>, K<sub>2</sub>TiF<sub>6</sub>:Mn<sup>4</sup><sup>+</sup>, and a 450 nm blue chip achieves a color gamut covering 97.4% of the National Television System Committee standard. This study demonstrates thermally-driven site-selective occupation as an effective strategy for emission tuning and validates SLAZO:Eu<sup>2+</sup> as a promising narrow-band green emitter for next-generation displays.","PeriodicalId":204,"journal":{"name":"Laser & Photonics Reviews","volume":"81 1","pages":""},"PeriodicalIF":11.0,"publicationDate":"2026-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146089254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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