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Schwinger-Keldysh non-perturbative field theory of open quantum systems beyond the Markovian regime: Application to spin-boson and spin-chain-boson models. 超越马尔可夫状态的开放量子系统的Schwinger-Keldysh非微扰场论:在自旋玻色子和自旋链玻色子模型中的应用。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-12-05 DOI: 10.1088/1361-6633/ae2888
Felipe Reyes-Osorio,Federico Garcia-Gaitan,David J Strachan,Petr Plechac,Stephen Richard Clark,Branislav K Nikolic
We develop a unified framework for open quantum systems composed of many mutually interacting quantum spins, or any isomorphic systems like qubits and qudits, surrounded by one or more independent bosonic baths. Our framework, based on Schwinger-Keldysh field theory (SKFT), can handle arbitrary spin value S, dimensionality of space, and geometry while being applicable to a large parameter space for system and bath or their coupling. It can probe regimes in which non-Markovian dynamics and nonperturbative effects pose formidable challenges for other state-of-the-art theoretical methods. This is achieved by working with the two-particle irreducible (2PI) effective action, which resums classes of Feynman diagrams of SKFT to an infinite order. Furthermore, such diagrams are generated via an expansion in 1/N, where N is the number of Schwinger bosons we employ to map spin operators onto canonically commuting ones, rather than via conventional expansion in system-bath coupling constant. We carefully benchmark our SKFT+2PI-computed results vs. numerically (quasi)exact ones from tensor network calculations applied to the archetypical spin-boson model where both methodologies are applicable. Additionally, we demonstrate the capability of SKFT+2PI to handle a much more complex spin-chain-boson model with multiple baths interacting with each spin where no benchmark from other methods is available at present. The favorable numerical cost of solving integro-differential equations produced by the SKFT+2PI framework with an increasing number of spins and time steps makes it a promising route for simulating driven-dissipative systems in quantum computing, quantum magnonics, and quantum spintronics. .
我们为开放量子系统开发了一个统一的框架,该系统由许多相互作用的量子自旋组成,或任何同构系统,如量子位和量子位,被一个或多个独立的玻色子场包围。该框架基于Schwinger-Keldysh场理论(SKFT),可以处理任意的自旋值S、空间维数和几何形状,同时适用于系统和系统及其耦合的大参数空间。它可以探索非马尔可夫动力学和非摄动效应对其他最先进的理论方法构成巨大挑战的制度。这是通过使用两粒子不可约(2PI)有效作用来实现的,它将SKFT的费曼图类恢复到无限阶。此外,这种图是通过在1/N中的展开生成的,其中N是我们用来将自旋算子映射到标准交换算子的Schwinger玻色子的数量,而不是通过在系统池耦合常数中的常规展开。我们仔细地将我们的SKFT+ 2pi计算结果与应用于原型自旋玻色子模型的张量网络计算的数值(准)精确结果进行了基准测试,其中两种方法都适用。此外,我们展示了SKFT+2PI处理更复杂的自旋链-玻色子模型的能力,其中每个自旋与多个浴相互作用,目前没有其他方法的基准。求解由SKFT+2PI框架产生的积分-微分方程的有利数值成本具有越来越多的自旋和时间步长,使其成为模拟量子计算,量子磁学和量子自旋电子学中驱动耗散系统的有前途的途径。 。
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引用次数: 0
Kolmogorov modes and linear response of jump-diffusion models. 跳跃-扩散模型的Kolmogorov模和线性响应。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-11-20 DOI: 10.1088/1361-6633/ae2206
Mickael Chekroun,Niccolò Zagli,Valerio Lucarini
We present a generalization of linear response theory for mixed jump-diffusion models-which combine both Gaussian and Lévy noise forcings that interact with the nonlinear dynamics-by deriving a comprehensive response formulas that accounts for perturbations to both the drift term and the jumps law. This class of models is particularly relevant for parameterizing the effects of unresolved scales in complex systems. Our formulas are thus particularly relevant to quantify uncertainties in either what needs to be parameterized (e.g. the jumps law), or to measure dynamical changes due to perturbations of the drift term (e.g. parameter variations). By generalizing the concepts of Kolmogorov operators and Green's functions, we obtain new forms of fluctuation-dissipation relations. The resulting response is decomposed into contributions from the eigenmodes of the Kolmogorov operator, providing a fresh look into the intimate relationship between a system's natural and forced variability. We demonstrate the theory's predictive power with two distinct climate-centric applications. First, we apply our framework to a paradigmatic El Niño-Southern Oscillation (ENSO) model subject to state-dependent jumps and additive white noise, showing how the theory accurately predicts the system's response to perturbations and how Kolmogorov modes can be used to diagnose its complex time variability. In a second, more challenging application, we use our linear response theory to perform accurate climate change projections in the Ghil-Sellers (GS) energy balance climate model, which is a spatially-extended model forced here by a spatio-temporal αstable process. This work provides a comprehensive approach to climate modeling and prediction that enriches Hasselmann's program, with implications for understanding climate sensitivity, detection and attribution of climate change, and assessing the risk of climate tipping points. Our results may find applications beyond the realm of climate, and seem of relevance for epidemiology, biology, finance, and quantitative social sciences, among others.
我们对混合跳跃-扩散模型的线性响应理论进行了推广,该模型结合了与非线性动力学相互作用的高斯和l杂讯强迫,推导了一个综合的响应公式,该公式考虑了漂移项和跳跃律的扰动。这类模型特别适用于参数化复杂系统中未确定尺度的影响。因此,我们的公式与量化需要参数化的不确定性(例如跳跃定律)或测量由于漂移项的扰动(例如参数变化)而引起的动态变化特别相关。通过推广Kolmogorov算子和Green函数的概念,得到了波动-耗散关系的新形式。由此产生的响应被分解为Kolmogorov算子的特征模态的贡献,为系统的自然变率和强迫变率之间的密切关系提供了一个新的视角。我们通过两种不同的以气候为中心的应用来证明该理论的预测能力。首先,我们将我们的框架应用于一个受状态依赖跳跃和加性白噪声影响的范式El Niño-Southern振荡(ENSO)模型,展示了该理论如何准确地预测系统对扰动的响应,以及如何使用Kolmogorov模式来诊断其复杂的时间变变性。在第二个更具挑战性的应用中,我们使用我们的线性响应理论在gil - sellers (GS)能量平衡气候模型中进行准确的气候变化预测,该模型是一个由时空α稳定过程强迫的空间扩展模型。这项工作为气候建模和预测提供了一种全面的方法,丰富了Hasselmann的计划,对理解气候敏感性、气候变化的检测和归因以及评估气候临界点的风险具有重要意义。我们的结果可能会在气候领域之外找到应用,并且似乎与流行病学,生物学,金融和定量社会科学等相关。
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引用次数: 0
Order parameter for non-equilibrium dissipation and ideal glass. 非平衡耗散和理想玻璃的序参量。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-31 DOI: 10.1088/1361-6633/ae1a15
Jun-Ying Jiang,Liang Gao,Hai-Bin Yu
Glass materials, as quintessential non-equilibrium systems, exhibit properties such as energy dissipation that are highly sensitive to their preparation histories. A key challenge has been identifying a unified order parameter to rationalize these properties. Here, we demonstrate that a configurational distance metric can effectively collapse energy dissipation data across diverse preparation histories and testing protocols, including varying cooling rates, aging processes, probing times, and the amplitudes of mechanical excitation, as long as the temperature remains above the kinetic ideal glass transition temperature (where the extrapolated structural relaxation time diverges). Our results provide a unified description of the non-equilibrium dissipation and suggest that the putative concept of the kinetic ideal glass transition is imprinted in material characteristics.
玻璃材料作为典型的非平衡系统,表现出对其制备历史高度敏感的能量耗散等特性。一个关键的挑战是确定一个统一的顺序参数来使这些属性合理化。在这里,我们证明了一个构型距离度量可以有效地分解不同制备历史和测试方案的能量耗散数据,包括不同的冷却速率、老化过程、探测时间和机械激励幅度,只要温度保持在动力学理想玻璃化转变温度之上(外推的结构弛豫时间发散)。我们的结果提供了对非平衡耗散的统一描述,并表明假定的动力学理想玻璃化转变概念烙印在材料特性中。
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demonstrate that a configurational distance metric can effectively collapse energy dissipation data across diverse preparation histories and testing protocols, including varying cooling rates, aging processes, probing times, and the amplitudes of mechanical excitation, as long as the temperature remains above the kinetic ideal glass transition temperature (where the extrapolated structural relaxation time diverges). Our results provide a unified description of the non-equilibrium dissipation and suggest that the putative concept of the kinetic ideal glass transition is imprinted in material characteristics.","PeriodicalId":21110,"journal":{"name":"Reports on Progress in Physics","volume":"1 1","pages":""},"PeriodicalIF":18.1,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145411601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Longitudinal acoustic spin and global spin-orbit interaction in vortex beams. 涡旋光束中的纵向声自旋和全局自旋轨道相互作用。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-21 DOI: 10.1088/1361-6633/ae15bc
Wei Wang,Yang Tan,Jingjing Liu,JianHua Jiang,Bin Liang,Jianchun Cheng
Spin and orbital angular momenta (AM) are of fundamental importance in physics. Acoustic waves, as typical longitudinal waves, have been well studied in terms of orbital AM but not for spin AM, as they are often perceived as spin-0 waves. Although spin AM density has been found in acoustics, the total spin AM is, however, often vanishing. At material boundaries, finite total spin AM and spin-orbit interaction can arise for evanescent waves but only for transverse spin AM not for longitudinal spin AM. Here, from a self-consistent theoretical frame, we establish the spin, orbital, and total AM of acoustic vortex beams, and discover that a non-zero integral longitudinal spin AM is carried by the propagating acoustic field. With the longitudinal acoustic spin, we unveil a new mechanism of spin-orbit interaction emerging when a vortex beam is compressed or expanded. Moreover, we reveal the connection and distinction between the acoustic canonical-Minkowski and kinetic-Abraham AM, and prove that only the former is conserved under the corresponding symmetry. Based on these findings, we propose new strategies for manipulating acoustic spin and orbital AM. Our discovery elucidates new fundamental aspects of spin and orbital AM as well as their interplay in acoustics, which can be extended to other classical waves and may open up new ways for AM-based applications in these systems.
自旋角动量和轨道角动量在物理学中具有重要的基础意义。声波作为典型的纵波,已经在轨道调幅方面进行了很好的研究,但对于自旋调幅却没有,因为它们通常被认为是自旋0波。虽然在声学中发现了自旋调幅的密度,但总的自旋调幅常常消失。在材料边界处,有限总自旋AM和自旋轨道相互作用可以产生倏逝波,但只有横向自旋AM而不是纵向自旋AM。本文从一个自洽的理论框架出发,建立了声涡旋波束的自旋、轨道和总调幅,发现了一个非零积分纵向自旋调幅是由传播的声场携带的。利用纵向声自旋,我们揭示了涡旋束被压缩或膨胀时出现的自旋-轨道相互作用的新机制。此外,我们揭示了声学经典- minkowski和动力学- abraham AM之间的联系和区别,并证明了在相应的对称下只有前者是守恒的。基于这些发现,我们提出了操纵声自旋和轨道调幅的新策略。我们的发现阐明了自旋和轨道调幅的新基本方面以及它们在声学中的相互作用,这可以扩展到其他经典波,并可能为这些系统中基于调幅的应用开辟新的途径。
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引用次数: 0
Macroscopicity and observational deficit in states, operations, and correlations. 宏观和观测缺陷的状态,操作,和相关性。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-16 DOI: 10.1088/1361-6633/ae140e
Teruaki Nagasawa,Eyuri Wakakuwa,Kohtaro Kato,Francesco Buscemi
To understand the emergence of macroscopic irreversibility from microscopic reversible dynamics, the idea of coarse-graining plays a fundamental role. In this work, we develop a unified inferential framework for macroscopic states, that is, coarse descriptions of microscopic quantum systems that can be inferred from macroscopic measurements. Building on quantum statistical sufficiency and Bayesian retrodiction, we characterize macroscopic states through equivalent abstract (algebraic) and explicit (constructive) formulations.Central to our approach is the notion of observational deficit, which quantifies the degree of irretrodictability of a state relative to a prior and a measurement. This leads to a general definition of macroscopic entropy as an inferentially grounded measure of asymmetry under Bayesian inversion. We formalize this structure in terms of inferential reference frames, defined by the pair consisting of a prior and a measurement, which encapsulate the observer's informational perspective.We then formulate a resource theory of microscopicity, treating macroscopic states as free states and introducing a hierarchy of macroscopicity-non-generating operations. This theory unifies and extends existing resource theories of coherence, athermality, and asymmetry.Finally, we apply the framework to study quantum correlations under observational constraints, introducing the notion of observational discord and deriving necessary and sufficient conditions for their vanishing in terms of information recoverability.
为了理解微观可逆动力学中宏观不可逆性的产生,粗粒化思想起着基本的作用。在这项工作中,我们为宏观状态开发了一个统一的推理框架,即可以从宏观测量推断出的微观量子系统的粗略描述。在量子统计充足性和贝叶斯回溯的基础上,我们通过等效的抽象(代数)和显式(构造)公式表征宏观状态。我们方法的核心是观测缺陷的概念,它量化了相对于先验和测量的状态的不可逆转程度。这导致宏观熵的一般定义为贝叶斯反演下的不对称性的推论基础度量。我们将这种结构形式化为推理参考框架,由先验和测量组成的对定义,它封装了观察者的信息视角。然后,我们制定了微观资源理论,将宏观状态视为自由状态,并引入了宏观-非生成操作的层次结构。该理论统一并扩展了现有的相干性、热性和不对称性资源理论。最后,我们应用该框架研究了观测约束下的量子相关,引入了观测不和谐的概念,并从信息可恢复性的角度推导了它们消失的充分必要条件。
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引用次数: 0
Spin-momentum locking in locally noncentrosymmetric quantum materials. 局部非中心对称量子材料中的自旋动量锁定。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-15 DOI: 10.1088/1361-6633/ae1379
Ke Zhang,Yusen Feng,Yu Chen,Jie Gong,Lin Xu,Zhenhua Wu,Chang Liu,Chaoyu Chen,Kenya Shimada,Liang Qiao
Abstract The primary focus of spintronics is the investigation of novel spin splitting effects and related spin-polarized quantum materials, which have been extensively pursued for their potential applications. The structural inversion asymmetric Rashba splitting, bulk inversion asymmetric Dresselhaus splitting, and ferromagnetic spin polarization derived from Zeeman splitting constitute the foundation of traditional spintronics. From a symmetry perspective, ferromagnets achieve spin splitting through the breaking of time-reversal symmetry. However, in time-reversal symmetric and inversion symmetric materials with spin-orbit coupling, unexpected forms of spin-splitting can also arise by breaking local inversion symmetry, known as hidden spin-momentum locking, bringing infinite vitality to fundamental research and future applications. This review first highlights notable advancements in spin-splitting within centrosymmetric systems, then examines the influence of hidden spin-momentum locking on superconducting and topological behaviors, concluding with a discussion on prospective opportunities in this emerging field. Given the rapid progress in non-relativistic spin splittings-particularly within altermagnetism-we develop appropriately scaled extensions to advance this emerging field. This review seeks to enhance our understanding of the "hidden effect" in fundamental research while uncovering additional quantum phenomena that emerge from introducing extra degrees of freedom-an aspect that underscores the unique appeal of quantum materials capable of continuously demonstrating novel effects. .
摘要自旋电子学的主要焦点是研究新的自旋分裂效应和相关的自旋极化量子材料,这些材料因其潜在的应用而受到广泛的关注。结构反演非对称Rashba分裂、体反演非对称Dresselhaus分裂以及由Zeeman分裂衍生的铁磁自旋极化构成了传统自旋电子学的基础。从对称性的角度来看,铁磁体是通过时间反转对称性的破坏来实现自旋分裂的。然而,在具有自旋-轨道耦合的时间反转对称和反演对称材料中,也可以通过打破局部反演对称而产生意想不到的自旋分裂形式,即隐性自旋动量锁定,为基础研究和未来应用带来无限活力。这篇综述首先强调了在中心对称系统中自旋分裂的显著进展,然后研究了隐藏自旋动量锁定对超导和拓扑行为的影响,最后讨论了这一新兴领域的潜在机会。鉴于非相对论性自旋分裂的快速发展,特别是在交替磁场中,我们开发了适当的扩展来推进这一新兴领域。这篇综述旨在加强我们对基础研究中“隐藏效应”的理解,同时揭示引入额外自由度所产生的额外量子现象——这一方面强调了量子材料能够不断展示新效应的独特吸引力。
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The primary focus of spintronics is the investigation of novel spin splitting effects and related spin-polarized quantum materials, which have been extensively pursued for their potential applications. The structural inversion asymmetric Rashba splitting, bulk inversion asymmetric Dresselhaus splitting, and ferromagnetic spin polarization derived from Zeeman splitting constitute the foundation of traditional spintronics. From a symmetry perspective, ferromagnets achieve spin splitting through the breaking of time-reversal symmetry. However, in time-reversal symmetric and inversion symmetric materials with spin-orbit coupling, unexpected forms of spin-splitting can also arise by breaking local inversion symmetry, known as hidden spin-momentum locking, bringing infinite vitality to fundamental research and future applications. This review first highlights notable advancements in spin-splitting within centrosymmetric systems, then examines the influence of hidden spin-momentum locking on superconducting and topological behaviors, concluding with a discussion on prospective opportunities in this emerging field. Given the rapid progress in non-relativistic spin splittings-particularly within altermagnetism-we develop appropriately scaled extensions to advance this emerging field. This review seeks to enhance our understanding of the \"hidden effect\" in fundamental research while uncovering additional quantum phenomena that emerge from introducing extra degrees of freedom-an aspect that underscores the unique appeal of quantum materials capable of continuously demonstrating novel effects.&#xD.","PeriodicalId":21110,"journal":{"name":"Reports on Progress in Physics","volume":"1 1","pages":""},"PeriodicalIF":18.1,"publicationDate":"2025-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145288334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-frequency non-phononic vibrations of amorphous solids. 非晶固体的低频非声子振动。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-01 DOI: 10.1088/1361-6633/ae0e34
Lijin Wang,Ding Xu,Shiyun Zhang,Yunhuan Nie,Hua Tong,Ning Xu
The inherent disorder imparts amorphous solids with a range of anomalous yet universally observed mechanical and thermodynamic properties at low temperatures, which distinguish them from their crystalline counterparts. A comprehensive understanding of these low-temperature anomalies is imperative from all perspectives but still seems to be a long-lasting challenge. In particular, it has long been recognized that low-frequency vibrations play an indispensable role in understanding low-temperature properties of amorphous solids. One noteworthy aspect is that the past decade has witnessed a remarkable surge in numerical and theoretical investigations of the low-frequency non-phononic spectrum beyond the Debye prediction; however, despite great efforts and advancements, some debated problems remain unsolved. Therefore, the discussion of the low-frequency non-phononic spectrum constitutes the primary focus of this review. Additionally, insights provided by low-frequency non-phononic vibrations in comprehending other elusive issues, such as the glass transition, phonon attenuation, two-level systems, and soft spots, are discussed.
固有的无序赋予非晶固体在低温下具有一系列异常但普遍观察到的机械和热力学性质,这将它们与晶体相区别。从各个角度全面了解这些低温异常是必要的,但似乎仍然是一个长期的挑战。特别是,低频振动在理解非晶固体的低温特性方面起着不可或缺的作用。一个值得注意的方面是,在过去的十年中,对低频非声子谱的数值和理论研究出现了显著的激增,超出了德拜的预测;然而,尽管付出了巨大的努力和进步,一些争论的问题仍然没有得到解决。因此,低频非声子谱的讨论是本综述的主要重点。此外,还讨论了低频非声子振动在理解其他难以捉摸的问题(如玻璃化跃迁、声子衰减、两能级系统和软点)方面提供的见解。
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引用次数: 0
Sufficient criteria for absolute separability in arbitrary dimensions via linear map inverses. 通过线性映射逆求任意维绝对可分性的充分准则。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-29 DOI: 10.1088/1361-6633/ae0cfa
Jofre Abellanet Vidal,Guillem Müller-Rigat,Grzegorz Rajchel-Mieldzioć,Anna Sanpera
Quantum states that remain separable (i.e., not entangled) under any global unitary transformation are known as absolutely separable and form a convex set. Despite extensive efforts, the complete characterization of this set remains largely unknown. In this work, we employ linear maps and their inverses to derive new sufficient analytical conditions for absolute separability in arbitrary dimensions, providing extremal points of this set and improving its characterization. Additionally, we employ convex geometry optimization to refine the characterization of the set when multiple non-comparable criteria for absolute separability are available. We also address the closely related problem of characterizing the absolute PPT (positive partial transposition) set, which consists of quantum states that remain positive under partial transposition across all unitary transformations. Finally, we extend our results to multipartite states.
在任意全局酉变换下保持可分(即不纠缠)的量子态称为绝对可分,它们构成凸集。尽管进行了广泛的努力,但这一群体的完整特征在很大程度上仍然未知。在这项工作中,我们利用线性映射及其逆得到了任意维绝对可分性的新的充分解析条件,给出了该集合的极值点并改进了它的表征。此外,当存在多个不可比较的绝对可分性标准时,我们采用凸几何优化来改进集合的表征。我们还解决了密切相关的问题,即描述绝对PPT(正偏转置)集,它由在所有幺正变换下偏转置保持正的量子态组成。最后,我们将结果扩展到多部态。
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引用次数: 0
Strain regulation by interface engineering in perovskite solar cells. 钙钛矿太阳能电池界面工程应变调节。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-26 DOI: 10.1088/1361-6633/ae0c22
Yang Ding,Hengyue Li,Jianhui Chang,Liming Ding,Junliang Yang
Perovskite solar cells (PSCs) have garnered attention for their high efficiency and low production costs. However, long-term operational stability remains a significant challenge due to strain-induced degradation that impacts the structural integrity and performance of the perovskite layer. Strain, arising from factors such as lattice mismatch between layers, thermal expansion during fabrication, and external mechanical forces, can induce structural defects, accelerate ion migration and further reduce the operational lifespan of devices. Research has shown that strategies such as doping, additive engineering, optimization of annealing processes, and interface modification can effectively relieve the residual strain produced in the fabrication process of perovskite film, thereby enhancing the overall performance of the device. Among them, interface engineering has proven to be a key strategy for regulating strain and accordingly enhancing device stability. This article provides a comprehensive overview of recent advances in interface engineering approaches aimed at strain regulation in PSCs. The role of interface design with strain regulation in enhancing crystallinity, reducing defect density, and improving long-term performance is discussed in details, offering insights into future strategies for improving the stability and efficiency of perovskite-based photovoltaic devices. .
钙钛矿太阳能电池(PSCs)因其高效、低成本的特点而备受关注。然而,由于应变引起的降解会影响钙钛矿层的结构完整性和性能,因此长期的操作稳定性仍然是一个重大挑战。由于层间晶格失配、制造过程中的热膨胀和外部机械力等因素引起的应变会诱发结构缺陷,加速离子迁移,进一步降低器件的使用寿命。研究表明,掺杂、增材工程、优化退火工艺、界面改性等策略可以有效缓解钙钛矿薄膜制备过程中产生的残余应变,从而提高器件的整体性能。其中,界面工程已被证明是调节应变从而提高器件稳定性的关键策略。本文提供了针对psc应变调节的界面工程方法的最新进展的全面概述。详细讨论了具有应变调节的界面设计在增强结晶度,降低缺陷密度和改善长期性能方面的作用,为提高钙钛矿基光伏器件的稳定性和效率的未来策略提供了见解。
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引用次数: 0
Stability strategies and luminescent applications of low-dimensional metal halide perovskites. 低维金属卤化物钙钛矿的稳定性策略及发光应用。
IF 18.1 1区 物理与天体物理 Q1 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-25 DOI: 10.1088/1361-6633/ae0b8f
Junhu Cai,Wenzong Lai,Hao Chen,Feifei Chen,Xiang Zhang,Yu Chen,Borui Jiang,Xiaogang Chen,Gongming Li,Nan Zha,Zheng Zhou,Huilong Yang,Tailiang Guo,Jiajun Luo,Enguo Chen
Traditional three-dimensional perovskite structures encounter significant challenges in achieving high-quality light emission. In contrast, low-dimensional metal halide perovskites (LDMHPs) have emerged as promising alternatives, owing to their exceptional luminescent properties. However, the stability of LDMHPs remains a critical issue, limiting their potential in light-emitting and display applications. This review first examines the luminescence mechanisms and instability factors associated with LDMHPs, then summarizes strategies to enhance the stability, offering insights for further improvement. Additionally, the specific applications of LDMHPs are discussed based on electroluminescence and photoluminescence. Finally, the challenges and future directions are explored for the commercialization of LDMHPs in luminescent or display devices. This review provides valuable guidance for ongoing researches in this field. .
传统的三维钙钛矿结构在实现高质量发光方面面临重大挑战。相比之下,低维金属卤化物钙钛矿(LDMHPs)由于其特殊的发光特性而成为有前途的替代品。然而,LDMHPs的稳定性仍然是一个关键问题,限制了它们在发光和显示应用中的潜力。本文首先研究了LDMHPs的发光机制和不稳定性因素,然后总结了增强稳定性的策略,为进一步改进提供了见解。此外,还从电致发光和光致发光的角度讨论了LDMHPs的具体应用。最后,探讨了LDMHPs在发光或显示器件中商业化的挑战和未来方向。这一综述对该领域的进一步研究具有重要的指导意义。
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引用次数: 0
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