Abstract Metal ions from natural and anthropogenic sources cause pollution to society and the environment is major concern in the present scenario. The deposition and contamination of metal ions in soil and water affect the biogeochemical cycles. Thus, it threatens the everyday life of living and non-living organisms. Reviews on the detection of metal ions through several techniques (Analytical methods, electrochemical techniques, and sensors) and materials (Nanoparticles, carbon dots (quantum dots), polymers, chiral molecules, metal-organic framework, carbon nanotubes, etc.) are addressed separately in the present literature. This review reveals the advantages and disadvantages of the techniques and materials for metal ion sensing with crucial factors. Furthermore, it focus on the capability of conjugated polymers (CPs) as metal ion sensors able to detect/sense hazardous metal ions from environmental samples. Six different routes can synthesize this type of CPs to get specific properties and better metal ion detecting capability in vast research areas. The metal ion detection by CP is time-independent, simple, and low cost compared to other materials/techniques. This review outlines recent literature on the conjugated polymer for cation, anion, and dual ion sensors. Over the last half decades published articles on the conjugated polymer are discussed and compared.
{"title":"Real scenario of metal ion sensor: is conjugated polymer helpful to detect hazardous metal ion","authors":"Pushparani Selvakumar Umabharathi, S. Karpagam","doi":"10.1515/revic-2022-0006","DOIUrl":"https://doi.org/10.1515/revic-2022-0006","url":null,"abstract":"Abstract Metal ions from natural and anthropogenic sources cause pollution to society and the environment is major concern in the present scenario. The deposition and contamination of metal ions in soil and water affect the biogeochemical cycles. Thus, it threatens the everyday life of living and non-living organisms. Reviews on the detection of metal ions through several techniques (Analytical methods, electrochemical techniques, and sensors) and materials (Nanoparticles, carbon dots (quantum dots), polymers, chiral molecules, metal-organic framework, carbon nanotubes, etc.) are addressed separately in the present literature. This review reveals the advantages and disadvantages of the techniques and materials for metal ion sensing with crucial factors. Furthermore, it focus on the capability of conjugated polymers (CPs) as metal ion sensors able to detect/sense hazardous metal ions from environmental samples. Six different routes can synthesize this type of CPs to get specific properties and better metal ion detecting capability in vast research areas. The metal ion detection by CP is time-independent, simple, and low cost compared to other materials/techniques. This review outlines recent literature on the conjugated polymer for cation, anion, and dual ion sensors. Over the last half decades published articles on the conjugated polymer are discussed and compared.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49169013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Larina, O. Babich, Anastasia Zhikhreva, S. Ivanova, Eugene Chupakhin
Abstract This article presents an overview of some of the available research studies of MOFs as catalysts. Catalytic studies of magnetic iron oxide nanoparticles with modified surfaces, MOFs with precious metals such as palladium, platinum, and silver, with zirconium, hafnium, copper, alkaline earth metals, lanthanides are generalized. The studies of the catalytic activity of micro- and mesoporous MOF structures are described.
{"title":"The use of metal-organic frameworks as heterogeneous catalysts","authors":"V. Larina, O. Babich, Anastasia Zhikhreva, S. Ivanova, Eugene Chupakhin","doi":"10.1515/revic-2022-0020","DOIUrl":"https://doi.org/10.1515/revic-2022-0020","url":null,"abstract":"Abstract This article presents an overview of some of the available research studies of MOFs as catalysts. Catalytic studies of magnetic iron oxide nanoparticles with modified surfaces, MOFs with precious metals such as palladium, platinum, and silver, with zirconium, hafnium, copper, alkaline earth metals, lanthanides are generalized. The studies of the catalytic activity of micro- and mesoporous MOF structures are described.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45736540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Su, Lai Hu, Senqiang Zhu, Jiapeng Lu, Jinyang Hu, Rui Liu, Hongjun Zhu
Abstract Transition metal complexes (TMCs) with strong and long-lived excited state absorption (ESA) usually exhibit high-performance optical power limiting (OPL) response. Several techniques, such as transmission vs. incident fluence curves and Z-scan have been widely used to assess the OPL performance of typical TMCs. The OPL performance of TMCs is highly molecular structure-dependent. Special emphasis is placed on the structure-OPL response relationships of Pt(II), Ir(III), Ru(II), and other metal complexes. This review concludes with perspectives on the current status of OPL field, as well as opportunities that lie just beyond its frontier.
{"title":"Transition metal complexes with strong and long-lived excited state absorption: from molecular design to optical power limiting behavior","authors":"H. Su, Lai Hu, Senqiang Zhu, Jiapeng Lu, Jinyang Hu, Rui Liu, Hongjun Zhu","doi":"10.1515/revic-2022-0013","DOIUrl":"https://doi.org/10.1515/revic-2022-0013","url":null,"abstract":"Abstract Transition metal complexes (TMCs) with strong and long-lived excited state absorption (ESA) usually exhibit high-performance optical power limiting (OPL) response. Several techniques, such as transmission vs. incident fluence curves and Z-scan have been widely used to assess the OPL performance of typical TMCs. The OPL performance of TMCs is highly molecular structure-dependent. Special emphasis is placed on the structure-OPL response relationships of Pt(II), Ir(III), Ru(II), and other metal complexes. This review concludes with perspectives on the current status of OPL field, as well as opportunities that lie just beyond its frontier.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44597203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract This paper aims to review recent advances on synthesis, crystal structures, thermal, spectroscopic, phase transitions, optical, dielectric, and catalysis properties of hydrate and anhydrous alkylenediammonium halogenometallates materials (Metal: Bi, Sb, Halogen: Cl, Br, I). These hybrid materials present rich structural diversities based on octahedra forming infinite zero dimensional, 1-dimensional chains, 2-dimensional layers, discrete bioctahedra, and discrete tetramer units. The effect, contribution and importance of hydrogen bonding N–H … X (X: Cl, Br, I) are reviewed in terms of solid state relationship. Particularly, a comparative study is made on hydrate and anyhdrous aliphatic chlorobismuthates with alkylenediammonium +NH3(CH2) n NH3+ based on structural data and V/Z variation with (CH2) n chains (n = 2–8, 12), and variation of BiCl63− Raman frequencies modes versus (CH2) n chains (n = 3–8). Hydrate salts with (n = 3, 12) consist of isolated BiCl63− anions and two water molecules, against others ones with isolated anionic chains [BiCl52−] n or Bi2Cl104− dimers, formed by distorted octahedra BiCl63− sharing corners, vices or edges. The reviewed optical and electronic band gaps suggested interesting compounds with band gaps (1.85–2.4 eV), as suitable materials in optoelectronic properties, photoactive layer in solution-processed photovoltaics, and bio-imaging or photovoltaic applications. It was concluded that iodobismuthate salts have generally the lowest bands gap, compared to that of bromo and chlorobismuthate slats. Catalysis proprieties are reviewed n fast (RhB) degradation under dark conditions for (C4N2H7)4Bi2Cl10, (C5H9N2)BiI4, and {(H-BPA)4·[(BiI6)I13]·2I3} n , and in organic salts synthesis under solvent-free conditions. Herein NH3(CH2) n NH3BiCl5 (n = 5–7) salts were used as highly efficient catalysts, which is a novel tendency in chlorobismuthate researchs in the green chemistry field.
{"title":"Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)","authors":"A. Ouasri","doi":"10.1515/revic-2022-0012","DOIUrl":"https://doi.org/10.1515/revic-2022-0012","url":null,"abstract":"Abstract This paper aims to review recent advances on synthesis, crystal structures, thermal, spectroscopic, phase transitions, optical, dielectric, and catalysis properties of hydrate and anhydrous alkylenediammonium halogenometallates materials (Metal: Bi, Sb, Halogen: Cl, Br, I). These hybrid materials present rich structural diversities based on octahedra forming infinite zero dimensional, 1-dimensional chains, 2-dimensional layers, discrete bioctahedra, and discrete tetramer units. The effect, contribution and importance of hydrogen bonding N–H … X (X: Cl, Br, I) are reviewed in terms of solid state relationship. Particularly, a comparative study is made on hydrate and anyhdrous aliphatic chlorobismuthates with alkylenediammonium +NH3(CH2) n NH3+ based on structural data and V/Z variation with (CH2) n chains (n = 2–8, 12), and variation of BiCl63− Raman frequencies modes versus (CH2) n chains (n = 3–8). Hydrate salts with (n = 3, 12) consist of isolated BiCl63− anions and two water molecules, against others ones with isolated anionic chains [BiCl52−] n or Bi2Cl104− dimers, formed by distorted octahedra BiCl63− sharing corners, vices or edges. The reviewed optical and electronic band gaps suggested interesting compounds with band gaps (1.85–2.4 eV), as suitable materials in optoelectronic properties, photoactive layer in solution-processed photovoltaics, and bio-imaging or photovoltaic applications. It was concluded that iodobismuthate salts have generally the lowest bands gap, compared to that of bromo and chlorobismuthate slats. Catalysis proprieties are reviewed n fast (RhB) degradation under dark conditions for (C4N2H7)4Bi2Cl10, (C5H9N2)BiI4, and {(H-BPA)4·[(BiI6)I13]·2I3} n , and in organic salts synthesis under solvent-free conditions. Herein NH3(CH2) n NH3BiCl5 (n = 5–7) salts were used as highly efficient catalysts, which is a novel tendency in chlorobismuthate researchs in the green chemistry field.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43272099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lin Hao, Tingting Zhang, Haoran Sang, Suyu Jiang, Jie Zhang, Jing Yang
Abstract Bismuth chloride oxide (BiOCl) is a typical V-VI-VII ternary oxide material, which is one of the widely studied metal oxides due to its unique surface, electronic and photocatalytic properties. However, the broad bandgap and the large number of photogenerated electron-hole pair complexes of BiOCl limit its photocatalytic efficiency. Since the photocatalytic performance of BiOCl is highly dependent on its exposed crystallographic facets, research attention has increasingly focused on the different structures and properties possessed by different crystallographic facets of BiOCl. This article reviews the basic principles of using different crystalline surfaces of BiOCl materials to enhance photocatalytic activity, summarizes the applications of BiOCl single-crystal catalysts and composite catalysts in the environmental field, and provides an outlook on the challenges and new research directions for future development in this emerging frontier area. It is hoped that the crystalline surface-related photocatalysis of BiOCl can be used to provide new guidance for the rational design of novel catalysts for various energy and environment-related applications.
{"title":"Advances in facet-dependent photocatalytic properties of BiOCl catalyst for environmental remediation","authors":"Lin Hao, Tingting Zhang, Haoran Sang, Suyu Jiang, Jie Zhang, Jing Yang","doi":"10.1515/revic-2022-0015","DOIUrl":"https://doi.org/10.1515/revic-2022-0015","url":null,"abstract":"Abstract Bismuth chloride oxide (BiOCl) is a typical V-VI-VII ternary oxide material, which is one of the widely studied metal oxides due to its unique surface, electronic and photocatalytic properties. However, the broad bandgap and the large number of photogenerated electron-hole pair complexes of BiOCl limit its photocatalytic efficiency. Since the photocatalytic performance of BiOCl is highly dependent on its exposed crystallographic facets, research attention has increasingly focused on the different structures and properties possessed by different crystallographic facets of BiOCl. This article reviews the basic principles of using different crystalline surfaces of BiOCl materials to enhance photocatalytic activity, summarizes the applications of BiOCl single-crystal catalysts and composite catalysts in the environmental field, and provides an outlook on the challenges and new research directions for future development in this emerging frontier area. It is hoped that the crystalline surface-related photocatalysis of BiOCl can be used to provide new guidance for the rational design of novel catalysts for various energy and environment-related applications.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46636568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gabriela Soriano-Giles, Edwin A. Giles-Mazón, Nazario Lopez, E. Reinheimer, V. Varela-Guerrero, María F. Ballesteros-Rivas
Abstract Metal-Organic Frameworks (MOFs) are a class of crystalline materials that, thanks to their large surface area and high porosity, allow them to be used in various areas of knowledge. This diversity of applications is due to the metal ions and the organic binders that compose them, but it is also important to highlight the ability of MOFs to function as hosts for a great variety of molecules of very different sizes and chemical properties. The first existing approaches for incorporating biomolecules in MOFs are discussed: pore encapsulation, surface binding, covalent binding, and in-situ encapsulation. Next, we discuss the obstacles of designing MOFs for effective gene delivery and how to enhance the gene delivery using different strategies.
{"title":"Metal organic frameworks (MOFS) as non-viral carriers for DNA and RNA delivery: a review","authors":"Gabriela Soriano-Giles, Edwin A. Giles-Mazón, Nazario Lopez, E. Reinheimer, V. Varela-Guerrero, María F. Ballesteros-Rivas","doi":"10.1515/revic-2022-0004","DOIUrl":"https://doi.org/10.1515/revic-2022-0004","url":null,"abstract":"Abstract Metal-Organic Frameworks (MOFs) are a class of crystalline materials that, thanks to their large surface area and high porosity, allow them to be used in various areas of knowledge. This diversity of applications is due to the metal ions and the organic binders that compose them, but it is also important to highlight the ability of MOFs to function as hosts for a great variety of molecules of very different sizes and chemical properties. The first existing approaches for incorporating biomolecules in MOFs are discussed: pore encapsulation, surface binding, covalent binding, and in-situ encapsulation. Next, we discuss the obstacles of designing MOFs for effective gene delivery and how to enhance the gene delivery using different strategies.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49183344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-05-30DOI: 10.1515/revic-2022-frontmatter2
{"title":"Frontmatter","authors":"","doi":"10.1515/revic-2022-frontmatter2","DOIUrl":"https://doi.org/10.1515/revic-2022-frontmatter2","url":null,"abstract":"","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41908996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dounia Tlamsamania, Mbark Ait-Mouha, S. Slassi, Youness Khaddam, Diana Londono Zuluaga, K. Yamni
Abstract Modern cements are complex materials with well-defined compositions that reach to high and consistent results. Automated techniques such as Rietveld analysis lead to provide an understanding of the composition and polymorphism of cement phases that could lead to control of the clinkering conditions to optimize characteristics and consequently quality product. For the characterization of cements used in the construction sector, Rietveld method has significant benefits over other analytical techniques. The precise information about phase assemblage and polymorphism lets monitoring the hydration behavior of binder materials. The objective of this paper is to report the quantitative Rietveld phase analyzes for three industrial clinkers, to review the most recent quantitative X-ray powder diffraction studies on anhydrous cement and to discuss the influence of the different parameters elaborated in the Rietveld method.
{"title":"Quantitative phase analysis of anhydrous clinker Portland using Rietveld method","authors":"Dounia Tlamsamania, Mbark Ait-Mouha, S. Slassi, Youness Khaddam, Diana Londono Zuluaga, K. Yamni","doi":"10.1515/revic-2022-0005","DOIUrl":"https://doi.org/10.1515/revic-2022-0005","url":null,"abstract":"Abstract Modern cements are complex materials with well-defined compositions that reach to high and consistent results. Automated techniques such as Rietveld analysis lead to provide an understanding of the composition and polymorphism of cement phases that could lead to control of the clinkering conditions to optimize characteristics and consequently quality product. For the characterization of cements used in the construction sector, Rietveld method has significant benefits over other analytical techniques. The precise information about phase assemblage and polymorphism lets monitoring the hydration behavior of binder materials. The objective of this paper is to report the quantitative Rietveld phase analyzes for three industrial clinkers, to review the most recent quantitative X-ray powder diffraction studies on anhydrous cement and to discuss the influence of the different parameters elaborated in the Rietveld method.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41466562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Khurram Shahzad, Mohammad Asad, A. Asiri, M. Irfan, M. Iqbal
Abstract Ruthenium complexes are considered as the most favorable alternatives to traditional platinum-based cancer drugs owing to their acceptable toxicity level, selectivity, variant oxidation states and ability to treat platinum-resistant cancer cells. They have similar ligand exchange kinetics as platinum drugs but can be tailored according to our desire by ligands influence. In the current study, we illustrate the in-vitro anticancer profile of some ruthenium complexes (2016–2021) against human hepatocellular carcinoma (HepG2). The anticancer activity of ruthenium complexes is determined by comparing their IC50 values with one another and positive controls. Fortunately, some ruthenium complexes including 3, 4, 6, 14, 15, 20, 42, and 48 exhibit surpassed in-vitro anticancer profile than that of positive controls promising as potential candidates against liver cancer. We also explored the structure-activity relationship (SAR) which is a key factor in the rational designing and synthesis of new ruthenium drugs. It covers the factors affecting anticancer activity including lipophilicity, planarity, area and bulkiness, the steric influence of different ligands, and electronic effects induced by ligands, stability, aqueous solubility and bioavailability to the target sites. The data reported here will provide strong support in the plausible design and synthesis of ruthenium anticancer drugs in the upcoming days.
{"title":"In-vitro anticancer profile of recent ruthenium complexes against liver cancer","authors":"Khurram Shahzad, Mohammad Asad, A. Asiri, M. Irfan, M. Iqbal","doi":"10.1515/revic-2021-0040","DOIUrl":"https://doi.org/10.1515/revic-2021-0040","url":null,"abstract":"Abstract Ruthenium complexes are considered as the most favorable alternatives to traditional platinum-based cancer drugs owing to their acceptable toxicity level, selectivity, variant oxidation states and ability to treat platinum-resistant cancer cells. They have similar ligand exchange kinetics as platinum drugs but can be tailored according to our desire by ligands influence. In the current study, we illustrate the in-vitro anticancer profile of some ruthenium complexes (2016–2021) against human hepatocellular carcinoma (HepG2). The anticancer activity of ruthenium complexes is determined by comparing their IC50 values with one another and positive controls. Fortunately, some ruthenium complexes including 3, 4, 6, 14, 15, 20, 42, and 48 exhibit surpassed in-vitro anticancer profile than that of positive controls promising as potential candidates against liver cancer. We also explored the structure-activity relationship (SAR) which is a key factor in the rational designing and synthesis of new ruthenium drugs. It covers the factors affecting anticancer activity including lipophilicity, planarity, area and bulkiness, the steric influence of different ligands, and electronic effects induced by ligands, stability, aqueous solubility and bioavailability to the target sites. The data reported here will provide strong support in the plausible design and synthesis of ruthenium anticancer drugs in the upcoming days.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46372641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Faisal Rehman, F. H. Memon, Akbar Ali, Shahbaz Khan, F. Soomro, M. Iqbal, K. Thebo
Abstract Graphene-based layered materials have got significant interest in membrane technology for water desalination, gas separation, organic nanofiltration, pervaporation, proton exchange applications, etc. and show remarkable results. Up to date, various methods have been developed for fabrication of high performance membrane. Most of them are only suitable for research purposes, but not appropriate for mass transport barrier and membrane applications that require large-area synthesis. In this comprehensive review, we summarized the current synthesis and fabrication methods of graphene-based membranes. Emphasis will be given on fabrication of both graphene-based nanoporous and lamellar membranes. Finally, we discuss the current engineering hurdles and future research directions yet to be explored for fabrication of such membranes.
{"title":"Recent progress on fabrication methods of graphene-based membranes for water purification, gas separation, and energy sustainability","authors":"Faisal Rehman, F. H. Memon, Akbar Ali, Shahbaz Khan, F. Soomro, M. Iqbal, K. Thebo","doi":"10.1515/revic-2022-0001","DOIUrl":"https://doi.org/10.1515/revic-2022-0001","url":null,"abstract":"Abstract Graphene-based layered materials have got significant interest in membrane technology for water desalination, gas separation, organic nanofiltration, pervaporation, proton exchange applications, etc. and show remarkable results. Up to date, various methods have been developed for fabrication of high performance membrane. Most of them are only suitable for research purposes, but not appropriate for mass transport barrier and membrane applications that require large-area synthesis. In this comprehensive review, we summarized the current synthesis and fabrication methods of graphene-based membranes. Emphasis will be given on fabrication of both graphene-based nanoporous and lamellar membranes. Finally, we discuss the current engineering hurdles and future research directions yet to be explored for fabrication of such membranes.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1,"publicationDate":"2022-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47639065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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