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Advances in facet-dependent photocatalytic properties of BiOCl catalyst for environmental remediation 用于环境修复的BiOCl催化剂的面依赖性光催化性能研究进展
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-06-24 DOI: 10.1515/revic-2022-0015
Lin Hao, Tingting Zhang, Haoran Sang, Suyu Jiang, Jie Zhang, Jing Yang
Abstract Bismuth chloride oxide (BiOCl) is a typical V-VI-VII ternary oxide material, which is one of the widely studied metal oxides due to its unique surface, electronic and photocatalytic properties. However, the broad bandgap and the large number of photogenerated electron-hole pair complexes of BiOCl limit its photocatalytic efficiency. Since the photocatalytic performance of BiOCl is highly dependent on its exposed crystallographic facets, research attention has increasingly focused on the different structures and properties possessed by different crystallographic facets of BiOCl. This article reviews the basic principles of using different crystalline surfaces of BiOCl materials to enhance photocatalytic activity, summarizes the applications of BiOCl single-crystal catalysts and composite catalysts in the environmental field, and provides an outlook on the challenges and new research directions for future development in this emerging frontier area. It is hoped that the crystalline surface-related photocatalysis of BiOCl can be used to provide new guidance for the rational design of novel catalysts for various energy and environment-related applications.
摘要氯化铋氧化物(BiOCl)是一种典型的V-VI-VII三元氧化物材料,由于其独特的表面、电子和光催化性能,是被广泛研究的金属氧化物之一。然而,BiOCl的宽带隙和大量的光生电子-空穴对复合物限制了其光催化效率。由于BiOCl的光催化性能高度依赖于其暴露的晶面,研究注意力越来越集中在BiOCl不同晶面所具有的不同结构和性能上。本文综述了利用不同晶面的BiOCl材料提高光催化活性的基本原理,总结了BiOCl单晶催化剂和复合催化剂在环境领域的应用,并展望了这一新兴前沿领域的挑战和新的研究方向。希望BiOCl的晶体表面相关光催化能为合理设计各种能源和环境相关应用的新型催化剂提供新的指导。
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引用次数: 2
Metal organic frameworks (MOFS) as non-viral carriers for DNA and RNA delivery: a review 金属有机框架(MOFS)作为DNA和RNA递送的非病毒载体:综述
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-06-03 DOI: 10.1515/revic-2022-0004
Gabriela Soriano-Giles, Edwin A. Giles-Mazón, Nazario Lopez, E. Reinheimer, V. Varela-Guerrero, María F. Ballesteros-Rivas
Abstract Metal-Organic Frameworks (MOFs) are a class of crystalline materials that, thanks to their large surface area and high porosity, allow them to be used in various areas of knowledge. This diversity of applications is due to the metal ions and the organic binders that compose them, but it is also important to highlight the ability of MOFs to function as hosts for a great variety of molecules of very different sizes and chemical properties. The first existing approaches for incorporating biomolecules in MOFs are discussed: pore encapsulation, surface binding, covalent binding, and in-situ encapsulation. Next, we discuss the obstacles of designing MOFs for effective gene delivery and how to enhance the gene delivery using different strategies.
摘要金属有机框架(MOFs)是一类晶体材料,由于其大的表面积和高的孔隙率,使其能够用于各种知识领域。这种应用的多样性是由于金属离子和组成它们的有机粘合剂,但强调MOFs作为各种大小和化学性质非常不同的分子的宿主的能力也很重要。讨论了将生物分子掺入MOFs的第一种现有方法:孔包封、表面结合、共价结合和原位包封。接下来,我们讨论了设计用于有效基因递送的MOFs的障碍,以及如何使用不同的策略来增强基因递送。
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引用次数: 4
Frontmatter Frontmatter
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-05-30 DOI: 10.1515/revic-2022-frontmatter2
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引用次数: 0
Quantitative phase analysis of anhydrous clinker Portland using Rietveld method 用Rietveld法定量分析无水熟料波特兰的物相
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-05-13 DOI: 10.1515/revic-2022-0005
Dounia Tlamsamania, Mbark Ait-Mouha, S. Slassi, Youness Khaddam, Diana Londono Zuluaga, K. Yamni
Abstract Modern cements are complex materials with well-defined compositions that reach to high and consistent results. Automated techniques such as Rietveld analysis lead to provide an understanding of the composition and polymorphism of cement phases that could lead to control of the clinkering conditions to optimize characteristics and consequently quality product. For the characterization of cements used in the construction sector, Rietveld method has significant benefits over other analytical techniques. The precise information about phase assemblage and polymorphism lets monitoring the hydration behavior of binder materials. The objective of this paper is to report the quantitative Rietveld phase analyzes for three industrial clinkers, to review the most recent quantitative X-ray powder diffraction studies on anhydrous cement and to discuss the influence of the different parameters elaborated in the Rietveld method.
现代水泥是复杂的材料,具有明确的成分,达到高和一致的结果。Rietveld分析等自动化技术有助于了解水泥相的组成和多态性,从而控制熟化条件,优化特性,从而提高产品质量。对于建筑部门使用的水泥的表征,Rietveld方法比其他分析技术具有显著的优势。相组合和多态的精确信息可以监测粘结剂材料的水化行为。本文的目的是报告三种工业熟料的定量Rietveld相分析,回顾最近对无水水泥的定量x射线粉末衍射研究,并讨论在Rietveld方法中阐述的不同参数的影响。
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引用次数: 1
In-vitro anticancer profile of recent ruthenium complexes against liver cancer 钌配合物抗肝癌的体外抗癌研究进展
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-05-06 DOI: 10.1515/revic-2021-0040
Khurram Shahzad, Mohammad Asad, A. Asiri, M. Irfan, M. Iqbal
Abstract Ruthenium complexes are considered as the most favorable alternatives to traditional platinum-based cancer drugs owing to their acceptable toxicity level, selectivity, variant oxidation states and ability to treat platinum-resistant cancer cells. They have similar ligand exchange kinetics as platinum drugs but can be tailored according to our desire by ligands influence. In the current study, we illustrate the in-vitro anticancer profile of some ruthenium complexes (2016–2021) against human hepatocellular carcinoma (HepG2). The anticancer activity of ruthenium complexes is determined by comparing their IC50 values with one another and positive controls. Fortunately, some ruthenium complexes including 3, 4, 6, 14, 15, 20, 42, and 48 exhibit surpassed in-vitro anticancer profile than that of positive controls promising as potential candidates against liver cancer. We also explored the structure-activity relationship (SAR) which is a key factor in the rational designing and synthesis of new ruthenium drugs. It covers the factors affecting anticancer activity including lipophilicity, planarity, area and bulkiness, the steric influence of different ligands, and electronic effects induced by ligands, stability, aqueous solubility and bioavailability to the target sites. The data reported here will provide strong support in the plausible design and synthesis of ruthenium anticancer drugs in the upcoming days.
摘要钌配合物被认为是传统的基于铂的癌症药物的最有利的替代品,因为它们具有可接受的毒性水平、选择性、可变氧化态和治疗铂耐药性癌症细胞的能力。它们具有与铂类药物相似的配体交换动力学,但可以根据我们的愿望通过配体的影响进行定制。在目前的研究中,我们阐明了一些钌配合物(2016-2021)对人类肝细胞癌(HepG2)的体外抗癌作用。钌配合物的抗癌活性是通过将它们的IC50值彼此和阳性对照进行比较来确定的。幸运的是,一些钌配合物,包括3、4、6、14、15、20、42和48,表现出超过阳性对照的体外抗癌特性,有望成为癌症的潜在候选物。我们还探讨了结构-活性关系(SAR),这是合理设计和合成钌新药的关键因素。它涵盖了影响抗癌活性的因素,包括亲脂性、平面性、面积和体积、不同配体的空间影响、配体诱导的电子效应、稳定性、水溶性和对靶位点的生物利用度。本文报道的数据将在未来几天为钌抗癌药物的合理设计和合成提供有力支持。
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引用次数: 1
Recent progress on fabrication methods of graphene-based membranes for water purification, gas separation, and energy sustainability 用于水净化、气体分离和能源可持续性的石墨烯基膜制备方法的最新进展
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-03-30 DOI: 10.1515/revic-2022-0001
Faisal Rehman, F. H. Memon, Akbar Ali, Shahbaz Khan, F. Soomro, M. Iqbal, K. Thebo
Abstract Graphene-based layered materials have got significant interest in membrane technology for water desalination, gas separation, organic nanofiltration, pervaporation, proton exchange applications, etc. and show remarkable results. Up to date, various methods have been developed for fabrication of high performance membrane. Most of them are only suitable for research purposes, but not appropriate for mass transport barrier and membrane applications that require large-area synthesis. In this comprehensive review, we summarized the current synthesis and fabrication methods of graphene-based membranes. Emphasis will be given on fabrication of both graphene-based nanoporous and lamellar membranes. Finally, we discuss the current engineering hurdles and future research directions yet to be explored for fabrication of such membranes.
石墨烯基层状材料在膜技术中在海水淡化、气体分离、有机纳滤、渗透蒸发、质子交换等方面的应用得到了极大的关注,并取得了显著的成果。迄今为止,人们已经开发出各种制备高性能膜的方法。其中大多数仅适用于研究目的,而不适用于需要大面积合成的传质屏障和膜应用。本文综述了目前石墨烯基膜的合成和制备方法。重点是石墨烯基纳米孔膜和层状膜的制备。最后,我们讨论了目前的工程障碍和未来的研究方向有待探索的制造这种膜。
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引用次数: 5
Research progress of catalytic oxidation of volatile organic compounds over Mn-based catalysts – a review 锰基催化剂催化氧化挥发性有机物的研究进展
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-02-10 DOI: 10.1515/revic-2021-0042
Chaofan Sui, Shiping Zeng, Xiangyu Ma, Yue Zhang, Jingxin Zhang, Xiaomei Xie
Abstract With the rapid development of urbanization and industrialization, environmental pollution has become more severe. Volatile organic compounds (VOCs) could be originated from the following sources: domestic, mobile and industrial sources. As important air pollutants, VOCs could cause serious harm to the environment and human health. Therefore, removing VOCs has become a priority research direction of ecological issues. Among the many elimination methods, catalytic oxidation approaches are among the most effective and economical methods which can transform VOCs into CO2 and H2O. MnOx catalysts are among the most active catalysts, which can be further modified by different cations such as Cu2+, Co2+, Cr3+, Ni2+ and Ce4+ to form mixed oxides to improve the catalytic oxidation of VOCs activity. Moreover, MnOx can be loaded on the carrier, improving the redox and oxygen storage capacity and improving its stability and activity. This review explores the structure, preparation and oxidation state of Mn-based catalysts.
随着城市化和工业化的快速发展,环境污染日益严重。挥发性有机化合物(VOCs)可能来自以下来源:家庭、移动和工业来源。挥发性有机化合物是重要的大气污染物,对环境和人体健康造成严重危害。因此,去除挥发性有机化合物已成为生态问题的优先研究方向。在众多的消除方法中,催化氧化法是将VOCs转化为CO2和H2O的最有效和最经济的方法之一。MnOx催化剂是活性最高的催化剂之一,可以通过Cu2+、Co2+、Cr3+、Ni2+、Ce4+等不同阳离子进一步改性,形成混合氧化物,提高催化氧化VOCs的活性。此外,MnOx可以装载在载体上,提高了载体的氧化还原和储氧能力,提高了载体的稳定性和活性。本文综述了锰基催化剂的结构、制备方法和氧化态。
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引用次数: 5
Review of methods and technologies for the enrichment of low-grade phosphorites 低品位磷矿富集方法与技术综述
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-01-31 DOI: 10.1515/revic-2021-0041
Y. Raiymbekov, U. Besterekov, P. Abdurazova, U. Nazarbek
Abstract The article presents the results of generalization of known information on various methods of enrichment of low-grade phosphate raw materials in the world. Based on the review of literature materials, scientists propose several methods of enrichment: mechanical, calcination at high temperatures, flotation, chemical enrichment with various acids and salts. Analyzing and summarizing these data, the article describes the advantages and disadvantages of each proposed method of enrichment of low-grade phosphorites. It is known that the sphere of production of phosphorus-containing products is important for many agricultural countries that produce these products themselves or import from others. This review material is very important for those who are interested in the problems of attracting low-grade phosphates into the production cycle by enriching them.
摘要本文介绍了世界上各种低品位磷酸盐原料富集方法的已知信息的综合结果。在查阅文献资料的基础上,科学家们提出了几种富集方法:机械法、高温煅烧法、浮选法、用各种酸和盐进行化学富集法。通过对这些数据的分析和总结,介绍了所提出的每种低品位磷矿富集方法的优缺点。众所周知,含磷产品的生产领域对许多自己生产或从其他国家进口这些产品的农业国家来说很重要。这篇综述材料对于那些对通过富集低品位磷酸盐将其吸引到生产周期中的问题感兴趣的人来说非常重要。
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引用次数: 2
Potential applicability of Schiff bases and their metal complexes during COVID-19 pandemic – a review 希夫碱及其金属配合物在新冠肺炎大流行期间的潜在适用性——综述
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2022-01-21 DOI: 10.1515/revic-2021-0027
N. Aggarwal, S. Maji
Abstract The rapid growth and revolution in the area of emerging therapeutics has been able to save the life of millions of patients globally. Besides these developments, the microbes are consistently struggling for their own survival and hence becoming quite more sturdy and incurable to existing drugs. Covid-19 virus and Black Fungus are recent examples of failure of medical preparations and strength of these viruses beyond the imagination of medical practitioners. Henceforth the study has made an extensive survey of exiting literature on heterocyclic schiff bases and their transition metal complexes to look for their potential applicability as antimicrobial agents. The inherent physiognomies of the essential properties of these transition metal complexes including thermodynamic, kinetic and chelating are comparatively modifiable as per requirements. The study has found that the biological applications of these transition metal complexes are well suited to be used as antibacterial and antifungal agents.
摘要新兴疗法领域的快速发展和革命已经能够挽救全球数百万患者的生命。除了这些发展,这些微生物一直在为自己的生存而挣扎,因此变得更加坚固,对现有药物来说是无法治愈的。新冠肺炎病毒和黑真菌是最近医疗准备失败的例子,这些病毒的强度超出了医生的想象。此后,该研究对杂环席夫碱及其过渡金属配合物的现有文献进行了广泛的调查,以寻找其作为抗菌剂的潜在应用。这些过渡金属配合物的基本性质的固有特征,包括热力学、动力学和螯合,可以根据要求进行相对修改。研究发现,这些过渡金属配合物的生物学应用非常适合用作抗菌和抗真菌剂。
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引用次数: 7
Heterotridentate organodiphosphines in Pt(η3-P1X1P2)(Y) (X1 = B, S, or Si) and Pt(η3-P1P2Si1)(Y) derivatives-structural aspects Pt(η3-P1X1P2)(Y) (X1 = B, S或Si)和Pt(η3-P1P2Si1)(Y)衍生物中的异三齿有机二膦-结构方面
IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2021-12-20 DOI: 10.1515/revic-2021-0028
M. Melnik, P. Mikuš
Abstract This review covers almost 30 Pt(II) complexes of the composition Pt(η3-P1X1P2)(Y), (X1 = BL, SL, or SiL), (Y = H, OL, NL, CL, Cl, PL, or I) and Pt(η3-P1P2Si1)(CH3). Heterotridentate ligands form six types of metallocyclic rings: P1CNB1NCP2, P1C2S1C2P2, P1C2Si1C2P2, (most common), P1CNSi1NCP2, and P1C3Si1C3P2 with common B1, S1, or Si1 atoms. In P1C2P2C3Si1 the P2 atom is common. The structural data (Pt–L, L–Pt–L) are analyzed and discussed with an attention to the distortion of a square-planar geometry about Pt(II) atoms as well as trans-influence. The sum of Pt–L(x4) bond distances growing with covalent radius of the X1 and Y atoms.
摘要本文综述了近30种Pt(II)配合物,其组成分别为Pt(η3-P1X1P2)(Y)、(X1=BL、SL或SiL)、(Y=H、OL、NL、CL、CL、PL或I)和Pt(ω3-P1P2Si1)(CH3)。杂三齿配体形成六种类型的金属环:P1CNB1NCP2、P1C2S1C2P2、P1C2Si1C2P2(最常见)、P1CNSi1NCP2和具有常见B1、S1或Si1原子的P1C3Si1C3P2。在P1C2P2C3Si1中,P2原子是常见的。分析和讨论了结构数据(Pt–L,L–Pt–L),并注意到Pt(II)原子的正方形平面几何结构的畸变以及反式影响。Pt–L(x4)键距的总和随着X1和Y原子的共价半径而增长。
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引用次数: 2
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Reviews in Inorganic Chemistry
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