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GETTING A COMPLEX MASTER ALLOY FOR ALLOYING HIGH-MANGANESE STEELS AND CAST ALUMINUM ALLOYS 获得用于合金化高锰钢和铸铝合金的复杂母合金
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3458
M. Voron, Y. Kostetsky, Marina Fon Pruss
The work is dedicated to obtaining a complex Al-Mn-Fe master alloy for precise alloying high-manganese steels with aluminum high content as well as for making additions during aluminum alloys production. The addition of aluminum large quantity to steel during steelmaking is an especially difficult task, because of the low density and melting temperature of aluminum. A complex Al-Mn-Fe master alloy with more high density and melting temperature then aluminum may be proposed as an alternative for metal aluminum at precise steel alloying. Such master alloy also may be useful for preparing traditional cast aluminum alloys and special creep-resistant Al-based alloys. In this investigation, the master alloy was prepared via electron-beam casting technology (EBCT) with using cheap raw materials like ferromanganese and aluminum scrap. It was established there is a possibility to obtain an alloy with a high content of main components and low content of carbon due to the process peculiarities. The prepared master alloy Al-17Mn-4Fe has a density of 3.8 g/cm3 and a specific structure, that contains phases with a significantly higher melting point than pure aluminum.
该工作致力于获得一种复杂的Al-Mn-Fe母合金,用于精确合金化含铝高锰钢以及在铝合金生产过程中添加添加剂。由于铝的密度低、熔化温度低,在炼钢过程中向钢中大量添加铝是一项特别困难的任务。一种比铝密度更高、熔化温度更高的铝锰铁复合母合金可作为精密合金化金属铝的替代材料。这种母合金也可用于制备传统的铸造铝合金和特殊的抗蠕变铝基合金。本研究以锰铁和废铝等廉价原料为原料,采用电子束铸造技术(EBCT)制备了主合金。由于工艺的特殊性,有可能获得主要成分含量高、碳含量低的合金。制备的主合金Al-17Mn-4Fe的密度为3.8 g/cm3,具有特殊的结构,其相的熔点明显高于纯铝。
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引用次数: 0
FEM research of internal stresses evolution in the prestressing strand production 预应力钢绞线生产过程内应力演化的有限元研究
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3489
Alexey Korhunov, E. Medvedeva, P. Ivekeeva, Dmitrii Konstantiov
The article presents the finite-element modeling results of stranding, reduction, straightening and mechanicalthermal treatment (MTT) of prestressing strand (PSC strand). Computer models took into account the distribution of residual stresses formed at the preliminary stage of wire drawing. During the simulation, the effect of MTT on the internal stresses of the wires was studied: residual stresses after the drawing process and additional stresses after the stranding. All studied methods demonstrated a positive effect not only from the point of eliminating internal stresses, but also from the point of view of their favorable redistribution. The reduction of PSC strand in a monolith tool with strain degree 1-3% allows to minimize tensile stresses on the surface of the wires and save compressive stresses in the center of the wires. The straightening by a group of 5 rolls made it possible to reduce the tension of outer wires twice. The MTT application, combining the effects of various physical nature, made it possible to control over a wide range the redistribution of residual stresses in the wires after high strain degrees and the additional stresses created during the stranding, which affect the preservation of the geometric parameters of the PSC strand. The study showed that to eliminate longitudinal residual stresses, the magnitude of the tension in the MTT is the most important parameter. Therefore, with a minimum value of tension, the residual stresses are not redistributed either in the central or in the surface layers, regardless of the temperature of the MTT. However, with tension above 70 kN and a temperature of 380-400°C, the residual stresses in the center and on the surface of the wires are balanced or almost completely eliminated.
本文介绍了预应力钢绞线(PSC钢绞线)的绞合、还原、矫直和机械热处理(MTT)的有限元建模结果。计算机模型考虑了拉丝初期形成的残余应力分布。在模拟过程中,研究了MTT对钢丝内应力的影响:拉丝后的残余应力和绞合后的附加应力。所研究的方法不仅从消除内应力的角度来看,而且从它们的有利再分配的角度来看,都显示出积极的效果。在应变度为1-3%的整体工具中,PSC股的减少可以最大限度地减少金属丝表面的拉应力,并节省金属丝中心的压应力。由一组5辊矫直使得有可能减少张力外钢丝两次。MTT的应用,结合各种物理性质的影响,可以在大范围内控制高应变度后金属丝中残余应力的重新分布,以及在成股过程中产生的额外应力,这些应力影响PSC股几何参数的保存。研究表明,为了消除纵向残余应力,MTT内的张力大小是最重要的参数。因此,当张力值最小时,无论MTT的温度如何,残余应力都不会在中心层或表层重新分布。然而,当张力大于70 kN,温度为380-400℃时,丝芯中心和表面的残余应力被平衡或几乎完全消除。
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引用次数: 1
The effect of hydrogen charging on the quality of zinc and powder paint coatings 加氢对锌和粉末涂料质量的影响
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3544
K. Kreislová, L. Turek, L. Mindos
There are shown some case studies when the defects in coatings (hot dip galvanised and duplex coatings with powder paints) were caused by hydrogen charging into matrix of substrate steel. Steel was exposed into hydrochloric acid and then the zinc coatings had been formed at higher temperature. The evidence of hydrogen recombination and its molecules ́ diffusion from coating layers is shown on cross-sections. The hydrogen release caused the defects on subsequently powder coated galvanized plates, too.
有一些案例研究表明,涂层(热浸镀锌和粉末涂料双相涂层)的缺陷是由氢气充入基体钢。钢暴露在盐酸中,然后在更高的温度下形成锌涂层。在截面上显示了氢复合及其分子从涂层扩散的证据。氢的释放也导致了后续粉末镀锌板的缺陷。
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引用次数: 0
Multicriteria Inventory classification in the expedition warehouse of the metallurgical company 冶金公司考察仓库的多标准库存分类
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3645
Tomáš Malčic, P. Besta
This paper deals with the optimization of storage and retrieval operations in the expedition warehouse of the metallurgical company. First, the problem of warehouse management in the metallurgical industry is defined. In the literature review, the approaches, methods, and results from studies of different authors are presented. In the main part of the paper, the idea of application of the principles and methods from the automotive industry in the metallurgical industry is described. For this purpose, the differences between the logistics processes in these two industries are described. Implementation of multicriteria inventory management for optimization of storage location assignment and subsequently the order picking is proposed. Conclusions from this paper will serve as a foundation for future work centered around the design of multicriteria support tools for decisionmaking processes related to storage and retrieval operations.
本文研究了冶金公司考察仓库储运作业的优化问题。首先,对冶金行业的仓储管理问题进行了界定。在文献综述中,介绍了不同作者的研究方法、方法和结果。在论文的主体部分,阐述了将汽车工业的原理和方法应用于冶金工业的思路。为此,描述了这两个行业的物流过程之间的差异。提出了一种多准则库存管理的实现方法,用于优化库位分配和随后的订单拣选。本文的结论将为未来围绕与存储和检索操作相关的决策过程的多标准支持工具的设计工作奠定基础。
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引用次数: 1
Sintered permanent magnets prepared from hydrogenated (Nd-Fe-b strip-cast alloy + pr3(Co,cu) compound) mixture 用氢化(Nd-Fe-b)带铸合金+ pr3(Co,cu)化合物)混合物制备烧结永磁体
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3608
P. A. Prokofev, N. Kolchugina, K. Skotnicová, G. Burkhanov, M. Zheleznyi, N. Dormidontov, A. Bakulina, T. Čegan, J. Juřica
The application of powder blending procedure shows promise in manufacturing Nd-Fe-B magnets; in this case, hydrides, oxides, intermetallic compounds, etc. are used as one of the mixture components. The application of these additions allows one to increase the hysteretic characteristics of Nd-Fe-B magnets at the expense of realized grain-boundary diffusion and grain-boundary structuring processes since these characteristics of the magnets are highly sensitive to their microstructure, composition of phases, and distribution of alloy components as well. This study is focused on the possibility of using the Pr3Co0.6Cu0.4Hx composition as the addition to the powder mixture for manufacturing Nd-Fe-B magnets and on the processes occurred during hydrogen treatment of the addition. The base alloy having the composition Nd-24.0, Pr-6.5, Dy-0.5, B-1.0, Al0.2, Fe-balance was prepared by strip-casting and subjected to hydrogen decrepitation at 270 °C for 1 h. The Pr3Co0.6Cu0.4 alloy was prepared by arc melting in an argon atmosphere and subjected to homogenizing annealing at 600 °C for 90 h and subsequent hydrogenation under the conditions used for the strip-cast alloy. The phase composition of Pr3Co0.6Cu0.4Hx was studied by X-ray diffraction analysis, DTA, scanning electron microscopy, and electron microprobe analysis. The Pr3Co0.6Cu0.4Hx composition was shown to undergo the hydrogenolysis with the formation of PrHx hydride (or hydrogen solid solution in Pr), Co+Cu fine mixture, and PrCu compound. The behavior of the additions in manufacturing sintered permanent magnets is analyzed from the viewpoint of the grain-boundary structuring effect of the addition. The sintered magnet prepared from the hydrogenated mixture Nd-Fe-B strip-cast alloy + Pr3(Co,Cu) compound exhibits the following hysteretic parameters: Br = 1.35 T, jHc = 1008 kA/m, and (BH)max = 349 kJ/m3.
粉末混合工艺在钕铁硼磁体制造中的应用前景广阔;在这种情况下,氢化物、氧化物、金属间化合物等被用作混合组分之一。这些添加物的应用可以增加Nd-Fe-B磁体的滞后特性,但代价是实现晶界扩散和晶界结构过程,因为磁体的这些特性对其微观结构、相组成和合金成分的分布高度敏感。本研究的重点是使用Pr3Co0.6Cu0.4Hx成分作为粉末混合物中添加物来制造Nd-Fe-B磁体的可能性,以及添加物在加氢处理过程中发生的过程。采用带铸法制备了成分为Nd-24.0, Pr-6.5, Dy-0.5, B-1.0, Al0.2, Fe-balance的基体合金,并在270℃下进行氢时效1 h。采用氩气电弧熔化法制备了Pr3Co0.6Cu0.4合金,在600℃下进行均匀退火90 h,然后在带铸合金的条件下进行加氢。通过x射线衍射分析、差热分析、扫描电镜和电子探针分析研究了Pr3Co0.6Cu0.4Hx的相组成。Pr3Co0.6Cu0.4Hx组分发生氢解,生成PrHx氢化物(或Pr中的氢固溶体)、Co+Cu精细混合物和PrCu化合物。从添加剂的晶界结构效应的角度分析了添加剂在烧结永磁体制造中的行为。由Nd-Fe-B带铸合金加氢混合物+ Pr3(Co,Cu)化合物制备的烧结磁体的磁滞参数为:Br = 1.35 T, jHc = 1008 kA/m, (BH)max = 349 kJ/m3。
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引用次数: 0
Evaluation of corrosivity of indoor museum atmospheres using lead specimens 用铅试样评价博物馆室内空气的腐蚀性
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3631
J. Švadlena, K. C. Strachotová, T. Prošek, M. Kouřil
The corrosivity of indoor atmospheres is usually evaluated according to the ISO 11844-1 standard, utilizing specimens of different metals. However, the sensitivity of this setup is not sufficient to the presence of specific organic pollutants, such as acetic and formic acid or formaldehyde. In this study, lead metal specimens were added as complementary specimens in the series of exposures including various museums and cultural sites. Temperature and relative humidity were monitored and adsorbent tubes were deployed for estimation of the content of the organic compound. For comparison and verification, lead specimens were exposed in laboratory conditions with controlled levels of acetic acid, which is supposed to be the main cause of the increase in lead corrosion rates. The results show that the use of lead specimens can provide valuable data about the corrosivity of the atmosphere due to its sensitivity to the presence of the carboxylic acids. This can be particularly important information for indoor storage conditions in museums and depositories. However, a proper method to evaluate the lead corrosion rates is necessary.
室内空气的腐蚀性通常根据ISO 11844-1标准进行评估,使用不同金属的样品。然而,这种装置的灵敏度不足以满足特定有机污染物的存在,如乙酸和甲酸或甲醛。在本研究中,铅金属标本作为补充标本加入了包括各种博物馆和文化遗址在内的一系列暴露中。监测了温度和相对湿度,并部署了吸附管来估计有机化合物的含量。为了进行比较和验证,铅样品暴露在控制乙酸水平的实验室条件下,这被认为是铅腐蚀率增加的主要原因。结果表明,由于铅对羧酸的存在很敏感,因此铅试样的使用可以提供有关大气腐蚀性的有价值的数据。这对于博物馆和仓库的室内储存条件来说是特别重要的信息。然而,有必要采用适当的方法来评估铅的腐蚀速率。
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引用次数: 0
Hydrophobic and antibacterial properties of laser micromachined steel surfaces 激光微加工钢表面的疏水性和抗菌性能
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3554
Š. Syrovátka, J. Martan
One of the main benefits of ultrashort laser micromachining is the possibility of preparing various surface structures, including a diversity of shapes and dimensions. The goal of this paper was to fabricate hydrophobic surface structures and to study coherency between the wettability and antibacterial properties of these structures for their further ways of application. The picosecond laser with a galvanometer scanner was used in the experiment for the fabrication of several types of surface structures. The next part of the experiment was testing of fabricated structures. Their wettability and antibacterial properties were tested and analyzed during several months. Tests showed that the fabrication of surface structures changed the wettability of the tested samples (the samples became more hydrophobic) and also showed that these structures affect their bacterial properties.
超短激光微加工的主要优点之一是可以制备各种表面结构,包括各种形状和尺寸。本文的目的是制备疏水表面结构,并研究这些结构的润湿性和抗菌性能之间的一致性,为其进一步的应用途径。皮秒激光与振镜扫描仪在实验中用于制造几种类型的表面结构。实验的下一部分是测试装配式结构。在几个月的时间里测试和分析了它们的润湿性和抗菌性能。实验表明,表面结构的制造改变了被测样品的润湿性(样品变得更疏水),也表明这些结构影响了它们的细菌特性。
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引用次数: 0
analysis of Jigless Spot Welding Process ParameterS 无夹片点焊工艺参数分析
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3657
Ehsaan-Reza Bagherian
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引用次数: 1
mold metal reactions of magnesium alloy az91E using sf6 and 3m novec 612 as protective gasses in investment casting technology 熔模铸造工艺中采用sf6和3m novec 612作为保护气体,研究了az91E镁合金的结晶金属反应
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3584
M. Dyčka, M. Juliš, L. Klakurková, L. Dyčková, P. Gejdoš
In this article, the intensity of mold metal reactions between ceramic shell and magnesium alloy AZ91E is studied. The two possible protective gasses used for melt protection are studied SF6 (sulphur hexafluoride) and 3M NOVEC 612. The scanning electron microscopy (SEM) with X-ray spectroscopy (EDS) were used for the analyses of the mold-metal reaction products on the interface between the magnesium alloy and the ceramic shell. Penetration of AZ91E into the ceramic shell was observed, thickness of mold-metal reaction products layer ranged from 0 μm to 80 μm. The intensity of mold metal reaction is much higher on the outer surface than on the inner surface of the casting. The thicker layer of the fine zircon particles as the first layer of ceramic shell seems to lower the mold metal reactions intensity to minimum. While using SF6, the penetration of AZ91E into ceramic shell was observed, the corroded layer consists of Al-enriched phase with higher content of oxygen. The use of 3M NOVEC 612 as the protective gas led to formation of continuous MgO layer between the ceramic shell and the magnesium alloy, thickness of this layer was up to 60 μm depending on the ceramic shell composition in the close surrounding area.
本文研究了陶瓷壳与镁合金AZ91E之间的模具金属反应强度。研究了SF6(六氟化硫)和3M NOVEC 612两种可能用于熔体保护的保护气体。采用扫描电子显微镜(SEM)和x射线能谱仪(EDS)对镁合金与陶瓷壳界面上的模-金属反应产物进行了分析。观察到AZ91E对陶瓷壳的渗透,模-金属反应产物层厚度为0 ~ 80 μm。铸件外表面的金属反应强度远高于内表面。较厚的细锆石颗粒层作为第一层陶瓷壳层似乎将模具金属反应强度降低到最低。当使用SF6时,观察到AZ91E对陶瓷壳的渗透,腐蚀层由富al相组成,氧含量较高。使用3M NOVEC 612作为保护气体,在陶瓷壳和镁合金之间形成了连续的MgO层,该层的厚度可达60 μm,具体厚度取决于陶瓷壳的成分。
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引用次数: 0
The mechanical parameters modeling of heavy steel plate snake/gradient temperature rolling with the same roll diameters 厚钢板蛇形/梯度温度轧制相同辊径的力学参数建模
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020019
Lian-yun Jiang, Zhen Tao, G. Yuan, Huang Jinbo, Wei Yaoyu, Li Heng, Wang Ping
The grains in the center of the heavy steel plate can be refined by the snake/gradient temperature rolling, and the deformation penetration, the microstructure, and the properties of the steel plate will be improved. The existing rolling mechanical models are not suitable for the snake/gradient temperature rolling, so it is necessary to establish the mechanical parameters model of the snake/gradient temperature rolling to instruct production. The yield criterion of rolled material was modified based on the idea of equivalent flow stress. The element stress analyses were carried out based on the uniform normal stress and nonuniform shear stress in the vertical sides of each slab. Then the equilibrium equation of the unit pressure based on the slab method was established on this basis. The deformation region was divided into three layers (the top layer, the bottom layer, and the central layer) and maximum four zones (back slip zone, front slip zone, cross shear zone, and reverse deflection zone) according to the temperature distribution and position of the neutral point, and then the 12 zones were formed during the snake/gradient temperature rolling. The boundary conditions of the existence of the back slip zone, the front slip zone, and the cross shear zone were established according to the relationship between the threading angle and the neutral angle. The accurate mechanical parameters model of the rolling force and rolling torque of the snake/gradient temperature rolling with the same roll diameters was set up on this basis. The ANSYS software has been used in the rolling process simulation by many scholars, and the calculating precision has been verified. So the rolling processes were simulated by the ANSYS software to validate the model precision. The results show that the maximum relative deviation of the rolling force analytic model is less than 7% compared with the numerical method, and the maximum relative deviation of the rolling torque analytic model is less than 11% compared with the measured results. The mechanical parameters model can accurately predict the rolling force and rolling torque during the snake/gradient temperature rolling with the same roll diameters, so as to provide a theoretical basis for the design of rolling mill and the setup of the process parameters.
蛇形/梯度温度轧制能使厚钢板中心的晶粒细化,使钢板的变形渗透、组织和性能得到改善。现有的轧制力学模型不适用于蛇形/梯度温度轧制,因此有必要建立蛇形/梯度温度轧制的力学参数模型来指导生产。基于等效流变应力的思想,对轧制材料的屈服准则进行了修正。单元应力分析是基于各板垂直侧均向正应力和非均向剪应力进行的。在此基础上,建立了基于平板法的单位压力平衡方程。根据温度分布和中性点位置,将变形区划分为3层(顶层、底层、中心层)和最大变形区4层(后滑移区、前滑移区、交叉剪切区、反挠度区),在蛇形/梯度温度滚动过程中形成12个变形区。根据穿线角与中性角的关系,建立了后滑移带、前滑移带和交叉剪切带存在的边界条件。在此基础上,建立了相同辊径下蛇形/梯度温度轧制的轧制力和轧制扭矩的精确力学参数模型。许多学者将ANSYS软件用于轧制过程仿真,并验证了其计算精度。利用ANSYS软件对轧制过程进行了仿真,验证了模型的精度。结果表明,轧制力分析模型与数值方法的最大相对偏差小于7%,轧制扭矩分析模型与实测结果的最大相对偏差小于11%。该力学参数模型能够准确预测相同辊径下蛇形/梯度温度轧制过程中的轧制力和轧制扭矩,从而为轧机的设计和工艺参数的设置提供理论依据。
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引用次数: 9
期刊
Revue De Metallurgie-cahiers D Informations Techniques
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