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The spectral and microscopical study of phytosynthesized plasmonic gold nanoparticles 植物合成等离子体金纳米粒子的光谱和显微研究
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.208
V. Bartošová, R. Smolková, L. Grishchenko, R. Linnik, Vladyslav V. Lisnyak, R. Mariychuk
Here, we present a facile and environmentally friendly method for the synthesis of gold nanoparticles (Au NPs) with an infrared response. The structure of the obtained Au NPs was investigated by transmission electron microscopy. Small and large Au NPs with different morphologies, including spheres, triangles, and hexagons, were imaged and studied, and the reasons for the morphological diversity were discussed. From the selected area diffraction data, the Au NPs showed sufficient crystallinity. The optical properties of the Au nanocolloids, investigated by UV-visible absorption spectroscopy, confirmed the presence of localized surface plasmon resonance (LSPR) peaks at 500…540 nm for Au NPs smaller than 30 nm. An increase in absorption intensity in the 600…1050 nm region indicates the formation of larger non-spherical Au NPs. The optical absorption spectra show the redshift of the second LSPR peak to the near-infrared region with a longer wavelength with increasing HAuCl4 concentration in the synthesis solution. In addition, we recorded the maxima of photoluminescence (PL) bands at 370 and 458 nm for the water-diluted Au colloids under 320 nm excitation and considered the possible reasons for PL. Attempts were made to elucidate the optical and PL behavior of the nanocolloids within the known models
在这里,我们提出了一种简单而环保的方法来合成具有红外响应的金纳米颗粒(Au NPs)。用透射电镜研究了所得金纳米粒子的结构。对不同形态的大小金纳米粒子(包括球体、三角形和六边形)进行了成像和研究,并讨论了形态多样性的原因。从选定区域的衍射数据来看,金纳米粒子具有足够的结晶度。紫外-可见吸收光谱研究了金纳米胶体的光学性质,证实了小于30 nm的金纳米胶体在500…540 nm处存在局域表面等离子体共振(LSPR)峰。在600 ~ 1050 nm区域吸收强度的增加表明形成了较大的非球形金纳米粒子。光学吸收光谱显示,随着合成溶液中HAuCl4浓度的增加,第二个LSPR峰向波长较长的近红外区域红移。此外,我们记录了320 nm激发下水稀释金胶体在370和458nm处的最大光致发光(PL)带,并考虑了PL的可能原因。我们试图在已知模型内阐明纳米胶体的光学和PL行为
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引用次数: 0
A method for fast calculating the electronic states in 2D quantum structures based on AIIIBV nitrides 基于aiibv氮化物的二维量子结构中电子态的快速计算方法
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.165
V. A. Slipokurov, P. Korniychuk, A. Zinovchuk
The paper presents a method for fast calculating the electronic states in two-dimensional quantum structures based on AIIIBV nitrides. The method is based on the representation of electronic states in the form of a linear combination of bulk wave functions of materials, from which quantum structures are made. The parameters and criteria for the selection of bulk wave functions that provides fast convergence of the numerical procedures for calculating the eigenvalues of the quantum Hamiltonian have been considered. The results of the calculations have been given both for one polar InGaN/GaN quantum well and for a system of several quantum wells. Being based on the full band structure of AIIIBV nitrides with a wurtzite-type crystal lattice, the proposed approach takes into account the states far from the center of the Brillouin zone, while preserving the computational efficiency of traditional methods of envelope function in approximating the effective mass.
本文提出了一种基于aiibv氮化物的二维量子结构中电子态的快速计算方法。该方法基于材料体波函数线性组合形式的电子态表示,量子结构由此产生。考虑了计算量子哈密顿特征值的数值过程的快速收敛的体波函数的选择参数和准则。本文给出了单极性InGaN/GaN量子阱和多个量子阱系统的计算结果。该方法基于具有纤锌矿型晶格的AIIIBV氮化物的全能带结构,考虑了远离布里渊区中心的状态,同时保留了传统包络函数方法在近似有效质量时的计算效率。
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引用次数: 0
Peculiarities of the effect of different types of SOR nanoimpurities on the value of ionic component of the electrical conductivity of the homeotropically aligned nematic liquid crystal 6 СВ 不同类型SOR纳米杂质对同向异性排列向列液晶电导率离子组分值影响的特殊性[6]СВ
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.173
Y. Garbovskiy, P. Kopčanský, O. Kovalchuk, T. Kovalchuk, L. V. Volokh
In this paper, the effects of SOR5, SOR10, and SOR15 nanoimpurities on the value of the ionic conductivity of the homeotropically aligned nematic liquid crystal 6CB are reported. Electrical measurements are carried out within a wide frequency range (from 6 Hz to 106 Hz) at room temperature (293 K). The largest changes in the electrical conductivity occur in the low-frequency range (less than 103 Hz) and depend on the type of nanoimpurity and on its concentration. Despite the similarity in the chemical composition of SOR5, SOR10, and SOR15, the measured dependences of the electrical conductivity of the studied samples on the concentration of nanoimpurities are substantially different. In the case of the SOR10 impurity, the ionic component of the electrical conductivity depends on the concentration of SOR10 according to a power law with an exponent approximately equal to 0.5, which is typical for the bimolecular recombination of charge carriers (i.e., the behavior of a weak electrolyte). Liquid crystal samples containing SOR5 and SOR15 nanoimpurities behave in a similar way in a low concentration region (between 0.01 and 0.05 mass %). Interestingly, further increase in the concentration of nanodopants (>0.05 mass %) results in a dramatically different behavior. The electrical conductivity of liquid crystals doped with SOR5 undergoes a sharp increase whereas the electrical conductivity of samples containing SOR15 decreases.
本文报道了SOR5、SOR10和SOR15纳米杂质对同向热带排列向列液晶6CB离子电导率的影响。在室温(293 K)下,在宽频率范围内(从6 Hz到106 Hz)进行电学测量。电导率的最大变化发生在低频范围(小于103 Hz),这取决于纳米杂质的类型及其浓度。尽管SOR5、SOR10和SOR15的化学组成相似,但所测样品的电导率对纳米杂质浓度的依赖关系却有很大不同。在SOR10杂质的情况下,电导率的离子成分取决于SOR10的浓度,根据指数约等于0.5的幂律,这是典型的电荷载流子的双分子重组(即弱电解质的行为)。含有SOR5和SOR15纳米杂质的液晶样品在低浓度区域(在0.01和0.05质量%之间)表现出相似的方式。有趣的是,进一步增加纳米掺杂剂的浓度(0.05质量%)会导致显著不同的行为。掺杂SOR5的液晶的电导率急剧增加,而含有SOR15的液晶的电导率则下降。
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引用次数: 0
Space charge region recombination, non-radiative exciton recombination and the band-narrowing effect in high-efficiency silicon solar cells 高效硅太阳能电池中的空间电荷区复合、非辐射激子复合和窄带效应
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.127
A. Sachenko, V. Kostylyov, V. Vlasiuk, I. Sokolovskyi, M. Evstigneev, D.F. Dvernikov, R. Korkishko, V. V. Chernenko
An expression for finding the dependence of narrowing the bands in silicon ΔEg on the level of illumination from the intrinsic absorption band (or short-circuit current) has been proposed. This expression is used to find experimental values of ΔEg in high-efficient silicon solar cells. The dependence ΔEg (J) or dependence ΔEg (JI), where JI is the short-circuit current density, has been rebuilt into the ΔEg (ΔnOC) dependence, where ΔnOC is the excitation level in open-circuit conditions. With this aim, the generation-recombination balance equation was solved taking into account six recombination mechanisms in silicon, including Shockley–Reed–Hall recombination, radiative recombination, interband Auger recombination, surface recombination, non-radiative exciton recombination, and recombination in the space charge region. The latter two recombination terms are not taken into account in studies of the key parameters of silicon solar cells and in programs for simulating the characteristics of these solar cells. Therefore, in this work their correct definition was performed, their contribution was compared with the contribution of other recombination mechanisms, and it has been shown that the description of the characteristics and key parameters of silicon SC without taking them into account is insufficiently correct. The experimental dependences ΔEg (ΔnOC) obtained in the work were compared with Schenk’s theory. It has been shown that there is a good agreement between them.
本文提出了一个表达式,用于计算硅中窄带ΔEg与本征吸收带(或短路电流)的照明水平的关系。该表达式用于计算高效硅太阳能电池中ΔEg的实验值。依赖关系ΔEg (J)或依赖关系ΔEg (JI),其中JI为短路电流密度,已重建为ΔEg (ΔnOC)依赖关系,其中ΔnOC为开路条件下的激励电平。为此,考虑了硅中六种复合机制,包括Shockley-Reed-Hall复合、辐射复合、带间俄歇复合、表面复合、非辐射激子复合和空间电荷区复合,求解了生成-复合平衡方程。在研究硅太阳电池的关键参数和模拟硅太阳电池特性的程序中,没有考虑后两个复合项。因此,在本工作中,对它们进行了正确的定义,并将它们的贡献与其他复合机制的贡献进行了比较,结果表明,没有考虑它们的硅SC的特性和关键参数的描述是不够正确的。所得的实验依赖关系ΔEg (ΔnOC)与Schenk理论进行了比较。这表明他们之间有很好的一致性。
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引用次数: 1
Diffuse reflectance spectroscopy of solid solutions in the Ag7PS6-Ag8GeS6 system Ag7PS6-Ag8GeS6体系中固溶体的漫反射光谱
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.152
T. Malakhovska, A. Pogodin, M. Filep, Y. Studenyak, O. Kokhan, O. Zubaka, V. Izai, P. Kúš
Samples of Ag7+x(P1–xGex)S6 (x = 0, 0.1, 0.25, 0.33, 0.5, 0.75, 1.0) solid solutions were obtained in the form of microcrystalline powders by grinding in an agate mortar. The diffuse reflectance spectra of the obtained Ag7+x(P1–xGex)S6 samples were studied in the spectral range 200 to 1400 nm at 293 K. The spectral dependences were analyzed using multilevel approximation by applying the Kubelka–Munk function and the Tauc method. It has been found that for Ag7+x(P1 xGex)S6 solid solutions, a red shift of the reflection edge beginning is observed with increasing the Ge content. The pseudo-gap values of Ag7+x(P1–xGex)S6 solid solutions was estimated by the Tauc method. It was found that the heterovalent cationic substitution P+5 → Ge+4 within the anionic sublattice leads to a monotonic nonlinear decrease in the pseudo-gap values.
在玛瑙砂浆中研磨得到了Ag7+x(P1-xGex)S6 (x = 0、0.1、0.25、0.33、0.5、0.75、1.0)固溶体样品。对所得的Ag7+x(P1-xGex)S6样品在293 K下200 ~ 1400 nm范围内的漫反射光谱进行了研究。采用Kubelka-Munk函数和tac方法,采用多水平近似分析了谱相关性。研究发现,对于Ag7+x(P1 xGex)S6固溶体,随着Ge含量的增加,反射边开始出现红移。用Tauc法估计了Ag7+x(P1-xGex)S6固溶体的赝隙值。发现阴离子亚晶格内P+5→Ge+4的异价阳离子取代导致赝隙值的单调非线性减小。
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引用次数: 0
Study of low-energy gamma-ray detection performance of silicon photomultiplier with LaBr3(Ce) scintillator LaBr3(Ce)闪烁体硅光电倍增管低能伽玛射线探测性能研究
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.236
K. Huseynzada, A. Mammadli, K. Isayev, J. Naghiyev, M. Holik, V. Tryshyn, S. Lyubchyk, D. Pekur
Recent progress in the field of scintillators and silicon photomultipliers (SiPM) has allowed development of new scintillation detectors capable of detecting low-energy X- and gamma-ray sources that are widely used in medicine, security and industry. Such scintillation detectors are compact, insensitive to magnetic fields, have low operation voltages and are functional at room temperature. These advantages of SiPM are considered to solve the main problems facing scintillation detectors in medicine and industry today. Development of detectors of low-energy electromagnetic radiation is relevant now. Scintillation detectors based on lutetium fine silicate, LaBr3(Ce), NaI and silicon avalanche photomultipliers offer a great potential for use for X- and gamma-ray detection. The present work demonstrates the gamma-ray detection performance of a new micropixel avalanche photodiode (MAPD) array (16 (4×4) elements – 15×15 cm) with a LaBr3(Ce) scintillator (15×15×30 mm) using 177Lu and 133Ba isotopes as the gamma-ray sources.
闪烁体和硅光电倍增管(SiPM)领域的最新进展使得能够探测低能量X射线和伽马射线源的新型闪烁探测器得以发展,这些探测器广泛应用于医学,安全和工业。这种闪烁探测器结构紧凑,对磁场不敏感,工作电压低,可在室温下工作。SiPM的这些优点被认为解决了目前医学和工业中闪烁探测器面临的主要问题。低能电磁辐射探测器的研制是当前研究的热点。基于细硅酸镥、LaBr3(Ce)、NaI和硅雪崩光电倍增管的闪烁探测器为X射线和伽马射线探测提供了巨大的潜力。本文以177Lu和133Ba同位素为伽马射线源,利用LaBr3(Ce)闪烁体(15×15×30 mm),演示了一种新型微像素雪崩光电二极管(MAPD)阵列(16 (4×4)元素- 15×15 cm)的伽马射线探测性能。
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引用次数: 0
Laser-induced thermal emission of carbon microparticles on transparent heat-sink substrates 透明热沉基板上碳微粒的激光诱导热发射
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.201
K. Zelenska, S. Zelensky, O. S. Kolesnik, T. Aoki, P. Teselko
Thermal emission is an informative tool to study materials’ properties at high temperatures under laser irradiation. The kinetics decay of laser-induced thermal emission from carbon microparticles deposited on heat-sink surfaces of transparent dielectrics (glass and sapphire) was studied. A Q-switched YAG:Nd3+ laser (pulse duration τi = 20 ns, energy/power density 0.5 J·cm–2, 25 MW·cm–2) was employed to excite thermal emission. In calculations, the classical heat conduction equation was used. With increasing the thermal conductivity of substrate (from glass to sapphire), reduction in the emission pulse duration has been observed.
热发射是研究材料在激光照射下高温特性的重要工具。研究了沉积在透明介质(玻璃和蓝宝石)热沉表面的碳微粒激光诱导热发射的动力学衰减。采用调q YAG:Nd3+激光器(脉冲持续时间τi = 20 ns,能量/功率密度0.5 J·cm-2, 25 MW·cm-2)激发热辐射。在计算中,采用经典的热传导方程。随着基材导热系数的增加(从玻璃到蓝宝石),可以观察到发射脉冲持续时间的减少。
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引用次数: 0
Kinetics of charge carriers in bilateral macroporous silicon 双侧大孔硅中载流子动力学
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.159
V. Onyshchenko, L. Karachevtseva, K. Andrieieva, N. Dmytruk, A. Z. Evmenova
The kinetics of charge carriers in bilateral macroporous silicon with macroporous layers of equal thicknesses is calculated by the finite difference method. A diffusion equation for a monocrystalline substrate and macroporous layers is solved. The boundary conditions are defined at the boundaries between the monocrystalline substrate and the macroporous silicon layers on both sides. Stationary distribution of excess charge carriers in the bilateral macroporous silicon with the macroporous layers of equal thicknesses calculated by the finite difference method is set as the initial condition. Under stationary conditions, excess charge carriers are generated by light with the wavelengths of 0.95 µm and 1.05 µm. It is shown that at the counting times much longer than the relaxation time, all the distributions of the concentration of excess minority carriers generated by light with any wavelength approach the same distribution with exponentially decreasing value.
用有限差分法计算了具有等厚度大孔层的双侧大孔硅中载流子的动力学。求解了单晶衬底和大孔层的扩散方程。边界条件定义在单晶衬底和两侧大孔硅层之间的边界处。以有限差分法计算的等厚度双侧大孔硅中多余载流子的平稳分布为初始条件。在固定条件下,波长为0.95µm和1.05µm的光会产生多余的载流子。结果表明,在计数次数远长于弛豫时间时,任意波长的光产生的过量少数载流子浓度的分布都趋于相同的指数递减分布。
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引用次数: 0
Formation of ZnO films on SiC/porous Si/Si substrates SiC/多孔Si/Si衬底上ZnO薄膜的形成
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.140
V. Kidalov, A. Dyadenchuk, V. Baturin, O. Karpenko, O. Kolomys, V. V. Ponomarenko, Z. Maksimenko, V. Strelchuk, Y. Bacherikov, O. B. Okhrimenko
Reactive magnetron sputtering was used to obtain ZnO films on SiC/porous Si/Si substrates. The silicon carbide film on the surface of porous Si was obtained using chemical substitution of atoms. It has been shown that ZnO films grown at the partial oxygen pressure 0.6 Pa are characterized by a smoother and more uniform surface than coatings grown at the oxygen pressure 0.1 Pa. Being based on the analysis of Raman and photoluminescence spectra, it has been shown that the increase in partial pressure of oxygen leads to the increase in structural disorder of the ZnO crystal lattice, on the one hand, and at the same time to a decrease in the concentration of intrinsic defects, including ionized oxygen vacancies Oi, on the other hand.
采用反应磁控溅射技术在SiC/多孔Si/Si衬底上制备ZnO薄膜。采用化学取代原子的方法在多孔硅表面制备了碳化硅薄膜。结果表明,在0.6 Pa氧分压下生长的ZnO薄膜比在0.1 Pa氧分压下生长的ZnO薄膜表面更光滑、均匀。基于拉曼光谱和光致发光光谱的分析表明,氧气分压的增加一方面导致ZnO晶格结构无序性的增加,另一方面导致包括电离氧空位Oi在内的本征缺陷浓度的降低。
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引用次数: 0
Transformation of defects in semiconductor structures under action of magnetic fields stimulated by drift phenomena 半导体结构中缺陷在漂移现象激发的磁场作用下的转变
Pub Date : 2023-06-26 DOI: 10.15407/spqeo26.02.147
G. Milenin, R. Redko
The phenomenon of directed motion of mobile charged point defects in semiconductor structures under action of magnetic fields has been discussed. The features of defect drift in sign-changing magnetic fields have been studied. The effect of directional movement of charged defects under the combined action of constant and alternating magnetic fields has been analyzed. Analytical relations have been presented for the drift rate of defects in semiconductor structures under given impacts.
讨论了半导体结构中可移动带电点缺陷在磁场作用下的定向运动现象。研究了变符号磁场中缺陷漂移的特征。分析了恒定磁场和交变磁场共同作用下带电缺陷定向运动的影响。给出了给定冲击下半导体结构中缺陷漂移速率的解析关系式。
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引用次数: 0
期刊
Semiconductor physics, quantum electronics and optoelectronics
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