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Integrated dynamical phase-variation diffracto-metry of single crystals with defects of three and more types 含三种及三种以上缺陷的单晶动态变相综合衍射法
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.017
V. Molodkin, V. Storizhko, V. Kladko, V. Lizunov, A. I. Nizkova, A. Gudimenko, S. I. Olikhovskii, M. G. Tolmachev, S. V. Dmitriev, I. I. Demchyk, E.I. Bogdanov, B. I. Hinko
Generalization of the methods for the purposeful influence of the interrelated variations inherent to different experimental conditions on changes in the selectivity of the sensitivity of the azimuthal dependence of the total integrated intensity of dynamical diffraction to various types of defects in single crystals has been carried out. As a result, the improved phase-variation methods with additionally increased sensitivity and informativity of non-destructive structural diagnostics aimed at multi-parametrical single crystal systems have been developed.
推广了不同实验条件下固有的相互关联的变化对单晶中各种类型缺陷的动态衍射总积分强度的方位依赖性的选择性灵敏度变化的有目的影响的方法。因此,针对多参数单晶系统的非破坏性结构诊断,改进的相位变化方法进一步提高了灵敏度和信息量。
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引用次数: 0
Experimental study of the compensation method for atmospheric attenuation of probing laser radiation in active electro-optical systems that provide an increase of target image contrast 有源电光系统探测激光辐射大气衰减补偿方法的实验研究,以提高目标图像对比度
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.105
L. Kupchenko, A. S. Rybiak, О.А. Goorin, A.P. Hurin, А.V. Ponomar, O. Biesova
The article deals with the experimental study of the compensation method for atmospheric attenuation of laser radiation in active electro-optical remote sensing systems with dynamic spectral processing of optical signals that provides an increase of target image contrast. The compensation method for atmospheric attenuation of laser radiation in active electro-optical systems consists in forming the spectral intensity of the probing radiation not only on the basis of a priori data on the spectral features of the reflecting surfaces of the target and the background, but also taking into account the spectral transmittance of the optical radiation propagation medium. The experimental setup has been developed, in which the source of radiation in the transmitting part of the electro- optical system is three semiconductor lasers operating in the ranges of the red, green and blue parts of the spectrum. Absorption light filters were used in the experiment as elements simulating the spectral properties of the reflecting surfaces of the target and background. The cuvettes with a liquid absorbing optical radiation were used as elements simulating atmospheric attenuation.
本文通过对光信号进行动态光谱处理,提高目标图像对比度,对有源电光遥感系统中激光辐射大气衰减的补偿方法进行了实验研究。在有源电光系统中,大气对激光辐射衰减的补偿方法不仅是根据目标和背景反射面光谱特征的先验数据来形成探测辐射的光谱强度,而且还要考虑光辐射传播介质的光谱透射率。建立了一种实验装置,其中电光系统发射部分的辐射源是在光谱的红、绿、蓝部分范围内工作的三个半导体激光器。实验采用吸收滤光片作为模拟目标和背景反射表面光谱特性的元件。采用液体吸收光辐射的比色皿作为模拟大气衰减的元件。
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引用次数: 0
Electromagnetic radiation of semiconductor crystals in crossed electric and magnetic fields 半导体晶体在交叉电场和磁场中的电磁辐射
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.025
G. Milenin, R. Redko
The features of generation of electromagnetic radiation by semiconductor crystals in crossed electric and magnetic fields have been analyzed. Analytical relations for calculating the power of cyclotron radiation have been given. The obtained results are of interest for the purposes of obtaining the sources of electromagnetic radiation in the terahertz frequency range.
分析了半导体晶体在交叉电场和磁场中产生电磁辐射的特点。给出了计算回旋辐射功率的解析关系式。所得结果对获得太赫兹频率范围内的电磁辐射源具有重要意义。
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引用次数: 0
Surface-enhanced Raman scattering of As2S3 and Se thin films formed on Au nano-structures 在Au纳米结构上形成As2S3和Se薄膜的表面增强拉曼散射
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.049
V. Yukhymchuk, V. M. Rubish, V. Dzhagan, O. Hreshchuk, O. Isaieva, N. Mazur, M. Durkot, A. Kryuchyn, V. Kyrylenko, V. M. Novichenko, V.V. Kremenytskyi, Z. Maksimenko, M. Valakh
The effect of plasmonic nanostructures (NSs) on the Raman spectra and underlying structural changes in thin chalcogenide films is investigated. Several tens of nanometers thick As 2 S 3 and Se films were deposited by thermal sputtering on glass and surface-enhanced Raman spectroscopy (SERS) substrates based on gold nanostructures for comparison. The films on glass were practically not detectable by the Raman spectroscopy. Using gold NSs as the substrates enabled reliable registration of the Raman spectra of both the As 2 S 3 and Se films. The registered Raman spectra contained all the features usually present in the films with the thicknesses ~1 μm or more. Based on our analysis of the spectra obtained at different excitation wavelengths, we may conclude that the SERS chemical mechanism makes the main contribution to the enhancement of the Raman signal from chalcogenide films. Adjustment of the parameters of SERS substrates to tune their plasmon band position in resonance with the excitation laser radiation enables increasing the plasmonic enhancement contribution. Besides the effect of enhancement, localized plasmon resonance in the gold NSs causes local heating of the chalcogenide film around them leading to local structural transformations, which can be controlled using the Raman spectra.
研究了等离子体纳米结构(NSs)对硫系薄膜拉曼光谱和底层结构变化的影响。采用热溅射的方法在基于金纳米结构的玻璃和表面增强拉曼光谱(SERS)衬底上沉积了数十纳米厚的as2o3和Se薄膜,并进行了比较。玻璃上的薄膜几乎无法用拉曼光谱检测到。使用金纳米粒子作为衬底,可以可靠地记录as2o3和Se薄膜的拉曼光谱。注册的拉曼光谱包含了厚度大于等于1 μm薄膜的所有特征。通过对不同激发波长下的光谱分析,我们可以得出结论,SERS化学机制是硫系化合物薄膜拉曼信号增强的主要原因。调整SERS衬底的参数以调整其等离子体带位置与激发激光辐射的共振,可以增加等离子体增强的贡献。除了增强效应外,金纳米粒子中的局部等离子体共振还会引起其周围硫系化合物膜的局部加热,从而导致局部结构转变,这可以通过拉曼光谱来控制。
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引用次数: 0
Luminescent and Raman study of nanostruc-tures formed upon annealing of SiOx:Sm films SiOx:Sm薄膜退火后纳米结构的发光和拉曼研究
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.068
K. Michailovska, I. Indutnyi, P. Shepeliavyi, M. Sopinskyy, V. Dan’ko, V. Yukhymchuk
ncs-Si–SiO x :Sm structures formed by high-temperature air annealing of the SiO x films doped with samarium during thermal co-evaporation in vacuum of silicon monoxide and metallic Sm was studied. By measuring the spectra of photoluminescence (PL), it has been shown that doping of SiO x films with Sm stimulates their decomposition into Si and SiO 2 , and also reduces the transition temperature of silicon nanoparticle from the amorphous state to the crystalline one. With an increase in the impurity content up to 2 wt.%, along with the ncs-Si luminescence, the PL spectrum exhibits emission bands of Sm 3+ and Sm 2+ ions, which do not appear at a lower Sm concentration. The presence of silicon nanocrystals in SiO x films doped with Sm and annealed at 970 °C in air has been confirmed using Raman scattering spectra. A possible mechanism for interaction of samarium ions with the SiO x matrix and ncs-Si has been discussed.
研究了一氧化硅与金属Sm在真空中热共蒸发过程中掺杂钐的SiO x薄膜经高温空气退火后形成的ncs-Si-SiO x:Sm结构。通过光致发光(PL)光谱的测量表明,Sm的掺杂促进了SiO x薄膜分解为Si和sio2,并降低了硅纳米颗粒从非晶态到结晶态的转变温度。当杂质含量增加到2 wt.%时,随着ncs-Si的发光,PL光谱呈现出sm3 +和sm2 +离子的发射带,而在较低的Sm浓度下则不出现。用拉曼散射光谱证实了掺Sm并在970℃空气中退火的SiO x薄膜中存在硅纳米晶体。讨论了钐离子与siox基体和ncs-Si相互作用的可能机理。
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引用次数: 1
Modeling of characteristics of highly efficient textured solar cells based on c-silicon. The influence of recombination in the space charge region 基于c-硅的高效纹理太阳能电池特性建模。复合对空间电荷区的影响
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.005
A. Sachenko, V. Kostylyov, V. Vlasiuk, I. Sokolovskyi, M. Evstigneev, T. Slusar, V. V. Chernenko
Theoretical modeling of the optical and photovoltaic characteristics of highly efficient textured silicon solar cells (SC), including short-circuit current, open-circuit voltage and photoconversion efficiency, has been performed in this work. In the modeling, such recombination mechanisms as non-radiative exciton recombination relative to the Auger mechanism with the participation of a deep recombination level and recombination in the space charge region (SCR) was additionally taken into account. In a simple approximation, the external quantum efficiency of the photocurrent for the indicated SC in the long-wavelength absorption region has been simulated. A theory has been proposed for calculating the thickness dependences of short-circuit current, open-circuit voltage and photoconversion efficiency in them. The calculated dependences are carefully compared with the experimental results obtained for SC with the p+-i-α-Si:H/n-c-Si/i-n+-α-Si:H architecture and the photoconversion efficiency of about 23%. As a result of this comparison, good agreement between the theoretical and calculated dependences has been obtained. It has been ascertained that without taking into account recombination in SCR, a quantitative agreement between the experimental and theoretical light I V characteristics and the dependence of the output power in the SC load on the voltage on it cannot be obtained. The proposed approach and the obtained results can be used to optimize the characteristics of textured SC based on monocrystalline silicon.
本文对高效纹理硅太阳能电池(SC)的光学和光伏特性进行了理论建模,包括短路电流、开路电压和光转换效率。在建模中,还考虑了深层复合层参与的相对于俄歇机制的非辐射激子复合和空间电荷区(SCR)的复合等复合机制。在一个简单的近似,光电流的外量子效率的指示SC在长波长吸收区已经模拟。提出了一种计算短路电流、开路电压和光转换效率与厚度关系的理论。计算结果与p+-i-α-Si:H/n-c-Si/i-n+-α-Si:H结构的SC的实验结果进行了仔细的比较,光转换效率约为23%。这种比较的结果是,理论依赖关系与计算依赖关系很好地吻合。已经确定,如果不考虑可控硅中的复合,实验和理论的光I - V特性以及SC负载中输出功率对电压的依赖关系之间的定量一致是无法获得的。所提出的方法和所得结果可用于优化单晶硅织构SC的特性。
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引用次数: 1
Electrical properties of highly nitrogen-doped 6H-SiC single crystals: Microwave cavity perturbation study 高氮掺杂6H-SiC单晶的电学性质:微波腔微扰研究
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.030
D. Savchenko, D.M. Yatsyk, O.M. Genkin, Yu.F. Nosachov, O. V. Drozdenko, V. Moiseenko, E. Kalabukhova
The silicon carbide (SiC) single crystals of 6H polytype with nitrogen donor concentration ND – NA) ≈ 1∙1017 ...4∙1019 cm –3 grown using the modified Lely method were studied applying the cavity perturbation method. From the temperature dependence of the resonant frequency shift and microwave loss of the cavity loaded with samples under study, the temperature dependence of the conductivity was estimated. From the temperature dependence of the natural logarithm of conductivity versus 1000/T, the activation energies for processes corresponding to electron transitions from impurity levels to the conduction band (ε1) and electron hopping over nitrogen donors in the D0 bands (ε3) were determined. It was found that in 6H-SiC ε1 = 50 meV for (ND – NA) ≈ 1∙10 17 cm –3 , ε1 = 32 meV and ε3 = 6 meV for (ND – NA) ≈ 1∙1019cm–3 , ε1 = 13.5 meV and ε3 = 3.5 meV for ((ND – NA) ≈ 4∙1019 cm–3.
氮供体浓度为ND - NA)≈1∙1017的6H型碳化硅(SiC)单晶采用改进的Lely法培养的4∙1019 cm -3,采用空腔摄动法进行研究。从加载样品腔的谐振频移和微波损耗的温度依赖性出发,估计了电导率的温度依赖性。根据电导率的自然对数对1000/T的温度依赖性,确定了电子从杂质能级跃迁到导带(ε1)和电子在D0带(ε3)上跳过氮供体的过程的活化能。结果表明,在6H-SiC中,(ND - NA)≈1∙10 17 cm - 3的ε1 = 50 meV, (ND - NA)≈1∙1019cm-3的ε1 = 32 meV和ε3 = 6 meV, (ND - NA)≈4∙1019 cm - 3的ε1 = 13.5 meV和ε3 = 3.5 meV。
{"title":"Electrical properties of highly nitrogen-doped 6H-SiC single crystals: Microwave cavity perturbation study","authors":"D. Savchenko, D.M. Yatsyk, O.M. Genkin, Yu.F. Nosachov, O. V. Drozdenko, V. Moiseenko, E. Kalabukhova","doi":"10.15407/spqeo26.01.030","DOIUrl":"https://doi.org/10.15407/spqeo26.01.030","url":null,"abstract":"The silicon carbide (SiC) single crystals of 6H polytype with nitrogen donor concentration ND – NA) ≈ 1∙1017 ...4∙1019 cm –3 grown using the modified Lely method were studied applying the cavity perturbation method. From the temperature dependence of the resonant frequency shift and microwave loss of the cavity loaded with samples under study, the temperature dependence of the conductivity was estimated. From the temperature dependence of the natural logarithm of conductivity versus 1000/T, the activation energies for processes corresponding to electron transitions from impurity levels to the conduction band (ε1) and electron hopping over nitrogen donors in the D0 bands (ε3) were determined. It was found that in 6H-SiC ε1 = 50 meV for (ND – NA) ≈ 1∙10 17 cm –3 , ε1 = 32 meV and ε3 = 6 meV for (ND – NA) ≈ 1∙1019cm–3 , ε1 = 13.5 meV and ε3 = 3.5 meV for ((ND – NA) ≈ 4∙1019 cm–3.","PeriodicalId":21598,"journal":{"name":"Semiconductor physics, quantum electronics and optoelectronics","volume":"98 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91467129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Optical characteristics of silver-based nano-composites fabricated by an environmentally friendly method 环境友好法制备银基纳米复合材料的光学特性
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.076
T. Malakhovska, A. Pogodin, M. Filep, M. Pop, Y. Studenyak, K.M. Nemesh, R. Mariychuk, V. Vakulchak, V. Komanický, S. Vorobiov
This work presents a simple and environmentally friendly method of synthesis of chitosan and Ag nanocomposites. The structure of the obtained organic matrix was determined by Fourier-transform infrared spectroscopy (FTIR). Formation of chitosan- chitin copolymer was discovered. Nanocomposite films with silver content of 9–71 wt.% were prepared. The microstructure and elemental composition of the obtained films were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The prepared films are characterized by uniform distribution of silver nanoparticles in the organic matrix. Optical properties were studied by diffuse reflectance spectroscopy. The diffuse reflectance spectra of the films have maxima. The increase of the Ag 0 concentration in the nanocomposite films was found to lead to the maximum shift of the diffuse reflectance spectra to longer wavelengths. The optical transitions energies were estimated using the Kubelka–Munk function in combination with the Tauc method.
本文提出了一种简单、环保的合成壳聚糖和银纳米复合材料的方法。用傅里叶变换红外光谱(FTIR)测定了所得有机基质的结构。发现了壳聚糖-几丁质共聚物的形成。制备了银含量为9 ~ 71 wt.%的纳米复合薄膜。采用扫描电子显微镜(SEM)和x射线能谱仪(EDS)研究了薄膜的微观结构和元素组成。所制备的薄膜具有银纳米粒子在有机基质中均匀分布的特点。用漫反射光谱法研究了其光学性质。薄膜的漫反射光谱有最大值。研究发现,随着银浓度的增加,纳米复合膜的漫反射光谱向更长波方向最大位移。利用Kubelka-Munk函数结合tac方法估计了光跃迁能。
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引用次数: 1
Complex formation of 1D-coordination poly-mers based on arendiyl-bisphosphinic acid 基于arendiyl-双膦酸的一维配位聚合物的配合物形成
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.036
R. Balabai, O. Bondarenko, M.V. Yatsiuta
Within the framework of the density functional theory and the ab initio pseudopotential, we have obtained the spatial distributions of the valence electrons density, the electron energy spectra and the atom charge states of 1D-coordination polymers based on arendiyl-bisphosphinic acids and metal ions. Formation of one-dimensional polymer chains takes place under participation of strong intermolecular bonds.
在密度泛函理论和从头算赝势的框架下,我们得到了基于双膦酸和金属离子的一维配位聚合物的价电子密度、电子能谱和原子电荷态的空间分布。一维聚合物链的形成是在强分子间键的参与下进行的。
{"title":"Complex formation of 1D-coordination poly-mers based on arendiyl-bisphosphinic acid","authors":"R. Balabai, O. Bondarenko, M.V. Yatsiuta","doi":"10.15407/spqeo26.01.036","DOIUrl":"https://doi.org/10.15407/spqeo26.01.036","url":null,"abstract":"Within the framework of the density functional theory and the ab initio pseudopotential, we have obtained the spatial distributions of the valence electrons density, the electron energy spectra and the atom charge states of 1D-coordination polymers based on arendiyl-bisphosphinic acids and metal ions. Formation of one-dimensional polymer chains takes place under participation of strong intermolecular bonds.","PeriodicalId":21598,"journal":{"name":"Semiconductor physics, quantum electronics and optoelectronics","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87307041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of gamma-ray sensitivity of YAG:Ce based scintillation structures YAG:Ce基闪烁结构的伽马射线灵敏度研究
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.089
D. Pekur, D. Khmil’, Y. Bacherikov, A. Mammadli, J. Naghiyev, N.Y. Suleymanova, C.Y. Abbasova, S. Lyubchyk
Ionizing radiation is widely used nowadays for diagnosing and probing a wide range of objects due to the high reliability and quality of the results obtained in such research. Use of highly sensitive ionizing radiation sensors enables the reduction of the radiation dose involved in the research. Moreover, sensitive systems for monitoring environmental parameters may be also created based on such sensors. In this work, the efficiency of a low density radiation detector with the composite scintillation structure based on powdery YAG:Ce phosphor as the converting coating of photosensitive detector was investigated. The possibility to detect gamma radiation from the 241 Am and 137 Cs based sources by the ionizing radiation detector comprising YAG:Ce 3+ composite converting scintillation structure and micropixel avalanche photodiode (MAPD) was found. The number of detected gamma rays emitted by the 241 Am source was shown to increase linearly with the thickness of the composite converting scintillation structure. The thickness of the composite converting scintillation structure of 495 µm was found to enable registration of gamma-rays with the energies in the range of 26 to 662 keV.
由于电离辐射研究结果的高可靠性和高质量,目前被广泛用于诊断和探测各种物体。使用高灵敏度的电离辐射传感器可以减少研究中涉及的辐射剂量。此外,还可以基于这种传感器创建用于监测环境参数的敏感系统。本文研究了以YAG:Ce粉末荧光粉为光敏探测器转换涂层的复合闪烁结构低密度辐射探测器的效率。发现了用YAG: ce3 +复合转换闪烁结构和微像素雪崩光电二极管(MAPD)组成的电离辐射探测器探测241 Am和137 Cs源伽马辐射的可能性。探测到的241 Am源发射的伽马射线的数量与复合转换闪烁结构的厚度呈线性增加。复合转换闪烁结构厚度为495µm,可以记录能量在26 ~ 662 keV之间的伽玛射线。
{"title":"Investigation of gamma-ray sensitivity of YAG:Ce based scintillation structures","authors":"D. Pekur, D. Khmil’, Y. Bacherikov, A. Mammadli, J. Naghiyev, N.Y. Suleymanova, C.Y. Abbasova, S. Lyubchyk","doi":"10.15407/spqeo26.01.089","DOIUrl":"https://doi.org/10.15407/spqeo26.01.089","url":null,"abstract":"Ionizing radiation is widely used nowadays for diagnosing and probing a wide range of objects due to the high reliability and quality of the results obtained in such research. Use of highly sensitive ionizing radiation sensors enables the reduction of the radiation dose involved in the research. Moreover, sensitive systems for monitoring environmental parameters may be also created based on such sensors. In this work, the efficiency of a low density radiation detector with the composite scintillation structure based on powdery YAG:Ce phosphor as the converting coating of photosensitive detector was investigated. The possibility to detect gamma radiation from the 241 Am and 137 Cs based sources by the ionizing radiation detector comprising YAG:Ce 3+ composite converting scintillation structure and micropixel avalanche photodiode (MAPD) was found. The number of detected gamma rays emitted by the 241 Am source was shown to increase linearly with the thickness of the composite converting scintillation structure. The thickness of the composite converting scintillation structure of 495 µm was found to enable registration of gamma-rays with the energies in the range of 26 to 662 keV.","PeriodicalId":21598,"journal":{"name":"Semiconductor physics, quantum electronics and optoelectronics","volume":"161 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77731599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
Semiconductor physics, quantum electronics and optoelectronics
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