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Silicon lenses with HDPE anti-reflection coatings for low THz frequency range 低太赫兹频率范围内HDPE抗反射涂层的硅透镜
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.059
A. Shevchik-Shekera, F. Sizov, O. Golenkov, I. Lysiuk, V.О. Petriakov, Mykola Kovbasa
Presented in this paper have been the design, fabrication, and testing of the high resistance floating-zone silicon (HRFZ-Si) optics with the anti-reflection (AR) high-density polyethylene (HDPE) coatings, for the low part of terahertz (THz) frequency range (ν ≈ 0.14 THz), by using the precision press molding. Experimental results of the transmission of the wafers and lenses with double-sided anti-reflection HDPE coatings for radiation frequency 0.14 THz showed an increase in the transmittance T values up to ≈1.45 times as compared to T magnitudes in wafers and lenses without HDPE coatings. The capability to use terahertz lenses with HDPE interference films and the technology of press molding, as a cheaper alternative to the horn antenna applications for the terahertz range of 0.14 THz was shown. With advancements in THz imaging and 6G communication technologies, further implementation of these Si optical elements is possible.
本文介绍了在太赫兹(THz)频率范围(ν≈0.14 THz)的低频段(ν≈0.14 THz),采用精密压制成型的方法,设计、制造和测试了高阻浮区硅(HRFZ-Si)光学器件,并在其上涂有抗反射(AR)高密度聚乙烯(HDPE)涂层。对辐射频率为0.14 THz的双面增透HDPE涂层的晶片和透镜的透射率进行了实验,结果表明,与未涂HDPE涂层的晶片和透镜相比,透射率T值增加了约1.45倍。展示了使用带有HDPE干涉膜的太赫兹透镜和压制成型技术的能力,作为0.14太赫兹范围内喇叭天线应用的更便宜的替代方案。随着太赫兹成像和6G通信技术的进步,这些Si光学元件的进一步实现是可能的。
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引用次数: 0
Application of the surface plasmon resonance phenomenon to controlling suspensions 表面等离子体共振现象在控制悬浮液中的应用
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.084
A. Fedorenko, N. Kachur, H. Dorozinska, G. Dorozinsky, V.P. Maslo, O. Sulima, T. Rudyk
Represented in this paper are the results of investigations aimed at checking up the capabilities of devices based on the surface plasmon resonance (SPR) phenomenon to be applied for studying the properties of water suspensions. As an example, the authors used here the suspensions of tooth pastes Sensodyne and Colgate in distilled water. For measurements, we used the SPR device Plasmon-71 operating in the near infrared spectral range. Results of these measurements were compared to those obtained using the spectrophotometric ones. The measured values of the sedimentation velocity obtained using both the applied methods confirmed availability to efficiently apply SPR devices for studying the opaque multi-component suspensions.
本文介绍了基于表面等离子体共振(SPR)现象的装置用于研究水悬浮液性质的能力的研究结果。作为一个例子,作者在这里使用了Sensodyne和高露洁牙膏在蒸馏水中的悬浮液。为了测量,我们使用了SPR装置等离子体-71在近红外光谱范围内工作。将这些测量结果与分光光度法测量结果进行了比较。两种方法得到的沉降速度实测值证实了SPR装置有效应用于不透明多组分悬浮液研究的可行性。
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引用次数: 0
Dynamics of temperature dependence of the dielectric properties of a nanocomposite material based on linear polyethylene in the vicinity of the percolation transition 线性聚乙烯纳米复合材料介电性能在渗透转变附近的温度依赖动力学
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.041
O. Kovalchuk, T. Kovalchuk, Y. Garbovskiy, R.F. Svistilnik, D.V. Pushkarov, L. V. Volokh, O.A. Lagoda, I. V. Oleinikova
Within the frequency range of 30 to 105 Hz and temperatures of 18 to 80 °C, the dielectric properties of linear low-density polyethylene with impurities of flame retardant (20 wt.%) and multilayer carbon nanotubes (1.5 wt.%) were investigated using the oscilloscopic method. This concentration value of carbon nanotubes slightly exceeds the concentration of nanotubes (1%), at which the percolation transition begins for the dependence of the polymer electrical conductivity on the content of nanotubes. It has been shown that the frequency dependence of electrical conductivity can be approximated by two exponential dependences. It has been found that when the sample is cooled, changes in the values of dielectric permittivity and electrical conductivity do not occur in the same way as when heated. The temperature dependences of conductivity for low (102 Hz) and high (104 Hz) frequencies have been obtained.
在频率为30 ~ 105 Hz、温度为18 ~ 80℃的条件下,用示波器法研究了含阻燃剂(20 wt.%)和多层碳纳米管(1.5 wt.%)的线性低密度聚乙烯的介电性能。碳纳米管的浓度略高于纳米管的浓度(1%),此时聚合物电导率对纳米管含量的依赖开始发生渗透转变。电导率的频率依赖性可以用两个指数依赖性来近似表示。已经发现,当样品冷却时,介电常数和电导率值的变化与加热时不同。获得了低(102 Hz)和高(104 Hz)频率下电导率的温度依赖性。
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引用次数: 0
Utilizing machine learning algorithm in predicting the power conversion efficiency limit of a monolithically perovskites/silicon tandem structure 利用机器学习算法预测单片钙钛矿/硅串联结构的功率转换效率极限
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.114
M. Ganoub, O. Al-Saban, S. Abdellatif, K. Kirah, H. A. Ghali
Tandem structures have been introduced to the photovoltaics (PV) market to boost power conversion efficiency (PCE). Single-junction cells’ PCE, either in a homojunction or heterojunction format, are clipped to a theoretical limit associated with the absorbing material bandgap. Scaling up the single-junction cells to a multi-junction tandem structure penetrates such limits. One of the promising tandem structures is the perovskite over silicon topology. Si junction is utilized as a counter bare cell with perovskites layer above, under applying the bandgap engineering aspects. Herein, we adopt BaTiO 3 /CsPbCl 3 /MAPbBr 3 /CH 3 NH 3 PbI 3 /c-Si tandem structure to be investigated. In tandem PVs, various input parameters can be tuned to maximize PCE, leading to a massive increase in the input combinations. Such a vast dataset directly reflects the computational requirements needed to simulate the wide range of combinations and the computational time. In this study, we seed our random-forest machine learning model with the 3×10 6 points’ dataset with our optoelectronic numerical model in SCAPS. The machine learning could estimate the maximum PCE limit of the proposed tandem structure at around 37.8%, which is more than double the bare Si-cell reported by 18%.
串联结构已被引入光伏(PV)市场以提高功率转换效率(PCE)。单结电池的PCE,无论是同质结还是异质结,都被限制到与吸收材料带隙相关的理论极限。将单结电池扩展到多结串联结构突破了这些限制。其中一个很有前途的串联结构是钙钛矿硅拓扑结构。在应用带隙工程方面,硅结被用作钙钛矿层的对抗裸电池。本文采用batio3 /CsPbCl 3 /MAPbBr 3 / ch3nh3 pbi3 /c-Si串联结构进行研究。在串联pv中,可以调整各种输入参数以最大化PCE,从而导致输入组合的大量增加。如此庞大的数据集直接反映了模拟大范围组合所需的计算需求和计算时间。在本研究中,我们将随机森林机器学习模型与3×10 6点数据集结合在SCAPS中的光电数值模型中。机器学习可以估计所提出的串联结构的最大PCE限制约为37.8%,是裸硅电池(18%)的两倍多。
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引用次数: 1
Investigation of energy efficiency index for indoor LED lighting units 室内LED照明装置能效指标的研究
Pub Date : 2023-03-24 DOI: 10.15407/spqeo26.01.097
A. Gaballah, Alaaeldin A. Abdelmageed, E. El-Moghazy
The energy efficiency index (EEI) is an important factor used as an indicator either for building energy consumption or electronic device performance; it allows one to select effective devices that save energy. This work studies the performance of different types of LED lamps used in indoor lighting, the lamps currently available in the Egyptian market have been tested according to their photometric and electric parameters, namely: luminous flux, power factor, and EEI. Three different brands E, T, and V have been chosen with the nominal powers 9, 12, and 15 W. The results showed that both 9- and 15-Watt lamps have the same EEI values as 0.14, 0.13, and 0.12 for T, V, and E lamps, respectively, whereas 12-Watt lamps have EEI values of 0.16, 0.13, and 0.13 for T, V, and E lamps, respectively. The experimental testing of these lamps revealed that all the lamps have the same EEI class (A+) regardless of the nominal power. The results also revealed a relationship between the power factor and EEI: as the power factor increases, EEI increases, too. The expanded uncertainty in luminous flux has been calculated.
能源效率指数(EEI)是建筑能耗或电子设备性能的重要指标;它允许人们选择有效的节能设备。这项工作研究了不同类型的用于室内照明的LED灯具的性能,目前在埃及市场上销售的灯具已经根据其光度和电气参数进行了测试,即:光通量,功率因数和EEI。三个不同的品牌E, T和V已选择标称功率9,12和15w。结果表明,9瓦灯和15瓦灯的EEI值分别为T、V和E灯的0.14、0.13和0.12,而12瓦灯的EEI值分别为T、V和E灯的0.16、0.13和0.13。这些灯的实验测试表明,无论标称功率如何,所有灯都具有相同的EEI等级(A+)。结果还揭示了功率因数和EEI之间的关系:随着功率因数的增加,EEI也会增加。计算了光通量的扩展不确定度。
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引用次数: 2
Scanning probe lithography on Ge(111)-c(2×8) surface Ge(111)-c(2×8)表面扫描探针光刻
Pub Date : 2022-12-22 DOI: 10.15407/spqeo25.04.379
A. Goriachko
The paper describes nanometer scale lithography on atomically clean Ge(111)-c(2×8) surface performed in the ultra-high vacuum scanning tunneling microscope operating at 300 K. Using a standard Pt80Ir20 probe tip and applying bias voltages between 0.5 and 3 V, the Ge surface could be reliably imaged with atomic resolution without any modification of the sample. However, surface modification in highly localized area under the probe tip was observed at the bias voltages from 4 to 5 V. Such modification could occur in the form of the deposition of the tip material onto the scanned area of the sample, extraction of the sample material or generation of defects in the sample crystalline structure. Possible physical mechanisms of the processes outlined above as well as the strategies to achieve reliable scanning probe nanolithography are discussed.
本文描述了在300 K超高真空扫描隧道显微镜下对原子清洁的Ge(111)-c(2×8)表面进行纳米级光刻。使用标准的Pt80Ir20探针尖端并施加0.5至3 V的偏置电压,可以在不修改样品的情况下以原子分辨率可靠地成像Ge表面。然而,在4 ~ 5 V的偏置电压下,在探针尖端高度局部区域观察到表面修饰。这种修饰可以在样品的扫描区域上沉积尖端材料,提取样品材料或在样品晶体结构中产生缺陷的形式发生。讨论了上述过程的可能物理机制以及实现可靠扫描探针纳米光刻的策略。
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引用次数: 0
Self-organized structures induced by external white noise and nanosized levels of their formation in the non-crystalline As-S(Se) semiconductor systems 非晶As-S(Se)半导体系统中外部白噪声诱导的自组织结构及其纳米级形成
Pub Date : 2022-12-22 DOI: 10.15407/spqeo25.04.402
M. Mar’yan, N. Yurkovych, V. Šebeň
Discussed in this paper are the singularity and self-organizing effect of instability and randomness under the influence of external white noise on formation of non-crystalline materials. The random nature of the receiving medium together with the disorganizing effect was found to be capable to initiate formation of qualitatively new self-organized structures in non-crystalline solids. Also analyzed in the paper is the effect of a random temperature field applied to the melt during the cooling process in non-crystalline As-S(Se) semiconductor systems. The conditions for a non-crystalline system in a fluctuating external environment to adjust its properties to the average properties of the environment and to correspond to the deterministic case were identified. Furthermore, the conditions for non-additive reaction of the system to a random environment and formation of a new mode of energy conversion in the self-organized structure at the nanoscale level are determined. The spectrum of the structures created in this way is more diverse as compared to the spectrum corresponding to respective deterministic conditions.
本文讨论了在外部白噪声的影响下,不稳定性和随机性的奇异性和自组织效应对非晶体材料形成的影响。发现接收介质的随机性质以及无序效应能够在非结晶固体中引发新的定性自组织结构的形成。本文还分析了在非晶As-S(Se)半导体体系冷却过程中施加随机温度场对熔体的影响。确定了在波动的外部环境下,非晶体体系将其性质调整到环境的平均性质并与确定性情况相对应的条件。在此基础上,确定了该体系与随机环境发生非加性反应的条件,并在纳米级自组织结构中形成了一种新的能量转换模式。与对应于各自确定性条件的光谱相比,以这种方式创建的结构的光谱更加多样化。
{"title":"Self-organized structures induced by external white noise and nanosized levels of their formation in the non-crystalline As-S(Se) semiconductor systems","authors":"M. Mar’yan, N. Yurkovych, V. Šebeň","doi":"10.15407/spqeo25.04.402","DOIUrl":"https://doi.org/10.15407/spqeo25.04.402","url":null,"abstract":"Discussed in this paper are the singularity and self-organizing effect of instability and randomness under the influence of external white noise on formation of non-crystalline materials. The random nature of the receiving medium together with the disorganizing effect was found to be capable to initiate formation of qualitatively new self-organized structures in non-crystalline solids. Also analyzed in the paper is the effect of a random temperature field applied to the melt during the cooling process in non-crystalline As-S(Se) semiconductor systems. The conditions for a non-crystalline system in a fluctuating external environment to adjust its properties to the average properties of the environment and to correspond to the deterministic case were identified. Furthermore, the conditions for non-additive reaction of the system to a random environment and formation of a new mode of energy conversion in the self-organized structure at the nanoscale level are determined. The spectrum of the structures created in this way is more diverse as compared to the spectrum corresponding to respective deterministic conditions.","PeriodicalId":21598,"journal":{"name":"Semiconductor physics, quantum electronics and optoelectronics","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78777661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Impact of post-annealing temperature on optical and surface properties of tellurium doped ZnO nanocrystalline films 后退火温度对碲掺杂ZnO纳米晶薄膜光学和表面性能的影响
Pub Date : 2022-12-22 DOI: 10.15407/spqeo25.04.398
A.U. Sonawan, B. Sonawane
Investigated in this work is the effect of post-annealing temperature on ZnO nanocrystalline thin films doped with 5 at.% tellurium. The spin coating method was used to deposit films on the microscopic glass substrates. XRD, AFM, and UV-spectro-photometry were used to characterize the films structure, surface roughness and optical properties. The XRD spectra showed that the nanocrystalline films are of monocrystalline nature. AFM has confirmed the nanocrystalline character of tellurium-doped ZnO. The transmission of exposed films has been decreased with the increase of annealing temperature. The average transmission of all the films has been revealed to be higher than 80%. The optical band gap varies slightly with post-annealing temperature.
本文研究了退火后温度对掺杂5at的ZnO纳米晶薄膜的影响。%碲。采用自旋镀膜法在微细玻璃基板上沉积薄膜。采用XRD、AFM和uv光谱光度法对膜的结构、表面粗糙度和光学性能进行了表征。XRD谱分析表明,纳米晶膜为单晶性质。原子力显微镜证实了碲掺杂ZnO的纳米晶性质。随着退火温度的升高,曝光膜的透射率降低。所有影片的平均传输率都在80%以上。光学带隙随退火后温度变化不大。
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引用次数: 0
“Electronic nose”-type chemosensory systems for detection of gaseous poisonous substances 用于检测气态有毒物质的“电子鼻”型化学感觉系统
Pub Date : 2022-12-22 DOI: 10.15407/spqeo25.04.429
A. V. Mamykin, O. Kukla, A. S. Pavluchenko, Z. Kazantseva, I. Koshets, A. Pud, N. Ogurtsov, Yuriy Noskov, V. Kalchenko
The work is devoted to a study of the detection sensitivity and selectivity of a series of simulants of gaseous poisonous substances (PS). Two different sensor types were used, namely: 1) a quartz crystal microbalance (QCM), exhibiting a shift of the resonant frequency of quartz plates coated with calixarene thin layers, and 2) chemoresistive electrodes coated with layers of nanocomposites of intrinsically conducting polymers (ICP) changing their conductance under the influence of adsorbed gas molecules. The concentration of the analyzed volatile compounds varied within the range of 10 to 1000 ppm. The detection threshold ranged from 10 to 100 ppm depending on the analyzed substance for both transducer types. The response time was from 10 to 20 s for the QCM sensors and up to 1 minute for the ICP based sensors. The possibility of qualitative identification of poisonous substances in a wide concentration range by means of statistical analysis of the sensor array data is demonstrated.
研究了一系列气体有毒物质(PS)模拟物的检测灵敏度和选择性。使用了两种不同类型的传感器,即:1)石英晶体微天平(QCM),显示涂有杯芳烃薄层的石英板的谐振频率发生位移;2)涂有本质导电聚合物(ICP)纳米复合材料层的化学电阻电极在吸附气体分子的影响下改变其电导。所分析的挥发性化合物的浓度在10至1000 ppm的范围内变化。检测阈值范围从10到100 ppm取决于两种传感器类型的分析物质。QCM传感器的响应时间为10到20秒,基于ICP的传感器的响应时间为1分钟。通过对传感器阵列数据的统计分析,证明了在大浓度范围内定性鉴定有毒物质的可能性。
{"title":"“Electronic nose”-type chemosensory systems for detection of gaseous poisonous substances","authors":"A. V. Mamykin, O. Kukla, A. S. Pavluchenko, Z. Kazantseva, I. Koshets, A. Pud, N. Ogurtsov, Yuriy Noskov, V. Kalchenko","doi":"10.15407/spqeo25.04.429","DOIUrl":"https://doi.org/10.15407/spqeo25.04.429","url":null,"abstract":"The work is devoted to a study of the detection sensitivity and selectivity of a series of simulants of gaseous poisonous substances (PS). Two different sensor types were used, namely: 1) a quartz crystal microbalance (QCM), exhibiting a shift of the resonant frequency of quartz plates coated with calixarene thin layers, and 2) chemoresistive electrodes coated with layers of nanocomposites of intrinsically conducting polymers (ICP) changing their conductance under the influence of adsorbed gas molecules. The concentration of the analyzed volatile compounds varied within the range of 10 to 1000 ppm. The detection threshold ranged from 10 to 100 ppm depending on the analyzed substance for both transducer types. The response time was from 10 to 20 s for the QCM sensors and up to 1 minute for the ICP based sensors. The possibility of qualitative identification of poisonous substances in a wide concentration range by means of statistical analysis of the sensor array data is demonstrated.","PeriodicalId":21598,"journal":{"name":"Semiconductor physics, quantum electronics and optoelectronics","volume":"54 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85293381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Thermostimulated luminescence and photoluminescence of microcrystalline zinc sulphide ZnS:Cu 微晶硫化锌ZnS:Cu的热激发发光和光致发光
Pub Date : 2022-12-22 DOI: 10.15407/spqeo25.04.422
S. Kutovyy, О. Stanovyi
In the work, photoluminescence (PL) and thermoluminescence (TL) spectra of a zinc sulfide phosphor series, namely microcrystalline ZnS:Cu obtained by self-propagating high-temperature synthesis (SHS), were obtained and analyzed. Based on the spectral analysis, the character of the influence of annealing parameters on the intensity of the “blue” (B) and “green” (G) PL bands is established. The behaviors of the PL and TL bands are compared and the TL bands in the blue and green spectral regions are identified. The TL mechanism was assumed to be the specific nature of the centers that cause the B- and G-bands of PL.
本文对自传播高温合成(SHS)法制备的硫化锌荧光粉系列微晶ZnS:Cu的光致发光(PL)和热致发光(TL)光谱进行了分析。在光谱分析的基础上,建立了退火参数对“蓝”(B)和“绿”(G)光强的影响特征。比较了PL波段和TL波段的行为,确定了蓝、绿光谱区的TL波段。TL机制被认为是引起PL的B和g波段的中心的特定性质。
{"title":"Thermostimulated luminescence and photoluminescence of microcrystalline zinc sulphide ZnS:Cu","authors":"S. Kutovyy, О. Stanovyi","doi":"10.15407/spqeo25.04.422","DOIUrl":"https://doi.org/10.15407/spqeo25.04.422","url":null,"abstract":"In the work, photoluminescence (PL) and thermoluminescence (TL) spectra of a zinc sulfide phosphor series, namely microcrystalline ZnS:Cu obtained by self-propagating high-temperature synthesis (SHS), were obtained and analyzed. Based on the spectral analysis, the character of the influence of annealing parameters on the intensity of the “blue” (B) and “green” (G) PL bands is established. The behaviors of the PL and TL bands are compared and the TL bands in the blue and green spectral regions are identified. The TL mechanism was assumed to be the specific nature of the centers that cause the B- and G-bands of PL.","PeriodicalId":21598,"journal":{"name":"Semiconductor physics, quantum electronics and optoelectronics","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81039554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Semiconductor physics, quantum electronics and optoelectronics
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