In this study, it is aimed to produce and characterize antibacterial polyurethane (PU)/Zinc oxide (ZnO) nanofibers by electrospinning method. Firstly, polymer solutions were prepared at various ZnO concentrations such as 0, 0.2, 0.4, 0.6, 0.8, 1. Then solution properties (conductivity, viscosity, surface tension) were determined and analysed the effects of ZnO concentration on the solution properties. PU/ZnO nanofibers produced via electrospinning under the optimum process parameters (voltage, distance between electrodes, feed rate and atmospheric conditions). Finally, the nanofibers were characterized in terms of fibre morphology, thermal stability, permeability and antibacterial activity using SEM-EDS, DSC-TGA, water vapour permeability and disk diffusion methods. According to the solution results; it was observed that conductivity and surface tension decrease significantly with ZnO addition. On the other hand, solution viscosity increases as the ZnO concentration increases. From the SEM images, it has been seen clearly that average fibre diameter increases with ZnO concentration and incorporation of ZnO particles to the fibre structure was verified by SEM-EDS. According to the thermal analyse result, nanofibers begin to degrade between 271.94 ºC and 298.73 ºC. In addition, water vapour permeability increases as the ZnO concentration increase. Lastly antibacterial activity against gram negative (E.coli) and gram positive (S. aureus) was determined with specific zone diameter.
{"title":"ELECTROSPINNING OF ANTIBACTERIAL POLYURETHANE/ZnO\u0000NANOFIBERS","authors":"İ.Y. Mol, F. C. Çallıoğlu","doi":"10.35530/tt.2021.29","DOIUrl":"https://doi.org/10.35530/tt.2021.29","url":null,"abstract":"In this study, it is aimed to produce and characterize antibacterial polyurethane (PU)/Zinc oxide\u0000(ZnO) nanofibers by electrospinning method. Firstly, polymer solutions were prepared at various ZnO\u0000concentrations such as 0, 0.2, 0.4, 0.6, 0.8, 1. Then solution properties (conductivity, viscosity, surface\u0000tension) were determined and analysed the effects of ZnO concentration on the solution properties. PU/ZnO\u0000nanofibers produced via electrospinning under the optimum process parameters (voltage, distance between\u0000electrodes, feed rate and atmospheric conditions). Finally, the nanofibers were characterized in terms of\u0000fibre morphology, thermal stability, permeability and antibacterial activity using SEM-EDS, DSC-TGA,\u0000water vapour permeability and disk diffusion methods. According to the solution results; it was observed\u0000that conductivity and surface tension decrease significantly with ZnO addition. On the other hand, solution\u0000viscosity increases as the ZnO concentration increases. From the SEM images, it has been seen clearly that\u0000average fibre diameter increases with ZnO concentration and incorporation of ZnO particles to the fibre\u0000structure was verified by SEM-EDS. According to the thermal analyse result, nanofibers begin to degrade\u0000between 271.94 ºC and 298.73 ºC. In addition, water vapour permeability increases as the ZnO\u0000concentration increase. Lastly antibacterial activity against gram negative (E.coli) and gram positive (S.\u0000aureus) was determined with specific zone diameter.","PeriodicalId":22214,"journal":{"name":"TEXTEH Proceedings","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74773546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}