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Micro-galvanic corrosion behaviour of Mg−(7,9)Al−1Fe−xNd alloys 镁-(7,9)铝-1Fe-xNd 合金的微电镀腐蚀行为
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-01 DOI: 10.1016/S1003-6326(24)66579-9
Kai-xuan FENG , Tao LAI , Yang CHEN , Zheng YIN , Zhi-qin WU , Hong YAN , Hong-gun SONG , Chao LUO , Zhi HU
The localized micro-galvanic corrosion process and the kinetic information of Mg−(7,9)Al−1Fe−xNd alloys were investigated by in situ observation under electrochemical control and in situ atomic force microscopy (AFM) in an electrolyte environment. The results revealed that the formation of the Nd-rich phase in alloys resulted in a decrease in the Volta potential difference from ~400 mV (AlFe3/α-Mg) to ~220 mV (Nd-rich/α-Mg), reducing the corrosion products around the cathodic phase and corrosion current density of the microscale area. The addition of Nd significantly improved the corrosion resistance, mainly due to the suppression of the micro-galvanic corrosion between the second phases and substrate. Finally, the corrosion mechanism of Mg−(7,9)Al−1Fe−xNd alloys was discussed based on in situ observations and electrochemical results.
通过电化学控制下的原位观察和电解质环境中的原位原子力显微镜(AFM),研究了镁-(7,9)铝-1Fe-xNd 合金的局部微电化学腐蚀过程和动力学信息。结果表明,合金中富钕相的形成导致伏特电位差从 ~400 mV(AlFe3/α-Mg)降至 ~220 mV(富钕/α-Mg),从而减少了阴极相周围的腐蚀产物和微尺度区域的腐蚀电流密度。Nd 的加入大大提高了耐腐蚀性,主要原因是抑制了第二相与基体之间的微电蚀作用。最后,根据现场观察和电化学结果讨论了 Mg-(7,9)Al-1Fe-xNd 合金的腐蚀机理。
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引用次数: 0
Fabrication and anti-corrosion performance of superhydrophobic silane film on sintered NdFeB 烧结钕铁硼超疏水硅烷膜的制备与防腐蚀性能
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-01 DOI: 10.1016/S1003-6326(24)66586-6
Wen-tao JU , Li JIANG , Yan-xia LIANG , Shu-ting XU , Ke WANG , Yu-meng YANG , Ben-feng ZHU , Guo-ying WEI , Zhao ZHANG
An eco-friendly superhydrophobic protective film (DTMS/TEOS silane film) was fabricated on sintered NdFeB substrate through the utilization of electrochemically assisted deposition technology. The structure, properties, and film-forming mechanism of dodecyltrime-thoxysilane (DTMS)/tetraethoxysilane (TEOS) silane films were comprehensively analyzed using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS). Based on the test results, it can be determined that this film has a superhydrophobic property with a hydrophobicity angle of 152°. This special property can be attributed to the long alkyl chains in the DTMS molecule, the rough morphology, and the low surface energy of the DTMS/TEOS silane film. The surface of sintered NdFeB is coated with a layered three-dimensional network silane film that forms through the condensation of silanol substances. This film provides excellent corrosion resistance to the sintered NdFeB substrate, reducing its corrosion current density to 2.02×10−6 A/cm2. Moreover, the impact of film on the magnetic characteristics of sintered NdFeB was assessed and found to be minimal.
利用电化学辅助沉积技术,在烧结钕铁硼基底上制备了一种环保型超疏水保护膜(DTMS/TEOS 硅烷膜)。利用傅里叶变换红外光谱(FT-IR)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、电位极化曲线和电化学阻抗能谱(EIS)对十二烷基三肟基硅烷(DTMS)/四乙氧基硅烷(TEOS)硅烷薄膜的结构、性能和成膜机理进行了综合分析。根据测试结果,可以确定这种薄膜具有超疏水特性,疏水角为 152°。这种特殊性质可归因于 DTMS 分子中的长烷基链、粗糙的形态以及 DTMS/TEOS 硅烷薄膜的低表面能。烧结钕铁硼表面有一层通过硅醇物质缩合形成的层状三维网络硅烷膜。这层薄膜为烧结钕铁硼基底提供了出色的耐腐蚀性,使其腐蚀电流密度降低到 2.02×10-6 A/cm2。此外,还评估了薄膜对烧结钕铁硼磁特性的影响,结果发现这种影响微乎其微。
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引用次数: 0
Effect of sintering temperature and holding time on structure and properties of Li1.5Ga0.5Ti1.5(PO4)3 electrolyte with fast ionic conductivity 烧结温度和保温时间对具有快速离子导电性的 Li1.5Ga0.5Ti1.5(PO4)3 电解质的结构和性能的影响
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-01 DOI: 10.1016/S1003-6326(24)66588-X
Yin-yi LUO , Hao-zhang LIANG , Ping ZHANG , Lei HAN , Qian ZHANG , Li-dan LIU , Zhi-wei LUO , Tian-xiang NING , An-xian LU
Li1.5Ga0.5Ti1.5(PO4)3 (LGTP) is recognized as a promising solid electrolyte material for lithium ions. In this work, LGTP solid electrolyte materials were prepared under different process conditions to explore the effects of sintering temperature and holding time on relative density, phase composition, microstructure, bulk conductivity, and total conductivity. In the impedance test under frequency of 1−106 Hz, the bulk conductivity of the samples increased with increasing sintering temperature, and the total conductivity first increased and then decreased. SEM results showed that the average grain size in the ceramics was controlled by the sintering temperature, which increased from (0.54±0.01) μm to (1.21±0.01) μm when the temperature changed from 750 to 950 °C. The relative density of the ceramics increased and then decreased with increasing temperature as the porosity increased. The holding time had little effect on the grain size growth or sample density, but an extended holding time resulted in crack generation that served to reduce the conductivity of the solid electrolyte.
Li1.5Ga0.5Ti1.5(PO4)3(LGTP)被认为是一种很有前途的锂离子固态电解质材料。本研究在不同工艺条件下制备了 LGTP 固态电解质材料,探讨了烧结温度和保温时间对相对密度、相组成、微观结构、体积电导率和总电导率的影响。在频率为 1-106 Hz 的阻抗测试中,样品的体积电导率随烧结温度的升高而增大,总电导率先增大后减小。扫描电镜结果表明,陶瓷的平均晶粒尺寸受烧结温度的控制,当温度从 750 ℃ 变为 950 ℃ 时,平均晶粒尺寸从(0.54±0.01)μm 增加到(1.21±0.01)μm。随着孔隙率的增加,陶瓷的相对密度随温度升高而增加,然后降低。保温时间对晶粒尺寸增长或样品密度影响不大,但延长保温时间会导致裂纹产生,从而降低固体电解质的导电性。
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引用次数: 0
Interphase migration and enrichment of lead and zinc during copper slag depletion 铜渣贫化过程中铅和锌的相间迁移和富集
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-01 DOI: 10.1016/S1003-6326(24)66593-3
Jun HAO , Zhi-he DOU , Xing-yuan WAN , Ting-an ZHANG , Kun WANG
An interphase migration and enrichment model of lead and zinc during molten copper slag depletion was established. The occurrence of various components in copper slag was predicted using sulfur−oxygen potential calculations and confirmed through high-temperature experiments. The recovery rate of copper can reach 90.13% under the optimal conditions of 1200 °C, an iron to silicon mass ratio of 1.0, 3 wt.% ferrous sulfide, and a duration of 45 min. Lead (54.07 wt.%) and zinc (17.42 wt.%) are found in the flue dust as lead sulfate, lead sulfide, and zinc oxide, while copper matte contains lead (14.44 wt.%) and zinc sulfide (1.29 wt.%). The remaining lead and zinc are encapsulated as oxides within the fayalite phase.
建立了熔融铜渣贫化过程中铅和锌的相间迁移和富集模型。通过硫氧电位计算预测了铜渣中各种成分的出现,并通过高温实验进行了证实。在 1200 °C、铁硅质量比为 1.0、硫化亚铁重量百分比为 3、持续时间为 45 分钟的最佳条件下,铜的回收率可达 90.13%。铅(54.07 wt.%)和锌(17.42 wt.%)以硫酸铅、硫化铅和氧化锌的形式存在于烟尘中,而铜锍则含有铅(14.44 wt.%)和硫化锌(1.29 wt.%)。其余的铅和锌以氧化物的形式包裹在辉铜矿相中。
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引用次数: 0
Effect of combination of ultraviolet radiation and biocide on fungal-induced corrosion of high-strength 7075 aluminum alloy 紫外线辐射和杀菌剂组合对真菌诱导的高强度 7075 铝合金腐蚀的影响
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-01 DOI: 10.1016/S1003-6326(24)66576-3
Zheng-yu JIN , Chao WANG , Hai-xian LIU, Hong-wei LIU
The effect of ultraviolet (UV) radiation and biocide benzalkonium chloride (BKC) on fungal-induced corrosion of AA7075 induced by Aspergillus terreus (A. terreus) was deeply studied using analysis of biological activity, surface analysis, and electrochemical measurements. Results demonstrated that the planktonic and sessile spore concentrations decline by more than two orders of magnitude when UV radiation and BKC are combinedly used compared with the control. UV radiation can inhibit the biological activity of A. terreus and influence the stability of passive film of AA7075. Except for direct disinfection, the physical adsorption of BKC on the specimen can effectively inhibit the attachment of A. terreus. The combination of UV radiation and BKC can much more effectively inhibit the corrosion of AA, especially pitting corrosion, due to their synergistic effect. The combined application of UV radiation and BKC can be a good method to effectively inhibit fungal-induced corrosion.
采用生物活性分析、表面分析和电化学测量方法,深入研究了紫外线(UV)辐射和杀菌剂苯扎氯铵(BKC)对赤曲霉(A. terreus)诱导的 AA7075 真菌腐蚀的影响。结果表明,与对照组相比,紫外线辐射和 BKC 联合使用时,浮游孢子和无柄孢子的浓度下降了两个数量级以上。紫外线辐射可抑制赤霉菌的生物活性,并影响 AA7075 被动膜的稳定性。除直接消毒外,BKC 在试样上的物理吸附也能有效抑制赤霉菌的附着。由于紫外线辐射和 BKC 的协同作用,两者结合使用能更有效地抑制 AA 的腐蚀,尤其是点腐蚀。紫外线辐射和 BKC 的联合应用是一种有效抑制真菌引起的腐蚀的好方法。
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引用次数: 0
Influence of thermomechanical treatment on recrystallization and softening resistance of Cu−6.5Fe−0.3Mg alloy 热机械处理对 Cu-6.5Fe-0.3Mg 合金再结晶和抗软化性能的影响
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-01 DOI: 10.1016/S1003-6326(24)66584-2
Zhen-xia LIU , Da-wei YUAN , Xin LUO , Lan-hao WANG , Jin-shui CHEN , Hui-ming CHEN , Xiang-peng XIAO , Bin YANG
The recrystallization and softening resistance of a Cu−6.5Fe−0.3Mg (mass fraction, %) alloy prepared by Process 1 (cold rolling heat treatment) and Process 2 (hot/cold rolling heat treatment) were studied using Vickers hardness tests, tensile tests, scanning electron microscopy and transmission electron microscopy. The softening temperature, hardness and tensile strength of the alloy prepared by Process 2 were 110 °C, HV 15 and 114 MPa higher, respectively, than those of the alloy prepared by Process 1 after aging at 300 °C. The recrystallization activation energy of the alloys prepared by Process 1 and Process 2 were 72.83 and 98.11 kJ/mol, respectively. The pinning effects of the precipitates of the two alloys on grain boundaries and dislocations were basically the same. The softening mechanism was mainly attributed to the loss of dislocation strengthening. The higher Fe fiber density inhibited the average free migration path of dislocations and grain boundary migration in the alloy, which was the main reason for higher softening temperature of the alloy prepared by Process 2.
使用维氏硬度试验、拉伸试验、扫描电子显微镜和透射电子显微镜研究了通过工艺 1(冷轧热处理)和工艺 2(热/冷轧热处理)制备的铜-6.5Fe-0.3Mg(质量分数,%)合金的再结晶和抗软化性能。通过工艺 2 制备的合金在 300 °C 老化后的软化温度、硬度和拉伸强度分别比工艺 1 制备的合金高 110 °C、HV 15 和 114 MPa。工艺 1 和工艺 2 制备的合金的再结晶活化能分别为 72.83 和 98.11 kJ/mol。两种合金的析出物对晶界和位错的钉扎效应基本相同。软化机制主要归因于位错强化的丧失。较高的铁纤维密度抑制了合金中位错的平均自由迁移路径和晶界迁移,这是工艺 2 制备的合金软化温度较高的主要原因。
{"title":"Influence of thermomechanical treatment on recrystallization and softening resistance of Cu−6.5Fe−0.3Mg alloy","authors":"Zhen-xia LIU ,&nbsp;Da-wei YUAN ,&nbsp;Xin LUO ,&nbsp;Lan-hao WANG ,&nbsp;Jin-shui CHEN ,&nbsp;Hui-ming CHEN ,&nbsp;Xiang-peng XIAO ,&nbsp;Bin YANG","doi":"10.1016/S1003-6326(24)66584-2","DOIUrl":"10.1016/S1003-6326(24)66584-2","url":null,"abstract":"<div><div>The recrystallization and softening resistance of a Cu−6.5Fe−0.3Mg (mass fraction, %) alloy prepared by Process 1 (cold rolling heat treatment) and Process 2 (hot/cold rolling heat treatment) were studied using Vickers hardness tests, tensile tests, scanning electron microscopy and transmission electron microscopy. The softening temperature, hardness and tensile strength of the alloy prepared by Process 2 were 110 °C, HV 15 and 114 MPa higher, respectively, than those of the alloy prepared by Process 1 after aging at 300 °C. The recrystallization activation energy of the alloys prepared by Process 1 and Process 2 were 72.83 and 98.11 kJ/mol, respectively. The pinning effects of the precipitates of the two alloys on grain boundaries and dislocations were basically the same. The softening mechanism was mainly attributed to the loss of dislocation strengthening. The higher Fe fiber density inhibited the average free migration path of dislocations and grain boundary migration in the alloy, which was the main reason for higher softening temperature of the alloy prepared by Process 2.</div></div>","PeriodicalId":23191,"journal":{"name":"Transactions of Nonferrous Metals Society of China","volume":"34 9","pages":"Pages 2900-2917"},"PeriodicalIF":4.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142531401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of brazing temperature on microstructure and tensile strength of γ-TiAl joint vacuum brazed with micro-nano Ti−Cu−Ni−Nb−Al−Hf filler 钎焊温度对使用微纳 Ti-Cu-Ni-Nb-Al-Hf 填料真空钎焊的 γ-TiAl 接头微观结构和拉伸强度的影响
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-01 DOI: 10.1016/S1003-6326(24)66560-X
Li LI , Yu-tong CHEN , Lei-xin YUAN , Fen LUO , Zhi-xue FENG , Xiao-qiang LI

A novel micro-nano Ti−10Cu−10Ni−8Al−8Nb−4Zr−1.5Hf filler was used to vacuum braze Ti−47Al− 2Nb−2Cr−0.15B alloy at 1160−1220 °C for 30 min. The interfacial microstructure and formation mechanism of TiAl joints and the relationships among brazing temperature, interfacial microstructure and joint strength were emphatically investigated. Results show that the TiAl joints brazed at 1160 and 1180 °C possess three interfacial layers and mainly consist of α2-Ti3Al, τ3-Al3NiTi2 and Ti2Ni, but the brazing seams are no longer layered and Ti2Ni is completely replaced by the uniformly distributed τ3-Al3NiTi2 at 1200 and 1220 °C due to the destruction of α2-Ti3Al barrier layer. This transformation at 1200 °C obviously improves the tensile strength of the joint and obtains a maximum of 343 MPa. Notably, the outward diffusion of Al atoms from the dissolution of TiAl substrate dominates the microstructure evolution and tensile strength of the TiAl joint at different brazing temperatures.

使用一种新型微纳米 Ti-10Cu-10Ni-8Al-8Nb-4Zr-1.5Hf 填料在 1160-1220 ℃ 下对 Ti-47Al- 2Nb-2Cr-0.15B 合金进行真空钎焊 30 分钟。重点研究了 TiAl 接头的界面微观结构和形成机理,以及钎焊温度、界面微观结构和接头强度之间的关系。结果表明,在 1160 和 1180 ℃ 下钎焊的 TiAl 接头具有三个界面层,主要由 α2-Ti3Al 、 τ3-Al3NiTi2 和 Ti2Ni 组成,但在 1200 和 1220 ℃ 时,由于 α2-Ti3Al 阻挡层的破坏,钎缝不再分层,Ti2Ni 被均匀分布的 τ3-Al3NiTi2 完全取代。1200 °C时的这种转变明显提高了接头的抗拉强度,最大可达343兆帕。值得注意的是,在不同钎焊温度下,TiAl 基体溶解产生的 Al 原子向外扩散主导了 TiAl 接头的微观结构演变和抗拉强度。
{"title":"Effect of brazing temperature on microstructure and tensile strength of γ-TiAl joint vacuum brazed with micro-nano Ti−Cu−Ni−Nb−Al−Hf filler","authors":"Li LI ,&nbsp;Yu-tong CHEN ,&nbsp;Lei-xin YUAN ,&nbsp;Fen LUO ,&nbsp;Zhi-xue FENG ,&nbsp;Xiao-qiang LI","doi":"10.1016/S1003-6326(24)66560-X","DOIUrl":"10.1016/S1003-6326(24)66560-X","url":null,"abstract":"<div><p>A novel micro-nano Ti−10Cu−10Ni−8Al−8Nb−4Zr−1.5Hf filler was used to vacuum braze Ti−47Al− 2Nb−2Cr−0.15B alloy at 1160−1220 °C for 30 min. The interfacial microstructure and formation mechanism of TiAl joints and the relationships among brazing temperature, interfacial microstructure and joint strength were emphatically investigated. Results show that the TiAl joints brazed at 1160 and 1180 °C possess three interfacial layers and mainly consist of <em>α</em><sub>2</sub>-Ti<sub>3</sub>Al, <em>τ</em><sub>3</sub>-Al<sub>3</sub>NiTi<sub>2</sub> and Ti<sub>2</sub>Ni, but the brazing seams are no longer layered and Ti<sub>2</sub>Ni is completely replaced by the uniformly distributed <em>τ</em><sub>3</sub>-Al<sub>3</sub>NiTi<sub>2</sub> at 1200 and 1220 °C due to the destruction of <em>α</em><sub>2</sub>-Ti<sub>3</sub>Al barrier layer. This transformation at 1200 °C obviously improves the tensile strength of the joint and obtains a maximum of 343 MPa. Notably, the outward diffusion of Al atoms from the dissolution of TiAl substrate dominates the microstructure evolution and tensile strength of the TiAl joint at different brazing temperatures.</p></div>","PeriodicalId":23191,"journal":{"name":"Transactions of Nonferrous Metals Society of China","volume":"34 8","pages":"Pages 2563-2574"},"PeriodicalIF":4.7,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S100363262466560X/pdf?md5=72a0ee726f1c6d250937105439b85faf&pid=1-s2.0-S100363262466560X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142239439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy 间断时效对 7A75 铝合金机械性能和耐腐蚀性的影响
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-01 DOI: 10.1016/S1003-6326(24)66550-7
Xian-wen YANG , Ling-ying YE , Yong ZHANG , Quan-shi CHENG

The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses, including electrical conductivity, mechanical properties, local corrosion properties, and slow strain rate tensile stress corrosion tests. Microstructure characterization techniques such as metallographic microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were also employed. The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging, and it even exceeds 700 MPa. Furthermore, the yield strength increases by 52.7 MPa, reaching 654.8 MPa after T6I6 aging treatment. The maximum depths of intergranular corrosion (IGC) and exfoliation corrosion (EXCO) decrease from 116.3 and 468.5 µm to 89.5 and 324.3 µm, respectively. The stress corrosion factor also decreases from 2.1% to 1.6%. These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance. Similarly, when the alloy is treated with T6I4, T6I6 and T6I7 aging, the sizes of grain boundary precipitates (GBPs) are found to be 5.2, 18.4, and 32.8 nm, respectively. The sizes of matrix precipitates are 4.8, 5.7 and 15.7 nm, respectively. The atomic fractions of Zn in GBPs are 9.92 at.%, 8.23 at.% and 6.87 at.%, respectively, while the atomic fractions of Mg are 12.66 at.%, 8.43 at.% and 7.00 at.%, respectively. Additionally, the atomic fractions of Cu are 1.83 at.%, 2.47 at.% and 3.41 at.%, respectively.

通过各种分析,包括电导率、机械性能、局部腐蚀性能和慢应变速率拉伸应力腐蚀试验,研究了间断时效对 7A75 铝合金挤压棒机械性能和耐腐蚀性能的影响。此外,还采用了金相显微镜、扫描电子显微镜(SEM)和透射电子显微镜(TEM)等微观结构表征技术。结果表明,T6I6 时效产生的合金抗拉强度与 T6I4 时效产生的合金抗拉强度相似,甚至超过了 700 兆帕。此外,经过 T6I6 时效处理后,屈服强度增加了 52.7 兆帕,达到 654.8 兆帕。晶间腐蚀(IGC)和剥落腐蚀(EXCO)的最大深度分别从 116.3 微米和 468.5 微米降至 89.5 微米和 324.3 微米。应力腐蚀因子也从 2.1% 降至 1.6%。这些研究结果表明,经过 T6I6 时效处理的合金具有高强度和优异的抗应力腐蚀开裂性能。同样,当合金经过 T6I4、T6I6 和 T6I7 时效处理时,发现晶界析出物(GBPs)的尺寸分别为 5.2、18.4 和 32.8 nm。基体析出物的尺寸分别为 4.8、5.7 和 15.7 nm。GBP 中锌的原子分数分别为 9.92%、8.23% 和 6.87%,而镁的原子分数分别为 12.66%、8.43% 和 7.00%。此外,铜的原子分数分别为 1.83%、2.47% 和 3.41%。
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引用次数: 0
Modeling and characterization on electroplastic effect during dynamic deformation of 5182-O aluminum alloy 5182-O 铝合金动态变形过程中的电塑性效应建模与表征
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-01 DOI: 10.1016/S1003-6326(24)66553-2
Hong-chun SHANG, Song-chen WANG, Yan-shan LOU

The coupling effects of electrical pulse, temperature, strain rate, and strain on the flow behavior and plasticity of 5182-O aluminum alloy were investigated and characterized. The isothermal tensile test and electrically-assisted isothermal tensile test were performed at the same temperature, and three typical models were further embedded in ABAQUS/Explicit for numerical simulation to illustrate the electroplastic effect. The results show that electric pulse reduces the deformation resistance but enhances the elongation greatly. The calibration accuracy of the proposed modified Lim−Huh model for highly nonlinear and coupled dynamic hardening behavior is not much improved compared to the modified Kocks−Mecking model. Moreover, the artificial neural network model is very suitable to describe the macromechenical response of materials under the coupling effect of different variables.

研究并表征了电脉冲、温度、应变率和应变对 5182-O 铝合金流动行为和塑性的耦合效应。在相同温度下进行了等温拉伸试验和电辅助等温拉伸试验,并进一步将三个典型模型嵌入 ABAQUS/Explicit 中进行数值模拟,以说明电塑性效应。结果表明,电脉冲降低了变形阻力,但大大提高了伸长率。与修正的 Kocks-Mecking 模型相比,针对高度非线性和耦合动态硬化行为提出的修正 Lim-Huh 模型的校准精度提高不多。此外,人工神经网络模型非常适合描述不同变量耦合效应下材料的宏观力学响应。
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引用次数: 0
Cross-section distortion and springback characteristics of double-cavity aluminum profile in force controlled stretch-bending 力控拉伸弯曲双腔铝型材的截面变形和回弹特性
IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-01 DOI: 10.1016/S1003-6326(24)66554-4
Zhi-wen LIU , Zi-xuan DONG , Cong-chang XU , Jie YI , Luo-xing LI

A 3D elastic-plastic FE model for simulating the force controlled stretch-bending process of double-cavity aluminum profile was established using hybrid explicit−implicit solvent method. Considering the computational accuracy and efficiency, the optimal choices of numerical parameters and algorithms in FE modelling were determined. The formation mechanisms of cross-section distortion and springback were revealed. The effects of pre-stretching, post-stretching, friction, and the addition of internal fillers on forming quality were investigated. The results show that the stress state of profile in stretch-bending is uniaxial with only a circumferential stress. The stress distribution along the length direction of profile is non-uniform and the maximum tensile stress is located at a certain distance away from the center of profile. As aluminum profile is gradually attached to bending die, the distribution characteristic of cross-section distortion along the length direction of profile changes from V-shape to W-shape. After unloading the forming tools, cross-section distortion decreases obviously due to the stress relaxation, with a maximum distortion difference of 13% before and after unloading. As pre-stretching and post-stretching forces increase, cross-section distortion increases gradually, while springback first decreases and then remains unchanged. With increasing friction between bending die and profile, cross-section distortion slightly decreases, while springback increases. Cross-section distortion decreases by 83% with adding PVC fillers into the cavities of profile, while springback increases by 192.2%.

采用显式-隐式混合溶剂法,建立了模拟双腔铝型材受力控制拉伸弯曲过程的三维弹塑性有限元模型。考虑到计算精度和效率,确定了 FE 建模中数值参数和算法的最佳选择。揭示了截面变形和回弹的形成机理。研究了预拉伸、后拉伸、摩擦和添加内部填料对成形质量的影响。结果表明,拉伸弯曲时型材的应力状态是单轴的,只有圆周应力。沿型材长度方向的应力分布不均匀,最大拉伸应力位于距离型材中心一定距离的位置。当铝型材逐渐贴到弯曲模具上时,型材截面变形沿长度方向的分布特征由 V 型变为 W 型。成型模具卸载后,由于应力松弛,横截面变形明显减小,卸载前后的最大变形差为 13%。随着预拉伸力和后拉伸力的增加,横截面变形逐渐增大,而回弹先减小后保持不变。随着弯曲模具和型材之间摩擦力的增加,横截面变形略有减小,而回弹增加。在型材空腔中加入聚氯乙烯填料后,横截面变形减少了 83%,而回弹增加了 192.2%。
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引用次数: 0
期刊
Transactions of Nonferrous Metals Society of China
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