Amorphous carbon, as an excellent solid lubricant film, is employed to protect moving mechanical components in manufacturing industry, but its excellent lubricity is often lost due to ‘environmental effect’ phenomenon. Understanding the molecular gas species states across sliding interface is a foundation to bring anti-environmental sensitivity into amorphous carbon for excellent lubricity in gas environment. Nevertheless, interfacial molecular gas species state understanding is impeded by the irreproducibility of sliding interface in post-testing analyses and theoretical simulation. An effective approach, a fractional coverage model combined with Eyring model was proposed in this study to understand ‘environmental effect’ related to sliding speed on the frictional behaviors of hydrogenated amorphous carbon (a-C:H) film. The model unveiled ‘environment-velocity coupling effect’ on frictional performances of a-C:H film under O2 environment. C
O-terminated interfaces exhibited higher electrostatic repulsion than O-C
O-terminated interfaces. Based on the above-mentioned electrostatic repulsion characteristics, the oxygen adsorption led to the formation of C
O bonds and reduced interfacial friction, but further oxygen adsorption resulted in the formation of O-C
O bonds and increased interfacial friction. Sliding speed affected potential barriers from motional oxygen molecules on the sliding interface, and this performance was somewhat like the characteristics of the Eyring reaction kinetics detailing shear force as a function of sliding velocity. Friction coefficient of full-covered hydrogenated film was linear in the natural logarithm value of sliding speed.
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