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Lubrication and Antibacterial Performance and Mechanism of Functionalized Ionic Liquids in Glycerol Media with Different Water Contents 功能化离子液体在不同含水量甘油介质中的润滑和抗菌性能及机理
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-09 DOI: 10.1016/j.triboint.2024.110307
Xiaoli Li , Yu Liu , Siyu Liu , Chufeng Sun , Jia Li , Yuchen Sun , Chaoyang Zhang , Shuang Sun , Qiangliang Yu , Bo Yu , Meirong Cai , Feng Zhou , Weimin Liu
Glycerol lubricants face limitations in industrial applications due to their inadequate antimicrobial properties. In this study, a functionalized long-chain quaternary ammonium salt ionic liquid, BTA-16-BTA, was synthesized. The antimicrobial and tribological properties of BTA-16-BTA as a lubricant additive in glycerol media with different water contents were investigated. The results show that the antimicrobial performance of the glycerol medium is positively correlated with the amount of BTA-16-BTA added. At the optimal concentration of 1.5% BTA-16-BTA dispersion, excellent friction-reducing, anti-wear, and extreme pressure properties were observed. The friction-reducing and anti-wear effects were further enhanced when 1% water was added to the system. The liquid medium containing BTA-16-BTA can inhibit the growth of Escherichia coli, indicating that BTA-16-BTA possesses antimicrobial properties.
甘油润滑剂由于抗菌性能不足而在工业应用中受到限制。本研究合成了一种功能化长链季铵盐离子液体 BTA-16-BTA。研究了 BTA-16-BTA 作为润滑油添加剂在不同含水量的甘油介质中的抗菌和摩擦学特性。结果表明,甘油介质的抗菌性能与 BTA-16-BTA 的添加量呈正相关。在最佳浓度为 1.5% 的 BTA-16-BTA 分散体中,观察到了极佳的减摩、抗磨和极压性能。当系统中加入 1%的水时,减摩和抗磨效果进一步增强。含有 BTA-16-BTA 的液体介质可以抑制大肠杆菌的生长,这表明 BTA-16-BTA 具有抗菌特性。
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引用次数: 0
Analysis of Grease Mechanical Degradation in Standard Equipment 标准设备中的润滑脂机械降解分析
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-09 DOI: 10.1016/j.triboint.2024.110308
Alan Gurt, Michael Khonsari
As a grease is used in a bearing, its rheological properties may change substantially due to prolonged shear, causing it to no longer meet its application requirements. The change to grease structural integrity may be succinctly quantified by measuring the change in consistency, corresponding to shear/mechanical stability. There are only two standardized methods for measuring the mechanical stability of greases: prolonged working in a grease worker and subjecting to roller degradation in a roll stability test.
This paper provides a detailed analysis of the shear environment of these two tests and uses recently identified measurement techniques to track the degradation of two different greases over time in each test. Results are then compared to shearing in a rheometer at shear rates that are estimated to be similar. It is shown that the shearing environments within the grease worker and roll stability test can be predicted and reproduced with reasonable accuracy in a rheometer. Various time scales of mechanical stability are identified, with the standard two-hour duration of the roll stability test found to exist within a transient time scale that may not accurately reflect the long-term mechanical stability of a grease. This study demonstrates that both tools can be used to reasonably estimate the changes to mechanical properties of a grease during the churning phase of a bearing or milling process during manufacturing, though it is recommended that the duration of the standard roll stability test be extended beyond the identified transient period.
在轴承中使用润滑脂时,由于长时间的剪切,其流变特性可能会发生重大变化,导致其不再符合应用要求。润滑脂结构完整性的变化可以通过测量稠度的变化(与剪切/机械稳定性相对应)来简单量化。测量润滑脂机械稳定性的标准化方法只有两种:在润滑脂工人中长期工作和在轧辊稳定性测试中进行轧辊降解。本文详细分析了这两种测试的剪切环境,并使用最近确定的测量技术来跟踪两种不同润滑脂在每种测试中随时间推移的降解情况。然后将结果与在流变仪中剪切的结果进行比较,估计剪切速率相似。结果表明,润滑脂工人和辊子稳定性测试中的剪切环境可以在流变仪中进行预测和再现,准确度相当高。研究确定了机械稳定性的各种时间尺度,发现轧辊稳定性测试的标准两小时持续时间属于瞬时时间尺度,可能无法准确反映润滑脂的长期机械稳定性。这项研究表明,这两种工具都可用于合理估计轴承搅动阶段或制造过程中铣削过程中润滑脂机械性能的变化,但建议将标准轧辊稳定性测试的持续时间延长到已确定的瞬态时间段之后。
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引用次数: 0
Mechanical properties of CoCrFeNi-X (X = Ti,Sn) high entropy alloy and tribological properties in simulated seawater environment CoCrFeNi-X (X = Ti,Sn) 高熵合金在模拟海水环境中的机械性能和摩擦学性能
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-09 DOI: 10.1016/j.triboint.2024.110306
Xinghua Zhang , Zisi Jiang , Hao Chen , Muye Niu , Jun Cheng
Five multimajor element CoCrFeNi-X(X = Ti,Sn) high entropy alloys (HEA) were prepared by vacuum hot press sintering. The phase composition, mechanical properties and tribological properties of CoCrFeNi-X(X = Ti,Sn) alloys in simulated seawater were investigated. The phase structure of CoCrFeNiTi high-entropy alloy is solid solution FCC phase, R phase, σ phase, and Laves phase. But after addition Sn elements, the phase structure become the FCC phase and Ni-Sn solid solution phase. CoCrFeNiTi alloy has lower density (7.17 g/cm3) and higher hardness (750 HV) than that of CoCrFeNiSn. The compressive yield strength of CoCrFeNiTi HEA is better than CoCrFeNiSn HEA. The CoCrFeNiSn high-entropy alloys showed lower wear rates. The main reason is that SnO2 is generated on the wear scar surface, which has good wetting and corrosion inhibition effects, so CoCrFeNiSn HEA shows better wear resistance in simulated seawater. The main wear mechanism of the CoCrFeNiSn HEA is abrasive wear, oxidative wear, exfoliation wear and corrosive wear.
通过真空热压烧结法制备了五种多主量元素 CoCrFeNi-X(X = Ti,Sn)高熵合金(HEA)。研究了模拟海水中 CoCrFeNi-X(X = Ti,Sn) 合金的相组成、力学性能和摩擦学性能。CoCrFeNiTi 高熵合金的相结构为固溶体 FCC 相、R 相、σ 相和 Laves 相。但加入锡元素后,相结构变为 FCC 相和 Ni-Sn 固溶相。与 CoCrFeNiSn 相比,CoCrFeNiTi 合金的密度(7.17 g/cm3)更低,硬度(750 HV)更高。CoCrFeNiTi HEA 的抗压屈服强度优于 CoCrFeNiSn HEA。CoCrFeNiSn 高熵合金的磨损率较低。主要原因是磨损痕表面生成了 SnO2,具有良好的润湿和缓蚀效果,因此 CoCrFeNiSn HEA 在模拟海水中表现出更好的耐磨性。CoCrFeNiSn HEA 的主要磨损机理是磨料磨损、氧化磨损、剥离磨损和腐蚀磨损。
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引用次数: 0
Preparation and friction wear performance of ZrO2/MoS2 PEO composite coating ZrO2/MoS2 PEO 复合涂层的制备与摩擦磨损性能
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-09 DOI: 10.1016/j.triboint.2024.110312
Jiayu He, Faqin Xie, Xiangqing Wu, Lang Li, Rui Luo, Hanming Yang, Shaoqing Wang
PEO composite coatings doped with ZrO2 and MoS2 particles were prepared on the surface of TC21 alloy using the PEO process. The morphologies and phase compositions of the coatings were analyzed using FE-SEM, TEM, XRD refinement and XPS. The tribological and self-lubricating properties of the coatings were investigated through fretting wear experiments. The results indicate co-doping reduced the friction coefficient by approximately 30 %. The co-doped coating demonstrated higher crystallinity, whereas the ZrO2 coating contained a significant amount of amorphous material. The wear mechanisms of the coating included three-body abrasive, adhesive, and oxidative wear. The self-lubricating properties of the coating were derived from the presence of MoS₂ and the destruction and deformation of the coating surface during fretting wear.
采用 PEO 工艺在 TC21 合金表面制备了掺杂 ZrO2 和 MoS2 颗粒的 PEO 复合涂层。使用 FE-SEM、TEM、XRD 细化和 XPS 分析了涂层的形貌和相组成。通过摩擦磨损实验研究了涂层的摩擦学和自润滑性能。结果表明,共掺杂使摩擦系数降低了约 30%。共掺杂涂层的结晶度更高,而 ZrO2 涂层则含有大量无定形物质。涂层的磨损机制包括三体磨损、粘着磨损和氧化磨损。涂层的自润滑特性来自于 MoS₂的存在以及摩擦磨损过程中涂层表面的破坏和变形。
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引用次数: 0
Tribological application of oleylamine incorporated flexible metal-organic frameworks MIL-88A based self-lubricating composite 基于 MIL-88A 自润滑复合材料的油胺掺杂柔性金属有机框架的摩擦学应用
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-09 DOI: 10.1016/j.triboint.2024.110313
Xiao Yang , Feilong Huang , Yunbo Wang , Weihua Cao , Jinghan Zheng , Xiaowen Qi
To expand the application of MOFs in self-lubricating composites, we synthesized metal organic frameworks (MOFs) MIL-88A tailored for oleylamine (Ole) adsorption, resulting in the Ole@MIL-88A composite with oleylamine adsorbed. This material was incorporated into epoxy resin (EP) to form EP/Ole@MIL-88A composites. The composites were firstly applied to axle sleeves for tribological evaluations. The tests revealed that the EP/10 wt% Ole@MIL-88A composite had the lowest COF (0.137), with a 65.9 % decrease compared to pure EP. The EP/8 wt% Ole@MIL-88A displayed the lowest wear depth, with a 68.4 % reduction compared to pure EP. This research signifies the initial application of MOF-based self-lubricating composites to mechanical components and engineering evaluations, laying the groundwork for their design in future industrial settings.
为了扩大 MOFs 在自润滑复合材料中的应用,我们合成了专门用于吸附油胺(Ole)的金属有机框架(MOFs)MIL-88A,得到了吸附油胺的 Ole@MIL-88A 复合材料。将这种材料与环氧树脂(EP)结合,形成 EP/Ole@MIL-88A 复合材料。首先将这些复合材料应用于车轴套筒进行摩擦学评估。测试表明,与纯 EP 相比,EP/10 wt% Ole@MIL-88A 复合材料的 COF(0.137)最低,下降了 65.9%。EP/8 wt% Ole@MIL-88A 的磨损深度最低,与纯 EP 相比降低了 68.4%。这项研究标志着基于 MOF 的自润滑复合材料在机械部件和工程评估中的初步应用,为其在未来工业环境中的设计奠定了基础。
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引用次数: 0
Tribological properties of a smart Ti3C2Tx-based epoxy coating: Providing an idea to solve the weak tribological properties of traditional smart coatings 基于 Ti3C2Tx 的智能环氧涂层的摩擦学性能:为解决传统智能涂层摩擦学性能薄弱的问题提供思路
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-05 DOI: 10.1016/j.triboint.2024.110302
Han Yan, Leifeng Shi, Dezhi Zeng, Lin Zhang
Friction damage is always a major threat to the wide application of smart anticorrosion coatings. Here, the tribological properties of a smart Ti3C2Tx-based epoxy coating (MLT@EP) is adjusted by the reasonable collocation of mesoporous silica nanocapsules loading onto Ti3C2Tx-based plane (MLT). MLT@EP not only maintains good smart anticorrosion, but also has remarkable anti-friction and anti-wear properties. Its friction coefficient exhibits a low and steady trend, and the wear rate arrived at 1.14 × 10−5 mm3/N·m, which is decreased by 58.3 ∼ 93.3 % compared to control groups. The excellent tribological properties are mainly attributed to the synergistic effect of MXene-based lubrication film, high resistance to plastic deformation, and strong internal interaction.
摩擦损伤一直是智能防腐涂料广泛应用的主要威胁。本文通过在Ti3C2Tx基平面(MLT)上合理搭配介孔二氧化硅纳米胶囊,调整了Ti3C2Tx基智能环氧涂层(MLT@EP)的摩擦学性能。MLT@EP 不仅具有良好的智能防腐性能,还具有显著的抗摩擦和抗磨损性能。其摩擦系数呈低而稳定的趋势,磨损率为 1.14 × 10-5 mm3/N-m,与对照组相比降低了 58.3 ∼ 93.3 %。优异的摩擦学性能主要归功于基于 MXene 的润滑膜的协同效应、高抗塑性变形能力和强内部相互作用。
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引用次数: 0
Analysis of tribological behavior of Laser Powder Bed Fusion (LPBF) CuCrZr alloy through reciprocating loading on the columnar structure 通过柱状结构上的往复加载分析激光粉末床熔化 (LPBF) CuCrZr 合金的摩擦学行为
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-05 DOI: 10.1016/j.triboint.2024.110301
G. Prabu , Che-Hua Yang , Ibrahim A. Alnaser , N. Jeyaprakash
The objective of this research is to assess the degree of wear on the pin across different pitch distances. The Laser Powder Bed Fusion (LPBF) process was utilized to manufacture the CuCrZr alloy, and the microstructural examination revealed both columnar and equiaxed structures in the specimen. A study was conducted on the nanowear occurring in the columnar structure at pitch values of 3 µm (deformed-region), 10 µm (plastic-region), and 20 µm (undeformed-region), while applying a force of 1000µN. The wear depths at these pitch values were 2700 nm, 2300 nm, and 2150 nm, respectively. The ploughing wear mechanism occurred consistently across all three pitch values. The wear rates at the 3 µm, 10 µm, and 20 µm pitch were found to be 1.103 × 10-4, 0.920 × 10-4, and 0.85 × 10-4 mm3N-1m-1, respectively.
这项研究的目的是评估销钉在不同间距下的磨损程度。利用激光粉末床熔化(LPBF)工艺制造了 CuCrZr 合金,微观结构检查发现试样中既有柱状结构,也有等轴结构。在施加 1000µN 的力时,对柱状结构在间距值为 3 µm(变形区)、10 µm(塑性区)和 20 µm(未变形区)时发生的纳米磨损进行了研究。这些间距值的磨损深度分别为 2700 nm、2300 nm 和 2150 nm。犁状磨损机制在所有三个间距值上都一致。3 微米、10 微米和 20 微米间距的磨损率分别为 1.103 × 10-4、0.920 × 10-4 和 0.85 × 10-4 mm3N-1m-1。
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引用次数: 0
Physics-based numerical implementation framework towards multi-scale contact problem 基于物理的多尺度接触问题数值实现框架
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-05 DOI: 10.1016/j.triboint.2024.110297
Tao Yang, Xiongfeng Tang, Zhixue Yan, Guoqing Wang, Gai Zhao, Hanmin Peng
This paper establishes a general computational framework to solve the muti-scale contact problem by integrating the statistical contact model with the finite element format. Compared to existing models, the proposed method is applicable to most geometric configurations and can effectively evaluate the pressure distribution. In this work, a modified Karush-Kuhn-Tucker (KKT) condition is proposed by the assumption that asperity height obeys the Gaussian distribution. Therefore, in the variational formula, the contact contribution is decomposed into body contribution and asperity contribution, corresponding to the nominal smooth surface and roughness, respectively. Then the linearization and constraint enforcement of these two components are derived, followed by a nonlinear Newton-Raphson-based iterative algorithm. The contact patch test and Hertz contact test are conducted, and the predicted results are consistent with the theoretical and experimental values, confirming the effectiveness and accuracy of the proposed approach. It is worth noting that in the Hertz contact test, the contact pressure distribution varies progressively with the roughness level and external force, tending to the Hertz limit or Gaussian limit. This means that the proposed method can be applied to any roughness and load. Finally, the contact behaviors of the transmission interface of a piezoelectric actuator, i.e., a typical multi-scale contact problem, are studied as an engineering application case.
本文通过将统计接触模型与有限元格式相结合,建立了解决多尺度接触问题的通用计算框架。与现有模型相比,本文提出的方法适用于大多数几何构型,并能有效评估压力分布。在这项工作中,提出了一种改进的 Karush-Kuhn-Tucker (KKT) 条件,即假定表面高度服从高斯分布。因此,在变分公式中,接触贡献被分解为本体贡献和非球面贡献,分别对应于标称光滑表面和粗糙度。然后推导出这两个部分的线性化和约束执行,接着是基于牛顿-拉弗森的非线性迭代算法。通过接触贴片测试和赫兹接触测试,预测结果与理论值和实验值一致,证实了所提方法的有效性和准确性。值得注意的是,在赫兹接触试验中,接触压力分布随粗糙度和外力的变化而逐渐变化,趋向于赫兹极限或高斯极限。这意味着所提出的方法可适用于任何粗糙度和载荷。最后,作为工程应用案例,研究了压电致动器传动界面的接触行为,即典型的多尺度接触问题。
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引用次数: 0
Effect of external magnetic field on the fretting wear mechanism of the ferromagnetic materials 外磁场对铁磁材料摩擦磨损机理的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-05 DOI: 10.1016/j.triboint.2024.110305
Jingfen Lu , Jifan He , Guozheng Kang , Bin Lan , Jianhua Liu , Minhao Zhu
With the widespread implementation of maglev technology in fields such as rail transit and military, it is imperative to investigate the effects of magnetic fields on fretting damage in metallic materials. This study conducted multi-parameter fretting wear tests on typical ferromagnetic counterparts in the presence of an external permanent magnetic field. Subsequently, the wear behavior and damage mechanism of the fretting interface were elucidated through multi-scale characterization analysis. The results indicated that the operation state of the fretting interface was shifted towards the partial slip regime under the magnetic field. Meanwhile, the external magnetic field transformed the dominant wear mechanism from abrasive wear to adhesive wear. The influence of the external magnetic field on fretting wear has been demonstrated to manifest in dual aspects: Firstly, the Hertzian contact stress at the interface is enhanced by the magnetic field induction force, resulting in a remarkable reduction of about 79.83 % in accumulated dissipation energy; Secondly, the effectiveness of debris being expelled from the worn interface decreased, and the wear progression was further impeded by the accumulated debris, so that the abrasion loss is significantly reduced by about 60.66 %. These findings provide valuable theoretical data and practical reference for the protection of fretting damage in ferromagnetic materials under the action of a magnetic field.
随着磁悬浮技术在轨道交通和军事等领域的广泛应用,研究磁场对金属材料摩擦磨损的影响势在必行。本研究对外部永久磁场存在下的典型铁磁材料进行了多参数烧蚀磨损测试。随后,通过多尺度表征分析,阐明了烧蚀界面的磨损行为和损伤机理。结果表明,在磁场作用下,摩擦界面的运行状态向部分滑移机制转变。同时,外磁场将主导磨损机制从磨料磨损转变为粘着磨损。外磁场对摩擦磨损的影响表现在两个方面:首先,界面上的赫兹接触应力在磁场感应力的作用下得到增强,从而使累积耗散能量显著降低了约 79.83%;其次,从磨损界面排出碎屑的效率降低,磨损进程进一步受到累积碎屑的阻碍,从而使磨损损耗显著降低了约 60.66%。这些研究结果为保护铁磁材料在磁场作用下的烧蚀损伤提供了宝贵的理论数据和实践参考。
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引用次数: 0
Novel vegetable biolubricants containing ionic liquid 含有离子液体的新型植物生物润滑剂
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-05 DOI: 10.1016/j.triboint.2024.110255
María-Dolores Avilés, Tomás Caparros, Paloma Mostaza, María-Dolores Bermúdez, Francisco J. Carrión-Vilches
Novel biolubricants based on vegetable avocado oils modified by the ionic liquid diethylmethylammonium methanesulfonate (IL), were investigated. Neat (Av) and epoxidized avocado (EAv) oils with 1 wt% IL were studied in a metal-ceramic tribopair under pin-on-disc configuration. The best tribological performance was found for the EAv+ 1 %IL oil, with higher viscosity, and friction coefficient and wear rate up to 74.5 % and 98.8 % lower than that of neat lubricants. The presence of IL and epoxidized oil tribofilm inside the wear tracks was confirmed using X-ray photoelectronic spectroscopy. These results highlight the potential use of ionic liquids as efficient additives in biolubricant oils.
研究了基于经离子液体二乙基甲基铵甲烷磺酸盐(IL)改性的植物鳄梨油的新型生物润滑剂。在针盘配置下的金属陶瓷摩擦对中研究了含有 1 wt% IL 的纯鳄梨油 (Av) 和环氧化鳄梨油 (EAv)。EAv+ 1 %IL 油的摩擦学性能最佳,粘度更高,摩擦系数和磨损率分别比纯润滑油低 74.5 % 和 98.8 %。使用 X 射线光电子能谱确认了磨损轨迹内存在 IL 和环氧化油三膜。这些结果凸显了离子液体作为生物润滑油高效添加剂的潜在用途。
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引用次数: 0
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Tribology International
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