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Removal Behavior of Pb2+, Cd2+, Zn2+ from wastewater of lead, zinc mining – Cho Don, Bac Kan by halloysite clay 高岭土对曹敦北坎铅锌矿废水中Pb2+、Cd2+、Zn2+的去除行为
Pub Date : 2023-07-11 DOI: 10.51316/jca.2023.036
D. T. Le, Luc The Trinh, Bac Hoang Bui, Dung Tien Cong, Thao Phuong Thi Le
Halloysite from Thach Khoan, Phu Tho province showed nanotube structure with a chemical formula Al2Si2O5(OH)4.2H2O when fully hydrated and Al2Si2O5(OH)4 when dehydrated, specific surface areas are 15.7434 and 22.0211 m2/g. Halloysite was used to study on adsorption behaviour of Pb2+, Cd2+, Zn2+ (M2+) ions. The effect of factors on the M2+ adsorption efficiency was investigated. The adsorption efficiency of Pb2+, Cd2+, Zn2+ obtained 90.75; 73.75 and 67.09 % respectively under the suitable condition: halloysite mass of 0.7 g/50 mL solution, initial concentration of 40 mg/L M2+, pH for Pb2+, Cd2+, Zn2+ = 5.31; 6.2; 5.6 espectively, contact time of 80 minutes (for Pb2+, Cd2+) and 100 minutes (for Zn2+) at room temperature (30 oC). Adsorption isotherm curves were studied based on Langmuir and Freundlich models. The kinetic of the adsorption process was investigated following the first-order-pseudo and second-order-pseudo models. Removal efficiency of Pb2+, Cd2+ and Zn2+ from the wastewater of lead, zinc mining – Cho Don, Bac Kan was 99,59 %; 92,08 % và 99,46 %, respectively.
富苴省Thach Khoan的高岭土在完全水合和脱水时分别表现出化学式为Al2Si2O5(OH)4.2H2O和Al2Si2O5(OH)4的纳米管结构,比表面积分别为15.7434和22.0211 m2/g。采用高岭土对Pb2+、Cd2+、Zn2+ (M2+)离子的吸附行为进行了研究。考察了各因素对M2+吸附效率的影响。对Pb2+、Cd2+、Zn2+的吸附效率为90.75;适宜条件为:高岭土质量为0.7 g/50 mL, M2+初始浓度为40 mg/L, pH为Pb2+、Cd2+、Zn2+ = 5.31;6.2;在室温(30℃)下,接触时间分别为Pb2+、Cd2+ 80分钟和Zn2+ 100分钟。基于Langmuir和Freundlich模型研究了吸附等温线。采用一级伪模型和二级伪模型研究了吸附过程的动力学。曹敦北坎铅锌矿废水中Pb2+、Cd2+、Zn2+的去除率分别为99.59%;分别为92,08%和99,46%。
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引用次数: 0
Construction of NdFeO3 nanoparticles on reduced graphene oxide for an enhanced visible light assisted-Fenton degradation of organic pollutant in oily wastewater 在还原氧化石墨烯上构建NdFeO3纳米颗粒以增强可见光辅助fenton降解含油废水中的有机污染物
Pub Date : 2023-07-10 DOI: 10.51316/jca.2023.029
N. Phan, N. Chu
In this study, reduced graphene oxide (rGO) incorporated on NdFeO3  (NFO/rGO) nanocomposite was successfully synthesized by using a facile hydrothermal method for photo-Fenton degradation of phenol in oily wastewater. The structural, elemental, morphological, optical property, and photo-Fenton performance of NFO/rGO nanocomposite were evaluated. From the characterizations, the prepared NFO/rGO nanocomposite showed a heterostructure between reduced graphene oxide (rGO) and NdFeO3. In addition, the prepared NFO/rGO photocatalyst has efficient charge separation compared to that of pure NFO. The photo-Fenton catalytic activity of the NFO/rGO photocatalyst was investigated by phenol degradation under visible light irradiation, with a maximum removal efficiency of 94.3 % after 90 min. In contrast to pure NFO, the introduction of rGO could suggestively enhance the photo-Fenton catalytic activity by increasing the specific surface area and narrow band gap energy. The possible reaction mechanism was also discussed.
在本研究中,采用水热法成功合成了NdFeO3 (NFO/rGO)纳米复合材料上的还原性氧化石墨烯(rGO),用于光- fenton降解含油废水中的苯酚。评价了NFO/rGO纳米复合材料的结构、元素、形态、光学性能和光fenton性能。从表征来看,所制备的NFO/rGO纳米复合材料呈现出介于还原氧化石墨烯(rGO)和NdFeO3之间的异质结构。此外,与纯NFO相比,制备的NFO/rGO光催化剂具有高效的电荷分离。通过可见光下苯酚降解研究了NFO/rGO光催化剂的光- fenton催化活性,90 min后最大去除率为94.3%。与纯NFO相比,rGO的引入可以通过增加比表面积和窄带隙能来增强光- fenton催化活性。并对可能的反应机理进行了讨论。
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引用次数: 0
Study on the application of biochar made from agricultural by-products to treat arsenic pollution in water 农副产物生物炭处理水中砷污染的应用研究
Pub Date : 2023-07-10 DOI: 10.51316/jca.2023.026
Hien Chu, N. Tran, D. Dang, Viet Minh Nguyen, Hieu Cong Nguyen, Thao Truong, Binh Thi Lai
Now, water pollution is one of the leading concerns in the world especially heavy metal polltion. In recent years, researches on the use of agricultural waste as biochar and modified biochar to treat heavy metals in water are receiving the attention of scientists because of the economy as well as the high processing efficiency that it brings. In this study, biochar from rice husk was synthesized and modified by iron, then the obtained materials were characterized by SEM, FTIR methods. The results show that the Fe-biochar shows a high potential to remove arsenic at pH = 4 and the adsorption capacity was 18,96 – 28,49 mg/g.
现在,水污染是世界上最受关注的问题之一,尤其是重金属污染。近年来,利用农业废弃物作为生物炭和改性生物炭处理水中重金属的研究因其经济性和较高的处理效率而受到科学家们的关注。本研究以稻壳为原料合成了生物炭,并对其进行了铁改性,并用SEM、FTIR等方法对其进行了表征。结果表明,在pH = 4的条件下,铁生物炭对砷的吸附量分别为18、96 ~ 28、49 mg/g。
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引用次数: 0
Highly effective graphene membrane for transformer oil purification 用于变压器油净化的高效石墨烯膜
Pub Date : 2023-07-10 DOI: 10.51316/jca.2023.028
T. T. Vu, Chi Thi Linh Nguyen, T. V. Pham
A highly effective adsorbent comprised of the Graphene membrane was created using the sonification method in this study. For all we know, the resulting Graphene membrane was employed as an adsorbent for transformer oil purification for the first time. The quality of the treated oil was evaluated through several factors, such as acid number TAN(mg KOH/g), color, breakdown voltage, and viscosity.  The results indicated that the Graphene membrane exceeded the other commercial adsorbents in terms of purifying capacity. Several reasons, including the unreduced oxygen functional groups, vacancy defects on the surface of the Graphene flake, the high specific surface area, and the proper pore size of the Graphene membrane for oil refining, might explain this exceptional outcome. Furthermore, the 3D structure of the Graphene membrane can extend the residence purification time of the transformer oil, assisting in the improvement of the purification capability of the Graphene membrane.
本研究采用超声法制备了一种由石墨烯膜组成的高效吸附剂。据我们所知,所得到的石墨烯膜首次被用作变压器油净化的吸附剂。通过酸值TAN(mg KOH/g)、颜色、击穿电压和粘度等因素评价处理后油的质量。结果表明,石墨烯膜的净化能力优于其他工业吸附剂。有几个原因,包括未还原的氧官能团、石墨烯薄片表面的空位缺陷、高比表面积以及用于炼油的石墨烯膜的适当孔径,可能解释了这种特殊的结果。此外,石墨烯膜的三维结构可以延长变压器油的停留净化时间,有助于提高石墨烯膜的净化能力。
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引用次数: 0
Sol-gel synthesis and characterization of neodymium orthoferrite for disposing oily wastewater 处理含油废水用正铁氧体钕的溶胶-凝胶合成及表征
Pub Date : 2023-07-10 DOI: 10.51316/jca.2023.027
N. Phan, N. Chu
The aim of this study was to design and characterize a NdFeO3-based photocatalyst prepared by sol-gel method for treatment of oily wastewater. Different characterization techniques such as X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), UV–vis spectrophometer were used to elucidate the structure, morphology, surface functional groups, and optical absorption properties of the prepared NdFeO3 photocatalyst. The photo-Fenton degradation performance of the as-prepared NdFeO3 photocatalyst was investigated by degrading oily-containing wastewater under visible light irradiation. The NdFeO3 photocatalyst manifests the high chemical oxygen demand (COD) removal efficiency of 97.6 % for 120 min reaction) thanks to its narrow band gap energy and high crystalline degree.
本研究的目的是设计并表征溶胶-凝胶法制备的用于含油废水处理的ndfeo3基光催化剂。采用x射线衍射(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)、紫外-可见分光光度计等表征技术对制备的NdFeO3光催化剂的结构、形貌、表面官能团和光学吸收性能进行了表征。通过可见光照射下对含油废水的降解,考察了制备的NdFeO3光催化剂的光- fenton降解性能。NdFeO3光催化剂具有窄带隙能和高结晶度,在120 min的反应时间内COD去除率达到97.6%。
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引用次数: 0
Hydrothermal Synthesis and Catalytic Activity of a Nanosized Fe2V4O13 Material in Heterogeneous Fenton-like Reaction for Degradation of Organic Compounds 纳米级 Fe2V4O13 材料的水热合成及其在异相 Fenton 类反应中降解有机化合物的催化活性
Pub Date : 2023-07-09 DOI: 10.51316/jca.2023.024
Vân-Anh Nguyen, Manh Dang-Vu Nguyen, Canh Ba Bui, Lien Hong Nguyen, Nga To Thi Phan, Ha Hong Cao
In this research, the nanosized Fe2V4O13 complex oxide material was synthesized by the hydrothermal method. Its structure, morphology characterization, and other properties were determined using X-ray, SEM, EDX, and DTA-TG methods. The catalytic activity of the material was evaluated in terms of the decolorization and the degradation of the Indigo carmine dye. The optimal condition for the degradation and the reusability of the catalyst were determined. The results showed that the heterogeneous Fenton-like catalyst is a promise for wastewater treatment.
本研究采用水热法合成了纳米级 Fe2V4O13 复合氧化物材料。采用 X 射线、SEM、EDX 和 DTA-TG 方法测定了该材料的结构、形貌特征和其他性质。通过对靛蓝胭脂红染料的脱色和降解,评估了该材料的催化活性。确定了降解的最佳条件和催化剂的可重复使用性。结果表明,这种类似芬顿的异相催化剂有望用于废水处理。
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引用次数: 0
Investigation of the Cam leaf extraction process oriented to synthesize silver nanoparticles (Ag NPs) 面向合成银纳米粒子(Ag NPs)的Cam叶片提取工艺研究
Pub Date : 2023-05-31 DOI: 10.51316/jca.2023.014
Cuong Manh Le, Chung Cong Le, Thai Thanh Tran, Lan Anh Thi Luu
In the present work, the extract process of Cam leaves powder (Peristrophe bivalvis(L.) Merr) was investigated. The results exhibited optimal parameters of the extract process. Green synthesis of silver nanoparticles was demonstrated using the freshly prepared aqueous extract of the Cam leaves powder as a reducing and stabilizing agent. The silver nanoparticles were characterized by analytical techniques such as UV-Vis, FTIR, Raman, XRD, and EDX. Characterization techniques confirmed that the silver nanoparticles were synthesized
本研究主要对锦葵叶粉的提取工艺进行了研究。Merr)被调查。结果表明,提取工艺参数最优。用新鲜制备的茶叶粉末水提取物作为还原剂和稳定剂,证明了纳米银的绿色合成。采用UV-Vis、FTIR、Raman、XRD、EDX等分析技术对纳米银进行了表征。表征技术证实了银纳米颗粒的合成
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引用次数: 0
Research and fabrication of high purity α-Al2O3 from Tan Rai aluminum hydroxide 谭雷氢氧化铝制备高纯α-Al2O3的研究
Pub Date : 2023-05-31 DOI: 10.51316/jca.2023.013
Vo Van Mai, Anh Van Thi Bui, Toan Ta, Phuong Thi Tuyet Nguyen
This paper deals the effects of some factors on the fabrication process of high purity α-Al2O3 from Tan Rai Al(OH)3. The obtained results of surface morphology (SEM), crystal structure (XRD), composition (EDX) of the original Al(OH)3 and Al2O3 show that Al(OH)3 washed with CH3COOH 2N is best at 80oC, efficient Dissolution reached the highest when using 25% HCl, Al2O3 calcined at 1400oC for 2 hours. The obtained Al2O3 has the structure α-Al2O3, the highpurity.
研究了几种因素对Tan Rai Al(OH)3制备高纯α-Al2O3工艺的影响。对原Al(OH)3和Al2O3的表面形貌(SEM)、晶体结构(XRD)和组成(EDX)进行了分析,结果表明:用CH3COOH 2N水洗Al(OH)3在80℃时效果最好,用25%的HCl、Al2O3在1400oC下煅烧2 h时有效溶解达到最高。所得Al2O3具有α-Al2O3结构,纯度高。
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引用次数: 0
Effect of pH and active radical on the photodegradation of Ciprofloxacin antibiotic in wastewater using novel catalyst based on rGO/halloysite composite decorating with copper iron oxide pH和活性自由基对氧化石墨烯/高岭土复合铜铁修饰光降解废水中环丙沙星抗生素的影响
Pub Date : 2023-05-31 DOI: 10.51316/jca.2023.015
Ngo Ha-Son, L. Nguyen
A new generation photocatalyst CuFe2O4/rGO/halloysite nanotube (HNT) was manufactured using a simple procedure in this work. Material characterisation results reveal that the CuFe2O4 active phase with a size of around 30-40 nm is spread rather consistently across the sandwich-like structure of rGO/HNT. The material's bandgap energy is around 1.9 eV, which boosts the material's capacity to function even in the visible light area. The catalytic activity test showed that the catalyst, with an active phase composition of 70% by weight, was able to completely decomposing CIP after just 1 hour of light. The pHpzc value and pH impact were also investigated. The findings suggest that the material can completely handle CIP in a neutral environment (pH = 7). Scavenger tests also demonstrated the involvement of reactive radicals in CIP degradation, with holes (h+) and hydroxyl radicals (●OH) having the major effect. These important results constitute the basis for the in-depth investigations of the CIP degradation mechanism.
采用简单的工艺制备了新一代CuFe2O4/rGO/高岭土纳米管(HNT)光催化剂。材料表征结果表明,尺寸约为30-40 nm的CuFe2O4活性相均匀地分布在rGO/HNT的三明治状结构上。该材料的带隙能量约为1.9 eV,即使在可见光区域也能提高材料的功能。催化活性测试表明,该催化剂的活性相组成为70%(重量比),光照1小时即可完全分解CIP。研究了pHpzc值和pH值对pH值的影响。研究结果表明,该材料可以在中性环境(pH = 7)下完全处理CIP。清道夫试验还表明,活性自由基参与了CIP的降解,其中孔洞(h+)和羟基自由基(●OH)起主要作用。这些重要结果为深入研究CIP降解机理奠定了基础。
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引用次数: 0
Simulation of working process of oxygen concentrator equipment by pressure swing adsorption 变压吸附法对制氧设备工作过程的模拟
Pub Date : 2023-05-31 DOI: 10.51316/jca.2023.019
T. D. Vu, Duong Van Le, Minh Duc Mai, Hung Duy Vu
Oxygen is essential for human respiration and the existence of all living organisms. Medically it is used to treat diseases related to impaired respiratory function. In industrial scale, gaseous oxygen is separated from the air by liquefaction and fractional distillation techniques, while on a small and medium scale oxygen is usually separated by using zeolite molecular sieves and pressure swing adsorption (PSA) technology. During the Covid-19 pandemic, the demand for oxygen concentrators (PSA type) for personal and family use is very high. However, there isn’t any Vietnamese factory for production oxygen concentrator, so it is imported from abroad. In this paper, a pilot-scale oxygen concentrator was built at the Department of chemical process equipment, Hanoi University of Science and Technology. The operation of the device has been simulated and optimized on Aspen Adsorption software. The optimization parameters obtained will be used to design the equipment in industrial scale.
氧气是人类呼吸和所有生物存在所必需的。医学上用于治疗与呼吸功能受损有关的疾病。在工业规模上,气态氧通过液化和分馏技术从空气中分离出来,而在中小型规模上,通常使用沸石分子筛和变压吸附(PSA)技术分离氧气。在2019冠状病毒病大流行期间,对个人和家庭使用的氧气浓缩器(PSA型)的需求非常高。但是,越南没有生产制氧机的工厂,所以从国外进口。本文在河内科技大学化工过程装备系建立了一个中试制氧机。在Aspen吸附软件上对装置的运行进行了模拟和优化。得到的优化参数将用于工业规模的设备设计。
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引用次数: 0
期刊
Vietnam Journal of Catalysis and Adsorption
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