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Effects of translation misalignment on ion optics with slit apertures 平移错位对带有狭缝孔径的离子光学的影响
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1016/j.vacuum.2024.113793
Zhi Yang , Honghui Guo , Hongtao Liu , Jinwei Bai , Yong Cao
For ion thrusters, the deflection of the ion beam caused by the relative translation of the grids is one of the primary factors limiting the erosion lifetime of the ion optical system. A two-dimensional (2D) simulation package of the ion optic system is developed to investigate the ion sputtering corrosion due to grid translation misalignment. For benchmark cases, the 2D simulation package shows a reasonable consistency compared to the experimental method in ion beam deflection angle and drain-to-beam current ratio, indicating the effectiveness of the simulation package. The deviation between the simulated deflection angle and the experimental value is within 8.86%. Furthermore, this 2D package is employed to analyze the variation patterns of ion beam, ion collection, and the distribution of ion sputtering rates caused by grid translation. The simulation results indicate that the ion beam deflection occurs in the direction opposite to grid translation. The number of ions collected at different positions on the acceleration grid shows different tendencies. Only the upstream surface Sy− and the aperture surface Sx+ will be subjected to energetic ion impingement. The sputtering of energetic ions on these two surfaces becomes the dominant factor limiting the grid’s ion corrosion lifetime when the grid translation is significant. The sputtering rate of energetic ions can exceed that of charge exchange (CEX) ions by more than 10 times. The proportion of the region where energetic ions contribute to sputtering expands with increasing grid misalignment, reaching up to 52.5% on surface Sx+. Additionally, the downstream surface Sy+ and the aperture surface Sx− are only subjected to CEX ion sputtering regardless of grid translation. Moreover, the CEX ion sputtering regions on surfaces Sx− and Sx+ expand as the grid misalignment distance increases. The peak in the ion sputtering rate distribution profile on surface Sy+ becomes more prominent due to grid translation, with the sputtering rate at the peak position reaching approximately 1.65 times that of the surrounding lower-rate regions. The analysis of the electric field indicates that local electric field variations caused by grid misalignment are the underlying reason for the ion erosion characteristics.
对于离子推进器来说,栅格的相对平移导致的离子束偏转是限制离子光学系统侵蚀寿命的主要因素之一。我们开发了离子光学系统的二维(2D)模拟软件包,以研究栅格平移错位引起的离子溅射腐蚀。在基准案例中,二维模拟软件包与实验方法相比,在离子束偏转角和漏极与离子束电流比方面显示出合理的一致性,表明了模拟软件包的有效性。模拟偏转角与实验值的偏差在 8.86% 以内。此外,该二维软件包还用于分析网格平移引起的离子束、离子收集和离子溅射率分布的变化规律。模拟结果表明,离子束偏转的方向与网格平移的方向相反。加速栅上不同位置收集的离子数量呈现不同的趋势。只有上游表面 Sy- 和孔径表面 Sx+ 会受到高能离子的撞击。当加速栅平移较大时,这两个表面上的高能离子溅射成为限制加速栅离子腐蚀寿命的主要因素。高能离子的溅射率可超过电荷交换(CEX)离子的溅射率 10 倍以上。高能离子溅射区域的比例随着栅格偏移的增加而扩大,在 Sx+ 表面高达 52.5%。此外,下游表面 Sy+ 和孔径表面 Sx- 只受到 CEX 离子的溅射,与网格平移无关。此外,表面 Sx- 和 Sx+ 上的 CEX 离子溅射区域随着网格错位距离的增加而扩大。由于网格平移,表面 Sy+ 上的离子溅射率分布曲线峰值变得更加突出,峰值位置的溅射率约为周围低速率区域的 1.65 倍。电场分析表明,栅格错位引起的局部电场变化是离子侵蚀特性的根本原因。
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引用次数: 0
Microstructure evolution behavior and SERS properties of self-grown Ag/Ag-Nb nano-island films sputtered on flexible substrates 在柔性基底上溅射自生长的银/银-铌纳米岛薄膜的微结构演化行为和 SERS 特性
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-03 DOI: 10.1016/j.vacuum.2024.113802
Haitao Zheng , Mingshuai Shen , Zunyan Xie , Ziyi Li , Mengran Zhang , Haoliang Sun
Ag-Nb alloy films with varying Nb content were deposited on flexible polyimide substrates by the magnetron sputtering metho. The results show that dense and monodisperse Ag nano-islands were self-grown on the surfaces of as-deposited Ag-31.1 at% Nb alloy films. FDTD simulations revealed that the local electric field strength is closely related to the covering Ag layer, size and spacing of self-grown nano-islands. A 166-nm Ag-31.1 % Nb alloy film covered with 15-nm Ag layer served as the SERS substrate presented excellent and stable SERS performance and can detect 5 × 10−14 mol/L R6G solution. The preparation method of Ag nano-island/alloy films offers a novel approach for producing reproducible and highly sensitive SERS substrates.
利用磁控溅射法在柔性聚酰亚胺基底上沉积了不同铌含量的铌镁合金薄膜。结果表明,在沉积的 Ag-31.1 at% Nb 合金薄膜表面自生长出致密、单分散的 Ag 纳米层。FDTD 模拟显示,局部电场强度与覆盖的银层、自生长纳米岛的尺寸和间距密切相关。166纳米的Ag-31.1% Nb合金薄膜上覆盖着15纳米的Ag层,作为SERS基底,该薄膜具有优异稳定的SERS性能,可检测5×10-14 mol/L R6G溶液。纳米银岛/合金薄膜的制备方法为生产可重现的高灵敏度 SERS 基底提供了一种新方法。
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引用次数: 0
Novel Carbon@BaMoZrFe12O19 photocatalytic peroxymonosulfate activation for ibuprofen removal 用于去除布洛芬的新型碳@BaMoZrFe12O19 光催化过硫酸盐活化技术
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-03 DOI: 10.1016/j.vacuum.2024.113801
Abeer A. AlObaid , Jin Yang , Sajid Mahmood , Ghulam Abbas Ashraf , Noor Hassan , Raqiqa Tur Rasool , Muhammad Adnan , Zeeshan Ajmal , Amna Mir
This study reports a successful synthesis of a novel Carbon@BaMoZrFe12O19 Mhexaferrite photocatalyst (NPs) using the coprecipitation method. Afterthat, the NPs were used as an activator for peroxymonosulfate (PMS) to remove ibuprofen (IBU) from water. NPs were subjected for a thorough characterization process utilizing various analytical techniques including XRD, FTIR, UV, PL TEM, SEM/EDS, and X-ray photoelectron spectroscopy (XPS). Significantly, the utilization of NPs for PMS activation demonstrated a notable improvement in the elimination of IBU under visible light. The research conducted a thorough investigation into the effects of various parameters, such as activating systems, initial pH, inorganic salts, IBU contents, and water matrix on the efficiency of IBU degradation. The significance of reactive oxygen species, such as sulfate and hydroxyl radicals, as well as singlet oxygen, in the removal of IBU, was clarified by chemical quenching tests. In addition, NPs exhibited competent magnetic separation and reprocessing capacities. The magnetic NPs revealed excellent constancy and recyclability, by sustaining degrading productivity after five consecutive cycles. Therefore, the present study offers a significant contributions to the understanding of photocatalytic degradation for organic pollutants through the utilization of magnetic photocatalysts.
本研究报告采用共沉淀法成功合成了一种新型碳@BaMoZrFe12O19六价铁氧体光催化剂(NPs)。随后,该 NPs 被用作过一硫酸盐 (PMS) 的活化剂,用于去除水中的布洛芬 (IBU)。利用各种分析技术,包括 XRD、FTIR、UV、PL TEM、SEM/EDS 和 X 射线光电子能谱 (XPS),对 NPs 进行了全面的表征。值得注意的是,在可见光下,利用 NPs 活化 PMS 对消除 IBU 有明显改善。研究深入探讨了活化体系、初始 pH 值、无机盐、IBU 含量和水基质等各种参数对 IBU 降解效率的影响。通过化学淬灭试验,明确了活性氧(如硫酸根自由基、羟基自由基以及单线态氧)在去除 IBU 过程中的重要作用。此外,NPs 还表现出良好的磁分离和再处理能力。磁性 NPs 在连续五个周期后仍能保持降解生产力,显示出卓越的恒定性和可回收性。因此,本研究为了解利用磁性光催化剂光催化降解有机污染物做出了重要贡献。
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引用次数: 0
Ni and Sb improve the microstructure, mechanical properties, and solder joint reliability of Sn-3.0Ag-0.5Cu alloy 镍和锑可改善 Sn-3.0Ag-0.5Cu 合金的微观结构、机械性能和焊点可靠性
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-02 DOI: 10.1016/j.vacuum.2024.113782
Biao Wang , Jikang Yan , Jiangshan Liu , Jianhua Zhao , Lingyan Zhao
In this study, SAC305-0.1Ni and SAC305-0.1Ni-xSb (x = 1.5 wt %, 2.0 wt %, 2.5 wt %) composite solders were fabricated by incorporating Ni and Sb alloying elements into Sn3.0Ag0.5Cu (SAC305) solder. A comprehensive investigation was carried by utilizing X-ray diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), microhardness tests, nanoindentation, transmission electron microscopy (TEM), and a universal mechanical testing machine. The effects of Ni and Sb additions on microstructures, thermal properties, wettability, mechanical characteristics, as well as thermal aging, interfacial growth, and mechanical properties of welded joints were systematically explored, and these results were compared with SAC305 solder. The results indicated that the incorporation of Sb and Ni enhanced the microstructure of the solder alloy through the formation of (Cu, Ni)6Sn5 and SnSb phases, leading to a 23.90 % increase in the solder wetted area. Additionally, the formation of (Cu, Ni)6Sn5 and SnSb intermetallic compounds (IMC) increased resistance to dislocation motion, thereby enhancing the mechanical properties of the solder alloys in comparison to SAC305 solder. The creep resistance of the solder alloys was significantly improved, with a corresponding 49.19 % increase in Vickers hardness. During the thermal aging of solder joints, the interfacial growth coefficient decreased, with the SAC305-0.1Ni-2.0Sb joints exhibiting the lowest value at 0.0185. Furthermore, the co-addition of Ni and Sb consistently enhanced the mechanical properties of the welded joints. The average tensile strength of SAC305-0.1Ni-2.0Sb joints reached 77.87 MPa, which represents a 28.45 % increase compared to SAC305 joints. As the Sb content increased, the fracture mode transitioned from brittle fracture to ductile fracture, and eventually to a mixed ductile-brittle fracture.
本研究通过在锡3.0银0.5铜(SAC305)焊料中加入镍和锑合金元素,制备了SAC305-0.1镍和SAC305-0.1镍-xSb(x = 1.5 wt %、2.0 wt %、2.5 wt %)复合焊料。利用 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、差示扫描量热 (DSC)、显微硬度测试、纳米压痕、透射电子显微镜 (TEM) 和通用机械试验机进行了全面研究。系统地探讨了添加镍和锑对焊接接头的微观结构、热性能、润湿性、机械特性以及热老化、界面生长和机械性能的影响,并将这些结果与 SAC305 焊料进行了比较。结果表明,通过形成(Cu, Ni)6Sn5 和 SnSb 相,Sb 和 Ni 的加入增强了焊料合金的微观结构,使焊料润湿面积增加了 23.90%。此外,(Cu, Ni)6Sn5 和 SnSb 金属间化合物 (IMC) 的形成增加了对位错运动的阻力,因此与 SAC305 焊料相比,提高了焊料合金的机械性能。焊料合金的抗蠕变性显著提高,维氏硬度也相应提高了 49.19%。在焊点的热老化过程中,界面生长系数下降,SAC305-0.1Ni-2.0Sb 焊点的界面生长系数最低,为 0.0185。此外,镍和锑的共同添加持续增强了焊点的机械性能。SAC305-0.1Ni-2.0Sb 接头的平均抗拉强度达到 77.87 兆帕,与 SAC305 接头相比提高了 28.45%。随着锑含量的增加,断裂模式从脆性断裂过渡到韧性断裂,并最终过渡到韧性-脆性混合断裂。
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引用次数: 0
In situ formation SiC nanowires on loofah sponge-derived porous carbon for efficient electromagnetic wave absorption 在丝瓜海绵多孔碳上原位形成碳化硅纳米线,实现高效电磁波吸收
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-02 DOI: 10.1016/j.vacuum.2024.113769
Xiaolin Guo , Haiyu Li , Zhaoyang Zhang , Pengfei Xing , Shuai Wang , Shengnan Jiang , Yanxin Zhuang
A lightweight, heterogeneous, three-dimensional network-structured composite has been meticulously developed with the specific goal of optimizing impedance matching and elevating electromagnetic wave absorption properties. SiC nanowires-carbon composites were synthesized through a novel process involving combined carbothermal reduction and chemical vapor deposition, utilizing loofah sponge as the foundational material. Accessible and cost-effective organosilane waste was applied as the silicon source. The resulting composites manifest exceptional electromagnetic wave absorption performance with a minimum reflection loss of −46.34 dB and a wide effective bandwidth of 3.84 GHz at a thin thickness of 1.9 mm. Superior electromagnetic wave absorption is attributed to synergistic interplay of multiple interfacial polarizations, dipole polarization, conductive losses, and multiple reflections and scattering. This work presents an innovative pathway toward fabricating highly efficient electromagnetic wave-absorbing materials while effectively repurposing recycled waste.
为了优化阻抗匹配和提高电磁波吸收特性,我们精心研制了一种轻质、异质、三维网络结构复合材料。SiC 纳米线-碳复合材料是利用丝瓜海绵作为基础材料,通过碳热还原和化学气相沉积相结合的新工艺合成的。有机硅烷废料被用作硅源,这种废料易于获取且成本低廉。所制成的复合材料具有优异的电磁波吸收性能,最小反射损耗为 -46.34 dB,有效带宽为 3.84 GHz,厚度仅为 1.9 mm。优异的电磁波吸收性能归功于多重界面极化、偶极子极化、导电损耗以及多重反射和散射的协同作用。这项工作为制造高效电磁波吸收材料提供了一条创新途径,同时有效地重新利用了回收废物。
{"title":"In situ formation SiC nanowires on loofah sponge-derived porous carbon for efficient electromagnetic wave absorption","authors":"Xiaolin Guo ,&nbsp;Haiyu Li ,&nbsp;Zhaoyang Zhang ,&nbsp;Pengfei Xing ,&nbsp;Shuai Wang ,&nbsp;Shengnan Jiang ,&nbsp;Yanxin Zhuang","doi":"10.1016/j.vacuum.2024.113769","DOIUrl":"10.1016/j.vacuum.2024.113769","url":null,"abstract":"<div><div>A lightweight, heterogeneous, three-dimensional network-structured composite has been meticulously developed with the specific goal of optimizing impedance matching and elevating electromagnetic wave absorption properties. SiC nanowires-carbon composites were synthesized through a novel process involving combined carbothermal reduction and chemical vapor deposition, utilizing loofah sponge as the foundational material. Accessible and cost-effective organosilane waste was applied as the silicon source. The resulting composites manifest exceptional electromagnetic wave absorption performance with a minimum reflection loss of −46.34 dB and a wide effective bandwidth of 3.84 GHz at a thin thickness of 1.9 mm. Superior electromagnetic wave absorption is attributed to synergistic interplay of multiple interfacial polarizations, dipole polarization, conductive losses, and multiple reflections and scattering. This work presents an innovative pathway toward fabricating highly efficient electromagnetic wave-absorbing materials while effectively repurposing recycled waste.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"231 ","pages":"Article 113769"},"PeriodicalIF":3.8,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mo vacancies enhancing Pt, Ni co-incorporated Mo2C nanofibers for high-efficiency water decomposition 钼空位增强铂、镍共掺Mo2C纳米纤维的高效水分解性能
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-01 DOI: 10.1016/j.vacuum.2024.113792
Keke Huang , Yaotian Yan , Jingxuan Li , Liang Qiao , Jiehe Sui , Wei Cai , Xiaohang Zheng
Hard alloy type compounds are promising candidates for developing robust and cost-effective electrocatalysts due to the good conductivity and lattice hardness. However, their insufficient intrinsic activities require further surface modification, which remains a significant challenge due to the high hardness and surface inertness. Herein, a vacancies-promoted heteroatoms integration method is provided to construct Pt and Ni co-incorporated molybdenum carbide nanofibers ((Pt, Ni)-Mo2C). The Pt and Ni atoms filling into the Mo vacancy reduce the formation energy by ∼5.5 eV, which indicates an improved crystal stability. The electrons flow from Mo, Ni centers to Pt, C centers, resulting in the shifted average valence of Mo, Ni sites and moderate oxidation states of Pt, C sites. Therefore, the hydrogen adsorption free energy (ΔG∗H) of Mo and C sites increases from ∼-0.6 eV to ∼-0.03 eV (C sites) and ∼-0.2 eV (Mo sites), resulting in a state closer to ideal state (0 eV). As a result, the (Pt, Ni)-Mo2C catalyst exhibits an excellent overpotential of 64 mV at 10 mA cm−2 for hydrogen evolution reaction (HER), reducing by 149 mV than pure Mo2C. Current work paves a favorable method for integrating dissimilar atoms to modify hard alloy type compound surface.
硬质合金型化合物具有良好的导电性和晶格硬度,是开发坚固耐用且经济高效的电催化剂的理想候选材料。然而,由于硬度和表面惰性较高,它们的内在活性不足,需要进一步的表面改性,而这仍然是一个巨大的挑战。本文提供了一种空位促进杂原子整合的方法来构建铂和镍共嵌碳化钼纳米纤维((Pt, Ni)-Mo2C)。填充到 Mo 空位中的铂原子和镍原子使形成能降低了 5.5 eV,从而提高了晶体的稳定性。电子从 Mo、Ni 中心流向 Pt、C 中心,导致 Mo、Ni 位点的平均价态偏移和 Pt、C 位点的中等氧化态。因此,Mo 和 C 位点的氢吸附自由能(ΔG∗H)从 ∼-0.6 eV 增加到 ∼-0.03 eV(C 位点)和 ∼-0.2 eV(Mo 位点),从而更接近理想状态(0 eV)。因此,(Pt, Ni)-Mo2C 催化剂在 10 mA cm-2 氢进化反应(HER)中表现出 64 mV 的优异过电位,比纯 Mo2C 减少了 149 mV。目前的工作为整合不同原子以改性硬质合金型化合物表面铺平了道路。
{"title":"Mo vacancies enhancing Pt, Ni co-incorporated Mo2C nanofibers for high-efficiency water decomposition","authors":"Keke Huang ,&nbsp;Yaotian Yan ,&nbsp;Jingxuan Li ,&nbsp;Liang Qiao ,&nbsp;Jiehe Sui ,&nbsp;Wei Cai ,&nbsp;Xiaohang Zheng","doi":"10.1016/j.vacuum.2024.113792","DOIUrl":"10.1016/j.vacuum.2024.113792","url":null,"abstract":"<div><div>Hard alloy type compounds are promising candidates for developing robust and cost-effective electrocatalysts due to the good conductivity and lattice hardness. However, their insufficient intrinsic activities require further surface modification, which remains a significant challenge due to the high hardness and surface inertness. Herein, a vacancies-promoted heteroatoms integration method is provided to construct Pt and Ni co-incorporated molybdenum carbide nanofibers ((Pt, Ni)-Mo<sub>2</sub>C). The Pt and Ni atoms filling into the Mo vacancy reduce the formation energy by ∼5.5 eV, which indicates an improved crystal stability. The electrons flow from Mo, Ni centers to Pt, C centers, resulting in the shifted average valence of Mo, Ni sites and moderate oxidation states of Pt, C sites. Therefore, the hydrogen adsorption free energy (ΔG<sub>∗H</sub>) of Mo and C sites increases from ∼-0.6 eV to ∼-0.03 eV (C sites) and ∼-0.2 eV (Mo sites), resulting in a state closer to ideal state (0 eV). As a result, the (Pt, Ni)-Mo<sub>2</sub>C catalyst exhibits an excellent overpotential of 64 mV at 10 mA cm<sup>−2</sup> for hydrogen evolution reaction (HER), reducing by 149 mV than pure Mo<sub>2</sub>C. Current work paves a favorable method for integrating dissimilar atoms to modify hard alloy type compound surface.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"231 ","pages":"Article 113792"},"PeriodicalIF":3.8,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142659411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Single-layer GaInTe3: Water-splitting photocatalyst low exciton binding and ultrahigh solar conversion efficiency 单层 GaInTe3:低激子结合和超高太阳能转换效率的水分离光催化剂
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-01 DOI: 10.1016/j.vacuum.2024.113795
Jia-Yu Bao , Si-Hai Wen , Yi Xiang , Le-Jun Wang , Tong-De Rao , Wen-Bo Yuan , Chun-Ming Yang , Mei-Ying Huang , Yong-Sheng Xie , Kai Wu , Lei Hu
Herein, we analyze the water decomposition possibility of single-layer (SL) GaInTe3 under the −2% to +2 % biaxial strain via first-principles stimulations. Our results find that SL GaInTe3 exhibits effective separation of photogenerated electrons and holes, which is strongly affirmed by the electronic property and the quite loose exciton binding. Furthermore, SL GaInTe3 has a suitable band edge and excellent visible-light capture ability, making it an ideal candidate for solar-assisted water decomposition. In addition, SL GaInTe3 shows a solar-to-hydrogen (STH) conversion of more than 33.0 %, further emphasizing its potential as a highly efficient photocatalyst. In conclusion, SL GaInTe3 has been supported by conclusive evidence as a photocatalytic material with excellent performance, providing new support and encouragement for the development of hydrogen production technology. Moreover, the effective thickness of 2D materials is defined as the largest spreading height of the electron cloud in covalent bonds perpendicular to the 2D atomic plane.
在此,我们通过第一原理激励分析了单层(SL)GaInTe3在-2%至+2%双轴应变下的水分解可能性。我们的结果发现,单层 GaInTe3 能有效分离光生电子和空穴,这在电子特性和相当松散的激子结合中得到了有力的证实。此外,SL GaInTe3 还具有合适的能带边缘和出色的可见光捕获能力,是太阳能辅助水分解的理想候选材料。此外,SL GaInTe3 的太阳能-氢气(STH)转化率超过 33.0%,进一步凸显了其作为高效光催化剂的潜力。总之,SL GaInTe3 作为一种性能卓越的光催化材料已得到确凿证据的支持,为制氢技术的发展提供了新的支持和鼓励。此外,二维材料的有效厚度是指共价键中电子云垂直于二维原子平面的最大扩散高度。
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引用次数: 0
Multicore@shell nanoparticle synthesis from a single multicomponent target by gas aggregation source 利用气体聚集源从单一多组分靶合成多核@壳纳米粒子
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-01 DOI: 10.1016/j.vacuum.2024.113794
Amir Mohammad Ahadi , Tim Tjardts , Salih Veziroglu , Marie Elis , Thomas Strunskus , Lorenz Kienle , Franz Faupel , Alexander Vahl
Synthesis of multifunctional nanomaterials is known as a critical challenge in advanced nanoscience. Multicore@shell nanostructures are generated here via a gas phase synthesis approach. To achieve this objective, we used conventional DC magnetron sputtering in conjunction with a gas aggregation chamber. We employed a customized Au-Ti target to produce metal-metal oxide multicore@shell nanoparticles (NPs) with tunable properties. The deposited NPs were characterized with regard to their chemical composition, morphology, structural status, NP size distribution and optical properties. The obtained data clearly confirms that the crystalline Au cores are encapsulated in a TiOx matrix in each individual NP. Furthermore, the chemical composition and size distribution of the NPs can be affected by the operating pressure. Our approach provides a versatile route with many different possibilities to synthesize multicore@shell NPs from a variety of composite targets for well-desired applications including environmental, optical/plasmonic, and energy.
众所周知,多功能纳米材料的合成是先进纳米科学中的一项关键挑战。多核@壳纳米结构是通过气相合成方法生成的。为了实现这一目标,我们将传统的直流磁控溅射与气体聚集室结合使用。我们采用定制的金钛靶来生产具有可调特性的金属-金属氧化物多核@壳纳米粒子(NPs)。沉积的 NPs 在化学成分、形态、结构状态、NP 尺寸分布和光学特性等方面都有特征。所获得的数据清楚地证实,在每个 NP 中,结晶金核都封装在 TiOx 基质中。此外,NPs 的化学成分和尺寸分布也会受到操作压力的影响。我们的方法提供了一种多功能途径,可从多种复合靶合成多核@壳 NPs,用于环境、光学/等离子体和能源等理想应用领域。
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引用次数: 0
Tailoring oxygen vacancies in Ga2O3 thin films and controlled formation of Ga2O3/SiO2 heterostructures via annealing 调整 Ga2O3 薄膜中的氧空位并通过退火控制 Ga2O3/SiO2 异质结构的形成
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-31 DOI: 10.1016/j.vacuum.2024.113791
Asma O. Al Ghaithi , Inas Taha , Sumayya M. Ansari , Nitul Rajput , Baker Mohammad , Haila M. Aldosari
This study examines the effects of annealing duration on the oxygen vacancies in gallium oxide (Ga2O3) thin films. Ga2O3 thin films were deposited by RF magnetron sputtering on (100) silicon substrates and subsequently annealed in an argon atmosphere at 1000 °C for 1, 2, 4, and 7 h. The impact of the annealing time on the morphology, oxygen content, optical bandgap, and thickness of Ga2O3 thin films was thoroughly investigated. All annealed films exhibited a polycrystalline β-Ga2O3 phase with a monoclinic crystal structure and a preferred orientation along the (400) plane. Increasing the annealing time resulted in larger grains, a denser interfacial layer, and reduced microstrain. Prolonged annealing also facilitated the escape of oxygen atoms, creating oxygen vacancies that formed a defect band below the conduction band, significantly lowering the optical bandgap. Cross-sectional transmission electron microscopy revealed a Ga2O3/SiO2 heterostructure formation, with Ga2O3 thickness decreasing and SiO2 thickness increasing with longer annealing times. These findings enhance the understanding of the role of annealing in optimizing Ga2O3 thin films for electronic and optoelectronic applications.
本研究探讨了退火时间对氧化镓(Ga2O3)薄膜中氧空位的影响。研究人员采用射频磁控溅射法在 (100) 硅基底上沉积 Ga2O3 薄膜,然后在 1000 °C 的氩气环境中分别退火 1、2、4 和 7 小时。所有退火薄膜都呈现出多晶β-Ga2O3相,具有单斜晶体结构,并沿(400)面优先取向。延长退火时间可使晶粒增大,界面层更致密,并降低微应变。延长退火时间还有利于氧原子逸出,产生氧空位,形成低于导带的缺陷带,显著降低了光带隙。横截面透射电子显微镜显示了 Ga2O3/SiO2 异质结构的形成,随着退火时间的延长,Ga2O3 厚度减小,SiO2 厚度增加。这些发现加深了人们对退火在优化 Ga2O3 薄膜在电子和光电应用中的作用的理解。
{"title":"Tailoring oxygen vacancies in Ga2O3 thin films and controlled formation of Ga2O3/SiO2 heterostructures via annealing","authors":"Asma O. Al Ghaithi ,&nbsp;Inas Taha ,&nbsp;Sumayya M. Ansari ,&nbsp;Nitul Rajput ,&nbsp;Baker Mohammad ,&nbsp;Haila M. Aldosari","doi":"10.1016/j.vacuum.2024.113791","DOIUrl":"10.1016/j.vacuum.2024.113791","url":null,"abstract":"<div><div>This study examines the effects of annealing duration on the oxygen vacancies in gallium oxide (Ga<sub>2</sub>O<sub>3</sub>) thin films. Ga<sub>2</sub>O<sub>3</sub> thin films were deposited by RF magnetron sputtering on (100) silicon substrates and subsequently annealed in an argon atmosphere at 1000 °C for 1, 2, 4, and 7 h. The impact of the annealing time on the morphology, oxygen content, optical bandgap, and thickness of Ga<sub>2</sub>O<sub>3</sub> thin films was thoroughly investigated. All annealed films exhibited a polycrystalline β-Ga<sub>2</sub>O<sub>3</sub> phase with a monoclinic crystal structure and a preferred orientation along the (400) plane. Increasing the annealing time resulted in larger grains, a denser interfacial layer, and reduced microstrain. Prolonged annealing also facilitated the escape of oxygen atoms, creating oxygen vacancies that formed a defect band below the conduction band, significantly lowering the optical bandgap. Cross-sectional transmission electron microscopy revealed a Ga<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> heterostructure formation, with Ga<sub>2</sub>O<sub>3</sub> thickness decreasing and SiO<sub>2</sub> thickness increasing with longer annealing times. These findings enhance the understanding of the role of annealing in optimizing Ga<sub>2</sub>O<sub>3</sub> thin films for electronic and optoelectronic applications.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"231 ","pages":"Article 113791"},"PeriodicalIF":3.8,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142572212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microscopic scale analysis of the dynamic changes of the melt pool and the evolution of dendritic structure during L-DED of GH3536 alloy GH3536 合金 L-DED 过程中熔池动态变化和树枝状结构演变的显微尺度分析
IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1016/j.vacuum.2024.113790
Kaikai Xu , Yadong Gong , Jibin Zhao , Qiang Zhao
This paper presents the establishment of a melt pool flow model, wherein the solute field and phase field are concurrently integrated to simulate the dynamic transformations within the melt pool and the evolution of dendrites during the solidification process. Experimental validation affirms the model's precision. The simulation outcomes indicate the persistence of a pronounced symmetry within the melt pool throughout the flow process. Intriguingly, perturbations in the powder and variations in heat transfer give rise to a vortex-like internal flow pattern within the melt pool. These findings align harmoniously with the experimental results concerning the dimensions of the melt pool (melt width, melt depth, and melt height). Specifically, the growth rate of dendrite tips and the dendrite count exhibit significant sensitivity to alterations in temperature gradient. As the temperature gradient escalates, the primary dendrite arm spacing diminishes, accompanied by heightened development of secondary dendrite arms. In congruence with the simulated dendrite evolution process, the microstructure within the deposited layer derived from experimental observations primarily comprises columnar crystals. The growth of dendrites unfolds perpendicularly to the melt pool boundary, following the trajectory of decreasing temperature gradient, thereby mirroring the simulated dendrite evolution process.
本文介绍了熔池流动模型的建立,该模型同时整合了溶质场和相场,以模拟凝固过程中熔池内的动态转变和树枝状物的演变。实验验证证实了模型的精确性。模拟结果表明,在整个流动过程中,熔池内持续存在明显的对称性。耐人寻味的是,粉末的扰动和传热的变化会在熔池中产生类似涡旋的内部流动模式。这些发现与有关熔池尺寸(熔池宽度、熔池深度和熔池高度)的实验结果非常吻合。具体来说,树枝状突起的生长速度和树枝状突起的数量对温度梯度的变化非常敏感。随着温度梯度的增加,一级树突臂的间距减小,同时二级树突臂的生长速度加快。与模拟的树枝状突变过程一致,实验观察得出的沉积层内的微观结构主要由柱状晶体组成。树枝状晶体的生长垂直于熔池边界,沿着温度梯度下降的轨迹展开,从而反映了模拟的树枝状晶体演变过程。
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Vacuum
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