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Distribution of ion energy and concentration in the expansion region of radio-frequency inductive coupled plasmas with deuterium and deuterium-nitrogen mixtures 氘和氘氮混合物射频电感耦合等离子体膨胀区的离子能量和浓度分布
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.vacuum.2026.115125
Xiao Xi , Xuxu Liu , Wei Jin , Jipeng Zhu , Hai Jin , Xiaoqiu Ye , Changan Chen
In this study, a 13.56 MHz radio frequency power supply was used to generate an external solenoid inductively coupled plasma source. An ion energy mass spectrometer equipped with a Bessel box and quadrupole mass filter was employed to investigate the characteristics of ion in expansion region. The ion species, concentration and their energy distributions with different working gases, including deuterium, nitrogen and their mixtures, have been analyzed by adjusting the gas flow rate or relative concentration over a wide parametric range. The results give the evolution of deuterium series D+/D2+/D3+, nitrogen series N+/N2+/N2D+, and the ammonia series ND+/ND2+/ND3+/ND4+. The ion energy distribution of D3+, N2+ and ND4+ display multi-peak distributions, indicating sheath voltage modulation and frequent collisional production in gas phase. The signal intensities and peak energies of these ions show distinct trends with respect to the gas flow rate. The reaction processes been given to illustrate the transformation path within and between different ion series. The reactions can be divided into three stages: ionization regime, intermediate regime and recombination regime, depending on the overall gas flow rate. And the N2D+ is an effective media during molecular assisted recombination stage. These results benefit plasma processing and chemical synthesis.
在本研究中,使用13.56 MHz射频电源产生外部电磁电感耦合等离子体源。采用配备贝塞尔箱和四极杆质量过滤器的离子能量质谱仪研究了膨胀区离子的特性。通过在较宽的参数范围内调节气体流速或相对浓度,分析了不同工作气体(包括氘、氮及其混合物)下离子的种类、浓度及其能量分布。得到了氘系D+/D2+/D3+、氮系N+/N2+/N2D+、氨系ND+/ND2+/ND3+/ND4+的演化规律。D3+、N2+和ND4+离子能量分布呈多峰分布,表明鞘层电压调制,气相频繁发生碰撞。这些离子的信号强度和峰值能量随气体流速的变化有明显的趋势。给出了反应过程来说明不同离子系内部和之间的转化路径。根据总气体流速的不同,反应可分为电离态、中间态和复合态三个阶段。N2D+是分子辅助重组阶段的有效载体。这些结果有利于等离子体加工和化学合成。
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引用次数: 0
Research on the phase interface structure and orientation relationship of the intermetallic compounds layer in Sn-3.0Ag-0.5Cu/Cu joints during isothermal aging Sn-3.0Ag-0.5Cu/Cu接头等温时效过程中金属间化合物层相界面结构及取向关系研究
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.vacuum.2026.115123
Dongdong Chen , Zan Long , Sirong Zhu , Huaxin Liang , Yuan Teng , Cunji Pu , Jikang Yan , Yanqing Lai , Jianhong Yi
The structure of the interfacial layer is important for evaluating the reliability of an electronic package. Herein, we comprehensively investigated the changes in morphology and thickness of intermetallic compounds interlayer during aging, the diffusion of elements during the reflow soldering and isothermal aging, as well as the phase structural and crystallographic relationships among β-Sn, Cu6Sn5, and Cu3Sn phases. After aging, Cu6Sn5/β-Sn interface exhibited special [010]βSn//[210]Cu6Sn5 crystallographic relationship, while the angle between (101)βSn and (121)Cu6Sn5 was 174.1°. Cu6Sn5/Cu3Sn interface showed special [111]Cu6Sn5//[001]Cu3Sn crystallographic relationship, while the angle between (312)Cu6Sn5 and (210)Cu3Sn was 58.7°. The growth patterns of Cu6Sn5 and Cu3Sn phases during isothermal aging were investigated further based on the interface orientation relationship. This study reported the growth of the interface IMCs layer via the interfacial structure of Cu6Sn5/β-Sn, Cu6Sn5/Cu3Sn, and Cu3Sn/Cu, which further improves the orientation relationship of interface phases. Meanwhile, this work provides a valuable basis for improving the reliability of solder service.
界面层的结构是评价电子封装可靠性的重要因素。本文全面研究了时效过程中金属间化合物层间形貌和厚度的变化,回流焊和等温时效过程中元素的扩散,以及β-Sn、Cu6Sn5和Cu3Sn相的相结构和晶体学关系。时效后,Cu6Sn5/β-Sn界面呈现出特殊的[010]β−Sn//[210]Cu6Sn5结晶关系,而(1 - 01)β−Sn与(1 - 21)Cu6Sn5之间的夹角为174.1°。Cu6Sn5/Cu3Sn界面表现出特殊的[111]Cu6Sn5//[001]Cu3Sn结晶关系,而(31 - 2)Cu6Sn5与(21 - 0)Cu3Sn之间的夹角为58.7°。基于界面取向关系,进一步研究了等温时效过程中Cu6Sn5和Cu3Sn相的生长规律。本研究报道了Cu6Sn5/β-Sn、Cu6Sn5/Cu3Sn、Cu3Sn/Cu三种界面结构下界面IMCs层的生长,进一步改善了界面相取向关系。同时,为提高焊料服务的可靠性提供了有价值的依据。
{"title":"Research on the phase interface structure and orientation relationship of the intermetallic compounds layer in Sn-3.0Ag-0.5Cu/Cu joints during isothermal aging","authors":"Dongdong Chen ,&nbsp;Zan Long ,&nbsp;Sirong Zhu ,&nbsp;Huaxin Liang ,&nbsp;Yuan Teng ,&nbsp;Cunji Pu ,&nbsp;Jikang Yan ,&nbsp;Yanqing Lai ,&nbsp;Jianhong Yi","doi":"10.1016/j.vacuum.2026.115123","DOIUrl":"10.1016/j.vacuum.2026.115123","url":null,"abstract":"<div><div>The structure of the interfacial layer is important for evaluating the reliability of an electronic package. Herein, we comprehensively investigated the changes in morphology and thickness of intermetallic compounds interlayer during aging, the diffusion of elements during the reflow soldering and isothermal aging, as well as the phase structural and crystallographic relationships among β-Sn, Cu<sub>6</sub>Sn<sub>5</sub>, and Cu<sub>3</sub>Sn phases. After aging, Cu<sub>6</sub>Sn<sub>5</sub><strong>/</strong>β-Sn interface exhibited special <span><math><mrow><msub><mrow><mo>[</mo><mn>010</mn><mo>]</mo></mrow><mrow><mi>β</mi><mo>−</mo><mi>S</mi><mi>n</mi></mrow></msub><mo>/</mo><mo>/</mo><msub><mrow><mo>[</mo><mn>210</mn><mo>]</mo></mrow><mrow><mi>C</mi><msub><mi>u</mi><mn>6</mn></msub><mi>S</mi><msub><mi>n</mi><mn>5</mn></msub></mrow></msub></mrow></math></span> crystallographic relationship, while the angle between <span><math><mrow><msub><mrow><mo>(</mo><mrow><mover><mn>1</mn><mo>‾</mo></mover><mn>01</mn></mrow><mo>)</mo></mrow><mrow><mi>β</mi><mo>−</mo><mi>S</mi><mi>n</mi></mrow></msub></mrow></math></span> and <span><math><mrow><msub><mrow><mo>(</mo><mrow><mover><mn>1</mn><mo>‾</mo></mover><mn>21</mn></mrow><mo>)</mo></mrow><mrow><mi>C</mi><msub><mi>u</mi><mn>6</mn></msub><mi>S</mi><msub><mi>n</mi><mn>5</mn></msub></mrow></msub></mrow></math></span> was 174.1°. Cu<sub>6</sub>Sn<sub>5</sub><strong>/</strong>Cu<sub>3</sub>Sn interface showed special <span><math><mrow><msub><mrow><mo>[</mo><mn>111</mn><mo>]</mo></mrow><mrow><mi>C</mi><msub><mi>u</mi><mn>6</mn></msub><mi>S</mi><mi>n</mi><mn>5</mn></mrow></msub><mo>/</mo><mo>/</mo><msub><mrow><mo>[</mo><mn>001</mn><mo>]</mo></mrow><mrow><mi>C</mi><msub><mi>u</mi><mn>3</mn></msub><mi>S</mi><mi>n</mi></mrow></msub></mrow></math></span> crystallographic relationship, while the angle between <span><math><mrow><msub><mrow><mo>(</mo><mrow><mn>3</mn><mover><mn>1</mn><mo>‾</mo></mover><mover><mn>2</mn><mo>‾</mo></mover></mrow><mo>)</mo></mrow><mrow><mi>C</mi><msub><mi>u</mi><mn>6</mn></msub><mi>S</mi><msub><mi>n</mi><mn>5</mn></msub></mrow></msub></mrow></math></span> and <span><math><mrow><msub><mrow><mo>(</mo><mrow><mn>2</mn><mover><mn>1</mn><mo>‾</mo></mover><mn>0</mn></mrow><mo>)</mo></mrow><mrow><mi>C</mi><msub><mi>u</mi><mn>3</mn></msub><mi>S</mi><mi>n</mi></mrow></msub></mrow></math></span> was 58.7°. The growth patterns of Cu<sub>6</sub>Sn<sub>5</sub> and Cu<sub>3</sub>Sn phases during isothermal aging were investigated further based on the interface orientation relationship. This study reported the growth of the interface IMCs layer via the interfacial structure of Cu<sub>6</sub>Sn<sub>5</sub><strong>/</strong>β-Sn, Cu<sub>6</sub>Sn<sub>5</sub><strong>/</strong>Cu<sub>3</sub>Sn, and Cu<sub>3</sub>Sn/Cu, which further improves the orientation relationship of interface phases. Meanwhile, this work provides a valuable basis for improving the reliability of solder service.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115123"},"PeriodicalIF":3.9,"publicationDate":"2026-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146025498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A carbon nanotubes cathode ionization gauge with a straight path of electrons 一种碳纳米管阴极电离计,具有电子的直线路径
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.vacuum.2026.115102
Guoheng Yu , Detian Li , Huzhong Zhang , Weijun Huang , Changkun Dong , Zhenhua Xi , Gang Li , Zhangyi Zhong , Weidong Kang
Carbon nanotubes (CNTs) are a type of field emission cathode material with broad application potential. Compared with hot filament cathodes, CNTs cathodes possess advantages such as low operating temperature and energy efficiency. In this article, a CNTs electron emitter is integrated into an ionization gauge featuring a straight electron path. A series of tests were performed on the CNTs cathode and the prototype gauge. The optimal operating potential of the prototype gauge was determined through simulations and experiments. The prototype achieved a sensitivity of 0.317 Pa1 in argon and 0.240 Pa1 in nitrogen. This prototype gauge exhibits good linearity in the range from 10−6 Pa to 10−3 Pa in argon and nitrogen, while its sensitivity fluctuations are 1.17 % and 3.2 %, and within half an hour, the sensitivity fluctuations in the two gases are 1.6 % and 2.2 % respectively. Under simulated normal operating conditions, the repeatability is less than 3 %. This novel developed ionization gauge has simultaneously achieved high sensitivity and good stability. This study provides insights for the application of CNTs cathodes in the ionization gauges.
碳纳米管是一种具有广泛应用潜力的场发射阴极材料。与热丝阴极相比,CNTs阴极具有工作温度低、能效高等优点。在本文中,将碳纳米管电子发射器集成到具有直电子路径的电离计中。对碳纳米管阴极和原型压力表进行了一系列测试。通过仿真和实验,确定了原型仪表的最佳工作电位。样品在氩气和氮气中的灵敏度分别为0.317 Pa−1和0.240 Pa−1。在10−6 Pa ~ 10−3 Pa的氩气和氮气环境中,样品表具有良好的线性关系,灵敏度波动幅度分别为1.17%和3.2%,半小时内,两种气体的灵敏度波动幅度分别为1.6%和2.2%。在模拟正常工作条件下,重复性小于3%。这种新型电离计具有高灵敏度和良好的稳定性。本研究为碳纳米管阴极在电离计中的应用提供了新的思路。
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引用次数: 0
Fabrication and characterization of core-shell HEA-reinforced 316L composite prepared by LPBF LPBF制备核壳hea增强316L复合材料的制备与表征
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.vacuum.2026.115122
Qiqi Chen, Xueli Zhao, Shaoning Niu, Xini Xiong, Yongjuan Dai, Shaofeng Yang
This study introduced the laser powder bed fusion of core-shell AlCrFeCoNi high-entropy alloy (HEA)-reinforced 316L stainless steel matrix composites (MMCs) with enhanced mechanical performance. To prevent diffusion between the HEA and the 316L matrix during the forming process, a core-shell structured HEA-reinforcing phase was prepared by an in-situ hydrolysis reaction of a silicon source salt. The microstructural characteristics and mechanical properties of LPBF-fabricated MMCs containing 20 wt% AlCrFeCoNi were systematically examined. Microstructural analysis revealed that core-shell HEAs with a single BCC phase were homogeneously dispersed within the 316L matrix, effectively transforming the coarse-grained microstructure into a refined one. This grain refinement can be attributed to the heterogeneous nucleation effect induced by the core-shell HEA particles during solidification. The 20 wt% HEA-316L composite exhibited higher strength and fracture toughness, namely a yield strength of 759±2 MPa, ultimate tensile strength of 798±2 MPa, and elongation of 29.6 ± 1.5 %.
本研究采用激光粉末床熔接技术制备了具有增强力学性能的AlCrFeCoNi高熵合金增强316L不锈钢基复合材料。为了防止HEA在形成过程中与316L基体之间的扩散,采用硅源盐原位水解法制备了核壳结构的HEA增强相。系统地研究了含20wt % AlCrFeCoNi的lpbf制备的mmc的显微组织特征和力学性能。显微组织分析表明,具有单一BCC相的核壳HEAs均匀分散在316L基体中,有效地将粗晶组织转变为精细化组织。这种晶粒细化可归因于核壳HEA颗粒在凝固过程中诱导的非均质成核效应。20 wt%的HEA-316L复合材料具有较高的强度和断裂韧性,屈服强度为759±2 MPa,极限抗拉强度为798±2 MPa,伸长率为29.6±1.5%。
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引用次数: 0
Study on the principle of mass loss of Penning Negative ion source cathode 潘宁负离子源阴极质量损失原理的研究
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.vacuum.2026.115116
Yuhang Chen , Jie Li , Chao Pan , Ruili Ma , Jidong Long , Xiaozhong He , Jinshui Shi , Kefu Liu
High-power, compact, built-in Penning negative hydrogen ion source has been widely used in particle accelerator applications. But the problem of its short operating life has been an issue, with cathode mass loss being the main factor affecting its life. The material lost from the cathode will condense on the anode wall and will flake off under alternating heat and cold. The flaking material is directed from the cathode to the anode under the action of an electric field, and when the debris is too large it will short-circuit the cathode and anode directly. To solve this key problem, it is necessary to study the specific causes of cathode mass loss, and optimize the operation methods and design ideas of the ion source through these causes. In this paper, the cathode mass loss mechanism was investigated. It is considered that the cathode mass of this ion source is mainly lost through the evaporation process during the large arc current operation under the high purity gas environment. And several optimization measures are proposed in the operation and design of the equipment.
大功率、紧凑、内置的彭宁负氢离子源已广泛应用于粒子加速器中。但其使用寿命短的问题一直是一个问题,阴极质量损失是影响其寿命的主要因素。从阴极流失的材料会凝结在阳极壁上,并在冷热交替下剥落。剥落物在电场作用下由阴极向阳极定向,当碎屑过大时将直接使阴极和阳极短路。要解决这一关键问题,有必要研究阴极质量损失的具体原因,并通过这些原因优化离子源的操作方法和设计思路。本文对阴极质量损失机理进行了研究。认为该离子源的阴极质量主要是在高纯气体环境下大电弧电流运行时通过蒸发过程损失的。并在设备的运行和设计中提出了若干优化措施。
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引用次数: 0
Thermal stability of nano-mesoscopic structure in Ce-Added FeCrAl ODS steel aged at 700 °C for 10,000 h 添加ce的FeCrAl ODS钢700℃时效10000 h纳米介观结构的热稳定性
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.vacuum.2026.115105
Zhan-Xing Li, Wen-Qian Wang, Peng Dou
FeCrAl oxide dispersion strengthened (ODS) steel is a promising candidate cladding material for Generation IV nuclear reactors due to its excellent resistance to creep, irradiation, oxidation, and corrosion. The thermal stability of matrix grains and, moreover, the phase, dispersion morphology and metal/oxide interface structure of nanoparticles in 16Cr–2Al–0.1Ti–0.35Ce–0.35Y2O3 (wt. %) ODS steel aged at 700 °C for 10,000 h was investigated using S/TEM and HRTEM. After aging, the matrix grain size increased from 1.0 μm to 1.1 μm. For the nanoparticles, the mean diameter changed from 8.9 nm to 9.3 nm; the number density decreased from 5.9 × 1021 m−3 to 5.5 × 1021 m−3, and the inter-particle spacing increased from 139.5 nm to 140.7 nm. The proportion of Y–Ce–O oxides changed slightly from 52.2 % to 55.3 %, while that of Y–Ti–O changed from 22.1 % to 21.3 %. The proportion of coherent/semi-coherent particles changed from 88.6 % to 90.7 %. The nano-mesoscopic structure exhibited no significant changes, demonstrating its excellent thermal stability. Owing to the stable nano-mesoscopic structure, the Vickers hardness decreased only slightly from 275 HV to 263 HV. The origins of the thermal stability of the nano-mesoscopic structure were discussed in terms of Ostwald ripening, diffusion behavior, Zener pinning, and strengthening mechanisms.
铁铁氧化物弥散强化(ODS)钢因其优异的抗蠕变、抗辐照、抗氧化和耐腐蚀性能,是第四代核反应堆极具前景的包层材料。采用S/TEM和HRTEM研究了16Cr-2Al-0.1Ti-0.35Ce-0.35Y2O3 (wt. %) ODS钢在700℃时效10000 h后基体晶粒的热稳定性以及纳米颗粒的物相、分散形态和金属/氧化物界面结构。时效后,基体晶粒尺寸由1.0 μm增大到1.1 μm。纳米颗粒的平均直径从8.9 nm变化到9.3 nm;粒子数密度由5.9 × 1021 m−3减小到5.5 × 1021 m−3,粒子间距由139.5 nm增大到140.7 nm。Y-Ce-O氧化物的比例从52.2%变化到55.3%,Y-Ti-O的比例从22.1%变化到21.3%。相干/半相干粒子的比例从88.6%增加到90.7%。纳米介观结构无明显变化,表现出优异的热稳定性。由于稳定的纳米介观结构,合金的维氏硬度仅从275 HV略微下降到263 HV。从奥斯特瓦尔德成熟、扩散行为、齐纳钉钉和强化机制等方面讨论了纳米介观结构热稳定性的来源。
{"title":"Thermal stability of nano-mesoscopic structure in Ce-Added FeCrAl ODS steel aged at 700 °C for 10,000 h","authors":"Zhan-Xing Li,&nbsp;Wen-Qian Wang,&nbsp;Peng Dou","doi":"10.1016/j.vacuum.2026.115105","DOIUrl":"10.1016/j.vacuum.2026.115105","url":null,"abstract":"<div><div>FeCrAl oxide dispersion strengthened (ODS) steel is a promising candidate cladding material for Generation IV nuclear reactors due to its excellent resistance to creep, irradiation, oxidation, and corrosion. The thermal stability of matrix grains and, moreover, the phase, dispersion morphology and metal/oxide interface structure of nanoparticles in 16Cr–2Al–0.1Ti–0.35Ce–0.35Y<sub>2</sub>O<sub>3</sub> (wt. %) ODS steel aged at 700 °C for 10,000 h was investigated using S/TEM and HRTEM. After aging, the matrix grain size increased from 1.0 μm to 1.1 μm. For the nanoparticles, the mean diameter changed from 8.9 nm to 9.3 nm; the number density decreased from 5.9 × 10<sup>21</sup> m<sup>−3</sup> to 5.5 × 10<sup>21</sup> m<sup>−3</sup>, and the inter-particle spacing increased from 139.5 nm to 140.7 nm. The proportion of Y–Ce–O oxides changed slightly from 52.2 % to 55.3 %, while that of Y–Ti–O changed from 22.1 % to 21.3 %. The proportion of coherent/semi-coherent particles changed from 88.6 % to 90.7 %. The nano-mesoscopic structure exhibited no significant changes, demonstrating its excellent thermal stability. Owing to the stable nano-mesoscopic structure, the Vickers hardness decreased only slightly from 275 HV to 263 HV. The origins of the thermal stability of the nano-mesoscopic structure were discussed in terms of Ostwald ripening, diffusion behavior, Zener pinning, and strengthening mechanisms.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115105"},"PeriodicalIF":3.9,"publicationDate":"2026-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146025497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seed-layer-assisted crystallization engineering of CdS for high-performance CdS/SnS heterojunction solar cells 用于高性能CdS/SnS异质结太阳能电池的CdS种子层辅助结晶工程
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.vacuum.2026.115103
Yanping Lv , Ziyi Qin , Menghe Liu , Jun Zhang , Ming Yang , Hao Wu
Tin(II) sulfide (SnS) has exhibited promising characteristics for photovoltaic applications, yet the efficiency of SnS thin-film photovoltaics is still constrained by carrier transport bottlenecks at interfaces and defect-mediated recombination near the buffer/absorber heterojunction. This study systematically investigates the influence of seed-layer-induced crystallization engineering on the CdS buffer layer to optimize SnS device performance. XRD and cross-sectional TEM confirm the transition to a polycrystalline CdS structure, while TPV and EIS analyses reveal a significant enhancement in recombination resistance and carrier lifetime. Moreover, the seed-layer-induced crystallization leads to a favorable downshift of the CdS conduction band minimum, facilitating electron injection from SnS into CdS and thereby improving charge collection. As a result, the optimized FTO/CdS/SnS/Ag solar cells achieve a notable 83 % increase in PCE (from 1.16 % to 2.12 %), underscoring the critical importance of crystallinity control and interface engineering in developing high-performance SnS-based photovoltaics.
硫化锡(Tin(II) sulfide, SnS)在光伏应用中表现出了很好的特性,但SnS薄膜光伏电池的效率仍然受到界面载流子输运瓶颈和缓冲/吸收异质结附近缺陷介导的重组的限制。本研究系统探讨了种子层诱导结晶工程对CdS缓冲层的影响,以优化SnS器件的性能。XRD和横截面TEM证实了向多晶CdS结构的转变,而TPV和EIS分析表明复合电阻和载流子寿命显著增强。此外,种子层诱导结晶导致CdS导带最小值的有利下移,有利于电子从SnS注入CdS,从而改善电荷收集。结果表明,优化后的FTO/CdS/SnS/Ag太阳能电池的PCE显著提高了83%(从1.16%提高到2.12%),强调了结晶度控制和界面工程在开发高性能的基于sn的光伏电池中的重要性。
{"title":"Seed-layer-assisted crystallization engineering of CdS for high-performance CdS/SnS heterojunction solar cells","authors":"Yanping Lv ,&nbsp;Ziyi Qin ,&nbsp;Menghe Liu ,&nbsp;Jun Zhang ,&nbsp;Ming Yang ,&nbsp;Hao Wu","doi":"10.1016/j.vacuum.2026.115103","DOIUrl":"10.1016/j.vacuum.2026.115103","url":null,"abstract":"<div><div>Tin(II) sulfide (SnS) has exhibited promising characteristics for photovoltaic applications, yet the efficiency of SnS thin-film photovoltaics is still constrained by carrier transport bottlenecks at interfaces and defect-mediated recombination near the buffer/absorber heterojunction. This study systematically investigates the influence of seed-layer-induced crystallization engineering on the CdS buffer layer to optimize SnS device performance. XRD and cross-sectional TEM confirm the transition to a polycrystalline CdS structure, while TPV and EIS analyses reveal a significant enhancement in recombination resistance and carrier lifetime. Moreover, the seed-layer-induced crystallization leads to a favorable downshift of the CdS conduction band minimum, facilitating electron injection from SnS into CdS and thereby improving charge collection. As a result, the optimized FTO/CdS/SnS/Ag solar cells achieve a notable 83 % increase in PCE (from 1.16 % to 2.12 %), underscoring the critical importance of crystallinity control and interface engineering in developing high-performance SnS-based photovoltaics.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115103"},"PeriodicalIF":3.9,"publicationDate":"2026-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146026012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elucidating long period stacking ordered phases in Mg-Gd-Ag alloys with Zn doping: A synergistic experimental and first-principles study Zn掺杂Mg-Gd-Ag合金中长周期有序堆积相的研究:一个协同实验和第一性原理研究
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.vacuum.2026.115120
Yao Tao , Xia Chen , Qiang Chen , Bin Chen
Magnesium alloys are promising candidates for lightweight engineering applications. However, the presence of Ag impedes the formation of long-period stacking ordered (LPSO) phases in Mg-Gd-Ag alloys, thereby restricting the optimization of their mechanical properties. While Zn doping is well-documented to facilitate LPSO phase formation in Mg-RE-TM systems, the underlying mechanism by which Zn modulates this process in Ag-containing Mg-Gd alloys remains elusive. Herein, we investigate the LPSO phases in Mg140Gd16TM12 (TM = Ag, Zn) alloys with varying Zn/Ag ratios via HAADF-STEM and first-principles calculations, clarifying their thermodynamic stability, mechanical properties, and electronic structures. Experimental results confirm the formation of 14H and 18R LPSO phases, with Zn substituting Ag to facilitate LPSO nucleation. First-principles calculations show that all Zn-containing phases exhibit negative formation enthalpies, with increasing Zn content enhancing thermodynamic stability (Mg140Gd16Zn12 being the most stable). Zn doping reduces Young's and shear moduli but improves ductility, as indicated by the increasing Pugh ratio (1.49–1.55) and Poisson's ratio (0.226–0.233). Electronic structure analysis reveals deep hybridization of Mg-p, Gd-d, and Zn-d orbitals in the −2.5∼2.0 eV range; Zn enrichment weakens Ag's bridging effect, making Zn-d orbitals dominant in bonding. This work provides insights for optimizing Mg-Gd-Ag alloy performance via composition regulation.
镁合金是轻量化工程应用的有前途的候选者。然而,Ag的存在阻碍了Mg-Gd-Ag合金中长周期有序堆积相(LPSO)的形成,从而限制了其力学性能的优化。虽然锌掺杂促进了Mg-RE-TM体系中LPSO相的形成,但锌在含银Mg-Gd合金中调节这一过程的潜在机制仍然难以捉摸。本文通过HAADF-STEM和第一性原理计算研究了不同Zn/Ag比的Mg140Gd16TM12 (TM = Ag, Zn)合金中的LPSO相,阐明了它们的热力学稳定性、力学性能和电子结构。实验结果证实了14H和18R LPSO相的形成,Zn取代Ag有利于LPSO成核。第一性原理计算表明,所有含Zn相的生成焓均为负,随着Zn含量的增加,热力学稳定性增强(Mg140Gd16Zn12最稳定)。锌的掺入降低了杨氏模量和剪切模量,但提高了材料的延性,增加了Pugh比(1.49 ~ 1.55)和泊松比(0.226 ~ 0.233)。电子结构分析表明,Mg-p、Gd-d和Zn-d轨道在−2.5 ~ 2.0 eV范围内存在深度杂化;Zn富集减弱了Ag的桥接作用,使Zn-d轨道在成键中占主导地位。这项工作为通过成分调节优化Mg-Gd-Ag合金的性能提供了见解。
{"title":"Elucidating long period stacking ordered phases in Mg-Gd-Ag alloys with Zn doping: A synergistic experimental and first-principles study","authors":"Yao Tao ,&nbsp;Xia Chen ,&nbsp;Qiang Chen ,&nbsp;Bin Chen","doi":"10.1016/j.vacuum.2026.115120","DOIUrl":"10.1016/j.vacuum.2026.115120","url":null,"abstract":"<div><div>Magnesium alloys are promising candidates for lightweight engineering applications. However, the presence of Ag impedes the formation of long-period stacking ordered (LPSO) phases in Mg-Gd-Ag alloys, thereby restricting the optimization of their mechanical properties. While Zn doping is well-documented to facilitate LPSO phase formation in Mg-RE-TM systems, the underlying mechanism by which Zn modulates this process in Ag-containing Mg-Gd alloys remains elusive. Herein, we investigate the LPSO phases in Mg<sub>140</sub>Gd<sub>16</sub>TM<sub>12</sub> (TM = Ag, Zn) alloys with varying Zn/Ag ratios via HAADF-STEM and first-principles calculations, clarifying their thermodynamic stability, mechanical properties, and electronic structures. Experimental results confirm the formation of 14H and 18R LPSO phases, with Zn substituting Ag to facilitate LPSO nucleation. First-principles calculations show that all Zn-containing phases exhibit negative formation enthalpies, with increasing Zn content enhancing thermodynamic stability (Mg<sub>140</sub>Gd<sub>16</sub>Zn<sub>12</sub> being the most stable). Zn doping reduces Young's and shear moduli but improves ductility, as indicated by the increasing Pugh ratio (1.49–1.55) and Poisson's ratio (0.226–0.233). Electronic structure analysis reveals deep hybridization of Mg-p, Gd-d, and Zn-d orbitals in the −2.5∼2.0 eV range; Zn enrichment weakens Ag's bridging effect, making Zn-d orbitals dominant in bonding. This work provides insights for optimizing Mg-Gd-Ag alloy performance via composition regulation.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115120"},"PeriodicalIF":3.9,"publicationDate":"2026-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146025495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Co addition on the heterogenous gradient structure, magnetic properties, and nanocrystallization process of FeSiBPCCu nanocrystalline alloys with high Fe and Cu contents Co添加对高铁、高铜FeSiBPCCu纳米晶合金异质梯度结构、磁性能及纳米晶化过程的影响
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.vacuum.2026.115108
Lei Xie , Jian Wang , Qiang Li , Hao Wang , Chuntao Chang , Aina He , Yaqiang Dong
This study investigates the effects of Co addition on the glass-forming ability (GFA), thermal stability, soft magnetic properties (SMPs), and crystallization behavior of the Fe84-xCoxSi2B9P3C0.5Cu1.5 (x = 0–20) nanocrystalline alloys (NAs). Research has found that rapid cooling ribbons form uneven gradient structures along the thickness direction due to the cooling rate of the wheel-side (WS) being greater than that of the free-side (FS), while the addition of Co enhances the GFA and weakens this gradient structure. Crystallization kinetics analysis shows that the nucleation and growth activation energy of the FS α-Fe(Co) crystal is higher than that of the WS, resulting in slower crystallization rate α-Fe(Co) crystals in the FS. Furthermore, Co addition leads to a more significant difference in crystallization rates between the FS and WS, thus resulting in a more uniform and finer NA nanostructure. Meanwhile, the addition of Co expands the crystallization window and inhibits the precipitation of compound phases. Finally, the NAs obtained by annealing at 480 °C for 10 min achieved excellent combination of high Bs (1.83–1.94 T) and low Hc (5–10 A/m), breaking through the trade-off between Bs and Hc in traditional soft magnetic materials. This study contributes to the understanding of the crystallization process of gradient non-uniform materials and provides guidance for the development of Fe-based NAs with high Bs and low Hc.
本研究考察了Co的加入对Fe84-xCoxSi2B9P3C0.5Cu1.5 (x = 0-20)纳米晶合金(NAs)的玻璃形成能力(GFA)、热稳定性、软磁性能(SMPs)和结晶行为的影响。研究发现,由于车轮侧(WS)的冷却速度大于自由侧(FS)的冷却速度,快速冷却带沿厚度方向形成不均匀的梯度结构,而Co的加入增强了GFA,减弱了这种梯度结构。结晶动力学分析表明,FS α-Fe(Co)晶体的成核和生长活化能高于WS,导致FS中α-Fe(Co)晶体的结晶速率较慢。此外,Co的加入使FS和WS的结晶速率差异更显著,从而使NA纳米结构更加均匀和精细。同时,Co的加入扩大了结晶窗口,抑制了复合相的析出。最后,在480°C下退火10 min得到的NAs实现了高Bs (1.83-1.94 T)和低Hc (5-10 A/m)的完美结合,突破了传统软磁材料中Bs和Hc之间的权衡。本研究有助于理解梯度非均匀材料的结晶过程,为高Bs低Hc铁基NAs的开发提供指导。
{"title":"Effect of Co addition on the heterogenous gradient structure, magnetic properties, and nanocrystallization process of FeSiBPCCu nanocrystalline alloys with high Fe and Cu contents","authors":"Lei Xie ,&nbsp;Jian Wang ,&nbsp;Qiang Li ,&nbsp;Hao Wang ,&nbsp;Chuntao Chang ,&nbsp;Aina He ,&nbsp;Yaqiang Dong","doi":"10.1016/j.vacuum.2026.115108","DOIUrl":"10.1016/j.vacuum.2026.115108","url":null,"abstract":"<div><div>This study investigates the effects of Co addition on the glass-forming ability (GFA), thermal stability, soft magnetic properties (SMPs), and crystallization behavior of the Fe<sub>84-x</sub>Co<sub>x</sub>Si<sub>2</sub>B<sub>9</sub>P<sub>3</sub>C<sub>0.5</sub>Cu<sub>1.5</sub> (x = 0–20) nanocrystalline alloys (NAs). Research has found that rapid cooling ribbons form uneven gradient structures along the thickness direction due to the cooling rate of the wheel-side (WS) being greater than that of the free-side (FS), while the addition of Co enhances the GFA and weakens this gradient structure. Crystallization kinetics analysis shows that the nucleation and growth activation energy of the FS α-Fe(Co) crystal is higher than that of the WS, resulting in slower crystallization rate α-Fe(Co) crystals in the FS. Furthermore, Co addition leads to a more significant difference in crystallization rates between the FS and WS, thus resulting in a more uniform and finer NA nanostructure. Meanwhile, the addition of Co expands the crystallization window and inhibits the precipitation of compound phases. Finally, the NAs obtained by annealing at 480 °C for 10 min achieved excellent combination of high <em>B</em><sub>s</sub> (1.83–1.94 T) and low <em>H</em><sub>c</sub> (5–10 A/m), breaking through the trade-off between <em>B</em><sub>s</sub> and <em>H</em><sub>c</sub> in traditional soft magnetic materials. This study contributes to the understanding of the crystallization process of gradient non-uniform materials and provides guidance for the development of Fe-based NAs with high <em>B</em><sub>s</sub> and low <em>H</em><sub>c</sub>.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115108"},"PeriodicalIF":3.9,"publicationDate":"2026-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146026013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The dependence of vacuum gap breakdown voltage on field emission properties 真空隙击穿电压与场发射特性的关系
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.vacuum.2026.115107
S.A. Barengolts , Yu.I. Mamontov , I.V. Uimanov , Yu.A. Zemskov
The dielectric strength of high-voltage vacuum gaps is a critical issue in the development and operation of high-power electrophysical devices. It is well known that the onset of a significant field-emission current from the vacuum gap cathode precedes vacuum breakdown. In this study, we investigate the correlation between the static vacuum breakdown voltage and the cathode's field emission properties. We examined a pure copper cathode with dimensions on the order of tens of micrometers. A series of sequential field-emission current-voltage measurements and vacuum breakdown tests were conducted. Additionally, the field-emission orthodoxy factor was calculated. For different cathode surface states, we obtained sets of local electric field enhancement factors, β, emission orthodoxy factors, and breakdown voltages. Assuming a specific breakdown electric field strength and using the determined β values, we estimated breakdown voltage values and compared these with experimentally measured ones. Our analysis revealed that within a particular range of the field-emission orthodoxy factor, the corresponding β values allowed the estimation of the breakdown voltage with approximately 10 % error. These results suggest that it is possible to develop an approach for predicting static vacuum breakdown voltage based solely on the field emission properties of the cathode.
高压真空间隙的介电强度是大功率电物理器件研制和运行中的一个关键问题。众所周知,真空间隙阴极的场发射电流在真空击穿之前就开始了。在本研究中,我们研究了静态真空击穿电压与阴极场发射特性的关系。我们检查了一个纯铜阴极,其尺寸约为几十微米。进行了一系列连续场发射电流电压测量和真空击穿试验。此外,还计算了场发射正统系数。对于不同的阴极表面状态,我们得到了一组局域电场增强因子、β、发射正统因子和击穿电压。假设一个特定的击穿电场强度,并使用确定的β值,我们估计击穿电压值,并将其与实验测量值进行比较。我们的分析表明,在场发射正统系数的特定范围内,相应的β值允许击穿电压的估计误差约为10%。这些结果表明,有可能开发一种仅基于阴极场发射特性来预测静态真空击穿电压的方法。
{"title":"The dependence of vacuum gap breakdown voltage on field emission properties","authors":"S.A. Barengolts ,&nbsp;Yu.I. Mamontov ,&nbsp;I.V. Uimanov ,&nbsp;Yu.A. Zemskov","doi":"10.1016/j.vacuum.2026.115107","DOIUrl":"10.1016/j.vacuum.2026.115107","url":null,"abstract":"<div><div>The dielectric strength of high-voltage vacuum gaps is a critical issue in the development and operation of high-power electrophysical devices. It is well known that the onset of a significant field-emission current from the vacuum gap cathode precedes vacuum breakdown. In this study, we investigate the correlation between the static vacuum breakdown voltage and the cathode's field emission properties. We examined a pure copper cathode with dimensions on the order of tens of micrometers. A series of sequential field-emission current-voltage measurements and vacuum breakdown tests were conducted. Additionally, the field-emission orthodoxy factor was calculated. For different cathode surface states, we obtained sets of local electric field enhancement factors, <em>β</em>, emission orthodoxy factors, and breakdown voltages. Assuming a specific breakdown electric field strength and using the determined <em>β</em> values, we estimated breakdown voltage values and compared these with experimentally measured ones. Our analysis revealed that within a particular range of the field-emission orthodoxy factor, the corresponding <em>β</em> values allowed the estimation of the breakdown voltage with approximately 10 % error. These results suggest that it is possible to develop an approach for predicting static vacuum breakdown voltage based solely on the field emission properties of the cathode.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115107"},"PeriodicalIF":3.9,"publicationDate":"2026-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146080121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Vacuum
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