Waste management最新文献_第5页

Comparative study on pyrolysis characteristics of common fractions from real municipal solid waste using Py-GC/MS and principal component analysis 应用Py-GC/MS和主成分分析对真实城市生活垃圾中常见馏分热解特性进行对比研究

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-13 DOI: 10.1016/j.wasman.2026.115348

Rui Zhang , Wenxi Zhao , Hiroki Harada , Masaki Takaoka

Efficient thermal conversion of municipal solid waste (MSW) requires a mechanistic understanding of real, heterogeneous waste, yet most mechanistic studies rely on simplified or simulated MSW, leaving the molecular-level impacts of real heterogeneity insufficiently understood. This study aims to systematically characterize pyrolysis of real MSW fractions and evaluate the influence of sample- and temporal-scale heterogeneity. Two MSW samples were collected from an incineration plant on the same day (morning vs. afternoon), classified and cryogenically milled to assess achievable laboratory homogeneity and temporal heterogeneity. Pyrolysis gas chromatography–mass spectrometry (Py-GC/MS) was conducted based on thermogravimetric profiles. Principal component analysis (PCA) was applied on the results to jointly distinguish MSW fractions and quantify heterogeneity effect via distances in principal-component space. PCA revealed a distance pattern of technical replicates < inter-batch < inter-fraction, confirming sufficient homogenization by cryogenic milling and detectable temporal variability in real MSW. Real MSW predominantly produced hydroxyacetaldehyde and levoglucosan from biomass-based fractions (Paper, Cloth, Wood, Kitchen Waste) and styrene from Resin. These differed from those reported for simulated MSW, e.g., acetic acid (sawdust), D-allose (cotton clothes), acetic acid (vegetables), underscoring the importance of using real MSW in mechanistic investigations. Increasing temperature shifted biomass volatiles from anhydrosugars toward carbonyls and gases, while Resin evolved from benzene and straight-chain compounds to cyclic species. The PCA-based distance framework in this study provides a methodological approach for quantifying heterogeneity, assessing representativeness, and improving the reliability of lab micro-scale analyses of real MSW.

城市固体废物（MSW）的有效热转化需要对真实的、非均质废物的机理理解，然而大多数机理研究依赖于简化或模拟的城市固体废物，而对真实非均质废物的分子水平影响了解不足。本研究旨在系统表征真实生活垃圾馏分的热解过程，并评估样品和时间尺度非均质性对热解过程的影响。在同一天（上午和下午）从焚烧厂收集了两个生活垃圾样本，进行分类和低温研磨，以评估可实现的实验室同质性和时间异质性。基于热重谱进行热解气相色谱-质谱分析（Py-GC/MS）。应用主成分分析（PCA）对结果进行联合区分，并通过主成分空间的距离量化异质性效应。PCA揭示了技术重复的距离模式&批次间&组分间，证实了低温碾磨的充分均质化和真实生活垃圾中可检测的时间变化。真正的城市生活垃圾主要从生物质组分（纸、布、木材、厨房垃圾）和树脂中产生羟乙醛和左旋葡聚糖。这些不同于模拟城市生活垃圾的报道，例如醋酸（锯末），D-allose（棉衣），醋酸（蔬菜），强调了在机理研究中使用真实城市生活垃圾的重要性。升高的温度使生物质挥发物从无水糖转向羰基和气体，而树脂则从苯和直链化合物进化为环状物质。本研究中基于pca的距离框架为量化异质性、评估代表性和提高真实城市生活垃圾实验室微观分析的可靠性提供了一种方法学方法。

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引用次数: 0

Urban waste management inequities in New York city: a case study on spatial patterns of controlled and uncontrolled street waste and their associated factors 纽约市城市废物管理的不平等：受控制和不受控制的街道废物空间格局及其相关因素的案例研究

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-09 DOI: 10.1016/j.wasman.2026.115333

Siwei Zhang, Jun Ma

Comprehensive urban waste management systems, addressing municipal waste collection and construction waste disposal, are essential for maintaining livable and sustainable cities. Understanding the spatial distribution patterns of controlled and uncontrolled waste, along with their underlying environmental and socioeconomic determinants, is essential for developing more effective urban waste management strategies. However, comprehensive analysis of street-level waste distribution and its relationship with socioeconomic factors remains limited, particularly regarding environmental justice implications. This study developed a computer vision approach to detect controlled and uncontrolled waste in New York City and analyzed their spatial distribution patterns to examine associations with urban environmental and socioeconomic characteristics. We employed Swin Transformer architecture for automated waste detection from street-view imagery. Spatial analysis, logistic regression, and interpretable machine learning using SHAP (SHapley Additive exPlanations) were applied to analyze 43 variables across environmental and socioeconomic factors. Results revealed contrasting distribution profiles where controlled waste concentrated in high-density, well-developed areas with higher education levels, while uncontrolled waste exhibited dual marginalization in urban peripheries and socioeconomically disadvantaged communities. Hispanic populations showed 14.9 % higher odds of uncontrolled waste exposure (OR = 1.149, p = 0.032), confirming environmental justice concerns. This research provides the first comprehensive quantitative evidence of street-level waste inequality, revealing significant spatial and social disparities that support targeted policy interventions through data-driven hotspot identification for vulnerable communities in urban waste management systems.

解决城市废物收集和建筑废物处理问题的综合城市废物管理系统对于维持宜居和可持续城市至关重要。了解控制和不控制废物的空间分布模式，以及其潜在的环境和社会经济决定因素，对于制定更有效的城市废物管理战略至关重要。然而，对街道垃圾分布及其与社会经济因素的关系的综合分析仍然有限，特别是对环境正义的影响。本研究开发了一种计算机视觉方法来检测纽约市的受控和非受控废物，并分析其空间分布模式，以研究其与城市环境和社会经济特征的关系。我们使用Swin Transformer架构从街景图像中自动检测垃圾。空间分析、逻辑回归和使用SHapley加性解释（SHapley Additive explanation）的可解释机器学习应用于分析环境和社会经济因素中的43个变量。结果显示，受控制的垃圾集中在高密度、经济发达、教育水平较高的地区，而不受控制的垃圾则在城市边缘和社会经济条件较差的社区呈现双重边缘化。西班牙裔人群未受控制的废物暴露的几率高出14.9% (OR = 1.149, p = 0.032)，证实了对环境正义的关注。该研究首次提供了街头垃圾不平等的综合定量证据，揭示了显著的空间和社会差异，通过数据驱动的城市垃圾管理系统中脆弱社区的热点识别，为有针对性的政策干预提供了支持。

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引用次数: 0

Effect of seasonal variability on aerobic biostabilisation kinetics of mechanically pre-treated organic fraction municipal solid waste 季节变化对机械预处理有机部分城市生活垃圾好氧生物稳定动力学的影响

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-08 DOI: 10.1016/j.wasman.2026.115336

Vladimir Mironov , Egor Barvashov , Shenghua Zhang , Sofia Telegina , Ang Li

This study investigates how seasonal variations in the composition and properties of the mechanically sorted organic fraction of municipal solid waste (ms-OFMSW) affect the rate of aerobic biostabilisation. A one-year study, monthly samples of raw ms-OFMSW were taken from a full-scale mechanical–biological treatment plant and tested for morphological composition, physicochemical parameters, and respiratory activity under conditions of 14-day pilot-scale biostabilisation process. Results showed that a maximum microbial activity estimated from an oxygen uptake rate of 1381 ± 164 mg O₂ kg⁻¹ DM h⁻¹ and heat emission of 8609 ± 1370 J kg⁻¹ h⁻¹, was observed within the first 10 ± 2h at 39.8 ± 0.8 °C. In spring and summer, the rate of biodegradation decreased by more than half due to low pH (5.3–5.5) and a high proportion of paper and fine fractions, which led to the accumulation of thermal energy (up to 146.8 kJ kg⁻¹) and a decrease in oxygen uptake (up to 33.7 g O₂ kg⁻¹). In contrast, higher shares of yard waste in autumn (23.2 %) and food waste in winter (29.9 %) created favorable conditions with moderate pH (5.7–6.1), temperatures of 62–68 °C, and elevated oxygen uptake (77.8–90.1 g O₂ kg⁻¹). These findings highlight the importance of operational control of the properties of raw ms-OFMSW for the possibility of predicting biostabilisation and developing methods for adaptive process control.

本研究探讨了城市固体废物（ms-OFMSW）机械分类有机组分的组成和性质的季节变化如何影响好氧生物稳定速率。在为期一年的研究中，研究人员每月从一个大型机械生物处理厂采集原始ms-OFMSW样品，并在为期14天的中试生物稳定过程中测试其形态组成、理化参数和呼吸活动。结果表明，在39.8±0.8°C温度下，前10±2h内微生物活性最高，吸氧速率为1381±164 mg O2 kg−1 DM h−1，放热速率为8609±1370 J kg−1 h−1。在春季和夏季，由于pH值较低（5.3-5.5），纸和细组分的比例较高，生物降解率下降了一半以上，导致热能积累（高达146.8 kJ kg - 1）和氧气吸收减少（高达33.7 g O2 kg - 1）。相比之下，秋季院子垃圾（23.2%）和冬季食物垃圾（29.9%）的比例较高，为pH（5.7-6.1）适中、温度为62-68°C、氧气吸吸量（77.8-90.1 g O2 kg−1）升高创造了有利条件。这些发现强调了对原料ms-OFMSW性能的操作控制对于预测生物稳定性和开发自适应过程控制方法的重要性。

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引用次数: 0

Recovery of diverse solid wastes into porous materials via thermal processing: Review of melt structure, processing parameter, and application 各种固体废物通过热加工回收成多孔材料：熔体结构、加工参数和应用综述

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-08 DOI: 10.1016/j.wasman.2026.115343

Weiyi Ji , Yifan Zhou , Jian-Xin Lu , Christopher Cheeseman , Chi-Sun Poon

Converting multiple solid wastes into sustainable porous materials via thermal processing is a practical approach to beneficially recycling waste and reducing landfill burden. The resulting value-added products have great potential as insulation and lightweight materials for construction purposes. The properties of these waste-based porous materials (WBPM) are mainly determined by the thermal process, specifically the high-temperature matrix properties and the gas evolution process. This review provides insights into the key factors affecting the melt structure of the matrix and the gas, from the perspective of the composition of starting materials, thermal treatment conditions, and additives. In particular, the effects of the main oxide components constituting solid waste on the melt structure and crystallisation are analysed. The conventional and novel applications of WBPM are summarised and discussed. These insights provide significant information for facilitating the highly efficient utilisation of solid wastes into value-added porous materials on a large scale.

通过热处理将多种固体废物转化为可持续多孔材料是有效回收废物和减少垃圾填埋负担的可行方法。由此产生的增值产品作为建筑用途的绝缘和轻质材料具有很大的潜力。这些废物基多孔材料（WBPM）的性能主要取决于热过程，特别是高温基体性能和气体释放过程。本文从原料组成、热处理条件和添加剂等方面综述了影响基体和气体熔体结构的关键因素。特别分析了构成固体废物的主要氧化物组分对熔体结构和结晶的影响。总结和讨论了WBPM的传统应用和新应用。这些见解为促进固体废物大规模高效利用成增值多孔材料提供了重要信息。

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引用次数: 0

Synergistic electrochemical multi-resources recovery from spent LiFePO4 and etching solvents 废LiFePO4和蚀刻溶剂的协同电化学多资源回收

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-08 DOI: 10.1016/j.wasman.2026.115338

Wei Jin , Chaoqi Wang , Feilong Zhang

The recycling of spent lithium (Li)-ion batteries (LFP) is crucial for resource sustainability and environmental protection. Conventional hydrometallurgical processes often require the addition of external strong oxidizing agents and elevated temperatures to achieve satisfactory metal leaching, presenting both economic and environmental challenges. This study proposes an innovative and sustainable “waste-to-wealth” strategy for the simultaneous recovery of valuable metals from spent LFP cathodes and copper (Cu) from etching waste liquid. The core of this strategy is an integrated “three-birds-with-one-stone” separation technology combining electrochemical oxidation and deposition. Without requiring external oxidants, chloride ions naturally present in the etching wastewater are electrochemically oxidized in situ at a Ru-Ir-Ti anode to generate active chlorine species, which effectively destroy the LFP crystal structure for Li extraction. Simultaneously, Cu ions are directly electrodeposited onto the cathode as metallic Cu powder. Under optimal conditions (0.2 M HCl, 120 min), leaching efficiencies of 100 % for Li and 73.3 % for Fe were achieved, along with a Cu deposition efficiency of 99.6 %. Subsequent selective precipitation yielded high-purity, battery-grade Li₃PO₄ (99.5 % purity). Mechanistic studies confirmed that active chlorine species are the primary contributors to the highly efficient Li leaching. This novel process eliminates the need for external oxidants and heating, offering a greener, more cost-effective, and streamlined alternative for the coordinated recovery of spent batteries and heavy-metal-containing wastewater, demonstrating significant potential for practical application within a circular economy framework.

废旧锂离子电池的回收利用对资源可持续性和环境保护具有重要意义。传统的湿法冶金工艺通常需要添加外部强氧化剂和提高温度才能达到令人满意的金属浸出，这对经济和环境都提出了挑战。本研究提出了一种创新和可持续的“废物转化财富”战略，同时从废LFP阴极和蚀刻废液中回收有价金属和铜（Cu）。该战略的核心是电化学氧化与沉积相结合的一体化“三鸟一石”分离技术。在不需要外部氧化剂的情况下，蚀刻废水中天然存在的氯离子在Ru-Ir-Ti阳极上原位电化学氧化，生成活性氯物质，有效破坏LFP晶体结构，用于Li提取。同时，铜离子以金属铜粉的形式直接电沉积在阴极上。在最佳条件下（0.2 M HCl, 120 min）， Li的浸出率为100%，Fe的浸出率为73.3%，Cu的沉积效率为99.6%。随后的选择性沉淀得到了高纯度的电池级Li3PO4（纯度为99.5%）。机理研究证实，活性氯是高效锂浸出的主要贡献者。这种新工艺消除了外部氧化剂和加热的需要，为废旧电池和含重金属废水的协调回收提供了一种更环保、更具成本效益和精简的替代方案，在循环经济框架内展示了巨大的实际应用潜力。

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引用次数: 0

Catalytic upcycling of waste polystyrene plastics into production of fuels and chemicals: A review 废聚苯乙烯塑料催化升级回收用于燃料和化工产品的研究进展

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-08 DOI: 10.1016/j.wasman.2026.115344

Yuanxing Pu , Xuefeng Hu , Huixian Du

Polystyrene (PS), one of the world’s most widely produced plastics, generates significant white pollution due to its non-biodegradable nature. However, these waste materials contain abundant carbon resources that can serve as raw materials for producing high-value products, making it necessary to convert them into valuable chemicals. Catalytic upcycling and recycling technologies achieve this by selectively breaking and recombining chemical bonds, thereby efficiently converting waste PS into valuable chemical products like styrene monomers, aromatics and fuels. This represents one of the core pathways to achieve a “plastic circular economy.” This paper reviews recent research progress in novel catalytic technologies (e.g., thermal catalysis, photocatalysis, and electrocatalysis) for PS recycling, with particular emphasis on elucidating reaction mechanisms, reaction processes, and product-directed control mechanisms. Finally, it discusses the application prospects and future development trends of plastic catalytic upgrading technologies, providing valuable insights for achieving a sustainable plastic circular economy. This review offers a systematic perspective on technological breakthroughs in the catalytic recycling of waste PS, aiming to lay the foundation for the recyclability and long-term sustainable production of PS.

聚苯乙烯（PS）是世界上生产最广泛的塑料之一，由于其不可生物降解的性质，产生了严重的白色污染。然而，这些废物中含有丰富的碳资源，可以作为生产高价值产品的原材料，因此有必要将其转化为有价值的化学品。催化升级和回收技术通过选择性地破坏和重组化学键来实现这一目标，从而有效地将废弃PS转化为有价值的化学产品，如苯乙烯单体、芳烃和燃料。这是实现“塑料循环经济”的核心途径之一。本文综述了近年来新型催化技术（如热催化、光催化和电催化）在PS回收中的研究进展，重点阐述了反应机理、反应过程和产物导向控制机制。最后讨论了塑料催化升级技术的应用前景和未来发展趋势，为实现可持续的塑料循环经济提供了有价值的见解。本文综述了废PS催化回收的技术突破，旨在为PS的可回收性和长期可持续生产奠定基础。

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引用次数: 0

Recovery of multiple polyol grades from complex flexible polyurethane foams by depolymerization with alkanolamines 用烷醇胺解聚法从复合柔性聚氨酯泡沫中回收多个多元醇等级

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-08 DOI: 10.1016/j.wasman.2026.115340

Zoë De Herdt , Muhammad Adeel , Lukasz Pazdur , Matthew Porters , Victor Beeckmans , Jonas Cassimon , Christophe M.L. Vande Velde , Pieter Billen

The chemical recycling of polyurethane (PU) foams is limited by their chemical complexity, especially in multi-polyol formulations, resulting in low recovery rates of high-value products. This study presents a novel chemical depolymerization approach using diethanolamine (DEA) to achieve three-phase separation and maximize recovery of aromatic amines derived from isocyanates. Reaction parameters including temperature, reaction time, and DEA:PU ratio were evaluated, identifying optimal conditions (240 °C, 30 min, DEA:PU 2:1 by mass) that consistently produced a clear three-phase separation and yielded methylenedianiline (MDA) at 89 % of the theoretical maximum. Layer analysis revealed a distinct component distribution: the top and middle phases contained mainly polyols (82.7 % Polyol 1, 87.4 % Polyol 2, respectively), while the bottom phase was predominantly MDA and unreacted DEA. Urea-containing intermediates formed under milder conditions, gradually decomposing into aromatic amines under extended reaction times, revealed aminolysis as the dominant reaction pathway. The method was successfully applied to MDI- and TDI-based foams, with up to five polyols, and to mixed foams, demonstrating robustness and versatility. A predictive test, mixing polyols and cleaving agents at room temperature, reliably indicated the feasibility of three-phase separation even before depolymerization. Testing other cleaving agents showed that alkanolamines with primary or secondary amines, such as 2-aminoethanol, can also induce three-phase separation. The potential of other amines requires further investigation for optimized and efficient macroscopic phase separation.

聚氨酯（PU）泡沫的化学回收受到其化学复杂性的限制，特别是在多多元醇配方中，导致高价值产品的回收率低。本研究提出了一种新的化学解聚方法，利用二乙醇胺（DEA）实现三相分离，最大限度地回收异氰酸酯衍生的芳香胺。对反应参数包括温度、反应时间和DEA:PU比进行了评估，确定了最佳条件（240°C, 30 min， DEA:PU 2:1质量比），该条件始终能产生清晰的三相分离，并以理论最大值的89%产亚甲二苯胺（MDA）。层析结果表明，组分分布明显，顶相和中间相以多元醇为主（多元醇1占82.7%，多元醇2占87.4%），底相以MDA和未反应的DEA为主。含尿素中间体在较温和的条件下形成，在较长的反应时间下逐渐分解为芳香胺，表明氨解是主要的反应途径。该方法已成功应用于MDI和tdi基泡沫（含多达5种多元醇）以及混合泡沫，证明了其稳健性和通用性。在室温下混合多元醇和裂解剂的预测试验可靠地表明，在解聚之前就可以进行三相分离。对其他裂解剂的测试表明，烷醇胺与伯胺或仲胺，如2-氨基乙醇，也可以诱导三相分离。其他胺的潜力需要进一步研究，以优化和有效的宏观相分离。

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引用次数: 0

Sustainable discharge of lithium-ion batteries using coconut water: a natural alternative to chloride-based electrolytes 使用椰子水的锂离子电池可持续放电：氯基电解质的天然替代品

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-08 DOI: 10.1016/j.wasman.2025.115321

Helton Rogger Regatieri, Hugo Ferreira dos Santos, Ruan Vinícius Rocha Damaceno, Henrique Cesar Linhares Almeida, José Ricardo Cezar Salgado

The neutralization of lithium-ion batteries (LIBs) prior to recycling is a crucial safety step to avoid short circuits, thermal runaway, or toxic emissions. Conventional protocols commonly rely on chloride-based aqueous solutions, such as NaCl or KCl, which accelerate discharge due to their high ionic conductivity. However, these electrolytes present risks associated with corrosion and environmental contamination. In this study, coconut water as a natural and biodegradable alternative for discharging LIBs has been investigated. Aqueous solutions of NaCl and KCl (1.0–3.0 mol L⁻¹), as well as commercial coconut water, both within and beyond expiration dates, were evaluated under controlled laboratory conditions. Coconut water demonstrated slower yet stable discharge behavior, achieving complete battery neutralization within 28 h, with no evidence of casing corrosion. Its ionic content, primarily K⁺, was sufficient to support low-risk, long-duration discharge processes. Additionally, expired coconut water performed similarly to non-expired samples, indicating suitability for repurposing food-grade waste. This work highlights coconut water as a cost-effective and sustainable alternative to synthetic electrolytes in decentralized recycling workflows, aligning with circular economy principles and reducing the environmental burden of battery end-of-life management.

锂离子电池（lib）在回收前的中和是避免短路、热失控或有毒物质排放的关键安全步骤。传统的方案通常依赖于氯基水溶液，如NaCl或KCl，由于其高离子导电性，可以加速放电。然而，这些电解质存在与腐蚀和环境污染相关的风险。在本研究中，研究了椰子水作为一种天然的、可生物降解的锂离子电池的替代排放物。在受控的实验室条件下，对NaCl和KCl （1.0-3.0 mol L−1）的水溶液以及过期和过期的商业椰子水进行了评估。椰子水表现出较慢但稳定的放电行为，在28小时内完全中和电池，没有证据表明套管腐蚀。其离子含量，主要是K+，足以支持低风险，长时间的放电过程。此外，过期的椰子水的表现与未过期的样品相似，表明重新利用食品级废物的适用性。这项工作强调，在分散的回收工作流程中，椰子水是合成电解质的一种具有成本效益和可持续的替代品，符合循环经济原则，减少了电池报废管理的环境负担。

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引用次数: 0

Carbon footprint of coke-making in Europe and the cost-effectiveness of plant design: Optimization by using alternative reductants 欧洲焦炭生产的碳足迹和工厂设计的成本效益：通过使用替代还原剂进行优化

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-07 DOI: 10.1016/j.wasman.2026.115346

Mario Ávila , Sofie Verbrugge , Inge Bellemans , Kim Verbeken

This study evaluates the potential of partially replacing coking coal—a critical raw material—with solid recovered fuel (SRF) pellets made from non-recyclable waste plastics. Total CO₂ emissions and gross profit (GP) from metallurgical coke production in 2019, 2022, and 2023 were assessed across nine plant configurations under two scenarios: the Benchmark Scenario (BS) using only coking coal, and the AlterCoal Scenario (AS) replacing 2 wt% of the coking coal by SRF pellets. Results show indirect and total emissions in the AS decreased by 5.7 % and 6.4 %, respectively. Higher pellet density increased GP, though with a minor rise in emissions. Additionally, a linear correlation was found between GP and oven pushes: plants with fewer daily pushes—due to larger ovens—achieved greater profitability and GP per ton of direct CO₂ emitted. These results provide guidelines for steel plants considering this process, thereby contributing to the broader goal of emission reduction.

这项研究评估了用不可回收的废塑料制成的固体回收燃料（SRF）颗粒部分替代焦煤（一种关键原料）的潜力。在两种情景下，对2019年、2022年和2023年冶金焦炭生产的总二氧化碳排放量和毛利润（GP）进行了评估：基准情景（BS）仅使用炼焦煤，以及替代煤炭情景（AS）用SRF颗粒替代2%的炼焦煤。结果表明，AS的间接排放量和总排放量分别下降了5.7%和6.4%。更高的颗粒密度增加了GP，尽管排放量略有增加。此外，在GP和烘箱推力之间发现了线性相关性：由于烘箱较大，每天推力较少的工厂获得了更高的盈利能力和每吨直接二氧化碳排放的GP。这些结果为考虑这一过程的钢铁厂提供了指导方针，从而有助于实现更广泛的减排目标。

引用次数: 0

Spent LiFePO4 batteries valorization: integrated process for battery-grade FePO4 production 废LiFePO4电池增值：电池级FePO4生产的集成工艺

IF 7.1 2区环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL

Waste management

Pub Date : 2026-01-07 DOI: 10.1016/j.wasman.2026.115335

Jiawei Du, Jialin Qing, Guiqing Zhang, Zuoying Cao, Qinggang Li, Mingyu Wang, Wenjuan Guan, Shengxi Wu, Xinsheng Wu

To address the long-standing challenges in recycling spent LiFePO₄ batteries, this study proposes an integrated process. Alkaline pressure leaching enables selective Li extraction, while simultaneously removing Al to achieve deep Fe-Al separation; P and Fe are enriched in the residues. Subsequent H₂SO₄ leaching attains 99.2 % P and 94.8 % Fe extraction efficiency, with Ca transformed into construction-grade CaSO₄·2H₂O. TBP and Lix984 facilitate > 99 % removal of F and Cu via multi-stage extraction, resulting in raffinate with F/Cu concentrations < 2 mg/L. Finally, H₂O₂ at 3times the theoretical dosage oxidizes Fe²⁺, and crystallization yields battery-grade FePO₄. The full-process recovery efficiencies of Li, Fe, and P were 97.88 %, 92.91 %, and 95.49 %. This process enables full-element recovery and exhibits good suitability for industrial-scale application.

为了解决废旧LiFePO4电池回收的长期挑战，本研究提出了一种综合工艺。碱压浸可选择性提取Li，同时去除Al，实现Fe-Al深度分离；磷和铁在残留物中富集。后续H2SO4浸出P和Fe的提取率分别为99.2%和94.8%，Ca转化为建筑级CaSO4·2H2O。通过多级萃取，TBP和Lix984对F和Cu的去除率达到99%，得到F/Cu浓度为2mg /L的萃余液。最后，以3倍理论用量的H2O2氧化Fe2+，结晶生成电池级FePO4。Li、Fe、P的全流程回收率分别为97.88%、92.91%、95.49%。该工艺能够实现全元素回收，并表现出良好的工业规模应用适用性。

引用次数: 0