首页 > 最新文献

Atmospheric Environment最新文献

英文 中文
Dust trace metals implications on school’s indoor air quality linked to human health risk at Khurianwala (Pakistan) 微量金属粉尘对 Khurianwala(巴基斯坦)学校室内空气质量的影响与人类健康风险有关
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-28 DOI: 10.1016/j.atmosenv.2024.120889
Muhammad Hassan Bashir , Atiq ur Rehman , Hamaad Raza Ahmad , Amor Hedfi , Manel Ben Ali , Fehmi Boufahja , Khaled Elmnasri , Ezzeddine Mahmoudi , Muhammad Tahir Shehzad
In an environment, trace metals (TMs) are characterized by high density and potential toxicity. Airborne dust particles distribute TMs in the environment including educational institutes that enters the human body and cause severe health issues. Therefore, this research aimed at quantifying the concentration of cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) present in classroom dust and determine associated health risk through different environmental models by employing R-studio. Dust samples from 12 schools situated in rural and urban areas and close to the industrial zones in Khurrianwala, Faisalabad were analyzed on atomic absorption spectrophotometer. The results showed that the dust samples contained Cd, Cu, Ni, Pb, and Zn in ranges of 0.02–2.5, 2.5–24.3, 5.4–41.5, 3.6–55.8, and 5.8–146.7 mg kg−1, respectively. The geo-accumulation index indicated that dust samples were contaminated with Cd and Pb. The contamination factor revealed that Ni and Cu contamination was minimal in all schools, while Cd and Pb showed moderate to high contamination at each school. Excluding rural regions, the pollution load index was high in industrial zone and urban regions. The hazard quotient indicated a little chance of non-carcinogenic risk in children from dust ingestion. The non-carcinogenic health hazard range (HI < 1) and the total cancer risk range (10−6 < TCR ≤10−4) were inferior for cancer-causing in adults and children, respectively. Findings of the study suggested that assessing the health risk caused by TMs contaminated dust in the school environment is essential to avoid any health complications in adults and children.
环境中的痕量金属(TMs)具有高密度和潜在毒性的特点。空气中的尘埃微粒会在包括教育机构在内的环境中散发微量金属,进入人体后会导致严重的健康问题。因此,本研究旨在利用 R-studio 软件,通过不同的环境模型,量化教室灰尘中的镉(Cd)、铜(Cu)、镍(Ni)、铅(Pb)和锌(Zn)的浓度,并确定相关的健康风险。研究人员用原子吸收分光光度计分析了来自费萨拉巴德 Khurrianwala 城乡地区和工业区附近 12 所学校的粉尘样本。结果显示,粉尘样本中的镉、铜、镍、铅和锌的含量范围分别为 0.02-2.5、2.5-24.3、5.4-41.5、3.6-55.8 和 5.8-146.7 毫克/千克。地质累积指数表明,灰尘样本受到了镉和铅的污染。污染因子显示,镍和铜在所有学校的污染程度都很轻微,而镉和铅在每所学校都显示出中度到高度污染。除农村地区外,工业区和城市地区的污染负荷指数较高。危害商数表明,儿童因摄入粉尘而产生非致癌风险的几率很小。成人和儿童的非致癌健康危害范围(HI <1)和总致癌风险范围(10-6 <TCR≤10-4)分别低于致癌健康危害范围(HI <1)和总致癌风险范围(10-6 <TCR≤10-4)。研究结果表明,要避免成人和儿童的健康出现任何并发症,评估学校环境中受三卤甲烷污染的粉尘所造成的健康风险至关重要。
{"title":"Dust trace metals implications on school’s indoor air quality linked to human health risk at Khurianwala (Pakistan)","authors":"Muhammad Hassan Bashir ,&nbsp;Atiq ur Rehman ,&nbsp;Hamaad Raza Ahmad ,&nbsp;Amor Hedfi ,&nbsp;Manel Ben Ali ,&nbsp;Fehmi Boufahja ,&nbsp;Khaled Elmnasri ,&nbsp;Ezzeddine Mahmoudi ,&nbsp;Muhammad Tahir Shehzad","doi":"10.1016/j.atmosenv.2024.120889","DOIUrl":"10.1016/j.atmosenv.2024.120889","url":null,"abstract":"<div><div>In an environment, trace metals (TMs) are characterized by high density and potential toxicity. Airborne dust particles distribute TMs in the environment including educational institutes that enters the human body and cause severe health issues. Therefore, this research aimed at quantifying the concentration of cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) present in classroom dust and determine associated health risk through different environmental models by employing R-studio. Dust samples from 12 schools situated in rural and urban areas and close to the industrial zones in Khurrianwala, Faisalabad were analyzed on atomic absorption spectrophotometer. The results showed that the dust samples contained Cd, Cu, Ni, Pb, and Zn in ranges of 0.02–2.5, 2.5–24.3, 5.4–41.5, 3.6–55.8, and 5.8–146.7 mg kg<sup>−1</sup>, respectively. The geo-accumulation index indicated that dust samples were contaminated with Cd and Pb. The contamination factor revealed that Ni and Cu contamination was minimal in all schools, while Cd and Pb showed moderate to high contamination at each school. Excluding rural regions, the pollution load index was high in industrial zone and urban regions. The hazard quotient indicated a little chance of non-carcinogenic risk in children from dust ingestion. The non-carcinogenic health hazard range (HI &lt; 1) and the total cancer risk range (10<sup>−6</sup> &lt; TCR ≤10<sup>−4</sup>) were inferior for cancer-causing in adults and children, respectively. Findings of the study suggested that assessing the health risk caused by TMs contaminated dust in the school environment is essential to avoid any health complications in adults and children.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"339 ","pages":"Article 120889"},"PeriodicalIF":4.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142540148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating and comparison of WRF-chem model configurations for wind field impact on the April 2022 dust episode in western Iran 评估和比较 WRF-化学模型配置对伊朗西部 2022 年 4 月沙尘暴的风场影响
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-28 DOI: 10.1016/j.atmosenv.2024.120892
Elham Mobarak Hassan , Mahnaz Karimkhani , Jeff Sepehri (Jafar)
Accurate estimation of wind direction and speed is essential for enhancing the simulation and prediction of dust storms. Being highly susceptible to dust storms, Western Iran necessitates a detailed evaluation of dust concentration and wind fields. This study employs the WRF-Chem model to simulate these parameters over the period from April 7 to 26, 2022. Four different model configurations were tested, involving the Yonsei University (YSU) and Mellor-Yamada-Janjic (MYJ) boundary layer schemes, as well as the Lin and WRF Single-Moment 6-Class (WSM6) microphysics schemes. The results indicate that during the selected period, different synoptic systems led to the release of dust from Iraq and Saudi Arabia and its transport to western Iran. The mid-level southerly and southwesterly wind directions have a significant impact on dust transport to the northwestern regions of Iran by high and complex mountainous terrain. The horizontal and vertical distribution of simulated dust demonstrates good agreement with TERRA satellite imagery, MERRA-2 dust surface concentration, and CALIPSO, respectively. The daily dust concentration of the WRF-Chem model has a correlation of −0.32 to −0.96 with visibility and 0.68 to 0.86 with MERRA-2 data in Western Iran. The simulated dust concentration relation with visibility and AERONET AOD (Aerosol Optical Depth at 500 nm) was calculated at −0.78 and 0.29, respectively in Zanjan station. The horizontal and vertical distribution, temporal series, and statistical indices of the wind field show that the WRF-Chem model performs well in the Iran West boundary, especially in the west and northwest, where the 10-m wind speed increased to 14 m s−1. The boundary layer scheme in the WRF-Chem model has a more significant impact than the microphysics scheme in simulated 10-m wind speed and dust concentration. The final result shows that the combination of the YSU boundary layer and WSM6 microphysics schemes performs very well in simulating wind fields and dust in western Iran under various weather conditions.
风向和风速的精确估算对于加强沙尘暴的模拟和预测至关重要。伊朗西部极易受到沙尘暴的影响,因此有必要对沙尘浓度和风场进行详细评估。本研究利用 WRF-Chem 模型模拟了 2022 年 4 月 7 日至 26 日期间的这些参数。测试了四种不同的模型配置,包括延世大学(YSU)和 Mellor-Yamada-Janjic (MYJ)边界层方案,以及 Lin 和 WRF 单瞬 6 级(WSM6)微物理方案。结果表明,在所选时段内,不同的同步系统导致沙尘从伊拉克和沙特阿拉伯释放并输送到伊朗西部。中层的南风和西南风风向对伊朗西北部地区的高山复杂地形的沙尘输送有显著影响。模拟沙尘的水平和垂直分布分别与 TERRA 卫星图像、MERRA-2 沙尘表面浓度和 CALIPSO 非常吻合。在伊朗西部,WRF-Chem 模型的日沙尘浓度与能见度的相关性为 -0.32 至 -0.96,与 MERRA-2 数据的相关性为 0.68 至 0.86。在赞詹站,模拟的沙尘浓度与能见度和 AERONET AOD(500 纳米气溶胶光学深度)的相关性分别为-0.78 和 0.29。风场的水平和垂直分布、时间序列和统计指数表明,WRF-Chem 模式在伊朗西部边界表现良好,特别是在西部和西北部,10 米风速增加到 14 米/秒。在模拟 10 米风速和沙尘浓度方面,WRF-Chem 模式中的边界层方案比微物理方案影响更大。最终结果表明,YSU 边界层和 WSM6 微物理方案的组合在模拟伊朗西部各种天气条件下的风场和沙尘时表现非常出色。
{"title":"Evaluating and comparison of WRF-chem model configurations for wind field impact on the April 2022 dust episode in western Iran","authors":"Elham Mobarak Hassan ,&nbsp;Mahnaz Karimkhani ,&nbsp;Jeff Sepehri (Jafar)","doi":"10.1016/j.atmosenv.2024.120892","DOIUrl":"10.1016/j.atmosenv.2024.120892","url":null,"abstract":"<div><div>Accurate estimation of wind direction and speed is essential for enhancing the simulation and prediction of dust storms. Being highly susceptible to dust storms, Western Iran necessitates a detailed evaluation of dust concentration and wind fields. This study employs the WRF-Chem model to simulate these parameters over the period from April 7 to 26, 2022. Four different model configurations were tested, involving the Yonsei University (YSU) and Mellor-Yamada-Janjic (MYJ) boundary layer schemes, as well as the Lin and WRF Single-Moment 6-Class (WSM6) microphysics schemes. The results indicate that during the selected period, different synoptic systems led to the release of dust from Iraq and Saudi Arabia and its transport to western Iran. The mid-level southerly and southwesterly wind directions have a significant impact on dust transport to the northwestern regions of Iran by high and complex mountainous terrain. The horizontal and vertical distribution of simulated dust demonstrates good agreement with TERRA satellite imagery, MERRA-2 dust surface concentration, and CALIPSO, respectively. The daily dust concentration of the WRF-Chem model has a correlation of −0.32 to −0.96 with visibility and 0.68 to 0.86 with MERRA-2 data in Western Iran. The simulated dust concentration relation with visibility and AERONET AOD (Aerosol Optical Depth at 500 nm) was calculated at −0.78 and 0.29, respectively in Zanjan station. The horizontal and vertical distribution, temporal series, and statistical indices of the wind field show that the WRF-Chem model performs well in the Iran West boundary, especially in the west and northwest, where the 10-m wind speed increased to 14 m s<sup>−1</sup>. The boundary layer scheme in the WRF-Chem model has a more significant impact than the microphysics scheme in simulated 10-m wind speed and dust concentration. The final result shows that the combination of the YSU boundary layer and WSM6 microphysics schemes performs very well in simulating wind fields and dust in western Iran under various weather conditions.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"340 ","pages":"Article 120892"},"PeriodicalIF":4.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142662939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Accelerated surface brightening in China: The decisive role of reduced anthropogenic aerosol emissions 中国地表加速变亮:人为气溶胶排放减少的决定性作用
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-28 DOI: 10.1016/j.atmosenv.2024.120893
Qixiang Chen , Chunlin Huang , Zhaohui Ruan , Ming Xu , Hongxia Li , Xinlei Han , Shikui Dong , Xing Yang
A profound comprehension of the key determinants behind the fluctuations in surface solar radiation (SSR) over decadal timescales is essential for advancing the fields of energy meteorology, climatology, and solar resources. While there is a general agreement among prior research on the significant impact of aerosols on SSR, a granular understanding of the specific influence that varying aerosol types exert on SSR remains elusive. This investigation delves into the respective impacts of aerosols and cloud radiative effects across China, utilizing data from the Clouds and the Earth's Radiant Energy System (CERES). It further dissects the distinct impacts of different aerosol types on the decadal-scale variations in SSR, employing spectral aerosol optical depths derived from the MODIS aerosol products. The findings reveal a predominantly positive trend in SSR, ranging from 1.5 to 2.5 W/m2/yr between the years 2011 and 2022 for the majority of China's regions. However, certain areas within Northeast and Western China exhibit a decline in SSR exceeding −1 W/m2/yr. Notably, in Eastern China, a downward trend in aerosol radiative effect is observed, with a pronounced reduction of approximately −2 W/m2/yr noted specifically during the summer in Northern China. The study infers that the reduction in urban industrial emissions and biomass burning aerosols is linked to the acceleration of the brightening phenomenon in China. Our results underscore that stringent regulation of anthropogenic emissions could yield dual benefits: environmental amelioration and an upsurge in solar resource. These insights merit serious contemplation in the formulation of future policy and decision-making frameworks.
深刻理解十年时间尺度上地表太阳辐射(SSR)波动背后的关键决定因素对于推动能源气象学、气候学和太阳能资源领域的发展至关重要。尽管之前的研究普遍认为气溶胶对 SSR 有重大影响,但对不同类型的气溶胶对 SSR 的具体影响仍缺乏深入了解。本研究利用云和地球辐射能量系统(CERES)的数据,深入研究了气溶胶和云辐射效应对中国各地的影响。利用 MODIS 气溶胶产品得出的光谱气溶胶光学深度,进一步剖析了不同类型气溶胶对 SSR 十年尺度变化的不同影响。研究结果表明,2011-2022年间,中国大部分地区的SSR呈正向变化趋势,范围在1.5-2.5 W/m2/yr之间。不过,东北和西部的某些地区 SSR 出现下降,降幅超过-1 W/m2/yr。值得注意的是,在华东地区,气溶胶辐射效应呈下降趋势,特别是在华北地区的夏季,气溶胶辐射效应明显下降,降幅约为-2 W/m2/yr。研究推断,城市工业排放和生物质燃烧气溶胶的减少与中国亮化现象的加速有关。我们的研究结果强调,严格控制人为排放可以产生双重效益:改善环境和增加太阳能资源。这些见解值得我们在制定未来政策和决策框架时认真思考。
{"title":"Accelerated surface brightening in China: The decisive role of reduced anthropogenic aerosol emissions","authors":"Qixiang Chen ,&nbsp;Chunlin Huang ,&nbsp;Zhaohui Ruan ,&nbsp;Ming Xu ,&nbsp;Hongxia Li ,&nbsp;Xinlei Han ,&nbsp;Shikui Dong ,&nbsp;Xing Yang","doi":"10.1016/j.atmosenv.2024.120893","DOIUrl":"10.1016/j.atmosenv.2024.120893","url":null,"abstract":"<div><div>A profound comprehension of the key determinants behind the fluctuations in surface solar radiation (SSR) over decadal timescales is essential for advancing the fields of energy meteorology, climatology, and solar resources. While there is a general agreement among prior research on the significant impact of aerosols on SSR, a granular understanding of the specific influence that varying aerosol types exert on SSR remains elusive. This investigation delves into the respective impacts of aerosols and cloud radiative effects across China, utilizing data from the Clouds and the Earth's Radiant Energy System (CERES). It further dissects the distinct impacts of different aerosol types on the decadal-scale variations in SSR, employing spectral aerosol optical depths derived from the MODIS aerosol products. The findings reveal a predominantly positive trend in SSR, ranging from 1.5 to 2.5 W/m<sup>2</sup>/yr between the years 2011 and 2022 for the majority of China's regions. However, certain areas within Northeast and Western China exhibit a decline in SSR exceeding −1 W/m<sup>2</sup>/yr. Notably, in Eastern China, a downward trend in aerosol radiative effect is observed, with a pronounced reduction of approximately −2 W/m<sup>2</sup>/yr noted specifically during the summer in Northern China. The study infers that the reduction in urban industrial emissions and biomass burning aerosols is linked to the acceleration of the brightening phenomenon in China. Our results underscore that stringent regulation of anthropogenic emissions could yield dual benefits: environmental amelioration and an upsurge in solar resource. These insights merit serious contemplation in the formulation of future policy and decision-making frameworks.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"340 ","pages":"Article 120893"},"PeriodicalIF":4.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Combined-phase source apportionment of ambient PM2.5, PAHs and VOCs from an industrialized environment: Consequences of photochemical initial concentrations 来自工业化环境的环境 PM2.5、多环芳烃和挥发性有机化合物的综合阶段源分配:光化学初始浓度的后果
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-26 DOI: 10.1016/j.atmosenv.2024.120894
Uwayemi M. Sofowote , Ewa Dabek-Zlotorzynska , Mahmoud M. Yassine , Dennis Mooibroek , May Siu , Valbona Celo , Philip K. Hopke
Air pollutants in the particulate (PM2.5 species, PAHs) and gaseous phases (VOCs) collected between 2013 and 2019 once every three or six days for a period of 24 hours in an industrialized city in Ontario were analyzed to apportion their common sources. The consequences of using these species jointly for receptor modelling were assessed via combined-phase source apportionment that used the data as is, and in a protocol that factored in the potential for photochemical losses of gas-phase species. Thus, photochemically corrected initial concentrations (PIC) were calculated. Analyses of the inputs followed either with positive matrix factorization or its dispersion-normalized variant (DN-PMF). Comparisons of applying PMF to the originally observed input data (BASE) and DN-PMF on data with PIC corrections were made. When the inputs consisted only of VOCs, three factors were resolved with BASE PMF: natural gas, vehicular emissions, and industrial emissions co-emitted with summertime gasoline evaporation. A fourth factor was obtained, representing reactive VOCs when DN-PIC PMF was used. When the combined phase input data were analyzed, nine factors were resolved for both BASE and DN-PIC PMF. These factors in order of diminishing average PM mass contributions were: particulate sulphate, secondary organic aerosol (SOA), particulate nitrate (pNO3), biomass burning with natural gas, crustal matter, winter blend of gasoline, coking/coal combustion, steelmaking, and summer blend/light duty vehicular emissions. When BASE and DN-PIC PMF results are compared, the average PM mass contribution of the summer gasoline fuel factor increased from 2% in BASE case to 5%, suggesting severe underestimation of this source's contributions without DN-PIC. Also, substantial increases of reactive VOCs in the SOA factor, and PAHs with ≥four rings in the pNO3 and steelmaking factors were observed with DN-PIC PMF compared to the BASE PMF case, indicating that for SOA, reactive VOCs at this location contributed to SOA sources.
分析了2013年至2019年期间在安大略省的一个工业化城市每隔3天或6天收集一次、持续24小时的颗粒物(PM2.5物种、多环芳烃)和气相(挥发性有机化合物)中的空气污染物,以分摊其共同来源。通过使用原数据的综合相源分配,以及考虑到气相物种光化学损失可能性的协议,评估了将这些物种联合用于受体建模的后果。因此,计算出了光化学校正初始浓度(PIC)。输入分析采用正矩阵因式分解法或其分散归一化变体(DN-PMF)。对最初观测到的输入数据(BASE)进行了正矩阵因式分解,并对经过 PIC 修正的数据进行了 DN-PMF 分析。当输入数据仅包括挥发性有机化合物时,BASE PMF 解决了三个因子:天然气、车辆排放和与夏季汽油蒸发共同排放的工业排放。使用 DN-PIC PMF 时,第四个因子代表反应性挥发性有机化合物。在分析综合阶段输入数据时,BASE 和 DN-PIC PMF 都解决了九个因子。这些因子按可吸入颗粒物平均质量贡献递减的顺序排列为:颗粒硫酸盐、二次有机气溶胶(SOA)、颗粒硝酸盐(pNO3)、生物质燃烧与天然气、地壳物质、冬季混合汽油、炼焦/燃煤、炼钢和夏季混合/轻型车辆排放。当比较基准和 DN-PIC PMF 结果时,夏季汽油燃料因子的平均 PM 质量贡献从基准情况下的 2% 增加到 5%,这表明在没有 DN-PIC 的情况下严重低估了这一来源的贡献。此外,与 BASE PMF 案例相比,DN-PIC PMF 观察到 SOA 因子中的活性 VOCs 以及 pNO3 和炼钢因子中≥四环的 PAHs 显著增加,表明对于 SOA 而言,该地点的活性 VOCs 是 SOA 的贡献源。
{"title":"Combined-phase source apportionment of ambient PM2.5, PAHs and VOCs from an industrialized environment: Consequences of photochemical initial concentrations","authors":"Uwayemi M. Sofowote ,&nbsp;Ewa Dabek-Zlotorzynska ,&nbsp;Mahmoud M. Yassine ,&nbsp;Dennis Mooibroek ,&nbsp;May Siu ,&nbsp;Valbona Celo ,&nbsp;Philip K. Hopke","doi":"10.1016/j.atmosenv.2024.120894","DOIUrl":"10.1016/j.atmosenv.2024.120894","url":null,"abstract":"<div><div>Air pollutants in the particulate (PM<sub>2.5</sub> species, PAHs) and gaseous phases (VOCs) collected between 2013 and 2019 once every three or six days for a period of 24 hours in an industrialized city in Ontario were analyzed to apportion their common sources. The consequences of using these species jointly for receptor modelling were assessed via combined-phase source apportionment that used the data <em>as is</em>, and in a protocol that factored in the potential for photochemical losses of gas-phase species. Thus, photochemically corrected initial concentrations (PIC) were calculated. Analyses of the inputs followed either with positive matrix factorization or its dispersion-normalized variant (DN-PMF). Comparisons of applying PMF to the originally observed input data (BASE) and DN-PMF on data with PIC corrections were made. When the inputs consisted only of VOCs, three factors were resolved with BASE PMF: natural gas, vehicular emissions, and industrial emissions co-emitted with summertime gasoline evaporation. A fourth factor was obtained, representing reactive VOCs when DN-PIC PMF was used. When the combined phase input data were analyzed, nine factors were resolved for both BASE and DN-PIC PMF. These factors in order of diminishing average PM mass contributions were: particulate sulphate, secondary organic aerosol (SOA), particulate nitrate (pNO3), biomass burning with natural gas, crustal matter, winter blend of gasoline, coking/coal combustion, steelmaking, and summer blend/light duty vehicular emissions. When BASE and DN-PIC PMF results are compared, the average PM mass contribution of the summer gasoline fuel factor increased from 2% in BASE case to 5%, suggesting severe underestimation of this source's contributions without DN-PIC. Also, substantial increases of reactive VOCs in the SOA factor, and PAHs with ≥four rings in the pNO3 and steelmaking factors were observed with DN-PIC PMF compared to the BASE PMF case, indicating that for SOA, reactive VOCs at this location contributed to SOA sources.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"340 ","pages":"Article 120894"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142560920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deciphering the key drivers of oxidative potential during ammonium nitrate-mediated aqueous-phase photoreaction of methoxyphenols 解读硝酸铵介导的甲氧基苯酚水相光反应过程中氧化潜能的关键驱动因素
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-26 DOI: 10.1016/j.atmosenv.2024.120895
Racliffe Weng Seng Lai , Tian Qiu , Xuyang Zhang , Yalin Wang , Tianwei Hao , Xinlei Ge , Lin Du , Mingjin Tang , Ka In Hoi , Kai Meng Mok , Yong Jie Li
Methoxyphenols are released in abundance from lignin pyrolysis during biomass burning. Apart from being atmospheric brown carbon components that absorb solar radiation and warm the climate, methoxyphenols also undergo photoreaction in the atmospheric aqueous phase and form secondary organic aerosols (aqSOA). While efforts have been devoted to understanding chemical evolutions and climate-related optical properties of aqSOA, their potential health impacts also require timely investigations. Herein, we used the dithiothreitol (DTT) assay to investigate oxidative potential of the aqSOA formed during the 8-h aqueous-phase photoreaction of two typical methoxyphenols, vanillin and vanillic acid, under pH 2 or 8, and with or without ammonia nitrate. The highest DTT consumption rates (RDTT) were observed for vanillin aqSOA formed in the presence of ammonia nitrate and at pH 8. At pH 2, although RDTT increased rapidly during early photoreaction, it reduced after prolonged illumination. High-resolution mass spectrometry and linear regression analyses were performed to correlate the photoreaction products with the observed RDTT. Results showed that three products that present quinone, lactone and dimer structures, respectively, should be the key drivers of elevated RDTT for aqSOA formed during photoreaction of vanillin and vanillic acid alone, whereas it shifted to the nitrogen-containing aromatic compounds during their photoreaction with ammonia nitrate. Our results have revealed the role of nitrogen-containing aromatic compounds in the oxidative potential and health effects of aqSOA from biomass burning, which was rarely recognized before and warrants immediate assessments.
在生物质燃烧过程中,木质素热解会释放出大量甲氧基苯酚。除了作为大气中的褐碳成分吸收太阳辐射并使气候变暖之外,甲氧基苯酚还会在大气水相中发生光反应并形成二次有机气溶胶(aqSOA)。虽然人们一直致力于了解二次有机气溶胶的化学演变和与气候相关的光学特性,但它们对健康的潜在影响也需要及时调查。在此,我们使用二硫苏糖醇(DTT)测定法研究了两种典型的甲氧基苯酚(香兰素和香草酸)在 pH 值为 2 或 8、有或没有硝酸氨的条件下进行 8 小时水相光反应过程中形成的 aqSOA 的氧化潜能。在有硝酸氨和 pH 值为 8 的条件下,观察到形成的香兰素 aqSOA 的 DTT 消耗率(RDTT)最高。 在 pH 值为 2 的条件下,虽然 RDTT 在光反应早期迅速增加,但在长时间光照后会降低。为了将光反应产物与观察到的 RDTT 联系起来,进行了高分辨率质谱分析和线性回归分析。结果表明,在香兰素和香草酸单独发生光反应时形成的 aqSOA 的 RDTT 升高的主要驱动因素应该是三种分别具有醌、内酯和二聚体结构的产物,而在它们与硝酸氨发生光反应时,RDTT 则转移到含氮芳香化合物上。我们的研究结果揭示了含氮芳香族化合物在生物质燃烧产生的 aqSOA 的氧化潜能和健康影响中的作用,这一点以前很少被认识到,需要立即进行评估。
{"title":"Deciphering the key drivers of oxidative potential during ammonium nitrate-mediated aqueous-phase photoreaction of methoxyphenols","authors":"Racliffe Weng Seng Lai ,&nbsp;Tian Qiu ,&nbsp;Xuyang Zhang ,&nbsp;Yalin Wang ,&nbsp;Tianwei Hao ,&nbsp;Xinlei Ge ,&nbsp;Lin Du ,&nbsp;Mingjin Tang ,&nbsp;Ka In Hoi ,&nbsp;Kai Meng Mok ,&nbsp;Yong Jie Li","doi":"10.1016/j.atmosenv.2024.120895","DOIUrl":"10.1016/j.atmosenv.2024.120895","url":null,"abstract":"<div><div>Methoxyphenols are released in abundance from lignin pyrolysis during biomass burning. Apart from being atmospheric brown carbon components that absorb solar radiation and warm the climate, methoxyphenols also undergo photoreaction in the atmospheric aqueous phase and form secondary organic aerosols (aqSOA). While efforts have been devoted to understanding chemical evolutions and climate-related optical properties of aqSOA, their potential health impacts also require timely investigations. Herein, we used the dithiothreitol (DTT) assay to investigate oxidative potential of the aqSOA formed during the 8-h aqueous-phase photoreaction of two typical methoxyphenols, vanillin and vanillic acid, under pH 2 or 8, and with or without ammonia nitrate. The highest DTT consumption rates (R<sub>DTT</sub>) were observed for vanillin aqSOA formed in the presence of ammonia nitrate and at pH 8. At pH 2, although R<sub>DTT</sub> increased rapidly during early photoreaction, it reduced after prolonged illumination. High-resolution mass spectrometry and linear regression analyses were performed to correlate the photoreaction products with the observed R<sub>DTT</sub>. Results showed that three products that present quinone, lactone and dimer structures, respectively, should be the key drivers of elevated R<sub>DTT</sub> for aqSOA formed during photoreaction of vanillin and vanillic acid alone, whereas it shifted to the nitrogen-containing aromatic compounds during their photoreaction with ammonia nitrate. Our results have revealed the role of nitrogen-containing aromatic compounds in the oxidative potential and health effects of aqSOA from biomass burning, which was rarely recognized before and warrants immediate assessments.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"340 ","pages":"Article 120895"},"PeriodicalIF":4.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142662934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aerosol classification under non-clear sky conditions based on geostationary satellite FY-4A and machine learning models 基于地球静止卫星 FY-4A 和机器学习模型的非晴空条件下的气溶胶分类
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-24 DOI: 10.1016/j.atmosenv.2024.120891
Bin Chen , Qia Ye , Xingzhao Zhou , Zhihao Song , Yuxiang Ren
Accurately identifying and classifying aerosols is a key to understanding their sources, assessing their chemical and physical changes, and comprehending their feedback mechanisms within climate system. However, existing aerosol classification methods have two limitations: First, ground remote sensing products have limited spatial coverage, and polar orbit satellite data suffer from low temporal resolution. Second, satellite-based aerosol classification methods are affected by cloud interference, resulting in data gaps. To overcome these challenges, this study utilized the extreme tree algorithm (ET) and integrated the FY-4A TOAR dataset with meteorological and geographical information, using a sequential forward selection method for optimal input feature selection. Focusing on the Asian region (70–140°E, 15–55°N), three models were used to generate hourly aerosol classification products: the Clear air-Cloud-Aerosol-Mixed cloud and aerosol (CCAM-ET) model, the Dust-Polluted dust-Other aerosols-Mixed aerosols (DPOM-ET) model under clear sky conditions, and the DPOM-ET model under non-clear sky conditions. The evaluated accuracy of the CCAM-ET model was 85%, demonstrating its effectiveness in identifying cloud and aerosol under various conditions. The CCAM model can achieve an accuracy of 78% when aerosols are located above clouds and 59% when they are below clouds. The DPOM-ET model achieved an evaluation accuracy of 89% for clear sky areas and 87% for non-clear sky areas, respectively, and was superior to traditional methods. Long-term data indicated a significant correlation between the distributions of different types of aerosols and human activity. Polluted dust is common in southwest China during spring and in northern China during winter. Additionally, from 2018 to 2020, dust occurrences decreased on the Indian Peninsula, while non-dust aerosols increased significantly in India and Southeast Asia.
准确识别和分类气溶胶是了解其来源、评估其化学和物理变化以及理解其在气候系统中的反馈机制的关键。然而,现有的气溶胶分类方法有两个局限性:首先,地面遥感产品的空间覆盖范围有限,极轨卫星数据的时间分辨率较低。其次,基于卫星的气溶胶分类方法受云层干扰的影响,导致数据缺失。为了克服这些挑战,本研究利用极端树算法(ET),将 FY-4A TOAR 数据集与气象和地理信息整合在一起,采用顺序前向选择法进行最佳输入特征选择。以亚洲地区(70-140°E,15-55°N)为重点,使用三种模型生成每小时气溶胶分类产品:晴空-云-气溶胶-混合云和气溶胶(CCAM-ET)模型、晴空条件下的粉尘-污染粉尘-其他气溶胶-混合气溶胶(DPOM-ET)模型和非晴空条件下的 DPOM-ET 模型。经评估,CCAM-ET 模型的准确率为 85%,证明了其在各种条件下识别云和气溶胶的有效性。当气溶胶位于云层之上时,CCAM 模型的准确率为 78%,当气溶胶位于云层之下时,准确率为 59%。DPOM-ET 模型在晴朗天空区域和非晴朗天空区域的评估准确率分别达到 89% 和 87%,优于传统方法。长期数据表明,不同类型气溶胶的分布与人类活动之间存在明显的相关性。污染性沙尘在中国西南地区的春季和北方地区的冬季很常见。此外,从2018年到2020年,印度半岛的沙尘发生率有所下降,而印度和东南亚的非沙尘气溶胶则显著增加。
{"title":"Aerosol classification under non-clear sky conditions based on geostationary satellite FY-4A and machine learning models","authors":"Bin Chen ,&nbsp;Qia Ye ,&nbsp;Xingzhao Zhou ,&nbsp;Zhihao Song ,&nbsp;Yuxiang Ren","doi":"10.1016/j.atmosenv.2024.120891","DOIUrl":"10.1016/j.atmosenv.2024.120891","url":null,"abstract":"<div><div>Accurately identifying and classifying aerosols is a key to understanding their sources, assessing their chemical and physical changes, and comprehending their feedback mechanisms within climate system. However, existing aerosol classification methods have two limitations: First, ground remote sensing products have limited spatial coverage, and polar orbit satellite data suffer from low temporal resolution. Second, satellite-based aerosol classification methods are affected by cloud interference, resulting in data gaps. To overcome these challenges, this study utilized the extreme tree algorithm (ET) and integrated the FY-4A TOAR dataset with meteorological and geographical information, using a sequential forward selection method for optimal input feature selection. Focusing on the Asian region (70–140°E, 15–55°N), three models were used to generate hourly aerosol classification products: the Clear air-Cloud-Aerosol-Mixed cloud and aerosol (CCAM-ET) model, the Dust-Polluted dust-Other aerosols-Mixed aerosols (DPOM-ET) model under clear sky conditions, and the DPOM-ET model under non-clear sky conditions. The evaluated accuracy of the CCAM-ET model was 85%, demonstrating its effectiveness in identifying cloud and aerosol under various conditions. The CCAM model can achieve an accuracy of 78% when aerosols are located above clouds and 59% when they are below clouds. The DPOM-ET model achieved an evaluation accuracy of 89% for clear sky areas and 87% for non-clear sky areas, respectively, and was superior to traditional methods. Long-term data indicated a significant correlation between the distributions of different types of aerosols and human activity. Polluted dust is common in southwest China during spring and in northern China during winter. Additionally, from 2018 to 2020, dust occurrences decreased on the Indian Peninsula, while non-dust aerosols increased significantly in India and Southeast Asia.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"339 ","pages":"Article 120891"},"PeriodicalIF":4.2,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142551937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elucidating the impacts of aerosol radiative effects for mitigating surface O3 and PM2.5 in Delhi, India during crop residue burning period 阐明气溶胶辐射效应对缓解印度德里作物残茬焚烧期间地表 O3 和 PM2.5 的影响
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-22 DOI: 10.1016/j.atmosenv.2024.120890
Lakhima Chutia , Jun Wang , Huanxin Zhang , Xi Chen , Lorena Castro Garcia , Nathan Janechek
Atmospheric aerosol radiative effects regulate surface air pollution (O3 and PM2.5) via both the aerosol–photolysis effect (APE) and the aerosol–radiation feedback (ARF) on meteorology. Here, we elucidate the roles of APE and ARF on surface O3 and PM2.5 in the heavily polluted megacity, Delhi, India by using a regional model (WRF-Chem) with constraints from limited surface observations. While APE reduces surface O3 (by 6.1%) and PM2.5 concentrations (by 2.4% via impeding the secondary aerosol formations), ARF contributes to a 2.5% and 17.5% increase in surface O3 and PM2.5, respectively. The ARF from smoke enhances PM2.5 (by 8%), black carbon (by 10%), and primary organic aerosol (by 18%) during late autumn when crop residue burning is significant. The synergistic APE and ARF have a negligible impact on the total concentrations of O3 and PM2.5. Hence, the reduction of PM2.5 may lead to O3 escalation due to weakened APE. Sensitivity experiments indicate the need and effectiveness of reducing VOC emission for the co-benefits of mitigating both O3 and PM2.5 concentrations in Delhi.
大气气溶胶辐射效应通过气溶胶光解效应(APE)和气溶胶辐射反馈(ARF)对气象学的影响来调节地表空气污染(O3 和 PM2.5)。在此,我们利用区域模型(WRF-Chem)和有限的地面观测数据,阐明了气溶胶光解效应和气溶胶辐射反馈对印度德里这个污染严重的大城市地表臭氧和 PM2.5 的影响。APE降低了地表臭氧浓度(6.1%)和PM2.5浓度(通过阻碍二次气溶胶形成降低了2.4%),而ARF则使地表臭氧浓度和PM2.5浓度分别增加了2.5%和17.5%。在农作物秸秆大量焚烧的深秋,烟雾产生的二次气溶胶会使 PM2.5(增加 8%)、黑碳(增加 10%)和原生有机气溶胶(增加 18%)增加。APE 和 ARF 的协同作用对 O3 和 PM2.5 的总浓度影响微乎其微。因此,由于 APE 的减弱,PM2.5 的减少可能会导致 O3 的增加。敏感性实验表明,减少挥发性有机化合物的排放对于同时降低德里的 O3 和 PM2.5 浓度的共同效益是必要和有效的。
{"title":"Elucidating the impacts of aerosol radiative effects for mitigating surface O3 and PM2.5 in Delhi, India during crop residue burning period","authors":"Lakhima Chutia ,&nbsp;Jun Wang ,&nbsp;Huanxin Zhang ,&nbsp;Xi Chen ,&nbsp;Lorena Castro Garcia ,&nbsp;Nathan Janechek","doi":"10.1016/j.atmosenv.2024.120890","DOIUrl":"10.1016/j.atmosenv.2024.120890","url":null,"abstract":"<div><div>Atmospheric aerosol radiative effects regulate surface air pollution (O<sub>3</sub> and PM<sub>2.5</sub>) via both the aerosol–photolysis effect (APE) and the aerosol–radiation feedback (ARF) on meteorology. Here, we elucidate the roles of APE and ARF on surface O<sub>3</sub> and PM<sub>2.5</sub> in the heavily polluted megacity, Delhi, India by using a regional model (WRF-Chem) with constraints from limited surface observations. While APE reduces surface O<sub>3</sub> (by 6.1%) and PM<sub>2.5</sub> concentrations (by 2.4% via impeding the secondary aerosol formations), ARF contributes to a 2.5% and 17.5% increase in surface O<sub>3</sub> and PM<sub>2.5</sub>, respectively. The ARF from smoke enhances PM<sub>2.5</sub> (by 8%), black carbon (by 10%), and primary organic aerosol (by 18%) during late autumn when crop residue burning is significant. The synergistic APE and ARF have a negligible impact on the total concentrations of O<sub>3</sub> and PM<sub>2.5</sub>. Hence, the reduction of PM<sub>2.5</sub> may lead to O<sub>3</sub> escalation due to weakened APE. Sensitivity experiments indicate the need and effectiveness of reducing VOC emission for the co-benefits of mitigating both O<sub>3</sub> and PM<sub>2.5</sub> concentrations in Delhi.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"339 ","pages":"Article 120890"},"PeriodicalIF":4.2,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142551936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exposure to particulate matter when commuting in the urban area of Grenoble, France 在法国格勒诺布尔市区通勤时暴露于颗粒物的情况
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-22 DOI: 10.1016/j.atmosenv.2024.120887
Marie-Laure Aix, Mélaine Claitte, Dominique J. Bicout
Air pollution is a major cause of mortality and chronic diseases worldwide, with particulate matter (PM) being the primary contributor to this burden. Few studies have yet been carried out on the effect of modes of transport, times of day or travel locations on the exposure of individuals to PM. We conducted an experiment in Grenoble, France, in spring 2022 to study factors determining the individual exposure to PM. Using low-cost sensors (LCS), PM1 (PM < 1 μm) and PM2.5 (PM < 2.5 μm) levels were measured in four transport modes (bike, walk, bus, and tramway), across four different streets and at three different times of the day. Findings are: (i) - the mode of transport plays a more important role on levels of PMratios (PM concentration ratio to reference) than the time of the day or the location, (ii) - PMratios and inhalation doses are higher in active modes of transport (bike, walk) than in passive ones (bus, tram), (iii) – levels of exposure to PM are ranked as: tram < bus < walk < bike, and (iv) – a statistical model has been developed to predict PMratios as a function of transport mode, travel period, street ratio, and traffic. Exposures to PM in trams are found 12%–25% and 13%–20% lower than in passive modes of transport for PM1 and PM2.5, respectively. Wearing LCSs makes it possible to estimate commuters' exposure to PM and their use should be encouraged for prevention purposes.
空气污染是导致全球死亡和慢性疾病的主要原因,而颗粒物(PM)是造成这一负担的主要因素。关于交通方式、时间或出行地点对个人暴露于可吸入颗粒物的影响的研究还很少。2022 年春季,我们在法国格勒诺布尔进行了一项实验,研究决定个人暴露于可吸入颗粒物的因素。我们使用低成本传感器(LCS),测量了四种交通工具(自行车、步行、公共汽车和有轨电车)、四条不同街道和一天中三个不同时间段的 PM1(PM < 1 μm)和 PM2.5(PM < 2.5 μm)水平。研究结果如下(i) - 交通方式对可吸入颗粒物比率(可吸入颗粒物浓度与参考值之比)水平的影响比一天中的时间或地点更重要,(ii) - 主动交通方式(自行车、步行)的可吸入颗粒物比率和吸入剂量高于被动交通方式(公共汽车、有轨电车),(iii) - 可吸入颗粒物的暴露水平按以下方式排序有轨电车、公共汽车、步行、自行车,以及(iv) - 建立了一个统计模型,以预测可吸入颗粒物比率与交通方式、出行时间、街道比率和交通流量的关系。在 PM1 和 PM2.5 方面,有轨电车的 PM 暴露分别比被动式交通工具低 12%-25%和 13%-20%。佩戴有轨电车乘客保护套可以估算乘客暴露于可吸入颗粒物的情况,因此应鼓励使用有轨电车乘客保护套以达到预防目的。
{"title":"Exposure to particulate matter when commuting in the urban area of Grenoble, France","authors":"Marie-Laure Aix,&nbsp;Mélaine Claitte,&nbsp;Dominique J. Bicout","doi":"10.1016/j.atmosenv.2024.120887","DOIUrl":"10.1016/j.atmosenv.2024.120887","url":null,"abstract":"<div><div>Air pollution is a major cause of mortality and chronic diseases worldwide, with particulate matter (PM) being the primary contributor to this burden. Few studies have yet been carried out on the effect of modes of transport, times of day or travel locations on the exposure of individuals to PM. We conducted an experiment in Grenoble, France, in spring 2022 to study factors determining the individual exposure to PM. Using low-cost sensors (LCS), PM<sub>1</sub> (PM &lt; 1 μm) and PM<sub>2.5</sub> (PM &lt; 2.5 μm) levels were measured in four transport modes (bike, walk, bus, and tramway), across four different streets and at three different times of the day. Findings are: (i) - the mode of transport plays a more important role on levels of PM<sub>ratios</sub> (PM concentration ratio to reference) than the time of the day or the location, (ii) - PM<sub>ratios</sub> and inhalation doses are higher in active modes of transport (bike, walk) than in passive ones (bus, tram), (iii) – levels of exposure to PM are ranked as: tram &lt; bus &lt; walk &lt; bike, and (iv) – a statistical model has been developed to predict PM<sub>ratios</sub> as a function of transport mode, travel period, street ratio, and traffic. Exposures to PM in trams are found 12%–25% and 13%–20% lower than in passive modes of transport for PM<sub>1</sub> and PM<sub>2.5</sub>, respectively. Wearing LCSs makes it possible to estimate commuters' exposure to PM and their use should be encouraged for prevention purposes.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"339 ","pages":"Article 120887"},"PeriodicalIF":4.2,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a city-level surface ozone forecasting system using deep learning techniques and air quality model: Application in eastern China 利用深度学习技术和空气质量模型开发城市级地表臭氧预报系统:在华东地区的应用
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-18 DOI: 10.1016/j.atmosenv.2024.120865
Qianyun Li , Jie Li , Zixi Wang , Bing Liu , Wei Wang , Zifa Wang
Utilizing regional air quality models to accurately forecast surface ozone (O3) concentrations, particularly high concentrations, is essential for protecting public health. However, forecasts of air quality model often deviate from site observations due to the limitation of grid resolution and uncertainties from emission sources, meteorological conditions, and chemical reaction mechanisms. Especially, the underestimation is significant under condition of high O3 concentrations. Moreover, such deviations tend to accumulate as forecast lead time increases, compounding the challenges associated with reliable air quality forecast. In this study, we employed AlexNet architecture, a classical convolutional neural network, combined with multiple variables related to meteorology, chemistry, emission and geography to establish a non-linear relationship between grid-scale input variables and site-scale hourly O3 forecast biases in Eastern China, aiming to realize accurate city-level ozone forecast based on a regional air quality prediction model (i.e., Nested Air Quality Prediction Model System, NAQPMS). By assigning weights to high-bias samples and high-concentration samples within the loss function, the proposed Weighted AlexNet model (W_AlexNet) effectively reduced forecast biases and enhanced its capability to predict O3 pollution levels. Compared to NAQPMS, W_AlexNet model demonstrated a 25.71% improvement in RMSE and a 7.17% increase in IOA averagely for hourly O3 (O3-1h) forecasts across four different lead times (24-h, 48-h, 72-h, and 96-h). Notably, W_AlexNet model alleviated the tendency of NAQPMS to underestimate high concentrations and showed a superior performance in improving O3-1h pollution level forecasts, particularly for the 72-h and 96-h lead times. W_AlexNet model can effectively mitigate the bias accumulation effect over increasing lead times, thereby enhancing the reliability of longer-term forecasts. Thus, the W_AlexNet model serves as a post-processing model that can calibrate forecast biases in air quality prediction models, significantly improving the accuracy of O3 high concentration forecasts and providing more precise early warnings of O3 pollution. This underscores its utility in air quality management.
利用区域空气质量模型准确预测地表臭氧(O3)浓度,尤其是高浓度臭氧,对于保护公众健康至关重要。然而,由于网格分辨率的限制以及排放源、气象条件和化学反应机制的不确定性,空气质量模型的预测往往与现场观测结果存在偏差。尤其是在臭氧浓度较高的情况下,这种低估更为明显。此外,随着预报准备时间的延长,这种偏差会不断累积,从而加剧了可靠的空气质量预报所面临的挑战。在本研究中,我们采用经典卷积神经网络 AlexNet 架构,结合气象、化学、排放和地理相关的多个变量,建立了华东地区网格尺度输入变量与站点尺度每小时臭氧预报偏差之间的非线性关系,旨在实现基于区域空气质量预报模式(即嵌套空气质量预报模式系统,NAQPMS)的城市臭氧精确预报。通过在损失函数中为高偏差样本和高浓度样本分配权重,所提出的加权 AlexNet 模型(W_AlexNet)有效地减少了预报偏差,提高了预报臭氧污染水平的能力。与 NAQPMS 相比,W_AlexNet 模型在四个不同提前期(24 小时、48 小时、72 小时和 96 小时)的每小时臭氧(O3-1 小时)预测中,均方根误差(RMSE)改善了 25.71%,平均 IOA 增加了 7.17%。值得注意的是,W_AlexNet 模型缓解了 NAQPMS 低估高浓度的倾向,在改善 O3-1h 污染水平预报方面表现出色,尤其是在 72-h 和 96-h 提前期。W_AlexNet 模型可有效缓解偏差累积效应,从而提高长期预报的可靠性。因此,W_AlexNet 模型作为一种后处理模型,可以校准空气质量预测模型中的预测偏差,显著提高 O3 高浓度预测的准确性,并提供更精确的 O3 污染预警。这凸显了其在空气质量管理中的实用性。
{"title":"Development of a city-level surface ozone forecasting system using deep learning techniques and air quality model: Application in eastern China","authors":"Qianyun Li ,&nbsp;Jie Li ,&nbsp;Zixi Wang ,&nbsp;Bing Liu ,&nbsp;Wei Wang ,&nbsp;Zifa Wang","doi":"10.1016/j.atmosenv.2024.120865","DOIUrl":"10.1016/j.atmosenv.2024.120865","url":null,"abstract":"<div><div>Utilizing regional air quality models to accurately forecast surface ozone (O<sub>3</sub>) concentrations, particularly high concentrations, is essential for protecting public health. However, forecasts of air quality model often deviate from site observations due to the limitation of grid resolution and uncertainties from emission sources, meteorological conditions, and chemical reaction mechanisms. Especially, the underestimation is significant under condition of high O<sub>3</sub> concentrations. Moreover, such deviations tend to accumulate as forecast lead time increases, compounding the challenges associated with reliable air quality forecast. In this study, we employed AlexNet architecture, a classical convolutional neural network, combined with multiple variables related to meteorology, chemistry, emission and geography to establish a non-linear relationship between grid-scale input variables and site-scale hourly O<sub>3</sub> forecast biases in Eastern China, aiming to realize accurate city-level ozone forecast based on a regional air quality prediction model (i.e., Nested Air Quality Prediction Model System, NAQPMS). By assigning weights to high-bias samples and high-concentration samples within the loss function, the proposed Weighted AlexNet model (W_AlexNet) effectively reduced forecast biases and enhanced its capability to predict O<sub>3</sub> pollution levels. Compared to NAQPMS, W_AlexNet model demonstrated a 25.71% improvement in RMSE and a 7.17% increase in IOA averagely for hourly O<sub>3</sub> (O<sub>3</sub>-1h) forecasts across four different lead times (24-h, 48-h, 72-h, and 96-h). Notably, W_AlexNet model alleviated the tendency of NAQPMS to underestimate high concentrations and showed a superior performance in improving O<sub>3</sub>-1h pollution level forecasts, particularly for the 72-h and 96-h lead times. W_AlexNet model can effectively mitigate the bias accumulation effect over increasing lead times, thereby enhancing the reliability of longer-term forecasts. Thus, the W_AlexNet model serves as a post-processing model that can calibrate forecast biases in air quality prediction models, significantly improving the accuracy of O<sub>3</sub> high concentration forecasts and providing more precise early warnings of O<sub>3</sub> pollution. This underscores its utility in air quality management.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"339 ","pages":"Article 120865"},"PeriodicalIF":4.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Calibration of NO, SO2, and PM using Airify: A low-cost sensor cluster for air quality monitoring 使用 Airify 校准 NO、SO2 和 PM:用于空气质量监测的低成本传感器集群
IF 4.2 2区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-18 DOI: 10.1016/j.atmosenv.2024.120841
Marian-Emanuel Ionascu , Marius Marcu , Razvan Bogdan , Marius Darie
During the past decade, substantial efforts have been dedicated to advancing cost-effective sensor platforms for air quality monitoring. Calibration is a crucial step in ensuring that the data quality of low-cost air monitoring systems meets established standards. Recent research has extensively evaluated low-cost air monitoring platforms against the data quality objectives set by the European Directive. This paper introduces a novel calibration model for low-cost air quality sensors, significantly improving the accuracy of the measurement of nitric oxide (NO), sulfur dioxide (SO2), and particulate matter (PM1, PM2.5, and PM10), while promoting accessibility and adaptability in environmental monitoring technologies. This study extends the evaluation of a developed platform capable of integrating a diverse array of sensors to measure up to 12 parameters. Our proposed models demonstrate a significant improvement, achieving a 60% better accuracy for SO2. Additionally, these models deliver similar results for PMx and NO or exceed those of state of the art research. The calibration methodology meets the requirements of the Data Quality Objectives (DQO) for all monitored parameters and also achieves indicative levels for PM parameters.
在过去的十年中,人们一直致力于推进用于空气质量监测的高性价比传感器平台。校准是确保低成本空气监测系统的数据质量符合既定标准的关键步骤。最近的研究根据欧洲指令设定的数据质量目标,对低成本空气监测平台进行了广泛评估。本文介绍了一种适用于低成本空气质量传感器的新型校准模型,可显著提高一氧化氮(NO)、二氧化硫(SO2)和颗粒物(PM1、PM2.5 和 PM10)的测量精度,同时促进环境监测技术的可及性和适应性。本研究扩展了对已开发平台的评估,该平台能够集成各种传感器,测量多达 12 个参数。我们提出的模型显示出显著的改进,二氧化硫的精确度提高了 60%。此外,这些模型对可吸入颗粒物和氮氧化物的测量结果与最新研究结果相似,甚至更高。校准方法符合数据质量目标(DQO)对所有监测参数的要求,也达到了可吸入颗粒物参数的指示性水平。
{"title":"Calibration of NO, SO2, and PM using Airify: A low-cost sensor cluster for air quality monitoring","authors":"Marian-Emanuel Ionascu ,&nbsp;Marius Marcu ,&nbsp;Razvan Bogdan ,&nbsp;Marius Darie","doi":"10.1016/j.atmosenv.2024.120841","DOIUrl":"10.1016/j.atmosenv.2024.120841","url":null,"abstract":"<div><div>During the past decade, substantial efforts have been dedicated to advancing cost-effective sensor platforms for air quality monitoring. Calibration is a crucial step in ensuring that the data quality of low-cost air monitoring systems meets established standards. Recent research has extensively evaluated low-cost air monitoring platforms against the data quality objectives set by the European Directive. This paper introduces a novel calibration model for low-cost air quality sensors, significantly improving the accuracy of the measurement of nitric oxide (NO), sulfur dioxide (SO<sub>2</sub>), and particulate matter (PM<sub>1</sub>, PM<sub>2.5</sub>, and PM<sub>10</sub>), while promoting accessibility and adaptability in environmental monitoring technologies. This study extends the evaluation of a developed platform capable of integrating a diverse array of sensors to measure up to 12 parameters. Our proposed models demonstrate a significant improvement, achieving a 60% better accuracy for SO<sub>2</sub>. Additionally, these models deliver similar results for PM<sub>x</sub> and NO or exceed those of state of the art research. The calibration methodology meets the requirements of the Data Quality Objectives (DQO) for all monitored parameters and also achieves indicative levels for PM parameters.</div></div>","PeriodicalId":250,"journal":{"name":"Atmospheric Environment","volume":"339 ","pages":"Article 120841"},"PeriodicalIF":4.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Atmospheric Environment
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1