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Design of the system tundish-submerged nuzzle-tube mold of billet CCM under conditions of linear offsets of nuzzle and mold axes 对钢坯连铸机中间包-浸没型口-管型在型口与模轴线性偏移条件下的系统设计
Pub Date : 2020-09-09 DOI: 10.32339/0135-5910-2019-9-1037-1045
K. Vdovin, S. Shakhov, V. Tochilkin, О. A. Filatova
Perfection of the structure and modernization of billet CCMs elements is an important task of the modem metallurgy, solving of which provides an increase of machines productivity and continuously casted billets quality. The system tundish (T) -submerged nuzzle (SN) - tube mold (TM) and its facilities, forming the flows of metal in the tundish and the mold, are most important technological units of a billets CCM. Different designs of the equipment of the system T-SN-TM for metal supply to the tube mold with T rational installation in the TM considered, which allowed to decrease steel flows turbulence. It was shown, that the decrease of flow turbulence results in a decrease of liquid steel streams speed near the tube mold walls in the area of crystallizing ingot and provides favorable conditions for forming solidifying continuously casted billet of small section, provides the billet hard shell forming and decreases probability of emergency situations. The processes of metal flows control in the presented system also shown. General view of the system T-SN-TM of a billet CCM and its controlled parameters presented. General geometric dimensions of the mold and technological parameters of the casting process also presented. To evaluate peculiarities of the casting process in the system T-SN-TM at different values of axes offset of the SN and the mold, a mathematical simulation was accomplished. A model of internal volume of the metal, moving by a closed stream through the submerged nuzzle of the tundish into the TM upper part was built by means of a solid-state simulation package.
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引用次数: 0
Assessment of current trends in production of molybdenum, its alloys and molybdenum-containing products 钼、钼合金和含钼产品生产的当前趋势评估
Pub Date : 2020-09-02 DOI: 10.32339/0135-5910-2020-8-780-789
G. V. Galevskii, O. A. Polyakh, V. Rudneva, A. Anikin
The unique combination of physical and chemical properties of molybdenum, required by modern material science, predetermines the variety of applications of molybdenum-containing alloys and molybdenumcontaining metal products: metallurgy, various-profile mechanical engineering, electro-thermal equipment, as well as the need to systematize and update the scientific and technological information accumulated in molybdenum metallurgy. The purpose of the present work was to evaluate the current state of molybdenum production and application, including such issues as production of molybdenum trioxide, molybdenum and its alloys, industrial range of molybdenum and its alloys products, molybdenum consumption structure, identification of dominant trends and their forecasting in the medium term.Technical and economical information on production and consumption of molybdenum trioxide, molybdenum and its alloys was evaluated and systematized. The existing range of products from molybdenum and its alloys, the structure of world molybdenum consumption were evaluated, dominant trends and forecasts for the nearest period were determined. It was stated, that the main technology of molybdenum production is hydrogen reduction from high purity trioxide (up to 99.9%) in the form of powder followed by its compaction. The main producers of molybdenum are the United States, Chile, China, Peru, Canada and Mexico, which account for more than 90% of world production. In 2018, global consumption of molybdenum was about 262,000 tons, about 20% less than in 2011–2012. Ferromolybdenum is produced in Russia and abroad of various brands with molybdenum content of 50– 70%. Currently, the producers of ferromolybdenum in Russia are Sorsky, Zhireken ferromolybdenum and Nizhnevolzhsky ferroalloy plants. The total production capacity of Russian enterprises is estimated at 8.5 thousand tons of ferromolybdenum per year. Metallurgical enterprises of Russia declare production of 33 different types of intermediate products and final products from molybdenum and its alloys.
钼的物理和化学性质的独特组合是现代材料科学所要求的,这预先决定了含钼合金和含钼金属制品的各种应用:冶金、各种规格的机械工程、电热设备,以及对钼冶金方面积累的科技信息进行系统化和更新的需要。本文的目的是评价钼的生产和应用现状,包括三氧化钼的生产、钼及其合金的生产、钼及其合金产品的工业范围、钼的消费结构、主导趋势的确定和中期预测。对三氧化钼、钼及其合金的生产和消费技术经济资料进行了评价和整理。对钼及其合金的现有产品范围、世界钼消费结构进行了评价,确定了近期钼消费的主导趋势和预测。指出钼生产的主要工艺是将高纯度(纯度达99.9%)的三氧化物以粉末形式还原氢,然后压实。钼的主要生产国是美国、智利、中国、秘鲁、加拿大和墨西哥,占世界产量的90%以上。2018年,全球钼消费量约为26.2万吨,比2011-2012年减少约20%。在俄罗斯和国外生产各种品牌的钼铁,钼含量为50 - 70%。目前,俄罗斯的钼铁生产商有Sorsky、Zhireken和Nizhnevolzhsky铁合金厂。俄罗斯企业的总生产能力估计为每年8500吨钼铁。俄罗斯冶金企业宣布生产33种不同类型的钼及其合金的中间产品和最终产品。
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引用次数: 0
Development of a calculation method for evaluating technological parameters of the desulphurization process in a ladle 建立了钢包脱硫工艺参数的计算方法
Pub Date : 2020-08-10 DOI: 10.32339/0135-5910-2020-7-700-708
A. Kem, E. Y. Roshchupkina, A. Kozhukhov
To fulfil the requirements for pipe steels of strength group D in terms of sulfur content, the metal is subjected to ladle desulfurization. In the course of desulfurization, in order to reduce its duration, steel is mixed in the ladle by blowing with argon. To optimize the desulfurization process, a methodology has been developed for evaluating its technological parameters, which allows determining under production conditions the intensity of steel blowing in the ladle. As initial data for comparative calculations of the technological parameters of the process of desulfurization of pipe steel in a ladle according to the developed method, the indicators of industrial melts were used, including the chemical composition of steel and the main technological data characterizing the production parameters of desulfurization of pipe steels of strength group D. The algorithm for using the proposed technique provides for the calculation of sulfur activity and the coefficient of sulfur activity in a steel melt of a given composition; determination of the oxidizing potential of the slag-metal system and the sulfide capacity of the slag; calculation of the equilibrium sulfur distribution coefficient between steel and slag, as well as the volumetric mass transfer coefficient under equilibrium and production conditions. To determine the thermodynamic characteristics of the interaction of sulfur dissolved in a metal with slag, the sorption ability of the slags of the analyzed melts with respect to sulfur was calculated. Data are presented on the effect of sulfur activity in experimental melts on the final sulfur content in steel. The rational limits of the value of the integral indicator of the composition of refining slags and volumetric mass transfer coefficient, which provide the best indicators of the process of desulfurization of steel, were determined. The dependences of the influence of the volumetric mass transfer coefficient on the duration of the process and the final sulfur content in the metal were established. The proposed methodology for assessing the technological parameters of steel desulfurization can optimize the duration of its individual stages and, thereby, reduce the cost of the process as a whole.
为满足强度组D的管材含硫量的要求,对其进行钢包脱硫。在脱硫过程中,为了缩短脱硫时间,用吹氩的方法将钢混入钢包中。为了优化脱硫工艺,开发了一种评估脱硫工艺参数的方法,该方法可以确定在生产条件下钢包内吹钢的强度。采用工业熔体的指标,作为根据所建立的方法对钢包内钢管脱硫工艺参数进行对比计算的初始数据。包括钢的化学成分和表征强度组d管材脱硫生产参数的主要技术数据。使用本技术的算法提供给定成分的钢熔体中硫活度和硫活度系数的计算;渣-金属体系氧化电位和渣硫化物容量的测定;计算了平衡条件和生产条件下钢渣平衡硫分配系数以及体积传质系数。为了确定溶解在金属中的硫与炉渣相互作用的热力学特性,计算了所分析熔体的炉渣对硫的吸附能力。给出了试验熔体中硫活度对钢中最终硫含量影响的数据。确定了炼钢渣组成积分指标和体积传质系数取值的合理范围,为炼钢脱硫过程提供了最佳指标。建立了体积传质系数对过程持续时间和金属中最终硫含量的影响关系。所提出的钢铁脱硫技术参数评估方法可以优化其各个阶段的持续时间,从而降低整个过程的成本。
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引用次数: 0
Analysis of the blast furnace operations with a volume of 5000 m3 on tuyeres of different diameters from the positions of full mechanical energies of flows of combined blow and hearth gas 从吹气和炉底气混合流动的全机械能位置出发,分析了不同直径风口上容量为5000 m3的高炉的运行情况
Pub Date : 2020-08-10 DOI: 10.32339/0135-5910-2020-7-691-699
V. Lyalyuk
In the commissioning period of the development of pulverized coal injection technology (PCI) on a blast furnace No. 9 with a volume of 5000 m3 of PJSC “ArcelorMittal Kryvyi Rih”, frequent cases of burnout of refrigerators of the cooling system of the shoulders and air tyueres appeared due to the highly developed peripheral gas flow. An attempt to limit the gas flow at the periphery by controlling the distribution of charge materials on the top produced a short-term result. Based on the prevailing ideas, that to reduce the intensity of the peripheral gas flow, it is necessary to increase the speed of the blast and, accordingly, the kinetic energy of the blast flow, flowing out of the air tuyeres of a blast furnace, it was decided to reduce their diameter. As a result of analysis of the operation of the specified blast furnace using the technology of PCI on tuyeres with a diameter of 150 and 140 mm, increased peripheral gas flow with a smaller diameter was established. Based on the results of the analysis, conclusions were made by many researchers and it was shown that with constant kinetic energy of the blast, flowing from the tuyeres of different diameters, the dimensions of the combustion zone are always larger before the tuyeres of a larger diameter. This is explained by the fact that the kinetic energy of the gas flow is only a part of their total mechanical energy. It was shown that to analyze the change in the size of the combustion zones and the depth of penetration of the hearth gas, it is necessary to use the full mechanical energy of the flows of the combined blast on the cut of the tuyere and hearth gas. It was established that the transition to PCI in a blast furnace instead of natural gas, it always causes an increase in the peripheral gas flow. The main reason for this phenomenon is associated with a decrease in the total mechanical energy of blast and hearth gas. It was recommended on a blast furnace with a volume of 5000 m3 with a hearth diameter of 14.7 m and the PCI technology to maintain the total mechanical energy of the blast flow at least 2100–2600 kJ/s, and the full mechanical energy of the hearth gas flow at least 5100–5300 kJ/s.
在PJSC“ArcelorMittal Kryvyi Rih”5000m3 9号高炉喷煤粉技术(PCI)开发调试期间,由于周边气流高度发达,肩部和风道冷却系统的电冰箱经常出现烧坏的情况。通过控制顶部带电物质的分布来限制外围气体流动的尝试产生了短期的结果。根据流行的观点,为了降低外围气流的强度,有必要增加爆炸的速度,相应地,从高炉风口流出的冲击波的动能决定减小它们的直径。通过对某高炉在直径为150 mm和140 mm的风口上采用PCI技术的运行分析,得出了直径越小,外围气流流量越大的结论。在分析结果的基础上,许多研究者得出了结论,表明在冲击波动能恒定的情况下,从不同直径的风口流出,燃烧区的尺寸总是比大直径的风口更大。这可以用气流的动能只是总机械能的一部分这一事实来解释。结果表明,为了分析燃烧区大小和炉膛气侵彻深度的变化,必须利用组合冲击波流的全部机械能作用在风口和炉膛气的切口上。研究表明,高炉用PCI代替天然气,总能引起外围气体流量的增加。造成这种现象的主要原因与高炉煤气和炉底煤气的总机械能的减少有关。在容积为5000m3、炉膛直径为14.7 m、采用PCI技术的高炉上,建议保持高炉气流总机械能不低于2100-2600 kJ/s,炉膛煤气流量全机械能不低于5100-5300 kJ/s。
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引用次数: 3
Еfficiency increase of powdered coal application at hot metal production and limestone calcination under unstable technology conditions Еfficiency在不稳定的工艺条件下,粉煤在铁水生产和石灰石煅烧中的应用增加
Pub Date : 2020-08-10 DOI: 10.32339/0135-5910-2020-7-676-690
Yurii S. Semenov, A. Podkorytov, V. V. Gorupakha, I. Y. Semion, A. Y. Orobtsev, E. I. Shumel’chik
Operation of Ukraine ferrous metallurgy under conditions of dependence on import and instability of energy carriers supply, shortage of investments in modernization of production equipment, make the matter of cooperation between steel-works and research organization particularly actual. Basic results of cooperation between Z.I. Nekrasov Institute of Ferrous metallurgy, NAN of Ukraine and Dnepr steel-works in 2017–2019 on blast sfurnace operation pefection and technology of powdered coal injection into rotating limestone calcination furnaces. Results of the finding of the powdered coal optimal consumption shown, which ensure a high efficiency of the coke substitution, reaching of maximum possible blast furnace productivity as well as satisfactory utilization degree of the reducing gas ability. Results of implementation of a complex of measures presented, which ensure a rational distribution of the powdered coal by BF air tuyeres for making the heat conditions of the tuyere zone even by the blast furnace circle. Efficiency of application of technology of joint injection the powdered coal and natural gas was shown, which is achieved by improving the powdered coal combustion conditions in case of increase their mixing degree. Recommendations quoted for blast furnaces starting-up after their idling for a period exceeding the permissible one, without tapping the plug hot metal. The recommendations ensure an accident-free putting a blast furnace into operation followed by reaching planned parameters. Results of usage sensors information, measuring temperature of gas flow above the charge surface presented. The results allow to prove the correction of blast furnace charging mode by an expert module, generating correction impact to support control actions by technological personal. A complex of measures formed to prevent a disturbance of a blast furnace running in case of powdered coal injection in an amount exceeding 140 kg/t of hot metal and without application of special washover materials. The results of efficiency of the mastered technology, envisaging application manganese-bearing materials at a constant base, were shown. Results of diagnostics of workability of the facility for powdered coal injection into rotating limestone calcinating furnace presented, followed by elaboration recommendation on correction parameters of injection facility operation.
乌克兰黑色冶金业在依赖进口和能源载体供应不稳定、生产设备现代化投资不足的情况下开展业务,使钢铁厂和研究机构之间的合作问题特别现实。2017-2019年乌克兰涅克拉索夫黑色冶金研究所与第聂伯钢铁厂在高炉操作完善和旋转石灰石煅烧炉喷粉技术方面合作的基本成果结果表明,煤粉最优用量的确定,保证了焦炭替代效率高,高炉生产效率达到最大,还原气能力的利用程度令人满意。介绍了采取了一系列措施,保证高炉风口合理分配煤粉,使风口区域的热状况与高炉循环均匀。通过提高煤粉与天然气的混合度,改善煤粉的燃烧条件,实现了煤粉与天然气联合喷射技术的应用效果。高炉在空转时间超过允许的时间后启动,而不攻塞铁水的建议报价。这些建议确保高炉在达到计划参数后无事故投入运行。给出了利用传感器信息测量电荷面以上气流温度的结果。验证了专家模块对高炉装料方式的修正,产生了修正影响,支持了技术人员的控制行动。在喷煤量超过140公斤/吨的铁水而不使用特殊的洗涤材料的情况下,为防止高炉运行受到干扰而采取的综合措施。结果表明,所掌握的技术的效率,设想在一个恒定的基础上应用含锰材料。介绍了旋转石灰石煅烧炉喷粉装置的可操作性诊断结果,并对喷粉装置运行的修正参数提出了详细建议。
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引用次数: 3
Study of physical and mechanical properties of vanadium slag 钒渣物理力学性能研究
Pub Date : 2020-07-21 DOI: 10.32339/0135-5910-2020-6-614-619
Кажущаяся Плотность Металловключений, Извлеченных, ИЗ Ванадиевого Шлака, Очищенных ОТ Шлака
Technology of vanadium slag (VS) production and extraction vanadium out of it is money- and labor-consuming process, that stipulates the actuality of study of physical, mechanical and technological properties of VS and influences the effectiveness of its processing and utilization. It was noted, that the oxidizing-siliceous addition (OSA), used as a dilutant in the process of vanadium extraction, enables to ensure basic components content in the VS accounting the Technical Specifications ТУ 14-11-187–86. However, it changes the chemical and mineral compositions and distribution of metal inclusions by slag fractions, therefore all the studied parameters were considered by variants with the OSA and without it. The averaged chemical composition of VS, its mineral phases content and metal inclusions content presented. It was shown, that existing methods of evaluation of metal inclusions content in the VS do not ensure repeatability of the results. A methodology was proposed to evaluate slagging of metal inclusions by the hydrostatic weighing method. Besides, Influence of OSA on physical and mechanical properties of vanadium slag. A dependence of metal content in slag on its apparent density determined, which will increase accuracy of calculations of capacity of transport facilities, bunkers, warehouses etc. The study of the VS strength characteristics, knowledge of which is important for correct choice of crushing and grinding equipment, was accomplished with samples obtained with additions OSA and without OSA. The results obtained showed, that the strength of the VS without OSA is significantly higher, and the indices of crushability is lower, comparing with VS with OSA utilization. The VS with OSA additions is mechanical processed easier – at crushing, grinding. Besides, in this case the metal inclusions are opened better and during extraction out of a slag they are less slaggy.
钒渣的生产和提钒工艺是一项费时费力的工艺,这决定了钒渣的物理、力学和工艺性能研究的现状,影响了钒渣加工利用的有效性。在提钒过程中使用氧化硅质添加剂(OSA)作为稀释剂,可以保证VS中基本组分的含量(技术规范ТУ 14-11-187-86)。然而,它改变了渣组分中金属夹杂物的化学和矿物组成及分布,因此所有的研究参数都是通过有OSA和没有OSA的变量来考虑的。给出了VS的平均化学成分、矿物相含量和金属夹杂物含量。结果表明,现有的金属夹杂物含量测定方法不能保证结果的可重复性。提出了一种流体静力称重法评价金属夹杂物结渣的方法。此外,还研究了OSA对钒渣物理力学性能的影响。测定了矿渣中金属含量与表观密度的关系,提高了运输设施、地堡、仓库等容量计算的准确性。通过添加OSA和不添加OSA获得的样品,完成了VS强度特性的研究,这对于正确选择破碎和研磨设备非常重要。结果表明,不含OSA的VS强度明显高于含OSA的VS,可破碎性指标较低。添加OSA的VS更容易机械加工-在破碎,研磨。此外,在这种情况下,金属夹杂物较好地打开,在从渣中提取时,它们的渣较少。
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引用次数: 0
Study of processes in the blast channel of blast furnace air tuyere when using PCI 采用PCI的高炉风口风道工艺研究
Pub Date : 2020-07-10 DOI: 10.32339/0135-5910-2020-5-449-456
V. Titov, A. Radyuk, I. A. Levitskii, A. I. Ternovykh, A. Titlyanov, T. Sidorova
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引用次数: 0
Refining properties of magnesia slags by heat periods in EAF ДСП-135 with various degree of saturation by magnesium oxide 氧化镁在不同饱和程度的电炉中加热周期精炼氧化镁渣ДСП-135的性能
Pub Date : 2020-07-09 DOI: 10.32339/0135-5910-2020-4-353-358
A. Babenko, M. Ushakov, L. Mikhailova
To increase technological, technical and economical parameters in electric steelmaking, operation of modern EAFs under magnesia slags is a perspective way. Therefore, forming the magnesia slags, ensuring early formation of a stable refining slag foam, is an actuals task. The slag foam must have not only high refining properties, ensuring necessary degree of steel desulphurization, but also have low aggressive impact on refractory lining of EAF. The aim of the work was the study of influence of slags oxidation, basicity and saturation degree by magnesium oxide on their refining properties in EAF ДСП-135. In the process of the stud, industrial high-magnesia slags were used, formed in reducing and oxidizing periods of heat running in EAF ДСП-135. The refining properties of high-magnesia slags were evaluated by equilibrium phosphor concentration under slags of the investigated oxide system, completeness of phosphor oxidation reaction progress by periods of heat in the EAF and by variation of actual phosphor content in metal during oxidation period of heat. To calculate the equilibrium phosphor content under magnesia slags, the known calculation method was used with application of V.A. Kozheurov’ model, adapted to real oxide system. It was determined, that the forming of slags of oxidizing period with basicity of 1.9 and higher in the area, tending to their saturation by magnesium oxide, ensures the metal dephosphorization process development. At the basicity less 1.9, the development of metal dephosphorization process does not take place, and phosphor reduction process from slag in the metal is observed, resulting in an increase of its concentration, comparing with phosphor in the metal of melting period in average by 0.0005%. At the basicity of slags of oxidizing period 1.9 and higher, the process of the metal rephosphorization practically is not observed and phosphor content in the metal is at the level of its concentration in the metal of melting period. To keep high refining properties it was recommended to form the magnesia slags within the melting period and oxidizing period in the area tending to saturation by magnesium oxide with the basicity not lower 1.9.
为提高电炉炼钢的工艺、技术和经济参数,在氧化镁渣下运行现代电炉是一条有前景的途径。因此,形成氧化镁渣,确保早期形成稳定的精炼渣泡沫,是一项实际任务。熔渣泡沫既要有较高的精炼性能,保证钢的脱硫程度,又要对电炉耐火衬具有较低的侵蚀性。研究了氧化镁对炉渣氧化、碱度和饱和度对炉渣在电炉中精炼性能的影响ДСП-135。在铆焊过程中,使用了工业高镁渣,这些高镁渣是在电炉热运行的还原和氧化阶段形成的ДСП-135。通过所研究的氧化体系下的平衡磷浓度、电炉内的加热周期和热氧化期间金属中实际磷含量的变化来评价高镁渣的精炼性能。为了计算氧化镁渣下的平衡磷含量,采用了已知的计算方法,并应用了V.A. Kozheurov模型,适用于实际的氧化物体系。结果表明,该地区碱性为1.9以上的氧化期炉渣的形成趋向于氧化镁的饱和,保证了金属脱磷过程的顺利进行。在碱度低于1.9时,不发生金属脱磷过程的发展,金属中出现了从炉渣中还原磷的过程,导致其浓度比熔化期金属中的磷平均增加了0.0005%。氧化期矿渣碱度为1.9及以上时,几乎没有观察到金属的再磷酸化过程,金属中的磷含量处于熔化期金属的浓度水平。为保持较高的精炼性能,建议在碱度不低于1.9的氧化镁趋于饱和区域,在熔融期和氧化期形成镁渣。
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引用次数: 0
Perfection of sinter, coke and blast furnace production by application of digital technologies within the frame of “Industry 4.0” concept 在“工业4.0”概念框架下,应用数字技术完善烧结、焦炭和高炉生产
Pub Date : 2020-07-09 DOI: 10.32339/0135-5910-2020-4-339-343
A. Dmitriev, M. Zolotykh, G. Vitkina
. At present in view of computers and control systems development, the role of digitizing and digital transformation of metallurgical production has increased. The most important element of the transformation to digital metallurgy is the concept “Industry 4.0”. The basic components of the digital metallurgy are mathematical models of physical and chemical processes, running in metallurgical aggregates and databases of these processes. The Institute of Metallurgy of Ural branch of the Russian Academy of Sciences proposed an array of technical solutions for perfection of sintering and blast furnace production by application of digital technologies within the “Industry 4.0” concept. The proposed solutions are as follows: two-dimensional and three-dimensional analysis of forecast of blast furnace smelting phenomena, monitoring of BF hearth refractory lining state, optimization of composition and increase of metallurgical characteristics of iron ore sinter and coke. These technical solutions have been trialed at sintering plants, coke-production plants and at blast furnace shops of Russia and China.
. 目前,随着计算机和控制系统的发展,冶金生产的数字化和数字化改造的作用越来越大。向数字化冶金转型的最重要因素是“工业4.0”的概念。数字冶金的基本组成部分是物理和化学过程的数学模型,运行在冶金集合体和这些过程的数据库中。俄罗斯科学院乌拉尔分院冶金研究所提出了一系列技术解决方案,通过在“工业4.0”概念下应用数字技术来完善烧结和高炉生产。提出的解决方案有:对高炉冶炼现象进行二维和三维分析预测,监测高炉炉膛耐火衬状态,优化铁矿石烧结矿和焦炭的成分,提高其冶金特性。这些技术解决方案已在俄罗斯和中国的烧结厂、焦化厂和高炉车间进行了试验。
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引用次数: 3
Determination of adhesive characteristics of coatings by application a modern scratch test. Part 2. Examples of technological tasks solution by application scratch test 用现代划痕试验测定涂层的粘合特性。第2部分。通过应用程序划痕测试解决技术任务的示例
Pub Date : 2020-03-29 DOI: 10.32339/0135-5910-2020-3-242-250
V. Belov, E. Gubarev, O. Krivko, A. Papshev, N. Gofman, E. G. Samorodova
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引用次数: 1
期刊
Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information
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