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SECURITY OF SUCCESS — IN CLOSE TIES WITH SCIENCE AND PRODUCTION PLANTS Approaching 75th anniversary of the journal “Ferrous Metallurgy. Bulletin of Scientific, Technical and Economic Information” 成功的保障-与科学和生产工厂密切联系,接近《黑色冶金》杂志75周年。科技经济信息公报
Pub Date : 2019-06-27 DOI: 10.32339/0135-5910-2019-3-289-292
А. V. Bessonov
Scientific and technical journals are related to editions, which make considerableinfluence on equipment and technology of industrial production development. Under modern conditions, when a production science intensity becomes one of main factors of scientific and technical progress, the need in such editions becomes rather important. Facts of the history of the journal “Ferrous Metallurgy. Bulletin of Scientific, Technical and Economic Information” creation and formation shown, as one of most competent industry journals. Its input into forming of the scientific and technical information of domestic ferrous metallurgy system as well as into provision of ties between science and production plants shown. Main purpose of the journal is encouragement of innovation, fundamental and application investigations in the areas of improving ofmetallurgical equipment and technologies, provision of scientists and specialists of plants and organizations of steel industry and adjacent industries, professors, teachers and post-graduators of high schools by proved and reliable information about results of most promising and original investigations in areas of steel industry and metallurgical machine-building, by technical, economic and statistical information about results of domestic and world steel industries, knowledge on publications in the foreign periodic on scientific and technical subjects of the industry. The most important tasks of the journal are as follows: publication on the journal pages results of original scientific investigations and research and technical developments in the area of improving equipment and technology of metallurgical  production in the main stages of domestic and foreign steel industry; summarizing of results of scientific investigations and practical achievements at their implementation at plants of domestic and foreign steel industry; identification and promotion of perspective directions of scientific investigations; forming of atmosphere of open scientific discussion, stimulation of discussions; assistance to propagation of achievements of different scientific schools, publication of information about forthcoming scientific conferences, symposia, seminars and about their results. During the past 75 years from the Bulletin“Ferrous metallurgy” creation time, total 1432 issues of it were published.
科技期刊是与版本相关的,对工业生产发展的设备和技术有相当大的影响。在现代条件下,当一种生产科学强度成为科学技术进步的主要因素之一时,这种版本的需求就变得相当重要。《黑色冶金》杂志的历史事实。《科技经济信息公报》的创刊与形成,是我国最具竞争力的行业期刊之一。它对形成国内铁冶金系统的科学和技术信息的投入,以及对提供科学与生产工厂之间的联系的投入。该杂志的主要目的是鼓励在改进冶金设备和技术领域的创新、基础和应用研究,为钢铁工业和邻近工业的工厂和组织的科学家和专家、教授、教师和高中研究生提供有关钢铁工业和冶金机械制造领域最有前途和最原始的研究结果的可靠信息。了解国内和世界钢铁工业的技术、经济和统计资料,了解国外关于该行业科学和技术主题的刊物。本刊的主要任务是:在本刊上发表国内外钢铁工业主要阶段冶金生产设备和工艺改进方面的原创性科学调查研究成果和技术发展成果;总结了国内外钢铁工业工厂的科学调查结果和实践成果;科学研究前景方向的确定与推进形成开放的科学讨论氛围,激发讨论;协助宣传不同科学流派的成果,出版关于即将召开的科学会议、专题讨论会和讨论会及其结果的资料。《黑色冶金学通报》创刊75年来,共创刊1432期。
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引用次数: 5
Problems of implementation of best available technologiesat industrial plants 在工业工厂实施最佳可用技术的问题
Pub Date : 2019-06-27 DOI: 10.32339/0135-5910-2019-3-373-378
N. Tsarev, V. Aksenov
After the changes to the Federal law “On environment protection” came into force, the plants having considerable negative impact on environment, including plants of steel industry and non-ferrous metallurgy, from January 1, 2019 have to proceed to implementation of best available technologies. Among the problems, the information and analytical provision of such technologies implementation noticed. Formulation of “complex ecological permission” and “best available technology” (“BAT”) meanings considered. Items of registration considered, including order and terms, specified for BAT receiving, which substitutes the permission for emission of contaminants intoatmosphere, limits for contaminants emission, permission for contaminants discharge into environment, limits for contaminants discharge, norms for wastes formation and limits for their allocation. A list of supporting actions at implementation of measures on environment protection quoted, including state support ofactivity on BAT implementation and other measures decreasing negative impact on environment. Bureau of BAT elaborated information and technical reference books on BATs, which are available at internet-site http://burondt.ru/index/its-ndt.html. For steel industry and related industries list of the reference books on BATs recommended for familiarization. A reference to an electron resource, containing “List of main technological equipment, used at implementation of best available technologies” quoted. The document approved by the RF Government’ decree. Problems considered, related to BAT implementation, including absence of approved technological indices of BAT and incompleteness of list of equipment recommended for implementation.
在联邦法律“关于环境保护”的修改生效后,从2019年1月1日起,对环境有相当负面影响的工厂,包括钢铁工业和有色冶金工厂,必须着手实施最佳技术。在这些问题中,这种技术的信息和分析的提供引起了注意。考虑了“复杂生态许可”和“最佳可用技术”(“BAT”)含义的表述。所审议的登记项目,包括为BAT接收规定的命令和条款,以取代向大气排放污染物的许可、污染物排放的限制、污染物排放到环境中的许可、污染物排放的限制、废物形成的规范和废物分配的限制。列举了环境保护措施实施的支持行动清单,包括国家对实施“BAT”的支持活动和其他减少对环境负面影响的措施。蝙蝠局编写了蝙蝠的信息和技术参考书,可在网址http://burondt.ru/index/its-ndt.html上查阅。为钢铁行业及相关行业提供有关bat的参考书清单,供大家熟悉。引用电子资源的参考资料,其中包含“用于实施最佳可用技术的主要技术设备清单”。经RF政府法令核准的文件。所考虑的与BAT实施有关的问题,包括没有批准的BAT技术指标和建议实施的设备清单不完整。
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引用次数: 0
Study of hot briquetted iron secondary oxidation speed aimed at forecasting of its metallurgical value retention duration 研究热压块铁的二次氧化速度,以预测其冶金价值保持时间
Pub Date : 2019-06-27 DOI: 10.32339/0135-5910-2019-3-322-326
A. Timofeeva, T. V. Nikitchenko, A. Kozhukhov, N. Mazur
Hot briquetted iron (HBI), as also metallized pellets, undergo oxidation during transportation and storing. To forecast acceptable duration of HBI storing with metallurgical value retention it is important to have scientifically based data on the briquettes secondary oxidation speed. Methods of determining metallized pellets secondary oxidation speed are presented in domestic and foreign practice, but the matter of HBI secondary oxidation in scientific and technicalliterature practically is not covered. To determine HBI secondary oxidation speed two methods elaborated and tested at the Department of metallurgy and metal science of Stary Oskol Technological Institute after A.A. Ugarov (branch of National Research Technological University “MISiS”). The first– weighting method – based on determining of metal iron content change in HBI during a long term storing. During the experiment the mass of each briquette was weighted every 12 h within a month. The result of metal iron content determining by the experiment and by a chemical analysis had a difference of less than 1%. The weighting method enables to obtain the HBI reaction ability values without particular expenses, but requires carrying out long term enough experiments untilcomplete moisture removal out of the studied samples. The other method – determination of oxygen absorption speed bybriquettes in a closed vessel. It enables determining the reaction ability of the reduced iron within a comparatively short period, enables sufficient reliability duringthe briquettes testing. Based on it a methodology elaborated for determining of HBI secondary oxidation speed, meeting the requirements of real production. During loading-unloading operations, briquettes can partially go to ruin. The forming fragments of different sizes undergo a higher degree of oxidation that decreases the HBI metallurgical value. In view of this, studies of HBI oxidation speed continue depending on different sizes content and finalization of the methodology of determination of HBI secondary oxidation speed.
热压块铁(HBI)和金属化球团一样,在运输和储存过程中会发生氧化。为了预测具有冶金值保留的HBI可接受贮存时间,有科学依据的型煤二次氧化速度数据是很重要的。国内外实践中有金属化球团二次氧化速度的测定方法,但实际科技文献中对HBI二次氧化问题的研究较少。为了确定HBI二次氧化速度,在A.A. Ugarov(国立研究技术大学“MISiS”分校)之后,Stary Oskol技术研究所冶金和金属科学系制定并测试了两种方法。第一种加权法是基于测定HBI在长期贮存过程中金属铁含量变化的方法。试验期间,每个月每12 h称重一次。实验测定的金属铁含量与化学分析的测定结果相差不到1%。加权法可以在没有特别费用的情况下获得HBI反应能力值,但需要进行足够长时间的实验,直到所研究的样品完全去除水分。另一种方法。密闭容器中蜂窝煤吸氧速度的测定。它可以在相对较短的时间内确定还原铁的反应能力,使压块测试具有足够的可靠性。在此基础上,阐述了满足实际生产要求的HBI二次氧化速度的测定方法。在装卸过程中,煤块会部分损毁。不同尺寸的成形碎片发生较高程度的氧化,降低了HBI冶金值。鉴于此,HBI氧化速度的研究继续根据不同的尺寸含量和确定HBI二次氧化速度的方法。
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引用次数: 1
Development of electromagnetic stirring system at modernization ofhorizontal continuous caster 水平连铸机现代化中电磁搅拌系统的发展
Pub Date : 2019-06-27 DOI: 10.32339/0135-5910-2019-3-344-349
S. Shakhov, K. Vdovin, Yu. M. Rogachikov, D. Shakhov
Horizontal state of mold at continuous casting of steel in horizontal continuous casters (HCC) complicates the melt supply conditions and forming of billets, results in disturbing ofcasting process stability, in forming of zones of chemical and physical inhomogeneity, distortion of the billet geometric form, arising of longitudinal fractures, bleeding at the mold exit. A possibility to increase the quality of the billets, produced at HCCs relates to changing of conditions of the metal solidification, creation of forced melt movement, in particular, by application of electromagnetic field. To increase the casting stability andimprove quality of the billets from alloyed steels a modernization of a HCC accomplished. Within the modernization a system of electromagnetic stirring (EMS) for modernizedmold of the HCC was developed. The modernized mold for horizontal casting is equipped by a build-in two-phased stator of alternative current. The two phased EMS stator built-in into the mold shell, supplied by power from two-phased frequency convertor, developed and manufactured by “Electroprivod i silivaya electronica” LLC (Moscow). A water immersion winding is the main element of the EMS stator. The winding isolation resistance at the first stage of the water immersion stator running was more than 500 m ohm. The technology of the winding manufacturing provides a high coefficient of heat exchange between the copper wires and technical water, usedfor direct cooling. By this, high values of the winding magnetizing force is reached at a small volume that in its turn provides a wide range of stirring intensity control. The developed EMS system enables to decrease considerably the existing drawbacks of HCC.
卧式连铸机连铸钢时结晶器的水平状态使熔体供应条件和钢坯成形变得复杂,影响了铸造过程的稳定性,形成了化学和物理不均匀区,造成了钢坯几何形状的变形,产生了纵向断裂,出模处出血。在hcc生产的提高钢坯质量的可能性与改变金属凝固条件有关,特别是通过应用电磁场,产生强制熔体运动。为了提高铸钢的稳定性和提高钢坯的质量,完成了对连铸机的现代化改造。在现代化过程中,研制了一种用于HCC现代化模具的电磁搅拌系统。现代化的水平铸造模具配备了内置的交流两相定子。由“Electroprivod i silvaya electronica”LLC (Moscow)开发制造的两相EMS定子内置于模壳内,由两相变频器供电。浸水绕组是EMS定子的主要元件。水浸定子运行第一阶段绕组隔离电阻大于500 m欧姆。绕线制造技术提供了铜线和技术水之间的高热交换系数,用于直接冷却。通过这种方法,可以在小体积下获得较高的绕组磁化力,从而提供大范围的搅拌强度控制。发达的EMS系统能够大大减少HCC现有的缺点。
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引用次数: 1
Dynamics control in pipe cold rolling mill main drive 钢管冷轧机主传动的动态控制
Pub Date : 2019-06-27 DOI: 10.32339/0135-5910-2019-3-355-364
S. Rakhmanov
Elimination of unstable and critical states of deformed systems of pipes pilger cold rolling mill, heavy-loaded equipment of which functions under conditionsof increase dynamic loads, is mainly intended for mechanic system dynamics stabilization until the accepted level of loading. Active mechanicties in the initial dynamic model revealed, which stipulate the demonstration of pronounced parametric processes in the studied system of pipes cold rolling mill main driver. Analysis of reasons of parametric oscillations originating carried out for systems of pipes cold rolling mill main driver. Zones of dynamic instability of mechanic system functioning according to Eins–Strett diagram determined, that enable to make the choice of passive optimal rolling regimes at the stage of technological processes designing of pipes pilger cold rolling.A system of active control by main driver of pipes cold rolling mill elaborated based on its mathematical model. A structure of optimal control by angular oscillations driver line elements of pipes cold rolling mill selected and parameters ofactive control impacts of the automated servo control system determined. A mechanism of optimal control by dynamic state ofdriver line elements of pipes cold rolling mill proposed. Also proposed an outline of critical and instablestates elimination for the main driver line driver of pipes cold rolling mill, which is realized by means of adaptive active automated servo control facility. The modernized main driver line of pipes cold rolling mill is equipped by facilities and control systems, enabling to switch the initial mechanic system from a critical state into a zone ofdesired states in a servo regime. Sensors of threshold moments level of elasticity forcesare installed on the drive shaft of main driver of pipes cold rolling mill. During the drive shaft angular elastic oscillations, comprising of actual and desired parameters of mechanicsystem is made based on sensors signals. Next, a correspondent control impact is formed based on algorithm embedded into the electric drive servo control system. When the displayed point of the drive shaft reaches the desired area of system dynamic stability, the active drive control is switched off. If further the disturbing load, applied from the side of deformation seat, makes the drive line dynamic characteristics off the desired status, then the dynamic system control process is repeated in anautomated mode. Reliability of the results received confirmed by calculation example and experiments at the main driver of pipes cold rolling mill ХПТ-32.
钢管柱冷轧机是在动态载荷增大的条件下运行的重载设备,其变形系统的不稳定和临界状态的消除主要是为了使机械系统的动态稳定,直至达到可接受的载荷水平。在初始动力学模型中揭示了主动机制,规定了所研究的管道冷轧机主驱动系统具有明显的参数化过程。对钢管冷轧机主传动系统产生参数振荡的原因进行了分析。确定了按Eins-Strett图作用的机械系统的动态不稳定区域,为钢管柱冷轧工艺设计阶段被动优化轧制方案的选择提供了依据。在建立冷轧机主驱动主动控制系统数学模型的基础上,阐述了一种主驱动主动控制系统。选取了钢管冷轧机的角振荡驱动线元优化控制结构,确定了主动控制参数对自动伺服控制系统的影响。提出了一种管材冷轧机驱动线元动态最优控制机制。提出了用自适应主动自动伺服控制装置实现冷轧管机主驱动线驱动的临界和不稳定消除的概要。现代化的管材冷轧机主驱动线配备了相应的设备和控制系统,能够将初始机械系统从临界状态切换到伺服状态的期望状态区。在钢管冷轧机主驱动器的传动轴上安装了弹性力阈值力矩级传感器。在传动轴角弹性振荡过程中,根据传感器信号得到由机械系统实际参数和期望参数组成的参数。其次,基于嵌入电驱动伺服控制系统的算法,形成相应的控制冲击。当传动轴的显示点达到系统动态稳定的期望区域时,主动驱动控制被关闭。如果从变形座侧面施加的扰动载荷进一步使驱动线的动态特性偏离预期状态,则以自动化方式重复动态系统控制过程。通过算例和在冷轧管材主机厂ХПТ-32上的试验,验证了所得结果的可靠性。
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引用次数: 0
Study of properties of cored wire based on ferrochrome gas-cleaning dust 基于铬铁气体净化粉尘的包芯焊丝性能研究
Pub Date : 2019-06-27 DOI: 10.32339/0135-5910-2019-3-365-372
N. Kozyrev, A. A. Usol’tsev, A. Prudnikov, R. Kryukov, A. Mikhno
Applying of wear-resistant alloyed coatings by build-up welding is one of methods to provide high operation properties of technological, metallurgical in particular equipment. Technologies of strengthening by direct alloying or reducing of alloying materials from oxide phases by reducing agent directly in the arc during building-up are most efficient ones. For build-up, cored wires are used frequently nowadays. A possibility to manufacture cored wires based on ferrochrome production gas-cleaning dust and powders of silicon, aluminum, and aluminum production gas-cleaning dust as reducing agents considered. Chemical composition and relation between cored wires components quoted. Manufacturing of 5 mm diameter wire accomplished at laboratory facility by running through draw plate. Duringestimation of efficiency of the manufactured cored wires application a regime of build-up was selected, study of chemical composition of built-up metal carried-out, wearing tests made, measuring of built-up samples hardness carried-out. Coefficients of chrome recovery coefficient at different relation between filling materials were calculated. Statistical processing of the study results accomplished statistical dependences of components content influence onthe built-up layer properties plotted. Study of the built-up showed, that chrome recovery in the built-up layer depends completely on the cored wire filling coefficient. At that under other conditions being equal, the hardness always correlates with the wear, and increase of chrome concentration results in reduction of the surface wear. Dependents of mass share elements comprising the cored wire content on built-up layer hardness and its wear resistance determined. The dependences obtained can be used for forecasting of builtup layer hardness and its wear resistance while built-up metal chemical composition varying.
堆焊涂覆耐磨合金涂层是提高工艺、冶金设备运行性能的方法之一。直接合金化强化或在堆焊过程中直接用还原剂还原氧化相的合金化材料是最有效的强化技术。为了积累,现在经常使用芯线。考虑了以铬铁生产气体净化粉尘和硅粉、铝粉和铝生产气体净化粉尘为还原剂制造芯线的可能性。引用了芯线成分的化学成分及其相互关系。在实验室设备上通过拉拔板制造直径5mm的线材。在评估制造的芯线的应用效率时,选择了一种积累制度,研究了积累金属的化学成分,进行了磨损试验,测量了积累样品的硬度。计算了不同充填材料关系下的铬回收系数。对研究结果进行统计处理,绘制出组分含量对堆积层性质影响的统计依赖关系。对堆积层的研究表明,堆积层的铬回收率完全取决于芯线填充系数。在其他条件相同的情况下,硬度与磨损量呈正相关,铬浓度的增加使表面磨损量减小。组成芯线含量的质量份额元素对堆积层硬度及其耐磨性的依赖。所得相关性可用于预测堆积层硬度及其耐磨性随堆积层化学成分变化的变化。
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引用次数: 6
Elaboration of a technology for production conditional ilmenite concentrate by enrichment of titanium-magnetite ores 钛磁铁矿富集生产有条件钛铁矿精矿的工艺研究
Pub Date : 2019-06-20 DOI: 10.32339/0135-5910-2019-5-572-576
E. Degodya, O. P. Shavakuleva
The titanium-magnetite ores keep an important place among complex iron-containing ores. Utilization of these ores, comprising ores of Kopanskoe deposit, in steel industry is a serious problem, requiring for its solving enrichment resulting in obtaining iron-vanadium and ilmenite concentrates. A principal flow-chart of titanium-magnetite ores enrichment with obtaining conditional iron-vanadium and ilmenite concentrates elaborated. Results of flotation tests of non-magnetic fraction of Kopanskoe deposit titanium-magnetite ores, which is difficult for concentration. Application of flotation process for Kopanskoe deposit titaniummagnetite ores enrichment, which is difficult for concentration, enables not only to improve the enrichment indices, but considerably simplify the process chain of the plant equipment by excluding a big number of gravitational facilities. It was shown, that ilmenite and rutile flotation is successfully carried out in an acidic environment with the use of oleic acid, kerosene, sodium fluoride, sulfuric acid, foam activator VKP. The elaborated reagent complex provides obtaining conditional ilmenite concentrate. As a result of enrichment by application the elaborated magnetic flotation technology, iron-vanadium concentrate with a mass fraction of iron equal to 63.4 % and titanium dioxide – 4.5 % as well as ilmenite concentrate with a mass fraction of titanium dioxide equal to 45.2% obtained. The elaborated technology can be used for titanium-magnetite ores of Medvedevskoe, Kusinskoe, Chernorechenskoe deposits.
钛磁铁矿在复杂含铁矿石中占有重要地位。这些矿石(包括Kopanskoe矿床的矿石)在钢铁工业中的利用是一个严重的问题,需要解决其富集问题,从而获得铁钒和钛铁矿精矿。阐述了获得条件铁钒钛精矿富集钛磁铁矿的主要流程。Kopanskoe矿床难选钛磁铁矿非磁性部分浮选试验结果对于难选的Kopanskoe矿钛磁铁矿,采用浮选工艺富集,不仅提高了富集指标,而且省去了大量的重力设施,大大简化了厂内设备的工艺链。试验结果表明,在酸性环境下,采用油酸、煤油、氟化钠、硫酸、泡沫活化剂VKP,可成功浮选钛铁矿和金红石。所制备的复配试剂可获得有条件的钛铁矿精矿。采用精心设计的磁浮工艺进行富集,获得了铁质量分数为63.4%、钛白粉质量分数为4.5%的铁钒精矿和钛白粉质量分数为45.2%的钛铁矿精矿。该工艺可用于Medvedevskoe、Kusinskoe、Chernorechenskoe矿床的钛磁铁矿。
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引用次数: 1
Study of a possibility of enrichment of fine-crushed magnetite ore by dry magnetic separation 细粒磁铁矿干式磁选富集可能性的研究
Pub Date : 2019-06-20 DOI: 10.32339/0135-5910-2019-5-564-571
N. V. Sedinkina, O. Gorlova, N. Gmyzina, E. Degodya
Dry magnetic separation (DMS) enables to separate the non-magnetic fraction of iron ores at the initial stage of their concentration and therefore to decrease cost of their further processing. However, a considerable amount of metal is lost in DMS tails at that. The efficiency of DMS considerably depends on difference between the upper and lower limits of the ore coarseness) ore coarseness range), delivered for concentration. At the Magnitogorsk steel-works crushing and concentration plant No. 5 this range is from 50 mm up to 15 mm. To determine the optimal ore size, delivered to DMS, studies accomplished to determine the specific magnetic susceptibility of the magnetite and the burden for the magnetite ore of Maly Kuibas deposit. After the study of different size iron ore separation, a reasonability of the DMS feed size decreasing down to 30–7 mm shown. A possibility to obtain additional product of 7–0 mm size determined, suitable for sintering. It will enable to decrease the amount of material, delivered for crushing and wet magnetic separation, as well as to decrease expenses for transporting and storage of wet separation tails. Peculiarities of fine magnetite ore processing by DMS in a suspended state considered, optimal parameters of the separator determined and its high efficiency for magnetite ore of 7–0 mm size concentration shown.
干式磁选技术能够在铁矿石选矿的初始阶段分离出非磁性部分,从而降低其进一步加工的成本。然而,相当数量的金属在DMS尾部损失。DMS的效率在很大程度上取决于矿石粗度(矿石粗度范围)的上下限之间的差异。在马格尼托哥尔斯克钢铁厂5号粉碎和浓缩厂,这个范围从50毫米到15毫米。为确定最佳矿石粒度,对马力奎巴斯磁铁矿进行了比磁化率和矿体配比的研究。通过对不同粒度铁矿的分选研究,表明了DMS给矿粒度降至30 ~ 7mm的合理性。有可能获得额外的产品7-0毫米的大小确定,适合烧结。它可以减少用于破碎和湿式磁选的物料量,也可以减少湿式磁选尾料的运输和储存费用。考虑了悬浮状态下DMS分选细粒磁铁矿的特点,确定了DMS分选机的最佳参数,证明了DMS分选机对7 ~ 0 mm细粒磁铁矿的选矿效率高。
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引用次数: 2
Study of BOF slags properties with the purpose of their utilization technology perfection 研究转炉炉渣的性能,完善其利用技术
Pub Date : 2019-06-20 DOI: 10.32339/0135-5910-2019-5-623-631
N. Gmyzina, N. Sedinkina, O. Gorlova
Actuality of steel-making slags utilization is stipulated not only by the necessity to improve ecology situation at the sites of slag piles, but also by a possibility to obtain additional raw materials for metallurgical production. Increase of the domestic iron-containing raw materials at Magnitogorsky steel-works can be done by more effective processing of steel-making slags. To improve the technology of BOF slags processing, a work done to study their chemical and mineral composition. It was established, that primary and secondary BOF slags are attributed to basic and ultra-basic, since the SiO2 mass share is less than 25–40%. Petrographic study results and data of IR-spectroscopy showed, that larnite, alite, monticellite and oxide RO-phase (Fe2+, Mn2+, Mg2+)O are main mineral components of the BOF slags. In many cases, the structure of the secondary BOF slags has middle-size grains, and the structure of primary slags is fine-grained. The texture of the secondary and primary slag is more often massive. The BOF slags have globules of iron, the size of which varies from sub-millimeters up to 5 mm. Study of influence of various methods of BOF slag particles destruction on the degree of globules disclosure showed, that application of centrifugal-striking crushing facilities provides more selective globules disclosure comparing with other methods. It was proved, that dry magnetic separation in suspended state, due to its peculiarities, provides higher technological indices comparing with drum separator when separating fine slags even at increase material moisture up to 5%.
炼钢渣利用的现状不仅取决于改善渣堆所在地生态环境的必要性,也取决于是否有可能获得冶金生产所需的额外原料。通过对炼钢渣进行更有效的处理,可以提高马格尼托格尔斯基钢铁厂国内含铁原料的产量。为了改进转炉炉渣的处理工艺,对其化学和矿物组成进行了研究。由于SiO2质量份额小于25-40%,初步确定转炉炉渣为碱性和超碱性。岩石学研究结果和红外光谱数据表明,转炉炉渣的主要矿物成分为褐铁矿、褐铁矿、蒙脱石和氧化物ro相(Fe2+、Mn2+、Mg2+)O。在许多情况下,转炉二次炉渣的结构具有中等大小的颗粒,而一次炉渣的结构具有细颗粒。二次渣和一次渣的结构往往是块状的。转炉炉渣有铁球,大小从亚毫米到5毫米不等。通过对转炉炉渣颗粒破碎方式对球团暴露程度的影响研究表明,采用离心破碎设备比其他方法提供了更有选择性的球团暴露。试验证明,在物料含水率提高至5%以上时,悬浮状态下的干式磁选由于其自身的特性,在细矿渣的分选过程中,其工艺指标优于鼓式磁选机。
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引用次数: 0
Estimation of a possibility to use the quantumchemical approach while selecting reagents for coals flotation intensification 在选择煤浮选强化试剂时,估计使用量子化学方法的可能性
Pub Date : 2019-06-20 DOI: 10.32339/0135-5910-2019-5-577-582
N. Medyanik, E. Mullina, O. Mishurina, N. V. Derina, A. A. Turlina
Decrease of mined coal quality results in deterioration of main quality characteristics of coal concentrates: ash content, moisture, calorific efficiency and sintering ability. Application of selective reagent modes of coals flotation is an effective method of solving the problem. Elaboration of the reagent modes should be based on a study of mechanism of reagents action on the coal surface. Study of the aromatic esters effect on the physicochemical and flotation properties of gas coals from the Komsomolets mine of the Kuznetsk coal basin accomplished. It was shown that the low natural floatability of gas coals is due to the significant energy unsaturation of their surface, in particular, the presence of large pores, oxygen-containing groups and mineral impurities. The results of quantum chemical calculations demonstrate that the electrophilic centres of the coal are formed due to the electron density shift to the oxygen atoms. It was determined that the hydrophobization of the coal surface can be achieved using reagents that have more rigid nucleophilic nature compared to water molecules. The study of the quantum-chemical characteristics of aromatic esters suggests that they can interact with electrophilic areas of the organic mass of coal through a charge-controlled mechanism with the formation of charge transfer complexes. Results of the study of the aromatic esters effect on the physicochemical properties of coals surface and calculation of quantum-chemical characteristics of compositions, simulating the organic coals mass and studied reagents, allow to make a conclusion about possibility to intensify the coals flotation process based on application the quantum-chemical approach at the reagents selection.
采煤质量降低,导致煤精矿灰分、水分、热效率、烧结性能等主要质量指标的恶化。采用选择性药剂模式浮选煤是解决这一问题的有效途径。试剂模式的细化应以试剂在煤表面作用机理的研究为基础。研究了芳香酯对库兹涅茨克煤盆地共青团矿瓦斯煤理化性能和浮选性能的影响。结果表明,天然气煤的自然可浮性低是由于其表面存在明显的能量不饱和,特别是存在大孔隙、含氧基团和矿物杂质。量子化学计算结果表明,煤的亲电中心是由于电子密度向氧原子转移而形成的。结果表明,与水分子相比,煤表面的疏水性可以使用具有更刚性亲核性质的试剂来实现。芳香酯的量子化学特性研究表明,芳香酯可以通过电荷控制机制与煤的亲电区相互作用,形成电荷转移配合物。研究了芳香酯对煤表面物理化学性质的影响,计算了组分的量子化学特性,模拟了有机煤的质量和所研究的试剂,得出了在试剂选择上应用量子化学方法加强煤浮选过程的可能性。
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引用次数: 1
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Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information
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