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Effect of Electrode Potential and Structure on the Susceptibility to HESCC in Duplex Stainless Steels Analytical Evaluation of Hydrogen Embrittlement Type SCC and Its Mechanism in Duplex Stainless Steel Welds 电极电位和结构对双相不锈钢中HESCC敏感性的影响双相不锈钢焊缝氢脆型SCC的分析评价及其机理
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.9.245
Y. Mukai, M. Murata, Jing-bo Wang
In this paper the authors discussed the depedence of crack initiation properties on potential and the effect of microstructures on the crack initiation and propagation properties in duplex stainless steels. It was clear that at less noble potential crack initiation occured from ferritic phase near the tip of austenitic phase which was controled by HESCC in this region. On the other hand, at noble potential crack initiated from corrosion pets which was formed at the boundary of ferritic and austenitic phases. As the effect of potential on the time to failure with decreasing the potential the time to failure decreased greatly both in a single ferritic phase stainless steel and duplex stainless steels, but even at the potential of -1.5V vs SCE there were no failures to he observed in a single austentic phase stainless steel, which means that austenitic phase is unsusceptible to HESCC. Additionally, as the effecc of ferrite content on HESCC properties of duplex stainless steels, with decreasing ferrite content the threshold stress increased and crack growth rate decreased greatly, which means that austenitic phase has a keying effect on crack propagating through ferritic phase. At the region of ferrite content less than 45%, threshold stress was nearly as same as the tensile strength of the materials and crack could not propagate through austenitic phase because of the continuousness of the austenitic phase which will prevent crack propagating through ferritic phase. Therefore, ferrite content of 45% should be considered as a critical value for crack initiating and propagating in duplex stainless steels.
本文讨论了双相不锈钢裂纹起裂性能与电位的关系以及微观组织对裂纹起裂和扩展性能的影响。结果表明,在较低的电位下,裂纹起源于奥氏体尖端附近的铁素体相,该区域受HESCC控制。另一方面,在铁素体与奥氏体相界处形成的腐蚀带引发了高电位裂纹。电势对失效时间的影响随着电势的减小,单铁素体相不锈钢和双相不锈钢的失效时间都大大缩短,但即使在-1.5V vs SCE的电势下,单奥氏体相不锈钢中也没有观察到失效,这意味着奥氏体相对HESCC不敏感。此外,由于铁素体含量对双相不锈钢HESCC性能的影响,随着铁素体含量的降低,阈值应力增加,裂纹扩展速率大大降低,这意味着奥氏体相对裂纹通过铁素体相扩展起关键作用。在铁素体含量小于45%的区域,阈值应力与材料的抗拉强度基本一致,由于奥氏体相的连续性,裂纹无法通过奥氏体相扩展,从而阻止了裂纹通过铁素体相扩展。因此,45%的铁素体含量是双相不锈钢裂纹萌生和扩展的临界值。
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引用次数: 1
Influence of the Cross-sectional Area of Consumable Nozzle on Welding Phenomena in Electrosalg Welding 电液焊中焊嘴截面积对焊接现象的影响
Pub Date : 1900-01-01 DOI: 10.2207/qjjws1943.50.373
S. Nakata, Nobuharu Sakabata, Minoru Mouko
Influence of the cross-sectional area of consumable nozzle on the penetration in base plate and its stability and the possibility on the control of welding phenomena by changing the nozzle current is investigated using the mild steel plate with the thickness of 30 mm to develop narrow gap electroslag welding process with high efficiency and low heat input.It is experimentaly shown that the nozzle with large crosssectional area is useful in stable and high current welding process because of dispersing the welding current in slag pool by increasing the nozzle current. So, the method for estimating the nozzle current during welding is designed and, by this method, the nozzle current is estimated under various conditions in connection with the cross-sectional area of the nozzle.Adopting above results to high current narrow gap welding process, it is clarified that more stable and uniform penetration can be obtained by using the nozzle with large cross-sectional area. This result is due to the preheating effect at root faces of base plate in slag pool and dispersing the heat source in slag pool by increase of nozzle current.
采用30 mm厚的低碳钢板,研究了耗材喷嘴截面积对基板熔透及其稳定性的影响,以及通过改变喷嘴电流控制焊接现象的可能性,开发了高效低热输入的窄间隙电渣焊工艺。实验表明,大截面积喷嘴可以通过增大喷嘴电流分散熔渣池中的焊接电流,有利于稳定大电流焊接。因此,设计了焊接过程中喷嘴电流的估算方法,并利用该方法估算了与喷嘴截面积有关的各种条件下的喷嘴电流。将上述结果应用于大电流窄间隙焊接工艺,说明采用大截面积喷嘴可以获得更稳定、均匀的焊透。这是由于渣池底板根部表面的预热作用和喷嘴电流的增大使渣池热源分散的结果。
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引用次数: 0
Carbide Precipitation and Corrosion Resistance in HAZ of 15Cr-75Ni Alloy 15Cr-75Ni合金热影响区碳化物析出及耐蚀性
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.6.530
K. Ogawa, M. Miura, T. Minami
Carbide precipitation in niclel based alloy takes place at elevated temperature. The tendency of this phenomenon is stronger than in austenitic stainless steel. But the carbide precipitation in HAZ of nickel based alloy has not been investigated enough as that of austenitic stainless steel.The effect of weld thermal cycle on carbide precipiration of 15Cr-75Ni alloy (UNS N06600) and its relation with intergranular corrosion in nitric acid were investigated. And prevention of sensitization in HAZ was investigated from the view point of chemical composition.The susceptibility to intergarnular corrosion in HAZ agreed with the carbide behavior during weld thermal cycle and aging so far as the aging heat treatment condition of this work. The carbide in the base metal overaged is solid soluted and nucleates at the grain boundary by weld thermal cycle, and the carbide precipitated and grew during aging. The chrominm depleted zone has not healed after aged for 15 hours at 823K, so the carbide caused the intergranular sensitization.The sensitization in HAZ of 15Cr-75Ni Alloy can be prevented by the suitable addition of Nb; Nb/ C<40 in weight ratio.
镍基合金中的碳化物在高温下析出。这种现象的倾向比在奥氏体不锈钢中更强烈。但对镍基合金热影响区碳化物析出的研究还不像奥氏体不锈钢那样深入。研究了焊接热循环对15Cr-75Ni合金(UNS N06600)碳化物析出的影响及其与硝酸晶间腐蚀的关系。并从化学成分的角度探讨了热影响区致敏的预防措施。热影响区对晶间腐蚀的敏感性与本工作时效热处理条件下焊缝热循环和时效过程中碳化物的行为一致。焊缝热循环时效后,基体中的碳化物在晶界处固溶成核,碳化物在时效过程中析出长大。823K时效15小时后,贫铬区仍未愈合,碳化物引起了晶间敏化。适当添加Nb可防止15Cr-75Ni合金热影响区敏化;重量比Nb/ C<40。
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引用次数: 1
Effect of Continuous Postheating Time on Reduction of Preheating Temperature. 连续预热时间对降低预热温度的影响。
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.9.442
Y. Nishio, Kozo Kito, S. Kanemitsu
Continuous postheating for 1-5 hours at same temperature as preheating was carried out on weld cracking test of 80 kgf/mm2 tension steel, and following result were obtained.(1) Continuous postheating was recognized to be very useful to reduce the preheating temperature to prevent weld cracking.(2) The preheating temperature was reduced to 80°C by 1 hour postheating from 150°C which is the temperature without any postheating, and to 60°C by 5 hour postheating.
对80 kgf/mm2张力钢的焊缝开裂试验进行了与预热温度相同的连续预热1 ~ 5小时,得到了以下结果:(1)连续预热对降低预热温度防止焊缝开裂非常有用(2)预热1小时将预热温度从未预热时的150℃降至80℃,预热5小时降至60℃。
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引用次数: 1
Mechanical properties of weld metals subjected to thermal prestraining cycles and its application to deformation analysis of weld joint. 热预紧循环作用下焊缝金属的力学性能及其在焊缝变形分析中的应用。
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.3.862
Y. Itoh, K. Nagata, Tetsu Yanuki, Tadao Mori
Mechanical and metallurgical heterogeneity in wled joints, which is caused by thermal prestraining cycles, have an important effect upon their deformation and strength behaviors. If the mechanical properties of steels and weld metals subjected to thermal prestraining cycles can be estimated conveniently, it is easy to analyze the deformation behaviors of weld joints by use of numerical computation procedures.In this study three kinds of weld metals, which are formed at weld joints of a carbon steel (SM41B), an austenitic stainless steel (SUS304) and a martensitic cast steel (SCS5), were used for experiments. Their mechanical properties depended upon the thermal prestraining conditions, for example, peak temperature, retention time at constant temperature, multi-thermal prestraining cycles. The experimental results indicated that elastic limit, yield stress, strength coefficient and strain hardening exponent of materials sub-jected to thermal prestraining cycles could be expressed as a function of Vickers hardness.As an application, the material constants for elastic-plastic FEM analysis were determined from the Vickers hardness distribution of weld and butt weld joint were analyzed in terms of plastic zone extension from the view of mechanical heterogeneity.
热预紧循环引起的焊缝力学和金相非均质性对焊缝的变形和强度行为有重要影响。如果能方便地估计钢和焊缝金属在热预紧循环作用下的力学性能,就很容易利用数值计算程序分析焊缝的变形行为。本研究采用碳钢(SM41B)、奥氏体不锈钢(SUS304)和马氏体铸钢(SCS5)焊缝处形成的三种焊缝金属进行实验。其力学性能与热预紧条件有关,如峰值温度、恒温保持时间、多次热预紧循环等。实验结果表明,热预紧循环作用下材料的弹性极限、屈服应力、强度系数和应变硬化指数均可表示为维氏硬度的函数。作为应用,从焊缝的维氏硬度分布确定了弹塑性有限元分析的材料常数,从力学非均质性角度分析了对接焊缝的塑性区扩展情况。
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引用次数: 6
Effect of Plastic Deformation on Fatigue Crack Closure Behavior in Low Yield Strength Material and Its Welded Joint 塑性变形对低屈服强度材料及其焊接接头疲劳裂纹闭合行为的影响
Pub Date : 1900-01-01 DOI: 10.2207/qjjws.9.423
Y. Mukai, M. Murata
Crack closure behavior in fatigue crack propagation process was induced by plastic deformation near crack. In the paper, the effect of plastic deformation on fatigue crack closure in low strength material and its welded joint was studied.The results are as follows. Crack closure would be caused by plastic deformation near crack surface. Generally, crack opening ratio in high yield strength material is higher than that in low yield one. This tendency based on the degree of deformation near crack surface. In addition, in welded joint, crack propagation rate was higher than mother metal, though crack opening ratio showed almost 1 by the effect of residual stress. This could be explained by the effect of restrain for plastic deformation, which was induced by existence of compresive stress field ahead of crack.
疲劳裂纹扩展过程中的裂纹闭合行为是由裂纹附近的塑性变形引起的。本文研究了塑性变形对低强度材料及其焊接接头疲劳裂纹闭合的影响。结果如下:裂纹表面附近的塑性变形会导致裂纹闭合。一般来说,高屈服强度材料的裂纹张开率高于低屈服强度材料。这种趋势基于裂纹表面附近的变形程度。此外,在焊接接头中,裂纹扩展速率高于母材,但由于残余应力的影响,裂纹张开比几乎为1。这可以用裂纹前压应力场的存在对塑性变形的抑制作用来解释。
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引用次数: 0
Automatic real-time bead height control with arc sensor in TIG welding. TIG焊中电弧传感器自动实时控制焊头高度。
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.4.20
H. Nomura, Y. Sugitani, Yasuo Suzuki
Arc sensor, which utilizes the welding arc as a sensor, gives important groove information during welding. Automatic seam tracking control system with arc sensor developed by NKK has a fesature, that a turning point of transverse weaving with constant arc length control (AVC) is decided by the condition, when torch height reaches to constant set level. Under applying above control system, variation of groove and deposition area can be detected from the trace of weaving. The automatic real-time bead height control system has been developed utilizing above detected information. The area and width of weaving trace has close corelation with the area of groove and deposition. Experiments conducted with varied groove width proved satisfactory control ability for all position TIG welding.
电弧传感器是利用焊接电弧作为传感器,在焊接过程中提供重要的坡口信息。NKK公司开发的电弧传感器自动缝迹控制系统的特点是,当焊枪高度达到设定的恒定水平时,由条件决定一个定弧长控制横织的拐点。在应用上述控制系统后,可从织造痕迹中检测出沟槽和沉积面积的变化。利用上述检测信息,开发了水头高度自动实时控制系统。织迹的面积和宽度与沟槽和沉积的面积密切相关。实验结果表明,不同坡口宽度对TIG全位置焊接具有良好的控制能力。
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引用次数: 3
Predicting Heating and Cooling Times due to Local Preheating 预测加热和冷却时间由于局部预热
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.9.446
T. Terasaki, K. Ishimoto
Preheating procedure is applied to prevent cold cracking in steel construction. Then local preheating near the weld line is generally applied, because preheating whole the construction can not be did simultaneously. In case of using electric heaters as means of fecal preheating, the temperature of their heaters can be controlled by sensor fitted on some distance from the weld line. So it is necessary to estimate the temperature on weld line by temperature on the position of sensor.In this report, we derive the theoretical formula that finds the temperature of the other position but weld line during preheating, and cooling temperature and time on the weld line can be estimated by using the calculated values. We compared experimental data under various welding conditions with calculated values.
为了防止钢结构的冷裂,采用了预热程序。然后在焊缝附近进行局部预热,因为整个施工的预热不能同时进行。如果使用电加热器作为粪便预热的手段,加热器的温度可以通过安装在离焊缝一定距离的传感器来控制。因此,有必要通过传感器位置上的温度来估计焊缝上的温度。本文推导了预热过程中除焊缝外其他位置温度的理论计算公式,并利用计算值估计焊缝上的冷却温度和冷却时间。将不同焊接条件下的实验数据与计算值进行了比较。
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引用次数: 3
Automatic Real-Time Bead Height Control with Arc Sensor (Report 2) : Development of Multi-Pass MAG Arc Welding System 基于电弧传感器的自动实时焊头高度控制(报告二):多道MAG弧焊系统的开发
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.4.508
H. Nomura, Y. Sugitani, N. Tamaoki
The automatic seam tracking system by arc sensor method developed by NKK has an original feature, that a weaving arc in a groove performs groove surface tracking under constant arc length control (AVC or ACC) and the turning point of weaving is controlled by the condition when torch height reaches to constant preset level. In this system, weaving width well corresponds to groove width independently to variation of deposited amount of metal. Namely, variation value of weaving width is same as that of groove width. Based on this relationship, welding speed control system has been developed. Where, only the variation value of weaving width is used as detected parameter, and optimum value of welding speed to keep bead height constant is calculated and output at every cycle of weaving. The pulsed MAG arc welding system for multi-pass welding of V shaped butt joint has been developed. Main function of this system is adaptive microcomputer control with above mentioned arc sensor method, such as seam tracking, weaving width control and bead height control for every pass of welding.In addition, following functions are also composed: built-up sequence control where number of passes is automatically decided from weaving width, simplified operating system by man-machine dialogic style with liquid crystal display and a key board, and use of a couple of optical fiber cable for transmission of multiple control signals. This system has been already applied to the fabrication of steel box columns.
NKK公司开发的电弧传感器自动缝迹跟踪系统具有在定弧长控制(AVC或ACC)下,在槽内编织电弧进行槽面跟踪,并在火炬高度达到恒定预设水平时控制编织拐点的独创特点。在该系统中,编织宽度与沟槽宽度相对应,与金属沉积量的变化无关。即织造宽度的变化值与槽宽的变化值相同。基于这种关系,研制了焊接速度控制系统。其中,仅以编织宽度的变化值作为检测参数,计算每个编织周期保持头高不变的焊接速度的最优值并输出。研制了用于V型对接接头多道次焊接的脉冲MAG弧焊系统。该系统的主要功能是采用上述电弧传感器方法对焊缝跟踪、编织宽度控制、焊头高度控制等进行自适应微机控制。此外,还包括以下功能:内置顺序控制,根据编织宽度自动决定通道数;采用人机对话方式简化操作系统,采用液晶显示和键盘;使用几根光纤电缆传输多个控制信号。该系统已应用于钢箱柱的制造。
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引用次数: 5
期刊
Transactions of the Japan Welding Society
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