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The Nitrogen Absorption of Stainless Steel Weld Metal during Gas Tungsten Arc Welding 不锈钢焊缝金属在钨极气体保护焊中的氮吸收
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.2.669
T. Kuwana, H. Kokawa, Kensuke Naitoh
Using an arc atmosphere controlling chamber, effects of the welding conditions and atmosphere on the nitrogen content of the stainless steel weld metal by gas tungsten arc welding were investigated in comparison with those on the iron weld metal. The results are as follows:(1) The temperatures of stainless steel and iron molten pools were measured as about 1530°C and 1630°C, respectively.(2) The nitrogen content of stainless steel weld metal decreased with increasing the welding current, as well as that of iron weld metal.(3) The nitrogen content of stainless steel weld metal hardly depended on the arc length, as well as that of iron weld metal.(4) The nitrogen content of stainless steel weld metal increased with increasing the travel speed, while that of iron weld metal hardly depended on the travel speed.(5) The nitrogen content of stainless steel weld metal increased with the nitrogen partial pressure at low nitrogen partial pressure region, and was constant at the nitrogen partial pressure region above 0.2 atm in N2-Ar gas mixture atmosphere, as well as that of iron weld metal.(6) The nitrogen absorption by stainless steel weld metal was discussed with equilibrium data.
利用电弧气氛控制室,研究了焊接条件和气氛对不锈钢钨极气体保护焊焊缝金属氮含量的影响,并与对铁焊缝金属氮含量的影响进行了比较。结果表明:(1)不锈钢熔池温度约为1530℃,铁熔池温度约为1630℃。(2)不锈钢焊缝金属氮含量随焊接电流的增大而降低,铁焊缝金属氮含量随焊接电流的增大而降低。(3)不锈钢焊缝金属氮含量与电弧长度的关系不大;(4)不锈钢焊缝金属含氮量随运动速度的增加而增加,而铁焊缝金属含氮量与运动速度的关系不大。(5)在低氮分压区,不锈钢焊缝金属含氮量随氮气分压的增加而增加,在N2-Ar混合大气中,氮气分压在0.2 atm以上时,不锈钢焊缝金属含氮量保持不变。(6)用平衡数据讨论了不锈钢焊缝金属对氮的吸收。
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引用次数: 13
Bonding Mechanism and Microstructure of Bonded Zone of AIN Ceramics with Ti-AgCu Brazing Metal AIN陶瓷与Ti-AgCu钎焊金属的结合机理及结合区微观结构
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.9.494
H. Okamura, Hideki Shinohara, Takao Funamoto, T. Shida
Metallization and bonding of AIN ceramics were made using active brazing metal (Ti-AgCu). Active brazing metal used in metallization and bonding was in paste form prepared by adding Ti powder and organic solvent in to eutectic silver brazing metal powder.Characterization and bonding mechanism of the bonded layer, and relation between the thichness of the reacted layer and bonding strength were studied.The results of this study are as follows :(1) The microstructure of the bonded layer between AIN ceramics and Ti-AgCu brazing metal is found to be TiN layer of about 0.2 to 0.8 μm in thickness at the AIN interface, a composite layer of TiC, AICu as a middle layer and Ag-Cu alloy layer at the surface side.(2) Thickness of TiN layer did not change by the amount of Ti addition in silver brazing metal but the thicness of TiCu and AlCu layers are increased with increase of Ti addition in silverbrazing metal. Activation energy of growth of TiN layer is found to be 20 kJ/mol.(3) When the amount of Ti addition is more than 15 mass%, the bonding strength is decresed and the bonded layer is broken. Because the thickness of brittle TiCu layer increases with the increase of the Ti cotent in silver brazing metal.
采用活性钎焊金属(Ti-AgCu)对AIN陶瓷进行了金属化和键合。通过在共晶银钎焊金属粉中加入Ti粉和有机溶剂,制备了用于金属化和键合的活性钎焊金属。研究了反应层的表征和键合机理,以及反应层厚度与键合强度的关系。研究结果表明:(1)AIN陶瓷与Ti-AgCu钎焊金属的结合层微观结构为AIN界面处厚度约0.2 ~ 0.8 μm的TiN层,为TiC复合层;(2) TiN层厚度不随银钎焊金属中Ti添加量的增加而变化,而tiu和AlCu层厚度随银钎焊金属中Ti添加量的增加而增加。(3)当Ti的加入量大于15质量%时,结合强度降低,结合层断裂。因为脆性cu层的厚度随着银钎焊中Ti含量的增加而增加。
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引用次数: 8
Spot Welding of Iron-based and Cobalt-based Amorphous Alloy Foils (Report 2) 铁基和钴基非晶合金箔的点焊(报告二)
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.9.457
S. Fukushima, T. Kasugai
Further examinations and considerations were carried out for Foil S of Fe-Si-B alloy, Foil A of Fe-Co-Si-B alloy, Foil B of Fe-Ni-Mo-B alloy and Foil C of Co-Fe-Ni-Mo-Si-B alloy.Tensile shear strength of Foil B single spot-welded joints somewhat increased with the increase both in electrode force and in charging voltage, but fracture modes of these joints did not change so much. This result suggests that the increased electrode force could not suppress crystallization of Foil B weld nuggets.Tensile shear strength of Foil C single spot-welded joints did not vary so much; these joints were welded at various capacitances up to 700μF and both at a constant peak welding current of 1118 A and. at a higher electrode force of 83.1 N.Crystallization temperature Tx and melting temperature Tm of these foils were estimated through DSC in the course of heating. The order of the ratio Tx/Tm fairly relates to the order of spotweldability of these foils.Weld nuggets of Foil C produced by irradiating a defocused Nd-YAG laser beam pulse maintained the amorphous state, whereas weld nuggets of the other foils crystallized under the same condition.
对Fe-Si-B合金的S型箔、Fe-Co-Si-B合金的A型箔、Fe-Ni-Mo-B合金的B型箔和Co-Fe-Ni-Mo-Si-B合金的C型箔进行了进一步的考察和考虑。随着电极力和充电电压的增加,B箔单点焊接头的抗拉剪切强度有所增加,但接头的断裂方式变化不大。结果表明,增加电极力不能抑制B型焊块的结晶。铝箔C单点焊接头抗拉剪切强度变化不大;在峰值焊接电流为1118a和1118a的恒定条件下,以700μF的不同电容进行焊接。在较高的电极力为83.1 n时,通过DSC测定了这些箔在加热过程中的结晶温度Tx和熔化温度Tm。比率Tx/Tm的顺序与这些薄膜的可点焊性的顺序相当相关。在散焦Nd-YAG激光束脉冲照射下,C箔的焊块保持非晶态,而其他箔的焊块在相同条件下结晶。
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引用次数: 0
Measurement of temperature and velocity of thermally sprayed particles using thermal radiation. 用热辐射测量热喷涂颗粒的温度和速度。
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.8.132
S. Kuroda, H. Fujimori, T. Fukushima, S. Kitahara
Methods to measure the surface temperature and the velocity of thermally sprayed particles were developed and applied to plasma-sprayed Mo, Ni-Cr alloy, and alumina particles in the air.In the temperature measurement, radiation from particles within a cylindrical measurement volume is measured and its spectrum is analyzed by a monochromator. Then the spectrum is compared with the spectra of blackbody radiation to determine the surface temperature of the particles through the least squares method.Spatial filtering technique using a mask with four thin parallel slits was adopted in the velocity measurement. When a single particle travels in front of the plates, radiation passing through the spacings between the plates is detected by a photo-multiplier, which gives a signal with four peaks. Then the velocity v of the particle is given by υ=d/t, where d is the distance between the neighboring slits and t the period between the peaks. It was also found that the mean velocity of a high-density particle stream can be determined by analyzing the power spectrum of the signal by a method such as FFT.As the results of those measurements, the change in the temperature and the velocity of sprayed particles with the distance from the exit of a plasma-torch was obtained. Where as the metal powders exhibited similar history of cooling and deceleration with the distance, alumina particles were found to be accelerated to a much higher velocity close to 300 m/s but decelerated at a much faster rate. The temperature of alumina particles could be measured for only a limited region due to the weak radiation. Also the effects of particle size on the distribution of both the temperature and the velocity of sprayed Mo particles were examined.
研究了热喷涂颗粒表面温度和速度的测量方法,并将其应用于空气中等离子喷涂Mo、Ni-Cr合金和氧化铝颗粒。在温度测量中,测量圆柱形测量体积内粒子的辐射,并用单色仪分析其光谱。然后将光谱与黑体辐射光谱进行比较,通过最小二乘法确定粒子的表面温度。在速度测量中采用了四薄平行狭缝掩模的空间滤波技术。当单个粒子在光板前面移动时,通过光板之间间隙的辐射就会被光电倍增器探测到,从而产生四个峰的信号。然后粒子的速度v由υ=d/t给出,其中d是相邻狭缝之间的距离,t是峰值之间的周期。还发现高密度粒子流的平均速度可以用FFT等方法通过分析信号的功率谱来确定。根据这些测量结果,得到了喷射粒子的温度和速度随等离子炬出口距离的变化规律。随着距离的增加,金属粉末表现出相似的冷却和减速历史,氧化铝颗粒被加速到接近300 m/s的更高速度,但减速速度要快得多。由于辐射较弱,氧化铝颗粒的温度只能在有限的区域内测量。同时考察了不同粒径对喷射Mo颗粒温度和速度分布的影响。
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引用次数: 4
TLP Weldability of Nickel-Base Superalloys 镍基高温合金TLP可焊性
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS1943.49.462
A. Suzumura, T. Onzawa, H. Tamura
The TLP (Transient Liquid Phase) weldability of nickel-base heat-resistant alloys (Hastelloy X, Inconel X-750 and Udimet 500) have been studied by microscopy, electron-probe-microanalysis, tensile tests and stress-rupture tests of the joints.The major cause to restrict the TLP weldability was the formation during welding of a continuous array of stable Ti, Al and/or Nb compounds at the joint interface, which produce a weak plane joint grain boundary. In order to prevent this phenomenon, it was found important for interlayer alloys to melt moderately the base metal surface at the joint interface. For this purpose it was indicated that such interlayer alloys as including both boron and silicon which lower the melting point of the interlayer were more effective for TLP welding.
采用显微观察、电子探针显微分析、拉伸试验和接头应力断裂试验等方法,研究了镍基耐热合金(哈氏合金X、英科合金X-750和Udimet 500)的瞬态液相可焊性。限制TLP可焊性的主要原因是焊接过程中在接头界面处形成连续的稳定Ti、Al和/或Nb化合物阵列,形成弱平面接头晶界。为了防止这种现象的发生,层间合金在接头界面处适度地熔化母材表面是很重要的。同时含有硼和硅的层间合金可以降低层间的熔点,对TLP焊接效果更好。
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引用次数: 1
Desensitization of Stainless Steels by Laser Surface Heat-Treatment 不锈钢激光表面热处理的脱敏研究
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.5.445
Y. Nakao, K. Nishimoto
Laser heating was applied for the desensitization heat-treatment of the surface layer in the sensitized HAZ of Type 304 stainless steel. The degree of sensitization was examined by EPR technique and the 10% oxalic acid electrolytic etch test. The CO2 laser with maximum power of 1.5kW was used for heat-treatment. Time-Temperature-Desensitization diagram (TTDS diagram) for sensitized Type 304 stainless steels were developed by calculation assuming the chromium diffusion control for desensitization which might occur when the chromium depleted zone was healed up due to dissolution of chromium carbide and chromium diffusion from the matrix being heated at the solution annealing temperatures. TTDS diagrams calculated agree fairly well with ones determined by corrosion tests. Laser irradiation conditions (e.g., Laser power, beam diameter and traveling velocity )required for desensitization of sensitized Type 304 stainless steels were calculated using additivity rule from the TTDS diagram calculated and theoretical thermal curve of laser heating derived from the heat conduction theory. After laser beam irradiated under an optimum condition predicted by calculation, the sensitized HAZ of Type 304 stainless steel restored complete resistance to intergranular corrosion.
采用激光加热技术对304型不锈钢敏化热影响区表层进行了脱敏热处理。采用EPR技术和10%草酸电解刻蚀试验考察了其敏化程度。采用最大功率1.5kW的CO2激光器进行热处理。假定在溶液退火温度下,由于碳化铬的溶解和基体中铬的扩散而使贫铬区恢复时可能发生的铬扩散控制,通过计算得到了敏化304型不锈钢的时间-温度-脱敏图。计算的TTDS图与腐蚀试验结果吻合较好。根据计算得到的TTDS图和热传导理论导出的激光加热理论热曲线,利用可加法则计算出致敏304型不锈钢脱敏所需的激光辐照条件(如激光功率、光束直径和行进速度)。在计算预测的最佳条件下辐照后,304不锈钢敏化热影响区完全恢复了对晶间腐蚀的耐蚀性。
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引用次数: 8
Study on Penetration Form Using Stationary TIG Arc : Study on Low Speed DC-TIG Welding Method 固定TIG电弧熔透成形研究:低速DC-TIG焊接方法的研究
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.10.353
T. Hinata, K. Yasuda, Yukio Kasuga, T. Onzawa
Generally, in TIG arc welding method, the ratio of penetration depth (D) to bead width (W) is small and the deep penetration cannot be obtained comparatively. But in the case of using the stationary TIG arc when the welding conditions were set to the suitable range, the value of D/W is closer to unity and the penetration depth becomes deep. Paying attention to the above mentioned phenomenon, the authors have made researches into the practical application of the stationary TIG arc.In this paper, the welding conditions which we obtained from the above mentioned penetration forms were investigated using SUS304. It was found out that when suffer (S) content of the base metal is more than 0.005 mass%, both the method of using the electrode with at vertex angle above 60° or with in argon shielding gas and the method of using helium to shielding gas are successful to increase the penetration depth.In the case of using the base metal which contains sulfer about 0.001 mass%, the method of using the tip-cutting electrode in argon shielding gas is more effective for same purpose.
在TIG电弧焊法中,一般熔透深度D与焊头宽度W之比较小,无法获得较深的熔透。而在固定TIG电弧的情况下,当焊接条件设定在合适的范围内时,D/W值更接近于1,熔深变深。针对上述现象,笔者对固定式TIG电弧的实际应用进行了研究。本文以SUS304为材料,对上述焊透形式得到的焊接条件进行了研究。结果表明,当母材的硫化物含量大于0.005质量%时,采用顶角大于60°的电极或氩气保护的方法和氦气保护的方法都能有效地提高电极的穿透深度。对于含硫量约为0.001质量%的母材,在氩保护气体中使用尖端切割电极的方法更为有效。
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引用次数: 6
Mechanical Propertics of Mild Steel Weld Metals Produced in Pressurized Ar-CO_2 Atmospheres 加压Ar-CO_2气氛下低碳钢焊接金属的力学性能
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS.9.233
T. Kuwana, H. Kokawa, R. Kiguchi
Mild steel sheets with V-groove were welded in pressurized Ar-CO2 gas mixture atmospheres up to 2.0 MPa, using a 1.6 mm diameter solid wire. The effect of ambient gas pressure and gas composition on the mechanical properties of weld metals were studied. The Vickers hardness and tensile properties of weld metals were varied with the ambient gas composition but did not depend on the ambient gas pressure. The Charpy V notch toughness of weld metal was changed markedly with CO2 partial pressure in the atmosphere, and showed a maximum at 0.1-0.2 MPa CO2 partial pressure which resulted in about 0.03% oxygen content of weld metal having a fine ferrite microstructure. This suggests that toughness is strongly influenced by the oxygen content of weld metal. Mechanical properties of pressurized steel weld metal can be controlled by CO2% in the welding atmosphere, because the oxygen content of weld metal is determined by CO2 partial pressure.
采用直径1.6 mm的实心焊丝,在压力为2.0 MPa的Ar-CO2混合气体环境中焊接带有v型槽的低碳钢片。研究了环境气体压力和气体成分对焊缝金属力学性能的影响。焊接金属的维氏硬度和拉伸性能随环境气体成分的变化而变化,但不受环境气体压力的影响。随大气中CO2分压的变化,焊缝金属的夏比V缺口韧性发生显著变化,在0.1 ~ 0.2 MPa CO2分压下达到最大值,此时焊缝金属含氧量约为0.03%,具有良好的铁素体组织。这表明,韧性受焊缝金属含氧量的强烈影响。受压钢焊缝金属的力学性能可通过焊接气氛中CO2的2%来控制,因为焊缝金属的含氧量是由CO2分压决定的。
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引用次数: 1
Ductility Loss due to Dynamic Strain Aging in Heat-Affected Zone of High Strength Low Alloy Steel 高强度低合金钢热影响区动态应变时效引起的延性损失
Pub Date : 1900-01-01 DOI: 10.2207/QJJWS1943.50.465
Y. Kikuta, T. Araki, M. Yoneda, K. Yasuda, K. Matsueda
When tensile tests on mild steel are carried out at various temperatures, the serrated yielding and flow are observed at a certain testing temperature range, specially 100-300°C, and the consequent em-brittlement occurs. This phenomenon is generally known as a blue brittleness or a dynamic strain aging and is related to testing temperature, solute atom contents (carbon and/or nitrogen contents), strain rate and so forth.On the other hand, for base metal of QT-type high strength low alloy steels in which solute atoms such as carbon and nitrogen are fixed as carbide, nitride or carbo-nitride by heat treatment, such embrit-tlement seems to be not apt to occur comparatively. But, even if QT-type steels, there is a possibility of dynamic strain aging in heat-affected zone (HAZ) because of the above carbide, nitride or carbo-nitride dissolving by welding heats, and the consequent embrittlernent.This study was investigated about the ductility loss due to dynamic strain aging in HAZ of a 80 kg/mm2 class high strength low alloy steel.It is found by this study that dynamic strain aging and, thus, the ductility loss can occur in HAZ even if QT-type steels. The degree of ductility loss is increased in the order of upper bainite, lower bainite and martensite structure.These results can be qualitatively interpreted by considering as interaction between dislocations and solute atoms, specifically nitrogen atoms rather than carbon atoms.Transformed HAZ, which is heated above 1200°C and has martensite structure and, thus, a high content of free nitrogen atoms, is sensitive to ductility loss due to dynamic strain aging as well as the deterioration of grain coarsened HAZ toughness.
在不同温度下对低碳钢进行拉伸试验时,在一定的试验温度范围内,特别是在100-300℃,观察到锯齿状的屈服和流动,并产生脆脆。这种现象通常被称为蓝脆性或动态应变老化,它与测试温度、溶质原子含量(碳和/或氮含量)、应变速率等有关。另一方面,对于通过热处理将碳、氮等溶质原子固定为碳化物、氮化物或碳氮化物的qt型高强度低合金钢的母材,这种脆性元素似乎相对不易发生。但是,即使是qt型钢,由于上述碳化物、氮化物或碳氮化物在焊接热影响区溶解,以及随之而来的脆化,也有可能在热影响区发生动态应变时效。研究了80 kg/mm2级高强度低合金钢在热影响区动态应变时效引起的塑性损失。本研究发现,即使是qt型钢,在热影响区也会发生动态应变时效,从而导致塑性损失。塑性损失程度依次为上贝氏体、下贝氏体和马氏体组织。这些结果可以定性地解释为位错与溶质原子,特别是氮原子而不是碳原子之间的相互作用。相变HAZ加热到1200℃以上,具有马氏体组织,因此自由氮原子含量高,对动态应变时效造成的塑性损失和晶粒粗化HAZ韧性的恶化很敏感。
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引用次数: 0
Study of Residual Stress in the Vicinity of Interface Corner of Sprayed Coatings. 喷涂涂层界面角附近残余应力的研究。
Pub Date : 1900-01-01 DOI: 10.2207/qjjws.9.430
T. Terasaki, T. Akiyama, T. Hirai, K. Seo
This paper deals with the singularity of residual stress arising at the interface corner of sprayed substrates and the effects of specimen size, mechanical and physical properties on residual stress distributions using the theory of elasticity and a boundary element method (BEM).The residual stress distribution is not only defined by one singular term, then it is difficult to use a stress intensity factor as the parameter to define the strength of sprayed substrate.The residual stress distribution of test specimen satisfying following conditions are the same as that of sprayed substrate in a working field : The test specimen is composed of the substrate with the thickness being 4 times, and the length and the width being 8 times as large as a thickness of sprayed coating.The preheat temperature TB of substrate in order to make a residual stress zero is given by the temperature of sprayed coating and the ratio of linear thermal expansions of coating and substrate materials.
本文运用弹性理论和边界元法,研究了喷射基板界面角残余应力的奇异性,以及试样尺寸、力学和物理性能对残余应力分布的影响。残余应力分布不能用单一项来定义,难以用应力强度因子作为参数来定义喷涂基体的强度。满足以下条件的试件在工作现场的残余应力分布与喷涂基体相同:试件由厚度为喷涂涂层厚度4倍、长度和宽度为喷涂涂层厚度8倍的基体组成。使残余应力为零的基体预热温度TB由喷涂涂层温度和涂层与基体材料的线性热膨胀比给出。
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引用次数: 0
期刊
Transactions of the Japan Welding Society
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