Pub Date : 2024-09-11DOI: 10.1016/j.compscitech.2024.110865
Significant enhancement in out-of-plane thermal conductivity of carbon fiber/epoxy laminated composites without sacrificing mechanical strength is of great challenge for advanced composites. In this study, a novel graphene-based hierarchical structure was constructed by combining graphene foams (GrFs) with graphene nanoplatelets (GNPs) together and laminating with carbon fiber (CF) fabrics. The GrFs acted as thermally-conductive skeletons in bridging CF fabrics together to remarkably increase out-of-plane thermal conductivity of composites, while the GNPs were helpful to further increasing heat-transfer paths and effectively transferring stress between continuous CFs for high mechanical reinforcement. The hierarchical composites exhibited extremely high out-of-plane thermal conductivity of 2.64 W/m·K, increasing by 158.8 % than that of CF/Ep composites, and they also showed satisfactory tensile, flexural, and interlaminar shear strength. Such high performance is mainly due to the hierarchical structure, continuous heat-transfer paths, synergetic enhancement of GrFs with GNPs, and strong interfacial interactions between components for high-efficiency heat and stress transfer.
{"title":"Graphene-based hierarchical structure for significantly enhancing thermal conductivity of composites with high mechanical reinforcement","authors":"","doi":"10.1016/j.compscitech.2024.110865","DOIUrl":"10.1016/j.compscitech.2024.110865","url":null,"abstract":"<div><p>Significant enhancement in out-of-plane thermal conductivity of carbon fiber/epoxy laminated composites without sacrificing mechanical strength is of great challenge for advanced composites. In this study, a novel graphene-based hierarchical structure was constructed by combining graphene foams (GrFs) with graphene nanoplatelets (GNPs) together and laminating with carbon fiber (CF) fabrics. The GrFs acted as thermally-conductive skeletons in bridging CF fabrics together to remarkably increase out-of-plane thermal conductivity of composites, while the GNPs were helpful to further increasing heat-transfer paths and effectively transferring stress between continuous CFs for high mechanical reinforcement. The hierarchical composites exhibited extremely high out-of-plane thermal conductivity of 2.64 W/m·K, increasing by 158.8 % than that of CF/Ep composites, and they also showed satisfactory tensile, flexural, and interlaminar shear strength. Such high performance is mainly due to the hierarchical structure, continuous heat-transfer paths, synergetic enhancement of GrFs with GNPs, and strong interfacial interactions between components for high-efficiency heat and stress transfer.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142239748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-10DOI: 10.1016/j.compscitech.2024.110849
Artificial muscles, designed to replicate the movements of natural biological muscles, hold significant promise in the fields of robotics and prosthetics. Recent advancements have led to the development of fiber-reinforced actuators, drawing inspiration from biological tissues. Dielectric elastomer actuators (DEAs) are a type of electroactive artificial muscle. It is possible to enhance the uni-axial deformation of DEAs by constraining and applying pre-stretch on the actuator membrane. This can be achieved through uni-directional fibers bonded to the DEA that lead to transversely isotropic properties. However, combining membrane pre-stretch and fiber reinforcement may lead to instabilities such as fiber buckling due to the compressive load of the pre-stretched membrane or due to wrinkling during actuation. Understanding these instabilities is crucial as they can significantly impact the performance. A novel model taking into consideration these instabilities is established and experimentally validated. By calculating the force in the fiber direction, the buckling profile such as the wavelength and amplitude can be predicted. The validation of the model presented along with an extensive experimental investigation allow for a comprehensive analysis to explore the impact of fiber buckling on the performance and the force of uni-axial DEAs.
人造肌肉旨在复制天然生物肌肉的运动,在机器人和假肢领域大有可为。最近,人们从生物组织中汲取灵感,开发出了纤维增强致动器。介电弹性体致动器(DEA)是一种电活性人造肌肉。通过对致动器薄膜施加约束和预拉伸,可以增强 DEA 的单轴变形。这可以通过与 DEA 粘合的单向纤维来实现,从而产生横向各向同性的特性。然而,将膜预拉伸和纤维加固相结合可能会导致不稳定性,例如由于预拉伸膜的压缩负荷或在致动过程中的起皱导致纤维弯曲。了解这些不稳定性至关重要,因为它们会对性能产生重大影响。我们建立了一个考虑到这些不稳定性的新模型,并通过实验进行了验证。通过计算纤维方向上的力,可以预测屈曲曲线,如波长和振幅。通过对模型的验证和广泛的实验研究,可以进行综合分析,探索纤维屈曲对单轴 DEA 性能和力的影响。
{"title":"Investigation of buckling instabilities in fiber-reinforced DEAs","authors":"","doi":"10.1016/j.compscitech.2024.110849","DOIUrl":"10.1016/j.compscitech.2024.110849","url":null,"abstract":"<div><p>Artificial muscles, designed to replicate the movements of natural biological muscles, hold significant promise in the fields of robotics and prosthetics. Recent advancements have led to the development of fiber-reinforced actuators, drawing inspiration from biological tissues. Dielectric elastomer actuators (DEAs) are a type of electroactive artificial muscle. It is possible to enhance the uni-axial deformation of DEAs by constraining and applying pre-stretch on the actuator membrane. This can be achieved through uni-directional fibers bonded to the DEA that lead to transversely isotropic properties. However, combining membrane pre-stretch and fiber reinforcement may lead to instabilities such as fiber buckling due to the compressive load of the pre-stretched membrane or due to wrinkling during actuation. Understanding these instabilities is crucial as they can significantly impact the performance. A novel model taking into consideration these instabilities is established and experimentally validated. By calculating the force in the fiber direction, the buckling profile such as the wavelength and amplitude can be predicted. The validation of the model presented along with an extensive experimental investigation allow for a comprehensive analysis to explore the impact of fiber buckling on the performance and the force of uni-axial DEAs.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0266353824004196/pdfft?md5=de2e93ab5b973c831d3aa2f93d39b75b&pid=1-s2.0-S0266353824004196-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142230320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-08DOI: 10.1016/j.compscitech.2024.110859
Smart materials with high thermal conductivity are expected to have greatly application potential in thermal management for future electronic equipment. However, actual applications often require multifunctional properties of materials, such as high thermal conductivity (TC), good mechanical properties, and suitable electrical insulation performance. It is still a challenge to obtain such polymer composites with good comprehensive properties. Herein, the rational assembly of two-dimensional (2D) nanofillers of boron nitride nanosheets (BNNS) and graphene nanosheets (GNs) in nanofibrillated cellulose matrix is reported. The film shows 53.76 W m−1 K−1 of TC and 87.88 MPa of tensile strength. Meanwhile, the flexible film has the ability of response deformation by sensing the environmental temperature, which is promising for soft materials with excellent heat dissipation.
具有高热导率的智能材料有望在未来电子设备的热管理方面发挥巨大的应用潜力。然而,实际应用往往要求材料具有多功能特性,如高导热率(TC)、良好的机械性能和合适的电绝缘性能。如何获得这种具有良好综合性能的聚合物复合材料仍是一项挑战。本文报道了在纳米纤维素基质中合理组装氮化硼纳米片(BNNS)和石墨烯纳米片(GNs)的二维(2D)纳米填料。该薄膜的 TC 值为 53.76 W m-1 K-1,拉伸强度为 87.88 MPa。同时,这种柔性薄膜还具有感知环境温度而响应形变的能力,这对于具有良好散热性能的软性材料来说大有可为。
{"title":"Smart heat management flexible cellulose films with enhanced thermal conductivity via assembling graphene and boron nitride nanosheets","authors":"","doi":"10.1016/j.compscitech.2024.110859","DOIUrl":"10.1016/j.compscitech.2024.110859","url":null,"abstract":"<div><p>Smart materials with high thermal conductivity are expected to have greatly application potential in thermal management for future electronic equipment. However, actual applications often require multifunctional properties of materials, such as high thermal conductivity (TC), good mechanical properties, and suitable electrical insulation performance. It is still a challenge to obtain such polymer composites with good comprehensive properties. Herein, the rational assembly of two-dimensional (2D) nanofillers of boron nitride nanosheets (BNNS) and graphene nanosheets (GNs) in nanofibrillated cellulose matrix is reported. The film shows 53.76 W m<sup>−1</sup> K<sup>−1</sup> of TC and 87.88 MPa of tensile strength. Meanwhile, the flexible film has the ability of response deformation by sensing the environmental temperature, which is promising for soft materials with excellent heat dissipation.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0266353824004299/pdfft?md5=43396825aacd6245c31462c9e0b4cac3&pid=1-s2.0-S0266353824004299-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142163452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.compscitech.2024.110858
In the present work, the mode I fracture toughness at the initiation of a crack in a metal-composite bonded joint under high-speed loading is calculated, considering the effect of the elastic vibration of the specimen. A new hybrid analytical-experimental method is developed, which integrates kinematics from Digital Image Correlation (DIC) analysis to an analytical model to determine the fracture toughness and its individual components. The analytical model is based on Timoshenko beam theory and incorporates a Lagrangian contact formulation. The conditions under which the hybrid method can be applied are analysed. The experiments are conducted on a novel test set-up, featuring a wedge accelerated by a projectile from an air gun that is able to load the Double Cantilever Beam (DCB) specimen with an opening displacement rate up to . The results reveal a correlation between the fracture toughness, the displacement rate, and the vibrational characteristics of the specimen.
在本研究中,考虑到试样弹性振动的影响,计算了高速加载下金属复合材料粘接接头裂纹萌发时的 I 型断裂韧性。该方法将数字图像相关(DIC)分析的运动学与分析模型相结合,以确定断裂韧性及其各个组成部分。该分析模型基于季莫申科梁理论,并结合了拉格朗日接触公式。分析了混合方法的应用条件。实验是在一个新颖的测试装置上进行的,该装置的特点是用气枪射出的弹丸加速楔形物,该弹丸能以高达 2m/s 的开口位移率加载双悬臂梁 (DCB) 试样。结果表明,断裂韧性、位移速率和试样的振动特性之间存在相关性。
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Pub Date : 2024-09-05DOI: 10.1016/j.compscitech.2024.110846
To further decrease the mass and thickness of multifunctional wideband microwave absorption metamaterials (MAMs), this study applies photonic crystal principles to the field of microwave absorption. Drawing inspiration from the structural coloration regulation of Morpho Menelaus scales, a novel integrated bioinspired MAM named MM is designed. MM possesses low drag coefficient, hydrophobicity, mechanical load-bearing capacity, and wideband radar stealth functionality. Utilizing PA6@CF filaments and material extrusion 3D printing technology, mechanical test specimens and MM specimens optimized through particle swarm optimization (PSO) are rapidly fabricated at low cost. Reflectivity tests at normal incidence reveal that MM (with a thickness of 8 mm) achieves an effective absorption bandwidth (EAB) of 33.4 GHz within the 2–40 GHz frequency range. Under transverse magnetic polarization and 60° oblique incidence conditions, MM demonstrates a coverage rate of 98.5 % for EAB. Furthermore, three-point bending tests demonstrate MM's excellent deformation capabilities (up to 50 mm) and mechanical load-bearing performance (bending strength reaching 78 MPa), laying the groundwork for its application on complex surfaces. Lastly, targeting the application of microwave absorption metamaterials on high-speed moving objects, comparative analysis of MM and five typical MAMs reveals that MM exhibits the lowest drag coefficient (Cd = 0.132). In summary, this study offers a straightforward and replicable method for designing, optimizing, fabricating, and evaluating MAMs, while suggesting aerodynamic performance as a novel metric for assessing their multifunctional capabilities.
为了进一步降低多功能宽带微波吸收超材料(MAM)的质量和厚度,本研究将光子晶体原理应用于微波吸收领域。从 Morpho Menelaus 鳞片的结构着色调节中汲取灵感,设计出一种名为 MM 的新型集成生物启发超材料。MM 具有低阻力系数、疏水性、机械承载能力和宽带雷达隐身功能。利用 PA6@CF 长丝和材料挤出 3D 打印技术,通过粒子群优化(PSO)以低成本快速制造出机械测试试样和 MM 试样。正常入射下的反射率测试表明,MM(厚度为 8 毫米)在 2-40 GHz 频率范围内的有效吸收带宽(EAB)达到 33.4 GHz。在横向磁极化和 60° 斜入射条件下,MM 的 EAB 覆盖率达到 98.5%。此外,三点弯曲试验证明 MM 具有出色的变形能力(最大 50 毫米)和机械承重性能(弯曲强度达到 78 兆帕),为其在复杂表面上的应用奠定了基础。最后,针对微波吸收超材料在高速移动物体上的应用,对 MM 和五种典型 MAM 的对比分析表明,MM 的阻力系数最低(Cd = 0.132)。总之,本研究为设计、优化、制造和评估微波吸收超材料提供了一种直接且可复制的方法,同时建议将空气动力学性能作为评估其多功能性的新指标。
{"title":"Bioinspired 3D printed metamaterial for wideband microwave absorption and aerodynamic efficiency","authors":"","doi":"10.1016/j.compscitech.2024.110846","DOIUrl":"10.1016/j.compscitech.2024.110846","url":null,"abstract":"<div><p>To further decrease the mass and thickness of multifunctional wideband microwave absorption metamaterials (MAMs), this study applies photonic crystal principles to the field of microwave absorption. Drawing inspiration from the structural coloration regulation of Morpho Menelaus scales, a novel integrated bioinspired MAM named MM is designed. MM possesses low drag coefficient, hydrophobicity, mechanical load-bearing capacity, and wideband radar stealth functionality. Utilizing PA6@CF filaments and material extrusion 3D printing technology, mechanical test specimens and MM specimens optimized through particle swarm optimization (PSO) are rapidly fabricated at low cost. Reflectivity tests at normal incidence reveal that MM (with a thickness of 8 mm) achieves an effective absorption bandwidth (EAB) of 33.4 GHz within the 2–40 GHz frequency range. Under transverse magnetic polarization and 60° oblique incidence conditions, MM demonstrates a coverage rate of 98.5 % for EAB. Furthermore, three-point bending tests demonstrate MM's excellent deformation capabilities (up to 50 mm) and mechanical load-bearing performance (bending strength reaching 78 MPa), laying the groundwork for its application on complex surfaces. Lastly, targeting the application of microwave absorption metamaterials on high-speed moving objects, comparative analysis of MM and five typical MAMs reveals that MM exhibits the lowest drag coefficient (<em>C</em><sub>d</sub> = 0.132). In summary, this study offers a straightforward and replicable method for designing, optimizing, fabricating, and evaluating MAMs, while suggesting aerodynamic performance as a novel metric for assessing their multifunctional capabilities.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142147851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-05DOI: 10.1016/j.compscitech.2024.110847
The mechanical reinforcement of rubber by carbon black (CB) depends strongly on its the size and topography of CB clusters. However, the underlying mechanisms remain largely unexplored. This study uses atomic force microscopy (AFM) to probe interfacial properties at the nanoscale to elucidate the influence of the CB topological structure on macroscopic mechanical properties. A substantial amount of high-modulus bound rubber is found inside the CB aggregates, particularly in highly branched ones. This phenomenon plays a critical role in reinforcement, as corroborated by quantitative AFM nanomechanics, chain segment motion results and theoretical calculations. A quantitative analysis of the filler network reveals that the branched chain structure effectively reduces the packing spacing and improves the stress transfer efficiency.
{"title":"Revealing the nanoscale reinforcing mechanism: How topological structure of carbon black clusters influence the mechanics of rubber","authors":"","doi":"10.1016/j.compscitech.2024.110847","DOIUrl":"10.1016/j.compscitech.2024.110847","url":null,"abstract":"<div><p>The mechanical reinforcement of rubber by carbon black (CB) depends strongly on its the size and topography of CB clusters. However, the underlying mechanisms remain largely unexplored. This study uses atomic force microscopy (AFM) to probe interfacial properties at the nanoscale to elucidate the influence of the CB topological structure on macroscopic mechanical properties. A substantial amount of high-modulus bound rubber is found inside the CB aggregates, particularly in highly branched ones. This phenomenon plays a critical role in reinforcement, as corroborated by quantitative AFM nanomechanics, chain segment motion results and theoretical calculations. A quantitative analysis of the filler network reveals that the branched chain structure effectively reduces the packing spacing and improves the stress transfer efficiency.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142162965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-04DOI: 10.1016/j.compscitech.2024.110851
The shape memory effect allows stimuli-responsive materials to generate programmable morphing when subjected to external stimuli, facilitating the creation of active origami with 2D-to-3D shape transformation capabilities. However, the current active origami made of polymer-based stimuli-responsive materials exhibits poor mechanical performance due to the inherent low stiffness of materials, which hinders their exploration and engineering application. This work reported a novel fabrication and design method to construct 3D continuous fiber-reinforced self-locking Miura-ori (SLMO) composites with high energy absorption and cyclability by 4D printing of shape memory composites. The SLMO structure consists of a Miura-ori unit and a highly stretchable bottom stopper panel, where the Miura-ori unit actively morphs and locks into a predetermined configuration under external stimuli and the constraint of the stopper panel. Incorporating continuous fibers enhanced the strength of the Miura-ori facets, synergizing with the highly stretchable characteristic of the bottom panel to enable the SLMO structure to exhibit a push-to-pull deformation mode under compressive load. Structural analysis of the SLMO, stress-stretch behavior of the bottom panel, and buckling criteria of the Miura-ori facets were theoretically investigated to describe the push-to-pull deformation behavior of the SLMO structure and the conditions necessary for its realization. Moreover, the compressive behavior of the SLMO structure with different design parameters was investigated through experiments and theoretical analysis. By optimizing design parameters, it was demonstrated that the SLMO structure can sustain more than 10 cycles of 50% compressive strain. This approach broadens the practical and functional applications of active origami.
{"title":"4D printed continuous fiber-reinforced self-locking Miura-ori composites with high energy absorption and cyclability","authors":"","doi":"10.1016/j.compscitech.2024.110851","DOIUrl":"10.1016/j.compscitech.2024.110851","url":null,"abstract":"<div><p>The shape memory effect allows stimuli-responsive materials to generate programmable morphing when subjected to external stimuli, facilitating the creation of active origami with 2D-to-3D shape transformation capabilities. However, the current active origami made of polymer-based stimuli-responsive materials exhibits poor mechanical performance due to the inherent low stiffness of materials, which hinders their exploration and engineering application. This work reported a novel fabrication and design method to construct 3D continuous fiber-reinforced self-locking Miura-ori (SLMO) composites with high energy absorption and cyclability by 4D printing of shape memory composites. The SLMO structure consists of a Miura-ori unit and a highly stretchable bottom stopper panel, where the Miura-ori unit actively morphs and locks into a predetermined configuration under external stimuli and the constraint of the stopper panel. Incorporating continuous fibers enhanced the strength of the Miura-ori facets, synergizing with the highly stretchable characteristic of the bottom panel to enable the SLMO structure to exhibit a push-to-pull deformation mode under compressive load. Structural analysis of the SLMO, stress-stretch behavior of the bottom panel, and buckling criteria of the Miura-ori facets were theoretically investigated to describe the push-to-pull deformation behavior of the SLMO structure and the conditions necessary for its realization. Moreover, the compressive behavior of the SLMO structure with different design parameters was investigated through experiments and theoretical analysis. By optimizing design parameters, it was demonstrated that the SLMO structure can sustain more than 10 cycles of 50% compressive strain. This approach broadens the practical and functional applications of active origami.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142151612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-04DOI: 10.1016/j.compscitech.2024.110850
Resistance welding of thermoplastic composites often suffers from quality issues due to high-pressure requirements and nonuniform heating, leading to nonbonding at the overlap edge. This study proposes an ultrasonic-assisted resistance welding method aimed at enhancing joint quality while operating at lower welding pressures. Results indicate that in traditional welding, reducing pressure tends to create voids near the weld line, whereas increasing pressure results in nonbonding at the overlap edge due to reduced temperatures. Introducing ultrasonic during the final phase of the welding process efficiently raises the temperature at the overlap edge and enhances the uniformity across the joint. Moreover, applying ultrasonic facilitates the squeeze flow of the polymer melt, extending the melt front and enlarging the effective bonding area. An improved squeeze flow reduces void formation caused by trapped air, diminishing the need for high pressure. The ultrasonic effects are more pronounced with increasing welding pressure. Consequently, glass fiber reinforced polyphenylene sulfide joints exhibit a 12 % increase in the maximum lap shear strength (LSS) compared to those welded without ultrasonic. Additionally, the use of ultrasonic achieves a 27 % reduction in pressure while maintaining an LSS comparable to the maximum values of the joints welded without ultrasonic.
{"title":"A novel method for reducing the welding pressure requirement in resistance welding of thermoplastic composites","authors":"","doi":"10.1016/j.compscitech.2024.110850","DOIUrl":"10.1016/j.compscitech.2024.110850","url":null,"abstract":"<div><p>Resistance welding of thermoplastic composites often suffers from quality issues due to high-pressure requirements and nonuniform heating, leading to nonbonding at the overlap edge. This study proposes an ultrasonic-assisted resistance welding method aimed at enhancing joint quality while operating at lower welding pressures. Results indicate that in traditional welding, reducing pressure tends to create voids near the weld line, whereas increasing pressure results in nonbonding at the overlap edge due to reduced temperatures. Introducing ultrasonic during the final phase of the welding process efficiently raises the temperature at the overlap edge and enhances the uniformity across the joint. Moreover, applying ultrasonic facilitates the squeeze flow of the polymer melt, extending the melt front and enlarging the effective bonding area. An improved squeeze flow reduces void formation caused by trapped air, diminishing the need for high pressure. The ultrasonic effects are more pronounced with increasing welding pressure. Consequently, glass fiber reinforced polyphenylene sulfide joints exhibit a 12 % increase in the maximum lap shear strength (LSS) compared to those welded without ultrasonic. Additionally, the use of ultrasonic achieves a 27 % reduction in pressure while maintaining an LSS comparable to the maximum values of the joints welded without ultrasonic.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142151615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-03DOI: 10.1016/j.compscitech.2024.110841
This study aims at obtaining an effective structural design strategy for stronger and more reliable Unidirectional glass fiber (UD-GF) composites by in-situ formed cross-linking from randomly distributed nano-/micro- Aramid pulp (AP) fibers. The flexural strength and stiffness have shown substantial improvements in both the transverse and longitudinal directions due to the AP cross-linking and the “brick-slurry” structure. With AP of 8 g/m2, up to 60–70 % improvement in flexural strengths (both transverse and longitudinal directions) and up to 20–37 % improvement in “effective modulus” have been observed. The noticeable longitudinal improvements have been attributed to the resin reinforcement and interlayer cross-linking provided by ultra-thin AP interlayers, and the resultant improvement in micro-buckling resistance under compression. Since sparsely distributed nano-/micro-AP can be readily incorporated in pultrusion and pre-preg manufacturing processes, this study is not only important for micro-mechanism study, but also provides a plausible improvement in manufacturing.
本研究旨在通过随机分布的纳米/微米芳纶浆料(AP)纤维的原位交联,为强度更高、更可靠的单向玻璃纤维(UD-GF)复合材料提供一种有效的结构设计策略。由于 AP 交联和 "砖浆 "结构,横向和纵向的抗弯强度和刚度都有大幅提高。当 AP 值为 8 g/m2 时,挠曲强度(横向和纵向)提高了 60-70%,"有效模量 "提高了 20-37%。纵向强度的明显改善归功于超薄 AP 中间膜提供的树脂加固和层间交联,以及由此带来的压缩下微弯曲阻力的改善。由于稀疏分布的纳米/微 AP 可以很容易地融入拉挤和预浸料制造工艺中,因此这项研究不仅对微观力学研究具有重要意义,而且还为制造工艺的改进提供了可能。
{"title":"Micro-buckling resistant unidirectional glass fiber composites with excellent transverse and longitudinal flexural properties from cross-linking by nano-/micro-aramid fibers","authors":"","doi":"10.1016/j.compscitech.2024.110841","DOIUrl":"10.1016/j.compscitech.2024.110841","url":null,"abstract":"<div><p>This study aims at obtaining an effective structural design strategy for stronger and more reliable Unidirectional glass fiber (UD-GF) composites by in-situ formed cross-linking from randomly distributed nano-/micro- Aramid pulp (AP) fibers. The flexural strength and stiffness have shown substantial improvements in both the transverse and longitudinal directions due to the AP cross-linking and the “brick-slurry” structure. With AP of 8 g/m<sup>2</sup>, up to 60–70 % improvement in flexural strengths (both transverse and longitudinal directions) and up to 20–37 % improvement in “effective modulus” have been observed. The noticeable longitudinal improvements have been attributed to the resin reinforcement and interlayer cross-linking provided by ultra-thin AP interlayers, and the resultant improvement in micro-buckling resistance under compression. Since sparsely distributed nano-/micro-AP can be readily incorporated in pultrusion and pre-preg manufacturing processes, this study is not only important for micro-mechanism study, but also provides a plausible improvement in manufacturing.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0266353824004111/pdfft?md5=7024641f061e5348a4ecb97a6c23dd6a&pid=1-s2.0-S0266353824004111-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142151614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-02DOI: 10.1016/j.compscitech.2024.110848
Polymer-based dielectric film capacitors are essential energy storage components in high-power energy storage devices benefiting from their high breakdown strength (Eb) and ultra-fast charge storage/release capability. However, the state-of-the-art commercial capacitor, biaxially oriented polypropylene (BOPP), exhibits limited energy storage density primarily due to low dielectric constant, which hinders the advancement of the film capacitor industry. Introducing high-permittivity (high-k) nanofillers into PP matrix to improve polarization is a promising method but poor filler dispersion leads to a remarkable decrease of Eb, while various strategies to enhance dispersion of fillers typically require sophisticated process involving toxic procedure and consuming significant time and cost. Herein, we show that a novel and scalable surface grafting method for high-k fillers can be achieved by a facile and short-period microwave irradiation with the assistance of silane coupling agent (KH560). As a demonstration, the KH560 is effectively grafted onto the surface of barium titanate (BT), achieving a high grafting ratio of 4.91 % at a yield of 85.1 % within a short time (40s). Furthermore, the surface modified BT nanofillers are introduced into PP matrix and then biaxially stretched. The as-prepared film exhibits excellent dispersion and superior compatibility, resulting in a remarkable enhancement of tensile strength (from 82 MPa to 115.4 MPa), breakdown strength (from 200 MV/m to 254 MV/m), and energy density (from 1.49 J/cm3 to 2.21 J/cm3). This work proposes a new strategy for constructing homogeneous polymer-based dielectric film by microwave activating high-k fillers and is crucial for the design of next-generation energy storage devices.
{"title":"A microwave-assisted, solvent-free approach for effective grafting of high-permittivity fillers to construct homogeneous polymer-based dielectric film with high energy density","authors":"","doi":"10.1016/j.compscitech.2024.110848","DOIUrl":"10.1016/j.compscitech.2024.110848","url":null,"abstract":"<div><p>Polymer-based dielectric film capacitors are essential energy storage components in high-power energy storage devices benefiting from their high breakdown strength (E<sub>b</sub>) and ultra-fast charge storage/release capability. However, the state-of-the-art commercial capacitor, biaxially oriented polypropylene (BOPP), exhibits limited energy storage density primarily due to low dielectric constant, which hinders the advancement of the film capacitor industry. Introducing high-permittivity (high-k) nanofillers into PP matrix to improve polarization is a promising method but poor filler dispersion leads to a remarkable decrease of E<sub>b</sub>, while various strategies to enhance dispersion of fillers typically require sophisticated process involving toxic procedure and consuming significant time and cost. Herein, we show that a novel and scalable surface grafting method for high-k fillers can be achieved by a facile and short-period microwave irradiation with the assistance of silane coupling agent (KH560). As a demonstration, the KH560 is effectively grafted onto the surface of barium titanate (BT), achieving a high grafting ratio of 4.91 % at a yield of 85.1 % within a short time (40s). Furthermore, the surface modified BT nanofillers are introduced into PP matrix and then biaxially stretched. The as-prepared film exhibits excellent dispersion and superior compatibility, resulting in a remarkable enhancement of tensile strength (from 82 MPa to 115.4 MPa), breakdown strength (from 200 MV/m to 254 MV/m), and energy density (from 1.49 J/cm<sup>3</sup> to 2.21 J/cm<sup>3</sup>). This work proposes a new strategy for constructing homogeneous polymer-based dielectric film by microwave activating high-k fillers and is crucial for the design of next-generation energy storage devices.</p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142128886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}