Ultra-high performance seawater and sea sand concrete (UHPSSC) is a promising material for marine engineering applications; however, reinforcement corrosion induced by internal chlorides remains a critical challenge. This study aims to address this issue by exploring the synergistic use of metakaolin (MK) and alkali-rich white mud (WM) as supplementary cementitious materials to regulate chloride binding and mitigate corrosion risk in UHPSSC. The study investigates replacing silica fume with MK and incorporating 10 wt.% and 20 wt.% WM into UHPSSC. The mechanical properties, hydration behavior, microstructure, and chloride binding capacity are analyzed. Complete replacement of silica fume with MK reduced compressive strength from 131.5 MPa to 123.6 MPa at 28 days, while 10 wt.% WM (WM10) counteracted this reduction, increasing strength by 3%. However, 20 wt.% WM caused significant performance deterioration. Microstructural analysis revealed that MK alone deteriorates the pore structure, whereas WM10 enhances pozzolanic reactions and reduces porosity. MK significantly increases chloride immobilization, and WM further strengthens chemical chloride binding, with WM10 showing nearly twice the amount of chemically bound chlorides at 60 days compared to conventional UHPSSC. WM10 effectively mitigates corrosion risk in UHPSSC by reducing the free chloride content by over 30% and achieving the lowest [Cl⁻]/[OH⁻] ratio (≈0.017), well below the corrosion threshold. This study establishes a solid theoretical framework for UHPSSC mix design and presents an innovative approach for controlling chloride-induced corrosion in marine concrete.
扫码关注我们
求助内容:
应助结果提醒方式:
