The asphalt industry has considerable potential to valorize waste plastics; however, the modification mechanism of wax-based pyrolysis products still lacks quantitative metrics and robust validation. In this study, the microstructural characteristics of linear low-density polyethylene pyrolysis wax were characterized using gel permeation chromatography, Fourier-transform infrared spectroscopy, and proton nuclear magnetic resonance. A pyrolysis wax-asphalt system was then constructed via molecular dynamics modeling. By integrating the Flory-Huggins interaction parameter, repulsion parameters, and related descriptors, a quantitative evaluation framework was established to elucidate how pyrolysis wax alters asphalt colloidal structure and inter-component interactions. The results indicate that pyrolysis wax, a highly saturated and non-polar polyethylene-derived alkane, preferentially forms a homogeneous phase with the saturates fraction, whereas it exhibits pronounced repulsion toward aromatics, resins, and asphaltenes. This incompatibility selectively displaces aromatics and resins and promotes localized aggregation. Four-fraction tests and fluorescence microscopy observations further corroborate the proposed mechanism, providing a theoretical basis for the efficient utilization of waste-plastic-derived pyrolysis wax in asphalt applications.
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