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Comparison of waste glass and fly ash as silica sources for autoclaved materials 废玻璃和粉煤灰作为蒸压材料硅源的比较
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139154
Yaomin Gao , Gelong Xu , Jiwei Cai , Qing Tian , Ruixue Liu , Jiaqi Zhang , Zixuan Du
The effect of fly ash (FA) and glass powder (GP) as siliceous materials on the strength, hydration products and microstructure of autoclaved materials are investigated. The results indicated that GP is more beneficial to the growth of compressive strength than FA. At the Ca/Si ratio of 0.7, the compressive strength of the GP mixture is 95.7 % higher than that of the FA mixture, and the compressive strength presents a monotonously increasing trend with the increase of the GP replacement ratio for FA. The silica in GP has a higher reactivity than FA to form more hydration products. The main hydration product in the GP mixture is mainly the amorphous C-S-H with a lower Ca/Si ratio, which is difficult to crystalize and transform into tobermorite. FA facilitates the formation of tobermorite, and with the substitution of GP for FA, the fibrous tobermorite is displaced by sheet-like tobermorite and even the foil-like phases at a high GP substitution ratio. Furthermore, the hydration products in the GP mixture have a lower density than that in the FA mixture, but it is conducive to reducing the porosity of the autoclaved material. The low porosity is an important reason that GP as siliceous raw material is eligible for preparing high-strength autoclaved material.
研究了粉煤灰(FA)和玻璃粉(GP)作为硅质材料对蒸压材料强度、水化产物和微观结构的影响。结果表明,GP 比 FA 更有利于抗压强度的增长。在 Ca/Si 比为 0.7 时,GP 混合物的抗压强度比 FA 混合物高 95.7%,并且抗压强度随着 GP 替代 FA 比例的增加呈单调上升趋势。GP 中的二氧化硅比 FA 具有更高的反应活性,能形成更多的水化产物。GP 混合物中的主要水化产物主要是 Ca/Si 比值较低的无定形 C-S-H,它很难结晶并转化成托勃莫来石。FA 有利于托勃莫来石的形成,随着 GP 取代 FA,纤维状托勃莫来石被片状托勃莫来石取代,甚至在 GP 取代率较高时,箔状相也会被取代。此外,GP 混合物中的水合产物密度低于 FA 混合物,但有利于降低蒸压材料的孔隙率。低孔隙率是 GP 作为硅质原料可用于制备高强度蒸压材料的重要原因。
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引用次数: 0
Probing the Abyss: Bacteria-based self-healing in cementitious construction materials – A Review 探索深渊:基于细菌的水泥基建筑材料自愈合 - 综述
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139054
Trupti Sharma , Anirban Banerjee , Prakash Nanthagopalan
The inclusion of bacteria in developing advanced, self-sensing, and self-healing cement-based materials in crack healing is a sustainable and innovative approach in Civil Engineering applications. As a response to the surrounding environment, the bacterial metabolism leads to microbially induced calcium carbonate precipitation (MICCP). This phenomenon is mostly prevalent with genus Bacillus and other genera. Bacteria being ubiquitous, survive in different environmental conditions, and can precipitate calcium carbonate through different biochemical pathways. Largely, (ureolytic) and (non-ureolytic) bacteria are studied for calcium carbonate precipitation in the cracks and heal them sustainably. Though immense work has been done and published in this domain, the technology transfer from lab-scale to meso-scale has been inefficient due to various factors. Primarily, the bacteria’s specific growth conditions such as optimum pH, temperature, humidity, oxygen availability could limit the translation of this technology to the real-world. Secondly, parameters such as water quality used for mixing of the cementitious materials, curing conditions, incubation time and temperature, and humidity vary from lab to lab causing diverse observations. Thirdly, the BBSHCM's formulation with lab-grade chemicals is expensive. The researchers are exploring alternative nutrient substitutes. Enormous literature ranging from meso to macro-scale studies has been published. This review is a wide-ranging effort to compile the knowledge from published literature on the roles of ureolytic and non-ureolytic bacteria in calcite formation, the problems associated with the delivery of bio-healants at the site of damage, impact of MICCP bacteria on the healing ability and mechanical properties of cementitious material, studies from various field trials, and the economic viability of these systems are discussed and summarised at the end. The aim is to present a comprehensive understanding of the concept of bacteria-based self-healing cementitious material (BBSHCM). To conclude, the variations in results and prospects are recognized and proposed in the final section.
在开发先进的自感应和自修复水泥基裂缝愈合材料时加入细菌,是土木工程应用中一种可持续的创新方法。作为对周围环境的反应,细菌的新陈代谢会导致微生物诱导碳酸钙沉淀(MICCP)。这种现象主要发生在芽孢杆菌属和其他属中。细菌无处不在,能在不同的环境条件下生存,并能通过不同的生化途径沉淀碳酸钙。人们主要研究(尿素分解)和(非尿素分解)细菌在裂缝中沉淀碳酸钙并持续愈合裂缝的作用。虽然在这一领域已经做了大量工作并发表了论文,但由于各种因素,从实验室规模到中观规模的技术转让一直效率低下。首先,细菌的特定生长条件(如最佳 pH 值、温度、湿度、氧气可用性)会限制该技术在现实世界中的应用。其次,不同实验室的水泥基材料混合水质、固化条件、培养时间、温度和湿度等参数各不相同,导致观察结果也不尽相同。第三,BBSHCM 的实验室级化学品配方价格昂贵。研究人员正在探索其他营养替代品。从中观到宏观研究的大量文献已经出版。本综述广泛收集了已发表文献中关于尿解和非尿解细菌在方解石形成过程中的作用、生物修复剂在损伤部位的输送相关问题、MICCP 细菌对水泥基材料愈合能力和机械性能的影响、各种现场试验研究的知识,并在最后讨论和总结了这些系统的经济可行性。目的是全面介绍基于细菌的自愈合水泥基材料(BBSHCM)的概念。最后,在最后一节中对结果和前景的变化进行了总结和建议。
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引用次数: 0
Experimental study on high-cycle fatigue performance of laser cladding additively manufactured 316L stainless steel 激光熔覆快速成型 316L 不锈钢高循环疲劳性能的实验研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139214
Ziyi Wang , Yue Yuan , Xiang Zhang , Bin Zeng , Chun-Lin Wang
Laser cladding (LC) technology has garnered significant attention for its application in the repair of corrosion damage in steel structures. However, research on the high-cycle fatigue performance of LC materials remains limited. This study employed 316L stainless steel powder to produce LC specimens and conducted uniaxial tensiletensile high-cycle fatigue tests to explore various laser deposition directions and surface roughnesses. The resulting SN curves provide insights into the high-cycle fatigue behaviour of LC materials. Additionally, SEM images were utilized to analyse the fatigue failure fracture characteristics. The experimental results reveal that cladding materials deposited parallel to the loading direction exhibit superior high-cycle fatigue performance. Fatigue fractures in the specimens generally originate from laser fusion defects, which not only reduce the lifespan of the specimen but also influence the failure location. Fatigue failure assessments of the laser-cladded materials were conducted via equivalent life diagrams, which revealed a high degree of correlation with the actual failure conditions. Existing fatigue design curves for base materials can be applied to the high-cycle fatigue performance design of laser-cladded 316L stainless steel, demonstrating a performance that surpasses the average level of steel butt welds.
激光熔覆(LC)技术因其在钢结构腐蚀损伤修复中的应用而备受关注。然而,对 LC 材料高循环疲劳性能的研究仍然有限。本研究采用 316L 不锈钢粉末制作 LC 试样,并进行了单轴拉伸高循环疲劳试验,以探索各种激光沉积方向和表面粗糙度。由此得出的 SN 曲线有助于深入了解 LC 材料的高循环疲劳行为。此外,还利用扫描电子显微镜图像分析了疲劳破坏的断裂特征。实验结果表明,平行于加载方向沉积的覆层材料具有优异的高循环疲劳性能。试样的疲劳断裂一般源于激光熔融缺陷,这不仅会缩短试样的寿命,还会影响断裂位置。通过等效寿命图对激光熔覆材料进行了疲劳失效评估,结果显示与实际失效条件高度相关。现有的母材疲劳设计曲线可用于激光包覆 316L 不锈钢的高循环疲劳性能设计,其性能超过了钢对接焊缝的平均水平。
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引用次数: 0
Mechanical properties and micro-mechanisms of geopolymer solidified salinized loess 土工聚合物固化盐渍化黄土的力学性能和微观机制
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139211
Xi Yang , Zaiqiang Hu , Yi Wang , Yao Zhang , Xiaoliang Wang , Bin Hou , Yuxuan Wei , Chaochao Liu
Salinized loess exhibits poor engineering properties, including low strength, salt migration, and instability, due to the combined characteristics of loess and saline soil. This poses serious threats to the safety and stability of buildings, roads, and other infrastructure. To address this issue, this study aims to solidify salinized loess using geopolymer produced through alkali activation of industrial waste, including slag powder and fly ash. An orthogonal experimental design was used to systematically investigate the mechanical properties, microstructural characteristics, and solidification mechanism of geopolymer solidified salinized loess. The tests included unconfined compressive strength (UCS), direct shear, pH, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) to evaluate the influences of different factors on the solidification effect. The results showed that the sodium silicate solution modulus was the primary factor affecting the strength of solidified salinized loess, followed by the amounts of fly ash and slag powder. The Baumé degree (°Bé) had the least impact. Under the optimal conditions (1 modulus, 35 °Bé, slag powder and fly ash ratio of 1:0), the UCS of the sample at 28 days reached 3204.06 kPa, which increased by 16.32 times compared with the unsolidified sample. Lowering the modulus and increasing the proportion of slag powder and the Baumé degree increased the sample pH. Micro-analysis revealed that the strength increase was mainly due to the bonding of soil particles by gel substances (C-S-H, N-A-S-H, andC-A-S-H) formed during alkali activation, as well as the filling effect of unreacted slag powder and fly ash. The findings of this study provide valuable theoretical and practical insights for treating salinized loess in engineering, offering essential references for optimizing geopolymer solidifier ratios.
由于黄土和盐碱土的综合特性,盐碱化黄土的工程特性很差,包括强度低、盐分迁移和不稳定性。这对建筑物、道路和其他基础设施的安全性和稳定性构成了严重威胁。为解决这一问题,本研究旨在使用通过碱活化工业废料(包括矿渣粉和粉煤灰)生产的土工聚合物来固化盐碱化黄土。本研究采用正交实验设计,系统地研究了土工聚合物固化盐渍化黄土的力学性能、微观结构特征和固化机理。试验包括无压抗压强度(UCS)、直接剪切力、pH值、扫描电子显微镜(SEM)、能量色散光谱(EDS)和 X 射线衍射(XRD),以评估不同因素对固化效果的影响。结果表明,硅酸钠溶液模量是影响固化盐化黄土强度的主要因素,其次是粉煤灰和矿渣粉的用量。波美度(°Bé)的影响最小。在最佳条件下(模量 1,35 °Bé,矿渣粉和粉煤灰的比例为 1:0),28 天时样品的 UCS 达到 3204.06 kPa,与未固化样品相比增加了 16.32 倍。降低模量、增加矿渣粉比例和波美度可提高样品的 pH 值。微观分析表明,强度增加的主要原因是碱活化过程中形成的凝胶物质(C-S-H、N-A-S-H 和 C-A-S-H)对土颗粒的粘结作用,以及未反应的矿渣粉和粉煤灰的填充作用。该研究结果为工程中处理盐渍化黄土提供了宝贵的理论和实践见解,为优化土工聚合物固化剂配比提供了重要参考。
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引用次数: 0
Performance optimization of novel wear-resistant reflective cooling coatings for asphalt pavement 新型沥青路面耐磨反射冷却涂层的性能优化
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139207
Wei Si , Qiutai Gu , Yike Yin , Xiangyu Luo , Moxuan Xia , Xin Li , Maoning Zhong , Yongping Hu
To enhance the wear resistance of traditional asphalt pavement reflective coatings and extend their cooling effect, this study employed Potassium Hexatitanate Whiskers (PHW) as a functional material to manufacture pavement reflective coatings. It was found that PHW exhibited excellent wear resistance though agglomeration resulted in adverse effects. Therefore, untreated PHW (U-PHW) underwent inorganic-organic surface modification to produce modified PHW (M-PHW). The results indicated that M-PHW exhibited excellent optical properties, with a reflectance of 78.9 %. M-PHW exhibited more uniform dispersion in the resin matrix, which significantly enhanced the coating reflectivity. Moreover, the interfacial bonding strength between M-PHW and the resin matrix was significantly improved, enhancing the wear resistance of the coating. Especially with a whisker content of 16 units, the tensile strength of the M-PHW coating reached 96.20 MPa, representing a 43.0 % increase compared to the U-PHW coating, while achieving a maximum outdoor cooling value of 5.6 °C.
为了提高传统沥青路面反光涂层的耐磨性并延长其冷却效果,本研究采用六钛酸钾晶须(PHW)作为功能材料来制造路面反光涂层。研究发现,PHW 具有优异的耐磨性,但结块会带来不利影响。因此,对未经处理的 PHW(U-PHW)进行了无机-有机表面改性,制成了改性 PHW(M-PHW)。结果表明,M-PHW 具有优异的光学特性,反射率高达 78.9%。M-PHW 在树脂基体中的分散更加均匀,从而显著提高了涂层的反射率。此外,M-PHW 与树脂基体之间的界面结合强度也得到了显著提高,从而增强了涂层的耐磨性。特别是在晶须含量为 16 个单位时,M-PHW 涂层的拉伸强度达到 96.20 兆帕,与 U-PHW 涂层相比提高了 43.0%,同时室外最大冷却值达到 5.6 °C。
{"title":"Performance optimization of novel wear-resistant reflective cooling coatings for asphalt pavement","authors":"Wei Si ,&nbsp;Qiutai Gu ,&nbsp;Yike Yin ,&nbsp;Xiangyu Luo ,&nbsp;Moxuan Xia ,&nbsp;Xin Li ,&nbsp;Maoning Zhong ,&nbsp;Yongping Hu","doi":"10.1016/j.conbuildmat.2024.139207","DOIUrl":"10.1016/j.conbuildmat.2024.139207","url":null,"abstract":"<div><div>To enhance the wear resistance of traditional asphalt pavement reflective coatings and extend their cooling effect, this study employed Potassium Hexatitanate Whiskers (PHW) as a functional material to manufacture pavement reflective coatings. It was found that PHW exhibited excellent wear resistance though agglomeration resulted in adverse effects. Therefore, untreated PHW (U-PHW) underwent inorganic-organic surface modification to produce modified PHW (M-PHW). The results indicated that M-PHW exhibited excellent optical properties, with a reflectance of 78.9 %. M-PHW exhibited more uniform dispersion in the resin matrix, which significantly enhanced the coating reflectivity. Moreover, the interfacial bonding strength between M-PHW and the resin matrix was significantly improved, enhancing the wear resistance of the coating. Especially with a whisker content of 16 units, the tensile strength of the M-PHW coating reached 96.20 MPa, representing a 43.0 % increase compared to the U-PHW coating, while achieving a maximum outdoor cooling value of 5.6 °C.</div></div>","PeriodicalId":288,"journal":{"name":"Construction and Building Materials","volume":"455 ","pages":"Article 139207"},"PeriodicalIF":7.4,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative analysis of the performance of Thin Spray-on Liner with shotcrete and mesh support 采用喷射混凝土和网格支撑的薄喷衬砌性能比较分析
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139195
Jun Yang , Zhe Li , Xiaohui He , Ying Zhao , Zhicheng Sun , Ziniu Wang , Wenhui Bian
In order to study the effect of different surface protection components, such as Thin Spray-on Liner (TSL), in the support system of prestressed bolts on the critical rock mass, based on the similarity theory, physical modeling tests were designed and carried out for the support of the critical rock mass by the combination of NPR bolts and PR bolts with three types of surface protection components, such as TSL, sprayed concrete, and metal mesh, respectively. The test results show that the three types of surface protection components can significantly increase the threshold value of crack development of the critical rock specimen and effectively improve the peak bearing capacity of the critical rock body, and at the same time, the NPR bolts with higher strength and elongation have a more significant effect on the improvement of the peak bearing capacity of the critical rock specimen. In addition, TSL and spray-mixed support and specimen surface can realize close fit, in the loading of the early support response is more timely, in the late loading, compared with the spray-mixed material in the rupture of debris collapse, TSL in the occurrence of tearing can still be tightly adhered to the specimen proximity surface of the rock specimen, to prevent specimen debris fall. For the phenomenon of TSL coating rupture in the experiments, the energy balance equation was established to analyze the connection between the actual energy absorption effect and the theoretical value of the combination of TSL and bolts under the pre-stressed bolts support system, and it was found that the combination of pre-stressed bolts and TSL greatly improved the actual energy absorption effect of the support system as a whole, and the analytical results of the various experimental subgroups showed better results than the theoretical values. The analysis results of the subgroups show a good fit.
为了研究预应力螺栓支撑体系中不同表面保护构件(如薄喷衬里(TSL))对临界岩体的影响,基于相似性理论,设计并开展了NPR螺栓和PR螺栓分别与TSL、喷射混凝土和金属网等三种表面保护构件组合支撑临界岩体的物理模型试验。试验结果表明,三种表面保护部件均能显著提高临界岩体试件的裂缝发展临界值,有效提高临界岩体的峰值承载力,同时,强度和延伸率较高的 NPR 螺栓对临界岩体试件峰值承载力的提高效果更为显著。此外,TSL与喷混支座及试件表面可实现紧密贴合,在加载初期支座响应较为及时,在加载后期,与喷混材料在碎屑破裂坍塌时相比,TSL在发生撕裂时仍能紧贴试件临近岩体试件表面,防止试件碎屑掉落。针对实验中TSL涂层破裂的现象,建立了能量平衡方程,分析了预应力螺栓支撑体系下TSL与螺栓组合的实际吸能效果与理论值之间的联系,发现预应力螺栓与TSL的组合大大提高了支撑体系整体的实际吸能效果,各实验子组的分析结果均表现出优于理论值的效果。各分组的分析结果显示出良好的拟合效果。
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引用次数: 0
Self-sensing performance of the CAC-based MWCNT/NCB composite at high temperatures 基于 CAC 的 MWCNT/NCB 复合材料在高温下的自感应性能
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139113
Alamgir Khan , Yingzi Yang , Shafi Ullah , Hassan Bilal , Zhichao Xu , Xiaobing Ma
Cement-based smart intrinsic composites incorporating nanocarbon-based fillers are recognized for their self-sensing abilities at ambient temperatures. However, these cement-based composites are susceptible to spalling under high-temperature conditions. Utilizing the spalling resistance of calcium aluminate cement (CAC), this study investigates the mechanical properties and piezoresistive behavior of CAC composites that incorporate multi-walled carbon nanotubes (MWCNT) and nanocarbon black (NCB) under ambient and after exposure to peak temperatures of 200°C, 400°C, and 500°C for 2 hours. The results indicate that a higher MWCNT/NCB content leads to increased compressive strength and reduced electrical resistivity. The piezoresistive performance of the composites exhibited an initial increase across CNB1 (MWCNT/NCB: 0.25/0.20 wt%), CNB2 (MWCNT/NCB: 0.50/0.40 wt%), and CNB3 (MWCNT/NCB: 0.75/0.60 wt%). However, a decline was observed in CNB4 (MWCNT/NCB: 1.0/0.80 wt%). Notably, CNB3, with its optimal concentration, demonstrated a significant enhancement in piezoresistivity, achieving a 44 % fractional change in electrical resistivity (FCR). After exposure to 200°C, the control specimen and CNB1-CNB4 exhibited peak compressive strength due to the additional hydration of anhydrous CAC and silica fume, and CNB3 reached a peak FCR of 49 %. Subsequently, after exposure to 500°C, all mixtures displayed a loss in strength; however, CNB3 and CNB4 exhibited a lower strength loss along with a slight decline in piezoresistive performance. These results highlight the potential application of CAC-based MWCNT/NCB smart intrinsic composites under extreme environmental conditions.
含有纳米碳基填料的水泥基智能本征复合材料因其在环境温度下的自感应能力而广受认可。然而,这些水泥基复合材料在高温条件下容易发生剥落。利用铝酸钙水泥(CAC)的抗剥落性,本研究调查了含有多壁碳纳米管(MWCNT)和纳米炭黑(NCB)的 CAC 复合材料在环境温度下以及暴露于 200°C、400°C 和 500°C 的峰值温度 2 小时后的机械性能和压阻行为。结果表明,MWCNT/NCB 含量越高,抗压强度越大,电阻率越小。复合材料的压阻性能在 CNB1(MWCNT/NCB:0.25/0.20 wt%)、CNB2(MWCNT/NCB:0.50/0.40 wt%)和 CNB3(MWCNT/NCB:0.75/0.60 wt%)中表现出最初的上升。然而,CNB4(MWCNT/NCB:1.0/0.80 wt%)则出现了下降。值得注意的是,最佳浓度的 CNB3 显著提高了压阻系数,实现了 44% 的电阻率分数变化(FCR)。暴露于 200°C 高温后,由于无水 CAC 和硅灰的额外水合作用,对照试样和 CNB1-CNB4 显示出峰值抗压强度,CNB3 的峰值 FCR 为 49%。随后,在暴露于 500°C 高温后,所有混合物的强度都有所下降;但 CNB3 和 CNB4 的强度下降较小,压阻性能也略有下降。这些结果凸显了基于 CAC 的 MWCNT/NCB 智能本征复合材料在极端环境条件下的潜在应用。
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引用次数: 0
Material characterization and thermal performance of polyethylene fiber-reinforced lightweight engineered geopolymer composites subjected to sulfate attacks 受硫酸盐侵蚀的聚乙烯纤维增强轻质工程土工聚合物复合材料的材料表征和热性能
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139156
Ali Raza , Abdelatif Salmi , Mohamed Hechmi El Ouni , Nejib Ghazouani , Bilal Ahmed , Wensu Chen
The purpose of this research is to use different amounts of fly ash (FA) and ground granulated blast furnace slag (GGBS) to replace ordinary Portland cement (OPC) in polyethylene (PE) fiber-reinforced lightweight engineered geopolymers (LEGP). The mechanical characteristics and durability of these composites are examined, and the results were compared with lightweight engineered cementitious composites (LECC). Expanded glass aggregates were used to produce lightweight LEGP and LECC composites. The composites were exposed to a 5 % Na2SO4 solution for up to 180 days. The performance of LEGP and LECC specimens under normal and sulfate environments was assessed using a variety of tests and analyses, including evaluations of relative slump, density, compressive stress-strain behavior, flexural strength, load-deflection response, split tensile strength, ultrasonic pulse velocity, initial surface absorption, mass change, and mercury intrusion porosimetry (MIP). Microstructural and mineralogical analysis of the composite matrix was conducted using scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). Thermogravimetric analysis (TGA) and differential thermogravimetry (DTG) were employed to evaluate the thermal stability of the composites. The results showed that in both normal and sulfate conditions, LEGP specimens with 100 % GGBS showed higher residual compressive, flexural, and split tensile strengths while having minimum initial surface absorption and mass loss as compared with LECC specimens. MIP analysis showed that LEGP mixes with 100 % FA exhibited a more notable increase in pore volume under sulfate exposure leading to reduced performance. LECC specimens subjected to 5 % Na2SO4 solution showed peaks of quartz, mullite, portlandite, and ettringite at higher intensities with calcite and nepheline minerals at lower intensities, while LEGP samples subjected to 5 % Na2SO4 solution were characterized by the formation of quartz, mullite, portlandite, calcite, zeolite, gypsum, and ettringite peaks. FTIR and DTG results showed that CSH and Ca(OH)2 were transformed into gypsum and mullite after a sulfate attack for 180 days.
本研究的目的是在聚乙烯(PE)纤维增强轻质工程土工聚合物(LEGP)中使用不同量的粉煤灰(FA)和磨细高炉矿渣(GGBS)来替代普通硅酸盐水泥(OPC)。研究了这些复合材料的机械特性和耐久性,并将结果与轻质工程水泥基复合材料(LECC)进行了比较。膨胀玻璃集料用于生产轻质 LEGP 和 LECC 复合材料。将这些复合材料暴露在 5% 的 Na2SO4 溶液中长达 180 天。采用各种测试和分析方法对 LEGP 和 LECC 试样在正常和硫酸盐环境下的性能进行了评估,包括相对坍落度、密度、压缩应力-应变行为、抗弯强度、载荷-挠度响应、劈裂拉伸强度、超声波脉冲速度、初始表面吸收、质量变化和汞侵入孔隙模拟 (MIP) 等方面的评估。使用扫描电子显微镜(SEM)、X 射线衍射(XRD)和傅立叶变换红外光谱(FTIR)对复合基质进行了微观结构和矿物学分析。热重分析法(TGA)和差热分析法(DTG)用于评估复合材料的热稳定性。结果表明,在正常和硫酸盐条件下,与 LECC 试样相比,含有 100% GGBS 的 LEGP 试样显示出更高的残余抗压、抗弯和劈裂拉伸强度,同时初始表面吸收和质量损失最小。MIP 分析表明,含 100% FA 的 LEGP 混合料在硫酸盐暴露下孔隙体积增加更明显,导致性能下降。在 5 %Na2SO4 溶液中的 LECC 试样显示出较高强度的石英、莫来石、硅酸盐和埃曲石峰,以及较低强度的方解石和霞石矿物,而在 5 %Na2SO4 溶液中的 LEGP 试样则显示出石英、莫来石、硅酸盐、方解石、沸石、石膏和埃曲石峰的形成。傅立叶变换红外光谱和 DTG 结果表明,C-S-H 和 Ca(OH)2 在硫酸盐侵蚀 180 天后转化为石膏和莫来石。
{"title":"Material characterization and thermal performance of polyethylene fiber-reinforced lightweight engineered geopolymer composites subjected to sulfate attacks","authors":"Ali Raza ,&nbsp;Abdelatif Salmi ,&nbsp;Mohamed Hechmi El Ouni ,&nbsp;Nejib Ghazouani ,&nbsp;Bilal Ahmed ,&nbsp;Wensu Chen","doi":"10.1016/j.conbuildmat.2024.139156","DOIUrl":"10.1016/j.conbuildmat.2024.139156","url":null,"abstract":"<div><div>The purpose of this research is to use different amounts of fly ash (FA) and ground granulated blast furnace slag (GGBS) to replace ordinary Portland cement (OPC) in polyethylene (PE) fiber-reinforced lightweight engineered geopolymers (LEGP). The mechanical characteristics and durability of these composites are examined, and the results were compared with lightweight engineered cementitious composites (LECC). Expanded glass aggregates were used to produce lightweight LEGP and LECC composites. The composites were exposed to a 5 % <span><math><mrow><mi>N</mi><msub><mrow><mi>a</mi></mrow><mrow><mn>2</mn></mrow></msub><mi>S</mi><msub><mrow><mi>O</mi></mrow><mrow><mn>4</mn></mrow></msub></mrow></math></span> solution for up to 180 days. The performance of LEGP and LECC specimens under normal and sulfate environments was assessed using a variety of tests and analyses, including evaluations of relative slump, density, compressive stress-strain behavior, flexural strength, load-deflection response, split tensile strength, ultrasonic pulse velocity, initial surface absorption, mass change, and mercury intrusion porosimetry (MIP). Microstructural and mineralogical analysis of the composite matrix was conducted using scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). Thermogravimetric analysis (TGA) and differential thermogravimetry (DTG) were employed to evaluate the thermal stability of the composites. The results showed that in both normal and sulfate conditions, LEGP specimens with 100 % GGBS showed higher residual compressive, flexural, and split tensile strengths while having minimum initial surface absorption and mass loss as compared with LECC specimens. MIP analysis showed that LEGP mixes with 100 % FA exhibited a more notable increase in pore volume under sulfate exposure leading to reduced performance. LECC specimens subjected to 5 % <span><math><mrow><mi>N</mi><msub><mrow><mi>a</mi></mrow><mrow><mn>2</mn></mrow></msub><mi>S</mi><msub><mrow><mi>O</mi></mrow><mrow><mn>4</mn></mrow></msub></mrow></math></span> solution showed peaks of quartz, mullite, portlandite, and ettringite at higher intensities with calcite and nepheline minerals at lower intensities, while LEGP samples subjected to 5 % <span><math><mrow><mi>N</mi><msub><mrow><mi>a</mi></mrow><mrow><mn>2</mn></mrow></msub><mi>S</mi><msub><mrow><mi>O</mi></mrow><mrow><mn>4</mn></mrow></msub></mrow></math></span> solution were characterized by the formation of quartz, mullite, portlandite, calcite, zeolite, gypsum, and ettringite peaks. FTIR and DTG results showed that <span><math><mrow><mi>C</mi><mo>−</mo><mi>S</mi><mo>−</mo><mi>H</mi></mrow></math></span> and <span><math><mrow><mi>Ca</mi><msub><mrow><mo>(</mo><mi>OH</mi><mo>)</mo></mrow><mrow><mn>2</mn></mrow></msub></mrow></math></span> were transformed into gypsum and mullite after a sulfate attack for 180 days.</div></div>","PeriodicalId":288,"journal":{"name":"Construction and Building Materials","volume":"455 ","pages":"Article 139156"},"PeriodicalIF":7.4,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142663835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion behavior of steel bars in simulated concrete pore solution under the coupling action of chloride salt and DC stray current 氯盐和直流杂散电流耦合作用下模拟混凝土孔隙溶液中钢筋的腐蚀行为
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-16 DOI: 10.1016/j.conbuildmat.2024.139126
Peng Zhao , Gang Xu , Qing Wang , Zhen Zeng
The stray current generated during the operation of rail transit projects located in coastal and saline soil areas often makes the concrete structures along the line in a deteriorating environment with the coexistence of chloride salt and stray current, which significantly accelerates the corrosion process of steel bars and endangers the safety of engineering structures. In this paper, the depassivation behavior and corrosion behavior of steel bars in simulated pore solution under the combined action of low DC stray current and chloride ion were studied by electrochemical method. The results show that when the DC stray current and chloride ion coexist, the steel bar is easy to depassivate, and the two promote each other, the coupling effect is obvious. At a constant chloride ion concentration, the pH, chloride ion concentration of the corrosive medium and current density will affect the corrosion current efficiency. In the high pH environment, the current efficiency gradually increases with the increase of chloride ion concentration, but as the pH decreases or the chloride ion concentration continues to increase, the current efficiency is slightly greater than 1.0. When the concentration of chloride ions is inconsistent, the higher the concentration of chloride ions in a local area, the more severe the corrosion of the rebar in that area. The difference in resistance between the steel bar and the cathode caused by the concentration difference of chloride ions is the main reason for the different electricity consumption in each region and the overall uneven corrosion.
位于沿海和盐碱地地区的轨道交通工程在运营过程中产生的杂散电流,往往使沿线混凝土结构处于氯盐和杂散电流共存的恶化环境中,大大加速了钢筋的腐蚀过程,危及工程结构的安全。本文采用电化学方法研究了低直流杂散电流和氯离子共同作用下模拟孔隙溶液中钢筋的去钝化行为和腐蚀行为。结果表明,当直流杂散电流和氯离子共存时,钢棒容易发生去钝化,二者相互促进,耦合效应明显。在氯离子浓度不变的情况下,腐蚀介质的 pH 值、氯离子浓度和电流密度都会影响腐蚀电流效率。在高 pH 值环境中,电流效率随氯离子浓度的增加而逐渐增大,但随着 pH 值的降低或氯离子浓度的继续增加,电流效率略大于 1.0。当氯离子浓度不一致时,局部区域的氯离子浓度越高,该区域的钢筋腐蚀越严重。氯离子浓度差异造成的钢筋与阴极之间的电阻差异,是造成各区域耗电量不同和整体腐蚀不均匀的主要原因。
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引用次数: 0
Mixture proportion optimization and durability evaluation of rejuvenating composite seal 再生复合密封材料的混合比例优化和耐久性评估
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-15 DOI: 10.1016/j.conbuildmat.2024.139208
Xueqi Wang , Mulian Zheng , Chenxu Gong , Hongyin Li , Sai Ma , Jinghan Xu
Composite seal (CS) is effective in restoring pavement surface function and prolonging the service life, employing a double-layer structure composed of micro-surfacing and chip seal. Rejuvenating composite seal (RCS) applying rejuvenating agents to the chip seal is dedicated to revitalizing the aged asphalt of the original pavement surface. However, limited studies have focused on enhancing interlayer and temperature performance through optimizing mixture ratios. In this study, a modified emulsified asphalt with self-developed rejuvenating agent was applied, and the orthogonal test considering interlayer shear resistance and high temperature stability was conducted for initially mixture proportion of RCS, then the preliminary ratio was optimized. The proportion for micro-surfacing was determined by mixing test, wet track abrasion test, and loaded wheel sticking sand test. Simultaneously, the recommended asphalt spraying amount of rejuvenating chip seal was determined by utilizing accelerated loading abrasion test. In view of the abrasion resistance, interlayer adhesion, and cracking resistance, the coupled effects of aggregate size and paving rate of rejuvenating chip seal were studied. Long-term wet track abrasion test, freeze-thaw cycle test, and UV aging test were conducted to evaluate the durability. The results show that the asphalt-aggregate ratio of micro-surfacing is 7.1 %. For 4.75 mm or 7 mm rejuvenating chip seal, the recommended asphalt spraying amount is 1.5 kg/m2 or 1.6 kg/m2, and the range of paving rate is 60 %–70 %. For 9.5 mm or 13.2 mm rejuvenating chip seal, the results are 1.7 kg/m2 or 1.8 kg/m2, and 80 %–90 %, respectively. Under the conditions, RCS has better interlayer shear resistance and temperature performance, which can improve durability.
复合封层(CS)采用由微铺层和芯片封层组成的双层结构,可有效恢复路面表面功能并延长使用寿命。在芯片封层中使用再生剂的再生复合封层(RCS)致力于恢复原路面表面的老化沥青。然而,通过优化混合料配比来提高层间和温度性能的研究还很有限。本研究应用了一种含有自主研发的再生剂的改性乳化沥青,并对 RCS 的初始混合料配比进行了考虑层间抗剪切性和高温稳定性的正交试验,然后对初步配比进行了优化。通过混合试验、湿履带磨损试验和加载车轮粘砂试验,确定了微表处的配比。同时,通过加速加载磨损试验确定了再生芯片封层的推荐沥青喷洒量。从耐磨性、层间附着力和抗裂性的角度,研究了集料粒径和再生刨花密封层摊铺率的耦合效应。为评估耐久性,还进行了长期湿迹磨损试验、冻融循环试验和紫外线老化试验。结果表明,微表处的沥青-骨料比为 7.1%。对于 4.75 毫米或 7 毫米的再生碎屑封层,建议的沥青喷洒量为 1.5 千克/平方米或 1.6 千克/平方米,摊铺率范围为 60%-70%。对于 9.5 毫米或 13.2 毫米的再生封层,结果分别为 1.7 千克/平方米或 1.8 千克/平方米,摊铺率范围为 80%-90%。在此条件下,RCS 具有更好的层间抗剪性能和温度性能,可提高耐久性。
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引用次数: 0
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Construction and Building Materials
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