To facilitate the high-value, large-scale utilization of industrial solid waste, a fully solid-waste CDRG cementitious material was developed using calcium carbide residue (CCR), desulfurization gypsum (DG), red mud (RM), and granulated blast furnace slag (GBFS). Fifteen experimental groups were designed employing a controlled-variable approach. Rheological properties, setting time, and unconfined compressive strength (UCS) were measured. Microscopic techniques, including SEM, FT-IR, and TG-DTG, were employed to investigate the effects of CCR content, DG content, and the RM:GBFS ratio on the properties of the CDRG cementitious materials and to elucidate the underlying strength development mechanism. The results indicate that CDRG cementitious materials exhibit distinct shear-thinning behavior, with shear rate-shear stress curves following the Modified Bingham model. Both the yield stress and plastic viscosity increased with higher CCR content, DG content, and RM:GBFS ratio. The setting time decreases with increasing CCR content and RM-GBFS ratio, while it increases with rising DG content. The UCS gradually increases with curing age. Group A shows a “first increase, then decrease” trend in UCS with increasing CCR content, while Group B exhibits a similar trend with increasing DG content. Specimens A4 (CCR content 20 %) and B4 (DG content 8 %) showed 28-day UCS values of 10.91 MPa and 15.89 MPa, respectively. The UCS of Group C gradually decreased with increasing RM proportion, with specimen C1 (RM:GBFS ratio 30:70) achieving the highest 28-day UCS of 15.97 MPa. Microscopic analysis indicated that the primary hydration products were C-S-H gel, ettringite (AFt), and minor amounts of portlandite (Ca(OH)2).The high-alkali environment provided by CCR promotes the dissolution of [SiO4]4- and [AlO4]5- from RM-GBFS. The SO42- supplied by DG further accelerates AFt formation. C-S-H gel and AFt interlock to fill pores, collectively enhancing material density and mechanical properties. This study exemplifies the concept of "turning waste into treasure" for resource utilization, providing novel insights and methodologies for the resource recovery of industrial solid wastes.
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