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Investigating the impact of porous steel slag aggregates on the low-temperature crack resistance of asphalt concrete 研究多孔钢渣集料对沥青混凝土低温抗裂性能的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.138914
Zehan Shen , Yuanjie Xiao , Ke Hou , Yuliang Chen , Fanwei Meng
The macroscopic and microscopic mechanisms of the impact of the porous characteristics of steel slag aggregates on the low-temperature crack resistance of asphalt concrete are not yet fully understood, which is detrimental to the effective maintenance of the durability of asphalt pavement containing steel slag aggregates. To address this deficiency, various index property tests were first conducted on steel slag aggregates, and the basic shape features of steel slag particles were captured and quantified through blue light laser scanning. Subsequently, the gradation of steel slag asphalt concrete (SSAC) was optimized, and two new preparation techniques for steel slag asphalt concrete were proposed. Finally, based on the laboratory low-temperature three-point bending (TPB) test, a refined discrete element method (DEM) model of the SSAC beam that can characterize various microscopic groups was constructed. The experimental research results show that controlling the heating temperature of steel slag aggregates according to their moisture content can ensure the full evaporation of pore moisture. Concurrently, extending the wet mixing time can ensure that the asphalt mortar fully fills the surface pores of the steel slag aggregates, and the low-temperature crack resistance of the SSAC specimens treated as above all satisfies the specification requirements. The numerical simulation results show that stress concentration occurs near the pores of the steel slag aggregates, which directly explains why cracks tend to appear near such pores. The higher the porosity of the steel slag aggregates, the greater the decrease in the comprehensive index of low-temperature crack resistance (up to a decrease of 6.5 %), and the easier it is for cracks to develop from the pores of steel slags. Whether or not the pores of steel slags are filled with asphalt mortar has a greater impact on the low-temperature fracture performance of SSAC. When the pores of steel slags are not filled with asphalt mortar, as the porosity of steel slags increases, the degree of decrease in u_0 increases (up to a decrease of 22.7 %), and the internal damage of steel slags also increases. In actual engineering applications, it is recommended to control the content of large-pore steel slag aggregates and ensure that the asphalt mortar fully fills the pores of the steel slag aggregates to improve low-temperature crack resistance of SSAC.
钢渣集料的多孔特性对沥青混凝土低温抗裂性影响的宏观和微观机理尚未完全明了,这不利于含钢渣集料沥青路面耐久性的有效保持。针对这一不足,首先对钢渣集料进行了各种指标性能测试,并通过蓝光激光扫描捕捉和量化了钢渣颗粒的基本形状特征。随后,优化了钢渣沥青混凝土(SSAC)的级配,并提出了两种新的钢渣沥青混凝土制备技术。最后,在实验室低温三点弯曲(TPB)试验的基础上,构建了可表征各种微观组的钢渣沥青混凝土梁离散元法(DEM)精细模型。实验研究结果表明,根据钢渣集料的含水量控制其加热温度可确保孔隙水分充分蒸发。同时,延长湿拌时间可确保沥青砂浆充分填充钢渣骨料表面孔隙,经上述处理的 SSAC 试件的低温抗裂性能均满足规范要求。数值模拟结果表明,应力集中发生在钢渣骨料的孔隙附近,这直接解释了为什么裂缝容易出现在这些孔隙附近。钢渣集料的孔隙率越高,抗低温裂纹综合指数的下降幅度就越大(最多下降 6.5%),裂纹就越容易从钢渣的孔隙中产生。钢渣孔隙是否被沥青砂浆填充对 SSAC 的低温断裂性能影响较大。当钢渣孔隙未被沥青砂浆填充时,随着钢渣孔隙率的增加,u_0 的降低程度也会增加(最多降低 22.7%),钢渣的内部损伤也会增加。在实际工程应用中,建议控制大孔隙钢渣集料的含量,确保沥青砂浆充分填充钢渣集料的孔隙,以提高 SSAC 的低温抗裂性能。
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引用次数: 0
High-efficiency dual protection of photoelectrochemical cathodic protection coating with In2O3/C3N4/CNT nanocomposites for 304 stainless steel in marine environment 在海洋环境中使用 In2O3/C3N4/CNT 纳米复合材料对 304 不锈钢进行高效的光电阴极保护涂层双重保护
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139096
Xiaoying Zhang , Xiaoyuan Li , Xiaoqing Wang , Zuquan Jin
A photoelectrochemical cathodic protection coating with EP/In2O3/C3N4/CNT composite was designed and its anti-corrosion mechanism was further investigated. It was found that the introduction of In2O3/C3N4 not only densified the microporous structure but also enhanced the hydrophobicity, tensile strength and UV aging resistance of epoxy resin (EP) coatings, improving the physical shielding effects of the coating. In addition, the photogenerated electrons produced by In2O3/C3N4 nanocomposites could transfer to surface of 304 SS through the electronic transmission network of CNT under illumination. Owing to its dual protection, the corrosion current (Icorr) of 304 SS/EP/In2O3/C3N4/CNT reduced by 95.8 % and 67.8 % of that of 304SS and 304 SS/EP in dark, respectively. Under illumination, the OCP values of EP/In2O3/C3N4 and EP/In2O3/C3N4/CNT composite coatings were rapidly shifted negatively to −170 mV and −274 mV, respectively, which were both lower than the self-corrosion potential of 304 SS. Therefore, the introduction of optoelectronic nanoparticles into coatings is believed to be an effective strategy for providing dual protection for metals, which not only improved the physical shielding effects of the coating but also enhanced the photocathodic protection performance at the dark state.
设计了一种 EP/In2O3/C3N4/CNT 复合材料光电阴极保护涂层,并进一步研究了其防腐机理。研究发现,In2O3/C3N4 的引入不仅使微孔结构致密化,还增强了环氧树脂(EP)涂层的疏水性、拉伸强度和抗紫外线老化性能,提高了涂层的物理屏蔽效果。此外,In2O3/C3N4 纳米复合材料产生的光生电子在光照下可通过 CNT 的电子传输网络传输到 304 SS 表面。在双重保护作用下,304 SS/EP/In2O3/C3N4/CNT 的腐蚀电流(Icorr)分别比 304SS 和 304 SS/EP 在黑暗条件下降低了 95.8% 和 67.8%。在光照下,EP/In2O3/C3N4 和 EP/In2O3/C3N4/CNT 复合涂层的 OCP 值迅速负移,分别为 -170 mV 和 -274 mV,均低于 304 SS 的自腐蚀电位。因此,在涂层中引入光电纳米粒子被认为是一种为金属提供双重保护的有效策略,它不仅提高了涂层的物理屏蔽效果,还增强了暗态下的光阴极保护性能。
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引用次数: 0
Gas production and slurry expansion behavior of hydrogen peroxide foamed cement pastes 过氧化氢发泡水泥浆的产气和浆体膨胀行为
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139006
Wenjian Xie , Bing Chen , Hui Rong
This study investigated the foaming behavior of hydrogen peroxide (H2O2) foamed cement pastes, with a particular focus on gas production and slurry expansion processes. The effects of varying manganese dioxide (MnO2) dosage (0 %–2 %) and H2O2 dosage (3 %–9 %) on the foaming process of fresh slurry and the properties of hardened specimens were examined. The findings revealed that gas production from H2O2 decomposition followed pseudo-first-order kinetics, with a portion of the generated gas volume converting into slurry volume at lower reaction speeds. While higher H2O2 dosages more effectively improved the final gas and slurry volume, increased MnO2 dosages were more effective in accelerating the foaming process and thereby improving H2O2 and gas utilization efficiency. Furthermore, higher MnO2 dosages raised the first-order reaction rate constants of the gas production curves, whereas higher H2O2 dosages had the opposite effect. Additionally, increased MnO2 or H2O2 dosages led to larger pore sizes and a reduction in dry density, compressive strength, and thermal conductivity. These findings underscore the significance of characterizing the foaming process and offer insights into the foaming mechanisms of cement pastes.
本研究调查了过氧化氢(H2O2)发泡水泥浆的发泡行为,尤其关注气体产生和浆体膨胀过程。研究了不同的二氧化锰(MnO2)用量(0 %-2 %)和 H2O2 用量(3 %-9 %)对新鲜水泥浆发泡过程和硬化试样性能的影响。研究结果表明,H2O2 分解产生的气体遵循伪一阶动力学,在较低的反应速度下,产生的部分气体体积转化为泥浆体积。虽然较高的 H2O2 用量能更有效地提高最终气体和泥浆体积,但增加 MnO2 用量能更有效地加速发泡过程,从而提高 H2O2 和气体的利用效率。此外,增加 MnO2 的用量可提高产气曲线的一阶反应速率常数,而增加 H2O2 的用量则效果相反。此外,增加 MnO2 或 H2O2 的用量会导致孔径增大,干密度、抗压强度和热导率降低。这些发现强调了表征发泡过程的重要性,并为水泥浆的发泡机制提供了启示。
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引用次数: 0
Enhancing sustainability in concrete construction: Utilizing copper slag for improved properties of geopolymer concrete 提高混凝土建筑的可持续性:利用铜渣改善土工聚合物混凝土的性能
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139044
Aman Deep, Pradip Sarkar
Geopolymer concrete (GPC), utilizing aluminosilicate precursor materials as binders, stands as an eco-friendly alternative to Portland cement concrete. These precursors commonly include natural resources like metakaolin, volcanic ash, and industrial solid waste such as fly ash (FA) and ground granulated blast furnace slag (GGBFS). However, despite not utilizing cement, GPC still faces environmental challenges due to the use of natural aggregates, leading to resource depletion. To mitigate this issue, researchers have explored replacing natural aggregates with waste materials, aiding both resource conservation and waste management. Copper slag (CS) is one such waste material with potential as fine aggregate in GPC. This study conducts a comprehensive evaluation of FA-GGBFS-based GPC incorporating CS as fine aggregate, revealing notable enhancements in transport, durability, and strength properties. The optimal replacement of 60 % natural sand with CS in GPC resulted in a 20–25 % increase in compressive strength, a 10–15 % improvement in slake durability, an 18–40 % reduction in water absorption, a 30–39 % decrease in permeable voids, and a 26–47 % reduction in depth of wear, all in comparison to the control specimen made with natural sand only. Thus, incorporating CS as a fine aggregate in GPC is recommended as an effective approach to enhance mechanical performance and durability, while contributing to sustainable construction practices.
土工聚合物混凝土(GPC)使用硅酸铝前体材料作为粘结剂,是波特兰水泥混凝土的环保型替代品。这些前体材料通常包括偏高岭土、火山灰等自然资源,以及粉煤灰(FA)和磨细高炉矿渣(GGBFS)等工业固体废弃物。然而,尽管不使用水泥,但由于使用天然骨料,GPC 仍然面临环境挑战,导致资源枯竭。为了缓解这一问题,研究人员探索了用废料替代天然骨料,既有助于节约资源,又有助于废物管理。铜渣(CS)就是这样一种具有在 GPC 中用作细骨料潜力的废料。本研究对以 FA-GGBFS 为基础、将 CS 用作细骨料的 GPC 进行了全面评估,结果显示其在运输、耐久性和强度性能方面都有显著提高。与仅使用天然砂制成的对照试样相比,在 GPC 中用 CS 替代 60% 天然砂的最佳方法使抗压强度提高了 20-25%,抗滑耐久性提高了 10-15%,吸水率降低了 18-40%,渗透空隙减少了 30-39%,磨损深度降低了 26-47%。因此,建议在 GPC 中加入希尔思作为细骨料,这是提高机械性能和耐久性的有效方法,同时也有助于可持续建筑实践。
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引用次数: 0
Analysis of vibration responses in a large airport ground transportation centre caused by maglev and subway trains 大型机场地面交通中心由磁悬浮列车和地铁列车引起的振动响应分析
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139144
Lidong Wang , Tianyang Sun , Jingcheng Chen , Zhen Zhao , Ying Yang , Zhengyu Fu , Yan Han
This study aims to assess the vibration response of the ground transportation centre (GTC) at an airport integrated transportation hub during the starting and braking processes of underground maglev and subway trains. In this work, we considered the actual motion states of trains entering and exiting the GTC and calculated the traction characteristics of maglev and subway trains. On this basis, the vertical coupling vibration models for a medium- and low-speed maglev train-guideway and a subway train-floating slab track considering variable-speed motion, as well as the vehicle longitudinal motion models, were established, and the vertical and longitudinal fastener forces of the tracks were obtained accordingly. Finally, based on the two-step analysis method, the vertical and longitudinal fastener forces were simultaneously applied to the track–GTC–soil finite element model to evaluate the structural vibrations induced by maglev and subway trains. The results show that the amplitude of the vertical fastener force is an order of magnitude greater than that of the longitudinal fastener force, and the amplitude of the vertical fastener force caused by subway trains is greater than that caused by maglev trains. The starting process of both maglev trains and subway trains results in a greater vertical vibration response of the GTC than the braking process, with the impact of subway trains being greater than that of maglev trains. Within the same area, the vertical vibration level observed at structural column observation points is lower than that at slab observation points. When maglev trains and subway trains start simultaneously, the vibration level response at some points exceeds the specified limit of 75 dB.
本研究旨在评估机场综合交通枢纽地面交通中心(GTC)在地下磁悬浮列车和地铁列车启动和制动过程中的振动响应。在这项工作中,我们考虑了列车进出地面交通中心的实际运动状态,并计算了磁悬浮列车和地铁列车的牵引特性。在此基础上,建立了考虑变速运动的中、低速磁悬浮列车-导轨和地铁列车-浮置板轨道的垂直耦合振动模型以及车辆纵向运动模型,并据此求得了轨道的垂直力和纵向扣件力。最后,基于两步分析法,将垂直力和纵向扣件力同时应用于轨道-GTC-土有限元模型,以评估磁悬浮列车和地铁列车引起的结构振动。结果表明,垂直扣件力的振幅比纵向扣件力的振幅大一个数量级,地铁列车引起的垂直扣件力的振幅大于磁悬浮列车引起的垂直扣件力的振幅。与制动过程相比,磁悬浮列车和地铁列车的启动过程都会导致 GTC 产生更大的垂直振动响应,其中地铁列车的影响大于磁悬浮列车。在同一区域内,结构柱观测点观测到的垂直振动水平低于板观测点。当磁悬浮列车和地铁列车同时启动时,某些点的振动水平响应超过 75 dB 的规定限值。
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引用次数: 0
Evaluation on reactivity of fly ash from different sources in alkali activated system-progressing environmentally construction through waste utilization 不同来源的粉煤灰在碱活化体系中的反应性评估--通过废物利用推进环境建设
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139118
Ke-yu Chen , Ri-yan Lan , Ting-quan He , Phirun Heng , Jin Xia
Fly ash, a byproduct of coal-fired thermal power stations, is among the most intricate artificially produced substances. The challenge of its suitable disposal has emerged as both an ecological issue and a squandering of potentially resources. Fly ash has good pozzolanic activity and contains reactive Al and Si components, it has the potential to dissolve under alkaline conditions to form a dense green gel, i.e. alkali activated binder. But, the widespread implementation of fly ash from different sources in generation of products is constrained by the heterogeneity of raw-material supply. In this work, physical performances, chemical-compositions, microstructures, element distribution, crystal structure, chemical-bonds, glassy content, as well as existence form of glassy-phases of eleven fly ashes sourced from different province in China were investigated via FESEM-EDS, XPS, XRD-Rietveld, FTIR, TEM NMR analysis. Then, a reactivity index of fly ash (R value) that concerned the effects of both initial state, particle morphology, internal composition was proposed. R value has been demonstrated to exhibit high predictive accuracy (R2 = 0.81–0.93) for predicting the strengths development of alkali activated products prepared with different activator modules, especially at early period. A further eleven literature datasets were utilized to validated against the accuracy of the predictions. R value facilitates an effective evaluation of fly ashes' fitness for fabricating high-strength alkali activated composites.
粉煤灰是燃煤热电厂的副产品,是最复杂的人工生产物质之一。粉煤灰的适当处置既是一个生态问题,也是对潜在资源的浪费。粉煤灰具有良好的胶凝活性,含有活性 Al 和 Si 成分,在碱性条件下有可能溶解形成致密的绿色凝胶,即碱活化粘结剂。但是,由于原材料供应的不均匀性,广泛使用不同来源的粉煤灰生产产品受到了限制。在这项工作中,通过 FESEM-EDS、XPS、XRD-Rietveld、FTIR、TEM NMR 分析,研究了来自中国不同省份的 11 种粉煤灰的物理性能、化学成分、微观结构、元素分布、晶体结构、化学键、玻璃态含量以及玻璃态的存在形式。然后,提出了粉煤灰的反应性指数(R 值),该指数涉及初始状态、颗粒形态和内部组成的影响。事实证明,R 值在预测使用不同活化剂模块制备的碱活化产品的强度发展方面具有很高的预测准确性(R2 = 0.81-0.93),尤其是在早期阶段。另外还利用了 11 个文献数据集来验证预测的准确性。R 值有助于有效评估粉煤灰是否适合用于制造高强度碱活化复合材料。
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引用次数: 0
Introducing the mineral powder to strengthen polyurethane grouting materials for crack repair of asphalt pavements 采用矿粉强化聚氨酯灌浆材料,用于沥青路面裂缝修补
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139023
Kun Xiong , Jiupeng Zhang , Yinzhang He , Junbo Li , Mingliang Zhang , Rui Li , Jianzhong Pei , Yuanyuan Li , Lei Lyu
Cracking in asphalt pavement may lead to structural distress while existing crack repair materials have significant shortcomings in terms of cost and construction efficiency. This study incorporates mineral powder into the polyurethane grouting materials to provide a more economical and durable solution for repairing cracks in asphalt pavement. The results of bonding and tensile tests show that excessive mineral powder may deteriorate the mechanical properties of polyurethane grouting materials, which is caused by the agglomeration of mineral powder observed by the microscale characterization. Characterization tests indicate that ultraviolet exposure results in the evolution of the chemical components and thermal stability of polyurethane grouting materials, subsequently causing the degeneration in the mechanical properties. The addition of mineral powders was found to increase the tensile strength of polyurethane grouting materials after Ultraviolet aging by 12 %, while the elongation at break measured in tensile tests remained essentially unchanged. The results of the splitting test, bending test, and immersion Marshall test prove the enhanced low-temperature property and moisture resistance of mineral powder-modified polyurethane grouting materials as compared to the styrene-butadiene-styrene emulsified asphalt. The economic analysis shows that this study presents a practical approach to cost-effective asphalt pavement crack repair, offering insights for enhancing the durability of asphalt pavements.
沥青路面出现裂缝可能会导致结构受损,而现有的裂缝修补材料在成本和施工效率方面存在明显缺陷。本研究在聚氨酯灌浆材料中加入矿物质粉末,为修复沥青路面裂缝提供更经济、更耐用的解决方案。粘结和拉伸试验结果表明,过量的矿物粉末可能会降低聚氨酯灌浆材料的机械性能,这是由微观表征观察到的矿物粉末团聚造成的。表征试验表明,紫外线照射会导致聚氨酯灌浆材料的化学成分和热稳定性发生变化,进而导致机械性能下降。研究发现,添加矿物质粉末后,紫外线老化后聚氨酯灌浆材料的拉伸强度提高了 12%,而拉伸试验中测得的断裂伸长率基本保持不变。劈裂试验、弯曲试验和浸水马歇尔试验的结果证明,与苯乙烯-丁二烯-苯乙烯乳化沥青相比,矿粉改性聚氨酯灌浆材料的低温性能和防潮性能都有所提高。经济分析表明,本研究提出了一种经济有效的沥青路面裂缝修复实用方法,为提高沥青路面的耐久性提供了启示。
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引用次数: 0
Enhanced anticorrosion mechanism of photocathodic protection coatings with zinc indium sulfide/titanium oxide Z-scheme heterojunctions 硫化锌铟/氧化钛 Z 型异质结增强光阴极保护涂层的防腐机理
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139109
Zheng Li , Xiaoying Zhang , Zuquan Jin , Haosen Jiang , Xiaoqing Wang , Yuehua Chen , Yue Zhang , Baorong Hou
In order to develop novel anti-corrosion technologies of metals, the photoelectrochemical cathodic protection (PECCP) coating with zinc indium sulfide/titanium oxide (Zn2In2S5/TiO2) was successfully fabricated and its enhanced anticorrosion mechanism was explored in marine environment under light and dark condition, respectively. It found that the improvement of anticorrosion performance is due to the introduction of Zn2In2S5/TiO2 with Z-scheme heterojunctions, which has been verified systematically through theoretical calculations and electrochemical experiments. Under illumination, the photoelectrons generated by Zn2In2S5/TiO2 Z-scheme heterojunctions were accumulated on the conduction band (CB) of Zn2In2S5 at an internal electric field (IEF) pointing from Zn2In2S5 to TiO2, which endowed Zn2In2S5/TiO2 with strong oxidation-reduction ability to provide PECCP for Q235CS and 304SS in 3.5 wt% NaCl. In the dark state, Zn2In2S5/TiO2 Z-scheme heterojunctions served as nanofills to enhance the maze effect, ensuring the remarkable anticorrosion performance of PECCP coating. Furthermore, the protective effect of Zn2In2S5/TiO2 coating was quantified as 74.23 % and 98.91 % for 304SS and Q235CS in 3.5 wt% NaCl for 30 days, respectively.
为开发新型金属防腐技术,成功制备了硫化锌铟/氧化钛(Zn2In2S5/TiO2)光电化学阴极保护(PECCP)涂层,并分别在海洋环境的明暗条件下探索了其增强防腐性能的机理。研究发现,防腐性能的提高得益于 Zn2In2S5/TiO2 中引入了 Z 型异质结,这一点通过理论计算和电化学实验得到了系统的验证。在光照下,Zn2In2S5/TiO2 Z 型异质结产生的光电子在 Zn2In2S5 的导带(CB)上积累,内电场(IEF)从 Zn2In2S5 指向 TiO2,这使得 Zn2In2S5/TiO2 具有很强的氧化还原能力,可在 3.5 wt% NaCl 中为 Q235CS 和 304SS 提供 PECCP。在暗态下,Zn2In2S5/TiO2 Z 型异质结作为纳米填料增强了迷宫效应,确保了 PECCP 涂层的显著防腐性能。此外,Zn2In2S5/TiO2 涂层对 304SS 和 Q235CS 在 3.5 wt% NaCl 中 30 天的保护效果分别达到 74.23% 和 98.91%。
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引用次数: 0
Using graphene oxide to enhance the bonding properties between carbon fibers and cement matrix to improve the mechanical properties of cement-based composites 利用氧化石墨烯增强碳纤维与水泥基体之间的粘合性能,从而改善水泥基复合材料的机械性能
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.138992
Wanfu Qiao , Mingxin Shi , Tianyi Ban , Bo Hou , Wenjiao Zhang , Xiangqing Kong
The mechanical properties of carbon fiber (CF) reinforced cement-based materials are significantly influenced by the interface performance between CF and cement matrix. Improving this interfacial bond can be achieved through the electrophoretic deposition (EPD) method, using graphene oxide (GO). The efficiency and quality of GO deposition on the CF surface are directly related to the EPD parameters. Therefore, in this study, GO electrophoretic deposition CF (GO/CF) was prepared by controlling two key EPD parameters: voltage (10 V, 15 V, 20 V) and time (20 min, 40 min, 60 min). Furthermore, the reinforcing effects of the GO/CF obtained through EPD treatment was compared to those of 3-aminopropyltriethoxysilane modified CF (APS/CF) prepared by common surface treatment method (silanization). The results of single fiber pullout test indicated that GO/CF-15/60 (treated at 15 V for 60 min) had the best bonding performance with cement matrix among the silanized and various EPD-treated samples. Compared to untreated CF, the bond strength of GO/CF-15/60 to the matrix increased by 262 %, and it was also 88.5 % higher than that of APS/CF. This is because GO with wrinkled structure and oxygen-containing functional groups form the optimal deposition morphology and quantity on the CF surface under this EPD parameter. This promotes the adhesion of more hydration products to the CF surface, leading to increased densification with the surrounding matrix. In terms of mechanical properties, when the fiber content was 0.5 vol%, the flexural and compressive strengths of GO/CF-15/60 reinforced cement paste increased by 25.53 % and 5.25 % at 28 d, respectively. The improved interfacial properties facilitate better load transfer between the fiber and matrix, effectively inhibiting the propagation of surrounding microcracks and resulting in superior mechanical strength. A comparison of the bond strength of each modified fiber with the mechanical strength of the corresponding cement paste revealed a strong positive correlation. Therefore, by controlling EPD parameters, the optimal interfacial properties of CF/matrix can be achieved, significantly enhancing the mechanical properties of cement-based materials.
碳纤维(CF)增强水泥基材料的机械性能在很大程度上受到碳纤维与水泥基体之间界面性能的影响。使用氧化石墨烯(GO)的电泳沉积(EPD)方法可以改善这种界面结合。GO 在 CF 表面沉积的效率和质量与 EPD 参数直接相关。因此,本研究通过控制两个关键的 EPD 参数:电压(10 V、15 V、20 V)和时间(20 分钟、40 分钟、60 分钟),制备了 GO 电泳沉积 CF(GO/CF)。此外,还比较了经 EPD 处理的 GO/CF 与采用普通表面处理方法(硅烷化)制备的 3- 氨基丙基三乙氧基硅烷改性 CF(APS/CF)的增强效果。单纤维拉拔试验结果表明,在硅烷化和各种 EPD 处理样品中,GO/CF-15/60(在 15 V 条件下处理 60 分钟)与水泥基体的粘结性能最好。与未经处理的 CF 相比,GO/CF-15/60 与基体的粘结强度提高了 262%,而且比 APS/CF 高出 88.5%。这是因为在该 EPD 参数下,具有皱褶结构和含氧官能团的 GO 在 CF 表面形成了最佳的沉积形态和数量。这促进了更多的水合产物附着在 CF 表面,从而增加了与周围基质的致密性。在力学性能方面,当纤维含量为 0.5 Vol% 时,GO/CF-15/60 增强水泥浆在 28 d 时的抗折强度和抗压强度分别提高了 25.53% 和 5.25%。界面性能的改善促进了纤维与基体之间更好的载荷传递,有效抑制了周围微裂缝的扩展,从而获得更高的机械强度。将每种改性纤维的粘结强度与相应水泥浆的机械强度进行比较后发现,两者之间存在很强的正相关性。因此,通过控制 EPD 参数,可以实现 CF/基体的最佳界面性能,从而显著提高水泥基材料的机械性能。
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引用次数: 0
Improved mechanical and microscopic properties of ultra-high-performance concrete with the addition of hybrid alkali-resistant glass fibers 添加混合耐碱玻璃纤维,改善超高性能混凝土的机械和微观性能
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139002
Pengqiang Zheng , Yue Li , Zhongjing Hu , Ziyang Feng , Qingbiao Wang , Weizhen Liu , Tangsha Shao , Hao Lv
Ultra-high-performance fiber-reinforced concrete (UHPFRC), wherein steel fibers are a primary component, is a new cementitious material with high tensile strength and impact resistance. However, steel fibers are susceptible to corrosion in the alkaline environment of concrete matrices. By contrast, alkali-resistant glass fiber (ARGF) exhibits better corrosion resistance. However, few studies have explored the effects of ARGF on UHPFRC, leaving the optimum ARGF content and its enhancement mechanism unclear. Therefore, this study proposes a UHPFRC design that utilizes AR-GF in place of steel fibers. The effects of different types, lengths, and admixtures of AR-GF are investigated using mechanical tests, scanning electron microscopy (SEM), and X-ray diffraction (XRD). The results show that the splitting tensile strength and flexural strength of the UHPFRC increase with fiber length and fiber dosage. The optimum fiber mixing ratio is 30 kg/m3 of 12 mm-long Anti-Crak® 62.4 combined with 0.05 kg/m3 of 6 mm long Anti-Crak® HD, leading to a 23.3 % increase in splitting tensile strength and 15.8 % increase in flexural strength compared to those of undoped concrete. By analyzing the ARGF dispersion pattern at the fracture surface of the flexural test, the ARGF dispersion analysis method was proposed. SEM shows that the ARGF is coated with C-S-H, which increases its adhesion to the concrete matrix. XRD confirms that ARGF does not affect the hydration reaction of the cement in the UHPFRC. Finally, a model of ARGF-reinforced UHPFRC is established to elucidate the reinforcing mechanism. This study provides guidance and a reference for the application of UHPFRC in engineering projects.
以钢纤维为主要成分的超高性能纤维增强混凝土(UHPFRC)是一种新型水泥基材料,具有很高的抗拉强度和抗冲击性。然而,钢纤维在混凝土基质的碱性环境中容易受到腐蚀。相比之下,耐碱玻璃纤维(ARGF)具有更好的耐腐蚀性。然而,很少有研究探讨 ARGF 对超高强度混凝土的影响,因此 ARGF 的最佳含量及其增强机制尚不明确。因此,本研究提出了一种利用 ARGF 替代钢纤维的超高压泡沫塑料复合材料设计。研究采用力学测试、扫描电子显微镜(SEM)和 X 射线衍射(XRD)对 AR-GF 的不同类型、长度和掺量的影响进行了研究。结果表明,UHPFRC 的劈裂拉伸强度和弯曲强度随纤维长度和纤维用量的增加而增加。最佳纤维混合比为 30 kg/m3 12 mm 长的 Anti-Crak® 62.4 和 0.05 kg/m3 6 mm 长的 Anti-Crak® HD,与未掺杂的混凝土相比,劈裂抗拉强度提高了 23.3%,抗折强度提高了 15.8%。通过分析抗折试验断裂面的 ARGF 分散模式,提出了 ARGF 分散分析方法。扫描电子显微镜显示 ARGF 涂覆了 C-S-H,这增加了其与混凝土基体的粘附性。XRD 证实 ARGF 不会影响 UHPFRC 中水泥的水化反应。最后,建立了 ARGF 加固 UHPFRC 的模型,阐明了其加固机理。该研究为超高分子量纤维增强混凝土在工程项目中的应用提供了指导和参考。
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Construction and Building Materials
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