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Optimal intensity measures and probabilistic fragility assessment for the long-span aqueduct structure with four-column bents 带四柱墩的大跨度渡槽结构的最佳强度措施和概率脆性评估
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.conbuildmat.2024.139100
Min Du , Xiaohong Yang , Sherong Zhang , Chao Wang , Ran Guo , Ji Yao , Ze Li
The intensity measure (IM) is a key factor in determining the accuracy of seismic performance assessment, which can represent the power of ground motion. However, the optimal IMs selection for long-span aqueduct structures with four-column bents has not been investigated in the previous study. This study aims to evaluate the optimal IMs for use in probabilistic seismic demand model (PSDM) and propose the scalar- and vector-valued fragility methods of the long-span aqueduct structure. To achieve this goal, taking the long-span aqueduct structure with four-column bents in the Central Yunnan Water Diversion Project in Southwest China as a typical case, a series of nonlinear dynamic time history analysis are conducted. Then, the 21 commonly-used IMs are tested and evaluated based on the different metrics (e.g. correlation, efficiency, practicality and proficiency). The optimal vector-valued IMs for the fragility analysis of the long-span aqueduct structure with four-column bents is proposed. Meanwhile, the PSDMs of optimal vector-valued IMs are also established and compared. Finally, the scalar- and vector-valued fragility functions are developed in terms of the optimal IMs. A method for seismic fragility analysis of the long-span aqueduct structure with four-column bents based on vector-valued IMs is proposed. The numerical results reveal that peak ground acceleration (PGA), peak pseudo acceleration spectrum (PSA), root-mean-square of acceleration (Arms) and characteristic intensity (Ic) are relatively appropriate IMs for seismic performance evaluation of the long-span aqueduct structure with four-column bents. In particular, PGA is considered to be the optimal IM due to its highest correlation, better efficiency, practicality and proficiency. The scalar-valued fragility curves can only describe the impact of the single IM on the damage probability of the aqueduct structure, which may overestimate or underestimate its damage probability. Furthermore, the vector-valued IMs can significantly increase the fitting ability of the PSDMs. The fragility surfaces are superior to scalar-valued fragility curve due to the vector-valued IMs can more accurately describe the ground motion information. In summary, the findings of this study highlight the significance of proposing the optimal IMs and developing vector-valued fragility surfaces when evaluating the seismic performance of the long-span aqueduct structure with four-column bents.
烈度(IM)是决定抗震性能评估准确性的关键因素,它可以代表地面运动的威力。然而,以往的研究并未对具有四柱桁架的大跨度渡槽结构的最佳烈度量值选择进行研究。本研究旨在评估用于概率地震需求模型(PSDM)的最优 IMs,并提出大跨度渡槽结构的标量和矢量脆性方法。为实现这一目标,以西南地区滇中引水工程四柱墩大跨度渡槽结构为典型案例,进行了一系列非线性动力时间历程分析。然后,根据不同的指标(如相关性、效率、实用性和熟练程度)对 21 种常用的 IM 进行了测试和评估。提出了用于带四柱墩的大跨度水渠结构脆性分析的最优矢量值 IMs。同时,还建立并比较了最优矢量值 IM 的 PSDM。最后,根据最优 IM 建立了标量值和矢量值脆性函数。提出了一种基于矢量值 IM 的四柱弧顶大跨度渡槽结构地震脆性分析方法。数值结果表明,峰值地面加速度(PGA)、峰值假加速度谱(PSA)、加速度均方根(Arms)和特征烈度(Ic)是四柱墩大跨度渡槽结构地震性能评估中相对合适的 IM。其中,PGA 因其最高的相关性、更好的效率、实用性和熟练性而被认为是最佳 IM。标量值脆性曲线只能描述单一 IM 对渡槽结构破坏概率的影响,可能会高估或低估其破坏概率。此外,矢量值 IM 可显著提高 PSDM 的拟合能力。脆性曲面优于标量值脆性曲线,这是因为矢量值 IM 能更准确地描述地面运动信息。总之,本研究的结果强调了提出最佳 IMs 和开发矢量值脆性曲面对于评估四柱墩大跨度输水管道结构抗震性能的重要意义。
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引用次数: 0
Aging behavior of polyether polyurethane binder: Thermal-oxidative, photo-oxidative, hydrolytic aging, and microscale 聚醚聚氨酯粘合剂的老化行为:热氧化、光氧化、水解老化和微观老化
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.conbuildmat.2024.139077
Qian Zhang , Xiaoya Hu , Hui Ma , Wei Li , Xiuqin Jin
Polyurethane pavements exhibit excellent toughness and weather resistance; however, as a polymer binder, polyurethane (PU) is prone to aging under the influence of natural factors such as heat, oxygen, light, and water. To investigate the microscale aging behaviors during thermal-oxidative, photo-oxidative, and hydrolytic aging, two types of one-component polyether polyurethanes were selected. Based on infrared spectroscopy test, atomic force microscope test, tensile performance test, and dynamic mechanical analysis test, the changes in micro-composition and micro-structure were comprehensively analyzed, and these changes were correlated with the macroscopic mechanical properties. The results indicate that no new functional groups were formed in the two types of PU during the aging processes, although molecular chain breakage occurred. Among them, the effect of thermal-oxidative aging on CO was obvious, while hydrolytic aging had a significant influence on C-H bond. After aging, the degree of hydrogen bonding increased, and microphase separation became more pronounced, variations of separation degree depending on the type of aging. Point aggregation of hard segments presented after the thermal-oxidative aging, while large area block or strip aggregation of hard segments was discovered after photo-oxidative aging. However, hard segments displayed fine-strip-aggregation and uniform dispersion in soft segments after the hydrolytic aging. A multidimensional radar chart composed of seven micro-factors revealed that chemical crosslinking dominated the polyurethane crosslinking, while physical crosslinking through hydrogen bonding between hard and soft segments was significantly enhanced. However, the strength of chemical crosslinking varied due to the residual isocyanate content in the original two types of PU. Correspondence analysis showed that the decline in tensile performance and the changes in DMA performance exhibited a high degree of consistency with microscale aging behaviors, indicating that the seven microscale factors can serve as systematic assessment indicators for formulating PU materials with enhanced anti-aging performance for pavement applications.
聚氨酯路面具有出色的韧性和耐候性,但作为一种聚合物粘结剂,聚氨酯(PU)在热、氧、光和水等自然因素的影响下容易老化。为了研究热氧化、光氧化和水解老化过程中的微观老化行为,我们选择了两种单组分聚醚聚氨酯。基于红外光谱测试、原子力显微镜测试、拉伸性能测试和动态力学分析测试,全面分析了微观组成和微观结构的变化,并将这些变化与宏观力学性能相关联。结果表明,两种聚氨酯在老化过程中虽然发生了分子链断裂,但没有形成新的官能团。其中,热氧化老化对 CO 的影响明显,而水解老化对 C-H 键的影响较大。老化后,氢键程度增加,微相分离更加明显,分离程度的变化取决于老化类型。热氧化老化后出现了硬段的点状聚集,而光氧化老化后则发现了硬段的大面积块状或条状聚集。然而,在水解老化后,硬段在软段中呈现出细条状聚集和均匀分散。由七个微观因素组成的多维雷达图显示,聚氨酯交联以化学交联为主,而通过硬段和软段之间氢键的物理交联则明显增强。不过,化学交联的强度因原有两种聚氨酯中残留的异氰酸酯含量而异。对应分析表明,拉伸性能的下降和 DMA 性能的变化与微观老化行为具有高度的一致性,这表明这七个微观因素可作为系统评估指标,用于配制具有更强抗老化性能的路面用聚氨酯材料。
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引用次数: 0
Microstructural properties of alkali-activated mortars prepared from Fenton oxidation and heat-treated dyeing sludge as the substitutions of slag 用芬顿氧化法和热处理染色污泥替代炉渣制备的碱活性砂浆的微观结构特性
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.conbuildmat.2024.139196
Dongyang Tian , Xiaocong Yang , Yongsheng Kang , Dongshuai Hou , Xinyu Cong , Shuang Lu
This study investigates three treatment methods for removing organic residues and enhancing dyeing sludge (DS) activity: high-temperature calcination, Fenton oxidation, and mechanical grinding. The treated DS was used as a substitute for ground granulated blast slag (GGBS) in producing alkali-activated mortars. A comprehensive characterization of the chemical composition and microstructure of DS was conducted to evaluate the effectiveness of these treatment methods. Results showed that DS contains phosphorus oxides, which, upon dissolution, react with calcium and alkaline ions to form insoluble calcium phosphate and fluorine hydroxyapatite. Subsequently, the mechanical properties, micromorphology, and microstructure of alkali-activated mortars with varying DS contents were analyzed to assess the potential of treated DS as a precursor. Test results revealed that mechanical/heat-activated DS (HDS) experienced minimal strength reduction at 10 % doping, achieving a compressive strength of 99 % compared to the control group. However, controlling the amount of alkali used was crucial, as an increase in alkali resulted in decreased compressive strength. DS treated through mechanical/chemical activation (CDS) also showed promising results, with CDS-9 achieving a compressive strength of 78.4 % of the control group after 56 days of curing. Notably, although the early strength of specimens with CDS was lower, a more significant increase in strength was observed at later stages. Mechanical activation (MDS) had the most adverse effect on strength, independent of the curing duration. The pore size distribution of alkali-activated mortars can be optimized by refining the macro-pores in samples and transforming them into harmless gel pores through HDS and CDS integration. This study offers a feasible strategy for DS activation and demonstrates the highly promising utilization of DS as a precursor for alkali-activated materials.
本研究探讨了去除有机残留物和提高染色污泥(DS)活性的三种处理方法:高温煅烧、芬顿氧化和机械研磨。经过处理的染色污泥被用来替代磨细高炉矿渣(GGBS),用于生产碱活性砂浆。对 DS 的化学成分和微观结构进行了全面鉴定,以评估这些处理方法的有效性。结果表明,DS 含有磷氧化物,溶解后会与钙离子和碱性离子反应,形成不溶性磷酸钙和氟羟基磷灰石。随后,分析了不同 DS 含量的碱激活砂浆的机械性能、微观形态和微观结构,以评估经处理的 DS 作为前体的潜力。测试结果表明,机械/热激活 DS(HDS)在掺量为 10% 时强度降低最小,与对照组相比,抗压强度达到 99%。不过,控制碱用量至关重要,因为碱用量增加会导致抗压强度降低。通过机械/化学活化(CDS)处理的 DS 也显示出良好的效果,CDS-9 在固化 56 天后的抗压强度达到对照组的 78.4%。值得注意的是,虽然使用 CDS 的试样早期强度较低,但后期强度有了更显著的提高。机械活化(MDS)对强度的影响最大,与固化时间长短无关。通过 HDS 和 CDS 集成,细化样品中的大孔隙并将其转化为无害的凝胶孔隙,可以优化碱活化砂浆的孔径分布。这项研究为 DS 活化提供了一种可行的策略,并证明了将 DS 用作碱活化材料的前体大有可为。
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引用次数: 0
Micro-mechanical performance study of the interfacial transition zone in ultra-high performance concrete containing coarse aggregates based on digital image correlation method 基于数字图像相关法的含粗集料超高性能混凝土界面过渡区微观力学性能研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.conbuildmat.2024.139162
Ziqi Gao , Jintao He , Ruoxi Yang , Feipeng Zhu , Pengxiang Bai , Dong Lei
To measure the mechanical properties of the interfacial transition zone (ITZ) in ultra-high performance concrete with coarse aggregates (UHPC-CA) under direct load, a mesoscopic experimental analysis is performed using a combination of an electron microscope (EM) camera and digital image correlation (DIC) technology in this study. With such a methodology, the stress-strain curve of the ITZ under compression is measured directly. Furthermore, the distribution of the nominal compressive elastic modulus (E*) and Poisson's ratio (v) of the ITZ is obtained. Finally, the effects of granulated blast-furnace slag (GGBS) contents (0 %, 30 %, 40 %, and 50 %) on ITZ’s properties are investigated, and their relevance to microstructure is further explored by scanning electron microscope (SEM). The results indicate that the E * in the ITZ follows a 'U'-shaped distribution. In comparison to the reinforced matrix, a compaction process in ITZ is observed obviously, resulting in a smaller v in this region. Besides, as the GGBS content increases, the mesoscopic mechanical properties of the ITZ gradually decline.
为了测量粗集料超高性能混凝土(UHPC-CA)界面过渡区(ITZ)在直接荷载作用下的力学性能,本研究结合使用了电子显微镜(EM)相机和数字图像相关(DIC)技术,进行了介观实验分析。通过这种方法,可以直接测量 ITZ 在压缩条件下的应力-应变曲线。此外,还获得了 ITZ 的名义压缩弹性模量(E*)和泊松比(v)的分布情况。最后,研究了粒化高炉矿渣(GGBS)含量(0%、30%、40% 和 50%)对 ITZ 性能的影响,并通过扫描电子显微镜(SEM)进一步探讨了它们与微观结构的相关性。结果表明,ITZ 中的 E * 呈 "U "型分布。与增强基体相比,ITZ 中的压实过程明显,导致该区域的 V 值较小。此外,随着 GGBS 含量的增加,ITZ 的中观力学性能逐渐下降。
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引用次数: 0
Accelerated carbonation of lime-treated clayey geomaterials: A synergistic strategy for sustainable earthworks and carbon capture applications 石灰处理粘土质土工材料的加速碳化:可持续土方工程和碳捕获应用的协同战略
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.conbuildmat.2024.139078
Dhanalakshmi Padmaraj , Chinchu Cherian , Dali Naidu Arnepalli
Lime is a popularly adopted binder for improving the mechanical properties and controlling the volume change behavior of problematic clayey soils. However, lime treatment offers certain limitations due to the durability issues arising from varying physico-chemical conditions exacerbated by climatic stresses or clay mineralogy. Lime-treated soils rich in mineral montmorillonite have experienced severe durability issues, with considerable strength decline, eventually falling below the minimum standards required for its application as a construction material. In this study, the innovative approach of “carbon mineralization” is adopted to augment the inadequate mechanical strength in the treated soil rich in mineral montmorillonite through carbonate cementation. Extensive mechanical and microstructure characterization techniques comprising unconfined compressive strength tests, scanning and transmission electron microscopy (SEM and TEM), thermogravimetric analysis (TGA), and mercury intrusion porosimetry (MIP) techniques were performed to identify the mechanism behind strength deterioration in lime-clay composites cured for 24 months in ambient conditions (99 % relative humidity and temperatures of 25 ℃ and 40 ℃). The results show that the unconfined compressive strength of treated soils reduced drastically beyond 9 months of curing. The newly derived parameter, effective precipitation factor from cementation levels, and macroporosity measurements at varying curing periods helped reveal the deterioration mechanism in the lime-clay composites. Accelerated carbonation of these composites resulted in a maximum of 74 % strength increment with a corresponding 15 % decrease in macroporosity. Carbonation enabled the nucleation of voluminous carbonates that fill and bridge the inter-aggregate pores of these composites via contact cementation, as evidenced by the micro-level images. In addition to rehabilitating deteriorated earthwork due to aging, the technique mitigates carbon emissions by capturing 37 % of CO2 released during lime production into stable carbonate minerals, promoting environmental sustainability.
石灰是一种常用的粘结剂,可用于改善粘性土壤的机械性能和控制其体积变化。然而,石灰处理也有一定的局限性,因为不同的物理化学条件会加剧气候应力或粘土矿物学所带来的耐久性问题。富含矿物蒙脱石的石灰处理土壤就经历了严重的耐久性问题,强度大幅下降,最终低于其作为建筑材料应用所需的最低标准。本研究采用了 "碳矿化 "这一创新方法,通过碳酸盐胶结来增强富含矿物蒙脱石的经处理土壤中不足的机械强度。为了确定在环境条件(相对湿度为 99%,温度为 25 ℃ 和 40 ℃)下固化 24 个月的石灰-粘土复合材料强度下降的机理,研究人员采用了广泛的机械和微观结构表征技术,包括无约束抗压强度测试、扫描和透射电子显微镜(SEM 和 TEM)、热重分析(TGA)和汞侵入孔隙模拟(MIP)技术。结果表明,经过处理的土壤在固化 9 个月后,无压抗压强度急剧下降。新推导出的参数、从胶结水平得出的有效沉淀系数以及不同固化期的大孔隙度测量结果有助于揭示石灰-粘土复合材料的劣化机制。这些复合材料加速碳化后,强度最大提高了 74%,大孔率相应降低了 15%。碳化使大量碳酸盐成核,通过接触胶结作用填充并弥合了这些复合材料的集料间孔隙,这一点在微观层面的图像中得到了证明。除了修复因老化而恶化的土方工程外,该技术还能将石灰生产过程中释放的 37% 的二氧化碳转化为稳定的碳酸盐矿物,从而减少碳排放,促进环境的可持续发展。
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引用次数: 0
Quasi-static and impact compression properties of glubam at different relative humidity conditions 不同相对湿度条件下胶蛤的准静态和冲击压缩特性
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.conbuildmat.2024.139172
C.Q. Chen , Q.C. Zhang , C. de Kergariou , F. Scarpa , Y. Xiao
Glued laminated bamboo (glubam), a product of bamboo lamination, presents a distinctive combination of eco-friendliness and mechanical strength. This study delves into the quasi-static and dynamic compression behaviour of glubam, examining the influence of key factors such as moisture content and carbonization. The experiment involved one control group and two groups of different carbonized degrees, with two relative humidity controls set at 65 % and 85 %. The results of the quasi-static compression tests revealed that higher moisture content reduced the ultimate stress and modulus of compression while enhancing the ductility of thick-strip glubam. Cross bamboo alignment bolstered the compressive strengths of longitudinal thin-strip glubam and provided considerable compressive capacity for transverse thin-strip glubam. Poisson’s ratios of glubam were also determined. During drop-tower impact testing, an input energy of 209.5 J resulted in the determination of the dynamic ultimate stress of glubam. The application of reasonable image procedures, supported by high-speed camera collections, aided in the efficient presentation of absorbed energy. Scanning electron microscope (SEM) images were employed to explore experimental results through the microstructure perspective.
胶合层压竹材(Glubam)是竹材层压的一种产品,具有生态友好性和机械强度的独特组合。本研究深入探讨了胶合竹材的准静态和动态压缩行为,考察了水分含量和碳化程度等关键因素的影响。实验包括一组对照组和两组不同碳化程度的对照组,两组相对湿度控制在 65 % 和 85 %。准静态压缩试验的结果表明,较高的含水率降低了粗条胶砂的极限应力和压缩模量,同时增强了其延展性。横向竹节排列增强了纵向薄条胶凝材料的抗压强度,并为横向薄条胶凝材料提供了相当大的抗压能力。此外,还测定了胶凝材料的泊松比。在落塔冲击试验中,输入能量为 209.5 J,从而确定了胶凝材料的动态极限应力。在高速相机采集的支持下,合理图像程序的应用有助于有效呈现吸收的能量。扫描电子显微镜(SEM)图像被用来从微观结构的角度探索实验结果。
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引用次数: 0
Bond stress-slip properties and analytical models between high-strength lightweight aggregate concrete and high-strength steel bars 高强度轻骨料混凝土与高强度钢筋之间的粘结应力-滑移特性及分析模型
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-13 DOI: 10.1016/j.conbuildmat.2024.139110
Hui Wei , Zhengyan Xiao, Tao Wu, Shibo Zhao, Wenshuo Shen
Twenty-eight pull-out specimens in thirteen groups were tested to investigate the bond properties between high-strength lightweight aggregate concrete (HSLC) and HRB600 bars with different bond lengths, steel fiber contents, concrete strength, and cover thickness. The analytical expressions for radial deformation, radial stress, and bond strength based on four deformation assumptions were derived and compared by incorporating the thick-walled cylinder model, bilinear softening constitutive curve, and fracture energy model of HSLC. Eventually, a three-segment bond stress-slip model was proposed. The test results showed that the increase in research parameters apart from bond length could improve the failure mode, bond strength, descending slope of curves, and bond toughness. The bond strength was in the range of 24.99 ∼ 39.79 MPa except for LC70–0S-L80 with splitting failure. The optimal match of mixture LC70–0.6S and HRB600 bars could fully utilize the mechanical properties of both materials, for which the allowable minimum ratio of cover thickness-to-rebar diameter was recommended to be 3.75. The bond toughness of specimens cast with LC70–0S, LC70–0.3S, LC50–0.6S, and LC70–0.6S increased sequentially at the same bond length. The calculation results indicated that the assumptions of constant and elastic deformation provided upper and lower predictions of bond strength, respectively, and the assumption of equivalent elastic deformation slightly overestimated the bond strength due to the nonlinear deformation of cracked concrete. The assumption of equivalent elastic deformation at cohesive stress equaling half of the tensile strength of concrete obtained satisfactory calculated bond strengths, and the predicted bond stress-slip curves agreed well with the experimental curves, describing accurately the cracking characteristics and bond behavior between HSLC and HRB600 bars.
为了研究高强度轻骨料混凝土(HSLC)与不同粘结长度、钢纤维含量、混凝土强度和覆盖层厚度的 HRB600 钢筋之间的粘结性能,测试了 13 组 28 个拉出试件。通过结合 HSLC 的厚壁圆柱体模型、双线性软化构成曲线和断裂能模型,推导并比较了基于四种变形假设的径向变形、径向应力和粘结强度的分析表达式。最终提出了三段粘结应力-滑移模型。试验结果表明,除粘接长度外,其他研究参数的增加可改善破坏模式、粘接强度、曲线下降斜率和粘接韧性。除 LC70-0S-L80 出现劈裂失效外,粘接强度范围为 24.99 ~ 39.79 MPa。LC70-0.6S 与 HRB600 混合杆的最佳匹配可充分发挥两种材料的机械性能,为此,建议允许的最小覆盖层厚度与杆直径之比为 3.75。使用 LC70-0S、LC70-0.3S、LC50-0.6S 和 LC70-0.6S 浇铸的试样在相同粘结长度下的粘结韧性依次增加。计算结果表明,恒定变形假设和弹性变形假设分别提供了较高和较低的粘结强度预测值,而等效弹性变形假设由于裂缝混凝土的非线性变形而略微高估了粘结强度。假设内聚应力等于混凝土抗拉强度一半时的等效弹性变形可获得令人满意的计算粘结强度,且预测的粘结应力-滑移曲线与实验曲线吻合良好,准确地描述了 HSLC 和 HRB600 钢筋之间的开裂特征和粘结行为。
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引用次数: 0
Intrusion kinetics and interfacial degradation mechanism of PU-steel system in chloride ion environment: A multiscale study 氯离子环境下聚氨酯-钢系统的侵入动力学和界面降解机理:多尺度研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-13 DOI: 10.1016/j.conbuildmat.2024.139151
Yuxuan Wu , Wenyuan Xu , Endian Fan
This study utilised density functional theory (DFT) to predict the movement pathways and rates of chloride ions within polyurethane (PU), as well as their molecular dynamics and charge distribution during the erosion process. Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and electrochemical tests revealed chemical and electrochemical changes at the PU/steel interface after immersion in sodium chloride solution. Shear strength and nanoindentation tests were used to examine the impact of microscale erosion on macroscale mechanical properties. The results showed that chloride-ion penetration into PU requires overcoming a substantial energy barrier driven by the concentration gradient between the saline solution and PU. After immersion in sodium chloride solution, the −NCO functional groups in PU were disrupted, reducing chemical stability and molecular elasticity. This process accelerates the hydrolysis of ester bonds, leading to a decline in interfacial mechanical properties. Electrochemical results showed that the resistance of the PU coating decreased over time, indicating a transition in the electrochemical reactions that eventually led to interfacial corrosion. After prolonged immersion, both the interfacial shear strength and modulus significantly decreased, whereas the shear ductility initially increased but later decreased.
本研究利用密度泛函理论(DFT)预测了氯离子在聚氨酯(PU)中的移动路径和速率,以及在侵蚀过程中的分子动力学和电荷分布。傅立叶变换红外光谱(FTIR)、X 射线光电子能谱(XPS)和电化学测试揭示了氯化钠溶液浸泡后聚氨酯/钢界面的化学和电化学变化。剪切强度和纳米压痕测试用于研究微观侵蚀对宏观机械性能的影响。结果表明,氯离子渗透到聚氨酯中需要克服盐溶液和聚氨酯之间的浓度梯度所产生的巨大能量障碍。在氯化钠溶液中浸泡后,聚氨酯中的 -NCO 官能团被破坏,从而降低了化学稳定性和分子弹性。这一过程加速了酯键的水解,导致界面机械性能下降。电化学结果显示,聚氨酯涂层的电阻随着时间的推移而降低,这表明电化学反应发生了转变,最终导致了界面腐蚀。经过长时间浸泡后,界面剪切强度和模量都明显下降,而剪切延展性最初有所上升,但后来又有所下降。
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引用次数: 0
Optimization of ventilation and dust removal parameters in plateau extra-long tunnel inclined shaft based on orthogonal numerical simulation test method 基于正交数值模拟试验方法的高原特长隧道斜井通风除尘参数优化研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-13 DOI: 10.1016/j.conbuildmat.2024.139131
Xiangdong Yang , Zhongan Jiang , Jihe Chen , Ya Chen , Bin Yang
Ventilation and dust removal system in the inclined shaft of the plateau long tunnel is an important component for ensuring safe excavation. The arrangement of wind tube and the volume of air flow have a significant impact on the movement of dust. In order to address the issues of poor ventilation and severe dust pollution in the inclined shaft of plateau long tunnels, this study establishes a dust generation and transportation model for the face of the inclined shaft based on the determination of dust source parameters and their physicochemical characteristics during the excavation process. The results indicate that the particles are predominantly spherical with an approximate diameter of 4 μm at a magnification of 500 times. The dust in high-altitude inclined shafts exhibits poor wettability, with a hydrophobic tendency during the excavation phase, making a ventilation dust removal scheme appropriate. After determining the physical parameters corresponding to the elevation of the inclined shaft, a series of orthogonal numerical simulations involving 3 factors at 5 levels were conducted. Analysis of range and variance revealed that optimal dust control is achieved when the air duct height is 5.725 m, the distance from the working face is 21 m, and the exit wind speed is 29.71 m/s. Comparative analysis confirmed the rationality of the ventilation dust removal scheme under the optimal combination of ventilation parameters. This provides guidance for engineering and environmental management in similar construction scenarios.
高原长隧道斜井的通风除尘系统是确保安全挖掘的重要组成部分。风筒的布置和风量的大小对粉尘的流动有很大的影响。针对高原长隧道斜井通风不畅、粉尘污染严重的问题,本研究在确定开挖过程中粉尘源参数及其理化特性的基础上,建立了斜井工作面粉尘产生与输送模型。结果表明,在放大 500 倍的情况下,颗粒主要呈球形,直径约为 4 μm。高空斜井中的粉尘润湿性较差,在挖掘阶段有疏水倾向,因此适合采用通风除尘方案。在确定与斜井海拔高度相对应的物理参数后,进行了一系列正交数值模拟,涉及 5 个级别的 3 个因子。范围和方差分析显示,当风筒高度为 5.725 米、距工作面距离为 21 米、出口风速为 29.71 米/秒时,可实现最佳的粉尘控制。对比分析证实了通风参数最优组合下通风除尘方案的合理性。这为类似施工情况下的工程和环境管理提供了指导。
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Application of porous luffa fiber as a natural internal curing material in high-strength mortar 多孔丝瓜纤维作为天然内固化材料在高强度砂浆中的应用
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-13 DOI: 10.1016/j.conbuildmat.2024.139169
Yi Han , Mingxin Shi , Sihwan Lee , Runsheng Lin , Kang-Jia Wang , Xiao-Yong Wang
This study explores the potential of renewable plant fibers as internal curing (IC) materials, analyzing their potential in high-strength mortar (HSM) applications. Experiments involving the incorporation of different volumetric ratios of luffa fiber into concrete assessed impacts on autogenous shrinkage (AS), mechanical properties, and microstructure. The research found that the addition of luffa fibers extended both the setting times of the mixture, and after final setting, continued the hydration reaction by releasing internally stored water. Compared to the control group, luffa fibers significantly reduced AS by up to 56.87 %, primarily due to their high-water absorption capacity (211 %), which mitigates the internal capillary pressures during the cement hydration process. Moreover, the inclusion of luffa fibers significantly affected the concrete's mechanical properties: a 1 % luffa addition enhanced the compressive strength at 28 days by 7.6 % over the control; concrete with 2 % luffa fiber exhibited the highest flexural strength at 28 days, showing a 9.4 % increase over the control. Microstructural analysis revealed that luffa fiber not only promoted continued hydration but also increased the content of hydration products and enhanced the compactness of the cementitious matrix. Overall, luffa fibers effectively reduce HSM’s AS and enhance its mechanical properties and microstructure, showing potential to improve concrete performance.
本研究探讨了可再生植物纤维作为内部固化(IC)材料的潜力,分析了其在高强度砂浆(HSM)应用中的潜力。在混凝土中加入不同体积比的丝瓜纤维的实验评估了其对自生收缩(AS)、机械性能和微观结构的影响。研究发现,添加丝瓜纤维可延长混合物的凝结时间,并在最终凝结后通过释放内部储存的水分继续水化反应。与对照组相比,丝瓜纤维显著降低了 AS,降幅高达 56.87%,这主要是由于丝瓜纤维的高吸水能力(211%)可减轻水泥水化过程中的内部毛细管压力。此外,加入丝瓜纤维对混凝土的机械性能也有显著影响:加入 1% 丝瓜纤维的混凝土在 28 天时的抗压强度比对照组提高了 7.6%;加入 2% 丝瓜纤维的混凝土在 28 天时的抗折强度最高,比对照组提高了 9.4%。微观结构分析表明,丝瓜纤维不仅能促进持续水化,还能增加水化产物的含量,提高水泥基质的密实度。总之,丝瓜纤维能有效降低 HSM 的 AS,提高其力学性能和微观结构,显示出改善混凝土性能的潜力。
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Construction and Building Materials
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