Coordination Chemistry Reviews最新文献_第7页

MOFs and their derivatives: Functionalization strategy and applications as sensitive electrode materials for environmental EDCs analysis

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-12 DOI: 10.1016/j.ccr.2025.216504

Md Maruf Ahmed , Ying Zhuo Shen , Zheng Wang , Jing Li , Jianping Du , Seitkhan Azat , Qin Xu

Endocrine-disrupting chemicals (EDCs) are a category of exogenous organic pollutants that pose substantial hazards to human health and the environment due to their ability to disrupt the functioning of the endocrine system. However, implementing suitable technology is one of the most effective ways to address EDCs. Electrochemical sensors provide cost-effective and fast solutions to this challenge, using metal-organic framework (MOF) technology. MOFs, as a distinct hierarchical structural class, offer diverse topologies, tunability, reactivity and porosity, but their lower conductivity and instability limit their effectiveness in electrochemical sensor applications. The study focuses on investigating the functionalization strategy of the outer and inner surfaces of MOF crystals, which involves introducing functional groups, replacing components, incorporating guest molecules, defect engineering and hybrid composite construction. We explore the latest advancement in electrochemical sensors based on MOFs, emphasizing their use in the recognition of environmental EDCs. The oxidation mechanisms of EDCs on the electrode surface were also discussed. In this review, we provide clear and straightforward guidance for the structural design of MOFs as well as the improvement of durable, efficient and resilient portable electrochemical sensors for environmental EDCs detection. Furthermore, this work addresses current challenges and highlights the future prospects of MOFs as sensor materials for environmental EDCs analysis.

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引用次数: 0

Advanced strategies for enhancing electrochemical performance of NiAl LDH electrodes in supercapacitors

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-10 DOI: 10.1016/j.ccr.2025.216497

Yong Zhang , Shuo Hu , Cui-e Li , Xin-hua Yan , Yuan-yuan Zhang , Rong-bi Yin , Yu-fei Wei , Ke-zheng Gao , Hai-li Gao

This paper focuses on the field of supercapacitors, which have attracted significant attention in recent years due to their high power density, excellent cycling stability, and fast charge-discharge capabilities. The paper systematically reviews diverse preparation strategies of NiAl layered double hydroxides (NiAl LDH) as electrode materials, including hydrothermal, solvothermal, electrodeposition, homogeneous precipitation, liquid-phase deposition, and templating methods. It elaborates on the characteristics, advantages, and suitability of these methods for various application scenarios. Furthermore, the paper explores various modification techniques for NiAl LDH electrode materials, such as doping with single-element, binary-element, and multi-element additives, as well as composite modifications involving carbon materials, metal-organic frameworks (MOFs), MXenes, and metal oxides. These strategies aim to effectively enhance the electrochemical performance of electrode materials. Additionally, advanced techniques for structural control of NiAl LDH, such as core-shell structures, nanoarrays, flower-like structures, and other complex morphologies, are detailed to optimize charge transfer and storage efficiency through structural innovation. The paper further tracks the research progress of various supercapacitors constructed using the aforementioned preparation and modification strategies of NiAl LDH electrodes, emphasizing their outstanding cyclic performance and increasing importance in energy storage applications. Through comprehensive examination and analysis of existing technologies, this study reveals trends in developing supercapacitor materials with higher electrochemical performance, providing theoretical foundations and practical guidance for future design and optimization of such advanced energy storage devices.

{"title":"Advanced strategies for enhancing electrochemical performance of NiAl LDH electrodes in supercapacitors","authors":"Yong Zhang , Shuo Hu , Cui-e Li , Xin-hua Yan , Yuan-yuan Zhang , Rong-bi Yin , Yu-fei Wei , Ke-zheng Gao , Hai-li Gao","doi":"10.1016/j.ccr.2025.216497","DOIUrl":"10.1016/j.ccr.2025.216497","url":null,"abstract":"<div><div>This paper focuses on the field of supercapacitors, which have attracted significant attention in recent years due to their high power density, excellent cycling stability, and fast charge-discharge capabilities. The paper systematically reviews diverse preparation strategies of NiAl layered double hydroxides (NiAl LDH) as electrode materials, including hydrothermal, solvothermal, electrodeposition, homogeneous precipitation, liquid-phase deposition, and templating methods. It elaborates on the characteristics, advantages, and suitability of these methods for various application scenarios. Furthermore, the paper explores various modification techniques for NiAl LDH electrode materials, such as doping with single-element, binary-element, and multi-element additives, as well as composite modifications involving carbon materials, metal-organic frameworks (MOFs), MXenes, and metal oxides. These strategies aim to effectively enhance the electrochemical performance of electrode materials. Additionally, advanced techniques for structural control of NiAl LDH, such as core-shell structures, nanoarrays, flower-like structures, and other complex morphologies, are detailed to optimize charge transfer and storage efficiency through structural innovation. The paper further tracks the research progress of various supercapacitors constructed using the aforementioned preparation and modification strategies of NiAl LDH electrodes, emphasizing their outstanding cyclic performance and increasing importance in energy storage applications. Through comprehensive examination and analysis of existing technologies, this study reveals trends in developing supercapacitor materials with higher electrochemical performance, providing theoretical foundations and practical guidance for future design and optimization of such advanced energy storage devices.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"531 ","pages":"Article 216497"},"PeriodicalIF":20.3,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143375337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An equal terms comparison of the proficiency of artificial phosphodiesterases by using simple models of RNA or DNA as benchmarks–the takeaway to design next generation supramolecular catalysts

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-10 DOI: 10.1016/j.ccr.2025.216479

Alessandro Casnati , Riccardo Salvio

This comprehensive review aims at identifying the structural features and general rules governing the design of enzyme mimics and supramolecular catalysts having the ability to hydrolytically cleave the phosphodiester bonds. Rate and binding constants of the artificial phosphodiesterases so far proposed and tested by using the model compounds, bis (p-nitrophenyl) phosphate (BNPP) and 2-hydroxypropyl p-nitrophenyl phosphate (HPNP) as widely recognized model substrates have been collected, elaborated and compared. These substrates have been extensively used over time to evaluate the performance of artificial phosphodiesterases, providing consistent and unique bases for comparing different catalysts. Notably, no other substrates have been tested as extensively and over such a prolonged period. A wide variety of supramolecular phosphodiesterases have been considered, comprising metal-free- and metallocatalysts, acyclic, macrocyclic or even nanostructured ones. The scope and limits of the use of Effective Molarity to evaluate the enhanced reactivity of some of these supramolecular catalysts are also discussed. The information collected allows to give the reader a take-home message for the design of next generation artificial phosphodiesterases.

本综述旨在确定具有水解裂解磷酸二酯键能力的酶模拟物和超分子催化剂的结构特征和一般设计规则。本文收集、阐述和比较了迄今为止提出的人工磷酸二酯酶的速率常数和结合常数，并使用模型化合物磷酸双（对硝基苯基）酯（BNPP）和 2-羟基丙基对硝基苯基磷酸酯（HPNP）作为公认的模型底物进行了测试。长期以来，这些底物被广泛用于评估人工磷酸二酯酶的性能，为比较不同催化剂提供了一致而独特的依据。值得注意的是，没有其他底物经过如此广泛和长期的测试。研究人员考虑了多种超分子磷酸二酯酶，包括无金属催化剂和金属催化剂、无环催化剂、大环催化剂甚至纳米结构催化剂。此外，还讨论了使用有效摩尔度来评估其中一些超分子催化剂反应活性增强的范围和局限性。收集到的信息为读者设计下一代人工磷酸二酯酶提供了启示。

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引用次数: 0

Metal-organic frameworks-based materials: A feasible path for redox flow battery

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-10 DOI: 10.1016/j.ccr.2025.216503

Tianxing Yuan, Shaotian Qi, Lingzhi Ye, Yanqin Zhao, Yingqiao Jiang, Zemin Feng, Jing Zhu, Lei Dai, Ling Wang, Zhangxing He

Among many energy storage devices, redox flow battery technology has become a cutting-edge technology to solve energy storage problems due to its advantages of large capacity, high safety and long life. However, the promotion of this technology is plagued by many problems such as poor ion selectivity of membrane and weak electrocatalytic activity of electrode. Metal-organic framework (MOF) is a reliable choice for redox flow battery membrane and electrode modification materials due to its three-dimensional porous structure, suitable specific surface area, excellent chemical stability and adjustable chemical composition. This paper comprehensively summarizes the latest research progress of MOF-related materials in redox flow battery. Firstly, the characteristics of MOF-based materials and the feasibility of applying them to redox flow battery are described. Furthermore, the pristine and functionalized MOF materials for membrane modification, as well as MOF-derived metal oxides and carbon materials for electrode modification are introduced. Finally, the challenges and hopes faced by the application of MOF-based materials in the field of redox flow battery in the future are summarized, aiming to provide help for related work and cause more research work on MOF-based materials in redox flow battery.

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引用次数: 0

Material design and mechanism interpretation of metal oxide nanofibers for improving gas sensitivity

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-10 DOI: 10.1016/j.ccr.2025.216492

Chunlan Wang , Yongle Song , Ming Zhao , Hongbing Lu , Jingli Wang , Xuming Zou

High performance and multifunctional gas sensors develop from various morphology of metal oxide nanomaterials are essential for industrial, medical and fire protection fields. It is worth noting that metal oxide nanofibers (MO_x NFs) have high specific surface area, excellent porosity and porous structure, which can effectively overcome the shortcomings of poor sensing performance, long response time and weak stability of traditional materials, that play a crucial role in gas sensing. Herein, the material design strategies of MO_x NFs for improving gas sensitivity are overviewed, including metal/non-metal doped/modified MO_x NFs, MO_x based heterojunction NFs, 2D materials/MO_x heterojunction NFs, metal doped/modified MO_x based heterojunction NFs, and special morphology (aligned, Janus, core-shell) of MO_x NFs. In addition, in each type of material design system, the paper explains the relevant gas-sensitive enhancement mechanism, and hopes to deepen the understanding of the relationship between material design, gas-sensitive mechanism and gas-sensitive performance by combining the abundant relevant gas-sensitive reports. Finally, the conclusions and prospects for the design of MO_x NFs gas-sensitive materials and the innovation of gas-sensitive sensors are presented.

{"title":"Material design and mechanism interpretation of metal oxide nanofibers for improving gas sensitivity","authors":"Chunlan Wang , Yongle Song , Ming Zhao , Hongbing Lu , Jingli Wang , Xuming Zou","doi":"10.1016/j.ccr.2025.216492","DOIUrl":"10.1016/j.ccr.2025.216492","url":null,"abstract":"<div><div>High performance and multifunctional gas sensors develop from various morphology of metal oxide nanomaterials are essential for industrial, medical and fire protection fields. It is worth noting that metal oxide nanofibers (MO<sub>x</sub> NFs) have high specific surface area, excellent porosity and porous structure, which can effectively overcome the shortcomings of poor sensing performance, long response time and weak stability of traditional materials, that play a crucial role in gas sensing. Herein, the material design strategies of MO<sub>x</sub> NFs for improving gas sensitivity are overviewed, including metal/non-metal doped/modified MO<sub>x</sub> NFs, MO<sub>x</sub> based heterojunction NFs, 2D materials/MO<sub>x</sub> heterojunction NFs, metal doped/modified MO<sub>x</sub> based heterojunction NFs, and special morphology (aligned, Janus, core-shell) of MO<sub>x</sub> NFs. In addition, in each type of material design system, the paper explains the relevant gas-sensitive enhancement mechanism, and hopes to deepen the understanding of the relationship between material design, gas-sensitive mechanism and gas-sensitive performance by combining the abundant relevant gas-sensitive reports. Finally, the conclusions and prospects for the design of MO<sub>x</sub> NFs gas-sensitive materials and the innovation of gas-sensitive sensors are presented.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"531 ","pages":"Article 216492"},"PeriodicalIF":20.3,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143375339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal-organic frameworks for low-concentration gases adsorption under ambient conditions: Characterization, modification, processing, shaping and applications

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-10 DOI: 10.1016/j.ccr.2025.216464

Hao Wang , Yufan Jiang , Rui Han , Qingling Liu , Caixia Liu , Zhimin Yan

Gaseous pollutants under ambient conditions are characterized by low concentrations and complex composition, which poses a challenge to applying adsorbents in air decontamination. Due to the tunability and adsorptive properties, MOF adsorbents have been widely studied and applied for adsorption and separation. This review introduces some novel characterizations and simulations for ambient gas adsorption. Then, the modification methods of MOF adsorbents for low-concentration gas adsorption were systematically summarised. In order to improve the adsorption capacity of MOFs, pore engineering and site modulating strategies have been accepted to optimize the pore structure of MOFs and to strengthen/increase the adsorption sites. Meanwhile, MOF adsorbents could also treat multi-component pollutants at low concentrations. Hydrophobic or flexible MOFs have been designed to achieve selective adsorption. Pore partition and site modification have been used to create tailored apertures and sites for binding each component. In order to promote the practical application of MOF adsorbents, research on the processing and shaping of MOFs has also been summarised. Finally, this review also lists the practical applications of MOF adsorbents, verifying the considerable potential of MOFs for adsorption under ambient conditions.

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引用次数: 0

Membranes constructing with excellent performances for aqueous zinc-ion battery: A review

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-08 DOI: 10.1016/j.ccr.2025.216478

Juan Wu , Mengyao Li , Haoyu Li , Zhezhe Wang , Ting Chen , Yude Wang

Aqueous Zinc-ion batteries (AZIBs) have attracted considerable attention as promising energy storage devices, because of the advantages of inherent high safety, superior theoretical capacity, and impressive chemical stability. However, zinc (Zn) anodes of the AZIBs are prone to significant dendrite growth, corrosion, passivation, and other side reactions. These challenges can severely undermine the stability of Zn anodes and further diminish the Coulombic efficiency of AZIBs. The functional membranes can effectively balance the flux of Zn²⁺ ions, homogenize the electric field distribution at the Zn anode interface, and suppress the self-discharge phenomenon of the battery, thereby achieving a dendrite-free Zn anode. Currently, AZIBs primarily utilize glass fibers (GF) as membranes; however, their considerable thickness and uneven pore size distribution can cause inconsistent carrier density at the Zn anode interface, leading to more significant interfacial issues. Some reviews have been reported about membranes in recent years, but there remains a deficiency of in-depth analysis regarding the impact of membrane modification strategies on the performance of Zn anodes. This work summarizes various membrane modification strategies, analyzes the mechanisms by which these strategies affect Zn anodes, and ultimately provides a systematic outlook on membrane design strategies and their intrinsic mechanisms for AZIBs in future commercial applications.

{"title":"Membranes constructing with excellent performances for aqueous zinc-ion battery: A review","authors":"Juan Wu , Mengyao Li , Haoyu Li , Zhezhe Wang , Ting Chen , Yude Wang","doi":"10.1016/j.ccr.2025.216478","DOIUrl":"10.1016/j.ccr.2025.216478","url":null,"abstract":"<div><div>Aqueous Zinc-ion batteries (AZIBs) have attracted considerable attention as promising energy storage devices, because of the advantages of inherent high safety, superior theoretical capacity, and impressive chemical stability. However, zinc (Zn) anodes of the AZIBs are prone to significant dendrite growth, corrosion, passivation, and other side reactions. These challenges can severely undermine the stability of Zn anodes and further diminish the Coulombic efficiency of AZIBs. The functional membranes can effectively balance the flux of Zn<sup>2+</sup> ions, homogenize the electric field distribution at the Zn anode interface, and suppress the self-discharge phenomenon of the battery, thereby achieving a dendrite-free Zn anode. Currently, AZIBs primarily utilize glass fibers (GF) as membranes; however, their considerable thickness and uneven pore size distribution can cause inconsistent carrier density at the Zn anode interface, leading to more significant interfacial issues. Some reviews have been reported about membranes in recent years, but there remains a deficiency of in-depth analysis regarding the impact of membrane modification strategies on the performance of Zn anodes. This work summarizes various membrane modification strategies, analyzes the mechanisms by which these strategies affect Zn anodes, and ultimately provides a systematic outlook on membrane design strategies and their intrinsic mechanisms for AZIBs in future commercial applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"531 ","pages":"Article 216478"},"PeriodicalIF":20.3,"publicationDate":"2025-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143350204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Emerging trends in MXene research: Synthesis, process and hybrid with nanomaterials for biosensing

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-08 DOI: 10.1016/j.ccr.2025.216493

Weiqiang Li , Guoyang Xie , Hengyi Xu

As an emerging 2D materials, MXene has attracted great attention due to its advantageous electrical properties, mechanical properties and biocompatibility. In addition, unique layered structure, large specific surface area, low work function and high electronegativity enable MXene as an ideal carrier to hybrid with nanomaterials through various strategies, including physical adsorption, in-situ reduction/growth, etc. These MXene hybrid nanomaterials have superior physicochemical properties and show great potential in sensing applications. In this review, we summarize the synthesis strategies and processing methods of MXene, and present their effects for sensing application. Then, the properties of MXene for sensing application including oxidation-resistant property, biocompatibility, hydrophilicity/hydrophobicity, and mechanical property are discussed. Subsequently, the mechanisms, motivations, and key challenges are introduced, followed by emphatically reviewed their assembly strategies and sensing application. Finally, we discuss the future perspectives for MXene hybrid nanomaterials and their application. It is believed that the MXene hybrid nanomaterials are crucial for the advancement of high-performance materials and the development of novel sensors.

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引用次数: 0

Bridging the gap between theory and treatment: Transition metal complexes as successful candidates in medicine

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-08 DOI: 10.1016/j.ccr.2025.216477

Sara Abdolmaleki , Alireza Aliabadi , Samad Khaksar

Transition metal complexes are a versatile area of research in the fields of chemistry, biochemistry, and medicine. Their unique electronic properties, reactivity patterns, and coordination chemistry make them valuable tools for understanding fundamental chemical principles and their interaction with biological molecules and systems, providing valuable insights into potential therapeutic strategies and the development of novel treatments for a wide range of diseases. This review explains the multifaceted role of transition metal complexes in the diagnosis and treatment of cancer and offers combination treatments as more effective solutions for cancer therapy. In addition, it is discussed that these compounds offer new opportunities to combat drug-resistant pathogens through their antibacterial, antifungal, antiviral, and antiparasitic activities. A series of transition metal complexes are presented that show promising results for the treatment of neurological diseases such as Alzheimer's, Parkinson's, multiple sclerosis, epilepsy, and stroke. Metal-organic frameworks (MOFs) are considered versatile platforms for the delivery of nucleic acids that offer specific benefits for the treatment of a range of diseases. The potential of metallic nanoparticles to improve tissue engineering is presented and it is discussed that integration of these nanoparticles into scaffolds can improve their properties and interactions with cells. Finally, it is argued that despite the potential benefits, researchers must address the challenges associated with metal complexes to continue to innovate and develop new strategies to combat disease and improve human health and well-being. This review focuses on the development and medical applications of transition metal complexes from the late 19th century to the present day.

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引用次数: 0

Chemiluminescent transition metal complexes: Mechanisms and applications

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-02-05 DOI: 10.1016/j.ccr.2025.216495

Jing-Hui Zhu , Mingrui Gu , Yahui Chen , Mingle Li , Xiaoqiang Chen , Juyoung Yoon , Xiaojun Peng

Chemiluminescence is an enchanting phenomenon involving the emission of photons intrinsically excited by chemical reactions, which has been broadly applied for analytical and bioanalytical sensing as well as theranostic applications. Luminescent transition metal complexes are competitive alternatives to traditional organic fluorophores, as they inherently possess multiple modifiable variations (metal centers, coordination ligands, and metal-ligand interplays) which can be intricately tuned to afford a large number of fascinating combinations with diverse functions and distinct mechanisms of action, providing unprecedented opportunities for innovative theranostic design. Transition metal complexes, like Ru(II), Ir(III), Cr(III), etc., have been employed for constructing chemiluminescence reaction systems. Interestingly, in addition to the merits exhibited by pure organic chemiluminophores, organometallic chemiluminescence systems displayed exceptional advantages, such as distinctive redox reactions on metal centers, easy-to-modify, tunable emission colors/brightness, adjustable reaction kinetics, excellent thermal- and photo-stability, and traceable cellular uptake regardless of metabolisms. However, compared to the thriving studies on pure organic chemiluminophores, the research on chemiluminescent transition metal complexes is still in its early stages though having a long history. Therefore, in this review, we summarize the reported designing principles and unique mechanisms of action exerted by various types of chemiluminescent transition metal complexes, with a focus on their applications in bioimaging and biomedical realms. The remaining challenges and future perspectives for chemiluminescence studies are also discussed. We believe this review can serve as a theoretical guide and application reference for the molecular design of innovative chemiluminophores for a wide variety of bio-applications.

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引用次数: 0