Pub Date : 2024-12-13DOI: 10.1016/j.ccr.2024.216395
Yan Zhang, Yuyue Zhou, Dalin Sun, Yingxia Nie, Deyu Wu, Lin Ban, Bing Tang, Song Yang, Hui Li, Tianyi Ma, Heng Zhang
Transition metal oxides have drawn considerable interest due to their distinctive structure, multiple notable oxidation states, non-toxicity, and environmental sustainability. In the field of catalysis research, a particularly promising and urgent area of focus is the creation of stable and highly effective catalysts based on transition metal oxides. The twin global issues of environmental degradation and energy scarcity demand the creation of novel eco-friendly solutions. These challenges underscore the urgent need for advancing cutting-edge sustainable technologies. Currently, significant attention is focused on photocatalysis, electrocatalysis, and photoelectrocatalysis as viable strategies for addressing energy conversion and environmental remediation challenges. CeO2 has emerged as a catalyst of great promise, primarily due to its unique surface characteristics and distinctive 4f electron configuration. Especially, the coordination of Ce4+ with O2− in CeO2, involving Ce(IV) to O(II) charge transfer, yields a critical defect and a highly active surface. Nevertheless, the limited light-absorbing capacity and electrical conductivity of traditional CeO2 hinder its practical application. Consequently, developing diverse strategies to introduce abundant defects and active sites is pivotal for expanding the catalytic applications of CeO2. This review offers an in-depth overview of recent progress in CeO2-based catalytic systems for photocatalytic, electrocatalytic, and photoelectrocatalytic applications, with a focus on sustainable energy production and environmental pollution mitigation. This review emphasizes the synthesis methods of diverse tailored microstructures (including microspheres, hollows, core-shells, and polytopes) of CeO2, as well as strategies to enhance its catalytic activity via elemental doping, atomic loading, and coupling with oxides, MOFs, and carbonaceous materials to modulate the electronic coordination structure. Additionally, the discussion focuses on the catalytic activities, stabilities, and reaction mechanisms of CeO2-based catalysts, including oxygen vacancy defects, interfacial effects, bonding of reaction product intermediates to catalyst metal active sites, and metal-carrier interactions. Furthermore, this review presents a detailed description of quantitative characterization methods for evaluating oxidation states and oxygen vacancies in CeO2-based materials. Furthermore, the review highlights the current challenges and potential prospects in this research area. By providing a comprehensive update on the latest advances, this review aims to facilitate the informed design of high-performance CeO2-based composite catalysts, serving as a valuable resource for the pursuit of sustainable development goals.
{"title":"CeO2-based functional materials: Advancing photo and electro-driven catalysis for environmental remediation and energy conversion","authors":"Yan Zhang, Yuyue Zhou, Dalin Sun, Yingxia Nie, Deyu Wu, Lin Ban, Bing Tang, Song Yang, Hui Li, Tianyi Ma, Heng Zhang","doi":"10.1016/j.ccr.2024.216395","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216395","url":null,"abstract":"Transition metal oxides have drawn considerable interest due to their distinctive structure, multiple notable oxidation states, non-toxicity, and environmental sustainability. In the field of catalysis research, a particularly promising and urgent area of focus is the creation of stable and highly effective catalysts based on transition metal oxides. The twin global issues of environmental degradation and energy scarcity demand the creation of novel eco-friendly solutions. These challenges underscore the urgent need for advancing cutting-edge sustainable technologies. Currently, significant attention is focused on photocatalysis, electrocatalysis, and photoelectrocatalysis as viable strategies for addressing energy conversion and environmental remediation challenges. CeO<sub>2</sub> has emerged as a catalyst of great promise, primarily due to its unique surface characteristics and distinctive 4f electron configuration. Especially, the coordination of Ce<sup>4+</sup> with O<sub>2</sub><sup>−</sup> in CeO<sub>2</sub>, involving Ce(IV) to O(II) charge transfer, yields a critical defect and a highly active surface. Nevertheless, the limited light-absorbing capacity and electrical conductivity of traditional CeO<sub>2</sub> hinder its practical application. Consequently, developing diverse strategies to introduce abundant defects and active sites is pivotal for expanding the catalytic applications of CeO<sub>2</sub>. This review offers an in-depth overview of recent progress in CeO<sub>2</sub>-based catalytic systems for photocatalytic, electrocatalytic, and photoelectrocatalytic applications, with a focus on sustainable energy production and environmental pollution mitigation. This review emphasizes the synthesis methods of diverse tailored microstructures (including microspheres, hollows, core-shells, and polytopes) of CeO<sub>2</sub>, as well as strategies to enhance its catalytic activity via elemental doping, atomic loading, and coupling with oxides, MOFs, and carbonaceous materials to modulate the electronic coordination structure. Additionally, the discussion focuses on the catalytic activities, stabilities, and reaction mechanisms of CeO<sub>2</sub>-based catalysts, including oxygen vacancy defects, interfacial effects, bonding of reaction product intermediates to catalyst metal active sites, and metal-carrier interactions. Furthermore, this review presents a detailed description of quantitative characterization methods for evaluating oxidation states and oxygen vacancies in CeO<sub>2</sub>-based materials. Furthermore, the review highlights the current challenges and potential prospects in this research area. By providing a comprehensive update on the latest advances, this review aims to facilitate the informed design of high-performance CeO<sub>2</sub>-based composite catalysts, serving as a valuable resource for the pursuit of sustainable development goals.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"8 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142820750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-11DOI: 10.1016/j.ccr.2024.216353
Hamid Ali, Yasin Orooji, Zeeshan Ajmal, Mohamed Abboud, Ahmed M. Abu-Dief, Khulood A. Abu Al-Ola, Hassan M.A. Hassan, Dewu Yue, Sheng-Rong Guo, Asif Hayat
Transition metal nitrides (TMNs) are emerging as versatile materials with significant potential across various fields due to their unique properties and functionalities. This review provides a comprehensive overview of TMNs, covering their crystal structure, stability, and the unique advantages they offer. TMNs exhibit superior catalytic activity, lower sintering sensitivity, and high selectivity, while operating at reduced temperatures. Density functional theory (DFT) studies have addressed their diverse properties, including electronic, optical, vibrational, plasmonic, mechanical, bulk, magnetic, structural, and morphological characteristics. The review categorizes TMNs into different types: unitary, binary, ternary, and quaternary nitrides, and explores various synthesis methods such as ammonolysis, chemical vapor deposition (CVD), electrodeposition, and pyrolysis. Additionally, it discusses the classification of TMNs into single metal-source nitrides and composite metal-source nitrides, highlighting materials like Fe<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>N, Co<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>N, and Ti<img alt="single bond" src="https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif" style="vertical-align:middle"/>N. Similarly, the functionalization strategies are also examined, covering boron-based, cyanide-based, and graphene-based TMNs etc. among others. The review evaluates the morphology of TMNs, including nanoflowers, nanospheres, and nanowires, and their influence on performance. Finally, the applications of TMNs are explored in detail, focusing on their performance in photocatalytic reactions (hydrogen (H<sub>2</sub>) evolution, oxygen (O<sub>2</sub>) evolution, overall water splitting, hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) production, carbon dioxide (CO<sub>2</sub>) reduction, and degradation), electrocatalysis (H<sub>2</sub> evolution reaction, O<sub>2</sub> evolution reaction, overall water splitting, CO<sub>2</sub> reduction), energy storage (batteries and supercapacitors), and solar cells. This synthesis of material highlights the extensive use and future promise of TMNs in enhancing technical advancements. This study aims to provide an extensive foundation that covers every aspect of TMNs, with a particular focus on their many functional features, unique morphologies, and dimensions. Our comprehensive approach provides readers with an in-depth understanding of TMNs properties and potential applications, setting our review apart through its extensive coverage and detailed analysis. This thorough overview highlights the enormous potential of TMNs to drive advancements in various technological and scientific fields.<h3>Novelty of this study</h3>The novel
{"title":"A comprehensive Review based on the synthesis, properties, morphology, functionalization, and potential applications of transition metals nitrides","authors":"Hamid Ali, Yasin Orooji, Zeeshan Ajmal, Mohamed Abboud, Ahmed M. Abu-Dief, Khulood A. Abu Al-Ola, Hassan M.A. Hassan, Dewu Yue, Sheng-Rong Guo, Asif Hayat","doi":"10.1016/j.ccr.2024.216353","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216353","url":null,"abstract":"Transition metal nitrides (TMNs) are emerging as versatile materials with significant potential across various fields due to their unique properties and functionalities. This review provides a comprehensive overview of TMNs, covering their crystal structure, stability, and the unique advantages they offer. TMNs exhibit superior catalytic activity, lower sintering sensitivity, and high selectivity, while operating at reduced temperatures. Density functional theory (DFT) studies have addressed their diverse properties, including electronic, optical, vibrational, plasmonic, mechanical, bulk, magnetic, structural, and morphological characteristics. The review categorizes TMNs into different types: unitary, binary, ternary, and quaternary nitrides, and explores various synthesis methods such as ammonolysis, chemical vapor deposition (CVD), electrodeposition, and pyrolysis. Additionally, it discusses the classification of TMNs into single metal-source nitrides and composite metal-source nitrides, highlighting materials like Fe<img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/>N, Co<img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/>N, and Ti<img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/>N. Similarly, the functionalization strategies are also examined, covering boron-based, cyanide-based, and graphene-based TMNs etc. among others. The review evaluates the morphology of TMNs, including nanoflowers, nanospheres, and nanowires, and their influence on performance. Finally, the applications of TMNs are explored in detail, focusing on their performance in photocatalytic reactions (hydrogen (H<sub>2</sub>) evolution, oxygen (O<sub>2</sub>) evolution, overall water splitting, hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) production, carbon dioxide (CO<sub>2</sub>) reduction, and degradation), electrocatalysis (H<sub>2</sub> evolution reaction, O<sub>2</sub> evolution reaction, overall water splitting, CO<sub>2</sub> reduction), energy storage (batteries and supercapacitors), and solar cells. This synthesis of material highlights the extensive use and future promise of TMNs in enhancing technical advancements. This study aims to provide an extensive foundation that covers every aspect of TMNs, with a particular focus on their many functional features, unique morphologies, and dimensions. Our comprehensive approach provides readers with an in-depth understanding of TMNs properties and potential applications, setting our review apart through its extensive coverage and detailed analysis. This thorough overview highlights the enormous potential of TMNs to drive advancements in various technological and scientific fields.<h3>Novelty of this study</h3>The novel","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"26 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142809817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-11DOI: 10.1016/j.ccr.2024.216380
Mustapha Umar, Basiru O. Yusuf, Mansur Aliyu, Ijaz Hussain, Aliyu M. Alhassan, Mohammed Mosaad Awad, Omer A. Taialla, Babar Ali, Khalid R. Alhooshani, Saheed A. Ganiyu
As the urgency to mitigate climate change intensifies, innovative solutions for CO2 capture have become paramount. This review highlights the revolutionary impact of biomass-derived carbon materials in the field of CO2 capture. These materials, sourced from agricultural residues, forestry waste, and other organic matter, offer a sustainable, cost-effective, and highly efficient alternative to conventional capture technologies. Key findings of this review highlight the superior CO2 adsorption capabilities of biomass-derived carbon materials, stemming from their large surface area and tunable pore structures. The review reveals that these materials outperform traditional sorbents like zeolites, metal-organic frameworks (MOFs), and amines in both efficiency and environmental impact. The life cycle assessments (LCAs) discussed demonstrate significant reductions in greenhouse gas emissions and energy demands when using biomass-derived carbons compared to coal-based systems. For instance, biochar-derived activated carbon exhibits 35% lower cradle-to-product gate energy demand and produces less than half the greenhouse gas emissions of coal-derived activated carbon. Moreover, the review underscores the versatility of synthesis methods such as pyrolysis and hydrothermal carbonization, which can be precisely adjusted to improve the effectiveness of these materials. Innovations like surface modifications and heteroatom doping are further pushing the boundaries of what biomass-derived carbons can achieve in CO2 capture applications. By exploring a wide range of case studies and industrial-scale applications, this review not only illustrates the practical benefits of these materials but also sets the stage for future advancements. These findings suggest a promising path forward for scalable, efficient, and sustainable CO2 capture technologies, marking a significant step toward a greener and more resilient future.
{"title":"Advancing frontiers in CO2 capture: The renaissance of biomass-derived carbon materials","authors":"Mustapha Umar, Basiru O. Yusuf, Mansur Aliyu, Ijaz Hussain, Aliyu M. Alhassan, Mohammed Mosaad Awad, Omer A. Taialla, Babar Ali, Khalid R. Alhooshani, Saheed A. Ganiyu","doi":"10.1016/j.ccr.2024.216380","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216380","url":null,"abstract":"As the urgency to mitigate climate change intensifies, innovative solutions for CO<sub>2</sub> capture have become paramount. This review highlights the revolutionary impact of biomass-derived carbon materials in the field of CO<sub>2</sub> capture. These materials, sourced from agricultural residues, forestry waste, and other organic matter, offer a sustainable, cost-effective, and highly efficient alternative to conventional capture technologies. Key findings of this review highlight the superior CO<sub>2</sub> adsorption capabilities of biomass-derived carbon materials, stemming from their large surface area and tunable pore structures. The review reveals that these materials outperform traditional sorbents like zeolites, metal-organic frameworks (MOFs), and amines in both efficiency and environmental impact. The life cycle assessments (LCAs) discussed demonstrate significant reductions in greenhouse gas emissions and energy demands when using biomass-derived carbons compared to coal-based systems. For instance, biochar-derived activated carbon exhibits 35% lower cradle-to-product gate energy demand and produces less than half the greenhouse gas emissions of coal-derived activated carbon. Moreover, the review underscores the versatility of synthesis methods such as pyrolysis and hydrothermal carbonization, which can be precisely adjusted to improve the effectiveness of these materials. Innovations like surface modifications and heteroatom doping are further pushing the boundaries of what biomass-derived carbons can achieve in CO<sub>2</sub> capture applications. By exploring a wide range of case studies and industrial-scale applications, this review not only illustrates the practical benefits of these materials but also sets the stage for future advancements. These findings suggest a promising path forward for scalable, efficient, and sustainable CO<sub>2</sub> capture technologies, marking a significant step toward a greener and more resilient future.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"4 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142804712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-10DOI: 10.1016/j.ccr.2024.216381
Pei-Hong Tong, Jing-Jie Yang, Yu-Fan Zhou, Yi-Fan Tang, Meng-Tian Tang, Yi Zang, Yu-Fei Pan, Li-Wei Dong, Ye-Xiong Tan, Ki Taek Nam, Xi-Le Hu, He Huang, Jia Li, Hong-Yang Wang, Tony D. James, Juyoung Yoon, Xiao-Peng He
Phototherapy is a form of light-mediated therapy, which includes photodynamic therapy (PDT) photothermal therapy (PTT), and the recently emerging photoimmunotherapy (PIT). PTT, PDT, PIT and their combinations with conventional chemotherapeutics have been used extensively to treat cancer due to their outstanding therapeutic efficacy, are non-invasive, mitigate side effects, and display spatial selectivity for a target organ. In addition to the many anticancer phototherapeutic agents developed, metal-organic frameworks (MOFs) are a new generation of promising light-responsive materials owing to their readily tunable chemical structures through simple coordination chemistry as well as their morphological diversity. When properly designed, MOFs can also serve as photodynamic and/or photothermal agents themselves whilst being a carrier to deliver chemo- and macromolecular therapeutic agents owing to their highly tunable porosity. This review highlights recent research progresses made in the development of MOFs-based materials for phototherapy and synergistic phototherapy, as well as discussing any remaining challenges.
{"title":"Metal-organic frameworks (MOFs) for phototherapy and synergistic phototherapy of cancer","authors":"Pei-Hong Tong, Jing-Jie Yang, Yu-Fan Zhou, Yi-Fan Tang, Meng-Tian Tang, Yi Zang, Yu-Fei Pan, Li-Wei Dong, Ye-Xiong Tan, Ki Taek Nam, Xi-Le Hu, He Huang, Jia Li, Hong-Yang Wang, Tony D. James, Juyoung Yoon, Xiao-Peng He","doi":"10.1016/j.ccr.2024.216381","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216381","url":null,"abstract":"Phototherapy is a form of light-mediated therapy, which includes photodynamic therapy (PDT) photothermal therapy (PTT), and the recently emerging photoimmunotherapy (PIT). PTT, PDT, PIT and their combinations with conventional chemotherapeutics have been used extensively to treat cancer due to their outstanding therapeutic efficacy, are non-invasive, mitigate side effects, and display spatial selectivity for a target organ. In addition to the many anticancer phototherapeutic agents developed, metal-organic frameworks (MOFs) are a new generation of promising light-responsive materials owing to their readily tunable chemical structures through simple coordination chemistry as well as their morphological diversity. When properly designed, MOFs can also serve as photodynamic and/or photothermal agents themselves whilst being a carrier to deliver chemo- and macromolecular therapeutic agents owing to their highly tunable porosity. This review highlights recent research progresses made in the development of MOFs-based materials for phototherapy and synergistic phototherapy, as well as discussing any remaining challenges.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"28 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142797276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chiral discrimination is crucial in drug safety, catalysis, materials science, and environmental sustainability, as enantiomers often exhibit distinct biological, chemical, and physical properties. Raman spectroscopic technologies have established efficient strategies for discriminating enantiomers through manipulating the Raman excitation and scattering light, as well as constructing chiral molecular recognition systems and chiral surface-enhanced Raman spectroscopy (SERS) substrates, which offer the advantages of non-destructive, label-free, and real-time analysis. This review systematically summarizes the principles and recent advances in Raman spectroscopic technologies for discriminating enantiomers. We begin by introducing the fundamental mechanisms and experimental progress of Raman optical activity (ROA), highlighting its importance in enantiomeric discrimination. Moving beyond the complex instruments used in ROA-based methods, we discuss critical breakthroughs in enantiomeric discrimination by combining plasmonic structures with conventional Raman spectrometers. The emerging strategies to discriminate enantiomers by both achiral and chiral plasmonic structures are summarized, with particular emphasis on the underlying mechanisms of chiral plasmonic structures in enantioselective SERS. Finally, we present the major challenges and future opportunities in this evolving field, providing insights into the future development directions.
{"title":"Raman spectroscopic technologies for chiral discrimination: Current status and new frontiers","authors":"Yu Tian, Ge Fang, Fengxia Wu, Juliana Gaithan Kauno, Haili Wei, Hsien-Yi Hsu, Fenghua Li, Guobao Xu, Wenxin Niu","doi":"10.1016/j.ccr.2024.216375","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216375","url":null,"abstract":"Chiral discrimination is crucial in drug safety, catalysis, materials science, and environmental sustainability, as enantiomers often exhibit distinct biological, chemical, and physical properties. Raman spectroscopic technologies have established efficient strategies for discriminating enantiomers through manipulating the Raman excitation and scattering light, as well as constructing chiral molecular recognition systems and chiral surface-enhanced Raman spectroscopy (SERS) substrates, which offer the advantages of non-destructive, label-free, and real-time analysis. This review systematically summarizes the principles and recent advances in Raman spectroscopic technologies for discriminating enantiomers. We begin by introducing the fundamental mechanisms and experimental progress of Raman optical activity (ROA), highlighting its importance in enantiomeric discrimination. Moving beyond the complex instruments used in ROA-based methods, we discuss critical breakthroughs in enantiomeric discrimination by combining plasmonic structures with conventional Raman spectrometers. The emerging strategies to discriminate enantiomers by both achiral and chiral plasmonic structures are summarized, with particular emphasis on the underlying mechanisms of chiral plasmonic structures in enantioselective SERS. Finally, we present the major challenges and future opportunities in this evolving field, providing insights into the future development directions.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"21 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142797731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-09DOI: 10.1016/j.ccr.2024.216356
Xiaoyu Qiu, Rui Wang
The creation of defects in metal-organic frameworks (MOFs), known as defect engineering, offers an additional way for MOFs to personalize their specific functions and applications. Defect engineering not only provides new opportunities for MOFs in the fields of adsorption and catalysis, but also opens up a new avenue in terms of physical properties such as mechanical response and conductance. In this review, we focus on two classes of synthetic strategies (de novo synthesis and post-synthetic modification) for defective MOFs and their applications in the fundamental field, the effects of defect engineering on MOFs performance are as well discussed in detail. In the end, we highlight the challenges and future developments that can be expected about defective MOFs. Overall, this review can be applied as a potent tool for revealing the structure–activity relationships and accelerating the on-demand design of defective MOFs. We also hope this review will provide powerful assistance to researchers in utilizing defect engineering for switching new avenues for MOFs, enabling the better design and synthesis of new materials with specific functionalities.
{"title":"From construction strategies to applications: Multifunctional defective metal-organic frameworks","authors":"Xiaoyu Qiu, Rui Wang","doi":"10.1016/j.ccr.2024.216356","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216356","url":null,"abstract":"The creation of defects in metal-organic frameworks (MOFs), known as defect engineering, offers an additional way for MOFs to personalize their specific functions and applications. Defect engineering not only provides new opportunities for MOFs in the fields of adsorption and catalysis, but also opens up a new avenue in terms of physical properties such as mechanical response and conductance. In this review, we focus on two classes of synthetic strategies (de novo synthesis and post-synthetic modification) for defective MOFs and their applications in the fundamental field, the effects of defect engineering on MOFs performance are as well discussed in detail. In the end, we highlight the challenges and future developments that can be expected about defective MOFs. Overall, this review can be applied as a potent tool for revealing the structure–activity relationships and accelerating the on-demand design of defective MOFs. We also hope this review will provide powerful assistance to researchers in utilizing defect engineering for switching new avenues for MOFs, enabling the better design and synthesis of new materials with specific functionalities.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"234 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142797730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-06DOI: 10.1016/j.ccr.2024.216354
Ji Zhou, Shuangxi Gu, Yuqin Xiang, Yun Xiong, Genyan Liu
UiO-67 species, a prominent class of metal-organic frameworks (MOFs) within the UiO (University of Oslo) subgroup, possess unique features. These include diverse synthetic methods, a wide variety of structures, host-guest chemistry, large and uniform pores, tunable surfaces, and flexible network topology, geometry, dimension, and chemical functionality. Due to these features, UiO-67 demonstrates remarkable potential applications in various scientific and life science fields. Literature surveys show that UiO-67 exhibits competitive and promising applications compared to other MOFs and even its close relatives, UiO-66 and UiO-68. Despite the rich chemistry and rapidly growing research on UiO-67, particularly in recent years, a comprehensive review of its applications is lacking. This review aims to fill this gap by providing the first systematic and complete classification of Zr-based UiO-67 MOF applications, synthetic methods, design and structures since 2008. The contents are categorized into key areas: design and synthesize, structural landscape, applications including, catalysis, adsorption, separation, sensing, medicine/drug delivery, and energy storage/conversion. Each category is further subdivided for specific applications. While the primary focus is on applications, the review also incorporates discussions on synthetic pathways and comparative studies. Finally, future perspectives for Zr-UiO-67 applications are explored, aiming to contribute to their wider use in multidisciplinary chemistry. Future research should focus on expanding the application of Zr-UiO-67 MOFs in diverse fields. This includes further exploration of their potential in CO2 capture and conversion, organic transformations, and CC bond formation catalysis. Additionally, the development of UiO-67-based materials for water treatment, environmental remediation, biosensing, drug delivery, and energy storage will be crucial.
UiO-67是UiO （University of Oslo）亚群中一类突出的金属有机骨架（mof），具有独特的特征。这些包括不同的合成方法、各种各样的结构、主客体化学、大而均匀的孔、可调的表面、灵活的网络拓扑、几何、尺寸和化学功能。由于这些特点，UiO-67在各种科学和生命科学领域显示出巨大的应用潜力。文献调查表明，与其他mof及其近亲UiO-66和UiO-68相比，UiO-67具有竞争力和广阔的应用前景。尽管UiO-67具有丰富的化学性质和快速增长的研究，特别是近年来，缺乏对其应用的全面回顾。本文旨在通过对2008年以来基于zr的UiO-67 MOF的应用、合成方法、设计和结构进行首次系统完整的分类来填补这一空白。内容分为：设计与合成、结构景观、应用包括催化、吸附、分离、传感、医学/药物传递和能量存储/转换。每个类别都进一步细分为特定的应用程序。虽然主要侧重于应用，但综述也包括对合成途径和比较研究的讨论。最后，对Zr-UiO-67的应用前景进行了展望，旨在促进其在多学科化学中的广泛应用。未来的研究应着眼于扩大Zr-UiO-67 mof在不同领域的应用。这包括进一步探索它们在二氧化碳捕获和转化、有机转化和CC键形成催化方面的潜力。此外，开发基于uio -67的材料用于水处理、环境修复、生物传感、药物输送和能量储存将是至关重要的。
{"title":"UiO-67: A versatile metal-organic framework for diverse applications","authors":"Ji Zhou, Shuangxi Gu, Yuqin Xiang, Yun Xiong, Genyan Liu","doi":"10.1016/j.ccr.2024.216354","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216354","url":null,"abstract":"UiO-67 species, a prominent class of metal-organic frameworks (MOFs) within the UiO (University of Oslo) subgroup, possess unique features. These include diverse synthetic methods, a wide variety of structures, host-guest chemistry, large and uniform pores, tunable surfaces, and flexible network topology, geometry, dimension, and chemical functionality. Due to these features, UiO-67 demonstrates remarkable potential applications in various scientific and life science fields. Literature surveys show that UiO-67 exhibits competitive and promising applications compared to other MOFs and even its close relatives, UiO-66 and UiO-68. Despite the rich chemistry and rapidly growing research on UiO-67, particularly in recent years, a comprehensive review of its applications is lacking. This review aims to fill this gap by providing the first systematic and complete classification of Zr-based UiO-67 MOF applications, synthetic methods, design and structures since 2008. The contents are categorized into key areas: design and synthesize, structural landscape, applications including, catalysis, adsorption, separation, sensing, medicine/drug delivery, and energy storage/conversion. Each category is further subdivided for specific applications. While the primary focus is on applications, the review also incorporates discussions on synthetic pathways and comparative studies. Finally, future perspectives for Zr-UiO-67 applications are explored, aiming to contribute to their wider use in multidisciplinary chemistry. Future research should focus on expanding the application of Zr-UiO-67 MOFs in diverse fields. This includes further exploration of their potential in CO<sub>2</sub> capture and conversion, organic transformations, and C<img alt=\"single bond\" src=\"https://sdfestaticassets-us-east-1.sciencedirectassets.com/shared-assets/55/entities/sbnd.gif\" style=\"vertical-align:middle\"/>C bond formation catalysis. Additionally, the development of UiO-67-based materials for water treatment, environmental remediation, biosensing, drug delivery, and energy storage will be crucial.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"79 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142782980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
InP quantum dots (QDs), owing to their non-toxicity, exceptional optoelectronic properties, and great potential as a substitute for Cd/Pb-based QDs, have garnered significant attention. As a straightforward yet effective strategy for modulating the performance of InP QDs, cation doping has lately emerged as a predominant approach. In this review, the mechanisms and performance tuning achieved through cation doping are delved into, covering aspects of growth kinetics, interface modification, and carrier modulation. A comprehensive analysis and summary of recent advances from preparation to applications including light emitting diodes (LEDs), catalysis, and bioimaging in various cation doping systems are presented. Finally, some perspectives and possible directions for the future development of cation-doped InP QDs are discussed. This review offers a thorough insight into performance enhancements achieved through cation doping in InP QDs, intending to facilitate the design and advance the application of next-generation, high-quality InP QDs technologies.
{"title":"Cation engineering modified InP quantum dots for enhanced properties and diversified applications","authors":"Rui Jiang, Jie Zhao, Maoyuan Huang, Zhongjie Cui, Shiliang Mei, Wanlu Zhang, Ruiqian Guo","doi":"10.1016/j.ccr.2024.216376","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216376","url":null,"abstract":"InP quantum dots (QDs), owing to their non-toxicity, exceptional optoelectronic properties, and great potential as a substitute for Cd/Pb-based QDs, have garnered significant attention. As a straightforward yet effective strategy for modulating the performance of InP QDs, cation doping has lately emerged as a predominant approach. In this review, the mechanisms and performance tuning achieved through cation doping are delved into, covering aspects of growth kinetics, interface modification, and carrier modulation. A comprehensive analysis and summary of recent advances from preparation to applications including light emitting diodes (LEDs), catalysis, and bioimaging in various cation doping systems are presented. Finally, some perspectives and possible directions for the future development of cation-doped InP QDs are discussed. This review offers a thorough insight into performance enhancements achieved through cation doping in InP QDs, intending to facilitate the design and advance the application of next-generation, high-quality InP QDs technologies.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"19 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142782975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-06DOI: 10.1016/j.ccr.2024.216355
George Elsa, Abdul Hanan, Rashmi Walvekar, Arshid Numan, Mohammad Khalid
Zirconium (Zr) based MXenes are a new type of two–dimensional (2D) transition metal carbides and carbonitrides that have attracted significant research interest in recent years. These materials exhibit a unique combination of physicochemical properties, making them attractive for a wide range of applications. Despite this growing attention, a systematic review of their synthesis methods, material properties, and applications is still lacking. This review provides a comprehensive overview of the state of research on Zr–MXenes, covering various aspects from synthesis to applications. The discussion includes an in–depth analysis of the different wet–chemical etching protocols used to obtain Zr–MXenes from Zr–containing MAX phases and the impact of these methods on the morphology of materials. Detailed characterization techniques have revealed important properties of Zr–MXenes, such as hydrophilicity, electrical conductivity, and ion storage capability. Further, this review examines the potential applications of Zr–MXenes in various fields, including energy storage, electromagnetic interference shielding, corrosion prevention, and biomedical applications. While, Zr–MXenes offer promising prospects, challenges related to large–scale production and property optimization must be addressed to facilitate their widespread adoption. By providing a comprehensive overview of Zr–MXene synthesis, properties, and applications, this review aims to inspire and guide future research and development efforts toward the rational design and utilization of these promising 2D nanomaterials.
{"title":"Zirconium–based MXenes: Synthesis, properties, applications, and prospects","authors":"George Elsa, Abdul Hanan, Rashmi Walvekar, Arshid Numan, Mohammad Khalid","doi":"10.1016/j.ccr.2024.216355","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216355","url":null,"abstract":"Zirconium (Zr) based MXenes are a new type of two–dimensional (2D) transition metal carbides and carbonitrides that have attracted significant research interest in recent years. These materials exhibit a unique combination of physicochemical properties, making them attractive for a wide range of applications. Despite this growing attention, a systematic review of their synthesis methods, material properties, and applications is still lacking. This review provides a comprehensive overview of the state of research on Zr–MXenes, covering various aspects from synthesis to applications. The discussion includes an in–depth analysis of the different wet–chemical etching protocols used to obtain Zr–MXenes from Zr–containing MAX phases and the impact of these methods on the morphology of materials. Detailed characterization techniques have revealed important properties of Zr–MXenes, such as hydrophilicity, electrical conductivity, and ion storage capability. Further, this review examines the potential applications of Zr–MXenes in various fields, including energy storage, electromagnetic interference shielding, corrosion prevention, and biomedical applications. While, Zr–MXenes offer promising prospects, challenges related to large–scale production and property optimization must be addressed to facilitate their widespread adoption. By providing a comprehensive overview of Zr–MXene synthesis, properties, and applications, this review aims to inspire and guide future research and development efforts toward the rational design and utilization of these promising 2D nanomaterials.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"4 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142782981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-06DOI: 10.1016/j.ccr.2024.216361
Lina He, Ziqi Wang, Hong Wang, Yi-nan Wu
Metal-organic frameworks (MOFs), as emerging porous crystalline materials comprising metal ions/clusters and organic linkers, display significant potential for applications in adsorption, separation, catalysis, and other environmental domains, owing to their intrinsic structural diversity. However, the stability of MOFs under various environmental conditions remains a critical challenge, potentially hindering their broader practical adoption. Hence, a thorough understanding of the effects of environmental factors on MOF stability is imperative. This review explores the impact of essential environmental parameters—including liquid water/moisture, acids/bases, coordinating anions, solar irradiation, bacteria, oxidation-reduction potential, natural organic matter, and minerals—on the structural integrity of MOFs. The underlying mechanisms by which these factors affect MOF stability are elucidated, and MOFs are classified according to their resilience or susceptibility under specific environmental conditions. Furthermore, illustrative case studies of both robust and vulnerable MOFs are discussed to highlight the principles guiding the selection of MOFs for diverse practical applications. The challenges and future direction in this field are also proposed. Overall, this review aims to serve as a critical resource, facilitating the effective transition of MOFs from laboratory settings to real implementations, thereby enhancing their practical utility and effectiveness in addressing challenges of environmental pollution control and energy-related issues.
{"title":"Are MOFs ready for environmental applications: Assessing stability against natural stressors?","authors":"Lina He, Ziqi Wang, Hong Wang, Yi-nan Wu","doi":"10.1016/j.ccr.2024.216361","DOIUrl":"https://doi.org/10.1016/j.ccr.2024.216361","url":null,"abstract":"Metal-organic frameworks (MOFs), as emerging porous crystalline materials comprising metal ions/clusters and organic linkers, display significant potential for applications in adsorption, separation, catalysis, and other environmental domains, owing to their intrinsic structural diversity. However, the stability of MOFs under various environmental conditions remains a critical challenge, potentially hindering their broader practical adoption. Hence, a thorough understanding of the effects of environmental factors on MOF stability is imperative. This review explores the impact of essential environmental parameters—including liquid water/moisture, acids/bases, coordinating anions, solar irradiation, bacteria, oxidation-reduction potential, natural organic matter, and minerals—on the structural integrity of MOFs. The underlying mechanisms by which these factors affect MOF stability are elucidated, and MOFs are classified according to their resilience or susceptibility under specific environmental conditions. Furthermore, illustrative case studies of both robust and vulnerable MOFs are discussed to highlight the principles guiding the selection of MOFs for diverse practical applications. The challenges and future direction in this field are also proposed. Overall, this review aims to serve as a critical resource, facilitating the effective transition of MOFs from laboratory settings to real implementations, thereby enhancing their practical utility and effectiveness in addressing challenges of environmental pollution control and energy-related issues.","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"8 1","pages":""},"PeriodicalIF":20.6,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142782979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
C bond formation catalysis. Additionally, the development of UiO-67-based materials for water treatment, environmental remediation, biosensing, drug delivery, and energy storage will be crucial.
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